The present invention relates to a lens device where a focal length is variable.
In a head mounted display (HMD) such as augmented reality (AR) glasses, virtual reality (VR) glasses, or mixed reality (MR) glasses, a lens for focusing a video on a pupil of a user is provided. In a case where the user wears the head mounted display, a relative position between the HMD and the pupil changes depending on the user. Therefore, the lens moves in an optical axis direction to change the focal length of the lens. In this case, the thickness of the HMD in the optical axis direction increases, and a sufficient reduction in size cannot be achieved.
On the other hand, U.S. Pat. No. 10,877,277B describes an Alvarez lens where two liquid crystal films having a lens action are translated relative to each other in an in-plane direction to change the focal length of the lens.
However, in the configuration described in U.S. Pat. No. 10,877,277B where the two liquid crystal films are translated in the in-plane direction, although the thickness of the lens in the optical axis direction can be reduced, the size of a region acting as the lens is less than that of the liquid crystal film, and a space for translating the two liquid crystal films is required. Therefore, the size in the in-plane direction increases, and a reduction in size is not sufficient.
An object of the present invention is to solve the above-described problem of the related art and to provide a small lens device where a focal length is variable.
In order to achieve the object, the present invention has the following configurations.
[1] A lens device comprising:
[2] The lens device according to [1],
[3] The lens device according to [2],
[4] The lens device according to any one of [1] to [3], which functions as an axicon lens.
[5] The lens device according to any one of [1] to [3], which functions as a spherical lens.
[6] The lens device according to any one of [1] to [3], which functions as an aspherical lens.
According to the present invention, a small lens device where a focal length is variable can be provided.
Hereinafter, a lens device according to an embodiment of the present invention will be described in detail based on preferable embodiments shown in the accompanying drawings.
In the present specification, numerical ranges represented by “to” include numerical values before and after “to” as lower limit values and upper limit values.
In the present specification, the meaning of the term “the same”, “identical”, or the like includes a case where an error range is generally allowable in the technical field.
In the present specification, “(meth)acrylate” represents “either or both of acrylate and methacrylate”.
In the present specification, Re(λ) represents an in-plane retardation at a wavelength λ. Unless specified otherwise, the wavelength λ refers to 550 nm.
In the present specification, Re(λ) is a value measured at the wavelength λ using AxoScan (manufactured by Axometrics, Inc.). By inputting an average refractive index ((nx+ny+nz)/3) and a film thickness (d (μm)) to AxoScan, the following expression
Re(λ)=R0(λ)
R0(λ) is expressed as a numerical value calculated by AxoScan and represents Re(λ).
A lens device according to an embodiment of the present invention comprising:
A lens device 10 shown in
In the following description, in a case where the first liquid crystal layer 12 and the second liquid crystal layer 14 do not need to be distinguished from each other, they will also be collectively referred to as the liquid crystal layer.
The first liquid crystal layer 12 and the second liquid crystal layer 14 are formed using a composition including a liquid crystal compound, and an optical axis derived from the liquid crystal compound is aligned in a vortex alignment pattern described below. In order to align the liquid crystal compound in the desired vortex alignment pattern, for example, as shown in
For use as the lens device 10, the lens device 10 may be in a state where the first liquid crystal layer 12 and the second liquid crystal layer are laminated on a support 30 and the alignment film 32. Alternatively, the lens device 10 may be in a state where, for example, only the alignment film 32 and the liquid crystal layers are laminated after peeling off the support 30. Alternatively, the lens device 10 may be in a state where, for example, only the liquid crystal layers are laminated after peeling off the support 30 and the alignment film 32.
As shown in
As represented by the gray scale in
The phase will be described using
For example, the phase of a center portion 20a of the first liquid crystal layer will be described using
As shown in
Next, the phase of the annular portion will be described using
As shown in
Next, in the second annular portion (second annular portion) 22a from the center portion 20a toward the radial direction, in case of being seen counterclockwise in the circumferential direction of the second annular portion 22a, the orientation of the optical axis 40 in the fine region rotates 1.5 times counterclockwise. That is, in the example shown in the drawing, in the second annular portion 22a, while the phase rotates once from the position of 0 in the circumferential direction of the second annular portion 22a, a phase change from 0 to 2π is repeated three times. That is, the number of phase changes in the second annular portion 22a is increased by one from that of the first annular portion 21a.
In the first liquid crystal layer 12, likewise, even in the third or subsequent annular portion from the center portion 20a toward the radial direction, in case of being seen counterclockwise in the circumferential direction, while the phase rotates once from the position of 0 in the circumferential direction of the annular portion, the phase change from 0 to 2π is repeated multiple times, and the number of repetitions of the phase change in one annular portion is increased by one from that of another annular portion inwardly adjacent thereto.
That is, in the n-th annular portion of the first liquid crystal layer 12 shown in
In the present invention, the first liquid crystal layer 12 includes the center portion and the plurality of annular portions, and in each of the center portion and the plurality of annular portions, the phase change in the circumferential direction is repeated once or more, and a pattern where the phase change is repeated n+m times (m represents the number of phase changes in the center portion) in the n-th annular portion will be referred to as the vortex alignment pattern.
In the vortex alignment pattern, in polar coordinates of r and φ with respect to the center of the center portion 20a of the first liquid crystal layer 12 as an origin, the angle θ1 [°] of the optical axis 40 in a region where φ is φ1 is represented by Expression 3a.
Here, θ0n1 [°] represents an angle of the optical axis of each of the center portion 20a and the annular portions at φ1=0°. In the examples shown in
A change in the angle θ1 of the optical axis 40 in the center portion 20a is represented by α1=m×0.5 in Expression 3a where m represents an integer of 1 or more. In addition, a change in the angle θ1 of the optical axis in the n-th annular portion from the center portion 20a is represented by α1=(m+n)×0.5 in Expression 3a.
m has the same definition as the number of phase changes in the center portion 20a, and in the examples shown in
In addition, Expression 3a in the first annular portion 21a of the example shown in
In addition, Expression 3a in the second annular portion 22a of the example shown in
Even in the n-th annular portion, the angle θ1 of the optical axis 40 is obtained from Expression 3a.
In the first liquid crystal layer 12 in the lens device according to the embodiment of the present invention, the angle θ1 of the optical axis obtained in Expression 3a is satisfied in a range of ±3°.
That is, in polar coordinates of r and φ with respect to the center of the center portion of the first liquid crystal layer as an origin, in a case where a pattern where the angle θ1 [°] of the optical axis of the first liquid crystal layer in a region where φ is φ1 satisfies a relationship represented by Expression 3 is set as a vortex alignment pattern, the center portion of the first liquid crystal layer has a vortex alignment pattern where α1=m×0.5 in a case where m represents an integer of 1 or more, and the n-th annular portion from the center portion of the first liquid crystal layer has a vortex alignment pattern where α1=(m+n)×0.5.
(Here, θ0n1 [°] represents an angle of the optical axis of each of the center portion and the annular portions at φ1=0°.)
On the other hand, as in the first liquid crystal layer 12, the second liquid crystal layer 14 includes a circular center portion and a plurality of annular portions that have centers matching with a center of the center portion and have different inner diameters provided in a radial direction of the center portion, and has a vortex alignment pattern where a phase change in the circumferential direction of the center portion and each of the annular portions is opposite to that of the first liquid crystal layer 12.
The vortex alignment pattern of the second liquid crystal layer 14 will be described using
As shown in
As shown in
Next, in the second annular portion (second annular portion) 22b from the center portion 20b toward the radial direction, in case of being seen counterclockwise in the circumferential direction of the second annular portion 22b, the orientation of the optical axis 40 in the fine region rotates 1.5 times clockwise. That is, in the example shown in the drawing, in the second annular portion 22b, while the phase rotates once from the position of 2π in the circumferential direction of the second annular portion 22b, a phase change from 2π to 0 is repeated three times. That is, the number of phase changes in the second annular portion 22b is increased by one from that of the first annular portion 21b. In addition, the phase change in the second annular portion 22b of the second liquid crystal layer 14 is opposite to the phase change in the second annular portion 22a of the first liquid crystal layer 12. In other words, in the second annular portion 22b, the phase change from 0 to 2π is repeated three times clockwise in the circumferential direction of the second annular portion 22b.
