Patent Grant
11692674
An embodiment of the present invention relates to a light-emitting element, a lighting device or a display device including the light-emitting element, and a manufacturing method of the lighting device or the display device.
As a light-emitting element, a light-emitting electrochemical cell (LEC) has been known. A light-emitting electrochemical cell has a structure in which a mixture of an emissive organic compound and an ionic liquid is sandwiched between a pair of electrodes. Electrons and holes are injected to the emissive organic compound by applying a direct current or an alternating current between the pair of electrodes, and light emission is obtained when the electrons and holes recombine (see Japanese Patent Applications No. 2011-103234 and 2000-67601.
An embodiment of the present invention is a light-emitting element. The light-emitting element includes a first electrode, a first light-emitting layer, an ionic-liquid layer, a second light-emitting layer, and a second electrode. The first light-emitting layer is located over the first electrode and includes a first emissive polymer and an ionic liquid. The ionic-liquid layer is located over the first light-emitting layer and includes an ionic liquid. The second light-emitting layer is located over the ionic-liquid layer and includes a second emissive polymer and an ionic liquid. The second electrode is located over the second light-emitting layer.
An embodiment of the present invention is a lighting device. The lighting device includes a first substrate, at least one first electrode, a first light-emitting layer, an ionic-liquid layer, a second light-emitting layer, at least one second electrode, a second substrate, and a sealing layer. The at least one first electrode is located over the first substrate. The first light-emitting layer is located over the at least one first electrode and includes a first emissive polymer and an ionic liquid. The ionic-liquid layer is located over the first light-emitting layer and includes an ionic liquid. The second light-emitting layer is located over the ionic-liquid layer and includes a second emissive polymer and an ionic liquid. The at least one second electrode is located over the second light-emitting layer, and the second substrate is located over the at least one second electrode. The sealing layer is located between the first substrate and the second substrate and surrounds the at least one first electrode.
An embodiment of the present invention is a method for manufacturing a lighting device. This method includes: forming a first electrode over a first substrate; forming a resin surrounding the first electrode over the first substrate; forming a first light-emitting layer including a first emissive polymer and an ionic liquid over the first electrode; forming a second electrode over a second substrate; forming a second light-emitting layer including a second emissive polymer and an ionic liquid over the second electrode; forming an ionic-liquid layer including an ionic liquid over the first light-emitting layer or the second light-emitting layer; bonding the first substrate and the second substrate so that the ionic-liquid layer is sandwiched by the first substrate and the second substrate; and curing the resin.
An embodiment of the present invention is a method for manufacturing a display device. This method includes: forming a pixel including a first electrode over a first substrate; forming a resin surrounding the pixel over the first substrate; forming a first light-emitting layer including a first emissive polymer and an ionic liquid over the first electrode; forming a second electrode over a second substrate; forming a second light-emitting layer including a second emissive polymer and an ionic liquid over the second electrode; forming an ionic-liquid layer including an ionic liquid over the first light-emitting layer or the second light-emitting layer; bonding the first substrate and the second substrate so that the ionic-liquid layer is sandwiched by the first substrate and the second substrate; and curing the resin.
An embodiment of the present invention is a display device. The display device includes a backlight unit and a liquid crystal module over the backlight unit. The backlight unit includes a first substrate, at least one first electrode, a first light-emitting layer, an ionic-liquid layer, a second light-emitting layer, a second electrode, a second substrate, and a sealing layer. The at least one first electrode is located over the first substrate. The first light-emitting layer is located over the at least one first electrode and includes a first emissive polymer and an ionic liquid. The ionic-liquid layer is located over the first light-emitting layer and includes an ionic liquid. The second light-emitting layer is located over the ionic-liquid layer and includes a second emissive polymer and an ionic liquid. The second electrode is located over the second light-emitting layer, and the second substrate is located over the second electrode. The sealing layer is located between the first substrate and the second substrate and surrounds the at least one first electrode.
An embodiment of the present invention is a display device. The display device includes a first substrate, at least one pixel, a second substrate, and a sealing layer. The at least one pixel is located over the first substrate, and the second substrate is located over the at least one pixel. The sealing layer is located between the first substrate and the second substrate and surrounds the pixel. The at least one pixel includes a first electrode, a first light-emitting layer, an ionic-liquid layer, a second light-emitting layer, and a second electrode. The first light-emitting layer is located over the first electrode and includes a first emissive polymer and an ionic liquid. The ionic-liquid layer is located over the first light-emitting layer and includes an ionic liquid. The second light-emitting layer is located over the ionic-liquid layer and includes a second emissive polymer and an ionic liquid. The second electrode is located over the second light-emitting layer.
