The present invention relates to a liquid crystal display panel, a method for manufacturing a liquid crystal display panel, and a photo-alignment processing device. More specifically, the present invention relates to a liquid crystal display panel having a configuration in which one pixel is divided into a plurality of alignment regions (domains), a method for manufacturing a liquid crystal display panel suitable for manufacturing the liquid crystal display panel, and a photo-alignment processing device.
A liquid crystal display device is a display device in which a liquid crystal composition is used to perform display. In a typical display system for the liquid crystal display device, a liquid crystal display panel including the liquid crystal composition enclosed between a pair of substrates is irradiated with light from a backlight, and voltage is applied to the liquid crystal composition to change an alignment of liquid crystal molecules, thereby controlling an amount of light passing through the liquid crystal display panel. Such a liquid crystal display device has features such as a thin profile, light weight, and low power consumption, and is therefore utilized in electronic devices such as a smartphone, a tablet PC, and an automotive navigation system.
Conventionally, alignment division techniques have been studied in which one pixel is divided into a plurality of alignment regions (domains) and the liquid crystal molecules are aligned in different azimuthal directions in different alignment regions, thereby enhancing a viewing angle characteristic. Examples of prior art documents that disclose an alignment division technique include, for example, PTLs 1 to 3.
PTL 1 discloses a liquid crystal display device that includes a first substrate, a second substrate, a liquid crystal layer vertically aligned and provided between the first substrate and the second substrate, a voltage application means for applying voltage to the liquid crystal layer, and a plurality of pixels, each including the liquid crystal layer in which an alignment state changes in response to voltage applied by the voltage application means. The liquid crystal layer in each of the plurality of pixels includes a four-divided domain obtained by arranging, in this order in a certain direction, a first domain, a second domain, a third domain, and a fourth domain, in which respective alignment directions of liquid crystal molecules positioned near a center in a thickness direction of the liquid crystal layer differ from each other at least in a voltage applied state. Corresponding to the four-divided domain, the first substrate includes two first regions having a regulation force that aligns liquid crystal molecules of the liquid crystal layer in a first direction, and a second region having a regulation force that aligns the liquid crystal molecules in a second direction opposite to the first direction and provided between the two first regions, and the second substrate includes a third region having a regulation force that aligns the liquid crystal molecules in a third direction intersecting with the first direction, and a fourth region having a regulation force that aligns the liquid crystal molecules in a fourth direction opposite to the third direction. Boundaries between the respective domains are each extended in a direction orthogonal to alignment directions of the respective domains.
PTL 2 discloses a liquid crystal display device that includes a display substrate provided with a plurality of pixel areas and having a curved shape curved in a first direction, a counter substrate facing the display substrate, coupled to the display substrate, and having a shape curved along the display substrate, and a liquid crystal layer disposed between the display substrate and the counter substrate. A plurality of domains are defined in each of the plurality of pixel areas, directions in which liquid crystal molecules of the liquid crystal layer are aligned differ from each other in at least two of the plurality of domains, and the plurality of domains are arranged in a second direction intersecting with the first direction.
PTL 3 discloses a liquid crystal display panel including, in order, a first substrate provided with pixel electrodes, a liquid crystal layer containing liquid crystal molecules, and a second substrate provided with counter electrodes. The liquid crystal display panel further includes pixels provided with at least four alignment regions, namely, a first alignment region, a second alignment region, a third alignment region, and a fourth alignment region. In the four alignment regions, tilt azimuthal directions of the liquid crystal molecules differ from each other. The alignment regions are disposed in a longitudinal direction of the pixels in the order of the first alignment region, the second alignment region, the third alignment region, and the fourth alignment region. The tilt azimuthal directions of the liquid crystal molecules in the first alignment region and the second alignment region differ by substantially 180°, or the tilt azimuthal directions of the liquid crystal molecules in the third alignment region and the fourth alignment region differ by substantially 180°.
PTL 1: JP 2006-85204 A
PTL 2: JP 2015-31961 A
PTL 3: WO 2017/047532
It is known that, in the alignment division technique, discontinuities in the alignment of liquid crystal molecules occur at boundaries between domains in which the alignment directions of the liquid crystal molecules differ, resulting in the occurrence of dark lines. The dark lines occur because the region where the alignment of the liquid crystal molecules is discontinuous does not transmit light when the liquid crystal display is performed. When a dark line occurs, a transmittance (contrast ratio) of the pixels decreases, and a light utilization efficiency of the liquid crystal display panel decreases. In recent years, while the definition of pixels has become increasingly enhanced and an area per pixel has decreased, a ratio of an area covered by the dark lines in the pixel has increased due to the unchanging area of the dark lines even when the pixels are made smaller, making it more important to prevent a reduction in light utilization efficiency. Further, when the dark lines occur in different positions on a pixel-by-pixel basis, a uniformity of the display also deteriorates.
Furthermore, the enhancement of the definition of pixels has led to a need for a higher precision alignment process to divide one pixel into a plurality of domains. As a result, photo-alignment process is now used as an alignment processing method and, to achieve high productivity, studies have been conducted on the use of scanning exposure in the photo-alignment process.
In this regard, the inventions described in PTLs 1 to 3 leave room for further investigation into suppressing the occurrence of dark lines to improve light utilization efficiency and controlling the occurring positions of dark lines to improve display uniformity while supporting pixel definition enhancement.
In light of the foregoing, an object of the present invention is to provide a liquid crystal display panel having excellent light utilization efficiency and display uniformity, a method for manufacturing a liquid crystal display panel suitable for manufacturing the liquid crystal display panel, and a photo-alignment processing device.
The present inventors conducted various studies on methods for suppressing dark lines in a liquid crystal display panel in which one pixel is divided into a plurality of alignment regions (domains), and noticed that the state of occurrence of dark lines varies depending on the arrangement of the domains. Then, the inventors of the present invention identified a specific arrangement optimal for suppressing the dark lines, have conceived that this arrangement brilliantly solves the above-described problems, and have arrived at the present invention.
