Liquefier for a heat pump, heat pump, and method for manufacturing a liquefier

Information

  • Patent Grant
  • 9939182
  • Patent Number
    9,939,182
  • Date Filed
    Monday, March 30, 2009
    15 years ago
  • Date Issued
    Tuesday, April 10, 2018
    6 years ago
Abstract
A liquefier for a heat pump includes a liquefier space, a compressor motor and a motor fixture for holding the stationary motor part, wherein the motor further has a motor shaft and a compressor wheel connected to the motor shaft. The motor fixture is formed so that the stationary motor part is held so that it is in contact with liquefied working fluid when liquefied working fluid is filled in the liquefier space. Furthermore, the compressor wheel extends into a region of the heat pump in which a channel for gaseous working fluid to be compressed passes.
Description
CROSS-REFERENCE TO RELATED APPLICATION

This application is a U.S. National Phase entry of PCT/EP2009/002313 filed Mar. 30, 2009, and claims priority to German Patent Application No. 10 2008 016627.8 filed Apr. 1, 2008, each of which is incorporated herein by references hereto.


BACKGROUND OF THE INVENTION

The present invention relates to heat pumps, and particularly to the special design of a liquefier for a heat pump.


WO 2007/118482 discloses a heat pump with an evaporator for evaporating water as the working liquid to produce working vapor. The heat pump further includes a compressor coupled to the evaporator to compress the working vapor. Here, the compressor is formed as a flow machine, wherein the flow machine comprises a radial wheel accepting uncompressed working vapor at its front side and expelling same by means of correspondingly formed blades at its side. By way of the suction, the working vapor is compressed so that compressed working vapor is expelled on the side of the radial wheel. This compressed working vapor is supplied to a liquefier. In the liquefier, the compressed working vapor, the temperature level of which has been raised through the compression, is brought into contact with liquefied working fluid, so that the compressed vapor again liquefies and thus gives off energy to the liquefied working fluid located in the liquefier. This liquefier working fluid is pumped through a heating system by a circulation pump. In particular, a heating flow, at which warmer water is output into a heating cycle, such as a floor heating, is arranged to this end. A heating return then again feeds cooled heating water to the liquefier so as to be heated again by newly condensed working vapor.


This known heat pump may be operated as an open cycle or as a closed cycle. The working medium is water or vapor. In particular, the pressure conditions in the evaporator are such that water having a temperature of 12° C. is evaporated. To this end, the pressure in the evaporator is at about 12 hPa (mbar). By way of the compressor, the pressure of the gas is raised to, e.g., 100 mbar. This corresponds to an evaporation temperature of 45° C. thus prevailing in the liquefier, and particularly in the topmost layer of the liquefied working fluid. This temperature is sufficient for supplying a floor heating.


If higher heating temperatures are required, more compression is adjusted. However, if lower heating temperatures are needed, less compression is adjusted.


Furthermore, the heat pump is based on multi-stage compression. A first flow machine is formed to raise the working vapor to medium pressure. This working vapor at a medium pressure may be guided through a heat exchanger for process water heating so as to then be raised to the pressure needed for the liquefier, such as 100 mbar, e.g. by a last flow machine of a cascade of at least two flow machines. The heat exchanger for process water heating is formed to cool the gas heated (and compressed) by a previous flow machine. Here, the overheating enthalpy is utilized wisely to increase the efficiency of the overall compression process. The cooled gas is then compressed further with one or more downstream compressors or directly supplied to the liquefier. Heat is taken from the compressed water vapor so as to heat process water to higher temperatures than, e.g., 40° C. therewith. However, this does not reduce the overall efficiency of the heat pump, but even increases it, because two successively connected flow machines with gas cooling connected therebetween achieve the demanded gas pressure in the liquefier with a longer life due to the reduced thermal stress and with less energy than if a single flow machine without gas cooling were present.


For a heating system to have acceptance in the market, it should not be too bulky and be offered in a form that can be handled well by workmen or builder-owners can be transported easily to typical locations and be set-up there, such as in cellars or heating rooms.


In particular, in heat pumps operated with water as liquefied working fluid and/or vapor as gaseous working fluid, high demands are made regarding the compressor. In particular, the compressor must have a high output so as to achieve required vapor compression. To this end, it is necessary for a compressor motor to operate at comparably high rotational speeds. Furthermore, in this connection, it is desirable for the compressor to have a radial wheel to achieve efficient, and nonetheless powerful, compression.


High rotational speeds for the motor, however, lead to the fact that the compressor motor contributes to noise development, which may be considerable, especially due to residual imbalances remaining after balancing and/or increasing with the rotational speed of the motor.


Moreover, even very efficient electric motors exhibit heat development also increasing with rising rotational speed, due to the finite ohmic resistances of the current-carrying parts.


The noise development is not that advantageous, indeed, but may be accepted, depending on the setup location of the heat pump, because a heat pump typically is not arranged in the living room, but in a cellar room, which is sonically decoupled from the living room anyway.


Waste heat losses of the motor are, however, even less desirable, because they immediately affect the efficiency of the heat pump. On the other hand, the waste heat requirements may become so high that the motor even has to be cooled actively so as not to loose its specified properties. A special cooling cycle and/or a simple waste heat removal of the motor, e.g. by air convection, however, reduces the efficiency of the heat pump or increases the costs for the heat pump.


SUMMARY

According to an embodiment, a liquefier for a heat pump may have: a liquefier space formed to hold liquefied working fluid; a compressor motor with a stationary motor part, a motor shaft, and a compressor wheel connected to the motor shaft; a motor fixture for holding the stationary motor part, wherein the motor fixture is formed to hold the stationary motor part so that it is in contact with liquefied working fluid when liquefied working fluid is filled in the liquefier space; and wherein the compressor wheel extends into a region in which a channel for gaseous working fluid to be compressed passes.


According to another embodiment, a heat pump may have: a liquefier for a heat pump as mentioned before; and an evaporator, wherein the evaporator is arranged below the liquefier in a setup direction of the heat pump.


According to another embodiment, a method of manufacturing a liquefier for a heat pump with a liquefier space formed to hold liquefier working fluid, with a compressor motor with a stationary motor part, a motor shaft and a compressor wheel connected to the motor shaft, a motor fixture for holding the stationary motor part, may have the step of: forming the motor fixture so that the stationary motor part is in contact with liquefied working fluid when liquefied working fluid is filled in the liquefier space, wherein the compressor wheel extends into a channel for gaseous working fluid to be compressed.