Hereinafter, each embodiment of the present invention is explained with reference to the drawings. The invention can be implemented in a variety of different modes within its concept and should not be interpreted only within the disclosure of the embodiments exemplified below.
The drawings may be illustrated so that the width, thickness, shape, and the like are illustrated more schematically compared with those of the actual modes in order to provide a clearer explanation. However, they are only an example, and do not limit the interpretation of the invention. In the specification and the drawings, the same reference number is provided to an element that is the same as that which appears in preceding drawings, and a detailed explanation may be omitted as appropriate.
In the specification and the claims, unless specifically stated, when a state is expressed where a structure is arranged “over” another structure, such an expression includes both a case where the substrate is arranged immediately above the “other structure” so as to be in contact with the “other structure” and a case where the structure is arranged over the “other structure” with an additional structure therebetween.
In the present embodiment, a structure of a light-emitting element 100 according to an embodiment of the present invention is explained. The light-emitting element 100 is a so-called light-emitting electrochemical cell.
A schematic cross-sectional view of the light-emitting element 100 is shown in
The first electrode 110 and the second electrode 118 each have a function to inject carriers (electrons and holes) to the first light-emitting layer 112 and the second light-emitting layer 116, respectively, and may include a metal such as aluminum, copper, titanium, molybdenum, tungsten, tantrum, silver, and magnesium or an alloy including a metal selected therefrom, for example. Alternatively, the first electrode 110 and the second electrode 118 may each include a conductive oxide such as indium-tin oxide (ITO) and indium-zinc oxide (IZO). The materials included in the first electrode 110 and the second electrode 118 may be the same as or different from each other. For example, when the first electrode 110 and the second electrode 118 are formed with a conductive oxide capable of transmitting visible light or with a film of a metal or an alloy having a thickness allowing visible light to pass therethrough, by which the emission obtained from the first light-emitting layer 112 and/or the second light-emitting layer 116 can be extracted through both electrodes. Alternatively, one of the first electrode 110 and the second electrode 118 is configured to transmit visible light, while the other is configured to reflect visible light using a metal or an alloy, by which the emission can be selectively extracted from the former electrode.
The first light-emitting layer 112 and the second light-emitting layer 116 each include an emissive polymer and an ionic liquid. Thicknesses of the first light-emitting layer 112 and the second light-emitting layer 116 are each selected from a range equal to or more than 50 nm and equal to or less than 300 nm, equal to or more than 50 nm and equal to or less than 200 nm, or equal to or more than 100 nm and equal to or less than 150 nm.
As an emissive polymer, a polymer which emits visible light when relaxing from an excited state to a ground state can be used. As an example, a conjugated polymer having π-conjugated multiple bonds in a main chain is represented. As a conjugated polymer, a poly(arylene vinylene), a polyarylene, polyacetylene, polythiophene, polypyrrole, polypyridine, polypyrimidine, a poly(ethynylene vinylene), polyaniline, and their derivatives are represented, for example. Alternatively, a G-conjugated polymer such as a polysilane may be used. Alternatively, a vinyl polymer with a luminophore having a π-conjugated system in a side chain such as poly(vinyl carbazole) may be employed. The structures of the emissive polymer (first emissive polymer) included in the first light-emitting layer 112 and the emissive polymer (second emissive polymer) included in the second light-emitting layer 116 may be the same as or different from each other.
The ionic liquid is liquid at a normal temperature (e.g., 20° C.) and is an organic electrolyte which polarizes when a potential difference is provided between the first electrode 110 and the second electrode 118. For example, when the first electrode 110 is applied with a voltage positively larger than the voltage of the second electrode 118, cations and anions of the ionic liquid are localized at vicinities of the second electrode 118 and the first electrode 110, respectively, resulting in p-type and n-type electric double layers at vicinities of the first electrode 110 and the second electrode 118, respectively. An electric field generated by the electric double layers drastically reduces the resistance between the first electrode 110 and the second electrode 118, which facilitates the injection of the holes and electrons to the first light-emitting layer 112 and the second light-emitting layer 116, respectively.
