This application claims priority to China Application Serial Number 202110498691.2, filed May 8, 2021, which is herein incorporated by reference.
The present disclosure relates to a light-emitting diode structure.
The statements in this section merely provide background information related to the present disclosure and do not necessarily constitute prior art.
Nowadays, various light-emitting diode (LED) packaging components have been widely used in the fields of backlight modules and general lighting, and many of them are mixed with multiple colors. The effectiveness of such LED packaging components depends on the luminous efficiency of the LED constituent materials and the light extraction rate of the external structure, and related research is very important in this field.
In the past ten years, in order to improve the light extraction rate, a rough surface can be formed on the light-emitting plane of the LED chip, the shape of the overall structure of the LED package can be adjusted, and highly reflective materials (such as aluminum) can also be used as the metal reflective structure. However, because metals are more susceptible to oxidation and the reflectance decreases over time, the more recent research direction has gradually turned to distributed Bragg reflector (DBR). Generally, DBR is formed by alternately stacking materials with different refractive indexes. The different materials in the stacked layer have different fixed thicknesses. The thickness is defined by a single and specific target light wavelength range. Based on the principle of constructive interference and destructive interference caused by beam phase difference, the light extraction rate is improved.
A DBR structure solves the problem of reduced reflectance due to quality degradation, and can achieve high reflectance in a narrow wavelength range (for example, the wavelength of light of a specific color). However, when the required wavelength range is widened, the reflectance will drop significantly. In addition, although the DBR structure can exhibit high reflectance for incident light compared to that parallel to the normal line of the plane, the reflectance will also be significantly reduced when the incident angle is increased. In this regard, some studies divide the DBR structure into different thickness regions, that is, make it include multiple groups of DBRs with different target light wavelength ranges. The laminated layers of the same material in each DBR still have the same thickness, but still cannot meet the needs of expanding the wavelength range, and obvious destructive interference often occurs.
According to an embodiment of the disclosure, a light-emitting diode structure includes a light-emitting part and a reflective part. The light-emitting part has a light-emitting surface. The reflective part is on a side of the light-emitting part opposite to the light-emitting surface. The reflective part is a gradient distributed Bragg reflection structure and includes a plurality of first dielectric layers and a plurality of second dielectric layers. The second dielectric layers are alternately stacked with the first dielectric layers and have a refractive index different from a refractive index of the first dielectric layers. Each of the first dielectric layers has a different optical thickness. Each of the second dielectric layers has a different optical thickness. The optical thicknesses of the first dielectric layers and the optical thicknesses of the second dielectric layers vary in a gradient way away from the light-emitting part.
In an embodiment of the disclosure, a difference between the optical thicknesses of any adjacent and contacting two of the first dielectric layers and the second dielectric layers is between 1% and 3%.
In an embodiment of the disclosure, the light-emitting diode structure further includes a flat layer and a protective layer. The flat layer is located between the light-emitting part and the reflective part and attached to the reflective part. The flat layer includes a dielectric material. The protective layer is attached to the reflective part. The reflective part is located between the flat layer and the protective layer. The protective layer includes a dielectric material.
In an embodiment of the disclosure, an actual thickness of the flat layer is between 4(λmax/4nf) and 8(λmax/4nf). An actual thickness of the protective layer is between 1(λmax/4np) and 2(λmax/4np). λmax is a maximum wavelength value of a selected wavelength range. nf and np are refractive indices of the flat layer and the protective layer, respectively.
In an embodiment of the disclosure, for incident light with a wavelength of 1000 nm to 1100 nm and incident toward the light-emitting part from a side of the protective layer, a reflectance of the reflective part is less than 15%.
In an embodiment of the disclosure, for incident light that is incident from the light-emitting part toward the protective layer and parallel to a normal direction of an interface between the reflective part and the flat layer, a reflectance of the reflective part is greater than 95%. For incident light that is incident from the light-emitting part toward the protective layer and forms an angle of 60° with the normal direction of the interface between the reflective part and the flat layer, a reflectance of the reflective part is greater than 40%.