In the second liquid crystal layer 14, likewise, even in the third or subsequent annular portion from the center portion 20b toward the radial direction, in case of being seen counterclockwise in the circumferential direction, while the phase rotates once from the position of 2π in the circumferential direction of the annular portion, the phase change from 2π to 0 is repeated multiple times, and the number of repetitions of the phase change in one annular portion is increased by one from that of another annular portion inwardly adjacent thereto.
That is, in the n-th annular portion of the second liquid crystal layer 14 shown in
This way, the second liquid crystal layer 14 includes the center portion and the plurality of annular portions, and in each of the center portion and the plurality of annular portions, the phase change in direction opposite to that of the first liquid crystal layer 12 is repeated once or more, and the phase change is repeated n+m times (m represents the number of phase changes in the center portion) in the n-th annular portion.
As in the first liquid crystal layer 12, in the above-described vortex alignment pattern, in polar coordinates of r and φ with the center of the center portion 20b of the second liquid crystal layer 14 as an origin, the angle θ2 [°] of the optical axis 40 in a region where φ is φ2 is represented by Expression 4a.
Here, θ0n2 [°] represents an angle of the optical axis of each of the center portion 20b and the annular portions at φ2=0°. In the examples shown in
A change in the angle θ2 of the optical axis 40 in the center portion 20b is represented by α2=−(m×0.5) in Expression 4a where m represents an integer of 1 or more. In addition, a change in the angle θ2 of the optical axis in the n-th annular portion from the center portion 20b is represented by α2=−(m+n)×0.5 in Expression 4a.
m has the same definition as the number of phase changes in the center portion 20b, and in the examples shown in
In addition, Expression 4a in the first annular portion 21b of the example shown in
In addition, Expression 4a in the second annular portion 22b of the example shown in
Even in the n-th annular portion, the angle θ2 of the optical axis 40 is obtained from Expression 4a.
In the second liquid crystal layer 14 in the lens device according to the embodiment of the present invention, the angle θ2 of the optical axis obtained in Expression 4a is satisfied in a range of ±3°.
That is, in polar coordinates of r and φ with respect to the center of the center portion of the second liquid crystal layer as an origin, in a case where a pattern where an angle θ2 [°] of the optical axis of the second liquid crystal layer in a region where φ is φ2 satisfies a relationship represented by Expression 4 is set as a vortex alignment pattern, the center portion of the second liquid crystal layer has a vortex alignment pattern where α2=m×0.5 in a case where m represents an integer of 1 or more, and the n-th annular portion from the center portion of the second liquid crystal layer has a vortex alignment pattern where α2=m+n×0.5.
(Here, θ0n2 [°] represents an angle of the optical axis of each of the center portion and the annular portions at φ2=0°).
In the vortex alignment pattern, an absolute value of α1 or α2 matches with the number of times the optical axis 40 rotates in case of being seen counterclockwise in the circumferential direction. In addition, the plus or minus sign of α1 or α2 represents the rotation direction of the optical axis 40. α1 or α2 represents the order of the vortex alignment pattern.
Here, an inner diameter rin-n1 and an outer diameter rout-n1 of an n-th annular portion from the center portion of the first liquid crystal layer and an inner diameter rin-n2 and an outer diameter rout-n2 of an n-th annular portion from the center portion of the second liquid crystal layer satisfy relationships represented by Expression 1 and Expression 2.
That is, in a case where the first liquid crystal layer 12 and the second liquid crystal layer 14 are arranged in the thickness direction such that the centers of the center portions match with each other, the center portions overlap each other and the n-th annular portions overlap each other in case of being seen from the thickness direction. As a result, an area where the laminate of the first liquid crystal layer and the second liquid crystal layer functions as a lens can be maintained.
The inner diameter rin-n1 and the outer diameter rout-n1 of an n-th annular portion from the center portion of the first liquid crystal layer and the inner diameter rin-n2 and the outer diameter rout-n2 of an n-th annular portion from the center portion of the second liquid crystal layer is preferably satisfy relationships represented by Expression 1a and Expression 2a, and more preferably satisfy relationships represented by Expression 1b and Expression 2b.
In addition, based on Expression 3 and Expression 4, the order of the center portion 20a and the n-th annular portion of the first liquid crystal layer 12 are the same as the order of the center portion 20b and the n-th annular portion of the second liquid crystal layer 14. That is, the number of repetitions of phase changes in the center portion 20a and the n-th annular portion of the first liquid crystal layer 12 is the same as the number of repetitions of phase changes in the center portion 20b and the n-th annular portion of the second liquid crystal layer 14.
In the lens device including the first liquid crystal layer 12 and the second liquid crystal layer 14, the focal length as a lens is variable by rotating the first liquid crystal layer 12 and the second liquid crystal layer 14 relative to each other around the center without changing the distance between the first liquid crystal layer 12 and the second liquid crystal layer 14.
This point will be described using a lens device including the first liquid crystal layer 12 shown in
By using an angle at which θ1 of the center portion 20a of the first liquid crystal layer 12 is 0° (that is, the phase is 0) as a reference line of the first liquid crystal layer 12 and using an angle at which θ2 of the center portion 20b of the second liquid crystal layer 14 is 0° (that is, the phase is 0=2π) as a reference line of the second liquid crystal layer 14, an angle between the reference line of the first liquid crystal layer 12 and the reference line of the second liquid crystal layer 14 is obtained as a relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14. In a case where the first liquid crystal layer 12 and the second liquid crystal layer 14 disposed to overlap each other are seen from the second liquid crystal layer 14 side, the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is represented by −180° to 180°, in which the positive sign represents the counterclockwise direction and the negative sign represents the clockwise direction regarding the rotation direction of the reference line of the second liquid crystal layer 14 with respect to the reference line of the first liquid crystal layer 12.
In a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is 0°, the phase as the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 is in a state conceptually shown in
In a case where the phase is in this state, that is, the phase of the entire surface is 0, the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 allows transmission of light without diffracting the light.
In a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is 180°, the phase as the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 is in a state conceptually shown in
Even in a case where the phase is in this state, that is, the phase distribution includes only 0, π, and 2π, the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 allows transmission of light without diffracting the light.
Next, for example, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is 30°, the phase as the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 is in a state conceptually shown in
In this phase state, the phase is uniform in each of regions corresponding to the center portion and the annular portions, and the phase varies between adjacent regions. That is, the regions having different phases are concentrically provided. In a case where this phase state is seen in the radial direction of each of the orientations from the center, the phase continuously changes from the center toward the outer side. That is, it can be said that the example shown in
In a case where the laminate including the first liquid crystal layer 12 and the second liquid crystal layer 14 has the pattern in which the optical axis continuously changes while rotating, circularly polarized light incident into the laminate is diffracted in an orientation direction along the arrangement axis. In this case, the diffraction direction of right circularly polarized light is opposite to that of left circularly polarized light. Accordingly, as shown in
In addition, for example, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is 60°, the phase as the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 is in a state conceptually shown in
In this phase state, as in
In addition, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is 60° as shown in
This way, the focal length of the laminate that acts as a lens can be changed by changing the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14. For example, for the circularly polarized light for which the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 acts as the condenser lens, the focal length for the condenser lens can be changed by changing the relative angle as shown in
On the other hand, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is −60°, the phase as the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 is in a state conceptually shown in
In this phase state, as in
In addition, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is −60° as shown in
Even in this case, as in the case of
This way, even in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is changed in the negative direction, the focal length of the laminate that acts as a lens can be changed. For example, for the circularly polarized light for which the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 acts as the divergent lens, (that is, the circularly polarized light that is converged in a case where the relative angle is positive), the focal length for the divergent lens can be changed by changing the relative angle as shown in
As described above, as a thin lens device where the focal length is variable, there is disclosed an Alvarez lens where liquid crystal films having a lens action are translated relative to each other in an in-plane direction to change the focal length of the lens. However, in the configuration where the two liquid crystal films are translated in the in-plane direction, the thickness of the lens in the optical axis direction can be reduced, but the size of a region acting as the lens is less than that of the liquid crystal film. In addition, a space for translating the two liquid crystal films is required. Therefore, the size in the in-plane direction increases, and there is a problem in that a reduction in size is not sufficient.
