Patent Application
20180044592
The present invention relates to the liquid crystal field, and particularly relates to a liquid crystal composition and use thereof in the liquid crystal display field.
Currently, liquid crystal has been widely applied in the information display field, and has also made some progress in optical communication applications. In recent years, the application field of liquid crystal compounds has been significantly broadened to various types of display devices, electro-optical devices, electronic components, sensors and the like. Nematic liquid crystal compounds have been most widely used in flat panel displays, particularly in TFT active matrix systems.
Liquid crystal display has gone through a long path of development since the discovery of liquid crystals. Particularly since the seventies, due to the development of large-scale integrated circuits and liquid crystal materials, the application of liquid crystals has made a breakthrough development in terms of display. Super Twisted Nematic (STN) mode proposed successively by T. Scheffer et al. in 1983-1985 and an Active Matrix (AM) mode proposed by P. Brody in 1972 were re-adopted. Conventional TN-LCD technology has been developed into STN-LCD and TFT-LCD technologies. Although the number of STN scanning lines can reach 768 or greater, there are still problems, such as response speed, viewing angle and gray scale, when the temperature rises. Therefore, for a large area, high information content, color display, an active matrix display mode becomes the first choice.
There are two types of “active matrix” including: 1. a metal oxide semiconductor (MOS) on a silicon wafer as a substrate; and 2. a thin film transistor (TFT) on a glass plate as a substrate.
Monocrystalline silicon as a substrate material limits the display size due to the fact that there were many problems occurring at junctions of each part of a display device or even a module assembly. Accordingly, the second type of thin film transistor is a promising active matrix type. The photoelectric effect utilized is generally the TN effect. A TFT includes a compound semiconductor, such as CdSe, or a TFT based on polycrystalline silicon or amorphous silicon.
Currently, the LCD product technologies have been well established and successfully solved technical problems regarding the viewing angle, resolution, color saturation, brightness, etc., and the display performance thereof has been close to or superior to that of CRT displays. Large-size and small-to-medium-size LCDs have gradually dominated the flat panel displays in respective fields. However, due to the limitation of (the high viscosity of) the liquid crystal material itself, the response time becomes a principal factor affecting high-performance displays.
In particular, the response time of a liquid crystal is limited by the rotational viscosity γ1 and the elastic constant of the liquid crystal. Therefore, reducing the rotational viscosity of a liquid crystal composition and increasing the elastic constant have a significant effect on reducing the response time of the liquid crystal display and accelerating the response speed of the liquid crystal display.
An object of the present invention is to provide a liquid crystal composition, and the liquid crystal composition has a low rotational viscosity and a large elastic constant, and is presented as having a shorter response time, so that the problem of the slow response of the liquid crystal display is effectively solved.
In order to achieve the above object, the following technical solution is specifically adopted:
a liquid crystal composition, comprising, in percentages by weight, 5-40% of one or more compounds represented by general formula I, 2-30% of one or more compounds represented by general formula II, and 20-70% of one or more compounds represented by general formula III; preferably comprising 9-30% of one or more compounds represented by general formula I, 3-26% of one or more compounds represented by general formula II, and 36-67% of one or more compounds represented by general formula III,
wherein R1 independently represents a C1-C12 linear alkyl group or a C2-C12 linear alkenyl group; R2 independently represents a C1-C12 linear alkyl group, a C1-C12 linear alkoxy group or a C2-C12 linear alkenyl group; R4 and R5 each independently represent an unsubstituted C1-C12 linear alkyl group or a C1-C12 linear alkyl group having one or more non-adjacent CH2 substituted with O, S or CH═CH;
X1 independently represents F, Cl, CN, a C1-C12 linear alkyl group, a C1-C12 linear alkoxy group or a C2-C12 linear alkenyl group;
Z1 and Z2 each independently represent a single bond or an acetylenic bond, with at least one of Z1 and Z2 being an acetylenic bond;
L1 independently represents H or F;
A1, A2 and A3 each independently represent:
A4 independently represents:
A5 and A6 each independently represent a trans-1,4-cyclohexylene group or a 1,4-phenylene group; and
m and n each independently represent 0 or 1.