In an embodiment of the disclosure, the light-emitting diode structure further includes a substrate located between the light-emitting part and the flat layer and attached to the flat layer.
In an embodiment of the disclosure, the selected wavelength range is 450 nm to 670 nm.
In an embodiment of the disclosure, an actual thickness of any one of the first dielectric layers is greater than actual thicknesses of two of the second dielectric layers respectively adjacent to opposite sides of said any one of the first dielectric layers. The actual thickness of any one of the second dielectric layers is smaller than the actual thicknesses of two of the first dielectric layers respectively adjacent to opposite sides of said any one of the second dielectric layers.
In an embodiment of the disclosure, actual thicknesses of the first dielectric layers are between 70 nm and 140 nm. Actual thicknesses of the second dielectric layers are between 35 nm and 70 nm.
In an embodiment of the disclosure, an actual thickness of the flat layer is between 400 nm and 1000 nm. An actual thickness of the protective layer is between 180 nm and 360 nm.
In an embodiment of the disclosure, the light-emitting diode structure further includes a substrate. The light-emitting part is located between the substrate and the reflective part.
In an embodiment of the disclosure, the light-emitting diode structure further includes a substrate. The reflective part is located between the substrate and the light-emitting part.
In an embodiment of the disclosure, the optical thicknesses of the first dielectric layers and the second dielectric layers that are stacked alternately vary in a gradient way away from the light-emitting part.
In the present disclosure, the effect of broadband and high reflectance can be achieved by disposing the reflective part with gradient optical thicknesses.
It is to be understood that both the foregoing general description and the following detailed description are by examples, and are intended to provide further explanation of the disclosure as claimed.
The disclosure can be more fully understood by reading the following detailed description of the embodiment, with reference made to the accompanying drawings as follows:
Reference will now be made in detail to the present embodiments of the disclosure, examples of which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers are used in the drawings and the description to refer to the same or like parts. However, specific structural and functional details disclosed herein are merely representative for purposes of describing example embodiments, and thus may be embodied in many alternate forms and should not be construed as limited to only example embodiments set forth herein. Therefore, it should be understood that there is no intent to limit example embodiments to the particular forms disclosed, but on the contrary, example embodiments are to cover all modifications, equivalents, and alternatives falling within the scope of the disclosure.
Reference is made to
Each of the first dielectric layers 210 has a different optical thickness, and each of the second dielectric layers 220 has a different optical thickness. The optical thickness refers to the product of the actual thickness and the refractive index of the medium (i.e., the dielectric layer). The actual thickness can be understood as the physical thickness that can be measured by using the software ruler function on the screen after taking a photo with a microscope. That is, the actual thickness is the generally recognized thickness. The optical thicknesses of the first dielectric layers 210 and the optical thicknesses of the second dielectric layers 220 vary in a gradient way away from the light-emitting part 100. The “vary in a gradient way” refers to gradual increase or decrease of the optical thickness along the stacking direction without repetitive optical thickness. In other words, the reflective part 200 can be understood as a Bragg reflection structure with gradient distributed optical thicknesses. Different thicknesses can be designed to correspond to different light wavelengths, and through thickness matching, a relatively wide wavelength band (for example, visible light band) incident from the light-emitting part 100 to the reflective part 200 can achieve good reflectivity, which solves the defect that most of the known distributed Bragg reflector (DBR) structures only have high reflectance for specific narrow bands. Some aspects of the “vary in a gradient way” are explained in more detail below.
In some embodiments, if the number of the first dielectric layers 210 is m (m is a positive integer), the actual thickness of the x-th layer (x is a positive integer and 1<x<m) is set to λx/4n1, and the optical thickness is λx/4. n1 is the refractive index of the first dielectric layers 210, λx is the selected wavelength range to be corresponded, and each first dielectric layer 210 corresponds to different λx. The value of λx may gradually increase (or decrease) from the first layer to the m-th layer. In addition, the first layer referred here may be the first dielectric layer 210 closest to the light-emitting part 100, and the m-th layer may be the first dielectric layer 210 farthest from the light-emitting part 100.
