The invention relates to the field of stain removal.
The invention may for example be used in the field of fabric care, such as garment care.
Oxidizing agents are widely used in area of cleaning, disinfecting and bleaching. Oxidizing agents like hydrogen peroxide having formula H2O2, carbamide, sodium percarbonate, sodium perborate are also very widely added in laundry powders and detergents to remove stains on garment.
The chemical reacting mechanism of stain removing by oxidization mechanism is illustrated by
The stain comprises colored molecule (chromophore) defining a first product P1.
The colored molecule is then oxidized by an oxidization agent or bleach, resulting in an intermediate product P2.
Water is then applied to the intermediate product, resulting in a colorless molecule defining a final product P3.
As the H2O2 concentration in commercial stain removing products is low, the bleaching reaction is not very effective and requires comparatively longer time to diminish the stain color, normally 5 min to 30 min treatment time is needed depending on the stain age and stain type.
Reaction can be accelerated by using high temperature (e.g. 70 degree C.) to reduce the treatment time significantly. But there is a risk of user's skin being injured if apply the high temperature stain removal system without taking off the stained cloth.
It is an object of the invention to propose a stain removal system that avoids or mitigates above-mentioned problems.
The invention is defined by the independent claims. The dependent claims define advantageous embodiments.
To this end, the stain removal system for treating a stained area on a cloth comprises:
Light acceleration is a good substitution of heat. A stain removal system with light source integration allows fast stain removing and user can use it to treat a stain on clothes while they are wearing it.
Small and light weight of the light source also enables designing a compact, portable stain removal system that is convenient for user to handle and bring along.
The invention also relates to a cartridge forming a container for containing a bleach chemical. The cartridge is adapted to cooperate with a stain removal system as described above. The cartridge may for example be adapted to couple to the stain removal system via a coupling valve arrangement. This may allow firm holding of the cartridge and also prevent any leakage of the bleach chemical. The coupling valve arrangement may be a part of the cartridge, or may be a part of the system to which the cartridge is adapted to cooperate.
The invention also relates to a method of treating a stained area on a cloth by a stain removal system as described above.
Detailed explanations and other aspects of the invention will be given below.
Particular aspects of the invention will now be explained with reference to the embodiments described hereinafter and considered in connection with the accompanying drawings, in which identical parts or sub-steps are designated in the same manner:
In the following, a bleach chemical refers to a group of chemicals that work through oxidation mechanisms to remove a stain. Including liquid type of bleach chemical like hydrogen peroxide and peroxy acids and solid type of bleach chemical like sodium percarbonate, sodium perborate, carbamide peroxide, etc.
The invention is based on the principle that light activation of hydrogen peroxide H2O2 helps peroxide decompose faster to form free radicals that react with organic molecules (stain colors).
Below is the light activated free radical generation:
H2O2+hv→2 OH. (1)
OH.+H2O2→HO2.+H2O (2)
HO2.+H2O2→OH.+H2O+O2 (3)
2 HO2.→H2O2+O2 (4)
In above chemical reactions, “hv” corresponds to the chemical equation for photon.
Selection of the light source, wavelength, intensity and exposure time affect the bleaching efficiency.
Light source can for example correspond to UV light which has a high photon energy. Blue light can also be considered. Although light source of longer wavelengths has lower photon energy which may result in less efficient photo catalysis, more heat generated by the longer wavelength light can still increase the oxidizing reaction.
Typical spectrum for blue light is between 492 nm to 455 nm.
Preferably, to ensure an efficient stain removal, the power of the light source is at least 500 mW.
In this invention, blue light is applied as an example but other light sources like IR, white light, green light etc. should not be excluded from the same principle.
The stain removal system comprises:
The container 104 may for example correspond to a bottle or recipient, as illustrated. For example, the bottle can be detachable from the device 101.
The system 105 for carrying the bleach chemical may correspond to the spout of the bottle, for example forming an elongated outlet.
The liquid bleach chemical is externally provided and dosed by user onto the stained area. The bleach chemical is in liquid form for this type of execution.
The light source 106 is preferably arranged at a front end FE of the system. In particular, the front end FE corresponds to the part of the stain removal system cooperating with the stained area. The light source 106 is preferably but not limited to be light emitting diode (LED) lamps. Higher light intensity increases the radical generation rate and result in better stain removal results.
Compared to the embodiment of
The system for carrying the bleach chemical to the stained area 102 comprises a tube 202 along which a valve 203 is arranged. The valve 203 can be opened or closed (not shown) by a user, mechanically or electrically, in order to open or close the liquid circuit. When the valve 203 is open, bleach chemical liquid is flowing down by gravity force until reaching the stained area 102.
Compared to the embodiment of
It is noted that in the various embodiments according to the invention, the container for containing a bleach chemical can take any form taken among:
Compared to the embodiment of
This embodiment comprises a water reservoir 503 and a water path 505a-505b for carrying water from the water reservoir 503 to the container 504 in order to dissolve the solid bleach chemical 502. The resulting dissolved solid bleach chemical releases a bleach solution, like H2O2, or mixture of H2O2 and peracetic acid, etc.
The water reservoir 503 comprises an opening 506 so that the user can fill-in water when the water reservoir 503 gets empty.
Preferably, a pump 302 is arranged along the water path 505a-505b to facilitate the carrying of water into the container, so that the solid bleach chemical 502 can be dissolved faster and more efficiently.
The solid bleach chemical 502 is arranged inside the container 504 which is closed by a detachable cover 507.
The solid bleach chemical 502 preferably defines a solid-chemical pill that can be dissolved by water. To this end, chemical powder is pressed into a certain shape (for example cylindrical) to form a pill.
