This application claims the benefit of the Korean Application No. P2002-8900 filed on Feb. 20, 2002, which is hereby incorporated by reference for all purposes as if fully set forth herein.
This application incorporates by reference two applications, Ser. No. 10/184,096, filed on Jun. 28, 2002, entitled “SYSTEM AND METHOD FOR MANUFACTURING LIQUID CRYSTAL DISPLAY DEVICES”and Ser. No. 10/184,088, filed on Jun. 28, 2002, entitled “SYSTEM FOR FABRICATING LIQUID CRYSTAL DISPLAY AND METHOD OF FABRICATING LIQUID CRYSTAL DISPLAY USING THE SAME”, as if fully set forth herein.
1. Field of the Invention
The present invention relates to a liquid crystal display (LCD) device, and more particularly, to a sealant pattern of an LCD device manufactured by applying a liquid crystal to the surface of a substrate.
2. Discussion of the Related Art
Generally, ultra thin flat panel displays have a display screen with a thickness of several centimeters or less. In particular, flat panel LCD devices are widely used in monitors for notebook computers, spacecraft, and aircraft because such LCD devices have low power consumption and are easy to carry.
Such an LCD device includes a lower substrate, an upper substrate, and a liquid crystal layer. A thin film transistor (TFT) and a pixel electrode are formed on the lower substrate. The upper substrate is formed to oppose the lower substrate. A light-shielding layer, a color filter layer, and a common electrode are formed on the upper substrate. The liquid crystal layer is formed between the lower and upper substrates. In operation an electric field is formed between the lower and upper substrates by the pixel electrode and the common electrode so that the electric field “drives” the alignment of molecules in the liquid crystal layer. Light transmittivity is controlled by driving the liquid crystal layer so that a picture image is displayed.
In the aforementioned LCD device, to form the liquid crystal layer between lower and upper substrates, a vacuum injection method based on capillary phenomenon and pressure difference has been conventionally used. However, such a vacuum injection method has a problem in that it takes long time to inject the liquid crystal into a large display panel, thereby reducing manufacturing productivity.
To solve such a problem, a method of applying liquid crystal on the substrate has been developed and is generally described with reference to
As shown in
A light-shielding layer (not shown) is formed on the upper substrate 3 to prevent light from leaking out from the gate and data lines and the thin film transistor. Color filter layers of red(R), green(G), and blue(B) are formed on the light-shielding layer, and a common electrode is formed on the color filter layers. An alignment film (not shown) is formed on at least one of the lower substrate 1 and the upper substrate 3 to initially align the liquid crystal molecules.
As shown in
In the method of manufacturing the LCD device based on the liquid crystal application method, a liquid crystal layer is formed on attached substrates before the sealant 7 is hardened. Therefore, if a thermo-hardening sealant is used as the sealant 7, the liquid crystal heats and expands so that it flows out of the substrate when it is heated. For this reason, a problem arises in that the liquid crystal 5 is contaminated. Therefore, in the method of manufacturing the LCD based on the liquid crystal application method, a sealant that is at least partially curable by ultraviolet (UV) light is used as the sealant 7.
The UV sealant is formed by a screen printing method or a dispensing method. In the screen printing method, since a screen comes into contact with the substrate, the alignment film formed on the substrate may be damaged. Also, if the substrate has a large sized area, loss of the sealant increases. In these respects, the dispensing method is preferably used.
As shown in
As shown in
Thereafter, although not shown, a cell cutting process and a final test process are performed, thereby completing a liquid crystal cell.
Meanwhile,
However, since the sealant 7 has high viscosity, it is concentrated upon the end of a nozzle of the dispensing device 8 before the sealant 7 is dispensed. For this reason, a blob “A” of the sealant 7 is excessively deposited at the point where deposition of the sealant 7 on the substrate is started.
As shown in
Accordingly, the present invention is directed to an LCD device and a method of manufacturing the same that substantially obviates one or more problems due to limitations and disadvantages of the related art.
An advantage of the present invention is to provide an LCD device and a method of manufacturing the same in which a sealant is formed so that a liquid crystal is not contaminated when both substrates are attached to each other and so that a cell cutting process can be easily performed.
