Claims
- 1. A composition comprising:70-99% by weight of at least one (chlorinated) organotin compound, 1-30% by weight of at least one (halo) polyfluoroalkenyl compound, and optionally an organic solvent.
- 2. The composition of claim 1, wherein said at least one (chlorinated) organotin compound is a compound of the formulaRxSnCl(4-x) wherein x is an integer of 1-4 and R is a C1-8 alkyl or alkenyl group, or a phenyl radical.
- 3. The composition of claim 2, where R is butyl and X is 1.
- 4. A method of preparing a fluorine-doped tin oxide film on a substrate, comprising contacting a hot substrate with the composition of claim 3 in the vapor state, wherein said substrate is at a temperature of ≧400° C.
- 5. A fluorine-doped tin oxide film prepared according to the method of claim 4.
- 6. The method of claim 4, wherein said film has a thickness of 500 to 9000 Å, a sheet resistance of 5-250 ohms/square, greater than 70% visible light transmittance and 0 to 20% haze measured as light defused/total light transmitted.
- 7. The method of claim 4, wherein said film has a thickness of 500 to 9000 Å, a sheet resistance of 5-250 ohms/square, greater than 70% visible light transmittance and 0 to 20% haze measured as light defused/total light transmitted.
- 8. A method of preparing a fluorine-doped tin oxide film on a substrate, comprising contacting a hot substrate with the composition of claim 2 in the vapor state, wherein said substrate is at a temperature of ≧400° C.
- 9. A fluorine-doped tin oxide film prepared according to the method of claim 8.
- 10. The method of claim 9, wherein said film has a thickness of 500 to 9000 Å, a sheet resistance of 5-250 ohms/square, greater than 70% visible light transmittance and 0 to 20% haze measured as light defused/total light transmitted.
- 11. The method of claim 8, wherein said first has a thickness of 500 to 9000 Å, a sheet resistance of 5-250 ohms/square, greater than 70% visible light transmittance and 0 to 20% haze measured as light defused/total light transmitted.
- 12. The composition of claim 1, wherein said at least one (halo) polyfluoroalkenyl compound has the following formula:CnFmXoHp where n is 4-25, m is 1-30, o is 0-30, p is 0-52, and X is halogen other than fluorine.
- 13. The composition of claim 12, wherein n is 4 to less than 25 and m is 2-30.
- 14. The composition of claim 1, comprising organic solvent.
- 15. A method of preparing a fluorine-doped tin oxide film on a substrate, comprising contacting a hot substrate with the composition of claim 1 in the vapor state, wherein said substrate is at a temperature of ≧400° C.
- 16. A fluorine-doped tin oxide film prepared according to the method of claim 13.
- 17. The film of claim 16, wherein said film has a thickness of 500 to 9000 Å, a sheet resistance of 5-250 ohms/square, greater than 70% visible light transmittance and 0 to 20% haze measured as light defused/total light transmitted.
- 18. The method of claim 15, wherein said film has a thickness of 500 to 900 Å, a sheet resistance of 5-250 ohms/square, greater than 70% visible light transmittance and 0 to 20% haze a slight defused/total light transmitted.
- 19. The composition of claim 1, comprising an organic solvent in an amount up to 29 weight %.
- 20. The composition of claim 1, wherein said at least one (halo) polyfluoroalkenyl compound has a linear, branched or cyclic structure.
Parent Case Info
This is a continuation of Ser. No. 09/557,792 filed Apr. 25, 2000 now abandoned which is a continuation of Ser. No. 08/113,196 filed Jul. 10, 1998
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
4590096 |
Lindner |
May 1986 |
A |
Continuations (2)
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Number |
Date |
Country |
Parent |
09/557772 |
Apr 2000 |
US |
Child |
10/145121 |
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US |
Parent |
09/113196 |
Jul 1998 |
US |
Child |
09/557772 |
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US |