Patent Application
20060115605
The present invention relates to a liquid crystal medium, to its use for electro-optical purposes, and to displays containing this medium.
There is a great demand for LCDs (liquid crystal displays), in particular of the matrix type, that have very high specific resistance at the same time as a large working-temperature range, short response times even at low temperatures and low threshold voltage. In particular, LC media for TN (twisted nematic) display cells are required which facilitate the following advantages in the cells:
For TN and STN (supertwisted TN) cells, LC media are desired which enable greater multiplexability, lower threshold voltages and broader nematic phase ranges, in particular at low temperatures. A further widening of the available parameter latitude (clearing point, smectic-nematic transition or melting point, viscosity, dielectric parameters, elastic parameters) is also desired.
For TV and monitor applications, LC media are desired which have a fast response time and a low threshold voltage, furthermore a good LTS (low temperature stability). Also, depending on the thickness of the switchable LC layer, a moderate or high birefringence may be required.
However, the LC media known in prior art have the disadvantage that they often do not allow all these requirements to be achieved simultaneously, without negatively affecting the other parameters of the LC cell.
The present invention has an aim of providing LC media, in particular for active matrix displays like those of the TFT (thin film transistor) type, and generally for TN or STN displays, which do not have the above-mentioned disadvantages or only do so to a reduced extent, and preferably simultaneously have very high specific resistances, low threshold voltages, an improved LTS and fast switching times. Another aim is to extend the pool of LC media available to the expert. Other aims will become evident to those in the art from the following description.
It has been found that these aims, for example, can be achieved if LC media according to the present invention are used in displays.
The present invention thus relates to an LC medium comprising, by weight:
Especially preferred is an LC medium comprising the following compounds
Further preferred is an LC medium comprising, by weight:
In the pure state, the compounds of the formulae I-VIII are colorless and form liquid crystalline mesophases in a temperature range which is favorably located for electro-optical use. They are stable chemically, thermally and to light.
The compounds of the formulae I-VIII are prepared by methods known per se, as described in the literature (for example in the standard works, such as Houben-Weyl, Methoden der organischen Chemie [Methods of Organic Chemistry], Georg-Thieme-Verlag, Stuttgart), to be precise under reaction conditions which are known and suitable for the said reactions. Use can also be made here of variants which are known per se, but are not mentioned here in greater detail.
The invention also relates to electro-optical displays which contain LC media of this type, and to the use of these LC media for electro-optical purposes. Very preferred are TFT displays having two plane-parallel outer plates, which, together with a frame, form a cell, integrated non-linear elements for switching individual pixels on the outer plates, and a nematic LC medium according to the present invention having positive dielectric anisotropy and a high specific resistance which is located in the cell.
The LC mixtures according to the invention enable a significant widening of the available parameter latitude. Especially, it was found that they have a fast switching time, low threshold voltage, good LTS, high specific resistance, high UV stability and high capacity holding ratio (HR) [as defined in S. Matsumoto et al., Liquid Crystals 5, 1320 (1989); K. Niwa et al., Proc. SID Conference, San Francisco, June 1984, p. 304 (1984); G. Weber et al., Liquid Crystals 5, 1381 (1989)]. Also, the achievable combinations of clearing point, rotational viscosity γ1, low Δn and dielectric anisotropy are superior to materials known from prior art.
The construction of an LC display according to the invention, including polarisers, electrode base plates and surface-treated electrodes corresponds to the conventional construction for displays of this type. The term “conventional construction” covers all derivatives and modifications of the LC display, in particular including matrix display elements based on poly-Si TFT or MIM (metal-insulator-metal). A significant difference between the displays according to the invention and the conventional displays based on the TN cell consists, however, in the choice of the parameters of the LC layer.
The LC mixtures which can be used in accordance with the invention are prepared in a manner conventional per se. In general, the desired amount of the components used in the lesser amount is dissolved in the components making up the principal constituent, advantageously at elevated temperature. It is also possible to mix solutions of the components in an organic solvent, for example in acetone, chloroform or methanol, and to remove the solvent again, for example by distillation, after thorough mixing.
The LC media may also comprise further additives known to the person skilled in the art and described in the literature. For example, 0-15% by weight of pleochroic dyes, stabilizers or chiral dopants can be added. Suitable dopants and stabilizers are shown below.
In the present application and in the examples below, the structures of the components of the LC media are indicated by the following acronyms:
The following list shows possible chiral dopants that can be added to the LC media according to the present invention, preferably in proportions of from 0.1 to 10 wt.-%, very preferably from 0.1 to 6 wt.-%:
The following list shows possible stabilizers that can be added to the LC media according to the present invention:
Above and below, percentages are percent by weight. All temperatures are given in degrees Celsius. m.p. denotes melting point, cl.p.=clearing point. Furthermore, C=crystalline state, N=nematic phase, S=smectic phase and I=isotropic phase. The data between these symbols represent the transition temperatures. An denotes the optical anisotropy and no the refractive index (589 nm, 20° C.). The flow viscosity ν20 (mm2/sec) and the rotational viscosity γ1 [mPa·s] were each determined at 20° C. V10 denotes the voltage for 10% transmission (viewing angle perpendicular to the plate surface). ton denotes the switch-on time and toff the switch-off time at an operating voltage corresponding to 2 times the value of V10. Δε denotes the dielectric anisotropy (Δε=ε∥−ε⊥, where ε∥ denotes the dielectric constant parallel to the longitudinal molecular axes and ε⊥ denotes the dielectric constant perpendicular thereto). The electro-optical data were measured in a TN cell at the 1st minimum (i.e. at a d·Δn value of 0.5 μm) at 20° C., unless expressly stated otherwise. The optical data were measured at 20° C., unless expressly stated otherwise.
Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The following preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.
In the foregoing and in the following examples, all temperatures are set forth uncorrected in degrees Celsius and, all parts and percentages are by weight, unless otherwise indicated.
The entire disclosure of all applications, patents and publications, cited herein and of corresponding Europe Application No. 04028195.8, filed Nov. 26, 2004, is incorporated by reference herein.
The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions of this invention for those used in the preceding examples.
From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditi
| Number | Date | Country | Kind |
|---|---|---|---|
| 04028195.8 | Nov 2004 | EP | regional |