That is, an aspect of the present invention is a liquid crystal display panel including, in the following order, a first substrate including a plurality of pixel electrodes and a first photo-alignment film, a liquid crystal layer containing liquid crystal molecules, and a second substrate including a common electrode and a second photo-alignment film. Given an alignment vector in which a major axis edge of the liquid crystal molecules closer to the first substrate is set to a start point and a major axis edge of the liquid crystal molecules closer to the second substrate is set to an end point, the first photo-alignment film and the second photo-alignment film are subjected to an alignment process such that a plurality of domains are formed in a display unit region overlapping with one of the plurality of pixel electrodes, with the alignment vectors of the plurality of domains differing from one another. The plurality of domains include a first domain, a second domain, a third domain, and a fourth domain disposed in order in a longitudinal direction of the display unit region. In a plan view of the plurality of domains, the alignment vector of the first domain and the alignment vector of the second domain have a mutually orthogonal relationship with the end points facing each other, the alignment vector of the second domain and the alignment vector of the third domain have a mutually parallel relationship with the start points facing each other, and the alignment vector of the third domain and the alignment vector of the fourth domain have a mutually orthogonal relationship with the end points facing each other.
According to another aspect of the present invention, a method for manufacturing the liquid crystal display panel includes carrying out the alignment process on the first photo-alignment film and the second photo-alignment film, the alignment process including emitting polarized light from a light source through a polarizer from an oblique direction, rotating a polarization axis of the polarizer within a range from −15° to +15° from a 45° azimuthal direction, and adjusting an exposure direction on surfaces of the first photo-alignment film and the second photo-alignment film to a substantially 45° azimuthal direction relative to an irradiation direction of light.
According to yet another aspect of the present invention, a photo-alignment processing device used in the method for manufacturing a liquid crystal display panel includes at least one photo-irradiation mechanism including a light source, a polarizer, and a rotation adjustment mechanism, and configured to emit light from the light source to a liquid crystal display panel substrate through the polarizer, and a stage on which the liquid crystal display panel substrate is mounted. Light is emitted while the liquid crystal display panel substrate is moved or while the light source is moved relative to the liquid crystal display panel substrate, an irradiation direction of the light relative to the liquid crystal display panel substrate and a movement direction of the liquid crystal display panel substrate or a movement direction of the light source are parallel, and the rotation adjustment mechanism is configured to rotate the polarization axis of the polarizer and adjust the exposure direction on a substrate plane of the liquid crystal display panel to a substantially 45° azimuthal direction relative to the irradiation direction of the light.
According to the present invention, it is possible to provide a liquid crystal display panel having excellent light utilization efficiency and display uniformity, a method for manufacturing a liquid crystal display panel suitable for manufacturing the liquid crystal display panel, and a photo-alignment processing device.
Embodiments of the present invention will be described hereinafter. The present invention is not limited to the contents described in the following embodiments, and appropriate design changes can be made within a scope that satisfies the configuration of the present invention.
First, a display method of the liquid crystal display device of the present embodiment will be described. In the liquid crystal display device in the present embodiment, light is incident on the liquid crystal display panel 100 from the backlight 110, and an amount of light passing through the liquid crystal display panel 100 is controlled by switching the alignment of the liquid crystal molecules 41 in the liquid crystal layer 40. The alignment of the liquid crystal molecules 41 is switched by applying voltage to the liquid crystal layer 40 using the plurality of pixel electrodes 31 and the counter electrode 51. When the voltage applied to the liquid crystal layer 40 is less than a threshold value (at the time of applying no voltage), the initial alignment of the liquid crystal molecules 41 is regulated by the first photo-alignment film 71 and the second photo-alignment film 72.
At the time of applying no voltage, the liquid crystal molecules 41 are aligned substantially perpendicular to the first substrate 30 and the second substrate 50. Here, the term “substantially perpendicular” means that the liquid crystal molecules 41 are aligned slightly tilted relative to the first substrate 30 and the second substrate 50 due to the photo-alignment process performed on the first photo-alignment film 71 and the second photo-alignment film 72. A pre-tilt angle of the liquid crystal molecules 41 relative to the first substrate 30 and the second substrate 50 at the time of applying no voltage is preferably greater than or equal to 85° and less than 90°. In a case that the voltage is applied between the pixel electrode 31 and the counter electrode 51, a vertical electric field occurs in the liquid crystal layer 40, and the liquid crystal molecules 41 are further tilted and aligned while the tilt azimuthal direction is maintained from the time of applying no voltage.
In the present specification, the tilt azimuthal directions of the liquid crystal molecules 41 will be described as appropriate using an alignment vector in which, in a plan view of the liquid crystal display panel 100, a major axis edge of the liquid crystal molecules 41 closer to the first substrate 30 is set to a start point (hereinafter, also referred to as “a tail of a liquid crystal director”) 41S, and a major axis edge of the liquid crystal molecules 41 closer to the second substrate 50 is set to an end point (hereinafter also referred to as “a head of the liquid crystal director”) 41T. Note that the alignment vector is in the same direction as the tilt azimuthal direction of the liquid crystal molecules 41 relative to the first photo-alignment film 71 closer to the first substrate 30, and is in an direction opposite to the tilt azimuthal direction of the liquid crystal molecules 41 relative to the second photo-alignment film 72 closer to the second substrate 50. In the present specification, the term “azimuthal direction” means a direction in a view projected onto a substrate plane without consideration of an inclination angle (a polar angle, pre-tilt angle) from a normal direction of the substrate plane. Further, the liquid crystal molecules 41 are aligned substantially vertically (slightly tilted) at the time of applying no voltage, and are aligned largely tilted at the time of applying the voltage while the tilt azimuthal direction at the time of applying no voltage is maintained, and thus the start point 41S and the end point 41T of the alignment vector may be confirmed while voltage is applied to the liquid crystal layer 40.
