This U.S. non-provisional patent application claims priority to and benefits of Korean Patent Application No. 10-2022-0055671 under 35 U.S.C. § 119, filed on May 4, 2022, the entire contents of which are incorporated herein by reference.
The disclosure herein relates to a light-emitting element and a display device including the same, and more particularly, to a light-emitting element including an insulating layer between a light-emitting layer and a hole transport region, and a display device including the same.
Recently, an organic electroluminescence display device, as an image display device, has been actively developed. The organic electroluminescence display device is different from a liquid crystal display device and is a so-called self-luminous display device which realizes display by having an organic compound-containing a light-emitting material emit light in the light-emitting layer through re-combination of holes and electrons injected from a first electrode and a second electrode.
In applying a light-emitting element to a display device, a low driving voltage, high luminous efficiency, and long lifespan are required for the light-emitting element, and the development of a structure for the light-emitting element is required to realize those requirements stably.
The disclosure provides a light-emitting element having high luminous efficiency and improved roll-off characteristics at a high luminance, and a display device including the same.
An embodiment of the disclosure provides a light-emitting element including a first electrode; an insulating layer including a plurality of sub-insulating layers disposed on the first electrode, spaced apart from each other by a distance in a first direction, and having a bar shape extending in a second direction substantially perpendicular to the first direction; a hole transport region disposed on the insulating layer and including a contact portion in contact with the first electrode; and a non-contact portion not contacting the first electrode; a light-emitting layer disposed on the hole transport region and including a light-emitting portion overlapping the contact portion in a plan view, and a diffusion portion overlapping the non-contact portion in a plan view; an electron transport region disposed on the light-emitting layer; and a second electrode disposed on the electron transport region.
In an embodiment, the light-emitting layer may emit light in a range of about 450 nm to about 520 nm.
In an embodiment, a thickness of each of the sub-insulating layers may be in a range of about 30 nm to about 60 nm.
In an embodiment, a width in the first direction of each of the plurality of sub-insulating layers may be in a range of about 150 nm to about 200 nm.
In an embodiment, the electron transport region may include a plurality of first portions overlapping the plurality of sub-insulating layers in a plan view, and a plurality of second portions non-overlapping the sub-insulating layers in a plan view, wherein each of the plurality of first portions may have a convex shape in the direction of the second electrode, and each of the plurality of second portions may have a convex shape in the direction of the first electrode.
In an embodiment, a sum of the separation distance between adjacent sub-insulating layers of the plurality of sub-insulating layers and a width in the first direction of one of the adjacent sub-insulating layers may be in a range of about 500 nm to about 600 nm.
In an embodiment, each of the plurality of sub-insulating layer may include a photosensitizer for laser interference lithography.
In an embodiment, the insulating layer may have a visible light transmittance of about 85% or more.
In an embodiment, the light-emitting layer may be a thermally-activated delayed fluorescent light-emitting layer, a hyper-fluorescent light-emitting layer, or a phosphorescent light-emitting layer.
In an embodiment, excitons may be formed in the light-emitting layer, and a density of the excitons in the light-emitting portion may be greater than a density of the excitons in the diffusion portion.
In an embodiment of the disclosure, a display device includes first to third light-emitting regions; a circuit layer disposed on a base substrate; and a light-emitting layer including a pixel defining film disposed on the circuit layer and having an opening, and first to third light-emitting elements, wherein each of the first to third light-emitting elements include a first electrode exposed by the pixel defining film; an insulating layer including a plurality of sub-insulating layers disposed on the first electrode, spaced apart from each other by a distance in a first direction in the opening, and having a bar shape extending in a second direction substantially perpendicular to the first direction in a plan view; a hole transport region disposed on the insulating layer and including a contact portion in contact with the first electrode, and a non-contact portion not contacting the first electrode; a light-emitting layer disposed on the hole transport region and divided by the pixel defining film; an electron transport region disposed on the light-emitting layer; and a second electrode disposed on the electron transport region.
In an embodiment, the light-emitting layer may be a thermally activated delayed fluorescent light-emitting layer, a hyper-fluorescent light-emitting layer, or a phosphorescent light-emitting layer.