The present invention is based on the finding that, by arranging at least the stationary motor part in the liquefier, and particularly in the space of the liquefier occupied by liquefied working fluid, when liquefied working fluid is filled in, possible cooling problems of the motor are solved easily. The motor is cooled well by the liquefied working fluid, which typically has a low heat transfer resistance, and, in particular, a lower heat transfer resistance than air and/or gas. Hence, by arranging the motor in the liquefied working fluid, sufficient cooling of the motor may be provided easily, such that the temperature of the motor does not rise substantially above the temperature in the liquefier. Since the temperature in the liquefier typically will remain below 60 degrees even on cold winter days, there still is a big margin for the motor temperature, because motors can also be operated at substantially higher temperature than 60° C.


Furthermore, motor losses, which develop through heat generation in the motor, easily are compensated for by 100% and converted to useful heat, because “loss heat” generated in the motor is immediately used to heat liquefied working fluid in the liquefier. Heating the liquefied working fluid, however, exactly is the useful mechanism of the heat pump in which vapor, when it condenses, heats the liquefied working fluid in the liquefier.


When selecting the motor, therefore, no attention must be paid additionally to a special, particularly low-loss-power implementation of the motor. Instead, motors not tuned to especially low power consumption may also be employed, because waste heat losses of the motor are converted into heated liquefier fluid anyway. This allows for employing motors that probably are not the best ones in terms of their loss properties, but are optimally suited for heat pump applications with respect to their long-term stability and other criteria, such as high rotation speeds, etc.


Furthermore, in one embodiment, the motor is held via a tubular member, which at the same time provides good sound protection. Potential vibrations the motor has due to the inevitable (remaining) imbalances are indeed transferred to the liquefied working fluid within the pipe. Yet, these vibrations remain within the pipe, since the pipe cannot make the outside liquefier volume vibrate due to its round and plane outside surface. For this reason, a tubular motor mount will lead to the fact that the sound development of the heat pump is reduced substantially, which even allows for operating the heat pump in living quarters, such as a bathroom of an apartment.


In one embodiment, a motor is employed at a bottom end of an up-flow conduit, in order to implement a first compressor stage compressing liquefied gas at low pressure up to medium pressure. In particular, when the evaporator is arranged below the liquefier (with respect to a setup direction of the heat pump), a motor shaft will penetrate a lower wall, i.e. a bottom, of the liquefier so as to be able to drive a radial wheel arranged in the path for evaporated working fluid. In order to implement a multi-stage compressor, a further compressor motor is arranged at another, i.e. in this case at the upper end of the up-flow conduit, wherein the motor again is in the liquefier fluid, but the radial wheel, which is driven by the motor, is in a gas channel to achieve gas compression, and thus typically gas compression of a last stage of a compressor. A circulation pump also is arranged within the up-flow conduit between both motors to generate a liquid flow in the up-flow conduit, the flow direction of which is directed opposite to the gradient of warm water to cold water within the heat pump.





BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the present invention will be explained in greater detail in the following with respect to the accompanying drawings, in which:



FIG. 1 is a schematic illustration of the heat pump with an evaporator, a compressor and a liquefier including a process water tank;



FIG. 2 is a schematic illustration of the process water tank of FIG. 1;



FIG. 3 is an enlarged illustration of the arrangement of the process water tank in the working fluid space;



FIG. 4 is a schematic illustration of the compressor/intermediate cooling cascade of FIG. 1;



FIG. 5 is an enlarged view of the arrangement of the second compressor stage at the upper end of the up-flow conduit;



FIG. 6 is an illustration even further enlarged as compared with FIG. 5 of the arrangement of the first compressor stage at the bottom end of the up-flow conduit;



FIG. 7 is a schematic illustration of an arrangement of a compressor motor in the up-flow conduit; and



FIG. 8 is a cross-section through the up-flow conduit with fixtures and additional cooling fins.





DETAILED DESCRIPTION OF THE INVENTION


FIG. 1 shows a schematic cross-sectional view of a heat pump in which a liquefier may be employed advantageously. The heat pump includes a heat pump housing 100 comprising, in a setup direction of the heat pump from the bottom to the top, first an evaporator 200 and a liquefier 300 above it. Furthermore, a first compressor stage 410 feeding a first intermediate cooler 420 is arranged between the evaporator 200 and the liquefier 300. Compressed gas output from the intermediate cooler 420 enters a second compressor stage 430 and there is condensed and supplied to a second intermediate cooler 440, from which the compressed, but intermediately cooled gas (vapor) is fed to a liquefier 500. The liquefier has a liquefier space 510, which comprises a working fluid space filled with liquefied working fluid, such as water, up to a filling level 520. The liquefier 500 and/or the liquefier space 510 are limited to the outside by a liquefier wall 505, which provides a lateral boundary of the liquefier shown in cross-section in FIG. 1 as well as a lower boundary, i.e. a bottom area of the liquefier shown in FIG. 1. Above the filling level 520, which sets the boundary between the liquefied working fluid 530 and the not (yet) liquefied, but gaseous working fluid 540, there is the gaseous working fluid, which was expelled by the second compressor 430 into the second intermediate cooler 440.


There is a process water tank 600 in the working fluid space 530. The process water tank 600 is formed such that its contents are separated from the liquefied working fluid in the working fluid space 530 in terms of liquid. Furthermore, the process water tank 600 includes a process water inflow 610 for cold process water and a process water outflow or process water flow 620 for warm process water.


It is to be noted that the process water tank may also be arranged outside the liquefied liquefier fluid, even though arrangement in the liquefier may be advantageous.


The process water tank 600 is arranged at least partially in the working fluid space 530. The process water tank includes a process water tank wall 630 arranged spaced from a wall 590 of the working fluid space so that a gap 640 formed to communicate with the gas region 540 results. Furthermore, the arrangement is such that, in operation, no liquefied working fluid or at least partially no liquefied working fluid is contained in the gap 640. An insulating effect between the water in the process water tank 600 and the liquefied working fluid (such as water) in the working fluid space 530 is obtained already when e.g. the upper region of the gap 640 is full of working fluid vapor and/or working fluid gas, while for some reason the lower region of the gap is filled with working fluid.