The first photo-alignment film 71 and the second photo-alignment film 72 are each a photo-alignment film in which a photo-alignment film material is deposited, and a photo-alignment process is performed thereon to cause it to exhibit a function of aligning the liquid crystal molecules 41 in a specific direction. The photo-alignment film material refers to a material in which a structural change generates when irradiated with light (electromagnetic waves) such as ultraviolet light or visible light, and thereby a property of regulating the alignment of the liquid crystal molecules 41 near a position where the structural change generates (alignment regulation force) is exhibited, and to general materials in which a level and/or direction of the alignment regulation force changes due to the structural change. For example, the photo-alignment film material includes a photoreactive site in which a reaction such as dimerization (dimer formation), isomerization, photo Fries transition, or decomposition is generated by light irradiation. Examples of the photo-reactive sites (functional groups) that dimerize and isomerize by light irradiation include cinnamate, cinnamoyl, 4-chalcone, coumarin, and stilbene. Examples of the photo-reactive sites (functional groups) that isomerize by light irradiation include azobenzene. Examples of the photo-reactive sites which are photo-Fries rearranged by light irradiation include phenolic ester structures. Examples of the photo-reactive sites which are decomposed by light irradiation include a dianhydride containing a cyclobutane ring such as 1,2,3,4-cyclobutanetetracarboxylic acid-1,2: 3,4-dianhydride (CBDA). Further, preferably the photo-alignment film material exhibits vertical alignability that can be used in a vertical alignment mode. Examples of the photo-alignment film material include polyamides (polyamic acids), polyimides, polysiloxane derivatives, methyl methacrylate, and polyvinyl alcohol including the photoreactive site.
A plurality of domains having different alignment vectors are provided in the pixel 10. These domains may be formed by varying the photo-alignment process performed on the first photo-alignment film 71 and the second photo-alignment film 72 from each other. When the voltage is applied to the liquid crystal layer 40, the liquid crystal molecules 41 are aligned tilted so as to be matched with the alignment vector of each domain.
In
As illustrated in
Note that in the first domain 10a, the second domain 10b, the third domain 10c, and the fourth domain 10d, an inter-substrate twist angle of the liquid crystal molecules 41 is preferably 45° or less, and more preferably substantially 0°. That is, in the first domain 10a, the second domain 10b, the third domain 10c, and the fourth domain 10d, an angle between the tilt azimuthal direction of the liquid crystal molecules 41 relative to the first photo-alignment film 71 closer to the first substrate 30 and the tilt azimuthal direction of the liquid crystal molecules 41 relative to the second photo-alignment film 72 closer to the second substrate 50 is preferably 45° or less, and more preferably substantially 0°.
Next, an overview of a configuration of the liquid crystal display device of the present embodiment will be described. The first substrate 30 may be an active matrix substrate (TFT substrate), for example. The TFT substrate can be one commonly used in the field of liquid crystal display panels.
The TFT formed of an oxide semiconductor is preferably used, channel thereof being formed in the oxide semiconductor. A compound (In—Ga—Zn—O) formed of indium (In), gallium (Ga), zinc (Zn), and oxygen (O), a compound (In—Tin—Zn—O) formed of indium (In), tin (Tin), zinc (Zn), and oxygen (O), a compound (In—Al—Zn—O) formed of indium (In), aluminum (Al), zinc (Zn), and oxygen (O), or the like may be used as the oxide semiconductor.
Each of the pixel electrodes 31 illustrated in
The second substrate 50 includes the counter electrode 51, and may be, for example, a color filter substrate (CF substrate). The color filter substrate can be one commonly used in the field of liquid crystal display panels.
Examples of the configuration of the color filter substrate include a configuration in which a black matrix formed into a lattice shape, a lattice, that is, the color filter formed inside the pixel, and the like are provided on the transparent substrate. The black matrix may be formed into the lattice shape in each pixel while overlapping with the boundary of the pixel, or also formed into the lattice shape in each half pixel while crossing the center of one pixel along the transverse direction. In a case that the black matrix overlapping with the region where a dark line occurs is formed, it is possible to make the dark line less likely to be observed.
The counter electrode 51 is disposed facing the pixel electrode 31 with the liquid crystal layer 40 interposed therebetween. The vertical electric field is formed between the counter electrode 51 and the pixel electrodes 31 and the liquid crystal molecules 41 are tilted, which allows the display to be performed. Color filters may be disposed in the order of red (R), green (G), and blue (B), in the order of yellow (Y), red (R), green (G), and blue (B), or in the order of red (R), green (G), blue (B), and green (G), in each column, for example.
The counter electrode 51 is preferably a planar electrode. The counter electrode 51 may be a transparent electrode, and can be formed of, for example, a transparent conductive material such as indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), or tin oxide (SnO), or an alloy thereof.
In the liquid crystal display panel 100 of the present embodiment, the first substrate 30 and the second substrate 50 are bonded to each other by the sealing member 80 provided to surround the liquid crystal layer 40, and thus the liquid crystal layer 40 is held in a predetermined region. An epoxy resin containing an inorganic or organic filler and a curing agent, or the like may be used as the sealing member 80, for example.
Further, in the present embodiment, a Polymer Sustained Alignment (PSA) technique may be used. In the PSA technique, a gap between the first substrate 30 and the second substrate 50 is filled with a liquid crystal composition containing a photopolymerizable monomer, the liquid crystal layer 40 is subsequently irradiated with light to polymerize the photopolymerizable monomer, a polymer is thus formed on the surfaces of the first photo-alignment film 71 and the second photo-alignment film 72, and the initial tilt (pre-tilt) of the liquid crystal is fixed by the polymer.
A polarization axis of the back face-side polarizer 20 and a polarization axis of the display surface-side polarizer 60 may be orthogonal to each other. Note that the polarization axis may be an absorption axis of the polarizer or a transmission axis of the polarizer. Typically, the back face-side polarizer 20 and the display surface-side polarizer 60 are those obtained by causing a polyvinyl alcohol (PVA) film to adsorb an anisotropic material such as a dichroic iodine complex and causing the anisotropic material to be aligned. Usually, a protection film such as a triacetyl cellulose film is laminated on both sides of the PVA film, and the PVA film puts to practical use. Note that an optical film such as a retardation film may be disposed between the back face-side polarizer 20 and the first substrate 30 and between the display surface-side polarizer 60 and the second substrate 50.
The backlight 110 is not particularly limited to a specific light as long as the backlight emits light including visible light, and may be any backlight that emits the light including only the visible light, or any backlight that emits the light including both the visible light and the ultraviolet light. A backlight that emits white light is suitably used in order to make color display by the liquid crystal display device possible. For example, a light emitting diode (LED) is suitably used as a type of the backlight. Note that, in the present specification, “visible light” means light (electromagnetic wave) having a wavelength that is greater than or equal to 380 nm and less than 800 nm.