In an embodiment, the light-emitting layer may include a first light-emitting layer disposed to correspond to the first light-emitting region, a second light-emitting layer disposed to correspond to the second light-emitting region, and a third light-emitting layer disposed to correspond to the third light-emitting region, and the first to third light-emitting layers may respectively emit light of different wavelength ranges.
In an embodiment, the electron transport region may include a plurality of first portions overlapping the plurality of sub-insulating layers in a plan view, and a plurality of second portions non-overlapping the sub-insulating layers in a plan view, wherein each of the first portions may have a convex shape in a direction of the second electrode, and each of the second portions may have a convex shape in a direction of the first electrode.
In an embodiment, in at least one of the first to third light-emitting elements, a thickness of each of the plurality of sub-insulating layers may be in a range of about 30 nm to about 60 nm.
In an embodiment, a sum of a separation distance between adjacent sub-insulating layers of the plurality of sub-insulating layers and a width in the first direction of one of the adjacent sub-insulating layers may be about 500 nm to about 600 nm.
In an embodiment, in at least one of the first to third light-emitting elements, the width in the first direction of each of the sub-insulating layers may be in a range of about 150 nm to about 200 nm.
In an embodiment, the insulating layer may have a visible light transmittance of about 85% or more.
In an embodiment, each of the plurality of sub-insulating layer may include a photosensitizer for laser interference lithography.
In an embodiment, the light-emitting layer may include a light-emitting portion overlapping the contact portion in a plan view, and a diffusion portion overlapping the non-contact portion in a plan view, wherein excitons may be formed in the light-emitting layer, and a density of the excitons in the light-emitting portion may be greater than a density of the excitons in the diffusion portion.
The accompanying drawings are included to provide a further understanding of the disclosure, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the disclosure and, together with the description, serve to explain principles of the disclosure. In the drawings:
In the disclosure, various modifications can be made, various forms can be used, and specific embodiments will be illustrated in the drawings and described in detail in the text. However, this is not intended to limit the disclosure to a specific form disclosed, and it will be understood that all changes, equivalents, and substitutes which fall in the spirit and technical scope of the disclosure should be included.
When an element, such as a layer, is referred to as being “on,” “connected to,” or “coupled to” another element or layer, it may be directly on, connected to, or coupled to the other element or layer or intervening elements or layers may be present. When, however, an element or layer is referred to as being “directly on,” “directly connected to,” or “directly coupled to” another element or layer, there are no intervening elements or layers present. To this end, the term “connected” may refer to physical, electrical, and/or fluid connection, with or without intervening elements.
Meanwhile, in the disclosure, “directly disposed” may mean that there is no layer, film, region, plate, etc. added between a portion such as a layer, film, region, or plate and another portion. For example, “direct disposed” may mean placing two layers or two members without using an additional member such as an adhesive member therebetween.
The same reference numerals or symbols refer to the same elements. In addition, in the drawings, the thicknesses, ratios, and dimensions of elements may be exaggerated for effective description of technical content.
The term “and/or” includes all combinations of one or more of which associated configurations may define. For example, “A and/or B” may be understood to mean “A, B, or A and B.”
For the purposes of this disclosure, the phrase “at least one of A and B” may be construed as A only, B only, or any combination of A and B. Also, “at least one of X, Y, and Z” and “at least one selected from the group consisting of X, Y, and Z” may be construed as X only, Y only, Z only, or any combination of two or more of X, Y, and Z.
Terms such as first and second may be used to describe various elements, but the elements should not be limited by the terms. These terms are only used for the purpose of distinguishing one element from other elements. For example, without departing from the scope of the disclosure, a first element may be referred to as a second element, and similarly, a second element may be referred to as a first element. Singular expressions may include plural expressions unless the context clearly indicates otherwise.
In addition, terms such as “below”, “lower”, “above”, and “upper” are used to describe the relationship between elements shown in the drawings. The terms are relative concepts and are described based on the directions indicated in the drawings.
Terms such as “include” or “have” are intended to designate the presence of a feature, number, step, action, element, part, or combination thereof described in the specification, and it should be understood that it does not preclude the possibility of presence or addition of one or more other features, numbers, steps, operations, elements, parts, or combinations thereof.
