Liquid crystalline compound and use thereof

Abstract

A process for producing a liquid crystalline compound represented by the following general formula (A): ##STR1##

Description

BACKGROUND OF THE INVENTION

The present invention relates to a liquid crystalline compound and use thereof. More particularly, the present invention relates to a process for producing a novel liquid crystalline compound, which exhibits liquid crystallinity and, in addition, photoconductivity and fluorescence, and use of the liquid crystalline compound in a liquid crystalline charge transport material.

Liquid crystalline compounds having various structures are known in the art and have been extensively used as a liquid crystal display material.

Materials, wherein a charge transport molecule which serves as a charge transport site are dissolved or dispersed in a matrix material, such as a polycarbonate resin, or materials, wherein a charge transport molecule structure pends as a pendant on a polymer backbone, such as polyvinyl carbazole, are known in the art. These materials have been extensively used as materials for photoconductors in copying machines, printers and the like.

For the above conventional charge transport materials, in the case of dispersive charge transport materials, that the charge transport molecule has high solubility in the polymer as a matrix is preferred from the viewpoint of improving the charge transport capability. In fact, however, bringing the charge transport molecule to a high concentration in the matrix leads to crystallization of the charge transport molecule in the matrix, and, for this reason, the upper limit of the concentration of the charge transport molecule is generally 20 to 50% by weight although it varies depending upon the kind of the charge transport molecule. This means that the matrix not having charge transport capability occupies not less than 50% by weight of the whole material. This in turn raises a new problem that the charge transport capability and response speed of a film formed from the material are limited by the excess matrix present in the material.

On the other hand, in the case of the pendant type charge transport polymer, the proportion of the pendant having charge transport capability can be increased. This polymer, however, involves many practical problems associated with mechanical strength, environmental stability and durability of the formed film, film-forming properties and the like. In this type of charge transport material, the charge transport pendants are locally located in close proximity, and the local proximity portion serves as a stable site in hopping of charges and functions as a kind of trap, unfavorably resulting in lowered charge mobility.

For all the above charge transport materials, electrical properties of such amorphous materials raise a problem that, unlike crystalline materials, the hopping site fluctuates in terms of space, as well as in terms of energy. For this reason, the charge transport depends greatly upon the concentration of the charge transport site, and the mobility is generally about 10.sup.-6 to 10.sup.-5 cm.sup.2 /vs which is much smaller than that of the molecular crystal, 0.1 to 1 cm.sup.2 /vs. Further, the amorphous materials have an additional problem that the charge transport properties depend greatly upon temperature and field strength. This is greatly different from the crystalline charge transport materials.

A polycrystalline charge transport material is a promissing material in applications where a charge transport layer having a large area is necessary, because it can form an even charge transport film having a large area can be evenly formed. The polycrystalline material, however, is inherently an uneven material from the microscopic viewpoint and involves a problem that a defect formed in the interface of particles should be inhibited.

Accordingly, the present invention aims to solve the above problems of the prior art and to provide a novel charge transport material which simultaneously realizes advantages of the amorphous materials, that is, structural flexibility and evenness in a large area, and advantages of the crystalline materials having molecular orientation and is excellent in high-quality charge transport capability, thin film-forming properties, various types of durability and the like.

DISCLOSURE OF INVENTION

An object of the present invention is to provide a novel liquid crystalline compound which exhibits liquid crystallinity and, in addition, photoconductivity and fluorescence and a process for producing the same.

Another object of the present invention is to provide a novel charge transport material which simultaneously realizes advantages of the amorphous materials, that is, structural flexibility and evenness in a large area, and advantages of the crystalline materials having molecular orientation and is excellent in high-quality charge transport capability, thin film-forming properties, various types of durability and the like.

According to one aspect of the present invention, there is provided a process for producing a liquid crystalline compound represented by the general formula (A) described below, comprising the steps of: reacting a compound represented by the general formula (1), described below, with a compound represented by the general formula (2) described below, brominating the reaction product to give a compound represented by the general formula (3) described below; and substituting the bromine atom with an R.sub.2 group.

According to another aspect of the present invention, there is provided a process for producing a liquid crystalline compound represented by the general formula (B) described below, comprising the step of: reacting a compound represented by the general formula (4), described below, with a compound represented by the general formula (5) described below.