In addition to the liquid crystal display panel 100 and the backlight 110, the liquid crystal display device of the present embodiment includes a plurality of members such as an external circuit such as a tape-carrier package (TCP) and a printed circuit board (PCB); an optical film such as a viewing angle increasing film and a luminance improving film; and a bezel (frame). Some components may be incorporated into another component. Components other than those described above are not particularly limited to specific components and, because such components can be those commonly used in the field of liquid crystal display devices, descriptions thereof are omitted.
Next, the effect obtained by provision of the liquid crystal display panel 100 of the present embodiment will be described below. Since in the liquid crystal display panel 100 of the present embodiment, a pixel including a plurality of domains is used, an excellent viewing angle characteristic is achieved, the occurrence of dark lines is suppressed, and high light utilization efficiency is achieved. In a case that a pixel including a plurality of domains is used, a region where the alignment of the liquid crystal molecules 41 is discontinuous may occur at the boundary between the domains adjacent to each other. In such a region, because the liquid crystal molecules 41 cannot be aligned in the intended direction, the light cannot be sufficiently transmitted during display, and the region is recognized as a dark portion. The dark portion formed in a linear shape is called a dark line. In a case that a dark line occurs, a luminance of the pixels decreases, and thus the light utilization efficiency of the liquid crystal display panel decreases. Further, in a case that dark lines occur in different positions on a pixel-by-pixel basis, a uniformity of the display deteriorates. In contrast, in the liquid crystal display panel 100 of the present embodiment, the alignment vectors of the plurality of domains in the pixel are controlled to a preferable relationship to perform display.
In the liquid crystal display panel 100 of the present embodiment, at two of the three boundaries between adjacent domains present in one pixel, an angular difference between the alignment vectors of the domains adjacent to each other is 90°. As a result, the number of double dark lines that occur in the pixels can be suppressed, and the light utilization efficiency and display uniformity can be improved. The principle by which the number of double dark lines is decreased is described below.
First, in the conventional liquid crystal display panel 400 illustrated in
In a case that double dark lines occur, the light utilization efficiency decreases. As a result, the display luminance decreases in a case that the backlight luminance is the same, and the power consumption increases in a case that the luminance of the backlight is increased to maintain the display luminance. Further, the double dark lines are not exactly two separate dark lines, and have an X shape pressed and crushed along the boundary between adjacent domains. Furthermore, because a position of a center point (intersection point) of the X shape is not defined, a position and a size of the dark lines differ on a pixel-by-pixel basis. Therefore, the double dark lines cause the optical characteristics of each pixel to be nonuniform and, as a result, the uniformity of the display when viewed across the entire panel is reduced. The variation in the occurrence of the double dark lines is due to the alignment of the boundary portions of the domains adjacent to each other being dependent on the relationship of the alignment of the domains adjacent to each other, and the like. Such variation in the occurrence of the double dark lines can be prevented by providing a structure for positioning (fixing) the center point (intersection point) of the X shape. For example, the shape of the dark lines can be stabilized by, for example, utilizing a shape of a slit (center slit) including a portion that extends substantially parallel with a domain boundary and an arrangement pattern, described later.
While the number of double dark lines that occur in a pixel is preferably small, in the conventional liquid crystal display panel 400 illustrated in
In contrast, in the liquid crystal display panel 100 of the present embodiment, a domain arrangement is devised such that, at two of the three boundaries between adjacent domains present in one pixel, an angular difference between the alignment vectors of the domains adjacent to each other is 90°. That is, at the boundary between the first domain 10a and the second domain 10b, and the boundary between the third domain 10c and the fourth domain 10d, the rotation angle of the liquid crystal directors is controlled to 90° and the occurrence of double dark lines is suppressed.
In the liquid crystal display panel 100 of the present embodiment, at only the boundary between the second domain 10b and the third domain 10c among the three boundaries of adjacent domains present in one pixel, an angular difference between the alignment vectors of the domains adjacent to each other is 180°, making it possible to suppress the number of double dark lines for each pixel to one.
In the liquid crystal display panel 100 of the present embodiment, the pixel electrode 31 is provided with a slit including a portion extending substantially parallel with the domain boundary, making it possible to cause the double dark lines that occur at the boundary between the second domain 10b and the third domain 10c to substantially disappear as well.
Note that in the present specification, “substantial elimination of the double dark lines” means that the occurrence of double dark lines is not clearly visually recognized, and is a concept encompassing not only a state in which the double dark lines are not formed, such as a case in which all the double dark lines disappear, or a case in which, among the two dark lines constituting the double dark lines, one dark line disappears and only the remaining one dark line is visually recognized; but also a state in which, among the two dark lines constituting the double dark lines, one dark line is less likely to be visually recognized and only the remaining one dark line is visually recognized. In a case that the center slit 33 is provided, the center slit 33 may not result in disappearance of the dark lines constituting the double dark lines when the center slit 33 is thin (has a small slit width), but at least one of the two dark lines is narrowed, making it possible to achieve a higher transmittance in the domain boundary region than when the center slit 33 is not provided, and thus the result can be evaluated as having achieved substantial elimination of the double dark lines.
On the other hand, the pixel electrode 31 having the shape illustrated in
The dark lines that occur in a pixel are not only double dark lines. Dark lines may also occur around the pixel (at or near the electrode edge). From the perspective of improving light utilization efficiency, preferably such dark lines are also caused to disappear. Dark lines around a pixel occur in locations where the head of the liquid crystal director faces the electrode edge. In such a location, the alignment direction of the liquid crystal molecules resulting from electric field distortion at the electrode edge and the alignment direction resulting from the photo-alignment process in the electrode differ by substantially 135° and thus, during the process of both alignments being continuously connected, a portion in which the major axis of the liquid crystal molecules and the absorption axes of the back face-side polarizer 20 and the display surface-side polarizer 60 orthogonal to each other are parallel (or perpendicular) is formed, and portions thereof are recognized as dark lines.
