The present application is based on Japanese patent application Nos. 2006-112115 and 2007-031149, the entire contents of which are incorporated herein by reference.
1. Field of the Invention
This invention relates to a light emitting element that a group III nitride-based compound semiconductor layer is formed on a sapphire substrate, and to a communication device using the same.
2. Description of the Related Art
A GaN-based light emitting element is known as one of group III nitride-based compound semiconductor light emitting elements. The GaN-based light emitting element has emission characteristics from a UV region to a visible region. Since emitted light thereof can be combined with a wavelength conversion means such as a phosphor to provide a high-brightness white light, it is a great deal proposed to use the GaN-based light emitting element for a white light source.
Light emitting elements can be also used as a light source for optical communications. Conventionally, a high-brightness light emitting element to emit a red light (630 to 640 nm) is used as an optical communication light source in a light-emitting unit of a communication device such that a light inputted into an optical fiber is received by a light receiving element in a light-receiving unit thereof, or a light transmitted through a space is received by the light receiving element in the light-receiving unit, and the received light is then photoelectric-converted to output a received signal.
Communication optical fibers formed of quartz with a low transmission loss are well known. However, in consideration of price and precision required in its connection work, a POF (plastic optical fiber) attracts attention since it is lower in cost than the quartz and it is easy to employ. The POF has a minimum value in transmission loss at about 570 nm, i.e., the transmission loss in a wavelength band of blue to green lights is smaller than that of the red light. Thus, the light-emitting unit with the GaN-based light emitting element can be well matched to the POF.
When the GaN-based light emitting element is used for the optical communication, the emission intensity and responsiveness of the light emitting element during the operation are important factors in order to have a communication speed equal to or more than that of the red light emitting element. In this regard, it is known that a GaN-based semiconductor causes a piezoelectric field due to the property of a semiconductor layer formed on the sapphire substrate, where in case of forming a quantum well structure, there is pointed out a problem that a band in the quantum well is inclined to promote the spatial separation of electron and hole to cause a reduction in the emission intensity.
JP-A-2005-056973 discloses a method that In composition ratio X and thickness of an InXGa1-XN quantum well is controlled to enhance the emission intensity.
However, the method of JP-A-2005-056973 has a problem that it is not suited for the high-speed optical communication since it is insufficient in responsiveness required in the communication light emitting element although it can provide a good emission intensity property for general display light emitting elements.
It is an object of the invention to provide a light emitting element that can cancel the piezoelectric field due to the element structure to provide an improved match to an optical transmission line.
It is a further object of the invention to provide a communication device using the light emitting element.
(1) According to one embodiment of the invention, a light emitting element comprises:
a well layer comprising a GaN-based semiconductor;
a barrier layer next to the well layer, the barrier layer comprising a GaN-based semiconductor; and
a GaN-based semiconductor layer formed between the well layer and the barrier layer,
wherein the GaN-based semiconductor layer includes a dopant to cancel piezoelectric field caused between the well layer and the barrier layer.
In the above embodiment (1), the following modifications and changes can be made.
(i) The GaN-based semiconductor layer is formed at an interface between the barrier layer and the well layer of a SQW (single-quantum well) structure.
(ii) The GaN-based semiconductor layer is formed at an interface between the barrier layer formed on a side of a p-type layer and the well layer, and the dopant comprises Mg.
(iii) The GaN-based semiconductor layer is formed at an interface between the barrier layer formed on a side of an n-type layer and the well layer, and the dopant comprises Si.
(iv) The GaN-based semiconductor layer comprises a thickness of not less than 1.3 nm.
(v) The GaN-based semiconductor layer comprises a thickness of not less than 2.6 nm and not more than 10 nm.
(vi) The GaN-based semiconductor layer comprises a Si concentration in a range of 2.5×1018/cm3 to 1.0×1019/cm3.
(vii) The GaN-based semiconductor layer is formed at an interface between the barrier layer and the well layer of an MQW (multiquantum well) structure.
