Patent Grant
11555151
The present invention relates to the field of liquid crystal display, in particular to a liquid crystal composition and a liquid crystal display element or liquid crystal display containing the liquid crystal composition.
According to the display mode, LCD can be divided into the following modes: twisted nematic (TN) mode, super twisted nematic (STN) mode, coplanar mode (IPS), vertical alignment (VA) mode. The liquid crystal composition is required to have the following characteristics regardless of the display mode:
(1) stable chemical and physical properties; (2) low viscosity; (3) suitable dielectric Δε; (4) suitable refractive index Δn; (5) good miscibility with other liquid crystal compounds.
Early commercial TFT-LCD products basically adopt TN display mode, and its biggest problem is narrow viewing angle. With the increase of product size, especially in the field of TV, IPS display mode and VA display mode with wide view angle are developed and applied in turn.
However, the liquid crystal medium used in the display elements of FFS mode, IPS mode and VA mode is not perfect. For the liquid crystal materials used in the display devices, it is required to have {circle around (1)} low driving voltage: the liquid crystal material has appropriate negative dielectric anisotropy and elastic coefficient K; {circle around (2)} fast response: the liquid crystal material has appropriate rotational viscosity γ1 and elastic coefficient K; {circle around (3)} high reliability: high charge retention, high specific resistance, excellent high temperature stability and strict requirements for the stability of UV light or conventional backlight lighting. With the development of LCD (liquid crystal display) technology, the response speed of LCD products is required to be higher and higher. The response speed of liquid crystal materials in the prior art is limited by the rotational viscosity γ1/elastic constant K of liquid crystals. Therefore, in order to achieve rapid response, it is necessary to try every means to reduce the rotational viscosity γ1 of liquid crystal materials and increase its elastic constant K. However, it is found that the rotational viscosity and the elastic constant are closely related parameters. When the rotational viscosity is reduced, the elastic constant will decrease, so the response time can not be reduced.
At present, the liquid crystal composition with excellent response speed and various poor displays is still expected to be obtained. Especially in VA mode and other modes, the liquid crystal medium used in the display element is negative dielectric anisotropy. Compared with the liquid crystal medium with positive dielectric anisotropy, it has the disadvantages of smaller dielectric, slower response time and higher driving voltage. Therefore, it is desirable to obtain a negative dielectric anisotropy liquid crystal medium with an improved response time.
In order to solve at least one problem existing in the prior art, the object of the present invention is to provide a liquid crystal composition with negative dielectric anisotropy, which has higher optical anisotropy and lower γ1/K33, so as to have improved response time, thereby improving response speed and improving display quality when applied to display devices.
To achieve the above purpose, the present disclosure adopts the following technical solutions:
A liquid crystal composition with negative dielectric anisotropy is provided, which comprises:
a compound represented by formula I with a mass content of 1-10% as the first component;
a compound represented by formula II with mass content of 1-20% as the second component;
more than two compounds represented by formula III as the third component;
more than three compounds represented by formula IV as the fourth component; and,
one or more polymerizable compounds as the fifth component,
wherein,
R1, R2, R3 and R4 independently represent alkyl group having a carbon atom number of 1-10, fluoro-substituted alkyl group having a carbon atom number of 1-10, alkoxy group having a carbon atom number of 1-10, fluoro-substituted alkoxy group having a carbon atom number of 1-10, alkenyl group having a carbon atom number of 2-10, fluoro-substituted alkenyl group having a carbon atom number of 2-10, alkenoxy group having a carbon atom number of 3-8 or fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one —CH2— or several —CH2— that are not adjacent of the groups indicated by R1, R2, R3 and R4 are selectively substituted by cyclopentyl, cyclobutyl or cyclopropyl;
represents 1,4-cyclohexylidene or 1,4-Phenylene;
n represents 0 or 1.
The present disclosure also provides a liquid crystal display element or liquid crystal display, which comprises a liquid crystal composition of the present disclosure. The liquid crystal display element is an active matrix addressable display element or a liquid crystal display or a passive matrix addressing display element or a liquid crystal display.
Compared with the prior art, the liquid crystal composition of the present disclosure has lower rotational viscosity (γ1) and low γ1/K33 on the basis of maintaining appropriate optical anisotropy (Δn), and the liquid crystal display element or liquid crystal display apparatus containing the liquid crystal composition of the present disclosure has a faster response speed.