Examples of methods for eliminating dark lines around a pixel includes providing a fine slit at least at an edge of the pixel electrode 31. According to this method, the alignment distortion of the liquid crystal molecules at the edge of the pixel electrode 31 is reduced, and the liquid crystal can be aligned in a desired direction at a position closer to the electric field edge, making it possible to suppress the occurrence of dark lines. Here, “fine slit” refer to a portion in which a plurality of pairs of a slit portion extending in a direction parallel with the desired alignment direction (alignment vector) of the liquid crystal and an electrode portion are formed side by side. Note that each of the slit portions of the fine slit may be narrower than the center slit 33, may have about the same width as that of the center slit 33, or may be thicker than the center slit 33.
Specific examples of the fine slit include the following first to fourth configurations.
In the first configuration, the fine slit is provided to the electrode edge closer to the head of the liquid crystal director.
In the second configuration, a fine slit 36 is provided not only to the electrode edge, but also along the boundary of adjacent domains that satisfy the domain boundary condition A, and the boundary of the adjacent domains is constituted by a solid electrode. According to the second configuration, due to an action of aligning the liquid crystal contained in the fine slit 36 in the desired alignment direction, an alignment distortion near the domain boundary can be suppressed, and the region where the alignment change occurs at the boundary between the adjacent domains that satisfy the domain boundary condition A becomes narrower, making it possible to narrow the dark lines. The boundary between the adjacent domains is configured by a solid electrode because an inclination of the electric field and a tilt angle (polar angle) component of the alignment of the liquid crystal molecules 41 are aligned. Note that, in the present specification, the term “inclination of the electric field” refers to a change in the electric field generated by a change in electrode density or the like, and indicates an electric field that includes components in a plane perpendicular to the substrate surface and influences an inclination angle (polar angle) of the liquid crystal molecules. In contrast, a change in the electric field generated by the fine slit 36 is referred to as “field distortion”. The fine slit 36 causes electrical potential having a groove shape parallel with the slit portion to be generated and a lateral electric field component parallel with the substrate surface and perpendicular to the slit portion to be generated. The alignment direction of the liquid crystal molecules changes due to this lateral electric field component, and the liquid crystal molecules are aligned in a direction parallel with the slit portion.
In the third configuration, the fine slit 36 is provided to increase an arrangement density of the electrode from the electrode edge toward an electrode inner side (center). According to the third configuration, the discontinuous electric field change at an interface between the region where the fine slit 36 is disposed and the region where the fine slit 36 is not disposed can be suppressed and changes in the electric field can be smoothened, making it possible to improve a response performance, a finger push recovery performance, and the like of the liquid crystal. In addition, because regions where voltages applied to the liquid crystal layer 40 differ from each other can be formed in the pixel electrode 31, a viewing angle improvement effect can also be achieved.
In the fourth configuration, the fine slit 36 is provided across the entire electrode. According to the fourth configuration, discontinuous electric field changes in the pixel electrode 31 can be eliminated, and the response performance, the finger push recovering performance, and the like of the liquid crystal can be improved.
In relation to the first to fourth configurations,
The corresponding relationship between the pixel electrodes illustrated in
Next, evaluation tests performed on the liquid crystal display panel 100 of the present embodiment will be described.
The liquid crystal display panel 100 of the present embodiment preferably has a pixel density (resolution) of 90 ppi or greater.
Mode efficiency ratio=Mode efficiency of liquid crystal display panel 100 in embodiment/Mode efficiency of liquid crystal display panel 300 in FIG. 25
The graph of
To optimize the mode efficiency, the relationship between the alignment vectors of the domains and the dark lines produced between adjacent domains or at the pixel edge was evaluated by the following method.
1. The polarizers were set in a crossed-Nicol state and, with a square wave having a frequency of 30 Hz and a voltage of 7 V applied to the evaluation cell, a micrograph of the pixel was taken. The imaging conditions included an objective lens having a magnification of 10, an ISO sensitivity of ISO200, and an exposure time of ¼ seconds.
2. The captured image was converted by gamma conversion to obtain gray-scale and luminance linearity.
3. From the pixel image, a luminance profile of the pixel in the major axis direction (direction perpendicular to the dark lines) was taken, a profile of the dark line portion was extracted, and a total luminance was calculated.
4. A luminous evaluation was conducted on various dark lines, and a relative luminance ratio was calculated using the luminance of the dark lines under the domain boundary condition A as 1.
When the end points of the alignment vectors of adjacent domains face each other and the alignment vectors form an angle of 90° (domain boundary condition A).
When the start points of the alignment vectors of adjacent domains face each other and the alignment vectors form an angle of 180° (domain boundary condition B).
When the end points of the alignment vectors of adjacent domains face each other and the alignment vectors form an angle of 180° (domain boundary condition C).
When the start points of the alignment vectors of adjacent domains face each other and the alignment vectors form an angle of 90° (domain boundary condition D).
When the start points and the end points of the alignment vectors of adjacent domains face each other and the alignment vectors form an angle of 90° (domain boundary condition E).
When the end point of the alignment vector of the domain faces the pixel edge portion (domain boundary condition F).
When the start point of the alignment vector of the domain faces the pixel edge portion (domain boundary condition G).
The evaluation results were as shown in Table 1 below. Note that the results obtained by the image processing and the results obtained by the simulation were substantially the same. Therefore, the following description is made using the results obtained by simulation. It was confirmed that the dark lines of the domain boundary conditions A, D were lightest and effective in enhancing transmittance. Further, the dark line luminance of the pixel edge portion was the same as that under the domain boundary condition A in a case that the end point of the alignment vector of the domain faces the pixel edge portion (domain boundary condition E), and was 1.08 times that under the domain boundary condition A in a case that the start point of the alignment vector of the domain faces the pixel edge portion (domain boundary condition F).
The present inventors discovered that transmittance at a dark line is improved by providing slits (ITO gaps) having an optimal width at positions directly below the dark line of the pixel electrode 31. According to the simulation, it was confirmed that a mode efficiency improvement effect was not achieved when the width of the slit is narrow or wide, and that there is an optimal width. In the domain arrangement of the present embodiment, the width of the center slit 33 provided at the boundary (domain boundary condition B) between the second domain 10b and the third domain 10c is preferably from 1 to 8 μm, and more preferably from 2.5 to 6 μm.