On the other hand, in the lens device according to the embodiment of the present invention, as described above, the focal length is variable by rotating the two liquid crystal layers relative to each other without changing the distance between the two liquid crystal layers in the thickness direction. Therefore, the size of the region that substantially acts as a region can be made substantially the same as the size of the two liquid crystal layers. Accordingly, a thin lens device where the size in the in-plane direction is also small and the focal length is variable can be obtained.
Here, a mechanism that rotates the first liquid crystal layer 12 and the second liquid crystal layer 14 relative to each other is not particularly limited, and various well-known rotation mechanisms such as an electric motor, an ultrasonic motor, or a rack-and-pinion mechanism can be appropriately used.
In addition, in the lens device 10 according to the embodiment of the present invention, in a case where the distance between the first liquid crystal layer 12 and the second liquid crystal layer 14 is excessively long, a part of light transmitted through the center portion and each of the annular portions of the first liquid crystal layer 12 is likely to be incident into the other regions instead of the center portion and each of the annular portions of the second liquid crystal layer 14 corresponding to the first liquid crystal layer 12. In this case, there is a concern that the lens device 10 cannot appropriately exhibit the above-described lens action. Accordingly, it is preferable that the distance between the first liquid crystal layer 12 and the second liquid crystal layer 14 is as short as possible in a range where the first liquid crystal layer 12 and the second liquid crystal layer 14 can rotate relative to each other.
Specifically, the distance between the first liquid crystal layer 12 and the second liquid crystal layer 14 is preferably 10 mm or less, more preferably 1 mm or less, and still more preferably 0.1 mm or less.
In addition, the diameter of the center portion and the inner diameter, the outer diameter, and the width in the radial direction and the like of each of the annular portions in the first liquid crystal layer 12 and the second liquid crystal layer 14 are not particularly limited, and may be appropriately set depending on the range of the focal length required as the lens device 10, the lens diameter, the size of a light source, the size of the device to be used, and the like.
The diameter of the center portion and the width in the radial direction of each of the annular portions in the first liquid crystal layer 12 and the second liquid crystal layer 14 are preferably 100 mm or less, more preferably 10 mm or less, and still more preferably 5 mm or less.
In addition, it is preferable that the width in the radial direction of each of the annular portions in the first liquid crystal layer 12 and the second liquid crystal layer 14 decreases in order from the center portion toward the outer side. As a result, in the phase state of the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is an angle at which the lens action occurs, the single period over which the optical axis rotates by 180° in the direction along the above-described arrangement axis gradually decreases from the center toward the outer side. As the single period decreases, the diffraction angle of light increases. Accordingly, by making the single period to gradually decrease from the center toward the outer side along the arrangement axis, the power of condensing or diverging light by the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 can be further improved, and the performance as a convex lens or a concave lens can be improved.
In addition, in the examples shown in
In addition, the orders α of the annular portions are at intervals of 0.5 from the center portion toward the outer side, but the present invention is not limited thereto. The orders α may be at intervals of 1.0, 1.5, or the like. In addition, the amount of change of the order of the annular portions adjacent to each other does not need to be fixed. However, from the viewpoint that the performance as a lens can be improved, it is preferable that the orders α of the annular portions from the center portion toward the outer side are at intervals of 0.5.
Here, in the above-described example, in the first liquid crystal layer 12, the orientation direction in which the optical axis is parallel to the radial direction in the center portion 20a matches with the orientation direction in which the optical axis is parallel to the radial direction in each of the annular portions. In addition, in the second liquid crystal layer 14, the orientation direction in which the optical axis is parallel to the radial direction in the center portion 20b matches with the orientation direction in which the optical axis is parallel to the radial direction in each of the annular portions. In other words, in a case where an azimuthal angle at which the optical axis is parallel to the radial direction in the n-th annular portion from the center portion with respect to an azimuthal angle at which the optical axis is parallel to the radial direction in the center portion 20a of the first liquid crystal layer 12 is represented by φn1 and an azimuthal angle at which the optical axis is parallel to the radial direction in the n-th annular portion from the center portion with respect to an azimuthal angle at which the optical axis is parallel to the radial direction in the center portion 20b of the second liquid crystal layer 14 is represented by φn2, φn1=0° and φn2=0° are satisfied.
However, the present invention is not limited to this example. In the first liquid crystal layer 12, the azimuthal angles φn1 at which the optical axis is parallel to the radial direction in the annular portions may be different from each other. In addition, in the second liquid crystal layer 14, the azimuthal angles φn2 at which the optical axis is parallel to the radial direction in the annular portions may be different from each other. That is, for example, in the first liquid crystal layer 12, φn1=φ11 in the first annular portion, φn1=φ21 in the second annular portion, and φn1=φ31 in the third annular portion, . . . may be different from each other. In addition, in the second liquid crystal layer 14, φn2=φ12 in the first annular portion, φn2=φ22 in the second annular portion, and φn2=φ32 in the third annular portion, . . . may be different from each other.
In addition, in each of the first liquid crystal layer 12 and the second liquid crystal layer 14, in a case where the azimuthal angles (φn1, φn2) at which the optical axis is parallel to the radial direction in the annular portions are different from each other, it is preferable that the orientation φn1 at which the optical axis is parallel to the radial direction in the n-th annular portion of the first liquid crystal layer 12 and the orientation φn2 at which the optical axis is parallel to the radial direction in the n-th annular portion of the second liquid crystal layer 14 satisfy φn1=φn2. That is, for example, it is preferable that φ11 in the first annular portion of the first liquid crystal layer 12 and φ12 in the first annular portion of the second liquid crystal layer 14 are the same, φ21 in the second annular portion of the first liquid crystal layer 12 and φ22 in the second annular portion of the second liquid crystal layer 14 are the same, and φ31 in the third annular portion of the first liquid crystal layer 12 and φ32 in the third annular portion of the second liquid crystal layer 14 are the same.
With the configuration where φn1 of the n-th annular portion of the first liquid crystal layer 12 and φn2 of the n-th annular portion of the second liquid crystal layer 14 satisfy φn1=φn2, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 is 0°, the laminate (lens device) of the first liquid crystal layer 12 and the second liquid crystal layer 14 can allow transmission of light without diffracting the light. That is, by changing the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14, the laminate (lens device) of the first liquid crystal layer 12 and the second liquid crystal layer 14 can switch between a state where the laminate functions as a condenser lens or a divergent lens and a state where the laminate allows transmission without diffracting the light.
The above-described lens device 10 including the first liquid crystal layer 12 and the second liquid crystal layer may function as an axicon lens, may function as a spherical lens, or may function as an aspherical lens.
The lens as which the lens device 10 functions is determined depending on the width of each of the annular portions of the first liquid crystal layer 12 and the second liquid crystal layer 14.
For example, in a case where the lens device functions as an axicon lens, the width of each of the annular portions of the first liquid crystal layer 12 and the second liquid crystal layer 14 may be fixed.
In addition, in a case where the lens device functions as a spherical lens, the width of each of the annular portions of the first liquid crystal layer 12 and the second liquid crystal layer 14 may be appropriately determined to be inversely proportional to the ½ power of the width of the first annular portion.