Additional advantages and features of the invention will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from practice of the invention. These and other advantages of the invention may be realized and attained by the structure particularly pointed out in the written description and claims hereof as well as the appended drawings.
To achieve these and other advantages and in accordance with the purpose of the invention, as embodied and broadly described herein, a method of manufacturing an LCD device according to the present invention includes preparing a lower substrate and an upper substrate; forming an auxiliary sealant and subsequently forming a main sealant on one of the lower and upper substrates, wherein the auxiliary sealant is formed in a dummy region and connect to the main sealant; applying a liquid crystal on one of the lower and upper substrates; attaching the lower and upper substrates; and curing at least the main sealant.
In one embodiment of the present invention, the supplementary UV sealant does not perform the ordinary the function of a sealant, that is, it does not prevent the liquid crystal from leaking out. While the main UV sealant acts as a sealant to confine the liquid crystal.
In another aspect of the present invention, a method of manufacturing a liquid crystal display (LCD) device includes preparing a lower substrate and an upper substrate; forming an auxiliary UV sealant and a main UV sealant on one of the lower and upper substrates, wherein the auxiliary UV sealant is formed in a dummy region and extends from the main UV sealant; applying a liquid crystal on one of the lower and upper substrates; attaching the lower and upper substrates; and irradiating UV light on the attached substrates.
In one aspect of the present invention, the supplementary UV sealant is formed in a dummy region on the substrate and then the closed type main UV sealant is formed, so that the sealant concentrated upon the end of a nozzle of a dispensing device is formed in the dummy region on the substrate.
It is to be understood that both the foregoing general description and the following detailed description of the present invention are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the principle of the invention.
In the drawings:
Reference will now be made in detail to the illustrated embodiments of the present invention, examples of which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers will be used throughout the drawings to refer to the same or like parts.
Although the drawings illustrate only one unit cell, a plurality of unit cells may be formed depending upon the size of the substrate.
As shown in
An alignment film (not shown) is formed on the pixel electrode to initially align the molecules of liquid crystal. The alignment film may be formed of polyamide or polyimide based compound, polyvinylalcohol (PVA), and polyamic acid by rubbing. Alternatively, the alignment film may be formed of a photosensitive material, such as polyvinvylcinnamate (PVCN), polysilioxanecinnamate (PSCN) or cellulosecinnamate (CelCN) based compound, by using a photo-aligmnent method.
A light-shielding layer (not shown) is formed on the upper substrate 30 to shield light leakage from the gate lines, the data lines, and the thin film transistor regions. A color filter layer (not shown) of R, G, and B is formed on the light-shielding layer. A common electrode (not shown) is formed on the color filter layer. Additionally, an overcoat layer (not shown) may be formed between the color filter layer and the common electrode. The alignment film is formed on the common electrode.
Silver (Ag) dots are formed outside the lower substrate 10 to apply a voltage to the common electrode on the upper substrate 30 after the lower and upper substrates 10 and 30 are attached to each other. Alternatively, the silver dots may be formed on the upper substrate 30.
For an in plane switching (IPS) mode LCD, the common electrode is formed on the lower substrate like the pixel electrode, and so that an electric field can be horizontally induced between the common electrode and the pixel electrode. The silver dots are not formed on the substrate.
As shown in
An auxiliary UV curable sealant 70a is formed in a dummy area at a corner region of the upper substrate 30, subsequently, a main UV curable sealant 70b having no injection hole is formed, using a dispensing method.
The auxiliary UV sealant 70a is prevents any problem that may occur due to a sealant concentrated upon the end of a nozzle of a dispensing device. Therefore, it does not matter where the auxiliary UV sealant 70a is formed in the dummy area of the substrate, i.e., any blob of-sealant will be formed away from the active region of the liquid crystal display device and away from a region where the liquid crystal panel will be cut away from the mother substrate assembly. Formation of the main UV sealant 70b is preceded by the formation of the auxiliary UV sealant 70a. The auxiliary UV sealant 70a may be formed in a straight line as shown. Alternatively, the auxiliary UV sealant 70a may be formed in a curved line or other shape as long as it is formed in a dummy region.