In the present embodiment, the first domain 10a, the second domain 10b, the third domain 10c, and the fourth domain 10d disposed in that order along the longitudinal direction of the pixel are adjusted so as to have an array of domain boundary conditions A-B-A. This is because a relationship between the alignment pattern and the dark line pattern and a slit width of the pixel electrode provided at dark lines are optimized, and thus, the display quality can be improved by maximization of the mode efficiency and elimination of the double dark lines.
For example, for the pixel having the array of the domain boundary conditions A-B-A illustrated in
(1.00×2+1.04+1.08×2)/5=1.04 (A)
On the other hand, for the pixel having an array of the domain boundary conditions C-D-C illustrated in
(0.90×2+1.00+1.08×2)/5=0.99 (B)
As described above, the pixel having the array of the domain boundary conditions A-B-A is provided with the center slit 33 at the boundary (domain boundary condition B) between the second domain 10b and the third domain 10c, substantially eliminating the double dark lines, and thus making it possible to improve mode efficiency. In a case that the domain boundary condition A is included in the array to narrow a width of dark lines and the slit is provided in the dark line portion under the domain boundary condition B, the luminance is maximized.
To identify an optimal combination of an electrode width L between the fine slits 36 and a width S of the fine slit 36, the mode efficiency was measured by changing the conditions, namely L and S, for the pixel electrode provided with the fine slit 36 having the shape and arrangement pattern illustrated in
The graphs of
In the graphs of
As a result, the electrode width (Line) between the fine slits 36 and the width (Space) of the fine slit 36 exhibited the same tendency in a case that the pixel pitch was 180 μm and in a case that the pixel pitch was 240 μm. That is, to obtain a mode efficiency greater than that without the fine slit 36, the width (Space) of the fine slit 36 and the pitch (Line+Space) of the fine slit 36 preferably satisfy the conditions below.
Width (Space) of fine slit 36 ≤5.1 μm
Pitch (Line+Space) of fine slit 36 ≤11 μm
Further, to ensure that a mode efficiency is reduced from the mode efficiency in the case that Line/Space=2.1 μm/3.1 μm by half of the difference between the mode efficiency in the case that Line/Space=2.1 μm/3.1 μm and the mode efficiency in the case that the fine slit is not provided, the width (Space) of the fine slit 36 and the pitch (Line+Space) of the fine slit 36 more preferably satisfy the conditions below.
Width (Space) of fine slit 36 <4.3 μm
Pitch (Line+Space) of fine slit 36 <8.3 μm
Next, a method for manufacturing the liquid crystal display panel 100 of the present embodiment will be described below. The method for manufacturing the liquid crystal display panel 100 of the present embodiment is not particularly limited to a specific method, but a method usually used in the field of liquid crystal display panels can be adopted. For example, the alignment process with respect to the first photo-alignment film 71 and the second photo-alignment film 72 is performed by a photo-alignment process in which light (electromagnetic waves) such as ultraviolet light and visible light is emitted. The photo-alignment process may be performed by using, for example, a device that includes a light source configured to irradiate the first photo-alignment film 71 and the second photo-alignment film 72 with light and has a function capable of continuously performing scanning exposure over a plurality of pixels. Examples of specific aspects of the scanning exposure include the aspect of irradiating the surface of the substrate with a light beam emitted from the light source while moving the substrate, the aspect of irradiating the surface of the substrate with a light beam emitted from the light source while moving the light source, and the aspect of irradiating the surface of the substrate with a light beam emitted from the light source while moving the light source and the substrate.
A specific example of the alignment process will be described below.
The photo-irradiation mechanism 280 includes a light source 220, a polarizer 230, and a rotation adjustment mechanism 260. The light source 220 and the polarizer 230 may be disposed in a lamp box 270. A type of the light source 220 is not particularly limited to a specific type, but a light source commonly used in the field of photo-alignment processing devices can be used. For example, a low-pressure mercury lamp, a deuterium lamp, a metal halide lamp, an argon resonance lamp, a xenon lamp, and the like can be used.
Light 221 emitted from the light source 220 may be light (electromagnetic wave) such as ultraviolet light and visible light, and the light 221 preferably has a wavelength from 280 nm to 400 nm.
For example, the polarizer 230 extracts linearly polarized light from the light emitted from the light source 220 toward the liquid crystal display panel substrate 30. Note that the term “polarization axis” refers to a direction in which the amount of light passing through the polarizer is maximum. Examples of the polarizer 230 include an organic resin polarizer, a wire grid polarizer, and a Polarizing beam splitter (PBS).
Examples of the organic resin polarizer include a polarizer obtained by causing polyvinyl alcohol to adsorb iodine and extending the resultant in a sheet shape, and the like.
For example, the wire grid polarizer includes an optical transparency base material and a plurality of metal thin wires formed on the optical transparency base material, and the plurality of metal thin wires are disposed in a period shorter than the wavelength of light incident on the wire grid polarizer. The metal thin wire is made of a light absorbing metal material such as chromium, for example. When the wire grid polarizer is irradiated with the light while overlapping with the liquid crystal display panel substrate 30, the liquid crystal molecules are aligned in the azimuthal direction orthogonal to an extending direction of the metal thin wire. In a case that the polarizer 230 is the wire grid polarizer, the polarization axis is the azimuthal direction orthogonal to the extending direction of the metal thin wire. Alignment division treatment can efficiently be performed using the wire grid polarizer having a different extending direction of the metal thin wire.
Examples of the polarizing beam splitter include a cube type and a plate type. Examples of the cube type PBS include a PBS in which inclined surfaces of two prisms are bonded together and an optical thin film is deposited on one of the inclined surfaces.
The polarizer 230 may be disposed perpendicular to an irradiation axis of the light. In a case that the polarizer 230 is not disposed perpendicular to the irradiation axis of the light, the alignment of the liquid crystal molecules may be influenced by a waveguide effect or the like in the polarizer 230. The irradiation axis of the light is a direction in which the light 221 emitted from the light source 220 toward the liquid crystal display panel substrate 30 propagates linearly. The polarizer being disposed perpendicular to the irradiation axis of the light means that the polarizer is disposed such that the light is emitted from the polarizer toward the liquid crystal display panel substrate in a normal direction of the polarizer, and the term “perpendicular” means a range in which an angle formed between the normal line of the polarizer and the irradiation axis of the light is less than 0.5°.