The liquid crystal layer having the vortex alignment pattern can be formed by applying a liquid crystal composition including a liquid crystal compound to an alignment film for aligning the liquid crystal compound in the predetermined vortex alignment pattern, forming a liquid crystal phase where an orientation of an optical axis derived from the liquid crystal compound is aligned in the vortex alignment pattern, and immobilizing the liquid crystal phase in a layer shape.
In addition, in the present invention, the liquid crystal layer may be formed by application of multiple layers. The application of the multiple layers refers to a method of forming the liquid crystal layer by repeating the following processes until a desired thickness is obtained, the processes including: forming a first liquid crystal immobilized layer by applying the liquid crystal composition for forming the first layer to the alignment film, heating the liquid crystal composition, cooling the liquid crystal composition, and irradiating the liquid crystal composition with ultraviolet light for curing; and forming a second or subsequent liquid crystal immobilized layer by applying the liquid crystal composition for forming the second or subsequent layer to the formed liquid crystal immobilized layer, heating the liquid crystal composition, cooling the liquid crystal composition, and irradiating the liquid crystal composition with ultraviolet light for curing as described above.
As a support that supports the alignment film and the optically-anisotropic layer, various sheet-shaped materials (films or plate-shaped materials) can be used as long as they can support the alignment film and the optically-anisotropic layer.
A transmittance of the support with respect to light to be diffracted is preferably 50% or more, more preferably 70% or more, and still more preferably 85% or more.
The thickness of the support is not particularly limited and may be appropriately set depending on the use of the lens device, a material for forming the support, and the like in a range where the alignment film and the liquid crystal layer can be supported.
The thickness of the support is preferably in a range of 1 to 1000 μm, more preferably in a range of 3 to 250 μm, and still more preferably in a range of 5 to 150 μm.
The support may have a monolayer structure or a multi-layer structure.
In a case where the support has a monolayer structure, examples thereof include supports formed of glass, triacetyl cellulose (TAC), polyethylene terephthalate (PET), polycarbonates, polyvinyl chloride, acryl, polyolefin, and the like. In a case where the support has a multi-layer structure, examples thereof include a support including: one of the above-described supports having a monolayer structure that is provided as a substrate; and another layer that is provided on a surface of the substrate.
The alignment film is formed on the surface of the support.
The alignment film is an alignment film for aligning the liquid crystal compound in a predetermined vortex alignment pattern during the formation of the liquid crystal layer.
The alignment film can be suitably used as a so-called photo-alignment film obtained by irradiating a photo-alignment material with polarized light or non-polarized light. That is, in the present invention, a photo-alignment film that is formed by applying a photo-alignment material to the support is suitably used as the alignment film.
The irradiation of polarized light can be performed in a direction perpendicular or oblique to the photo-alignment film, and the irradiation of non-polarized light can be performed in a direction oblique to the photo-alignment film.
Preferable examples of the photo-alignment material used in the alignment film that can be used in the present invention include: an azo compound described in JP2006-285197A, JP2007-76839A, JP2007-138138A, JP2007-94071A, JP2007-121721A, JP2007-140465A, JP2007-156439A, JP2007-133184A, JP2009-109831A, JP3883848B, and JP4151746B; an aromatic ester compound described in JP2002-229039A; a maleimide- and/or alkenyl-substituted nadiimide compound having a photo-alignable unit described in JP2002-265541A and JP2002-317013A; a photocrosslinking silane derivative described in JP4205195B and JP4205198B, a photocrosslinking polyimide, a photocrosslinking polyamide, or a photocrosslinking polyester described in JP2003-520878A, JP2004-529220A, and JP4162850B; and a photodimerizable compound, in particular, a cinnamate compound, a chalcone compound, or a coumarin compound described in JP1997-118717A (JP-H9-118717A), JP1998-506420A (JP-H10-506420A), JP2003-505561A, WO2010/150748A, JP2013-177561A, and JP2014-12823A.
Among these, an azo compound, a photocrosslinking polyimide, a photocrosslinking polyamide, a photocrosslinking polyester, a cinnamate compound, or a chalcone compound is suitably used.
The thickness of the alignment film 32 is not particularly limited. The thickness with which a required alignment function can be obtained may be appropriately set depending on the material for forming the alignment film 32.
The thickness of the alignment film 32 is preferably 0.01 to 5 μm and more preferably 0.05 to 2 μm.
In the present invention, a suitable exposure method of the alignment film for forming the vortex alignment pattern is a method of exposing the alignment film using a direct drawing method.
An exposure device 100 shown in
The light source 102 includes a laser and a linearly polarizing plate, and emits linearly polarized light. The emitted linearly polarized light is incident into the λ/2 plate 104. The λ/2 plate 104 is rotatably attached, and is rotatable around an axis perpendicular to an XY plane of the XY stage 108. The λ/2 plate 104 rotates around the axis perpendicular to the XY plane to convert the polarization direction of the incident linearly polarized light into any direction. The lens 106 focuses the linearly polarized light transmitted through the λ/2 plate 104 on the surface of the alignment film 32 disposed on the XY stage 108. The support 30 including the alignment film 32 is disposed on the XY stage 108, and the alignment film 32 (support 30) is moved in the X direction and/or the Y direction to change the position on the surface of the alignment film 32 where the light is focused. That is, the XY stage 108 scans the surface of the alignment film 32 with the light.
The rotation of the λ/2 plate 104 and the movement of the XY stage 108 are controlled by, for example, a computer to associate the position on the surface of the alignment film 32 where the light is focused and the polarization direction of the light with each other. As a result, a desired alignment pattern can be formed on the vortex alignment pattern.
The irradiation of the light beam from the light source 102, the rotation of the λ/2 plate 104, and the movement of the XY stage 108 may be performed alternately or simultaneously. That is, for example, the XY stage 108 is driven such that the alignment film 32 is moved to a predetermined position and stopped, and is rotated such that the polarization direction of the linearly polarized light transmitted through the λ/2 plate 104 is a predetermined direction. Next, the alignment film 32 is irradiated with the light beam from the light source 102 to expose a predetermined position on the surface of the alignment film 32, and the irradiation of the light is stopped. Next, the XY stage 108 is driven such that the alignment film 32 is moved to a next predetermined position (exposure position) and stopped, and is rotated such that the polarization direction of the linearly polarized light transmitted through the λ/2 plate 104 is a predetermined direction. Next, the alignment film 32 is irradiated with the light beam from the light source 102 to expose a predetermined position on the surface of the alignment film 32, and the irradiation of the light is stopped. This way, by alternately repeating the movement of the XY stage 108 and the irradiation of the light beam from the light source 102, the exposure of the alignment film 32 may be intermittently performed.
Alternatively, while driving the XY stage 108 to move the alignment film 32 in a predetermined direction and rotating the λ/2 plate 104, the surface of the alignment film 32 may be irradiated with the light beam from the light source 102 to continuously expose the surface of the alignment film 32.
Alternatively, for example, while irradiating a region corresponding to one center portion or one annular portion with the light beam from the light source 102, the XY stage 108 is driven to move the irradiation position in the circumferential direction of this region. Concurrently, the λ/2 plate is rotated according to the number of phase changes in the circumferential direction (the number of times the optical axis rotates) to expose the region. By repeating this exposure, each of the regions corresponding to the center portion or the annular portion may be exposed.
The intensity, exposure time, and the like of the light to be irradiated may be appropriately set depending on the material for forming the alignment film and the like.
The exposure amount per unit area can be adjusted by adjusting the intensity of the light to be irradiated and a scanning speed. From the viewpoint of performing sufficient exposure to apply aligning properties to the alignment film 32, the exposure amount is preferably 100 mJ/m2 or more and more preferably 150 mJ/m2. In addition, from the viewpoint of preventing a decrease in aligning properties caused by excessive irradiation, the exposure amount is preferably 5 J/m2 or less and more preferably 3 J/m2 or less.