(viii) The well layer comprises an emission area in a range of 1000 μm2 to 22000 μm2.
(2) According to another embodiment of the invention, a communication device comprises:
the light emitting element as defined by the above embodiment (1); and
an optical fiber through which to transmit a light emitted from the light emitting element.
In the above embodiment (2), the following modifications and changes can be made.
(ix) The optical fiber comprises a POF (plastic optical fiber) that comprises a minimum transmission loss in a range of an emission wavelength of the light emitting element.
(3) According to another embodiment of the invention, a communication device comprises:
a light-emitting unit comprising the light emitting element as defined by the above embodiment (1); and
a light-receiving unit to receive a visible light emitted from the light-emitting unit.
The preferred embodiments according to the invention will be explained below referring to the drawings, wherein:
The communication device 100 comprises a light-emitting unit 10 for outputting a signal light, a light-receiving unit. 20 for receiving the signal light, and a POF (plastic optical fiber) 30 which is an optical transmission line to connect the light-emitting unit 10 and the light-receiving unit 20 to allow the optical communication therebetween.
The light-emitting unit 10 comprises a signal processing section 11 to which an input signal to be optically transmitted is inputted from outside, a light emitting element 12 which is formed of a GaN-based semiconductor and emits to the POF 30 a light based on the input signal according to a current supplied from the signal processing section 11. The GaN-based semiconductor is represented by a general formula: AlXGaYIn1-X-YN (0≦X≦1, 0≦Y≦1, 0≦X+Y≦1) and includes a two-element compound semiconductor such as AlN, GaN and InN, a three-element compound semiconductor such as AlXGa1-XN, AlXIn1-XN and GaXIn1-XN (where 0<X<1).
The light-receiving unit 20 comprises a light-receiving element 21 for receiving the light to be transmitted through the POF 30, and a signal processing section 22 to waveform-process the photoelectric-converted signal to extract a desired output signal.
The POF 30 is formed of a material that is transparent to an emission wavelength of the light emitting element 12. In this embodiment, it is a single-core POF formed of a polymethylmethacrylate (PMMA) resin, and has a feature that its transmission loss is small to the emission wavelength of the GaN-based light emitting element. It may be a multicore POF formed of a similar material.
The light emitting element 12 is a horizontal type of light emitting element where its p-side and n-side electrodes are horizontally disposed. It comprises, sequentially stacked on a sapphire substrate 101 as a growth substrate for growing a group III nitride-based compound semiconductor, an AlN buffer layer 102, an Si-doped n-type GaN:Si contact/cladding layer 103, an SQW 104 with an InGaN/GaN quantum well structure, an Mg-doped p-type Al0.12Ga0.88N:Mg cladding layer 105, an Mg-doped p-type GaN:Mg contact layer 106, and a transparent electrode 107 formed of ITO (indium tin oxide) to spread current into the p-type GaN:Mg contact layer 106. The AlN buffer layer 102 through the p-type GaN:Mg contact layer 106 are formed by MOCVD (metalorganic chemical vapor deposition). The light emitting element 12 has an emission area of 22000 μm2, but the emission area is preferably smaller than this and the emission area is preferably not less than 1000 μm2. The optical output increases as the emission area increases, while the responsiveness is enhanced as the emission area decreases. Therefore, the emission area is desirably not less than 1000 μm2 and not more than 22000 μm2 so as to provide the light emitting element with a good responsiveness and a high optical output.
A pad electrode 108 of Au is formed on the surface of the transparent electrode 107. An n-side electrode 109 of Al is formed on the surface of the n-type GaN:Si contact/cladding layer 103 to be exposed by removing a part of the p-type GaN:Mg contact layer 106 through the n-type GaN:Si contact/cladding layer 103 by etching.
The AlN buffer layer 102 is formed by supplying TMG (trimethylgallium), TMA (trimethylaluminum) and an H2 carrier gas into a reactor in which the sapphire substrate 101 is placed.