A wavelength selection filter 235 may be included between the light source 220 and the polarizer 230. A main wavelength of the light emitted through the wavelength selection filter 235 may be from 280 nm to 400 nm. Light having a selection wavelength from 280 nm to 400 nm can generate a structural change of a material constituting the first photo-alignment film 71 and exhibiting the photo-alignment characteristic, and cause the material to exert the alignment regulation force. An intensity of the light emitted from the light source may be from 10 mJ/cm2 to 100 mJ/cm2.
The wavelength selection filter 235 is not particularly limited to a specific filter, and a wavelength selection filter commonly used in the field of photo-alignment processing devices can be used. Examples of the wavelength selection filter 235 include a wavelength selection filter in which a substance absorbing light having a wavelength other than the transmission wavelength is dispersed in the filter, a wavelength selection filter in which the surface of the filter is coated with a substance reflecting light having a wavelength other than the transmission wavelength, or the like.
The irradiation angle of the light relative to the liquid crystal display panel substrate 30 may be from 30° to 60°. The irradiation angle is represented by θ1 in
An extinction ratio of the polarizer may be from 50:1 to 500:1. The extinction ratio is represented by Tmax:Tmin, where Tmax is maximum transmittance in a case that the polarizer is irradiated with the light and Tmin is minimum transmittance obtained by rotating the polarizer by 90°. The light in the more desired polarization axis direction can be taken out as the extinction ratio is great (a value of Tmax in a case that Tmin is set to 1), and thus a variation in the tilt azimuthal direction of the liquid crystal molecules can be reduced.
The rotation adjustment mechanism 260 rotates a polarization axis 231 of the polarizer 230, and adjusts an exposure direction 253 on the surface of the liquid crystal display panel substrate 30 such that the exposure direction 253 substantially becomes 45° relative to an irradiation direction 252 of the light. By setting the exposure direction 253 to substantially 45° relative to the irradiation direction 252 of the light, the photo-alignment process can be performed on the liquid crystal display panel substrate 30 by scanning exposure having excellent productivity while a movement direction 251 of the liquid crystal display panel substrate 30 is kept in parallel with the irradiation direction 252 of the light. As illustrated in
For example, the polarization axis 231 is adjusted using the rotation adjustment mechanism 260 by the following method. The polarizer 230 is set such that the polarization axis 231 becomes 45° relative to the irradiation direction 252 of the light. The azimuthal direction of the polarization axis before the polarization axis is adjusted by the rotation adjustment mechanism may be referred to as “a 45° azimuthal direction”. Next, the rotation adjustment mechanism 260 rotates the polarizer 230 from the 45° azimuthal direction to adjust the azimuthal direction of the polarization axis 231 on the basis of data calculated by geometric computation in consideration of the light irradiation angle relative to the liquid crystal display panel substrate and a refractive index of the alignment film material. The rotation adjustment mechanism 260 can match the azimuthal direction of the polarization axis of the polarizer relative to the irradiation direction of the light with the exposure direction on the surface of the liquid crystal display panel substrate to set the tilt azimuthal direction of the liquid crystal molecules in the liquid crystal display panel to a desired angle. Note that when the photo-alignment process is performed without the rotation adjustment mechanism 230 while the polarization axis 231 is fixed to the 45° azimuthal direction, the tilt azimuthal direction of the liquid crystal molecules deviates by about from 10° to 45°.
The rotation adjustment mechanism 260 may rotate the polarization axis of the polarizer 230 within a range from −15° to +15° from the 45° azimuthal direction. When the rotation adjustment mechanism rotates the polarization axis within the range from −15° to +15°, even in a case where the light irradiation angle is changed relative to the liquid crystal display panel substrate 30, the exposure direction 253 can be adjusted to set the tilt azimuthal direction of the liquid crystal molecules to the desired angle. For example, the polarization axis 231 is rotated from the 45° azimuthal direction by +7.55° and set to 52.55° in order to adjust the exposure direction 253 on the surface of the liquid crystal display panel substrate plane to substantially 45° relative to the irradiation direction 252 of the light.
The photo-alignment processing device 200 may further include a rotation mechanism 264. The rotation mechanism 264 can rotate the polarization axis 231 of the polarizer 230 by selecting either substantially 45° or substantially 90° from the 45° azimuthal direction. In a case that a +45° azimuthal direction clockwise relative to the irradiation direction 252 of the light is set to the +45° azimuthal direction, and the polarization axis 231 of the polarizer 230 is rotated by 90° from the +45° azimuthal direction, the polarization axis 231 after rotation becomes a −45° azimuthal direction relative to the irradiation direction of the light. The polarization axis 231 is rotated by 90° from the +45° azimuthal direction and further adjusted by the rotation adjustment mechanism 260, which allows the light irradiation to be performed while the exposure direction 253 is set to substantially 45° relative to the irradiation direction 252 of the light before and after the rotation. Consequently, the embodiment is suitable for manufacturing a liquid crystal display panel having a new alignment control mode, in which four alignment regions having mutually different tilt azimuthal directions of the liquid crystal molecules are disposed in the longitudinal direction of the pixel as illustrated in
The rotation mechanism 264 can also rotate the polarization axis 231 of the polarizer 230 from the 45° azimuthal direction by substantially 45°. When the polarization axis 231 is rotated by 45° from the 45° azimuthal direction, the polarization axis 231 after rotation is parallel with the irradiation direction of the light, and thus the conventional photo-alignment process in which the polarization axis of the polarizer and the irradiation direction of the light are caused to match can also be performed.