Unless otherwise defined or implied herein, all terms (including technical and scientific terms) used in this specification have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. In addition, it will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the related technology, and should not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
Hereinafter, a display device according to an embodiment of the disclosure will be described with reference to the accompanying drawings.
Referring to
The display device DD may display an image IM through an active region AA-DD. The active region AA-DD may include a plane defined by a first direction axis DR1 and a second direction axis DR2. The active region AA-DD may further include a curved surface bent from at least one side of the plane defined by the first direction axis DR1 and the second direction axis DR2. As illustrated in
In this specification, the first direction axis DR1 and the second direction axis DR2 are perpendicular to each other, and the third direction axis DR3 may be a direction normal to the plane defined by the first direction axis DR1 and the second direction axis DR2.
The display device DD according to an embodiment of the disclosure may include a display module DM and a window WM disposed on the display module DM. The display module DM may include a base layer BS, a circuit layer DP-CL disposed on the base layer BS, and a light-emitting element layer DP-ED disposed on the circuit layer DP-CL.
The base layer BS may be a member configured to provide a base surface on which the light-emitting element layer DP-ED is disposed. The base layer BS may be a glass substrate, a metal substrate, a polymer substrate, or the like. However, the embodiment of the disclosure is not limited thereto, and the base layer BS may be an inorganic layer, a functional layer, or a composite layer (or composite material layer).
The base layer BS may have a multi-layered structure. For example, the base layer BS may have a three-layer structure of a polymer resin layer, an adhesive layer, and a polymer resin layer. In particular, the polymer resin layer may contain a polyimide-based resin. The polymer resin layer may include at least one of an acryl-based resin, a methacryl-based resin, a polyisoprene-based resin, a vinyl-based resin, an epoxy-based resin, a urethane-based resin, a cellulose-based resin, a siloxane-based resin, a polyamide-based resin, a novolak-type phenol-based resin, or a perylene-based resin. In this specification, an “X-based” resin means to include a functional group of “X”.
In an embodiment of the disclosure, the circuit layer DP-CL may be disposed on the base layer BS, and the circuit layer DP-CL may include transistors (not illustrated). Each of the transistors (not illustrated) may include a control electrode, an input electrode, and an output electrode. For example, the circuit layer DP-CL may include a switching transistor and a driving transistor which are configured to drive light-emitting elements ED-1, ED-2, and ED-3 of the light-emitting element layer DP-ED.
The light-emitting element layer DP-ED may be disposed on the circuit layer DP-CL. The light-emitting element layer DP-ED may include a pixel defining film PDL, the light-emitting elements ED-1, ED-2, and ED-3 disposed between portions of the pixel defining film PDL, and an encapsulation layer TFE disposed on the light-emitting elements ED-1, ED-2, and ED-3. The light-emitting element layer DP-ED may include an organic light-emitting element or a quantum dot light-emitting element as the light-emitting elements ED-1, ED-2, and ED-3.
The display device DD according to an embodiment of the disclosure may further include another layer between the light-emitting element layer DP-ED and the window WM. For example, the display device DD according to an embodiment of the disclosure may further include at least one of optical functional layers such as a light path control layer configured to change a light path between the light-emitting element layer DP-ED and the window WM or a reflection prevention layer configured to reduce the reflectance of external light incident from the outside.
The window WM may be disposed on the display module DM. The window WM may correspond to the uppermost layer of the display device DD. The window WM may be a tempered glass substrate that has been tempered. Since the window WM includes a reinforced surface, the display module DM may be reliably protected from an external impact. The window WM according to an embodiment of the disclosure may further include a printed layer (not illustrated) disposed on an inner or outer edge thereof. For example, the printed layer (not illustrated) may be a portion provided to correspond to a peripheral region NAA-DM. An adhesive member (not illustrated) may be further disposed between the window WM and the display module DM. The adhesive member (not illustrated) may include an optically clear adhesive layer.
The display module DM may include an active region AA-DM and a peripheral region NAA-DM adjacent to the periphery of the active region AA-DM. The active region AA-DM may be activated according to an electrical signal. The peripheral region NAA-DM may surround the active region AA-DM. A driving circuit or a driving line configured to drive the active region AA-DM, various signal lines or pads configured to provide an electrical signal to the active region AA-DM, electronic elements, or the like may be disposed in the peripheral region NAA-DM.