The n-type GaN:Si contact/cladding layer 103 is formed about 4 μm thick on the AlN buffer layer 102 by supplying TMG, NH3 and the H2 carrier gas into the reactor in which the sapphire substrate 101 is placed, while using as an Si source monosilane (═SiH4) which is a dopant for providing the n-type conductivity.
The SQW 104 is formed by supplying TMI (trimethylindium), TMG, NH3 and the H2 carrier gas into the reactor. TMI, TMG and NH3 are supplied to form the In0.15Ga0.85N well layer 104A, and TMG and NH3 are supplied to form the GaN barrier layer 104B. The In0.15Ga0.85N well layer 104A is desirably 1.0 to 4.0 nm in average thickness in consideration of the responsiveness and optical output.
In forming the GaN barrier layer 104B on the p-type layer side, as shown in
The p-type Al0.12Ga0.88N:Mg cladding layer 105 is formed by supplying NH3, TMG, TMA and H2 carrier gas as well as the Cp2Mg as an Mg source (dopant) into the reactor in which the sapphire substrate 101 is placed.
The p-type GaN contact layer 106 is formed by supplying NH3, TMG and H2 carrier gas as well as the Cp2Mg as an Mg source (dopant) into the reactor in which the sapphire substrate 101 is placed.
As shown in
In consideration of this, as shown in
With regard to the LED (1), the optical output is 3.4 W, the highest among them since it has the MQW light-emitting layer. However, the rise time and fall time are long and the cutoff frequency affecting the communication speed is low. Therefore, it is difficult to use it as a light source to conduct the high-speed optical communication. Herein, the rise time is defined as a time required in reaching 90% from 10% of a steady-state value in pulse response of current density, and the fall, time is defined as a time required in reaching 10% from 90% of a steady-state value. The cutoff frequency fc is calculated by the formula:
fc=(0.35/((tr+tf)/2)×1000
where tr is the rise time and tf is the fall time.
With regard to the LED (2), the communication response characteristics are enhanced since it has the single light-emitting layer as compared to the MQW light-emitting layer of the LED (1). However, the optical output of the LED (2) decreases as compared to the MQW.
With regard to the LED (3), the rise time and fall time are shortened and the cutoff frequency is high. Thus, the optical response speed can be enhanced.
In the first embodiment, the Mg-doped GaN layer 140 is formed at the interface between the InGaN well layer 104A and the GaN barrier layer 104B next to the p-type layer in order to cancel the piezoelectric field caused in the GaN-based semiconductor layer. Thus, the piezoelectric field causing the band inclination can be canceled to enhance the optical response speed.
Although in the first embodiment the Mg-doped GaN layer 140 is formed to cancel the piezoelectric field, other dopants than the Mg may be used such as Ca and Be. Further, other GaN-based semiconductor layer such as AlGaN, InGaN and AlInGaN may be used instead of the GaN. However, the GaN is preferably used in terms of easiness in controlling the band by the doping of Mg.
Although in the first embodiment the Mg-doped GaN layer 140 is formed on the side of the GaN barrier layer 104B next to the p-type layer in order to cancel the piezoelectric field, a layer to cancel the piezoelectric field may be formed on the side of the GaN barrier layer 104B next to the n-type layer.
The light emitting element 12 of the second embodiment is different from that of the first embodiment in that an Si-doped GaN layer 141 is, as shown in
As shown in
In consideration of this, as shown in
With regard to the LED's (1) and (2), results thereof are the same as explained earlier in the first embodiment and explanations thereof are omitted here. With regard to the LED's (4) and (5), by forming the Si-doped GaN layer 141, the fall time is shortened and the cutoff frequency is high to enhance the optical response speed. The optical outputs thereof are the same as the LED (2).
For example, the Si-doped GaN layer 141 is set to be 5.2 nm in thickness, and the rise/fall times thereof are measured according as the Si concentration changes.
As shown in
As shown in
For example, the Si-doped GaN layer 141 is set to be 5.0×1018/cm3 in Si concentration, and the rise/fall times thereof are measured according as the thickness of the Si-doped GaN layer 141 changes.
