Claims
- 1. A compound of the formula ##STR13## wherein R is an alkyl group with 1 to 12 carbon atoms or a group of ##STR14## ring A.sup.1 is 1,4-phenylene, which is unsubstituted or substituted with one fluorine atom, pyridine-2,5-diyl or pyrimidine-2,5-diyl;
- ring A.sup.2 is trans-1,4-cyclohexylene or trans-1,3-dioxane-2,5-diyl;
- R.sup.1 is an alkyl group with 1 to 12 or an alkenyl or alkoxyalkyl group with 2 to 12 carbon atoms;
- X.sup.1 is fluorine, chlorine, or bromine and can also be trifluoromethyl, trifluoromethoxy or difluoromethoxy when R is an alkyl group with 1 to 12 carbon atoms, when ring A.sup.1 is 1,4-phenylene substituted with one fluorine atom, pyridine-2,5-diyl or pyrimidine-2,5-diyl, when ring A.sup.2 is trans-1,3-dioxane-2,5-diyl, or when X.sup.2 or X.sup.3 is fluorine; and
- X.sup.2, X.sup.3 each independently is hydrogen or fluorine.
- 2. A compound according to claim 1 of the formula ##STR15## wherein R is an alkyl group with 1 to 12 carbon atoms; X.sup.4 is hydrogen or fluorine and X.sup.1 and X.sup.2 each independently is hydrogen or fluorine.
- 3. A compound according to claim 1 of the general formulas ##STR16## wherein R.sup.1, X.sup.1 and X.sup.2 are as defined in claim 1 and X.sup.4 is hydrogen or fluorine.
- 4. A compound according to claim 1, wherein R is alkyl with 1 to 7 carbon atoms and R.sup.1 is alkyl with 1 to 7 carbon atoms or alkenyl or alkoxyalkyl with 2 to 7 carbon atoms.
- 5. A compound according to claim 4, wherein R is an alkyl group with 2 to 5 carbon atoms.
- 6. A compound according to claim 3, wherein R.sup.1 is alkyl or alkenyl with 2 to 5 carbon atoms and A.sup.2 is trans-1,4-cyclohexylene.
- 7. The compound of claim 6 which is 4-[trans-4-propylcyclohexyl)ethynyl]-4'-fluorophenyl.
- 8. A compound according to claim 1 wherein A.sup.2 is trans-1,3-dioxane-2,5-diyl.
- 9. The compound of claim 8 which is 5-[(trans-5-propyl-1,3-dioxan-2-yl)ethynyl]-2-(3,4-difluorophenyl)-pyridine.
- 10. The compound of claim 6 which is 4-[(trans-4-vinylcyclohexyl)ethynyl]-4'-fluorobiphenyl.
- 11. The compound of claim 6 which is 4-[trans-4-(1E-propenylcyclohexyl)ethynyl]-4'-fluorobiphenyl.
- 12. The compound of claim 6 which is 4-[[trans-4-(3-butenyl)cyclohexyl]ethynyl]-4'-fluorobiphenyl.
- 13. The compound of claim 6 which is 4-[[trans-4-(4-pentenyl)cyclohexyl]ethynyl]-4'-fluorobiphenyl.
- 14. A compound of claim 4 wherein R.sup.1 is alkoxyalkyl with 2 to 7 carbon atoms.
- 15. The compound of claim 14 which is 4'-[[trans-4-(3-methoxypropyl)cyclohexyl]ethynyl]-4'-fluorobiphenyl.
- 16. A liquid crystalline mixture comprising at least two components, wherein at least one component is a compound of the formula ##STR17## wherein R is an alkyl group with 1 to 12 carbon atoms or a group of the formula ##STR18## ring A.sup.1 is 1,4-phenylene, which is unsubstituted or substituted with one fluorine atom, pyridine-2,5-diyl or pyrimidine-2,5-diyl;
- ring A.sup.2 is trans-1,4-cyclohexylene or trans-1,3-dioxane-2,5diyl;
- R.sup.1 is an alkyl group with 1 to 12 or an alkenyl or alkoxyalkyl group with 2 to 12 carbon atoms;
- X.sup.1 is fluorine, chlorine, or bromine and can also be trifluoromethyl, trifluoromethoxy or difluoromethoxy when R is an alkyl group with 1 to 12 carbon atoms, when ring A.sup.1 is 1,4-phenylene substituted with one fluorine atom, pyridine-2,5-diyl or pyrimidine-2,5-diyl, when ring A.sup.2 is trans-1,3-dioxane-2,5-diyl, or when X.sup.2 or X.sup.3 is fluorine; and
- X.sup.2, X.sup.3 each independently is hydrogen or fluorine.
Priority Claims (1)
Number |
Date |
Country |
Kind |
3006/92 |
Sep 1992 |
CHX |
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Parent Case Info
This is a continuation of application Ser. No. 08/107,554 filed Aug. 17, 1993, now abandoned.
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Entry |
Adomenas et al., "Acetylenic liquid crystals available by Castro reaction", Chemical Abstracts, vol. 95:219871e, p. 494 (1981). |
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Continuations (1)
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Number |
Date |
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Parent |
107554 |
Aug 1993 |
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