Referring to
The light-emitting regions PXA may include a first light-emitting region PXA-R, a second light-emitting region PXA-G, and a third light-emitting region PXA-B which respectively correspond to the light-emitting elements ED-1, ED-2, and ED-3. The first to third light-emitting regions PXA-R, PXA-G, and PXA-B may be regions in which light generated from each of the light-emitting elements ED-1, ED-2, and ED-3 is emitted. The first to third light-emitting regions PXA-R, PXA-G, and PXA-B may correspond to pixel openings OH in each of the light-emitting elements ED-1, ED-2, and ED-3.
In a plan view, the first to third light-emitting regions PXA-R, PXA-G, and PXA-B may not overlap each other and may be separated from each other. For example, a non-light-emitting region NPXA may be disposed between adjacent light-emitting regions PXA-R, PXA-G, and PXA-B.
Each of the light-emitting regions PXA-R, PXA-G, and PXA-B may be divided by the pixel defining film PDL. The non-light-emitting regions NPXA may be regions between neighboring light-emitting regions PXA-R, PXA-G, and PXA-B and correspond to the pixel defining film PDL. In this specification, each of the light-emitting regions PXA-R, PXA-G, and PXA-B may correspond to a pixel. The pixel defining film PDL may separate the light-emitting elements ED-1, ED-2, and ED-3 from each other. The light-emitting layers EML-R, EML-G, and EML-B of the light-emitting elements ED-1, ED-2, and ED-3 may be disposed in the openings OH defined in the pixel defining film PDL so that they may be separated from each other. Insulating layers IL-1, IL-2, and IL-3 of the light-emitting elements ED-1, ED-2, and ED-3 may be disposed in the openings OH defined in the pixel defining film PDL so that they may be separated from each other.
The light-emitting regions PXA-R, PXA-G, and PXA-B may be divided into groups according to the color of light generated from the light-emitting elements ED-1, ED-2, and ED-3. Three light-emitting regions PXA-R, PXA-G, and PXA-B configured to emit red light, green light, and blue light are disposed in the display device DD according to an embodiment of the disclosure, which is illustrated in
In the display device DD according to an embodiment of the disclosure, the light-emitting elements ED-1, ED-2, and ED-3 may emit light of different wavelength ranges. For example, in an embodiment of the disclosure, the display device DD may include a first light-emitting element ED-1 configured to emit red light, a second light-emitting element ED-2 configured to emit green light, and a third light-emitting element ED-3 configured to emit blue light. For example, the red light-emitting region PXA-R, the green light-emitting region PXA-G, and the blue light-emitting region PXA-B of the display device DD may respectively correspond to the first light-emitting element ED-1, the second light-emitting element ED-2, and the third light-emitting element ED-3.
The light-emitting regions PXA-R, PXA-G, and PXA-B in the display device DD according to an embodiment of the disclosure may be arranged in a stripe shape. Referring to
Although
The arrangement shape of the light-emitting regions PXA-R, PXA-G, and PXA-B is not limited to what is illustrated in
Each of the light-emitting elements ED-1, ED-2, and ED-3 may have the structure of a light-emitting element ED according to an embodiment of the disclosure, which will be described below with reference to
The encapsulation layer TFE may cover the light-emitting elements ED-1, ED-2, and ED-3. The encapsulation layer TFE may seal the light-emitting element layer DP-ED. The encapsulation layer TFE may be a thin-film encapsulation layer. The encapsulation layer TFE may be a single layer or include layers stacked on top of each other. The encapsulation layer TFE may include at least one insulating layer. The encapsulation layer TFE according to an embodiment of the disclosure may include at least one inorganic layer (hereinafter referred to as an inorganic encapsulation layer). The encapsulation layer TFE according to an embodiment of the disclosure may include at least one organic layer (hereinafter referred to as an organic encapsulation layer) and at least one inorganic encapsulation layer.