The container 504 comprises an inlet 601 to allow water W to enter in order to dissolve the solid bleach chemical 502. The detachable cover 507 comprises an outlet 602 to let the dissolved chemical solution DCS exit the container 504.
The detachable cover 507 is first detached by user from the body of the container 504. Then user inserts a solid bleach chemical 502 inside the container 504. Then user closes the container 504 by attaching the detachable cover 507 back to the body of the container 504. For example, the detachable cover 507 is detached/attached from the body of the container 504 via a screw arrangement (as illustrated), or a clipping mechanism (not shown).
The container 504b is intended to be used similarly as the container 504 in the embodiment of
The solid bleach chemical 502b preferably defines a powder-chemical porous pouch. The porous material containing the powder-chemical preferably has a pore size smaller than the grain size of the chemical powder, and is made of non-water dissolvable material forming a soft pod for containing said solid bleach chemical. This powder-chemical porous pouch may look like a “tea-bag”.
It shows that the light source 106 is arranged at a front end FE of the stain removal system in order to conveniently face a stained area. The container 504 containing the solid bleach chemical and its cover 507 are arranged in the central part of the front end FE.
Preferably, as illustrated for example in
For example, the heating system is an electrical heater 508 arranged in thermal contact with a bottom part of the water reservoir 503.
The goal of using this heating system is to carry heated water into the container 504 containing the solid bleach chemical.
The heated water provides the benefit of:
Alternatively, as illustrated for example in
In order to dissipate heat of the light source, the heat sink 802 is thermally coupled to the light source 106. The heat sink 802 comprises a water channel formed there into. The water channels have a water inlet 804 to which the tubing 505b is connected. When the light source 106 is switched-on, heat is dissipated and absorbed by the heat sink 802. As a result, water circulating into the water channel 801 gets heated before reaching the inlet 601 of the container 504 containing the solid bleach chemical. For example, as illustrated, the water channel 801 is spiral-shaped.
The water that passes in the water channel 801 is heated to a temperature dependent on:
The estimated temperature range of the heated water is between 40 and 80 degree C. The heated water then passes via the chemical to dissolve the solid bleach chemical and finally on to the garment. Chemical powder can be more effectively dissolved as the water temperature is elevated. And the stain removal effect can be also further increased as the temperature of chemical solution dosed is higher.
Water flows via a tubing 505a-505b from the water reservoir in direction of the container 504 containing the solid bleach chemical. In a cost-effective embodiment, water is only carried under gravity. In another embodiment (as shown), a water pump 302 actuated by a button 803 is inserted along the tubing.
At the front end FE, the light source 106 is arranged, for example a plurality of LEDs. For example, two LED elements of 10W blue light each are arranged at a distance d1=1 cm between the center CC of the LED elements and the center of the front end FE. Under such conditions, a red wine stain can be effectively removed within 5 min. This example is illustrated in
Preferably, the distance d1 between a central part of the light source (e.g. LED) and center central part of the front end FE of the system (logically corresponding to the center of the stained area 102 when the system is in contact with the cloth) has a value less 10 centimeters, considering the light intensity at the stain surface should be sufficient and the stain removal system must be as small as possible, in particular if it is a handheld device. Preferably the distance d1 has a value less than 5 cm.
Preferably, the stain removal system according to the invention further comprises a heating system for heating the stained area 102. The heat provided to the stained area 102 allows increasing speed of the chemical reaction during stain removal. Some examples will now be explained in more details along with
The heater fan 902 is preferably arranged at a mid-height position of the body of the stain removal system 901. The heater fan 902 combines an air fan 902a and a heating element 902b placed upstream in the air flow. The heater fan 902 primarily generates heat by convection to the stained area 102. The heater fan 902 is activated during the stain removal process.
A top hollow portion 903 is arranged to let (room-temperature) air to circulate towards the air fan 902a. Air flow is illustrated by arrows in dotted line style. A bottom hollow portion 904 is arranged to let the heated air to circulate towards the front end FE. In other words, air 905 that reaches the front end FE corresponds to heated air.
For example, the heater fan 902 is adapted to generate heated air up to 60 degrees Celsius at the front end. This range of temperature allows treating stain without taking off the clothes. At a temperature less than 60 degree C., combined with the use of the fan 902a, water evaporation of the treated stained area is accelerated significantly, leaving the treated clothes with less moisture.
Note that in
The infra-red lamp 1002 is arranged at the front end FE of the stain removal system 1001, with the goal to primarily generate heat by radiation to the stained area 102. For example, the infra-red lamp 1002 is adapted to generate heated radiation 1003 up to 60 degrees Celsius at the front end FE. This range of temperature allows treating stain without taking off the clothes.
Note that in
It is noted that the heater fan and the infra-red lamp can also be used after stain treatment, in order to dry the area where the stained area was initially.
As directly reflected by above description, the method of treating a stained area 102 on a cloth 103 by a stain removal system includes an initial step 1100 of retrieving (or receiving) the bleach chemical from a container, the container being in the form of a removable cartridge.
The method further comprises the steps of:
The above embodiments as described are only illustrative, and not intended to limit the technique approaches of the present invention. Although the present invention is described in details referring to the preferable embodiments, those skilled in the art will understand that the technique approaches of the present invention can be modified or equally displaced without departing from the protective scope of the claims of the present invention. In the claims, the word “comprising” does not exclude other elements or steps, and the indefinite article “a” or “an” does not exclude a plurality. Any reference signs in the claims should not be construed as limiting the scope.
Number | Date | Country | Kind |
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17185088.6 | Aug 2017 | EP | regional |
17207332.2 | Dec 2017 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2018/071363 | 8/7/2018 | WO | 00 |