The liquid crystal composition of the present invention further comprises 0-30% by weight of a compound represented by general formula IV, preferably 4-30% by weight of a compound represented by general formula IV, and more preferably 4-24% by weight of a compound represented by general formula IV,
wherein R6 and R7 each independently represent a C1-C12 linear alkyl group or a C1-C12 linear alkyl group having one or more non-adjacent CH2 substituted with O, S or CH═CH; and
A7 is selected from one of the following structures:
The liquid crystal composition of the present invention further comprises 0-30% by weight of compounds represented by general formulas V to IX, preferably 5-25% by weight of compounds represented by general formulas V to IX,
wherein R10 independently represents a C1-C12 linear alkyl group or a C2-C12 linear alkenyl group; R8, R9 and R11-R13 each independently represent a C1-C12 linear alkyl group; X2-X5 each independently represent F, CF3, OCF3 or OCF2H; L2-L9 each independently represent H or F; and
A8 and A9 each independently represent:
As an embodiment, the liquid crystal composition of the present invention comprises, in percentages by weight, 9-12% of one or more compounds represented by general formula I, 5-26% of one or more compounds represented by general formula II, 60-67% of one or more compounds represented by general formula III, and 5-24% of one or more compounds represented by general formula IV.
As another embodiment, the liquid crystal composition of the present invention comprises, in percentages by weight, 14-30% of one or more compounds represented by general formula I, 3-9% of one or more compounds represented by general formula II, 30-50% of one or more compounds represented by general formula III, 4-18% of one or more compounds represented by general formula IV, and 9-25% (preferably 9-23%) of one or more compounds represented by general formulas V to IX.
In the above-mentioned “one or more compounds represented by general formulas V to IX”, where only one compound is selected, it is preferred to select compound VII or V, and the range of the amount thereof is suitably 9-15%; where a mixture of two compounds is selected, compounds VII and V are preferred, and the range of the amount thereof is suitably 9-23%; and where a mixture of three compounds is selected, compounds V, VIII and IX, or compounds V, VII and IX are preferred, and the range of the amount thereof is suitably 15-25%.
The compound represented by general formula I provided by the present invention is a polar compound containing a 2-methyl-3,4,5-trifluorobenzene structure and a difluoromethoxy bridge bond, the structure having a large dielectric anisotropy.
Particularly, the compound represented by general formula I is selected from one or more of the compounds represented by formulas I-A to I-U:
wherein R1 independently represents a C1-C7 linear alkyl group.
Preferably, the compound represented by general formula I is selected from one or more of the compounds represented by formulas I-A-1 to I-U-4:
more preferably, the compound represented by general formula I is selected from one or more of formulas I-F-2, I-F-3, I-G-2, I-G-4, I-P-1, I-P-2, I-R-2, I-R-3, I-U-2 and I-U-4.
The acetylenic compound represented by general formula II provided by the present invention has a high optical anisotropy, and plays a significant role in increasing the optical anisotropy of the composition.
Particularly, the compound represented by general formula II is selected from one or more of formulas II-A to II-D:
wherein R2 independently represents a C1-C7 linear alkyl group or a C2-C7 linear alkenyl group; and R3 independently represents a C1-C7 linear alkyl group, a C1-C7 linear alkoxy group or a C2-C7 linear alkenyl group.
Preferably, the compound represented by general formula II is selected from one or more of formulas II-A-1 to II-D-16:
more preferably, the compound represented by general formula II is selected from one or more of formulas II-A-1, II-A-6, II-A-10, II-A-35, II-C-3 and II-C-6.
The compound represented by general formula III provided by the present invention has a bicyclic structure, and particularly, the compound represented by general formula III is selected from one or more of the following compounds:
wherein R4 independently represents a C1-C7 linear alkyl group; and R5 independently represents a C1-C7 linear alkyl group or linear alkoxy group or a C2-C7 linear alkenyl group.
Preferably, the compound represented by general formula III is selected from one or more of the compounds represented by formulas III-A-1 to III-C-24:
More preferably, the compound represented by general formula III is selected from one or more of formulas III-A-1, III-A-2, III-A-4, III-A-5 and III-C-4.
Particularly, the compound represented by general formula IV is selected from one or more of the following compounds of formulas IV-A to IV-C:
wherein R6 independently represents a C2-C10 linear alkyl group or linear alkenyl group; and R7 independently represents a C1-C8 linear alkyl group.
Preferably, the compound represented by general formula IV is selected from one or more of the structures of formulas IV-A-1 to IV-C-30:
More preferably, the compound represented by general formula IV is selected from one or more of formulas IV-A-1, IV-A-2, IV-A-5, IV-A-8, IV-A-12, IV-B-1 and IV-B-3.
Preferably, the compounds of general formulas V to IX are selected from one or more of formulas V-A to IX-N:
wherein R10 independently represents a C2-C7 linear alkyl group or linear alkenyl group; and R8, R9 and R11-R13 each independently represent a C2-C7 linear alkyl group.