In particular, since the liquid of the process water is less in the lower region than in the upper region, it is sufficient anyway, depending on the implementation, to ensure insulation only in the upper region, because it may even be partly favorable for the lower region to have no insulation or only little insulation to the liquefier space. This is due to the fact that the water supply is at about 12° C., or at lower temperatures, particularly in winter when the water from the water conduit is even colder. In contrast, the lower region of the working fluid space will have temperatures of maybe more than 30° C. and may e.g. be even at 37° C. Hence, at least for ensuring that the upper (warmer) region of the process water tank is warmer than the liquefier space, it is uncritical whether the lower region of the process water tank is insulated particularly thickly from the liquefier. Thus, it is not so critical if the lower region is filled with liquefied working fluid, as long as the region of the process water tank where a higher temperature results due to the layering is thermally insulated from the working fluid space 530.


Subsequently, the individual components of the heat pump described in FIG. 1 will be illustrated in greater detail.


In an evaporator inflow 210, liquid working fluid to be cooled is supplied, such as ground water, seawater, brine, river water, etc., if an open cycle takes place. In contrast, also a closed cycle may take place, wherein the liquefied working fluid supplied via the evaporator inflow conduit 210 in this case e.g. is water pumped into the ground and up again via a closed underground conduit. The seal and the compressors are designed such that a pressure that is such that water evaporates at the temperature at which it rises via the inflow conduit 210 forms in an evaporation space 220. So as to let this process take place as well as possible, the evaporator 200 is provided with an expander 230, which may be rotationally symmetrical, wherein it is fed at the center like an “inversed” plate, and the water then flows off from the center outwardly toward all sides and is collected in an also circular collecting trench 235. At one point of the collecting trench 235, an outflow 240 is formed, via which the water cooled by the evaporation and/or the working fluid is pumped down again in liquid form, i.e. toward the heat source, which may for example be the ground water or the soil.


A water jet deflector 245 is arranged so as to ensure that the water conveyed by the inflow conduit 210 does not splash upward, but flows off evenly toward all sides and ensures as efficient an evaporation as possible. An expansion valve 250, by which a pressure difference between both spaces may be controlled, if needed, is arranged between the evaporation space 220 and the working fluid space. Control signals for the expansion valve as well as for the compressors 410, 430 and for other pumps are supplied by an electronic controller 260, which may be arranged at any location, wherein issues like good accessibility from the outside for adjustment and maintenance purposes are more important than thermal coupling and/or decoupling from the evaporation space or from the liquefaction space.


The vapor contained in the evaporation space 220 is sucked by a first compressor stage 410 in a flow as uniform as possible via a shaping for the evaporation space, which narrows from the bottom upward. To this end, the first compressor stage includes a motor 411 (FIG. 6) driving a radial wheel 413 via a motor shaft 412 schematically depicted in FIG. 6. The radial wheel 413 sucks the vapor through its bottom side 413a and outputs the same in a compressed form at its output side 413b. Thus, the now compressed working vapor reaches a first portion of the vapor channel 414, from where the vapor reaches the first intermediate cooler 420. The first intermediate cooler 420 is characterized by a corresponding protrusion 421 for slowing the flow rate of the working gas overheated due to the compression, which may be penetrated by fluid channels, depending on the implementation, as not shown in FIG. 1, however. These fluid channels may, for example, be flown through by heating water, i.e. working fluid water, in the working fluid space 530. Alternatively or additionally, these channels may also be flown through by the cold water supply cycle 610, in order to already obtain preheating for the process water fed into the process water tank 600.


In another embodiment, the guiding of the fluid channel 420 around the cold bottom end of the working fluid space 530 of the liquefier 500 acts such that the working fluid vapor, which extends through this relatively long expanded working fluid channel, cools and gives off its overheating enthalpy on its way from the first radial wheel 33 (FIG. 5).


The working fluid vapor flows through the intermediate cooler 420 via a second channel portion 422 into a suction opening 433a of the radial wheel 433 of the second compressor stage and there is fed into the second intermediate cooler 440 laterally at an expulsion opening 433b. To this end, a channel portion 434 is provided extending between the lateral expulsion opening 433b of the radial wheel 433 and an input into the intermediate cooler 440.


The working vapor condensed by the second compressor stage 430 to the liquefier pressure then passes through the second intermediate cooler 440 and is then guided onto cold liquefied working fluid 511. This cold liquefied working fluid 511 is then brought onto an expander in the liquefier, which is designated with 512. The expander 512 has a similar shape to the expander 230 in the evaporator and again is fed by way of a central opening, wherein the central opening in the liquefier is fed by way of an up-flow conduit 580 in contrast to the inflow conduit 210 in the evaporator. Through the up-flow conduit 580, cooled liquefied working fluid, i.e. arranged at the bottom area of the working fluid space 530, is sucked from a bottom area of the working fluid space 530, as indicated by arrows 581, and brought up in the up-flow conduit 580, as indicated by arrows 582.


The working fluid in liquid form, which is cold because it comes from the bottom of the working fluid space, now represents an ideal “liquefaction partner” for the hot compressed working fluid vapor 540 in the vapor space of the liquefier. This leads to the fact that the liquefied working fluid conveyed by the up-flow conduit 580 is heated up more and more by the liquefying vapor on the way on which it flows from the central opening downward toward the edge, so that the water, when it enters the working fluid space filled with liquefied working fluid on the edge of the expander (at 517), heats up the working fluid space.


Liquefied working fluid of the working fluid space 530 is pumped into a heating system, such as floor heating, via a heating flow 531. There, the warm heating water gives off its temperature to the floor or to air or a heat exchanger medium, and the cooled heating water again flows into the working fluid space 530 via a heating return 532. There, it is again sucked via the flow 582 generated in the up-flow conduit 580, as illustrated at the arrows 581, and again conveyed onto the expander 512 so as to be heated again.


Subsequently, with respect to FIG. 1 and FIGS. 2 and 3, the process water tank 600 will be dealt with in greater detail. Apart from the cold water inflow 610 and the warm water flow 620, the process water tank 600 may further include a circulation return 621, which is connected to the warm water flow 620 and a circulation pump such that, by actuating the circulation pump, it is ensured that preheated process water is present at a process water tap. With this, it is ensured that the tap for warm water does not have to be actuated for a very long time at first until warm water exits the tap.