Monomers or oligomers each having both ends coupled to the acrylic group, mixed with an initiator are used as the UV sealants 70a and 70b. Alternatively, monomers or oligomers each having one end coupled to the acrylic group and the other end coupled to the epoxy group, mixed with an initiator are used as the UV sealants 70a and 70b.
Also, the liquid crystal 50 may be contaminated if it comes into contact with the main UV sealant 70b before the main UV sealant 70b is hardened. Accordingly, the liquid crystal 50 may preferably be applied on the central part of the lower substrate 10. In this case, the liquid crystal 50 is gradually spread even after the main UV sealant 70b is hardened. Thus, the liquid crystal 50 is uniformly distributed on the substrate.
The liquid crystal 50 may be formed on the upper substrate 30 while the UV sealants 70a and 70b may be formed on the lower substrate 10. Alternatively, the liquid crystal 50 and the UV sealants 70a and 70b may be formed on one substrate. In this case, there is an imbalance between the processing times of the substrate with the liquid crystal and the sealants and the substrate without the liquid crystal and the sealants in the manufacturing process. For this reason, the total manufacturing process time increases. Also, when the liquid crystal and the sealants are formed on one substrate, the substrate may not be cleaned even if the sealant contaminates the panel before the substrates are attached to each other.
Accordingly, a cleaning process for cleaning the upper substrate 30 may additionally be provided before the attaching process after the UV sealants 70a and 70b are formed on the upper substrate 30.
Meanwhile, spacers may be formed on either of the two substrates 10 and 30 to maintain a cell gap. Preferably, the spacers may be formed on the upper substrate 30.
Ball spacers or column spacers may be used as the spacers. The ball spacers may be formed in such a manner that they are mixed with a solution having an appropriate concentration and then spread at a high pressure onto the substrate from a spray nozzle. The column spacers may be formed on portions of the substrate corresponding to the gate lines or data lines. Preferably, column spacers may be used for the large sized substrate since the ball spacers may cause an uneven cell gap for the large sized substrate. The column spacers may be formed of a photosensitive organic resin.
As shown in
Then, as shown in
Upon irradiating the UV light, monomers or oligomers activated by an initiator constituting the UV sealants are polymerized and hardened, thereby bonding the lower substrate 10 to the upper substrate 30.
If monomers or oligomers each having one end coupled to the acrylic group and the other end coupled to the epoxy group, mixed with an initiator are used as the UV sealants, the epoxy group is not completely polymerized by the application of UV light. Therefore, the sealants may have to be additionally heated at about 120° C. for one hour after the UV irradiation, thereby hardening the sealants completely.
Afterwards, although not shown, the bonded substrates are cut into a unit cells and final test processes are performed.
In the cutting process, a scribing process is performed by forming a cutting line on surfaces of the substrates with a pen or wheel of a material having hardness greater than that of glass, such as diamond, and then the substrates are cut along the cutting line by mechanical impact (breaking process). Alternatively, the scribing process and the breaking process may simultaneously be performed using a pen or wheel of a diamond or other hard material.
The cutting line of the cutting process is formed between the start point of the auxiliary sealant, which may be a blob A of sealant, and a main UV sealant across the initially formed auxiliary UV sealant 70a. Consequently, a substantial portion of the excessively distributed auxiliary UV sealant 70a is removed.
If the UV light is irradiated upon the entire surface of the attached substrates, the UV light may deteriorate characteristics of devices such as a thin film transistor on the substrate and may change a pre-tilt angle of an alignment film formed for the initial alignment of the liquid crystal.
Therefore, in the second embodiment of the present invention, the UV light is irradiated when the area where no sealant is formed is covered with a mask.
Referring to
Also, the mask 80 may be placed at a lower side of the attached substrates. Also, although the UV light is irradiated upon the upper substrate 30 of the attached substrates as shown, the UV light may be irradiated upon the lower substrate 10 by turning the attached substrates.
If the UV light from a UV irradiating device 90 is reflected and irradiated upon an opposite side, it may deteriorate characteristics of devices, such as the thin film transistor on the substrate and the alignment film, as described above. Therefore, masks are preferably formed at lower and upper sides of the attached substrates.