As an ionic liquid, onium salts can be used. More specifically, an ammonium salt, an imidazolium salt, a sulfonium salt, a pyrazinium salt, a pyridinium salt, a pyrrolidinium salt, a phosphonium salt, or a piperidinium salt may be used. As a counter anion of these onium salts, tetrafluoroborate, acetate, trifluoroacetate, hexafluorophosphate, triflate, nitrate, perchlorate, bromide, chloride, bis(trifluoromethanesulfonyl)imidate, and the like are represented. The ionic liquid exists in a matrix of the emissive polymer in the first light-emitting layer 112 and the second light-emitting layer 116. That is, the emissive polymer exists in a state swelled with the ionic liquid.
In each of the first light-emitting layer 112 and the second light-emitting layer 116, a weight ratio of the emissive polymer and the ionic liquid (emissive polymer:ionic liquid) may be appropriately selected in a rage from 10:1 to 1:1, from 5:1 to 1:1, or from 4:1 to 2:1, for example. The ionic liquid (first ionic liquid) included in the first light-emitting layer 112 and the ionic liquid (second ionic liquid) included in the second light-emitting layer 116 may be the same as or different from each other.
The ionic-liquid layer 114 includes an ionic liquid. A thickness of the ionic-liquid layer 114 is appropriately selected from a range equal to or more than 10 nm and equal to or less than 50 nm, equal to or more than 10 nm and equal to or less than 30 nm, or equal to or more than 10 nm and equal to or less than 20 nm. The ionic liquid included in the ionic-liquid layer 114 may be the same as or different from the ionic liquid included in the first light-emitting layer 112 or the second light-emitting layer 116. In addition, two or more kinds of ionic liquids may be included in the ionic-liquid layer 114.
The substrate 102 supporting the light-emitting element 100 and the counter substrate 104 protecting the light-emitting element 100 may include glass, quartz, a metal such as aluminum, copper, stainless steel, or a polymer such as a polyimide, a polyamide, a polycarbonate, and an acrylic resin. The substrate 102 and the counter substrate 104 may be configured to have a sufficient strength to prevent deformation or may have flexibility so as to be readily deformed. In the latter case, a substrate including a polymer or a glass or metal substrate with a thickness adjusted to be readily deformed may be used. Materials included in the substrate 102 and the counter substrate 104 may be the same as or different from each other. For example, the substrate 102 and the counter substrate 104 may be configured so that one includes glass while the other includes a metal or a polymer. The light-emitting element 100 may also be configured so that the substrate 102 and the counter substrate 104 each include a metal and at least one of them has a thickness allowing visible light to pass therethrough.
The structure of the light-emitting element 100 is not limited to that described above. For example, a substrate including a metal such as aluminum, copper, and stainless steel may be used as one of the substrates (e.g., the counter substrate 104 in
Alternatively, one of the first light-emitting layer 112 and the second light-emitting layer 116 (the second light-emitting layer 116 in the example of
Generally, a light-emitting electrochemical cell is prepared by forming a single light-emitting layer including an emissive polymer and an ionic liquid over a first electrode, followed by forming a second electrode over the light-emitting layer using a sputtering method or an evaporation method. Therefore, the light-emitting layer is damaged during the formation of the second electrode, resulting in a decrease in flatness of the surface of the light-emitting layer. This damage is caused by the heat generated during the formation of the second electrode. The formation of depressions and projections on the surface of the light-emitting layer readily leads to defects such as a short circuit between the first electrode and the second electrode, formation of emission unevenness, and formation of a non-emissive region.
On the contrary, it is possible to effectively suppress the aforementioned defects in the light-emitting element 100. As demonstrated by a manufacturing method of the light-emitting element 100 described as a manufacturing method of a lighting device including the light-emitting element 100 in the Second Embodiment, the light-emitting element 100 having the aforementioned structures is manufactured by respectively forming the first light-emitting layer 112 and the second light-emitting layer 116 over the first electrode 110 and the second electrode 118 followed by overlapping and fixing the first electrode 110 and the second electrode 118 to each other so that the ionic-liquid layer 134 is sandwiched by the first electrode 110 and the second electrode 118. Therefore, the probability of generating damage to the first light-emitting layer 112 and the second light-emitting layer 116 can be remarkably reduced during the manufacture of the light-emitting element 100. Accordingly, a decrease in flatness caused by the formation of the second electrode 118 does not occur. In addition, the ionic-liquid layer 134 is capable of functioning as a buffer, which prevents the interelectrode short circuit even if depressions and projections are generated on the surfaces of the first light-emitting layer 112 and the second light-emitting layer 116 during the formation thereof. Hence, employment of the aforementioned structures suppresses the emission unevenness and enables the production of a highly reliable light-emitting element.