Furthermore, a schematically drawn process water heater 660, which may, for example, be formed as a heater coil 661 (FIG. 1), is provided in the process water tank. The process water heater is connected to a process water heater inflow 662 and a process water heater outflow 662. The liquid cycle in the process water heater 660 is, however, coupled from the process water in the process water tank, but may be coupled with the working fluid in the working fluid space 530, as illustrated in FIG. 1, in particular. Here, warm liquefied working fluid is sucked, by a pump that is not shown, through the process water heater inflow 662 near the entry location 517, where the highest temperatures are present, into the process water heater 660, transported through it and output again at the bottom, i.e. where the coldest temperatures in the working fluid space 530 are present. A pump that may be used for this may either be arranged in the process water tank itself (but decoupled in terms of liquid) so as to use the waste heat of the pump, or may be provided outside the process water tank in the liquefier space, which is of advantage for reasons of hygiene.


Thus, the process water tank 600 has an upper portion and a lower portion, wherein the heat exchanger 660 is arranged such that it extends more in the lower portion than in the upper portion. The process water heater with its heating coil thus only extends where the temperature level of the process water tank is equal to or smaller than the temperature of the liquefier water. In the upper portion of the process water tank, the temperature will, however, be above the temperature of the liquefier water, so that the heat exchanger with its active region, i.e. its heating coil, for example, does not have to be arranged there.


By way of the process water heater 660, the process water present in the process water tank 600 thus cannot be heated to any higher temperatures than are present at the warmest point in the liquefier, i.e. around the location 517, where the heated working fluid enters the working fluid volume in the liquefier from the expander 512.


A higher temperature is reached by using process water to achieve intermediate cooling of the compressed vapor. To this end, the process water tank includes a connection in its upper region to accommodate process water passed through the intermediate cooler 440, which is at a significantly higher temperature than is present at the location 517. This intermediate cooler outflow 671 thus serves to bring the topmost region of the process water tank 600 to a temperature above the temperature of the liquefied working fluid 530 near the working fluid level 520. Cooled process water and/or supplied cold process water is taken off at the bottom location of the process water tank via the intermediate cooler inflow 672 and supplied to the intermediate cooler 440. Depending on the implementation, the process water is heated not only by the second intermediate cooler 440, but also is heated by the first intermediate cooler 420/421, although this is not illustrated in FIG. 1.


In a usual design of the heat pump, it may be assumed that the intermediate cooling does not provide any such strong heating power for the intermediate cooler cycle alone to be sufficient to generate a sufficient amount of warm water. For this reason, the process water tank 600 is designed to have a certain volume, such that the process water tank is constantly heated to a temperature above the liquefier temperature in normal operation of the heat pump. Thus, a predetermined buffer is present for when a greater amount of water is taken out, such as for a bathtub or for several showers having been had simultaneously or in quick succession. Here, also an automatic process water preference effect occurs. If very much warm water is taken out, the intermediate cooler becomes colder and colder and will remove more and more heat from the vapor, which may well lead to reduced energy the vapor is still capable of giving off to the liquefier water. This effect of preferring the warm water dispensing is, however, desirable because heating cycles typically do not react that quickly, and at the moment at which one would like to have process water warm process water is more important than the issue of whether the heating cycle works slightly more weakly for a short period of time.


However, if the process water tank is fully heated, the process water heater 660 may be deactivated by the electronic controller by stopping the circulation pump. Furthermore, the intermediate cooler cycle may also be stopped via the connections 671, 672 and the corresponding intermediate cooler pump, because the process water tank is at its maximum temperature. However, this is not absolutely necessary, because when the process water tank is fully heated, the energy present there is to some extent reversely fed into the process water heater 660, which now acts as the process water cooler, in order to still advantageously utilize the overheating enthalpy to heat the working fluid space of the liquefier even at its lower, rather cooler location.


The arrangement of the process water tank in the liquefier space and the heating of the process water tank by a process water heater from the liquefier volume and/or by a cycle to an intermediate cooler thus does not necessarily have to be controlled especially tightly, but may even work without control, because preference of the warm water processing takes place automatically, and because, when warm water processing is not necessary, such as at longer periods during the night, the process water tank serves to additionally heat the liquefier further. The purpose of this heating is to be able to maybe even reduce the power consumption of the compressor, without the heating of the building, performed via the heating flow 531 and the heating return 532, falling below its nominal value.



FIG. 3 shows a schematic illustration of the accommodation of the process water tank 600 in the liquefier space. In particular, it is of advantage for the entire process water tank 600 to be arranged below the filling level 520 of the liquefied working fluid. If the heat pump is designed so that a filling level 520 of the liquefied working fluid may vary, a gap vapor feed 641 may be arranged above the maximum filling level 520 for liquefied working fluid in the working fluid space 530. With this, it is ensured that, even in the case of the maximum filling level 520, no working fluid may enter the gap 640 via the conduit 641. Thereby, vapor is present in the entire space 640, namely the vapor that is also in the region filled with vapor or gas region 540 of the liquefier. The process water tank 600 therefore is arranged by analogy with a thermos bottle in the liquefier, namely below the “water surface”.


By analogy with a thermos bottle, in which the inner region into which the liquid to be kept warm is filled is insulated by an evacuated region from the outside surrounding air, the process water tank 600 is insulated from the heating water in the space 530 by a vapor or gas filling, without any solid insulating material in the gap. Even though there is no high vacuum in the gap 640, a significant negative pressure, for example 100 mbar, still is present in the gap 640, particularly for heat pumps operated with water as the working fluid, i.e. operating at relatively low pressures.


The size of the gap, i.e. the shortest distance between the working fluid space wall 590 and the process water tank wall 630, is uncritical with respect to the dimensions and should be greater than 0.5 cm. The maximum size of the gap is arbitrary, but is limited by the fact that an increase of the gap at some point brings along more disadvantages due to less compactness and no longer provides any greater advantages with respect to the insulation. Therefore, it is of advantage to make the maximum gap between the walls 630 and 590 smaller than 5 cm.


Furthermore, it is of advantage to design the liquefier 500 so that the volume of liquefied working fluid, which at the same time represents the heating water storage, ranges from 100 to 500 liters. The volume of the process water tank will typically be smaller and may range from 5% to 50% of the volume of the working fluid space 530.


Furthermore, it is to be pointed out that the cross-sectional illustration in FIG. 1, apart from certain connecting conduits, which are self-explanatory, is rotationally symmetrical. This means that the expander 230 in the evaporator or the expander 512 may be formed, as it were, as an inverted plate in the top view.