That is, as shown in
Meanwhile, since the auxiliary UV sealant 70a does not act as a sealant, it does not require hardening. Also, since the region of the auxiliary UV sealant 70a overlaps the cell cutting line during the later cell cutting process, it is more desirable for the cell cutting process that the auxiliary UV sealant 70 is not hardened.
Referring to
In this case, in
The third embodiment is identical to the second embodiment except for the UV irradiation process. In the third embodiment, the UV light is irradiated at a tilt angle. Since the other elements of the third embodiment are identical to those of the second embodiment, the same reference numerals will be given to the same elements and their detailed description will be omitted.
If a light-shielding layer and a metal line such as gate and data lines are formed on a region where the UV sealant is formed, the UV light is not irradiated upon the region, thereby failing to harden the sealant. For this reason, adherence between the lower and upper substrates is reduced.
Therefore, in the third embodiment of the present invention, the UV light is irradiated at a tilt angle upon the substrate where the UV sealant is formed, so that the UV sealant is hardened even if the light-shielding layer or the metal line layer is formed between the UV irradiating surface and the sealant.
To irradiate the UV light at a tilt angle, as shown in
Also, the UV light may be irradiated at a tilt angle when the area where the sealant is not formed is covered with the mask as shown in
As shown in
At this time, although not shown, a thin film transistor, a pixel electrode, and an alignment film are formed on the lower substrate 10. A black matrix layer (not shown), a color filter layer (not shown), a common electrode (not shown) and an alignment film (not shown) are formed on the upper substrate 30. Also, spacers are formed between the lower and upper substrates 10 and 30 to maintain a cell gap between the substrates.
As aforementioned, the LCD device and the method of manufacturing the same according to the present invention have the following advantages.
Since the sealant concentrated upon the end of the nozzle of the dispensing device is formed in the dummy area on the substrate, the liquid crystal layer is not contaminated by the attaching process of the substrates and the cell cutting process is easily performed.
Furthermore, if the UV light is irradiated upon the substrate when the mask is formed at the lower and/or upper side of the attached substrates, the UV light is irradiated upon only the region where the UV sealant is formed. In this case, the alignment film formed on the substrate is not damaged and the characteristics of the devices, such as the thin film transistor, are not deteriorated.
Finally, if the UV light is irradiated at a tilt angle, the sealant can be hardened even if the light-shielding layer or the metal line is formed on the sealant, thereby avoiding reducing adherence between the lower and upper substrates.