Following the previous paragraph, actual values are now used for a more intuitive explanation. The following values are for ease of understanding and are not intended to limit the scope of this disclosure. For example, the reflective part 200 includes ten layers (i.e., m=10) of the first dielectric layers 210. The refractive index of the first dielectric layers 210 is 1.45 (i.e., silicon dioxide, n1=1.45), and the selected wavelength range for the first dielectric layers 210 is 460 nm to 640 nm. According to the aforementioned values, the actual value of λx is 460+(x−1)((640−460)/(10−1)). In other words, for the first dielectric layers 210, λ1 is 460 nm, λ2 is 480 nm, λ3 is 500 nm, and so on, λ10 is 640 nm. It can be further deduced that the actual thickness of the first layer of the first dielectric layers 210 is 79.3 nm (i.e., 460/(4*1.45)), and the optical thickness is 115 nm; the actual thickness of the second layer is 82.7 nm (i.e., 480/(4*1.45)), and the optical thickness is 120 nm; and so on, the actual thickness of the 10th layer is 110.3 nm (i.e., 640/(4*1.45)), and the optical thickness is 160 nm.
Similarly, if the number of the second dielectric layers 220 is p (p is a positive integer), the actual thickness of the y-th layer (y is a positive integer and 1<x<p) is λy/4n2, and the optical thickness is λy/4. n2 is the refractive index of the second dielectric layers 220, λy is the selected wavelength range to be corresponded, and each second dielectric layer 220 corresponds to different λy. The value of λy may gradually increase (or decrease) from the first layer to the p-th layer. In addition, the first layer referred here may be the second dielectric layer 220 closest to the light-emitting part 100, and the p-th layer may be the second dielectric layer 220 farthest from the light-emitting part 100.
Following the previous paragraph, actual values are now used for a more intuitive explanation. For example, the reflective part 200 includes eleven layers (i.e., p=11) of the second dielectric layers 220. The refractive index of the second dielectric layers 220 is 2.5 (i.e., trititanium pentoxide, n2=2.5), and the selected wavelength range for the second dielectric layers 220 is 450 nm to 650 nm. According to the aforementioned values, the actual value of λy is 450+(y−1)((650−450)/(11−1)). In other words, for the second dielectric layers 220, λ1 is 450 nm, λ2 is 470 nm, λ3 is 490 nm, and so on, λ11 is 650 nm. It can be further deduced that the actual thickness of the first layer of the second dielectric layers 220 is 45 nm (i.e., 450/(4*2.5)), and the optical thickness is 112.5 nm; the actual thickness of the second layer is 47 nm (i.e., 470/(4*2.5)), and the optical thickness is 117.5 nm; and so on, the actual thickness of the 11th layer is 65 nm (i.e., 650/(4*2.5)), and the optical thickness is 162.5 nm.
The first dielectric layers 210 and the second dielectric layers 220 above-mentioned can be combined to form a series of dielectric layer thicknesses in the selected wavelength range of 450 nm to 650 nm after being alternately stacked, and the thicknesses of these dielectric layers can meet the conditions and limitations of the above paragraphs. In more detail, after alternately stacking the first dielectric layers 210 and the second dielectric layers 220 using the above actual values, a structure with optical thicknesses varying in a gradient way can be formed. The optical thicknesses sequentially are 112.5 nm (a second dielectric layer 220), 115 nm (a first dielectric layer 210), 117.5 nm (a second dielectric layer 220), 120 nm (a first dielectric layer 210), . . . , 160 nm (a first dielectric layer 210), and 162.5 nm (a second dielectric layer 220). The structure has 21 layers (m layers+p layers), which can be used as an aspect of the reflective part 200. In other words, after the first dielectric layers 210 and the second dielectric layers 220 are alternately stacked, the optical thickness of each layer vary gradually from a position adjacent to the light-emitting part 100 along a direction away from the light-emitting part 100. In some embodiments, the second dielectric layer 220 with an optical thickness of 112.5 nm is the closest to the light-emitting part 100, and the second dielectric layer 220 with an optical thickness of 162.5 nm is the farthest from the light-emitting part 100. It should be noted that these limitations are only examples, and are based on the spirit of completing gradient and non-repetitive optical thicknesses, and achieving a broadband and high reflectance effect compared to the prior art.