The inorganic encapsulation layer may protect the light-emitting element layer DP-ED from moisture or oxygen, and the organic encapsulation layer may protect the light-emitting element layer DP-ED from foreign substances such as dust particles. The inorganic encapsulation layer may contain silicon nitride, silicon oxynitride, silicon oxide, titanium oxide, aluminum oxide, or the like, but is not particularly limited thereto. The organic encapsulation layer may contain an acryl-based compound, an epoxy-based compound, or the like. The organic encapsulation layer may contain a photopolymerizable organic material and is not particularly limited thereto.
The encapsulation layer TFE may be disposed on the second electrode EL2 and may be disposed to fill the opening OH.
The insulating layers IL-1, IL-2, and IL-3 of the light-emitting elements ED-1, ED-2, and ED-3 may include sub-insulating layers S-IL1 to S-ILn disposed to be spaced apart from each other in the second direction DR2 in a plan view. The sub-insulating layers S-IL1 to S-ILn may be disposed on the first electrode EL1 in the openings OH defined in the pixel defining film PDL. Each of the sub-insulating layers S-IL1 to S-ILn may have a shape extending in the first direction DR1. The insulating layers IL-1, IL-2, and IL-3 may control a contact area between the first electrode EL1 and the hole transport region HTR. The sub-insulating layers S-IL1 to S-ILn will be described in more detail with reference to
Referring to
The first electrode EL1 has conductivity. The first electrode EL1 may be formed of a metal material, a metal alloy, or a conductive compound. The first electrode EL1 may be an anode or a cathode. However, the embodiment of the disclosure is not limited thereto. The first electrode EL1 may be a pixel electrode. The first electrode EL1 may be a transmissive electrode, a transflective electrode, or a reflective electrode. The first electrode EL1 may contain at least one selected from the group consisting of Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF, Mo, Ti, W, In, Sn, and Zn, a compound of two or more selected therefrom, a mixture of two or more selected therefrom, or an oxide thereof.
The insulating layer IL may have insulating properties. The insulating layer IL may include N sub-insulating layers S-IL1 to S-ILn disposed to be spaced apart from each other in the second direction DR2. Each of the sub-insulating layers S-IL1 to S-ILn may have a bar shape extending in the first direction DR1. For the convenience of explanation,
The sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 may be disposed to be spaced apart from each other by a distance (e.g., a predetermined or selectable distance) in the second direction DR2. The insulating layer IL may expose a portion of the first electrode ELL The first sub-insulating layer S-IL1 and the second sub-insulating layer S-IL2 may be disposed to be spaced apart from each other by a first distance L1, the second sub-insulating layer S-IL2 and the third sub-insulating layer S-IL3 may be disposed to be spaced apart from each other by a second distance L2, and the third sub-insulating layer S-IL3 and the fourth sub-insulating layer S-IL4 may be disposed to be spaced apart from each other by a third distance L3. The separation distances L1, L2, and L3 of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 may all be the same, or at least one thereof may be different from the others.
The sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 disposed to be spaced apart from each other may affect the occurrence of a step difference on the surfaces of the hole transport region HTR, the light-emitting layer EML, the electron transport region ETR, and the second electrode EL2 which are disposed on the insulating layer IL. For example, in a cross-sectional view, the electron transport region ETR may include first portions PA1 respectively overlapping the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4, and second portions PA2 non-overlapping the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4. The first portions PA1 and the second portions PA2 may have a height difference in a thickness direction. The first portions PA1 may have a convex shape in the direction of the second electrode EL2, and the second portions PA2 may have a convex shape in the direction of the first electrode ELL Accordingly, the electron transport region ETR may have a curved shape. The descriptions of the first portions PA1 and the second portions PA2 of the electron transport region ETR may be equally applied to a contact portion AA1 and a non-contact portion AA2 of the hole transport region HTR, and a light-emitting portion EAA and a diffusion portion DAA of the light-emitting layer EML. The descriptions of the first portions PA1 and the second portions PA2 may be equally applied to a portion in which the second electrode EL2 overlaps the first portions PA1 and a portion in which the second electrode EL2 overlaps the second portions PA2, respectively.