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention. Thus, it is intended that the present invention covers the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.
Number | Date | Country | Kind |
---|---|---|---|
2002-8900 | Feb 2002 | KR | national |
Number | Name | Date | Kind |
---|---|---|---|
3978580 | Leupp et al. | Sep 1976 | A |
4094058 | Yasutake et al. | Jun 1978 | A |
4653864 | Baron et al. | Mar 1987 | A |
4691995 | Yamazaki et al. | Sep 1987 | A |
4775225 | Tsuboyama et al. | Oct 1988 | A |
5089358 | Taki et al. | Feb 1992 | A |
5247377 | Omeis et al. | Sep 1993 | A |
5263888 | Ishihara et al. | Nov 1993 | A |
5307190 | Wakita et al. | Apr 1994 | A |
5379139 | Sato et al. | Jan 1995 | A |
5406989 | Abe | Apr 1995 | A |
5410423 | Furushima et al. | Apr 1995 | A |
5499128 | Hasegawa et al. | Mar 1996 | A |
5507323 | Abe | Apr 1996 | A |
5511591 | Abe | Apr 1996 | A |
5517344 | Hu et al. | May 1996 | A |
5539545 | Shimizu et al. | Jul 1996 | A |
5548429 | Tsujita | Aug 1996 | A |
5642214 | Ishii et al. | Jun 1997 | A |
5677749 | Tsubota et al. | Oct 1997 | A |
5680189 | Shimizu et al. | Oct 1997 | A |
5724110 | Majima | Mar 1998 | A |
5742370 | Kim et al. | Apr 1998 | A |
5757451 | Miyazaki et al. | May 1998 | A |
5852484 | Inoue et al. | Dec 1998 | A |
5854664 | Inoue et al. | Dec 1998 | A |
5861932 | Inata et al. | Jan 1999 | A |
5875922 | Chastine et al. | Mar 1999 | A |
5898041 | Yamada et al. | Apr 1999 | A |
5946070 | Kohama et al. | Aug 1999 | A |
5952676 | Sato | Sep 1999 | A |
5952678 | Ashida | Sep 1999 | A |
5956112 | Fujimori et al. | Sep 1999 | A |
6001203 | Yamada et al. | Dec 1999 | A |
6011609 | Kato et al. | Jan 2000 | A |
6016178 | Kataoka et al. | Jan 2000 | A |
6016181 | Shimada | Jan 2000 | A |
6055035 | von Gutfeld et al. | Apr 2000 | A |
6163357 | Nakamura | Dec 2000 | A |
6177976 | Murai et al. | Jan 2001 | B1 |
6219126 | Von Gutfeld | Apr 2001 | B1 |
6226067 | Nishiguchi et al. | May 2001 | B1 |
6236445 | Foschaar et al. | May 2001 | B1 |
6239855 | Nakahara et al. | May 2001 | B1 |
6304306 | Shiomi et al. | Oct 2001 | B1 |
6304311 | Egami et al. | Oct 2001 | B1 |
6337730 | Ozaki et al. | Jan 2002 | B1 |
6373544 | Hirabayashi | Apr 2002 | B1 |
6414733 | Ishikawa et al. | Jul 2002 | B1 |
6573968 | Jeong | Jun 2003 | B2 |
6628365 | Park et al. | Sep 2003 | B1 |
20010021000 | Egami | Sep 2001 | A1 |
20010026348 | Murata et al. | Oct 2001 | A1 |
Number | Date | Country |
---|---|---|
1 003 066 | May 2000 | EP |
1003066 | May 2000 | EP |
51-65656 | Jun 1976 | JP |
51-065656- | Jun 1976 | JP |
57-038414 | Mar 1982 | JP |
57038414- | Mar 1982 | JP |
57-088428 | Jun 1982 | JP |
57088428- | Jun 1982 | JP |
58-027126 | Feb 1983 | JP |
58027126- | Feb 1983 | JP |
59-057221 | Apr 1984 | JP |
59-057221- | Apr 1984 | JP |
59-195222 | Nov 1984 | JP |
59-195222- | Nov 1984 | JP |
60-111221 | Jun 1985 | JP |
60-111221- | Jun 1985 | JP |
60-164723 | Aug 1985 | JP |
60164723- | Aug 1985 | JP |
60-217343 | Oct 1985 | JP |