Moreover, the vapor channels 414, 422 will extend in a circular way around the entire almost cylindrical space for the liquefied working fluid, which is circular in the top view.


Moreover, also the process water tank may be circular in the top view. The process water tank is arranged in the right half of the working fluid space 530, in the embodiment shown in FIG. 1. Depending on the implementation, however, it could also be arranged in a rotationally symmetrical manner, so that it would extend, as it were, like a ring around the up-flow conduit. Such a large-scale design of the process water tank often is not necessary, however, so that a design of the process water tank in a sector of the working fluid space that is circular in top view is sufficient, wherein this sector may be smaller than 180 degrees.


Subsequently, on the basis of FIG. 4, the compressor cycle with the arranged intermediate coolers will be illustrated in greater detail. In particular, as illustrated on the basis of FIG. 1, evaporated water vapor at low temperature and low pressure, such as at 10° C. and 10 mbar, reaches a first compressor stage 410 which may be implemented by a motor with an associated radial wheel via the evaporation conduit 200. It is already to be noted that the motor for driving the radial wheel according to the invention is arranged in the up-flow conduit 580, as will still be illustrated in greater detail and has already been explained in FIG. 6. At the output of the first compressor 410, also referred to as K1 in FIG. 4, vapor is fed into the vapor channel 414. This vapor has a pressure of about 30 mbar and typically has a temperature of about 40° C. due to the overheating enthalpy. This temperature of about 40° C. is now being removed from the vapor, without significantly affecting its pressure, via the first intermediate cooler 420.


The intermediate cooler 420, which is not shown in FIG. 1, includes e.g. a conduit arranged in thermal coupling to the surface of the expansion 421 and in the area of the gas channel 414 so as to remove energy from the vapor there. This energy may be used to heat the working fluid space 530 of the liquefier or to already heat part of the process water tank, such as the lower part, if the process water tank is designed as a layered reservoir. In this case, a further inflow originating from the first intermediate cooler would not be arranged at the top in the process water tank, but roughly in the middle of the process water tank. Alternatively, however, cooling of the gas to the temperature or near the temperature prevailing in the working fluid space already takes place by guiding the channels 414 and 422 along the working fluid space when the wall of the working fluid space is formed to be non-insulating, as it is of advantage.


Then, the gas, which is at the medium pressure of 30 mbar but is now cooled again, reaches the second compressor stage 430, where it is compressed to about 100 mbar and output into the gas output conduit 434 at a high temperature, wherein this temperature may be at 100-200° C. The gas is cooled by the second intermediate cooler 440, which heats the process water tank 600 via the connections 671, 672, as has been illustrated, but without significantly reducing the pressure. The compressed gas, now reduced in its overheating enthalpy, is supplied to the liquefier to heat the heating water, wherein the “channel” between the output of the intermediate cooler 440 and the liquefier expander 512 is designated with the reference numeral 438.


Subsequently, on the basis of FIG. 5, the more detailed construction of the second compressor stage 430 and the interaction with the second intermediate cooler 440 will be illustrated. The radial wheel 433 of the second compressor compresses the gas supplied via the channel 422 or, when the heat pump is operated with water, the vapor supplied via the channel 422 to a high temperature and a high pressure and outputs the heated and compressed vapor into the vapor output conduit 434, where the vapor then enters the second intermediate cooler 440, which is formed so that the gas has to take a relatively long path around this intermediate cooler, such as the zigzag path indicated by arrows 445, 446. This shaping for the path of the gas in the intermediate cooler may easily be achieved by plastic injection-molding methods.


The intermediate cooler has a middle intermediate cooler portion 447, which may be penetrated by piping not shown in FIG. 5. Alternatively, the middle portion 447 may be completely hollow and be flown through by process water to be heated in the sense of a flat conduit, in order to achieve the maximum heating effect possible. Corresponding conduits for process water may also be provided at the exterior walls in the intermediate cooler portion such that, in the intermediate cooler 440, there is a surface as cool as possible for the gas flowing through the intermediate cooler 440, so that as much thermal energy as possible can be given off to the circulating process water, in order to achieve, in the process water tank, a temperature significantly above the temperature in the liquefier space.


It is to be pointed out that the intermediate cooler 440 may also be formed alternatively. Indeed, several zigzag paths may be provided, until the gas may then enter the intermediate cooler output conduit 438 so as to be able to finally condense. Moreover, any heat exchanger concepts may be employed for the intermediate cooler 440, but wherein components flown through by process water are of advantage.


Subsequently, with reference to FIG. 7, the arrangement of the compressor motor in the up-flow conduit 580 will be illustrated. FIG. 7 shows the motor 411, which drives a motor shaft 412, which in turn is connected to an element 413 designated as compressor. The element designated as compressor 413 may be a radial wheel, for example. However, any other rotatable element sucking vapor at low pressure on the input side and expelling vapor at high pressure on the output side may be used as a compression element. In the arrangement shown in FIG. 7, only the compressor 413 is arranged, i.e. the rotatable compression member in the vapor stream extending from the space 220 to the vapor channel 414. The motor and a substantial part of the motor shaft, i.e. the elements 411 and 412, are not, however, arranged in the vapor medium, but in the liquefier space for liquefied working fluid, such as liquefier water, wherein this working fluid space is designated with 530. By way of the arrangement of the motor in the liquefier water, the motor waste heat, which also develops in highly low-loss motors, favorably is not given off to the environment in a useless way, but to the liquefied heating fluid to be heated itself. This liquefied heating fluid itself provides—as seen from the other side—good cooling for the motor so that the motor does not overheat and suffer damage.


The arrangement of the motor in the liquefier, and particularly in an up-flow conduit of the liquefier, also has another advantageous effect. In particular, inherent sound insulation is achieved in that the motion exerted by the motor on the surrounding liquefied working fluid does not result in the entire working fluid being set into motion, because this would then lead to sound generation. This sound generation would entail additional intensive sound-proofing measures, which again entails additional cost and additional effort, however. Yet, if the motor 411 is arranged in the up-flow conduit 580 or, generally speaking, in a cylindrical pipe, which does not necessarily have to be an upstream conduit, movement of the working fluid generated by movement of the motor does not lead to any noise generation outside the liquefier at all, or only to very reduced noise.