In general, at the interface between an organic layer and a metal layer, there is a problem in which energy loss increases due to surface plasmon-polaritons (SPP). Since the light-emitting element ED according to an embodiment of the disclosure includes the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4, and the surface of the electron transport region ETR has a curved shape due to a step difference formed by the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4, a diffraction grating may be formed at the interface between the electron transport region ETR, which is an organic layer, and the second electrode EL2, which is a metal layer. Accordingly, as a surface plasmon-polariton phenomenon may be reduced at the interface between the electron transport region ETR as an organic layer, and the second electrode EL2 as a metal layer, the efficiency of the light-emitting element ED may be improved. In case that the separation distances L1, L2, and L3 of adjacent sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 are adjusted, the luminous efficiency of light in a specific wavelength range, which is emitted from the light-emitting element ED, may be increased. For example, in case that the separation distances L1, L2, and L3 of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 are adjusted to be in a range of about 300 nm to about 400 nm, the light-emitting element ED configured to emit light having a wavelength range of about 450 nm to about 520 nm may exhibit excellent (or desirable) luminous efficiency.
The widths W1, W2, W3, and W4 of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 in the second direction DR2 may be in a range of about 150 nm to about 200 nm. The widths W1, W2, W3, and W4 of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 in the second direction DR2 may all be the same, or at least one thereof may be different from the others. In case that the widths W1, W2, W3, and W4 of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 in the second direction DR2 are less than about 150 nm or more than about 200 nm, the luminous efficiency of the light-emitting element ED may be reduced.
The sum of the separation distances L1, L2, and L3 of adjacent sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 and the widths W1, W2, W3, and W4 of the sub-insulating layers S-IL1, S-IL2, S-IL3, the S-IL4 in the second direction DR2 may be in a range of about 500 nm to about 600 nm. The sum of the separation distances L1, L2, and L3 of the adjacent sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 and the widths W1, W2, W3, and W4 of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 in the second direction DR2 is defined as a pitch of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4. The pitch of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 may affect the luminous efficiency of light emitted from the light-emitting element ED. In case that the wavelength range of the light emitted from the light-emitting element ED is blue light having a wavelength range of about 450 nm to about 520 nm, in case that the pitch of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 is adjusted to be in a range of about 500 nm to about 600 nm, the light-emitting element ED may have excellent luminous efficiency.
The thickness TIL of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 may be in a range of about 30 nm to about 60 nm. In case that the thickness TIL of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 is less than 30 nm, the step difference (or height or thickness difference) in a curved shape obtained by the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 is not large. Therefore, a diffraction grating is not formed at the interface between the electron transport region ETR and the second electrode EL2, and it is difficult to reduce a surface plasmon-polariton phenomenon. In case that the thickness TIL of the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 exceeds about 60 nm, an excessive step difference may be formed on the surface of the hole transport region HTR disposed on the insulating layer IL, thus causing a problem in which a leakage current occurs.
The insulating layer IL may contain an insulating material. For example, the insulating layer IL may contain a photosensitizer for laser interference lithography. A laser interference lithography process is a method of patterning by irradiating an interference pattern on a member containing a photosensitizer by using two laser beams. The photosensitizer for laser interference lithography may be a photoresist. In case that the photoresist is of a negative type, a portion on which light is irradiated may remain, and in case that the photoresist is of a positive type, the portion on which light is irradiated may be removed. In case that the insulating layer IL includes a photosensitizer for laser interference lithography, the insulating layer IL may be formed through a laser interference lithography process using an argon laser as a light source. However, this is only an example, and any material may be used for the insulating layer IL without limitation as long as the material has insulating properties. The insulating layer IL may have a visible light transmittance of about 85% or more.
The hole transport region HTR is provided on the first electrode ELL The hole transport region HTR may include at least one of a hole injection layer (not illustrated), a hole transport layer (not illustrated), a buffer layer or an auxiliary light-emitting layer (not illustrated), or an electron blocking layer (not illustrated). The thickness of the hole transport region HTR may be, for example, in a range of about 50 Å to about 15,000 Å.
The hole transport region HTR may have a single layer made of a single material, a single layer made of different materials, or a multi-layered structure having layers made of different materials.
