Embodiments of the disclosure relate generally to fire suppression. Embodiments of the disclosure relate to fire suppression apparatuses having a gas generator and a cooling system and to methods of using such fire suppression apparatuses to suppress a fire. Embodiments of the disclosure also relate to methods of cooling a fire suppressant gas using a liquid coolant.
In the past, Halon halocarbons have found extensive application in connection with fire suppression. The term “Halon halocarbons” generally refers to haloalkanes, or halogenoalkanes, a group of chemical compounds consisting of alkanes with linked halogens and, in particular, to bromine-containing haloalkanes. Halon halocarbons are generally efficient in extinguishing most types of fires, desirably are electrically non-conductive, tend to dissipate rapidly without residue formation and to be relatively safe for limited human exposure. In the past, Halon halocarbons, such as the halocarbon Halon 1301 (bromotrifluoromethane, CBrF3), have found utility as fire suppressants in or for areas or buildings typically not well suited for application of water sprinkler systems, areas such as data and computer centers, museums, libraries, surgical suites and other locations where application of water-based suppressants can result in irreparable damage to electronics, vital archival collections, or the like.
Halon halocarbons, however, have been found to have a detrimental impact on the environment due to an ozone depleting aspect with respect to the atmosphere.
Fire suppression apparatuses are disclosed, including a housing having gas generant material disposed therein, an initiator configured to ignite at least a portion of the gas generant material to form gas, and a cooling system disposed adjacent the housing. The cooling system includes a first chamber with a coolant material disposed therein and a second chamber. Upon actuation, at least a portion of the coolant material flows from the first chamber into the second chamber to mix with and cool the gas formed by the ignition of the gas generant material. In some embodiments, the fire suppression apparatus further includes a piston disposed within the first chamber of the cooling system, the piston being movable within the first chamber to pressurize the coolant material and flow the coolant material from the first chamber into the second chamber. The coolant material may be a liquid.
Methods for suppressing a fire with a fire suppression apparatus are disclosed, including igniting a gas generant material to form a fire suppressant gas, flowing the fire suppressant gas into first and second chambers of a cooling system, and flowing a coolant material from the first chamber into the second chamber by forcing a piston to move in the first chamber with the fire suppressant gas. The coolant material may mix with and cool the fire suppressant gas. The mixture of the coolant material and the fire suppressant gas may be directed toward a fire.
Methods for cooling a fire suppressant gas are also disclosed, including flowing a fire suppressant gas into a first and second chamber, moving a piston operatively disposed in the first chamber by pushing against the piston with the fire suppressant gas, flowing a coolant material from the first chamber into the second chamber by pushing against the coolant material with the piston, and mixing the coolant material and the fire suppressant gas in the second chamber.
A gas generant material 52 may be disposed within the generator housing 22 for generating a gas (e.g., a fire suppressant gas). Materials that may be used for the gas generant material 52 include, for example, materials known in the art of inflatable vehicular occupant safety restraint systems (e.g., airbag systems). Compositions suitable for gas generant material 52 are known to those of ordinary skill in the art and may differ depending upon the intended application for the generated gas. For use in fire suppression, particularly for human-occupied areas, the gas generant material 52 of gas generant wafers 66 may be an HACN composition, as disclosed in U.S. Pat. Nos. 5,439,537, 5,673,935, 5,725,699, and 6,039,820 to Hinshaw et al., the disclosure of each of which patents is incorporated by reference herein. The HACN used in the gas generant material 52 may be recrystallized and include less than approximately 0.1% activated charcoal or carbon. By maintaining a low amount of carbon in the gas generant material 52, the amount of carbon-containing gases, such as CO, CO2, or mixtures thereof, may be minimized upon combustion of the gas generant material 52. Alternatively, a technical grade HACN having up to approximately 1% activated charcoal or carbon may be used. It is also contemplated that conventional gas generant materials that produce gaseous combustion products that do not include carbon-containing gases or NOx may also be used.
The HACN composition, or other gas generant material 52, may include additional ingredients, such as at least one of an oxidizing agent, ignition enhancer, ballistic modifier, slag enhancing agent, cooling agent, a chemical fire suppressant, inorganic binder, or an organic binder. By way of example, the HACN composition may include at least one of cupric oxide, titanium dioxide, guanidine nitrate, strontium nitrate, and glass. Many additives used in the gas generant material 52 may have multiple purposes. For sake of example only, an additive used as an oxidizer may provide cooling, ballistic modifying, or slag enhancing properties to the gas generant material 52. The oxidizing agent may be used to promote oxidation of the activated charcoal present in the HACN or of the ammonia groups coordinated to the cobalt in the HACN. The oxidizing agent may be an ammonium nitrate, an alkali metal nitrate, an alkaline earth nitrate, an ammonium perchlorate, an alkali metal perchlorate, an alkaline earth perchlorate, an ammonium peroxide, an alkali metal peroxide, or an alkaline earth peroxide. The oxidizing agent may also be a transition metal-based oxidizer, such as a copper-based oxidizer, that includes, but is not limited to, basic copper nitrate ([Cu2(OH)3NO3]) (“BCN”), Cu2O, or CuO. In addition to being oxidizers, the copper-based oxidizer may act as a coolant, a ballistic modifier, or a slag enhancing agent. Upon combustion of the gas generant 52, the copper-based oxidizer may produce copper-containing combustion products, such as copper metal and cuprous oxide, which are miscible with cobalt combustion products, such as cobalt metal and cobaltous oxide. These combustion products produce a molten slag, which fuses at or near the burning surface of the wafer 66 and prevents particulates from being formed. The copper-based oxidizer may also lower the pressure exponent of the gas generant material 52, decreasing the pressure dependence of the burn rate. Typically, HACN-containing gas generants material that include copper-based oxidizers ignite more readily and burn more rapidly at or near atmospheric pressure. However, due to the lower pressure dependence, they burn less rapidly at extremely high pressures, such as those greater than approximately 3000 psi.