The stage 250 is a stage on which the liquid crystal display panel substrate 30 is mounted. The liquid crystal display panel substrate 30 is fixed onto the stage 250 and irradiated with the light while being moved, or the liquid crystal display panel substrate 30 is irradiated with the light while the light source is moved relative to the liquid crystal display panel substrate 30. The photo-alignment process can be efficiently performed by performing such a scanning exposure. The movement direction of the liquid crystal display panel substrate 30 or the movement direction of the light source 220 is parallel with the irradiation direction of the light relative to the liquid crystal display panel substrate 30, and thus an incident angle of light incident on the substrate from the light source becomes substantially the same in a light irradiation area of the light source, making a pre-tilt angle (polar angle) provided to the liquid crystal molecules also become substantially the same. For this reason, a variation in pre-tilt angle in the light irradiation area is suppressed to manufacture the liquid crystal display panel having excellent display quality. The photo-alignment processing device 200 may include a stage scanning mechanism that moves the stage 250 and/or a light source scanning mechanism that moves the light source 220. The term “parallel” includes a range in which the angle formed between the irradiation direction of the light and the movement direction of the liquid crystal display panel substrate 30 or the movement direction of the light source 220 is less than 5°.
In addition to the mechanisms described above, the photo-alignment processing device 200 may include a light blocking member 240. The alignment division treatment can be performed by performing the photo-alignment process while a portion not irradiated with the light is blocked by the light blocking member 240.
With use of the photo-alignment processing device, the azimuthal direction of the polarization axis of the polarizer relative to the irradiation direction of the light can be made to match the exposure direction on the surface of the liquid crystal display panel substrate and set the tilt azimuthal direction of the liquid crystal molecules 41 in the liquid crystal display panel 100 to the desired angle.
An example of a photo-alignment processing step using the photo-alignment processing device 200 will be described below with reference to
As illustrated in
An aspect of the present invention is a liquid crystal display panel including, in the following order, a first substrate including a plurality of pixel electrodes and a first photo-alignment film, a liquid crystal layer containing liquid crystal molecules, and a second substrate including a common electrode and a second photo-alignment film. Given an alignment vector in which a major axis edge of the liquid crystal molecules closer to the first substrate is set to a start point and a major axis edge of the liquid crystal molecules closer to the second substrate is set to an end point, the first photo-alignment film and the second photo-alignment film are subjected to an alignment process such that a plurality of domains are formed in a display unit region overlapping with one of the plurality of pixel electrodes, with the alignment vectors of the plurality of domains differing from one another. The plurality of domains include a first domain, a second domain, a third domain, and a fourth domain disposed in order in a longitudinal direction of the display unit region. In a plan view of the plurality of domains, the alignment vector of the first domain and the alignment vector of the second domain have a mutually orthogonal relationship with the end points facing each other, the alignment vector of the second domain and the alignment vector of the third domain have a mutually parallel relationship with the start points facing each other, and the alignment vector of the third domain and the alignment vector of the fourth domain have a mutually orthogonal relationship with the end points facing each other.
The liquid crystal molecules may be aligned substantially perpendicular to the first substrate and the second substrate in a case that no voltage is applied to the liquid crystal layer, and aligned tilted to match each of the alignment vectors of the plurality of domains in a case that voltage is applied to the liquid crystal layer.
In each of the plurality of domains, an inter-substrate twist angle of the liquid crystal molecules may be 45° or less.
Each of the plurality of pixel electrodes may include, in a boundary region between the second domain and the third domain, a slit disposed along the boundary region and a connecting portion connecting a region overlapping with the second domain and a region overlapping with the third domain.
The slit may include a portion parallel with or perpendicular to an end of a pixel electrode of the plurality of pixel electrodes or a portion parallel with or perpendicular to a source wiring line, a gate wiring line, or an auxiliary capacitance wiring line. The slit may include a branch portion forming an angle of substantially 45° relative to a long side portion of the slit and extending directly from the long side portion of the slit. The slit may include a wide portion in at least one location. The slit may include a plurality of regions with differing positions of upper sides and/or lower sides. Each of the plurality of pixel electrodes may further include a plurality of the slits with differing upper sides and/or lower sides. A width of the slit may be from 1 to 8 μm.
Each of the plurality of pixel electrodes may include, at least on an edge of each of the plurality of pixel electrodes, a plurality of fine slits parallel with the alignment vector. The plurality of first fine slits may each have a width of 5.1 μm or less. The plurality of first fine slits may each have a width of 4.3 μm or less. The plurality of first fine slits may be disposed periodically every 11 μm or less. The plurality of first fine slits may be disposed periodically every 8.3 μm or less.
Each of the plurality of pixel electrodes may include a solid electrode portion sandwiched between disposed regions of the plurality of fine slits, in at least one of a boundary region between the first domain and the second domain or a boundary region between the third domain and the fourth domain.
Each of the plurality of pixel electrodes may have a structure having an arrangement density of electrodes that increases from an edge to a center in at least one of a region overlapping with the first domain, a region overlapping with the second domain, a region overlapping with the third domain, or a region overlapping with the fourth domain.
In each of the plurality of pixel electrodes, the plurality of fine slits may be provided in a region overlapping with the first domain, the second domain, the third domain, and the fourth domain.
The liquid crystal display panel may have a pixel density of 90 ppi or greater.
According to another aspect of the present invention, a method for manufacturing the liquid crystal display panel includes carrying out the alignment process on the first photo-alignment film and the second photo-alignment film, the alignment process including emitting polarized light from a light source through a polarizer from an oblique direction, rotating a polarization axis of the polarizer within a range from −15° to +15° from a 45° azimuthal direction, and adjusting an exposure direction on surfaces of the first photo-alignment film and the second photo-alignment film to a substantially 45° azimuthal direction relative to an irradiation direction of light.
According to yet another aspect of the present invention, a photo-alignment processing device used in the method for manufacturing a liquid crystal display panel includes at least one photo-irradiation mechanism including a light source, a polarizer, and a rotation adjustment mechanism, and configured to emit light from the light source to a liquid crystal display panel substrate through the polarizer, and a stage on which the liquid crystal display panel substrate is mounted. Light is emitted while the liquid crystal display panel substrate is moved or while the light source is moved relative to the liquid crystal display panel substrate, an irradiation direction of the light relative to the liquid crystal display panel substrate and a movement direction of the liquid crystal display panel substrate or a movement direction of the light source are parallel, and the rotation adjustment mechanism is configured to rotate the polarization axis of the polarizer and adjust the exposure direction on a substrate plane of the liquid crystal display panel to a substantially 45° azimuthal direction relative to the irradiation direction of the light.
Number | Date | Country | Kind |
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2017-151018 | Aug 2017 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2018/028166 | 7/27/2018 | WO | 00 |