For example, the hole transport region HTR may have a single-layered structure having a hole injection layer (not illustrated) or a hole transport layer (not illustrated), or a single-layered structure made of a hole injection material and a hole transport material. The hole transport region HTR may have a single-layered structure made of different materials, or a structure made of a hole injection layer (not illustrated)/a hole transport layer (not illustrated), a hole injection layer (not illustrated)/a hole transport layer (not illustrated)/a buffer layer (not illustrated), a hole injection layer (not illustrated)/a buffer layer (not illustrated), a hole transport layer (not illustrated)/a buffer layer (not illustrated), or a hole injection layer (not illustrated)/a hole transport layer (not illustrated)/an electron blocking layer (not illustrated), which are sequentially stacked each other from the first electrode EL1, but the embodiment of the disclosure is not limited thereto.
The hole transport region HTR may be formed by using various methods such as a vacuum deposition method, a spin coating method, a casting method, a Langmuir-Blodgett (LB) method, an inkjet printing method, a laser printing method, or a laser induced thermal imaging (LITI) method.
The hole transport region HTR may include a contact portion AA1 contacting the first electrode EL1 and a non-contact portion AA2 in non-contact with the first electrode ELL The contact portion AA1 may be convex in the direction of the first electrode EL1, and the non-contact portion AA2 may be convex in the direction of the second electrode EL2.
The number of holes H transmitted to the light-emitting layer EML by the contact portion AA1 may be greater than the number of holes H transmitted to the light-emitting layer EML by the non-contact portion AA2. Accordingly, the number of excitons EX formed by the bonding of holes H and electrons E may vary depending on the location of the light-emitting layer EML, and the presence or absence of light emission may be determined according to the location of the light-emitting layer EML. For example, the presence or absence of light emission may be determined depending on whether or not the light-emitting layer EML overlaps the insulating layer IL.
The light-emitting layer EML is disposed on the hole transport region HTR. The light-emitting layer EML may have a single layer made of a single material, a single layer made of different materials, or a multi-layered structure having layers made of different materials.
The light-emitting layer EML may be a thermally-activated delayed fluorescent light-emitting layer, a hyper-fluorescent light-emitting layer, or a phosphorescent light-emitting layer. The light-emitting layer EML may contain a thermally-activated delayed fluorescent material, a hyper-fluorescent material, or a phosphorescent material which is used for triplet excitons EX to emit light. The luminous efficiency of a light-emitting element configured to emit thermally activated delayed fluorescent light, hyper-fluorescent light, or phosphorescent light may be reduced due to a triplet-triplet-annihilation (TTA) phenomenon in which interference between triplet excitons EX causes annihilation, or due to a triplet-polaron-quenching (TPQ) phenomenon in which interference between triplet excitons EX and the holes H or electrons E causes quenching. There is a problem in which a triplet-triplet-annihilation phenomenon and a triplet-polaron-quenching phenomenon increase as the density of triplet excitons EX in a portion increases.
The light-emitting layer EML may include a light-emitting portion EAA and a diffusion portion DAA. The light-emitting portion EAA may be convex in the direction of the first electrode EL1, and the diffusion portion DAA may be convex in the direction of the second electrode EL2. The light-emitting portion EAA may be a portion which overlaps the contact portion AA1 of the hole transport region HTR and through which the holes H are transmitted. The diffusion portion DAA may be a portion which overlaps the non-contact portion AA2 of the hole transport region HTR and through which the holes H are not transmitted.
The density of excitons EX in the light-emitting portion EAA may be greater than the density of excitons EX in the diffusion portion DAA. The excitons EX formed in the light-emitting portion EAA may be diffused into the diffusion portion DAA. Since some of the excitons EX generated in the light-emitting portion EAA are diffused into the diffusion portion DAA, the density of the excitons EX in the light-emitting portion EAA may be reduced. Accordingly, the triplet-triplet-annihilation phenomenon and the triplet-polaron-quenching phenomenon in the light-emitting portion EAA may be reduced. For example, in the light-emitting element ED according to an embodiment of the disclosure, since the light-emitting layer EML includes the light-emitting portion EAA and the diffusion portion DAA, the triplet-triplet-annihilation phenomenon and the triplet-polaron-quenching phenomenon may be reduced, and accordingly, there is an effect of reducing a roll-off phenomenon at a high luminance. The roll-off phenomenon refers to a phenomenon in which luminous efficiency decreases as the luminance of the light-emitting element ED increases. Hereinafter, in this specification, the meaning that the light-emitting element ED has improved roll-off characteristics may be the same as the meaning that the roll-off phenomenon is reduced.