In addition, the spot diameter of the focused light beam on the alignment film may be a size where a desired alignment pattern can be applied to the alignment film.
In addition, in the present invention, in order to obtain the configuration where the angles θ1 and θ2 of the optical axis in the fine regions of the liquid crystal layer satisfy Expression 3 and Expression 4, that is, in order to obtain the range of ±3 with respect to the angle of the optical axis acquired from Expression 3a and Expression 4a representing the above-described ideal vortex alignment pattern, it is necessary to improve the accuracy of exposure of the alignment film using the direct drawing method. To that end, in the present invention, in a case where the alignment film is exposed using the direct drawing method, a marker for alignment is given on the support 30 or the alignment film 32, and, in a case where the XY stage 108 is driven to align the exposure position of the alignment film 32 with a predetermined position, it is preferable that the marker is detected with the camera as described above, and the coordinates of the XY stage 108 are modified for alignment based on the position information of the marker. As a result, high-accuracy alignment can be performed, and a vortex alignment pattern capable of forming a liquid crystal layer where a variation in the angle of the optical axis with respect to the ideal vortex alignment pattern is small can be given to the alignment film.
During scanning in the circumferential direction of the center portion and each of the annular portions, the amount of change in the polarization angle of linearly polarized light (the rotation amount of the λ/2 plate 104) is preferably 45° or less. By finely performing the drawing, the change speed of the optical axis can be made to be fixed without depending on characteristics of the liquid crystal material.
The amount of movement of the movable stage is preferably ⅕ or less with respect to the length of the center portion and each of the annular portions in the circumferential direction. By finely performing the drawing, the change speed of the optical axis can be made to be fixed without depending on characteristics of the liquid crystal material.
The required accuracy of the amount of movement of the movable stage is preferably ⅕ or less, more preferably 1/10 or less, and still more preferably 1/20 or less with respect to the amount of movement Δr of the movable stage.
In the present invention, as described above, it is preferable that the marker is detected with the camera as described above, and the coordinates of the XY stage 108 are modified for alignment based on the position information of the marker.
In order to determine the position coordinates and the rotation angle of the alignment film 32 fixed to the XY stage 108, it is preferable to use a plurality of cameras during the alignment. By using the plurality of cameras, while maintaining an imaging magnification required for fine alignment, position coordinates of two points that are sufficiently spaced from each other on the alignment film 32 can be determined, and the sufficient accuracy for the position coordinates and the rotation angle can be ensured for the alignment.
As the marker, a single marker or a plurality of markers may be provided as long as the positions of two points that are sufficiently spaced from each other can be verified with a plurality of cameras. Here, the distance between the two points that are sufficiently spaced from each other is preferably 10 mm or more, more preferably 30 mm or more, still more preferably 50 mm or more, and still more preferably 80 mm or more.
In addition, it is also preferable that positions more than two points are simultaneously verified by a plurality of cameras.
In addition, a marker may be provided in at least one region, and it is preferable that markers are provided in three or more regions. By providing markers in three or more regions, the alignment can be performed using two markers provided at positions between which the exposure region is interposed in the X direction, and the alignment can be performed using two markers provided at positions between which the exposure region is interposed in the Y direction. Therefore, the coordinates of the XY stage can be more accurately aligned.
The shape of the marker can be any shape such as a cross shape, a dot shape, a linear shape, a circular shape, or a quadrangular shape. In addition, the marker may be an aggregate or a lattice.
The liquid crystal layer is formed on the surface of the alignment film 32.
As described above, the liquid crystal layer is obtained by immobilizing the liquid crystal phase where the liquid crystal compound is aligned, and has the vortex alignment pattern.
The liquid crystal layer can be formed by immobilizing the liquid crystal phase where the liquid crystal compound is aligned in the vortex alignment pattern.
The structure in which a liquid crystal phase is immobilized may be a structure in which the alignment of the liquid crystal compound as a liquid crystal phase is immobilized. Typically, the structure in which a liquid crystal phase is immobilized is preferably a structure which is obtained by aligning the polymerizable liquid crystal compound in the liquid crystal alignment pattern, polymerizing and curing the polymerizable liquid crystal compound with ultraviolet irradiation, heating, or the like to form a layer having no fluidity, and concurrently changing the state of the polymerizable liquid crystal compound into a state where the alignment state is not changed by an external field or an external force.
The structure in which a liquid crystal phase is immobilized is not particularly limited as long as the optical characteristics of the liquid crystal phase are maintained, and the liquid crystal compound 40 in the liquid crystal layer does not necessarily exhibit liquid crystallinity. For example, the molecular weight of the polymerizable liquid crystal compound may be increased by a curing reaction such that the liquid crystallinity thereof is lost.
Examples of a material used for forming the liquid crystal layer obtained by immobilizing a liquid crystal phase include a liquid crystal composition including a liquid crystal compound. It is preferable that the liquid crystal compound is a polymerizable liquid crystal compound.
In addition, the liquid crystal composition used for forming the liquid crystal layer may further include a surfactant and a polymerization initiator.
The polymerizable liquid crystal compound may be a rod-like liquid crystal compound or a disk-like liquid crystal compound.
Examples of the polymerizable liquid crystal compound for forming the rod-like liquid crystal layer include a rod-like nematic liquid crystal compound. As the rod-like nematic liquid crystal compound, an azomethine compound, an azoxy compound, a cyanobiphenyl compound, a cyanophenyl ester compound, a benzoate compound, a phenyl cyclohexanecarboxylate compound, a cyanophenylcyclohexane compound, a cyano-substituted phenylpyrimidine compound, an alkoxy-substituted phenylpyrimidine compound, a phenyldioxane compound, a tolan compound, or an alkenylcyclohexylbenzonitrile compound is preferably used. Not only a low-molecular-weight liquid crystal compound but also a polymer liquid crystal compound can be used.
It is preferable that the alignment of the rod-like liquid crystal compound is immobilized by polymerization. Examples of the polymerizable rod-like liquid crystal compound include compounds described in Makromol. Chem., (1989), Vol. 190, p. 2255, Advanced Materials (1993), Vol. 5, p. 107, U.S. Pat. Nos. 4,683,327A, 5,622,648A, 5,770,107A, WO95/22586A, WO95/24455A, WO97/00600A, WO98/23580A, WO98/52905A, JP1989-272551A (JP-H1-272551A), JP1994-16616A (JP-H6-16616A), JP1995-110469A (JP-H7-110469A), JP1999-80081A (JP-H11-80081A), and JP2001-64627. Further, as the rod-like liquid crystal compound, for example, compounds described in JP1999-513019A (JP-H11-513019A) and JP2007-279688A can also be preferably used. In addition, two or more kinds of polymerizable liquid crystal compounds may be used in combination. In a case where two or more polymerizable liquid crystal compounds are used in combination, the alignment temperature can be decreased.
Examples of the polymerizable group include an unsaturated polymerizable group, an epoxy group, and an aziridinyl group. Among these, an unsaturated polymerizable group is preferable, and an ethylenically unsaturated polymerizable group is more preferable. The polymerizable group can be introduced into the molecules of the liquid crystal compound using various methods. The number of polymerizable groups in the polymerizable liquid crystal compound is preferably 1 to 6 and more preferably 1 to 3.
In addition, as a polymerizable liquid crystal compound other than the above-described examples, for example, a cyclic organopolysiloxane compound having a cholesteric phase described in JP1982-165480A (JP-S57-165480A) can be used. Further, as the above-described polymer liquid crystal compound, for example, a polymer in which a liquid crystal mesogenic group is introduced into a main chain, a side chain, or both a main chain and a side chain, a polymer cholesteric liquid crystal in which a cholesteryl group is introduced into a side chain, a liquid crystal polymer described in JP1997-133810A (JP-H9-133810A), and a liquid crystal polymer described in JP1999-293252A (JP-H11-293252A) can be used.