The reason for this is that, although the working fluid is set to motion within the up-flow conduit and/or within the cylindrical object due to the mounting of the motor and to potentially additionally present cooling fins of the motor, this motion is not transferred to the liquefied working fluid surrounding the cylindrical pipe due to the wall of the cylindrical pipe. Instead, the entire noise-generating motion of the working fluid remains contained within the pipe, because the pipe itself may be turned back and forth due to its cylindrical shape, but does not generate any significant motion in the liquefier water surrounding the pipe by this back and forth rotation. For a more detailed illustration of this effect, reference is made to FIG. 8 in the following, with FIG. 8 illustrating a cross-section along the line A-A′ of FIG. 7.



FIG. 8 shows a pipe, which is the up-flow conduit 580, in one embodiment. A motor body 411, which is illustrated only by way of example to have a circular cross-section, is arranged in the pipe. The motor body 411 is held in the pipe 580 by fixtures 417. Depending on the implementation, only two, three or, as shown in FIG. 8, also four fixtures, or even more fixtures may be employed. In addition to the fixtures, cooling fins 418 may also be employed, which are attached in sectors formed by the fixtures 417, and particularly centered and/or uniformly distributed there, in order to achieve an optimum and well-distributed cooling effect.


It is to be pointed out that the fixtures 417 may also act as cooling fins, and that all cooling fins 418 may at the same time also be formed as fixtures. In this case, the material for the fixtures 417 may be a material of good thermal conductance, such as metal or plastics filled with metal particles.


The pipe 580 itself is also mounted within the liquefier by suspensions 583, leading to the motor being supported safely via the pipe.


Vibrations of the motor 411 may lead to motion of the motor around its axis, as illustrated at 419. This leads to the fact that strong motion is exerted on the liquefied working fluid within the pipe 580, because the cooling fins and fixtures act, so to speak, as “oars”. This motion of the liquefied working fluid, however, is limited to the region within the pipe 580, and no corresponding excitation of the liquefier water outside the pipe 580 is achieved. This is due to the fact that, although the pipe 580 has such “oars” on the inside because of the motor fixtures 417 and the cooling fins 418, the pipe 580 may have a smooth surface on the outside, which may be round, too. Hence, the pipe glides on the outside liquefier water due to the vibrational movement 419 without causing any disturbance in the outside liquefier water 530, and hence without generating disturbing sound. Such a disturbance only exists within the cross-section of the pipe 580 and does not reach the surrounding liquid in the liquefier as a disturbing wave from there.


Although an arrangement of the motor in a corresponding pipe having fixture fins and/or cooling fins on the inside already leads to sound containment, it is further of advantage to use the pipe 580 as an up-flow conduit at the same time, so as to achieve space-saving and efficient multi-functionality. The up-flow conduit 580 serves to transport cooled liquefier water into a region also reached by vapor that is to condense so as to give off its energy into the liquefier water as much as possible. To this end, cold liquefied working fluid is transported from the bottom up in the liquefier space. This transport is through the up-flow conduit, which may be arranged centrally, i.e. in the middle of the liquefier space, and feeds the expander 512 of FIG. 1. The up-flow conduit may, however, also be arranged in a decentralized manner, as long as it is surrounded by liquefier water in an area as large as possible, and advantageously completely.


So as to make the liquefier water flow through the up-flow conduit 580 from the bottom upward, a circulation pump 588, as drawn in FIG. 7, for example, is provided in the up-flow conduit. The circulation pump may similarly be arranged with fixtures on the up-flow conduit, although this is not shown in FIG. 7. Yet, the designs of the circulation pump are uncritical, because it does not have to provide such high compression power and/or rotational speeds. Simple operation of the circulation pump at low rotational speeds, however, already leads to the liquefier water flowing from the bottom up, namely along the flow direction 582. This flow leads to the heat generated in the motor 411 being removed, namely so that the motor is cooled with liquefier water that is as cold as possible. This does not only apply for the motor of the lower, first compressor 410, but also for the motor of the upper, second compressor 430.


In the embodiment shown in FIG. 6, the motor shaft 412 pierces the bottom of the liquefier space so as to drive the compressor arranged below the bottom of the liquefier space, i.e. the radial wheel 413 exemplarily shown in FIG. 6. To this end, the passage of the shaft through the wall, drawn at 412a, is formed as a sealed passage such that no liquefier water from above enters the radial wheel. The requirements for this seal are relaxed by the fact that the radial wheel 413 gives off the compressed fluid laterally and not at the top, so that the upper “lid” of the radial wheel already is sealed anyway, and thus there is enough space for generating an effective seal between the channel 414 and the liquefier space 530. Another case, which is shown in FIG. 5, is similar. The radial wheel 433 there again lies in the gas channel, whereas the motor is in the region of the liquefier, which is filled with liquefied working fluid, i.e. with water, for example.


The exemplary up-flow pipe 580 in FIG. 6 has a foot portion, which is only depicted schematically in FIG. 6. The foot portion is pierced to allow for a flow 581 from the liquefier space 530 into the pipe 580, wherein the pipe 580 is fixedly connected 583 to a wall of the liquefier space at locations (not depicted in FIG. 6) at which there are no breakthrough openings for the flow 581. Alternative mounting concepts for mounting the pipe, e.g., by way of suspension 583 from above or a lateral support by way of a support construction 583 surrounded by liquefier liquid, are possible as well.


In particular, the functionality of the circulation pump 588 leads to water conveyed through the up-flow conduit impinging on the lower boundary of the radial wheel. By way of this “impinging”, the water will flow, as it were, toward all sides across the upper expander 512. Yet, no water from the water flow located on the expander 512 is to enter the gas channel 434, of course. For this reason, the shaft 432 of the upper motor 431 may also again be sealed, again with much space remaining for the seal. Just like in the case of the lower motor, this is due to the fact that the lower boundary of the radial wheel 433 again is sealed anyway, i.e. is impermeable for both liquefied working fluid and evaporated working fluid. The compressed evaporated working fluid is expelled laterally and not downwardly with respect to FIG. 5. Hence, the sealing requirements of the shaft 432 again are relaxed due to the large area available.


The heat pump thus combines diverse advantages, due to its efficient construction. At first, due to the fact that the liquefier is arranged above the evaporator, the vapor will move from the evaporator upwardly in the direction of the first compressor stage. Due to the fact that vapor tends to rise anyway, the vapor will perform this movement due to the compression already, without the additional drive.