In the present embodiment, a structure of a lighting device 120 including the light-emitting element 100 and a manufacturing method thereof are explained. Since the light-emitting element 100 can be manufactured by a similar method to the lighting device 120, an explanation of a manufacturing method of the light-emitting element 100 is omitted. An explanation of the structures the same as or similar to those described in the First Embodiment may also be omitted.
A structure of the lighting device 120 is explained using schematic developed views in
The first electrode 130 is formed over the substrate 122. The at least one first electrode 130 may include a plurality of first electrodes 130. In this case, the plurality of first electrodes 130 may be arranged in a matrix form as shown in
The sealing layer 126 includes a cured resin. As the resin, a photosensitive or thermosetting epoxy resin, silicon resin, acrylic resin, and the like are represented, for example. The sealing layer 126 is disposed to surround the first electrode 130 and fixes the substrate 122 and the counter substrate 124. It is possible to prevent the entrance of impurities such as water and oxygen from the outside by providing the sealing layer 126.
A schematic view of a cross section along a chain line A-A′ in
A manufacturing method of the lighting device 120 shown in
First, the first electrode 130 is formed over the substrate 122 (
After that, the sealing layer 126 is formed over the substrate 122. Specifically, a photosensitive or thermoplastic resin 125 which is not yet cured is applied on the substrate 122 by utilizing an ink-jet method, a printing method, or the like. The resin 125 may be applied so that a closed shape is drawn over the substrate 122 (see
After that, the first light-emitting layer 132 is disposed over the first electrode 130. Specifically, the emissive polymer is dissolved in an organic solvent, and the ionic liquid is added thereto to prepare a mixture. This mixture may be homogeneous or inhomogeneous. The organic solvent may be selected from common organic solvents exemplified by aromatic hydrocarbons such as toluene, xylene, and tetralin, halogenated aromatic hydrocarbons such as chlorobenzene and dichlorobenzene, halogenated alkanes such as chloroform, dichloromethane, and 1,2-dichloroethane, and ethers such as tetrahydrofuran and dioxane. This mixture is applied in a region surrounded by the resin 125 by utilizing a spin-coating method, a spray method, an ink-jet method, a printing method, or the like. After that, the organic solvent is evaporated, leading to the formation of the first light-emitting layer 132 including the emissive polymer and the ionic liquid. Evaporation of the organic solvent may be conducted at a normal pressure or a reduced pressure. Moreover, the substrate 122 may be heated during evaporation of the organic solvent.
Similarly, the second electrode 138 is formed over the counter substrate 124. Similar to the formation of the first electrode 130, an undercoat may be formed over the counter substrate 124 prior to the formation of the second electrode 138. After that, the second light-emitting layer 136 is formed over the second electrode 138 (
Next, the ionic-liquid layer 134 is provided over the first light-emitting layer 132 (
After that, the substrate 122 and the counter substrate 124 are bonded to each other so that the first light-emitting layer 132 and the second light-emitting layer 136 are sandwiched by the substrate 122 and the counter substrate 124. Then, the resin 125 is photocured or thermally cured to form the sealing layer 126, by which the substrate 122 and the counter substrate 124 are simultaneously fixed to each other (
Alternatively, the substrate 122 and the counter substrate 124 may be fixed before forming the ionic-liquid layer 134. In this case, a pair of resins 125 is disposed over the substrate 122 or the counter substrate 124 so as to be spaced away from each other and then the substrate 122 and the counter substrate 124 are bonded before forming the ionic-liquid layer 134 as shown in
As described above, the lighting device 120 is manufactured by respectively forming the first light-emitting layer 132 and the second light-emitting layer 136 over the first electrode 130 and the second electrode 138, followed by bonding the substrate 122 and the counter substrate 124 to sandwich the ionic liquid 134 therebetween. Hence, it is possible to remarkably reduce the probability of damage generation to the first light-emitting layer 132 and the second light-emitting layer 136. In addition, since the ionic-liquid layer 134 is provided between the substrate 122 and the counter substrate 124, the entrance of impurities such as air and water between the substrate 122 and the counter substrate 124 (e.g., between the first light-emitting layer 132 and the second light-emitting layer 136) can be prevented, which contributes to an improvement of the reliability of the light-emitting element 100. Moreover, since the ODF method commonly applied in the manufacturing processes of liquid crystal display devices can be employed when the ionic-liquid layer 134 is formed, the lighting device 120 can be manufactured by utilizing existing manufacturing apparatus for semiconductor devices. Hence, implementation of the present embodiment enables the production of the highly reliable lighting device 120 at a low cost.