As the disk-like liquid crystal compound, for example, compounds described in JP2007-108732A and JP2010-244038A can be preferably used.
In a case where the disk-like liquid crystal compound is used in the liquid crystal layer, the liquid crystal compound 40 rises in the thickness direction in the liquid crystal layer, and the optical axis 40A derived from the liquid crystal compound is defined as an axis perpendicular to a disc plane, that is, a so-called fast axis.
In addition, the addition amount of the polymerizable liquid crystal compound in the liquid crystal composition is preferably 75 to 99.9 mass %, more preferably 80 to 99 mass %, and still more preferably 85 to 90 mass % with respect to the solid content mass (mass excluding a solvent) of the liquid crystal composition.
In order to obtain a high diffraction efficiency, it is preferable that a liquid crystal compound having high refractive anisotropy Δn is used as the liquid crystal compound.
The liquid crystal composition used for forming the liquid crystal layer may include a surfactant.
The surfactant is preferably a compound which can function as an alignment control agent contributing to the alignment of the liquid crystal compound in a stable or rapid manner. Examples of the surfactant include a silicone-based surfactant and a fluorine-based surfactant. Among these, a fluorine-based surfactant is preferable.
Specific examples of the surfactant include compounds described in paragraphs “0082” to “0090” of JP2014-119605A, compounds described in paragraphs “0031” to “0034” of JP2012-203237A, exemplary compounds described in paragraphs “0092” and “0093” of JP2005-99248A, exemplary compounds described in paragraphs “0076” to “0078” and paragraphs “0082” to “0085” of JP2002-129162A, and fluorine (meth)acrylate polymers described in paragraphs “0018” to “0043” of JP2007-272185A.
The surfactants may be used alone or in combination of two or more kinds.
As the fluorine-based surfactant, a compound described in paragraphs “0082” to “0090” of JP2014-119605A is preferable.
The addition amount of the surfactant in the liquid crystal composition is preferably 0.01 to 10 mass %, more preferably 0.01 to 5 mass %, and still more preferably 0.02 to 2 mass % with respect to the total mass of the liquid crystal compound.
In a case where the liquid crystal composition includes a polymerizable compound, it is preferable that the liquid crystal composition includes a polymerization initiator. In an aspect where a polymerization reaction progresses with ultraviolet irradiation, it is preferable that the polymerization initiator to be used is a photopolymerization initiator which initiates a polymerization reaction with ultraviolet irradiation.
Examples of the photopolymerization initiator include an α-carbonyl compound (described in U.S. Pat. Nos. 2,367,661A and 2,367,670A), an acyloin ether (described in U.S. Pat. No. 2,448,828A), an α-hydrocarbon-substituted aromatic acyloin compound (described in U.S. Pat. No. 2,722,512A), a polynuclear quinone compound (described in U.S. Pat. Nos. 3,046,127A and 2,951,758A), a combination of a triarylimidazole dimer and p-aminophenyl ketone (described in U.S. Pat. No. 3,549,367A), an acridine compound and a phenazine compound (described in JP1985-105667A (JP-S60-105667A) and U.S. Pat. No. 4,239,850A), and an oxadiazole compound (described in U.S. Pat. No. 4,212,970A).
The content of the photopolymerization initiator in the liquid crystal composition is preferably 0.1 to 20 mass % and more preferably 0.5 to 12 mass % with respect to the content of the liquid crystal compound.
In order to improve the film hardness after curing and to improve durability, the liquid crystal composition may optionally include a crosslinking agent. As the crosslinking agent, a curing agent which can perform curing with ultraviolet light, heat, moisture, or the like can be suitably used.
The crosslinking agent is not particularly limited and can be appropriately selected depending on the purpose. Examples of the crosslinking agent include: a polyfunctional acrylate compound such as trimethylol propane tri(meth)acrylate or pentaerythritol tri(meth)acrylate; an epoxy compound such as glycidyl (meth)acrylate or ethylene glycol diglycidyl ether; an compound such aziridine as 2,2-bis hydroxymethyl butanol-tris [3-(1-aziridinyl) propionate] or 4,4-bis(ethyleneiminocarbonylamino)diphenylmethane; an isocyanate compound such as hexamethylene diisocyanate or a biuret type isocyanate; a polyoxazoline compound having an oxazoline group at a side chain thereof; and an alkoxysilane compound such as vinyl trimethoxysilane or N-(2-aminoethyl)-3-aminopropyltrimethoxysilane. In addition, depending on the reactivity of the crosslinking agent, a well-known catalyst can be used, and not only film hardness and durability but also productivity can be improved. The crosslinking agents may be used alone or in combination of two or more kinds.
The content of the crosslinking agent is preferably 3% to 20 mass % and more preferably 5% to 15 mass % with respect to the solid content mass of the liquid crystal composition. In a case where the content of the crosslinking agent is in the above-described range, an effect of improving a crosslinking density can be easily obtained, and the stability of a liquid crystal phase is further improved.
Optionally, a polymerization inhibitor, an antioxidant, an ultraviolet absorber, a light stabilizer, a coloring material, metal oxide fine particles, or the like can be added to the liquid crystal composition in a range where optical performance and the like do not deteriorate.
In a case where the liquid crystal layer is formed, it is preferable that the liquid crystal composition is used as liquid.
The liquid crystal composition may include a solvent. The solvent is not particularly limited and can be appropriately selected depending on the purpose. An organic solvent is preferable.
The organic solvent is not particularly limited and can be appropriately selected depending on the purpose. Examples of the organic solvent include a ketone, an alkyl halide, an amide, a sulfoxide, a heterocyclic compound, a hydrocarbon, an ester, and an ether. The organic solvents may be used alone or in combination of two or more kinds. Among these, a ketone is preferable in consideration of an environmental burden.
In a case where the liquid crystal layer is formed, it is preferable that the liquid crystal layer is formed by applying the liquid crystal composition to a surface where the liquid crystal layer is to be formed, aligning the liquid crystal compound to a state where the liquid crystal phase is aligned in the predetermined liquid crystal alignment pattern, and curing the liquid crystal compound.
That is, in a case where the liquid crystal layer is formed on the alignment film 32, it is preferable that the liquid crystal layer obtained by immobilizing a liquid crystal phase is formed by applying the liquid crystal composition to the alignment film 32, aligning the liquid crystal compound in the predetermined liquid crystal alignment pattern, and curing the liquid crystal compound.
For the application of the liquid crystal composition, a printing method such as ink jet or scroll printing or a well-known method such as spin coating, bar coating, or spray coating capable of uniformly applying liquid to a sheet-shaped material can be used.
The applied liquid crystal composition is optionally dried and/or heated and then is cured to form the liquid crystal layer. In the drying and/or heating step, the liquid crystal compound in the liquid crystal composition may be aligned in the predetermined liquid crystal alignment pattern. In the case of heating, the heating temperature is preferably 200° C. or lower and more preferably 130° C. or lower.
The aligned liquid crystal compound is optionally further polymerized. Regarding the polymerization, thermal polymerization or photopolymerization using light irradiation may be performed, and photopolymerization is preferable. Regarding the light irradiation, ultraviolet light is preferably used. The irradiation energy is preferably 20 mJ/cm2 to 50 J/cm2 and more preferably 50 to 1500 mJ/cm2. In order to promote a photopolymerization reaction, light irradiation may be performed under heating conditions or in a nitrogen atmosphere. The wavelength of irradiated ultraviolet light is preferably 250 to 430 nm.
A thickness of the liquid crystal layer is not particularly limited and may be appropriately set depending on the use of the liquid crystal layer, the material for forming the liquid crystal layer, and the like.
