At least one embodiment of the present disclosure relates to a light emitting substrate and a manufacturing method thereof, and an electronic device.
Light emitting substrate having Organic Light-Emitting Diode (OLED) has advantages of fast response, high brightness, bright color, light weight, low energy consumption and so on, and thus it has been widely used in display devices and light emitting devices. The light emitting substrate having the organic light-emitting diode usually includes a light emitting structure, and a cathode and an anode that are electrically connected to the light emitting structure. The cathode and the anode provide electrical signals to the light emitting structure to control light emitting conditions of the light emitting structure, so that electrical properties of the cathode and the anode affect light emitting quality of the light emitting structure.
At least one embodiment of the present disclosure provides a manufacturing method of a light emitting substrate, and the method comprises: forming a pixel definition layer by a patterning process using a first mask, in which the pixel definition layer includes an opening and a partition portion defining the opening; forming a first electrode, in which the first electrode comprises a first portion covering at least a part of the partition portion and comprises a second portion in the opening; and forming an auxiliary electrode by a patterning process using the first mask, in which the auxiliary electrode is electrically connected with the first electrode, and the auxiliary electrode is on the partition portion.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, a surface, facing the first electrode, of the auxiliary electrode is in direct contact with a surface, facing the auxiliary electrode, of the first electrode.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the auxiliary electrode is formed after forming the first electrode, and the auxiliary electrode is on a side, away from the partition portion of the pixel definition layer, of the first electrode.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the forming the auxiliary electrode comprises: forming a sacrifice layer on a side, away from the pixel definition layer, of the first electrode by a patterning process using the first mask, in which the sacrifice layer exposes the first portion of the first electrode and covers the second portion of the first electrode; forming a conductive material layer, in which the conductive material layer includes a first portion and a second portion that are disconnected from each other; a first portion of the conductive material layer covers the first portion of the first electrode and is in direct contact with the first portion of the first electrode, a second portion of the conductive material layer is on a side, away from the second portion of the first electrode, of the sacrifice layer; and simultaneously removing the sacrifice layer and the second portion of the conductive material layer so that the first portion of the conductive material layer remains as the auxiliary electrode.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the sacrifice layer is a strippable layer, and the manufacturing method of the light emitting substrate further comprises: stripping the sacrifice layer to simultaneously remove the second portion of the conductive material layer which is on the sacrifice layer.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the forming the sacrifice layer comprises: forming a sacrifice material layer covering the first electrode; and performing a photolithography process on the sacrifice material layer by using the first mask to form the sacrifice layer, in which a material of the sacrifice layer comprises a first photoresist, the pixel definition layer is formed by a photolithographic process using a second photoresist and the first mask, and photosensitivity of the first photoresist is opposite to that of the second photoresist.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the forming the sacrifice layer comprises: forming a sacrifice material layer covering the first electrode, in which the sacrifice material layer is a strippable layer; forming a first photoresist layer on the sacrifice material layer; and performing a photolithography process on the sacrifice material layer by using the first mask and the first photoresist layer to form the sacrifice layer. A material of the first photoresist layer comprises a first photoresist, the pixel definition layer is formed by a photolithographic process using a second photoresist and the first mask, and photosensitivity of the first photoresist is opposite to that of the second photoresist.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the first photoresist is negative photoresist and the second photoresist is positive photoresist; or, the first photoresist is positive photoresist and the second photoresist is negative photoresist.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the auxiliary electrode is formed before forming the first electrode, the auxiliary electrode is on a side, close to the partition portion of the pixel definition layer, of the first electrode.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the forming the sacrifice layer comprises: forming a conductive material layer covering the pixel definition layer; and performing a photolithography process on the conductive material layer using the first mask and a first photoresist to form the auxiliary electrode; and the pixel definition layer is formed by a photolithography process using the first mask and a second photoresist, and photosensitivity of the first photoresist is same as that of the second photoresist.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, the conductive material layer is formed by an evaporation method.
For example, in the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure, a material of the first electrode is a metal material; a thickness of the first electrode is not more than 20 nm in a direction from a surface, away from the pixel definition layer, of the first electrode to a surface, close to the pixel definition layer, of the first electrode.
For example, the manufacturing method of the light emitting substrate provided by at least one embodiment of the present disclosure further comprises: forming a second electrode and a light emitting layer in the opening of the pixel definition layer, in which the second electrode is opposite to the first electrode, and the light emitting layer is between the first electrode and the second electrode, and light emitted by the light emitting layer exits through the first electrode.