According to a further aspect of the present invention, there is provided a process for producing a liquid crystalline compound represented by the general formula (C) described below, comprising the step of: reacting two moles of a compound represented by the general formula (6), described below, with one mole of a compound represented by the general formula (7) described below.

According to a yet further aspect of the present invention, there is provided a process for producing a liquid crystalline compound represented by the general formula (D) described below, comprising the step of: reacting two moles of a compound represented by the general formula (8), described below, with one mole of a compound represented by the general formula (9) described below.

According to a yet further aspect of the present invention, there is provided a liquid crystalline charge transport material which exhibits smectic liquid crystallinity and has a reduction potential relative to a standard reference electrode (SCE) in the range of from -0.3 to -0.6 (Vvs. SEC).

According to a yet further aspect of the present invention, there is provided a liquid crystalline charge transport material which exhibits smectic liquid crystallinity and has an oxidation potential relative to a standard reference electrode (SCE) in the range of from 0.2 to 1.3 (Vvs. SEC).

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1, 2, 3 and 4 are cross-sectional views of embodiments where the crystalline charge transport material according to the present invention has been applied to a charge transport layer in an image recording device;

FIG. 5 is a cross-sectional view of an embodiment where the liquid crystalline charge transport material has been applied to a space light modulating device; and

FIG. 6 is a cross-sectional view of an embodiment where the liquid crystalline charge transport material according to the present invention has been applied to a thin film transistor.

BEST MODE FOR CARRYING OUT THE INVENTION

Process for producing liquid crystalline compound

The first invention relates to a process for producing a liquid crystalline compound represented by the general formula (A), comprising the steps of: reacting a compound represented by the general formula (1) with a compound represented by the general formula (2); brominating the reaction product to give a compound represented by the general formula (3); and substituting the bromine atom of the compound (3) with an R.sub.2 group: ##STR2## wherein R.sub.1 and R.sub.2 represent (a) a cyano group, (b) a nitro group, (c) a fluorine atom, or (d) a C.sub.1 -C.sub.22 straight-chain or branched, saturated or unsaturated, alkyl or alkoxy group attached to the aromatic ring through an oxygen atom, or a sulfur atom, provided that at least one of R.sub.1 and R.sub.2 represents said alkyl or alkoxy group.

The second invention relates to a process for producing a liquid crystalline compound represented by the general formula (B), comprising the step of: reacting a compound represented by the general formula (4) with a compound represented by the general formula (5): ##STR3## wherein R.sub.1 and R.sub.2 represent a C.sub.1 -C.sub.22 straight-chain or branched saturated or unsaturated alkyl or alkoxy group attached to the aromatic ring through a cyano group, a nitro group, a fluorine atom, an oxygen atom, or a sulfur atom, provided that at least one of R.sub.1 and R.sub.2 represents said alkyl or alkoxy group; and X and Y are respectively groups which are reacted with each other to form a --COO--, --OCO--, --N.dbd.N--, --CH.dbd.N--, --N.dbd.N--, --CH.sub.2 S--, --CH.dbd.CH--, or acetylene group.

The third invention relates to a process for producing a liquid crystalline compound represented by the general formula (C), comprising the step of: reacting 2 moles of a compound represented by the general formula (6) with one mole of a compound represented by the general formula (7): ##STR4## wherein R.sub.1 is a C.sub.1 -C.sub.22 straight-chain or branched saturated or unsaturated alkyl or alkoxy group attached to the aromatic ring through an oxygen or sulfur atom.

The fourth invention relates to a process for producing a liquid crystalline compound represented by the general formula (D), comprising the step of: reacting two moles of a compound represented by the general formula (8) with one mole of a compound represented by the general formula (9): ##STR5## wherein R.sub.1 is a C.sub.1 -C.sub.22 straight-chain or branched saturated or unsaturated alkyl or alkoxy group attached to the aromatic ring through an oxygen or sulfur atom; and X and Y are respectively groups which are reacted with each other to form a --COO--, --OCO--, --N.dbd.N--, --CH.dbd.N--, --N.dbd.N--, --CH.sub.2 S--, --CH.dbd.CH--, or acetylene group.