As shown in
As shown in
In the second embodiment, the Si-doped GaN layer 141 is formed at the interface between the InGaN well layer 104A and the GaN barrier layer 104B next to the n-type layer in order to cancel the piezoelectric field caused in the GaN-based semiconductor layer. Thus, the piezoelectric field causing the band inclination can be canceled to enhance the optical response speed.
Although in the second embodiment the Si-doped GaN layer 141 is formed to cancel the piezoelectric field, other dopants than the Si may be used such as Ge and C. Further, other GaN-based semiconductor layer such as AlGaN, InGaN and AlInGaN may be used instead of the GaN. However, the GaN is preferably used in terms of easiness in controlling the band by the doping of Si.
The light emitting element 12 of the third embodiment is different from that of the first embodiment in that, in the SQW 104 as shown in
In the third embodiment, the Mg-doped GaN layer 140 is formed at the interface between the InGaN well layer 104A and the GaN barrier layer 104B next to the p-type layer, and the Si-doped GaN layer 141 is formed at the interface between the InGaN well layer 104A and the GaN barrier layer 104B next to the n-type layer in order to cancel the piezoelectric field caused in the GaN-based semiconductor layer. Thus, the piezoelectric field causing the band inclination can be further completely canceled to enhance the optical response speed.
Although in the above embodiments the light-emitting layer is formed of the SQW, the invention can be also applied to an MQW (multiquantum well).
The light emitting element 12 of the fourth embodiment is formed by applying the same composition as the third embodiment to the MQW other the SQW. It is different from that of the third embodiment in that, in the MQW 110 as shown in
In the fourth embodiment, adding to the effects of the third embodiment, the light emitting element 12 can have an optical output enhanced by the MQW.
As shown in
The light-emitting unit 210 comprises a signal processing section 211 to which an input signal to be optically transmitted is inputted from outside, the light emitting element 12 which is formed of a GaN-based semiconductor and emits through space toward the light-receiving unit 220 a light based on the input signal according to a current supplied from the signal processing section 211. Meanwhile, the light emitting element 12 is the same as in the first embodiment and explanations thereof are omitted here.
The light-receiving unit 220 comprises a light-receiving element 21 for receiving the light to be transmitted through space, and a signal processing section 222 to waveform-process the photoelectric-converted signal to extract a desired output signal.
Also in the fifth embodiment, the Mg-doped GaN layer 140 is formed at the interface between the InGaN well layer 104A and the GaN barrier layer 104B next to the p-type layer in order to cancel the piezoelectric field caused in the GaN-based semiconductor layer. Thus, the piezoelectric field causing the band inclination can be canceled to enhance the optical response speed.
Furthermore, since the light emitting element 12 emits a visible light, whether the communication is in action or not can be confirmed by human eyes. Especially, since the light emitting element 12 is formed of the GaN-based semiconductor layer to emit blue to green light, the human eyes can clearly perceive it. Further, since the optical output thereof can be higher than the optical communication LED to emit red light, long-distance communication can be achieved. In case of infrared communication, there are problems that the communication speed is as low as about 1 to 100 Mbps, and whether the communication is in action or not cannot be confirmed by the human eyes since it is not a visible light. In case of red light, since the optical output is as low as about 1 mW, a spatial distance available for the communication is only several centimeters and not practical.
As such, the communication device 200 of the embodiment can be cancel the piezoelectric field caused by the structure of the light emitting element, and can also use the communication signal light as a light for confirming the operation of the device.
Although the invention has been described with respect to the specific embodiments for complete and clear disclosure, the appended claims are not to be thus limited but are to be construed as embodying all modifications and alternative constructions that may occur to one skilled in the art which fairly fall within the basic teaching herein set forth.
Number | Date | Country | Kind |
---|---|---|---|
2006-112115 | Apr 2006 | JP | national |
2007-031149 | Feb 2007 | JP | national |