3-1. Modified Example 1
The structure of the lighting device 120 according to the present embodiment is not limited to that described above. For example, as shown in
When the reflection structure 128 is provided, the sealing layer 126 may be disposed over the reflection structure 128 as shown in
3-2. Modified Example 2
As demonstrated in
The use of a polymer for the substrate 122 and the counter substrate 124 enables the substrate 122 and the counter substrate 124 to be fixed to each other even though the sealing layer 126 is not used, which enables the production of the flexible lighting device 120 having an edge portion composed of a bent surface. Specifically, the first electrode 130 and the first light-emitting layer 132 are disposed over the flexible substrate 122 provided over a supporting substrate 123 such as a glass substrate, and then the ionic-liquid layer 134 is spread over the first light-emitting layer 132 as shown in
3-3. Modified Example 3
The lighting device 120 may have a linear shape. A perspective view of the lighting device 120 having a linear shape is shown in
As shown in
The lighting device 120 having such a linear shape can be manufactured by the following method. First, the outer surface of the first linear electrode 130 is coated with the first light-emitting layer 132 as shown in
The flexible counter substrate 124 is provided over a supporting substrate, which is not illustrated, over which the second electrode 138, the resin 125 disposed to surround the second electrode 138, and the second light-emitting layer 136 over the second electrode 138 are formed (
The first electrode 130 is rotated once, and the resin 125 is cured in a state where the outer peripheral surface of the first electrode 130 is entirely wound by the counter substrate 124, the second electrode 138, the second light-emitting layer 136, and the ionic-liquid layer 134 to form the sealing layer 126. With this process, the first light-emitting layer 132, the ionic-liquid layer 134, the second light-emitting layer 136, and the second electrode 138 are fixed to the outer peripheral surface of the first electrode 130. After that, the openings 129 and 131 are formed, thereby resulting in the lighting device 120 with a linear shape.
The use of a flexible metal wire as the second electrode 138 also enables the formation of the arbitrarily deformable lighting device 120 having a linear shape.
In the present embodiment, a display device 140 in which the lighting device 120 having the light-emitting element 100 is used as a backlight unit is explained. An explanation of the structures the same as or similar to those described in the First and Second Embodiments may be omitted.
A developed view of the display device 140 is shown in
A part of a cross section along a chain line D-D′ in
The optical sheet 142 is arranged over the lighting device 120. The structure of the optical sheet 142 may be arbitrarily determined, and a stack of a prism sheet 144 and a light-diffusing film 146 may be used as the optical sheet 142, for example. The prism sheet 144 is provided in order to collect and radiate the light emitted from the lighting device 120 toward the front direction of the liquid crystal module 150, and a plurality of prism-shaped depressions and projections is arranged in a stripe form on a surface of the prism sheet 144. The light-diffusing film 146 is a component to uniform the light and may include light-diffusing particles and a polymer matrix fixing the particles. Although not illustrated, the optical sheet 142 may be fixed to the lighting device 120 using an adhesive.
There is also no limitation to the structure of the liquid crystal module 150. For example, the liquid crystal module 150 has the array substrate 156 over which transistors 160 are formed through an undercoat 158. The transistor is structured by a semiconductor film 162, a gate insulating film 164, a gate electrode 166, an interlayer film 172, a source electrode 168, a drain electrode 170, and the like, for example. Although not illustrated, a plurality of transistors and capacity elements may be arranged in each pixel 152 of the array substrate 156.