At least one embodiment of the present disclosure further provides a light emitting substrate comprising: a pixel definition layer, a first electrode and an auxiliary electrode. The pixel definition layer comprises an opening and a partition portion; the first electrode comprises a first portion and a second portion; the first portion is on the partition portion and covers at least a part of the partition portion, and the second portion is in the opening; the auxiliary electrode is in contact with the first electrode in a surface-to-surface manner to be electrically connected with the first electrode, and is on the partition portion; the auxiliary electrode and the pixel definition layer have a substantially same pattern.
For example, in the light emitting substrate provided by at least one embodiment of the present disclosure, the auxiliary electrode is on a side, away from the partition portion of the pixel definition layer, of the first electrode.
For example, in the light emitting substrate provided by at least one embodiment of the present disclosure, the auxiliary electrode is on a side, close to the partition portion of the pixel definition layer, of the first electrode.
For example, in the light emitting substrate provided by at least one embodiment of the present disclosure, a material of the first electrode is a metal material; and a thickness of the first electrode is not more than 20 nm in a direction from a surface, away from the pixel definition layer, of the first electrode to a surface, close to the pixel definition layer, of the first electrode.
For example, the light emitting substrate provided by at least one embodiment of the present disclosure further comprises: a second electrode and a light emitting layer which are in the opening of the pixel definition layer; the second electrode is opposite to the first electrode, and the light emitting layer is between the first electrode and the second electrode; and light emitted by the light emitting layer exits through the first electrode.
At least one embodiment of the present disclosure further provides an electronic device comprising any one of the light emitting substrates provided by the embodiments of the present disclosure.
In order to clearly illustrate the technical solution of the embodiments of the disclosure, the drawings of the embodiments will be briefly described in the following; it is obvious that the described drawings are only related to some embodiments of the disclosure and thus are not limitative of the disclosure.
In order to make objects, technical details and advantages of the embodiments of the disclosure apparent, the technical solutions of the embodiments will be described in a clearly and fully understandable way in connection with the drawings related to the embodiments of the disclosure. Apparently, the described embodiments are just a part but not all of the embodiments of the disclosure. Based on the described embodiments herein, those skilled in the art can obtain other embodiment (s), without any inventive work, which should be within the scope of the disclosure.
Unless otherwise defined, all the technical and scientific terms used herein have the same meanings as commonly understood by one of ordinary skill in the art to which the present disclosure belongs. The terms “first,” “second,” etc., which are used in the description and the claims of the present application for disclosure, are not intended to indicate any sequence, amount or importance, but distinguish various components. Also, the terms “comprise,” “comprising,” “include,” “including,” etc., are intended to specify that the elements or the objects stated before these terms encompass the elements or the objects and equivalents thereof listed after these terms, but do not preclude the other elements or objects. “In,” “out,” “on,” “under” and the like are only used to indicate relative position relationship, and when the position of the object which is described is changed, the relative position relationship may be changed accordingly.
The figures in embodiments of the present disclosure are not drawn according to actual proportions or scales. An amount and specific size of each structure may be determined according to actual acquirements. The figures of the embodiments of the present disclosure are only schematic views.
It should be noted that the feature “strippable layer” refers to a structural layer that can be removed by a stripping process or lift-off process in the present disclosure.
It should be noted that, in the present disclosure, the feature “a surface, facing the first electrode, of the auxiliary electrode is in direct contact with a surface, facing the auxiliary electrode, of the first electrode” refers to that the entire surface, facing the first electrode, of the auxiliary electrode is in contact with the surface of the first electrode, that is, in the direction perpendicular to the substrate, no other intermediate layer or intermediate structure exists between any position of the entire surface, facing the first electrode, of the auxiliary electrode and the surface, facing the auxiliary electrode, of the first electrode.
In a manufacturing method of an organic light-emitting diode (OLED) substrate, the auxiliary cathode is usually be directly deposited by using a vapor deposition mask. However, on one hand, this solution needs to add the vapor deposition mask (e.g., fine metal mask (FMM)), and a metal material that to be deposited may adhere to the vapor deposition mask and thus the vapor deposition mask is difficult to be cleaned, resulting in a limited lifetime of the vapor deposition mask, thus increasing a cost of mask; on the other hand, this solution is suitable for manufacturing specific small-sized or medium-sized substrates, and is not easy to realize or has a high cost for large-sized substrates. Alternatively, in some manufacturing methods of the organic light-emitting diode substrate, the auxiliary cathode is fabricated on an encapsulation plate, and then the auxiliary cathode is electrically connected with the cathode when the encapsulation plate is bonded with the organic light-emitting diode substrate; this method requires a separate mask for forming the auxiliary cathode and is not suitable for thin film encapsulation. Or, in some manufacturing methods of the organic light-emitting diode substrate, an insulation layer is firstly manufactured on the transparent cathode and a via hole passing through the insulation layer is manufactured, the auxiliary cathode is manufactured on the insulating layer, and the auxiliary cathode is connected with the transparent cathode through the via hole; this solution requires additional steps for manufacturing the insulation layer and the via hole, and the mask for forming the via hole and the mask for manufacturing the auxiliary cathode are separately manufactured, thus greatly increasing a manufacturing cost.