[Liquid Crystal Composition]
In one aspect, the liquid crystal composition of the present disclosure comprises: a compound represented by formula I with a mass content of 1-10% as the first component and a compound represented by formula II with a mass content of 1-20% as the second component, more than two compounds represented by formula III as the third component, more than three compounds represented by formula IV as the fourth component and one or more polymerizable compounds as the fifth component,
wherein,
R1, R2, R3 and R4 independently represent alkyl group having a carbon atom number of 1-10, fluoro-substituted alkyl group having a carbon atom number of 1-10, alkoxy group having a carbon atom number of 1-10, fluoro-substituted alkoxy group having a carbon atom number of 1-10, alkenyl group having a carbon atom number of 2-10, fluoro-substituted alkenyl group having a carbon atom number of 2-10, alkenoxy group having a carbon atom number of 3-8 or fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one —CH2— or several —CH2— that are not adjacent of the groups indicated by R1, R2, R3 and R4 are selectively substituted by cyclopentyl, cyclobutyl or cyclopropyl;
represents 1,4-cyclohexylidene or 1,4-Phenylene;
n represents 0 or 1.
For example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert butyl, n-amyl, isoamyl, hexyl, heptyl, octyl, nonyl, decyl, etc. can be listed as the alkyl groups with carbon atom number of 1-10.
For example, methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, pentoxy, hexoxy, hepthoxy, octyloxy, nonoxy, decaoxy, etc. can be listed as the alkoxy groups with the carbon atom number of 1˜10.
For example, vinyl, 1-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-Pentenyl, 1-hexenyl, 2-hexenyl, 3-Hexenyl, etc., can be listed as Alkenyl with carbon atom number of 2˜10.
For example, cyclopentyl, cyclobutyl, cyclopropyl, methylcyclopentyl, methylcyclobutyl, methylcyclopentyl, etc. can be listed as a group obtained by substituted any one —CH2- or several —CH2- that are not adjacent of the alkyl groups with carbon atom numbers from 1 to 10 by cyclopentyl, cyclobutyl or cyclopropyl.
In one embodiment of the liquid crystal composition of the present disclosure, the compounds represented by formula III are preferably selected from the group consisting of compounds represented by formula III-1˜III-7:
In another embodiment of the liquid crystal composition of the present disclosure, the compounds represented by formula IV are preferably selected from the group consisting of compounds represented by formula IV-1˜IV-9:
In another embodiment of the liquid crystal composition of the present disclosure, the polymerizable compound is preferably selected from the group consisting of formulas RM-1 to rm-8:
In the liquid crystal composition of the present disclosure, there is no special restriction on the contents of the compounds of the formula I, formula II, formula III, formula IV and polymerizable compound, and those skilled in the art can select the appropriate content of each component according to needs. Preferably, in the liquid crystal composition of the invention, the total mass content of the components other than polymerizable compounds is 100%, the mass content of the compounds represented by formula I in the liquid crystal composition is 1-10%, preferably 5-8%; the mass content of the compounds in the liquid crystal composition represented by formula II is 1-20%, preferably 15-20%; the total mass content of the compounds represented by formula III in the liquid crystal composition is 5-40%, preferably 16-25%; the total mass content of the compound represented by formula IV in the liquid crystal composition is 5-50%, preferably 10-40%; the polymerizable compound is added on the basis of the total mass of the remaining liquid crystal is 100%, and the added mass content of the polymerizable compound can be, for example 0.01-1%, preferably 0.03-0.2%.
In a further embodiment of the liquid crystal composition of the present disclosure, it is preferred that one or more compounds represented by formula V other than those of formula I and II are also included:
wherein, R5 and R6 independently represent alkyl group having a carbon atom number of 1-10, fluoro-substituted alkyl group having a carbon atom number of 1-10, alkoxy group having a carbon atom number of 1-10, fluoro-substituted alkoxy group having a carbon atom number of 1-10, alkenyl group having a carbon atom number of 2-10, fluoro-substituted alkenyl group having a carbon atom number of 2-10, alkenoxy group having a carbon atom number of 3-8 or fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one —CH2— or several —CH2— that are not adjacent of the groups indicated by R5 and R6 are selectively substituted by cyclopentyl, cyclobutyl or cyclopropylene;
4-cyclohexylidene, 1,4-cyclohexene or 1,4-Phenylene.