The transistors 160 are covered with a leveling film 174 and are electrically connected to pixel electrodes 176 provided over the leveling film 174. The pixel electrode 176 is arranged in each pixel 152. An orientation film 178 is formed over the pixel electrodes 176. A counter substrate 190 is disposed over the array substrate 156 through a liquid crystal layer 180. The structure of the counter substrate 190 may also be arbitrarily selected, and color filters 188, a black matrix 186, and an overcoat 184 covering these components may be formed over the counter substrate 190 as shown in
In the example demonstrated in
The structure of the touch sensor 200 may also be arbitrarily determined, and an electrostatic capacitive type touch sensor may be employed. In this case, a first interlayer film 202 is formed over the liquid crystal module 150, over which a plurality of Tx electrodes 204 and a plurality of Rx electrodes 206 arranged to intersect each other are formed. Although a detailed explanation is omitted, the Tx electrodes and the Rx electrodes are each structured by a plurality of electrodes and are formed in the same plane (that is, over the first interlayer film 202). A second interlayer film 208 is disposed over the Tx electrodes and the Rx electrodes, and the adjacent electrodes included in each Tx electrode are electrically connected with a bridge electrode 210. A protection substrate 212 for protecting the touch sensor 200 is provided over the bridge electrode 210 through a third interlayer film 214.
As described in the Second Embodiment, the lighting device 120 according to an embodiment of the present invention has high reliability and can be manufactured at a low cost due to the structure and the manufacturing method thereof. Hence, implementation of the present embodiment allows the production of a highly reliable display device at a low cost.
In the present embodiment, a structure of a self-emission type display device 220 including the light-emitting element 100 is explained. An explanation of the structures the same as or similar to those described in the First to Third Embodiments may be omitted.
A developed view of the display device 220 is depicted in
A part of a cross section along a chain line E-E′ in
The transistors 242 are covered by a leveling film 256 and are electrically connected to the first electrodes 230 located over the leveling film 256. The first light-emitting layer 232, the ionic-liquid layer 234, the second light-emitting layer 236, the second electrode 238, and the counter substrate 228 are disposed over the first electrodes 230. A black matrix 260 and an overcoat 262 covering the black matrix 260 may be formed over the counter substrate 228. In this case, the second electrode 238 is formed over the counter substrate 228 through the overcoat 262. Although not illustrated, an undercoat may be interposed between the counter substrate 228 and the black matrix 260 or between the counter substrate 228 and the overcoat 262.
Here, although the first light-emitting layer 232 may be formed as a single layer shared by all of the pixels 224, the first light-emitting layer 232 is preferred to be formed in every pixel 224 so that the structures of the emissive polymers included are different between the pixels 224. In a similar way, although the second light-emitting layer 236 may be formed as a single layer shared by all of the pixels 224, the second light-emitting layer 236 is preferred to be formed in every pixel 224 so that the structures of the emissive polymers included are different between the pixels 224. In these cases, the first light-emitting layer 232 and the second light-emitting layer 236 are formed in every pixel 224 utilizing an ink-jet method or a printing method. Hence, the first light-emitting layer 232 may be separated between the adjacent pixels 224, and the second second-emitting layer 236 may also be separated between the adjacent pixels 224. Full color display can be realized by structuring the first light-emitting layer 232 and the second second-emitting layer 236 so that continuously arranged three pixels 224 or arbitrarily selected three pixels 224 respectively provide red, green, and blue emissions.
Although not illustrated, the display device 220 can also be manufactured by a similar method to that of the lighting device 120 described in the Second Embodiment. That is, a resin functioning as a raw material of the sealing layer 226 is formed to surround the plurality of first electrodes 230 arranged over the array substrate 222, and the first light-emitting layer 232 is further formed over the first electrodes 230 by utilizing an ink-jet method, a printing method, or the like. The second light-emitting layer 236 is also prepared over the second electrode 238 arranged over the counter substrate 228. After that, the ionic liquid is dropped in the region surrounded by the resin to form the ionic-liquid layer 234 over the first light-emitting layer 232. Then, the array substrate 222 and the counter substrate 228 are bonded to each other to sandwich the first light-emitting layer 232, the ionic-liquid layer 234, and the second light-emitting layer 236, and the resin is cured to form the sealing layer 226 and simultaneously fix the array substrate 222 and the counter substrate 228. Note that the resin may be formed over the counter substrate 228. In this case, the ionic-liquid layer 134 is applied to or dropped on the second light-emitting layer 236.