60217343- | Oct 1985 | JP |
61-007822 | Jan 1986 | JP |
61007822- | Jan 1986 | JP |
61-055625 | Mar 1986 | JP |
61055625- | Mar 1986 | JP |
S62-054225 | Mar 1987 | JP |
S62-054228 | Mar 1987 | JP |
62-089025 | Apr 1987 | JP |
62-090622 | Apr 1987 | JP |
62089025- | Apr 1987 | JP |
62090622- | Apr 1987 | JP |
62-205319 | Sep 1987 | JP |
62205319- | Sep 1987 | JP |
63-109413 | May 1988 | JP |
63-110425 | May 1988 | JP |
63-128315 | May 1988 | JP |
63109413- | May 1988 | JP |
63110425- | May 1988 | JP |
63128315- | May 1988 | JP |
63-311233 | Dec 1988 | JP |
63311233- | Dec 1988 | JP |
H03-009549 | Jan 1991 | JP |
H05-036425 | Feb 1993 | JP |
H05-036426 | Feb 1993 | JP |
H05-107533 | Apr 1993 | JP |
05-127179 | May 1993 | JP |
05127179- | May 1993 | JP |
05-154923 | Jun 1993 | JP |
05-154923- | Jun 1993 | JP |
05-265011 | Oct 1993 | JP |
05-281557 | Oct 1993 | JP |
05-281562 | Oct 1993 | JP |
05265011- | Oct 1993 | JP |
05281557- | Oct 1993 | JP |
05281562- | Oct 1993 | JP |
H06-018829 | Jan 1994 | JP |
06-051256 | Feb 1994 | JP |
06051256- | Feb 1994 | JP |
H06-064229 | Mar 1994 | JP |
06-148657 | May 1994 | JP |
06148657- | May 1994 | JP |
06-160871 | Jun 1994 | JP |
6160871- | Jun 1994 | JP |
H06-194637 | Jul 1994 | JP |
06-235925 | Aug 1994 | JP |
06-235925- | Aug 1994 | JP |
06-265915 | Sep 1994 | JP |
06265915- | Sep 1994 | JP |
06-313870 | Nov 1994 | JP |
06-313870- | Nov 1994 | JP |
07-084268 | Mar 1995 | JP |
07-084268- | Mar 1995 | JP |
07-128674 | May 1995 | JP |
07128674- | May 1995 | JP |
07-181507 | Jul 1995 | JP |
07181507- | Jul 1995 | JP |
H07-275770 | Oct 1995 | JP |
H07-275771 | Oct 1995 | JP |
H08-076133 | Mar 1996 | JP |
08-095066 | Apr 1996 | JP |
08-101395 | Apr 1996 | JP |
08-101395- | Apr 1996 | JP |
08-106101 | Apr 1996 | JP |
08095066- | Apr 1996 | JP |
08106101- | Apr 1996 | JP |
H08-110504 | Apr 1996 | JP |
H08-136937 | May 1996 | JP |
08-171094 | Jul 1996 | JP |
08-190099 | Jul 1996 | JP |
08171094- | Jul 1996 | JP |
08190099- | Jul 1996 | JP |
H08-173874 | Jul 1996 | JP |
08-240807 | Sep 1996 | JP |
08240807- | Sep 1996 | JP |
09-005762 | Jan 1997 | JP |
9-15614 | Jan 1997 | JP |
09-026578 | Jan 1997 | JP |
09005762- | Jan 1997 | JP |
09026578- | Jan 1997 | JP |
H09-001026 | Jan 1997 | JP |
09-311340 | Feb 1997 | JP |
09-61829 | Mar 1997 | JP |
09-061829- | Mar 1997 | JP |
09-073075 | Mar 1997 | JP |
09-073096 | Mar 1997 | JP |
09073075- | Mar 1997 | JP |
09073096- | Mar 1997 | JP |
H09-094500 | Apr 1997 | JP |
09-127528 | May 1997 | JP |
09127528- | May 1997 | JP |
9197416 | Jul 1997 | JP |
09-230357 | Sep 1997 | JP |
09230357- | Sep 1997 | JP |
09-281511 | Oct 1997 | JP |
09281511- | Oct 1997 | JP |
09311340- | Dec 1997 | JP |
10-123537 | May 1998 | JP |
10-123538 | May 1998 | JP |
10-142616 | May 1998 | JP |
10123537- | May 1998 | JP |
10123538 | May 1998 | JP |
10123538- | May 1998 | JP |
10142616- | May 1998 | JP |
10-177178 | Jun 1998 | JP |
10-177178- | Jun 1998 | JP |
H10-174924 | Jun 1998 | JP |
10-221700 | Aug 1998 | JP |