The technical features of the invention lie in: since compounds of type I have a strong dielectric anisotropy, compounds of type II have a large optical anisotropy, and compounds of type IV have a high clearing point and a large K-value characteristic, the use of these three types of compounds can adjust the physical parameter properties of the liquid crystal composition; moreover, the compounds of type III have a significant effect in reducing the viscosity of the system and increasing the response speed, and are a class of compounds that are essential for formulating fast-response liquid crystal mixtures. The combined use of the above-mentioned compounds can effectively reduce the rotational viscosity of the mixed liquid crystal, improves related properties of the mixed liquid crystal, and thus reduces the response time thereof.
The method for preparing the liquid crystal composition of the present invention is not particularly limited, and the liquid crystal composition of the present invention may be produced by mixing two or more compounds using a conventional method, or may be prepared according to a conventional method.
The liquid crystal composition provided by the present invention simultaneously contains a 2-methyl-3,4,5-trifluorophenyl compound, an acetylenic compound and a non-polar bicyclic compound, has a low viscosity, high resistivity, suitable optical anisotropy, large elastic constant and excellent light stability and thermal stability, and can reduce the response time of the liquid crystal display, thereby solving the problem of a slow response speed of the liquid crystal display. In addition, the liquid crystal composition can effectively improve the contrast characteristics of IPS and FFS liquid crystal displays. Therefore, the liquid crystal composition provided by the present invention is suitable for fast-response TN, IPS and FFS-type TFT liquid crystal display devices, and is particularly suitable for IPS and FFS liquid crystal display devices.
The following examples are intended to illustrate the invention, but not to limit the scope of the invention.
Unless otherwise indicated, the percentage in the present invention is weight percentage; the temperature unit is degrees Celsius; Δn represents optical anisotropy (at 25° C.); Δ∉ represents dielectric anisotropy (at 25° C., 1000 Hz); V10 represents voltage threshold, and is the characteristic voltage (V, at 25° C.) when the relative transmittance is changed by 10%; γ1 represents rotational viscosity (mPa·S, at 25° C.); Cp represents the clearing point (° C.) of the liquid crystal composition; and K11, K22 and K33 represent splay, twist and bend elastic constants (pN, at 25° C.), respectively.
In each of the following examples, the group structures in the liquid crystal compound are represented by the codes shown in Table 1.
Taking the following compound structures as an example:
is represented as 4CDUQKF, and
is represented as 5CCPUF
In each of the following examples, the liquid crystal compositions are all prepared by a thermal dissolution method, comprising the following steps of: weighing liquid crystal compounds in percentage by weight using a balance, wherein the order of weighing and addition is not particularly specified, and usually, the weighing and mixing are carried out successively in order of the melting points of the liquid crystal compounds from high to low; heating and stirring same at 60-100° C. so that each component is melted uniformly; then subjecting same to filtration and rotary evaporation; and finally performing encapsulation to obtain a target sample.
In each of the following examples, the weight percentage of each component in the liquid crystal composition and the performance parameters of the liquid crystal composition are shown in the following tables.
The values of the performance parameters of the liquid crystal compositions obtained in example 1 and comparative example 1 are summarized and compared, and reference can be made to table 14.
Upon comparison, it can be seen that, as compared with comparative example 1, the liquid crystal composition provided in example 1 has a low rotational viscosity and a large elastic constant, and therefore has a shorter response time and a faster response speed.
The values of the performance parameters of the liquid crystal compositions obtained in example 9 and comparative example 2 are summarized and compared, and reference can be made to table 16.
Upon comparison, it can be seen that, as compared with comparative example 2, the liquid crystal composition provided in example 9 has a low rotational viscosity and a large elastic constant, and therefore has a shorter response time and a faster response speed.
Although the present invention has been described in detail with general explanations and specific embodiments, it is obvious to a person skilled in the art that some modifications or improvements can be made thereto based on the present invention. Therefore, all these modifications and improvements which can be made without departing from the scope of the present invention belong to the scope claimed in the invention.
The liquid crystal composition provided by the present invention simultaneously contains a 2-methyl-3,4,5-trifluorophenyl compound, an acetylenic compound and a non-polar bicyclic compound, has a low viscosity, high resistivity, suitable optical anisotropy, large elastic constant and excellent light stability and thermal stability, and can reduce the response time of the liquid crystal display, thereby solving the problem of a slow response speed of the liquid crystal display. In addition, the liquid crystal composition can effectively improve the contrast characteristics of IPS and FFS liquid crystal displays. Therefore, the liquid crystal composition provided by the present invention is suitable for fast-response TN, IPS and FFS-type TFT liquid crystal display devices, and has broad application prospects and a good industrial applicability in the liquid crystal display field.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2015101119008 | Mar 2015 | CN | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/CN2015/095740 | 11/27/2015 | WO | 00 |