In some embodiments, the actual thickness of any one of the first dielectric layers 210 is greater than the actual thicknesses of two of the second dielectric layers 220 respectively adjacent to opposite sides of said any one of the first dielectric layers 210. In addition, the actual thickness of any one of the second dielectric layers 220 is smaller than the actual thicknesses of two of the first dielectric layers 210 respectively adjacent to opposite sides of said any one of the second dielectric layers 220. In some embodiments, the actual thickness of a single first dielectric layer 210 is between 70 nm and 140 nm, and the actual thickness of a single second dielectric layer 220 is between 35 nm and 70 nm.
Reference is made to
In some embodiments, the light-emitting diode structure 1000 further includes a flat layer 300 and a protective layer 400. The flat layer 300 includes a dielectric material, is located between the light-emitting part 100 and the reflective part 200, and is attached to the reflective part 200. In some embodiments, the composition material of the flat layer 300 is the same as the composition material of the first dielectric layers 210 (for example, silicon dioxide), but the disclosure is not limited thereto. The protective layer 400 includes a dielectric material and is attached to the reflective part 200. The reflective part 200 is located between the flat layer 300 and the protective layer 400. In some embodiments, the composition material of the protective layer 400 is the same as the composition material of the first dielectric layers 210 (for example, silicon dioxide), but the disclosure is not limited thereto. In some embodiments, the flat layer 300 and the protective layer 400 are made of the same material.
In some embodiments, the light-emitting diode structure 1000 includes a substrate 500. The substrate 500 is located between the light-emitting part 100 and the flat layer 300 and attached to the flat layer 300. The substrate 500 may be a growth substrate for growing the light-emitting part 100, but the disclosure is not limited thereto. Since the surface of the substrate 500 is cut and polished, the surface roughness is relatively large. If the first dielectric layer 210 or the second dielectric layer 220 of only about 100 nm are directly formed on the rough surface, the accuracy of the thicknesses will be excessively affected by the high surface roughness of the substrate 500, so that the first dielectric layer 210 and the second dielectric layer 220 lose their original function of adjusting the optical phase difference. Therefore, by first forming the flat layer 300, the light can have a consistent light phase difference response when entering the reflective part 200. In addition to the effect equivalent to the reflective part 200 reflecting the light from the light-emitting part 100, the protective layer 400 also has the effect of helping the laser light LL for cutting incident from the protective layer 400 to the light-emitting diode structure 1000 to pass through the reflective part 200 smoothly, which will be described in detail later.
The data results of a specific embodiment designed according to the above principles will be explained as follows. Reference is made to
The data of the above-mentioned equal-thickness Bragg reflection structure is taken from a structure where the first dielectric layers 210 are made of silicon dioxide and the second dielectric layers 220 are made of trititanium pentoxide. The “equal-thickness” means that in the lamination in the reflective part 200 (for example, thirteen silicon dioxide layers and fourteen trititanium pentoxide layers), the actual thicknesses of the silicon dioxide layers are substantially the same, and the actual thicknesses of the trititanium pentoxide layers are substantially the same. The actual thickness of the silicon dioxide layers is different from the actual thickness of the trititanium pentoxide layers. In the example of the equal-thickness Bragg reflection structure as the control group, the actual thickness of the silicon dioxide layers is, for example, 90 nm, and the actual thickness of the trititanium pentoxide layers is, for example, 50 nm.