According to a specific one embodiment of the present invention, there is provided a process for producing a liquid crystalline compound represented by the following general formula (I), comprising the steps of: reacting a 4-alkoxybenzaldehyde with o-aminobenzenethiol to synthesize a 2-(4'-alkoxyphenyl)benzothiazole; brominating the 2-(4'-alkoxyphenyl)benzothiazole to synthesize a 2-(4'-alkoxyphenyl)-6-bromobenzothiazole; and reacting the resultant bromide with an alkanethiol: ##STR6## wherein R represents a C.sub.4 -C.sub.20 alkyl group; and R' represents a C.sub.4 -C.sub.20 alkyl group, provided that the total number of carbon atoms contained in R and R' is 10 or more.

A further preferred embodiment of the production process will be described.

According to the present invention, a 4-alkoxybenzaldehyde is reacted with 1 mole or more, preferably 1.1 to 1.5 moles or more, based on one mole of the 4-alkoxybenzaldehyde, of o-aminobenzenethiol in a solvent suitable for a dehydration reaction (oxidative cyclization), preferably dimethylsulfoxide, at a temperature of 100.degree. C. or above, preferably 120.degree. to 160.degree. C., for about 30 min to 2 hr.

In this reaction, the aldehyde group, the amino group, and the thiol group are combined together to form a thiazole ring, thus giving a 2-(4'-alkoxyphenyl)benzothiazole as an intermediate. This reaction can be easily achieved, and the intermediate is produced in a high yield of not less than 90%. The intermediate may be purified before use in the subsequent step or alternatively used in the subsequent step without purification.

The 2-(4'-alkoxyphenyl)benzothiazole is then brominated. In the bromination, the 2-(4'-alkoxyphenyl)benzothiazole is dissolved in a suitable solvent, such as glacial acetic acid, and bromine in an equimolar or slightly excessive molar amount is dropwise added thereto. In this reaction, bromine is easily substituted in the 6-position of the benzothiazole ring to give a 2-(4'-alkoxyphenyl)-6-bromobenzothiazole, and the reaction under mild conditions with heating can give the bromide in a yield of not less than 60%. When this intermediate contains a dibromination product and/or a substance remaining unreacted as impurities, it is preferably purified by recrystallization before use in the subsequent step.

Finally, the above bromide is reacted with an alkanethiol to give a liquid crystalline compound according to the present invention. Since this reaction is an aromatic nucleophilic displacement reaction by taking advantage of a thiolate anion, it is preferably performed in an alkaline atmosphere. For example, a liquid crystalline compound represented by the general formula (I) is produced by suspending an oil dispersion of sodium hydride in an ether, dropwise adding a corresponding alkanethiol to the suspension to produce a sodium salt of the alkanethiol, and reacting the sodium salt with the above bromide in a suitable solvent at a temperature of about 30.degree. to 100.degree. C. for 30 min to 2 hr.

According to the process of the present invention, the number of carbon atoms of the alkyl group in the 4-alkoxybenzaldehyde and the alkanethiol is important, and the number of carbon atoms of the alkyl group is preferably not less than 4, preferably 4 to 20 from the viewpoint of developing excellent liquid crystallinity. For the alkanethiol, the number of carbon atoms of the alkyl group is 4 or more, preferably 4 to 20. These alkyl groups may be somewhat branched. However, in order to develop excellent liquid crystallinity, the alkyl group is more preferably linear with the total number of carbon atoms of R and R' being 10 or more, preferably 12 to 40.

Further, liquid crystalline compounds represented by the following general formula (II) also fall within the scope of the present invention: ##STR7## wherein R represents C.sub.7 H.sub.15 and R' represents C.sub.6 H.sub.13, C.sub.8 H.sub.17, C.sub.10 H.sub.21 or C.sub.12 H.sub.25.

The above liquid crystalline compounds according to the present invention can be produced in a high yield from a p-alkoxybenzaldehyde, for example, by the following reaction scheme: ##STR8## wherein R and R' are as defined above and DMI represents N,N'-dimethylimidazolidinone.