Preferably, the compounds represented by formula V are selected from the group consisting of compounds represented by formulas V-1˜V-6:
Preferably, the mass content of one or more compounds represented by formula V except for those in formula I and II is 0-20%, preferably 5-15%.
In a further embodiment of the liquid crystal composition of the present disclosure, preferably, one or more compounds represented by formula VI are also included:
wherein, R7 and R8 independently represent alkyl group having a carbon atom number of 1-10, fluoro-substituted alkyl group having a carbon atom number of 1-10, alkoxy group having a carbon atom number of 1-10, fluoro-substituted alkoxy group having a carbon atom number of 1-10, alkenyl group having a carbon atom number of 2-10, fluoro-substituted alkenyl group having a carbon atom number of 2-10, alkenoxy group having a carbon atom number of 3-8 or fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one —CH2— or several —CH2— that are not adjacent of the groups indicated by R7 and R8 are selectively substituted by cyclopentyl, cyclobutyl or cyclopropylene;
4-cyclohexylidene or 1,4-Phenylene.
Preferably, one or more compounds represented by formula VI are selected from the group consisting of compounds represented by formula VI-1˜VI-8:
Preferably, the mass content of the compound represented by formula VI in the liquid crystal composition is 0-30%, preferably 5-25%;
In the liquid crystal composition of the present disclosure, dopants with various functions can be added. In the case of dopants, the content of dopants is preferably 0.01˜1.5% in the liquid crystal composition. The dopants can be listed as antioxidants, ultraviolet absorbers and chiral agents.
Antioxidants can be listed,
t represents an integer from 1 to 10.
Chiral agents can be listed,
Ra represents alkyl with carbon atom number of 1-10.
Light stabilizers can be listed,
Za represents alkylene having a carbon atom number of 1 to 20, in which any one or more hydrogen is selectively substituted by halogen, and any one or more —CH2— is selectively substituted by —O—.
Ultraviolet absorbers can be listed,
Rb represents alkyl group having a carbon atom number of 1-10.
[Liquid Crystal Display Element or Liquid Crystal Display]
The present disclosure also relates to a liquid crystal display element or a liquid crystal display comprising any one of the above liquid crystal compositions; the display element or display is an active matrix display element or display or a passive matrix display element or display.
Preferably, the liquid crystal display element or liquid crystal display is preferably an active matrix liquid crystal display element or a liquid crystal display.
Preferably, the active matrix display element or display is a VA-TFT, IPS-TFT or FFS-TFT liquid crystal display element or display.
In order to explain the present disclosure more clearly, the present disclosure will be further explained in combination with the preferred embodiment. Those skilled in the art should understand that the contents described below are illustrative rather than restrictive, and the scope of protection of the present disclosure should not be limited.
In this manual, unless otherwise specified, the percentage refers to the mass percentage, and the temperature is degree centigrade (° C.). The specific meaning and test conditions of other symbols are as follows:
Cp is the clear point (° C.) of liquid crystal, and it is measured by DSC quantitative method;
An is the optical anisotropy, no is the refractive index of ordinary light, Ne is the refractive index of extraordinary light, the test conditions are 25±2° C., 589 nm, Abbe refractometer test;
Δε is the dielectric anisotropy, Δε=ε//−ε⊥, where ε// is the dielectric constant parallel to the molecular axis, and ε⊥ is the dielectric constant perpendicular to the molecular axis. The test conditions are 25±0.5° C., 20 um vertical box, INSTEC:ALCT-IR1 testing;
γ1 is the rotational viscosity (mPa·s), and the test conditions are 25±0.5° C. and 20 um vertical box, INSTEC:ALCT-IR1 testing;
K11 is the torsional elastic constant and K33 is the unfolding elastic constant INSTEC:ALCT-IR1, 20 um vertical box;
The preparation method of the liquid crystal composition is as follows: each liquid crystal monomer is weighed according to a certain proportion and put into a stainless steel beaker; the stainless steel beaker containing each liquid crystal monomer is heated and melted on the magnetic stirring instrument; after most of the liquid crystal monomer in the stainless steel beaker is melted, a magnetic rotor is added into the stainless steel beaker, and the mixture is stirred evenly and cooled to room temperature to obtain liquid crystal composition.