10221700- | Aug 1998 | JP |
10-282512 | Oct 1998 | JP |
10282512- | Oct 1998 | JP |
10-333157 | Dec 1998 | JP |
10-333157- | Dec 1998 | JP |
10-333159 | Dec 1998 | JP |
10-333159- | Dec 1998 | JP |
11-014953 | Jan 1999 | JP |
11014953- | Jan 1999 | JP |
11-038424 | Feb 1999 | JP |
11038424- | Feb 1999 | JP |
11-064811 | Mar 1999 | JP |
11064811- | Mar 1999 | JP |
11-109388 | Apr 1999 | JP |
11109388- | Apr 1999 | JP |
11-133438 | May 1999 | JP |
11-133438- | May 1999 | JP |
11-142864 | May 1999 | JP |
11-142864- | May 1999 | JP |
11142864 | May 1999 | JP |
11-174477 | Jul 1999 | JP |
11174477- | Jul 1999 | JP |
11-212045 | Aug 1999 | JP |
11212045- | Aug 1999 | JP |
11-248930 | Sep 1999 | JP |
H11-262712 | Sep 1999 | JP |
H11-264991 | Sep 1999 | JP |
11-326922 | Nov 1999 | JP |
11-326922- | Nov 1999 | JP |
11-344714 | Dec 1999 | JP |
11344714- | Dec 1999 | JP |
2000-002879 | Jan 2000 | JP |
2000-002879- | Jan 2000 | JP |
2000-029035 | Jan 2000 | JP |
2000029035- | Jan 2000 | JP |
2000-056311 | Feb 2000 | JP |
2000-056311- | Feb 2000 | JP |
2000-066165 | Mar 2000 | JP |
2000-066165- | Mar 2000 | JP |
2000-066218 | Mar 2000 | JP |
2000-093866 | Apr 2000 | JP |
2000-137235 | May 2000 | JP |
2000-147528 | May 2000 | JP |
3000-147528- | May 2000 | JP |
2000-137235- | Jun 2000 | JP |
2000-193988 | Jul 2000 | JP |
2000-193988- | Jul 2000 | JP |
2000-241824 | Sep 2000 | JP |
2000-241824- | Sep 2000 | JP |
2000-284295 | Oct 2000 | JP |
2000-284295- | Oct 2000 | JP |
2000-292799 | Oct 2000 | JP |
2000-292799- | Oct 2000 | JP |
2000-310759 | Nov 2000 | JP |
2000-310759- | Nov 2000 | JP |
2000-310784 | Nov 2000 | JP |
2000-310784- | Nov 2000 | JP |
2000-338501 | Dec 2000 | JP |
2000-338501- | Dec 2000 | JP |
2001-005401 | Jan 2001 | JP |
2001-005401- | Jan 2001 | JP |
2001-005405 | Jan 2001 | JP |
2001-005405- | Jan 2001 | JP |
2001-013506 | Jan 2001 | JP |
2001-013506- | Jan 2001 | JP |
2001-033793 | Feb 2001 | JP |
2001-033793- | Feb 2001 | JP |
2001-042341 | Feb 2001 | JP |
2001-042341- | Feb 2001 | JP |
2001-051284 | Feb 2001 | JP |
2001-051284- | Feb 2001 | JP |
2001-066615 | Mar 2001 | JP |
2001-066615- | Mar 2001 | JP |
2001-091727 | Apr 2001 | JP |
2001-091727- | Apr 2001 | JP |
2001-117105 | Apr 2001 | JP |
2001-117109 | Apr 2001 | JP |
2001-117109- | Apr 2001 | JP |
2001117105- | Apr 2001 | JP |
2001-133745 | May 2001 | JP |
2001-133745- | May 2001 | JP |
2001-133794 | May 2001 | JP |
2001-133799 | May 2001 | JP |
2001-133799- | May 2001 | JP |
2001-142074 | May 2001 | JP |
2001-147437 | May 2001 | JP |
2001133794- | May 2001 | JP |
2001142074- | May 2001 | JP |
2001147437- | May 2001 | JP |
2001-154211 | Jun 2001 | JP |
2001-166272 | Jun 2001 | JP |
2001-166272- | Jun 2001 | JP |
2001-166310 | Jun 2001 | JP |
2001-166310- | Jun 2001 | JP |
2001154211- | Jun 2001 | JP |
2001-183683 | Jul 2001 | JP |
2001-183683- | Jul 2001 | JP |
2001-201750 | Jul 2001 | JP |
201183675 | Jul 2001 | JP |
2001-209052 | Aug 2001 | JP |
2001-209052- | Aug 2001 | JP |