The gas generant material 52 may, by way of example, be a solid material that is formed as wafers 66 that are generally cylindrical. The wafers 66 of gas generant material 52 may each have one or more holes therethrough to provide improved ignition of the gas generant material 52 and increased gas flow through the gas generator 20 upon actuation thereof. The wafers 66 of gas generant material 52 may be arranged in one or more stacks, as shown in
Referring to
As shown in
Referring again to
Although a particular embodiment of a gas generator 20 is shown with reference to
As can be seen in
Although the views of
Referring now to
The cooling system 100 may include a second chamber 120 defined at least in part by a second housing 122. The second housing 122 may optionally include a flange 123 for connection to the gas generator 20. A plate 124 with at least one opening 126 therethrough may be disposed within the second housing 122. The second housing 122 may include at least one opening 140 for discharging fire suppressant gas therethrough, such as to suppress a fire.
As can be seen in
Various materials may be used as the coolant material 130. In one embodiment, the coolant material 130 may include at least one endothermically alterable material. The endothermically alterable material may include a liquid that may vaporize and/or decompose upon contact with the fire suppressant gas generated by the ignition of the gas generant 52, which may cool the fire suppressant gas.
In some embodiments, the endothermically alterable material may endothermically decompose and/or vaporize to form additional gaseous products, thus increasing the resulting quantity of gaseous products. Such an increase in the quantity of gaseous products may reduce the quantity of the gas generant material 52 required for proper functioning of the fire suppression apparatus. By reducing the required quantity of gas generant material 52, the size of the gas generator 20 of the fire suppression apparatus may be reduced, thus reducing the cost and/or size of the fire suppression apparatus and/or increasing the fire suppression capability of the fire suppression apparatus.
Suitable coolant materials 130 may include liquid materials that remain a liquid at ambient temperatures in which the fire suppression apparatus may operate (e.g., between about −35° C. and about 85° C.). Furthermore, any products formed from the coolant material 130 may be within acceptable effluent limits associated with particular fire suppression applications. Also, the coolant material 130 may be non-corrosive to facilitate storage in the first chamber 110. Examples of coolant materials 130 that generally meet such criteria include water mixed with calcium chloride (CaCl2) and water mixed with propylene glycol.
In addition to or as a part of the coolant material 130, the first chamber 110 may include one or more active fire suppression compounds that are generally useful for suppressing a fire upon contact therewith. Examples of chemically active fire suppression compounds that may be used include potassium acetate and alkali metal bicarbonates.
For example, a solution of 30% by weight potassium acetate in water can reduce the quantity of gas generant 52 required and generator housing 22 size and weight of a subject fire suppression apparatus by about 40% without significantly changing either the size of the first chamber 110 or the fire suppression capability of the fire suppression apparatus, as compared to an otherwise similar apparatus lacking the potassium acetate solution.
Another embodiment of a cooling system 200 of a fire suppression apparatus of the present disclosure is shown in
The cooling system 200 may operate in a similar manner to that described with reference to
Although
Referring to
As can be seen in
The present disclosure includes methods for cooling a fire suppressant gas. A fire suppressant gas may be flowed into a first chamber and a second chamber of a cooling system. The first chamber and the second chamber may be proximate each other. The fire suppressant gas may push against a piston in the first chamber to move the piston, causing a coolant material within the first chamber to flow from the first chamber into the second chamber. The coolant material may mix with the fire suppressant gas in the second chamber to cool the fire suppressant gas. The cooling of the fire suppressant gas may occur as described above with reference to any of
The present disclosure also includes methods for suppressing a fire. Such methods may include generating a fire suppressant gas with a gas generant material, as described above, and cooling the fire suppressant gas. The fire suppressant gas may be cooled by flowing the fire suppressant gas through a cooling system. The fire suppressant gas may force a coolant material to flow from a first chamber into a second chamber to mix with and cool the fire suppressant gas. In some embodiments, the fire suppressant gas may force a piston to move within the first chamber to pressurize the coolant material and flow it through a nozzle or an opening into the second chamber. After the coolant material and the fire suppression gas mix, the resulting mixture may be discharged from the second chamber. The mixture may be directed toward a fire and/or discharged in a space in which a fire exists to suppress the fire. The fire suppressant gas may be generated as described above with reference to
While the disclosure is susceptible to various modifications and alternative forms, specific embodiments have been shown by way of example in the drawings and have been described in detail herein. However, the disclosure is not intended to be limited to the particular forms disclosed. Rather, the disclosure encompasses all modifications, combinations, equivalents, and alternatives falling within the scope of the invention as defined by the following appended claims and their legal equivalents.
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