In the liquid crystal layer, it is preferable that an in-plane retardation (Re) value in the fine regions is a half wavelength, that is, λ/2. The in-plane retardation is calculated from the product of a difference Δn in refractive index generated by refractive index anisotropy of the region and the thickness of the liquid crystal layer. Here, the difference in refractive index generated by refractive index anisotropy of the region in the liquid crystal layer is defined by a difference between a refractive index of a direction of an in-plane slow axis of the region and a refractive index of a direction orthogonal to the direction of the slow axis. That is, the difference Δn in refractive index generated by refractive index anisotropy of the region R is the same as a difference between a refractive index of the liquid crystal compound in the direction of the optical axis and a refractive index of the liquid crystal compound in a direction perpendicular to the optical axis in a plane of the region. That is, the difference Δn in refractive index is the same as the difference in refractive index of the liquid crystal compound.
In the liquid crystal layer, it is preferable that the in-plane retardation value of the plurality of regions is a half wavelength. It is preferable that an in-plane retardation Re(550)=Δn550×d of the plurality of regions of the liquid crystal layer with respect to the incidence light having a wavelength of 550 nm is in a range defined by Expression (3). Here, Δn550 represents a difference in refractive index generated by refractive index anisotropy of the region in a case where the wavelength of incidence light is 550 nm, and d represents the thickness of the liquid crystal layer.
That is, in a case where the in-plane retardation Re(550)=Δn550×d of the plurality of regions of the liquid crystal layer satisfies Expression (3), a sufficient amount of a circularly polarized light component in light incident into the liquid crystal layer can be converted into circularly polarized light that travels in a direction tilted in a forward direction or reverse direction with respect to the arrangement axis direction. It is more preferable that the in-plane retardation Re(550)=Δn550×d satisfies 225 nm≤Δn550×d≤340 nm, and it is still more preferable that the in-plane retardation Re(550)=Δn550×d satisfies 250 nm≤Δn550×d≤330 nm.
Expression (3) is a range with respect to incidence light having a wavelength of 550 nm. However, an in-plane retardation Re(λ)=Δnλ×d of the plurality of regions of the liquid crystal layer with respect to incidence light having a wavelength of λ nm is preferably in a range defined by Expression (3-2) and can be appropriately set.
In addition, the value of the in-plane retardation of the plurality of regions of the liquid crystal layer in a range outside the range of Expression (3) can also be used. Specifically, by satisfying Δn550×d<200 nm or 350 nm<Δn550×d, the light can be classified into light that travels in the same direction as a traveling direction of the incidence light and light that travels in a direction different from a traveling direction of the incidence light. In a case where Δn550×d approaches 0 nm or 550 nm, the amount of the light component that travels in the same direction as a traveling direction of the incidence light increases, and the amount of the light component that travels in a direction different from a traveling direction of the incidence light decreases.
Further, it is preferable that an in-plane retardation Re(450)=Δn450×d of each of the plurality of regions of the liquid crystal layer with respect to incidence light having a wavelength of 450 nm and an in-plane retardation Re(550)=Δn550×d of each of the plurality of regions of the liquid crystal layer with respect to incidence light having a wavelength of 550 nm satisfy Expression (4). Here, Δn450 represents a difference in refractive index generated by refractive index anisotropy of the region in a case where the wavelength of incidence light is 450 nm.
Expression (4) represents that the liquid crystal compound in the liquid crystal layer has reverse dispersibility. That is, by satisfying Expression (4), the liquid crystal layer can correspond to incidence light having a wide range of wavelength.
Although the liquid crystal layer functions as a so-called λ/2 plate, the present invention includes an aspect where a laminate including the support and the alignment film that are integrated functions as a λ/2 plate.
Here, in the liquid crystal layer, it is preferable that (the optical axis of) the liquid crystal compound is subjected to a twisted alignment in the thickness direction. “The liquid crystal compound (optical axis) being twisted and aligned in the thickness direction” refers to a state where the orientation of the optical axis arranged in the thickness direction from one main surface to another main surface of the liquid crystal layer relatively changes and is twisted and aligned in the one direction. The twisting property may be right-twisted or left-twisted and may be applied depending on a desired diffraction direction. The optical axis in the entire thickness direction is twisted by less than one turn, that is, the twisted angle is less than 360°. The twisted angle of the liquid crystal compound in the thickness direction is preferably about 10° to 200° and more about preferably 20° to 180°. In addition, the twisted direction may be reversed halfway in the thickness direction. Even in this case, the twisted angle is less than 360°, and the twisted angle of the liquid crystal compound in the thickness direction is preferably about 10° to 200° and more about preferably 20° to 180°. In the cholesteric alignment, the twisted angle is 360° or more, and selective reflectivity in which specific circularly polarized light in a specific wavelength range is reflected is exhibited. In the present specification, “twisted alignment” does not include cholesteric alignment, and selective reflectivity does not occur in the liquid crystal layer having the twisted alignment.
The liquid crystal layer that is twisted and aligned in the thickness direction has a twisted structure in which the liquid crystal compound is turned and laminated in the thickness direction, and a total rotation angle between the liquid crystal compound present on one main surface side of the liquid crystal layer and the liquid crystal compound present on another main surface side of the liquid crystal layer is less than 360°.
This way, in order for the liquid crystal layer to have the configuration where the liquid crystal compound is twisted and aligned in the thickness direction, the liquid crystal composition for forming the liquid crystal layer may include a chiral agent.
The chiral agent has a function of causing a helical structure of a liquid crystal phase to be formed. The chiral agent may be selected depending on the purposes because a helical twisted direction and a helical twisting power (HTP) to be induced vary depending on compounds.
The chiral agent is not particularly limited, and a well-known compound (for example, Liquid Crystal Device Handbook (No. 142 Committee of Japan Society for the Promotion of Science, 1989), Chapter 3, Article 4-3, chiral agent for twisted nematic (TN) or super twisted nematic (STN), p. 199), isosorbide, or an isomannide derivative can be used.
In general, the chiral agent includes a chiral carbon atom. However, an axially chiral compound or a planar chiral compound not having a chiral carbon atom can also be used as the chiral agent. Examples of the axially chiral compound or the planar chiral compound include binaphthyl, helicene, paracyclophane, and derivatives thereof. The chiral agent may include a polymerizable group. In a case where both the chiral agent and the liquid crystal compound have a polymerizable group, a polymer which includes a repeating unit derived from the polymerizable liquid crystal compound and a repeating unit derived from the chiral agent can be formed due to a polymerization reaction of a polymerizable chiral agent and the polymerizable liquid crystal compound. In this aspect, it is preferable that the polymerizable group in the polymerizable chiral agent is the same as the polymerizable group in the polymerizable liquid crystal compound. Accordingly, the polymerizable group of the chiral agent is preferably an unsaturated polymerizable group, an epoxy group, or an aziridinyl group, more preferably an unsaturated polymerizable group, and still more preferably an ethylenically unsaturated polymerizable group.
In addition, the chiral agent may be a liquid crystal compound.
In a case where the chiral agent includes a photoisomerization group, a desired twisted alignment corresponding to a luminescence wavelength can be formed by irradiation of an actinic ray or the like through a photomask after coating and alignment, which is preferable. As the photoisomerization group, an isomerization portion of a photochromic compound, an azo group, an azoxy group, or a cinnamoyl group is preferable. Specific examples of the compound include compounds described in JP2002-80478A, JP2002-80851A, JP2002-179668A, JP2002-179669A, JP2002-179670A, JP2002-179681A, JP2002-179682A, JP2002-338575A, JP2002-338668A, JP2003-313189A, and JP2003-313292A.
The content of the chiral agent in the liquid crystal composition is preferably 0.01% to 200 mol % and more preferably 1% to 30 mol % with respect to the content molar amount of the liquid crystal compound.
In all of the above-described liquid crystal layers, the rod-like liquid crystal compound is used as the liquid crystal compound. However, the present invention is not limited to this configuration, and a disk-like liquid crystal compound can also be used.