Next, the solid lines in
The following several embodiments are provided in order to fine-tune the light extraction rate of the light-emitting diode structure 1000 to a better and stable state. In some embodiments, a difference between the optical thicknesses of any adjacent and contacting two of the first dielectric layers 210 and the second dielectric layers 220 is between 1% and 3%. It is worth noting that when the difference between the optical thicknesses of any adjacent two dielectric layers is greater than 3%, the reflectance will be poor due to too few stacked layers (for example, less than eighteen layers) in the fixed selected wavelength range (the highest reflectance is reduced to less than 98%). As a result, the overall efficiency is not as good as the existing metal mirrors. On the contrary, when the difference between the optical thicknesses of any adjacent two dielectric layers is less than 1%, although the reflectance can be maintained above 99%, there are too many stacked layers (probably more than forty layers) in the fixed wavelength range, other problems such as poor production efficiency and poor thermal conductivity will arise.
In some embodiments, if nf and np respectively represent the refractive indices of the flat layer 300 and the protective layer 400, the actual thickness of the flat layer 300 is between 4(λmax/4nf) and 8(λmax/4nf), and the actual thickness of the protective layer 400 is between 1(λmax/4np) and 2(λmax/4np). In some embodiments, nf=np=1.45, that is, the flat layer 300 and the protective layer 400 are both silicon dioxide layers. λmax is the maximum wavelength of the selected wavelength range. The selected wavelength range may be the main wavelength range emitted by the light-emitting part 100, but the disclosure is not limited thereto. In some embodiments, the selected wavelength range is from 450 nm to 670 nm for common visible light. At this time, λmax can be set to 670 nm. The parameter setting method illustrated in this paragraph can further optimize the aforementioned effects of the flat layer 300 and the protective layer 400.
In some embodiments, the actual thickness of the flat layer 300 is 5(λmax/4nf), and the actual thickness of the protective layer 400 is 2(λmax/4np). At this time, reference can be made to
In addition, in order to facilitate the laser cutting operation of the light-emitting diode structure 1000, for incident light with a wavelength of 1000 nm to 1100 nm and incident from a side of the protective layer 400 toward the light-emitting part 100, the reflectance of the reflective part 200 is controlled to be less than 15%, which can be achieved at least by the structural conditions that the actual thickness of the flat layer 300 is 5(λmax/4nf) and the actual thickness of the protective layer 400 is 2(λmax/4np). In this way, while increasing the reflectance of the reflective part 200 to the incident light from the light-emitting part 100, the laser cutting process with a long wavelength can also be allowed to achieve the dual effects of high light extraction rate and convenient laser cutting processing.
Reference is made to
Reference is made to
Reference is made to
Reference is made to
In summary, the embodiments of the present disclosure provide light-emitting diode structures with gradient distributed Bragg reflection structures. The optical thicknesses of the dielectric layers in the reflection structures vary in a gradient way in one direction, and there are no repetitive optical thicknesses among each other. In this way, the effect of broadband and high reflectance can be achieved. In addition, the arrangement of the flat layer and the protective layer not only can better control the light phase, but also make the reflectance to the infrared laser light low and stable. Therefore, the structure of the light-emitting diode structure can have dual effects such as high light extraction rate and easy cutting processing.
Although the present disclosure has been described in considerable detail with reference to certain embodiments thereof, other embodiments are possible. Therefore, the spirit and scope of the appended claims should not be limited to the description of the embodiments contained herein.
It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the present disclosure without departing from the scope or spirit of the disclosure. In view of the foregoing, it is intended that the present disclosure cover modifications and variations of this disclosure provided they fall within the scope of the following claims.
Number | Date | Country | Kind |
---|---|---|---|
202110498691.2 | May 2021 | CN | national |