At least one embodiment of the present disclosure provides a manufacturing method of a light emitting substrate, and the method comprises: forming a pixel definition layer by a patterning process using a first mask, in which the pixel definition layer includes an opening and a partition portion defining the opening; forming a first electrode, in which the first electrode comprises a first portion covering at least a part of the partition portion and comprises a second portion in the opening; and forming an auxiliary electrode by a patterning process using the first mask, in which the auxiliary electrode is electrically connected with the first electrode, and the auxiliary electrode is on the partition portion.
In the manufacturing method of the light emitting substrate provided by the embodiments of the present disclosure, the pixel definition layer and the auxiliary electrode are formed by using a same mask (i.e. the first mask), so that the mask for forming the auxiliary electrode does not need to be separately prepared, a process of forming the auxiliary electrode is simplified, and a cost for manufacturing the mask is saved. Providing the auxiliary electrode is equivalent to adding a circuit connected in parallel with the first electrode, so that an overall resistance of the first electrode structure (referring to an overall resistance of the electrode structure constituted by the first electrode and the auxiliary electrode) is reduced, a signal transmission speed is improved, and Joule heat is reduced, thereby being beneficial to prolonging a service life of the light emitting substrate and reducing energy consumption. For example, especially in a case where a thickness of the first electrode is small (for example, in a case where the first electrode is made of a metal material and is transparent to light, or in a case where the thickness of the first electrode is reduced in order to obtain an ultra-thin light emitting substrate, etc.), resulting in that a resistance of the first electrode is large and a phenomenon of excessive large resistance at some positions because of uneven thickness of the first electrode is easy to exist, this auxiliary cathode avoids or reduces this phenomenon. In addition, forming the auxiliary cathode on the partition portion (non-opening region) of the pixel definition layer improves performances of the first electrode without affecting the light transmittance ratio. The manufacturing method of the light emitting substrate provided by at least one embodiment of the disclosure is suitable for manufacturing light emitting substrates of various sizes, and a size range of the substrate to which the manufacturing method can be applicable is wide.
Illustratively,
For example, the manufacturing method of the light emitting substrate includes forming the auxiliary electrode using a first photoresist and the first mask. Before forming the auxiliary electrode, the manufacturing method of the light emitting substrate further includes forming the pixel definition layer by a patterning process using the first mask, for example, forming the pixel definition layer by the photolithography process using a second photoresist and the first mask. As illustrated in
As illustrated in
For example, in a case illustrated in
The manufacturing method of the light emitting substrate further comprises: forming the auxiliary electrode by a patterning process using the first mask, in which the auxiliary electrode is electrically connected with the first electrode, and the auxiliary electrode is on the partition portion.
For example, in one embodiment, the auxiliary electrode is formed after forming the first electrode, and the auxiliary electrode is on a side, away from the partition portion of the pixel definition layer, of the first electrode.
Illustratively, as illustrated in
Then, a photolithography process is performed on the sacrifice material layer 60 using the first mask 9 to form a sacrifice layer. For example, the sacrifice material layer 60 is exposed and developed using the first mask 9 to form the sacrifice layer 6 as illustrated in
The photoresist layer is capable of being stripped, a material of the sacrifice material layer 60 for example is the first photoresist, and thus the sacrifice material layer 60 is a strippable layer, i.e., the sacrifice layer is a strippable layer. The strippable layer can be removed by a stripping process.
As illustrated in
As illustrated in
As illustrated in
It should be noted that, in the embodiments of the present disclosure, the term “the entire surface 73 is in direct contact with the surface 51” refers to that no other layer or structure exists between any position of an entirety of the surface 73 and the surface 51.