The electron transport region ETR may have a single layer made of a single material, a single layer made of different materials, or a multi-layered structure having layers made of different materials.
For example, the electron transport region ETR may have a single-layered structure having an electron injection layer (not illustrated) or an electron transport layer (not illustrated), or a single-layered structure made of an electron injection material and an electron transport material. The electron transport region ETR may have a single-layered structure made of different materials, or a structure made of an electron transport layer (not illustrated)/an electron injection layer (not illustrated) or a hole blocking layer (not illustrated)/an electron transport layer (not illustrated)/an electron injection layer (not illustrated), which are sequentially stacked each other from the light-emitting layer EML, but the embodiment of the disclosure is not limited thereto. The thickness of the electron transport region ETR may be, for example, about 1000 Å to about 1500 Å.
The electron transport region ETR may be formed by using various methods such as a vacuum deposition method, a spin coating method, a casting method, a Langmuir-Blodgett method (LB), an inkjet printing method, a laser printing method, or a laser induced thermal imaging method (LITI).
In the electron transport region ETR, the first portions PA1 overlapping the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 and the second portions PA2 non-overlapping the sub-insulating layers S-IL1, S-IL2, S-IL3, and S-IL4 may have a height difference in the thickness direction. Accordingly, the surface of the electron transport region ETR may have a curved shape. The light-emitting element ED according to an embodiment of the disclosure may have improved luminous efficiency as surface plasmon-polaritons are reduced at the interface between the electron transport region ETR and the second electrode EL2.
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In the light-emitting element according to Embodiment 1 and in the light-emitting elements according to Comparative Embodiments 1 and 3, the degree of decrease in luminous efficiency at a low luminance is similar to the degree of decrease in luminous efficiency at a high luminance. Through this, it may be confirmed that, at a high luminance, the light-emitting element according to Embodiment 1 has roll-off characteristics similar in level to those of the light-emitting elements according to Comparative Embodiments 1 and 3.
It may be confirmed that the light-emitting element according to Embodiment 1 has higher external quantum efficiency than the light-emitting elements according to Comparative Embodiments 1 to 3.
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It may be confirmed that the light-emitting element according to Embodiment 2 has higher external quantum efficiency than that in Comparative Embodiments 1 and 4.
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The light-emitting element according to an embodiment of the disclosure includes an insulating layer including sub-insulating layers disposed between the light-emitting layer and the hole transport region and having a bar shape extending in the first direction so that a contact area between the hole transport region and the first electrode may be adjusted and a diffraction grating may be formed on the surface of the electron transport region disposed on the insulating layer. Accordingly, the light-emitting element according to an embodiment of the disclosure may have improved roll-off characteristics at a high luminance and excellent luminous efficiency. The display device including the light-emitting element according to an embodiment of the disclosure may have excellent luminous efficiency.
Since the light-emitting element according to an embodiment of the disclosure includes an insulating layer including bar-shaped sub-insulating layers disposed to be spaced apart from each other between the light-emitting layer and the hole transport region, the light-emitting element may have high luminous efficiency and a roll-off phenomenon may be suppressed at a high luminance.
Since the display device according to an embodiment of the disclosure includes a light-emitting element including an insulating layer including bar-shaped sub-insulating layers disposed to be spaced apart from each other between the light-emitting layer and the hole transport region, the display device may have high luminous efficiency and a roll-off phenomenon may be suppressed at a high luminance.
The above description is an example of technical features of the disclosure, and those skilled in the art to which the disclosure pertains will be able to make various modifications and variations. Thus, the embodiments of the disclosure described above may be implemented separately or in combination with each other.
Therefore, the embodiments disclosed in the disclosure are not intended to limit the technical spirit of the disclosure, but to describe the technical spirit of the disclosure, and the scope of the technical spirit of the disclosure is not limited by these embodiments. The protection scope of the disclosure should be interpreted by the following claims, and it should be interpreted that all technical spirits within the equivalent scope are included in the scope of the disclosure.
Number | Date | Country | Kind |
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10-2022-0055671 | May 2022 | KR | national |