It is a further advantage that the vapor is guided a long path along the liquefier after the first compressor stage. In particular, the vapor is guided around the entire liquefier volume, which entails several advantages. On the one hand, the overheating enthalpy of the vapor exiting the first evaporator is given off favorably directly to the bottom wall of the liquefier, at which the coldest working fluid is located. Then the vapor flows, as it were, from the bottom upward against the layering in the liquefier into the second compressor. With this, intermediate cooling is achieved virtually automatically, which may be enhanced by an additional intermediate cooler, which can be arranged in a constructively favorable manner, because enough space remains on the external wall.


Furthermore, the vapor channel 422 and/or 414, which surrounds the entire space with liquefied working fluid, which is, after all, the heating water reservoir, acts as an additional insulation to the outside. The vapor channel thus fulfils two functions, namely cooling toward the liquefier volume on the one hand, and insulation to the exterior of the heat pump on the other hand. According to the principle of the thermos flask, the entire liquefier space again is surrounded by a gap, which now is formed by the vapor channel 414 and/or 422. In contrast to the gap 640, in which there is higher vapor pressure, the vapor pressure in the channel 422 and/or 414 is even lower and is, e.g., in the range of 30 hPa or 30 mbar if water is used as the working fluid. By the liquefier thus being surrounded by a vapor channel operating in the medium pressure range, particularly good insulation thus is achieved inherently, without additional insulation effort. The exterior wall of the channel may be insulated to the outside. However, this insulation can be made substantially cheaper as compared with the case in which the liquefier would have to be insulated directly to the outside.


Furthermore, due to the fact that the vapor channel may extend around the entire working fluid volume, a vapor channel with a large cross-section and little flow resistance is obtained such that, in the case of a very compact design of the heat pump, a vapor channel having a sufficiently large effective cross-section is created, which leads to the fact that no friction losses, or only very small ones, develop.


Furthermore, the use of two evaporator stages, which may be arranged below the liquefier and above the liquefier, respectively, leads to the fact that both evaporator motors may be accommodated in the liquefier working fluid volume, so that good motor cooling is achieved, wherein the cooling waste heat at the same time serves for heating the heating water. Moreover, by arranging the second evaporator above the liquefier, it is ensured that as-short-as-possible paths to condensing may be achieved from there, wherein a part of this path that is as large as possible is utilized by a second intermediate cooler for removing the overheating enthalpy. This leads to the fact that almost the entire vapor path which the vapor covers after exiting the second compressor is part of the intermediate cooler, wherein, when the vapor exits the intermediate cooler, condensation takes place immediately, without having to take further, potentially lossy paths for the vapor.


The design with a circular cross-section both for the evaporator and for the liquefier allows for employing a maximum-size expander 230 for the evaporator and at the same time a maximum-size expander 512 for the liquefier, while still achieving a good and compact construction. With this, it is made possible that the evaporator and the liquefier can be arranged along an axis, wherein the liquefier may be arranged above the evaporator, as it has been explained, whereas an inverted arrangement may, however, be used depending on the implementation, but with the advantages of the large expanders still remaining.


Although it is of advantage to operate the heat pump with water as the working fluid, many described embodiments are also achieved with other working liquids that are different from water in that the evaporation pressure, and hence the liquefier pressure, are higher altogether.


Although the heat pump has been described such that the heating flow 531 and the heating return 532 directly heat a floor heating system, for example, i.e. an object to be heated, a heat exchanger such as a plate heat exchanger may be provided alternatively such that a heating cycle is decoupled from the liquefied working fluid in the working fluid space in terms of liquid.


Depending on the implementation, it is of advantage to produce the heat pump, and substantial elements thereof, in plastics injection-molding technology, for cost reasons in particular. Here, arbitrarily-shaped fixtures of the up-flow pipe on the wall of the liquefier, or the process water tank on the liquefier, or of heat exchangers in the process water tank, or of special shapes of the second intermediate cooler 440, in particular, may be achieved. In particular, the mounting of the motors on the radial wheels may also take place in one operation process, such that the motor housing is injection-molded integrally with the up-flow pipe, with then only the radial wheel being “inserted” in the completely molded liquefier, and particularly in the stationary motor part, without still necessitating many additional mounting steps for this.


While this invention has been described in terms of several embodiments, there are alterations, permutations, and equivalents which fall within the scope of this invention. It should also be noted that there are many alternative ways of implementing the methods and compositions of the present invention. It is therefore intended that the following appended claims be interpreted as including all such alterations, permutations, and equivalents as fall within the true spirit and scope of the present invention.