The structure of liquid crystal monomer in the embodiment of the disclosure is represented by codes. The codes for ring structures, end groups and linking groups of liquid crystals are represented as in Tables 1 and 2 below.
the code is CC-Cp-V1;
the code is CPY-2-O2;
the code is CCY-3-O2;
the code is COY-3-O2;
the code is CCOY-3-O2;
the code is Sb-CpO-O4;
the code is Sc-CpO-O4.
The formula and corresponding properties of the liquid crystal composition are shown in Table 3.
The formula and corresponding properties of the liquid crystal composition are shown in Table 4.
The formula and corresponding properties of the liquid crystal composition are shown in Table 5.
The formula and corresponding properties of the liquid crystal composition are shown in Table 6.
The formula and corresponding properties of the liquid crystal composition are shown in Table 7.
The formula and corresponding properties of the liquid crystal composition are shown in Table 8.
The formula and corresponding properties of the liquid crystal composition are shown in Table 9 below.
The formula and corresponding properties of the liquid crystal composition are shown in table 10 below.
The formula and corresponding properties of the liquid crystal composition are shown in Table 11 below.
In example 1, CC-3-V is replaced with CC-5-V, CCY-3-O2 is replaced with CCOY-3-O2, and the rest is the same as that of example 1, as the comparative example 1. Compared with the comparative example 1, example 1 has lower rotational viscosity γ1 and lower γ1/K33, which can obtain a fast response liquid crystal display.
The formula and corresponding properties of the liquid crystal composition are shown in Table 12.
PY-3-O2 and PY-O2-O2 in example 2 are replaced with Sb-CpO-O4 and Sc-CpO-O4, and the rest are the same as those in example 2, as the comparative example 2. Compared with the comparative example 2, example 2 has lower rotational viscosity γ1 and lower γ1/K33, and can obtain a fast response liquid crystal display.
The formula and corresponding properties of the liquid crystal composition are shown in table 13 below.
PY-O4-O2 in example 6 is replaced with Sb-CpO-O4, and the rest are the same as that of example 6, as the comparative example 3. Compared with the comparative example 3, example 6 has lower rotational viscosity γ1 and lower γ1/K33, and can obtain a fast response liquid crystal display.
The formula and corresponding properties of the liquid crystal composition are shown in table 14 below.
PY-O4-O2 and CPY-3-O2 in example 7 are replaced with Sc-CpO-O4 and CCOY-3-O2 respectively, and the rest are the same as those in example 7, as the comparative example 4. Compared with the comparative example 4, example 7 has lower rotational viscosity γ1 and lower γ1/K33, and can obtain a fast response liquid crystal display.
Obviously, the above-mentioned examples of the present disclosure are only for the purpose of clearly explaining the examples of the present disclosure, rather than limiting the implementation mode of the present disclosure. For ordinary technical personnel in the art, other changes or changes in different forms can be made on the basis of the above description. Here, it is impossible to enumerate all the examples, and all the technologies belong to the present disclosure The obvious changes or changes in the technical scheme are still within the scope of protection of the present disclosure.
| Number | Date | Country | Kind |
|---|---|---|---|
| 201911394886.1 | Dec 2019 | CN | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/CN2020/083216 | 4/3/2020 | WO |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2021/134962 | 7/8/2021 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20160244668 | Saito | Aug 2016 | A1 |
| 20170298276 | Saito | Oct 2017 | A1 |
| 20190048261 | Kurihara | Feb 2019 | A1 |
| 20200239776 | Kang | Jul 2020 | A1 |
| Number | Date | Country |
|---|---|---|
| 105121597 | Dec 2015 | CN |
| 107849454 | Mar 2018 | CN |
| 109988582 | Jul 2019 | CN |
| 110016353 | Jul 2019 | CN |
| 110577832 | Dec 2019 | CN |
| Number | Date | Country | |
|---|---|---|---|
| 20210292650 A1 | Sep 2021 | US |