2001-209056 | Aug 2001 | JP |
2001-209057 | Aug 2001 | JP |
2001-209058 | Aug 2001 | JP |
2001-209060 | Aug 2001 | JP |
2001-209060- | Aug 2001 | JP |
2001-215459 | Aug 2001 | JP |
2001-222017 | Aug 2001 | JP |
2001-222017- | Aug 2001 | JP |
2001-235758 | Aug 2001 | JP |
2001-235758- | Aug 2001 | JP |
2001-215459- | Sep 2001 | JP |
2001-255542 | Sep 2001 | JP |
2001-264782 | Sep 2001 | JP |
2001255542- | Sep 2001 | JP |
2001264782- | Sep 2001 | JP |
2001-201750- | Oct 2001 | JP |
2001-272640 | Oct 2001 | JP |
2001-272640- | Oct 2001 | JP |
2001-281675 | Oct 2001 | JP |
2001-281675- | Oct 2001 | JP |
2001-281678 | Oct 2001 | JP |
2001-281678- | Oct 2001 | JP |
2001-282126 | Oct 2001 | JP |
2001-282126- | Oct 2001 | JP |
2001-305563 | Oct 2001 | JP |
2001-305563- | Oct 2001 | JP |
2001-330837 | Nov 2001 | JP |
2001-330837- | Nov 2001 | JP |
2001-330840 | Nov 2001 | JP |
2001330840- | Nov 2001 | JP |
2001-356353 | Dec 2001 | JP |
2001-356353- | Dec 2001 | JP |
2001-356354 | Dec 2001 | JP |
2001356354- | Dec 2001 | JP |
2002-014360 | Jan 2002 | JP |
2002-023176 | Jan 2002 | JP |
2002014360- | Jan 2002 | JP |
2002023176- | Jan 2002 | JP |
2002-049045 | Feb 2002 | JP |
2002049045- | Feb 2002 | JP |
2002-079160 | Mar 2002 | JP |
2002-080321 | Mar 2002 | JP |
2002-082340 | Mar 2002 | JP |
2002-090759 | Mar 2002 | JP |
2002-090760 | Mar 2002 | JP |
2002082340- | Mar 2002 | JP |
2002090759- | Mar 2002 | JP |
2002090760- | Mar 2002 | JP |
2002-107740 | Apr 2002 | JP |
2002-122870 | Apr 2002 | JP |
2002-122872 | Apr 2002 | JP |
2002-122873 | Apr 2002 | JP |
2002107740- | Apr 2002 | JP |
2002122870 | Apr 2002 | JP |
2002122872- | Apr 2002 | JP |
2002122873- | Apr 2002 | JP |
2002-131762 | May 2002 | JP |
2002-139734 | May 2002 | JP |
2002-156518 | May 2002 | JP |
2002-169166 | Jun 2002 | JP |
2002-169167 | Jun 2002 | JP |
2002-182222 | Jun 2002 | JP |
2002080321- | Jun 2002 | JP |
2002-202512 | Jul 2002 | JP |
2002-202514 | Jul 2002 | JP |
2002-214626 | Jul 2002 | JP |
2002202512- | Jul 2002 | JP |
2002202514- | Jul 2002 | JP |
2002214626- | Jul 2002 | JP |
2002-229042 | Aug 2002 | JP |
2002-236276 | Aug 2002 | JP |
2002-258299 | Aug 2002 | JP |
2002-236292 | Sep 2002 | JP |
2002-277865 | Sep 2002 | JP |
2002-277866 | Sep 2002 | JP |
2002-277881 | Sep 2002 | JP |
2002-287156 | Oct 2002 | JP |
2002-296605 | Oct 2002 | JP |
2002-311438 | Oct 2002 | JP |
2002-311440 | Oct 2002 | JP |
2002-311442 | Oct 2002 | JP |
2002-323687 | Nov 2002 | JP |
2002-323694 | Nov 2002 | JP |
2002-333628 | Nov 2002 | JP |
2002-333635 | Nov 2002 | JP |
2002-333843 | Nov 2002 | JP |
2002-341329 | Nov 2002 | JP |
2002-341355 | Nov 2002 | JP |
2002-341356 | Nov 2002 | JP |
2002-341357 | Nov 2002 | JP |
2002-341358 | Nov 2002 | JP |
2002-341359 | Nov 2002 | JP |
2002-341362 | Nov 2002 | JP |
2003222883 | Aug 2003 | JP |
10-0211010 | Jul 1996 | KR |
10-0232905 | Oct 1996 | KR |
2000-0035302 | Jun 2000 | KR |
2000-0035302 | Jun 2000 | KR |
Number | Date | Country | |
---|---|---|---|
20030156246 A1 | Aug 2003 | US |