It should be noted that the auxiliary electrode 7 and the pixel definition layer 2 have a substantially same pattern. For example, in the process of exposing the pixel definition material layer 20 and the process of exposing the sacrifice material layer 60, by using a sufficiently strong illumination intensity, both a cross-sectional shape of the partition portion 22 of the formed pixel definition layer in the direction perpendicular to the base substrate 1 and a cross-sectional shape of the sacrifice layer 6 in the direction perpendicular to the base substrate 1 are rectangular or approximately rectangular (as illustrated in
For example, in the case where the first photoresist is negative photoresist and the second photoresist is positive photoresist, the cross-sectional shape of the formed sacrifice layer 6 in the direction perpendicular to the base substrate 1 is trapezoidal, and a length of an upper bottom, away from the base substrate 1, of the trapezoidal pattern is larger than a length of a lower bottom, close to the base substrate 1, of the trapezoidal pattern (not illustrated in the figure), thus a width, in a certain direction in a plane where the auxiliary electrode is located, of the auxiliary electrode formed subsequently is less than a width in the certain direction of the pixel definition layer 2. For another example, in the case where the first photoresist is positive photoresist and the second photoresist is negative photoresist, the cross-sectional shape of the formed sacrifice layer 6 in the direction perpendicular to the base substrate 1 is trapezoidal, and the length of the upper bottom, away from the base substrate 1, of the trapezoidal pattern is smaller than the length of the lower bottom, close to the base substrate 1, of the trapezoidal pattern (not illustrated in the figure), thus the width, in a certain direction in the plane where the auxiliary electrode is located, of the auxiliary electrode formed subsequently is larger than the width in the certain direction of the pixel definition layer 2. It is within the scope protected by this disclosure that the auxiliary electrode 7 and the pixel definition layer 2 have the substantially same pattern in consideration of dimensional errors in the process.
As illustrated in
As illustrated in
For the embodiment illustrated in
Illustratively, as illustrated in
Then, as illustrated in
As illustrated in
For the embodiment illustrated in
At least one embodiment of the disclosure further provides a light emitting substrate, and the light emitting substrate comprising: a pixel definition layer, a first electrode and an auxiliary electrode; the pixel definition layer comprises an opening and a partition portion; the first electrode comprises a first portion and a second portion, the first portion is on the partition portion and covers at least a part of the partition portion, and the second portion is in the opening; the auxiliary electrode is in contact with the first electrode in a surface-to-surface manner to be electrically connected with the first electrode and is on the partition portion; the auxiliary electrode and the pixel definition layer have a substantially same pattern.
As illustrated in
It should be noted that the term “the auxiliary electrode 7 is in contact with the first electrode 5 in the surface-to-surface manner” refers to that a surface 73, facing the first electrode 5, of the auxiliary electrode 7 is in contact with a surface 51, facing the auxiliary electrode 7, of the first electrode 5, that is, there is no other layer or structure between any position of the entire surface 73 and the surface 51, so as to reduce the contact resistance between the auxiliary electrode 7 and the first electrode 5, and simplify the manufacturing process, such as omitting a process of manufacturing a via hole connecting the auxiliary electrode 7 and the first electrode 5. The auxiliary electrode 7 and the pixel definition layer 2 have a substantially same pattern, i.e., the auxiliary cathode 7 is located in a non-opening region of the pixel definition layer, which improves performances of the first electrode without affecting a light transmittance ratio, and enables the pixel definition layer and the auxiliary cathode to be formed using the same mask in the process of manufacturing the light emitting substrate 10, thereby saving cost, simplifying the process, and widening a size range of the substrate to which the manufacturing method can be applicable.
For example, the auxiliary electrode 7 is on a side, away from the partition portion 22 of the pixel definition layer, of the first electrode 5.
For example, the light emitting substrate 10 further includes a second electrode 4 and a light emitting layer 3 that are in the opening 21 of the pixel definition layer 2. The light emitting layer 3 is between the first electrode 5 and the second electrode 4, and the second electrode 4 is opposite to the first electrode 5. For example, a material of the first electrode 5 is a metal material. The metal material is, for example, a metal with a small work function, such as magnesium or silver, to reduce damage to the light emitting layer 3 in the process of forming the first electrode 5 by an evaporation method. For example, a thickness of the first electrode 5 in a direction perpendicular to the base substrate 1 is not more than 20 nm, so that the first electrode 5 is transparent to light, light emitted by the light emitting layer 3 exits through the first electrode 5, and the first electrode 4 is opaque. That is, the light emitting substrate is of a top emission type. For example, the light emitting layer 3 includes a light emitting function layer, and the first electrode 5 and the second electrode 4 are respectively electrically connected with the light emitting function layer to control operation states of the light emitting function layer.
In this embodiment, features of the light emitting substrate that are not mentioned, such as a material of the auxiliary cathode 7, a material and a thickness of the first electrode 5, and the corresponding technical effects are the same as those in the above embodiment of the manufacturing method of the light emitting substrate, please refer to the previous descriptions and are not repeated here.
At least one embodiment of the present disclosure further provides an electronic device including any one of the light emitting substrates provided by the embodiments of the present disclosure. Illustratively,
What have been described above are only specific implementations of the present disclosure, the protection scope of the present disclosure is not limited thereto. The protection scope of the present disclosure should be defined by the claims.
Filing Document | Filing Date | Country | Kind |
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PCT/CN2019/080599 | 3/29/2019 | WO | 00 |