The aforementioned manufacturing method is the same as the manufacturing method of the lighting device 120. Therefore, implementation of the present embodiment enables the low-cost production of the display device 220 in which a highly reliable light-emitting element is arranged in each pixel 224.
In the present embodiment, a light-emitting element 106 different in structure from the light-emitting element 100 described in the First Embodiment is explained. An explanation of the structures the same as or similar to those described in the First to Fourth Embodiments may be omitted. The light-emitting element 106 is different from the light-emitting element 100 in that a plurality of conductive particles 113 is included in at least one of the ionic-liquid layer 114, the first light-emitting layer 112, and the second light-emitting layer 116. The conductive particles 113 may include a metal such as gold, silver, copper, and nickel or an alloy including a metal selected therefrom.
For example, the light-emitting element 106 includes the conductive particles 113 in the ionic-liquid layer 114 as shown in
The ionic-liquid layer 114 including the conductive particles 113 may be formed by adding the conductive particles 113 to the ionic liquid to be dispersed, followed by dropping or applying the resulting dispersion over the first light-emitting layer 112 or the second light-emitting layer 116 with an ODF method, a spray method, an ink-jet method, a printing method, a spin-coating method, or the like.
The conductive particles 113 may be uniformly dispersed in the ionic-liquid crystal layer 134 but may be non-uniformly dispersed. For example, the conductive particles 113 may be localized on one of the sides of the first light-emitting layer 112 and the second light-emitting layer 116 as shown in
As shown in
Similar to the ionic-liquid layer 234 including the conductive particles 113, the first light-emitting layer 112 and the second light-emitting layer 116 including the conductive particles 113 may be formed by dispersing the conductive particles 113 into a mixture containing the emissive polymer, an organic solvent, and the ionic liquid and applying the resulting dispersion onto the first electrode 110 or the second electrode 118 with a spin-coating method, a spray method. an ink-jet method, a printing method, or the like, followed by evaporating the organic solvent.
Alternatively, the conductive particles 113 may be arranged over the first electrode 110 or the second electrode 118 before forming the first light-emitting layer 112 or the second light-emitting layer 116. Specifically, a suspension in which the conductive particles 113 are dispersed in an organic solvent or water is used, and the dispersion is applied over the first electrode 110 or the second electrode 118 using a spin-coating method, a spray method, an ink-jet method, a printing method, or the like. After that, the organic solvent or water is evaporated, thereby arranging the conductive particles 113 over the first electrode 110 or the second electrode 118. After that, a mixture containing the emissive polymer, the organic solvent, and the ionic liquid is dropped or applied to provide the first light-emitting layer 112 or the second light-emitting layer 116.
Similar to the ionic-liquid layer 234, the conductive particles 113 may be uniformly or non-uniformly dispersed in the first light-emitting layer 112 or the second light-emitting layer 116. For example, the conductive particles 113 may be localized on the side of the first electrode 110 in the first light-emitting layer 112 and may be localized on the side of the second electrode 118 in the second light-emitting layer 116 as shown in
The aforementioned modes described as the embodiments of the present invention can be implemented by appropriately combining with each other as long as no contradiction is caused. Furthermore, any mode which is realized by persons ordinarily skilled in the art through the appropriate addition, deletion, or design change of elements or through the addition, deletion, or condition change of a process is included in the scope of the present invention as long as they possess the concept of the present invention.
It is understood that another effect different from that provided by each of the aforementioned embodiments is achieved by the present invention if the effect is obvious from the description in the specification or readily conceived by persons ordinarily skilled in the art.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2020-055546 | Mar 2020 | JP | national |
This application is a Continuation of International Patent Application No. PCT/JP2021/007954, filed on Mar. 2, 2021, which claims priority to Japanese Patent Application No. 2020-055546, filed on Mar. 26, 2020, the entire contents of which are incorporated herein by reference.
| Number | Date | Country |
|---|---|---|
| 110444674 | Nov 2019 | CN |
| 2000-067601 | Mar 2000 | JP |
| 2011-103234 | May 2011 | JP |
| Entry |
|---|
| English Machine Translation of Meng, CN110444674 (Year: 2023). |
| International Search Report dated Apr. 27, 2021 for the corresponding PCT Application No. PCT/JP2021/007954, with English translation. |
| Number | Date | Country | |
|---|---|---|---|
| 20230019409 A1 | Jan 2023 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2021/007954 | Mar 2021 | US |
| Child | 17949282 | US |