Claims
  • 1. A liquefier for a heat pump, comprising: a liquefier space formed to hold liquefied working fluid;a compressor motor with a motor body comprising a stationary motor part, a motor shaft, and a compressor wheel connected to the motor shaft; anda motor fixture for holding the motor body;wherein the compressor wheel extends into a region in which a channel for gaseous working fluid to be compressed passes,wherein the motor fixture is formed as a pipe having an inner wall and an outer wall, the inner wall of the pipe defining an interior region of the pipe and the outer wall of the pipe defining an exterior region of the pipe, wherein the motor body is held by at least two mounting fins extending between the inner wall of the pipe and the motor body within the interior region of the pipe, and wherein the inner wall of the pipe, the motor body and the mounting fins within the interior region of the pipe are surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space, andwherein the pipe being the motor fixture is mounted within the liquefier space by a support construction, wherein the outer wall of the pipe and the support construction is surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space.
  • 2. The liquefier according to claim 1, wherein the pipe is formed as an up-flow conduit in the liquefier space, wherein the liquefier is formed so that a flow directed opposite to a heat gradient of warm liquefied working fluid to cold liquefied working fluid in the liquefier space can be generated in the up-flow conduit.
  • 3. The liquefier according to claim 1, wherein a circulation pump formed to generate a flow in the pipe is arranged in the pipe, so that at least part of the motor body is arranged in a flow of liquefied working fluid.
  • 4. The liquefier according to claim 1, wherein the motor body comprises at least one cooling fin surrounded by the liquefied working fluid, which is present in addition to a mounting fin, or wherein at least one mounting fin also is formed as a cooling fin with a cooling function.
  • 5. The liquefier according to claim 1, further comprising: a further compressor motor for a multi-stage compressor with a further stationary motor part, a motor shaft, and a compressor wheel connected to the motor shaft, andwherein the motor fixture is formed to hold the further stationary motor part of the further compressor motor.
  • 6. The liquefier according to claim 5, wherein the motor body of the motor is arranged at a bottom end of the pipe and the further stationary motor part of the further motor at a top end thereof.
  • 7. The liquefier according to claim 1, wherein the motor shaft extends through a wall of the liquefier space, wherein a channel for the gaseous working fluid is adjacent to the wall of the liquefier space, and wherein the motor shaft is sealed with respect to the wall so that the motor shaft can rotate, but substantially no liquefied working fluid enters the channel from the liquefier space.
  • 8. The liquefier according to claim 1, wherein the motor shaft extends through a member within the liquefier, wherein the member divides a gas channel from a liquid region, wherein the motor shaft is sealed with respect to the member.
  • 9. The liquefier according to claim 1, wherein the pipe comprises a circular cross-section and comprises a plane surface on its outer wall.
  • 10. The liquefier according to claim 1, wherein the compressor wheel is a radial wheel.
  • 11. The liquefier according to claim 10, wherein the radial wheel comprises a plurality of blades and is formed so that a suction direction is different from an expulsion direction.
  • 12. The liquefier according to claim 1, wherein the motor is an electric motor.
  • 13. The liquefier according to claim 1, wherein the pipe comprises a foot portion, which is pierced to allow for a flow from the liquefier space into the pipe, wherein the pipe is fixedly connected to a wall of the liquefier space by the suspensions, the suspensions being formed at locations at which there are no breakthrough openings for the flow.
  • 14. A heat pump, comprising: a liquefier for a heat pump, comprising: a liquefier space formed to hold liquefied working fluid;a compressor motor with a motor body comprising a stationary motor part, a motor shaft, and a compressor wheel connected to the motor shaft;a motor fixture for holding the motor body,wherein the compressor wheel extends into a region in which a channel for gaseous working fluid to be compressed passes,wherein the motor fixture is formed as a pipe having an inner wall and an outer wall, the inner wall of the pipe defining an interior region of the pipe and the outer wall of the pipe defining an exterior region of the pipe, wherein the motor body is held by at least two mounting fins extending between the inner wall of the pipe and the motor body within the interior region of the pipe, and wherein the motor body and the mounting fins within the interior region of the pipe are surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space, so that a motion of the liquefied working fluid due to a vibration of the motor body is limited to the interior region of the pipe, andwherein the pipe is mounted within the liquefier space by a support construction, wherein the outer wall of the pipe and the support construction is surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space andan evaporator, wherein the evaporator is arranged below the liquefier in a setup direction of the heat pump.
  • 15. A method of manufacturing a liquefier for a heat pump, the liquefier comprising a liquefier space formed to hold liquefier working fluid; a compressor motor with a motor body comprising a stationary motor part, a motor shaft and a compressor wheel connected to the motor shaft; and a motor fixture for holding the stationary motor part, wherein the compressor wheel extends into a channel for gaseous working fluid to be compressed, comprising: forming the motor fixture as a pipe having an inner wall and an outer wall, the inner wall of the pipe defining an interior region of the pipe and the outer wall of the pipe defining an exterior region of the pipe, wherein the motor body is held by at least two mounting fins extending between the inner wall of the pipe and the motor body within the interior region of the pipe, and wherein the motor body and the mounting fins within the interior region of the pipe are surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space, so that a motion of the liquefied working fluid due to a vibration of the motor body is limited to the interior region of the pipe, wherein the pipe is mounted within the liquefier space by a support construction, wherein the outer wall of the pipe and the support construction is surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space.
  • 16. A liquefier for a heat pump, comprising: a liquefier space formed to hold liquefied working fluid;a compressor motor with a stationary motor part, a motor shaft, and a compressor wheel connected to the motor shaft; anda motor fixture for holding the stationary motor part, wherein the motor fixture is formed to hold the stationary motor part so that the stationary motor part is in contact with the liquefied working fluid when the liquefied working fluid is filled into the liquefier space;wherein the compressor wheel extends into a region in which a channel for gaseous working fluid to be compressed passes,wherein the motor fixture is formed as a pipe having an interior region, wherein the stationary motor part is held by at least two mounting fins within the interior region of the pipe, and wherein the interior region of the pipe is at least partially filled with the liquefied working fluid when the liquefied working fluid is filled into the liquefier space, andwherein the at least two mounting fins are surrounded by the liquefied working fluid when the liquefied working fluid is filled into the liquefier space.
Priority Claims (1)
Number Date Country Kind
10 2008 016 627 Apr 2008 DE national
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/EP2009/002313 3/30/2009 WO 00 12/28/2010
Publishing Document Publishing Date Country Kind
WO2009/121547 10/8/2009 WO A
US Referenced Citations (19)
Number Name Date Kind
1797287 Kucher Mar 1931 A
RE19908 Kucher Mar 1936 E
2214086 Rataiczak Sep 1940 A
2314591 McCormack Mar 1943 A
2575325 Ambrose et al. Nov 1951 A
3260067 McClure et al. Jul 1966 A
3342039 Bridge Sep 1967 A
4000777 Laing Jan 1977 A
4459820 Giuffrida Jul 1984 A
4573324 Tischer et al. Mar 1986 A
4903497 Zimmern et al. Feb 1990 A
6397621 Reynaud Jun 2002 B1
6499942 Nonaka Dec 2002 B1
7866179 Ophir Jan 2011 B2
20070245759 Sedlak Oct 2007 A1
20080016907 Barclay et al. Jan 2008 A1
20100064697 Sedlak Mar 2010 A1
20110117511 Harman May 2011 A1
20140075978 Sedlak Mar 2014 A1
Foreign Referenced Citations (14)
Number Date Country
3014029 Oct 1981 DE
3103508 Oct 1982 DE
0306405 Mar 1989 EP
2071294 Sep 1981 GB
S5026455 Mar 1975 JP
61-217662 Sep 1986 JP
S61217662 Sep 1986 JP
H02-267480 Jan 1990 JP
H08-509802 Oct 1996 JP
2001165514 Jun 2001 JP
2002-532221 Oct 2002 JP
2005-241204 Sep 2005 JP
2006147706 Jun 2006 JP
2006-258397 Sep 2006 JP
Non-Patent Literature Citations (2)
Entry
English Translation of Office Action, dated Mar. 3, 2009, in related German patent application No. 102008016627.8-13, 3 pages.
International Search Report and Written Opinion, dated Oct. 6, 2009, in related PCT patent application No. PCT/EP2009/002313, 15 pages.
Related Publications (1)
Number Date Country
20110100054 A1 May 2011 US