In the disk-like liquid crystal compound, the optical axis derived from the liquid crystal compound is defined as an axis perpendicular to a disk surface, that is so-called, a fast axis.
In addition, in the liquid crystal layer of the lens device according to the embodiment of the present invention, the rod-like liquid crystal compound and the disk-like liquid crystal compound may be used in combination.
In addition, the planar shape of the lens device (liquid crystal layer) is not limited to a circular shape, and may be appropriately set to a rectangular shape, an elliptical shape, or an amorphous shape depending on the configuration of the device used in the lens device.
The lens device according to the embodiment of the present invention can be combined with a display panel to obtain an image display apparatus.
The image display apparatus including the lens device according to the embodiment of the present invention can be suitably used as an image display apparatus of a head mounted display such as augmented reality (AR) glasses, VR glasses, or mixed reality (MR) glasses.
Hereinabove, the lens device according to the embodiment of the present invention has been described above. However, the present invention is not limited to the above-described examples, and various improvements and modifications can be made within a range not departing from the scope of the present invention.
Hereinafter, the characteristics of the present invention will be described in detail using examples. Materials, chemicals, used amounts, material amounts, ratios, treatment details, treatment procedures, and the like shown in the following examples can be appropriately changed within a range not departing from the scope of the present invention. Accordingly, the scope of the present invention is not limited to the following specific examples.
A flat plate-shaped glass substrate was prepared as the support.
The following coating liquid for forming an alignment film was applied to the support by spin coating. The support on which the coating film of the coating liquid for forming an alignment film was formed was dried using a hot plate at 60° C. for 60 seconds. As a result, an alignment film was formed.
Using a laser light source of a wavelength of 355 nm, a linearly polarizing plate, a λ/2 plate, a lens, and an XY stage (LD-242-MSC, manufactured by Chuo Precision Industrial Co., Ltd.), an exposure device for performing a direct drawing method was manufactured as shown in
Specifically, the support on which the alignment film was formed was placed on the XY stage, and the lens position was adjusted such that the focusing position was the surface of the alignment film. As the light source, a light source that emitted laser light having a wavelength (355 nm) was used. Next, the movement of the XY stage and the rotation of the λ/2 plate were synchronized such that the alignment direction of the liquid crystal compound (optical axis) is the alignment direction for obtaining the vortex alignment pattern shown in
As the liquid crystal composition forming the liquid crystal layer, the following composition A-1 was prepared.
The liquid crystal layer was formed by applying multiple layers of the composition A-1 to the alignment film P-1. The application of the multiple layers refers to repetition of the following processes including: preparing a first liquid crystal immobilized layer by applying the composition A-1 for forming the first layer to the alignment film, heating the composition A-1, and irradiating the composition A-1 with ultraviolet light for curing; and manufacturing a second or subsequent liquid crystal immobilized layer by applying the composition A-1 for forming the second or subsequent layer to the formed liquid crystal immobilized layer, heating the composition A-1, and irradiating the composition A-1 with ultraviolet light for curing as described above. Even in a case where the liquid crystal layer was formed by the application of the multiple layers such that the total thickness of the optically-anisotropic layer was large, the alignment direction of the alignment film was reflected from a lower surface of the liquid crystal layer to an upper surface thereof.
Regarding the first liquid crystal layer, the following composition A-1 was applied to the alignment film P-1 to form a coating film, the coating film was heated to 80° C. using a hot plate, the coating film was irradiated with ultraviolet light having a wavelength of 365 nm at an irradiation dose of 300 mJ/cm2 using a high-pressure mercury lamp in a nitrogen atmosphere. As a result, the alignment of the liquid crystal compound was immobilized.
Regarding the second or subsequent liquid crystal immobilized layer, the composition was applied to the first liquid crystal layer, and the applied composition was heated and irradiated with ultraviolet light for curing under the same conditions as described above. As a result, a liquid crystal immobilized layer was manufactured. This way, by repeating the application multiple times until the total thickness reached a desired film thickness, and the first liquid crystal layer was formed. The thickness of the first layer was 1.8 μm.
It was verified using a polarization microscope that the first liquid crystal layer had the vortex alignment pattern shown in
A second liquid crystal layer was prepared using the same method as that of the first liquid crystal layer, except that the second liquid crystal layer has a vortex alignment pattern different from the vortex alignment pattern of the first liquid crystal layer as shown in
By laminating the prepared first liquid crystal layer and the prepared second liquid crystal layer to be rotatable relative to each other, a lens device was prepared. The first liquid crystal layer and the second liquid crystal layer were in contact with each other.
Using an evaluation system conceptually shown in
The evaluation system 200 shown in
As the light source 202, a white LED light source was used. As the louver film 204 and the louver film 206, a security/privacy filter PF240W2E (manufactured by 3M) was used. In addition, the louver film 204 and the louver film 206 were disposed such that the louvers were orthogonal to each other. As the band pass filter 208, a band pass filter (#65-155, manufactured by Edmund Optics Inc.) that allowed transmission of only green light was used. As the screen 210, white paper was used.
By emitting white light from the light source 202 and allowing the white light to transmit the two louver films, parallel light was obtained. Next, the parallel light was allowed to transmit through the band pass filter 208 to obtain green light. By allowing the green light to transmit through the first liquid crystal layer 12 and the second liquid crystal layer 14 in this order, the screen 210 was irradiated with the transmitted light. The screen 210 was moved in the optical axis direction to a position at which the spot diameter of light in the screen 210 was the minimum, and a distance d between the second liquid crystal layer 14 and the screen 210 in this case was obtained as the focal length.
In a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 was 30°, the focal length was 73 cm. In addition, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 was 60°, the focal length was 35 cm. In addition, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 was 90°, the focal length was 25 cm.
As described above, it was able to be verified that the focal length was changed by changing the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14. It can be seen that, in the lens device according to the embodiment of the present invention, the thickness in the optical axis direction of the lens was thin, and the focal length was variable without changing the size in the in-plane direction.
The influence of a variation in the optical axis θ1 in the first liquid crystal layer 12 and the second liquid crystal layer 14 was verified by simulation.
In the first liquid crystal layer 12 and the second liquid crystal layer 14 prepared in Example 1, the angle of the optical axis of the first liquid crystal layer 12 was represented by θ1={α1×φ1+θ0n1}∓α, the angle of the optical axis of the second liquid crystal layer 14 was represented by θ2={α2×φ2+θ0n2}±α, random numbers were generated between +a while changing a to 0°, 0.5°, 1.0°, 2.5°, 5.0°, and 7.5°, and a case where there was a variation in the vortex alignment patterns (the angles of the optical axis) of the first liquid crystal layer 12 and the second liquid crystal layer 14 was simulated. In the first liquid crystal layer 12 and the second liquid crystal layer 14 prepared in Example 1, θ0n1=0° and θ0n2=0°.
In a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 was 60°, the phase of the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 was obtained by simulation. The results thereof are shown in
Likewise, in a case where the relative angle between the first liquid crystal layer 12 and the second liquid crystal layer 14 was 30°, the phase of the laminate of the first liquid crystal layer 12 and the second liquid crystal layer 14 was obtained by simulation. The result is shown in
It can be seen from
As can be seen from the above results, the effects of the present invention are obvious.
Number | Date | Country | Kind |
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2022-123211 | Aug 2022 | JP | national |
This application is a Continuation of PCT International Application No. PCT/JP2023/025918 filed on Jul. 13, 2023, which claims priority under 35 U.S.C. § 119 (a) to Japanese Patent Application No. 2022-123211 filed on Aug. 2, 2022. The above applications are hereby expressly incorporated by reference, in their entirety, into the present application.
Number | Date | Country | |
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Parent | PCT/JP2023/025918 | Jul 2023 | WO |
Child | 19031008 | US |