The present invention provides a novel liquid crystalline compound which exhibits liquid crystallinity and, in addition, photoconductivity and fluorescence. The novel liquid crystalline compound is useful as a material for a liquid crystal display, a photosensitive material for electrophotography and the like. In particular, the liquid crystalline compound of the present invention has strong fluorescence and, hence, when used as a material for a color liquid crystal display or used in combination with a dichroic dye, can effectively utilize an ultraviolet portion in a backlight source, offering a display image having excellent sharpness and brightness.

Liquid crystalline charge transport material

According to a further aspect of the present invention, there is provided a liquid crystalline charge transport material which exhibits smectic liquid crystallinity and has a reduction potential relative to a standard reference electrode (SCE) in the range of from -0.3 to -0.6 (Vvs. SEC). According to a further aspect of the present invention, there is provided a liquid crystalline charge transport material which exhibits smectic liquid crystallinity and has an oxidation potential relative to a standard reference electrode (SCE) in the range of from 0.2 to 1.3 (Vvs. SEC).

A liquid crystalline molecule, by virtue of its molecular structure, has self-orientation, and, in the case of charge transport utilizing this molecule as a hopping site, unlike the above molecule dispersive material, the spacial and energy scattering of the hopping site is inhibited, enabling a band-like transport property such as found in a molecular crystal to be realized. This enables a mobility of about 10.sup.-3 to 10.sup.-2 cm.sup.2 /vs, that is, a larger mobility than that in the conventional molecular dispersive material, to be realized, and, in addition, the charge transport properties do not depend upon electric field.

In order that the material serves as a hole transport material, the molecule should have a low ionization potential, and, hence, the oxidation potential should be in the range of from 0.2 to 1.3 (Vvs. SEC) relative to a standard reference electrode (SCE). Further, in order that the material serves as an electron transport material, the molecule should have high electron affinity, and, hence, the reduction potential should be in the range of from -0.3 to -0.6 (Vvs.SEC). The above requirements are the same as the well known requirements for a charge transport molecule used in the conventional molecule dispersive material.

Preferred liquid crystalline charge transport materials of the present invention will be listed in Tables 1 to 71. Among the charge transport materials listed in these tables, more preferred materials are those which satisfy the above requirements, have (aromatic ring of 6 .pi. electron system) n (wherein n is an integer of 1 to 4) cores and exhibit smectic liquid crystallinity, those wherein the aromatic ring of 6 .pi. a electron system is linked through a carbon-carbon double bond or a carbon-carbon triple bond, and those which has a core of a benzothiazole ring, a benzoxazole ring, a benzimidazole ring, a naphthalene ring, or other aromatic ring of 10 .pi. electron system and exhibit smectic liquid crystallinity.

The liquid crystalline charge transport materials according to the present invention are useful for various applications such as photosensors, electroluminescence devices, photoconductors, space modulating devices, and thin film transistors.

The liquid crystalline charge transfer materials according to the present invention can realize high-speed mobility and inhibition of the creation of structural traps. Therefore, high-speed response photosensors may be mentioned as the first application thereof. Next, by virtue of excellent charge transport properties, the liquid crystalline charge transfer materials according to the present invention can be used as a charge transfer layer in electroluminescence devices. Further, since electric field orientation and photoconductivity can be simultaneously switched, they can be used in image display devices.

The application to image display devices will be described as a representative example. In an image display device, when a device comprising a transparent substrate, such as glass, a transparent electrode, such as ITO (indium-tin-oxide), a charge generating layer capable of generating carriers according to exposure, the liquid crystalline charge transport material of the present invention, and a counter electrode (such as a gold electrode) laminated in that order is subjected to imagewise exposure (input image) through the bottom of the device as shown in the schematic diagram, the liquid crystalline charge transport material is aligned according to the exposure, resulting in flow of carriers in the counter electrode (gold electrode). The input image can be reproduced by optical reading of the alignment of the liquid crystal. The larger the smectic properties of the liquid crystal, the longer the storage time of the alignment of the liquid crystal and the longer the storage time of the input information.

FIGS. 1 to 3 are explanatory diagrams of embodiments where the liquid crystalline charge transport material according to the present invention has been applied to a charge transport layer in an image recording device. FIG. 1 is a schematic view of a photosensor, an embodiment where the liquid crystalline charge transport material according to the present invention has been applied to a charge transport layer. Use of the photosensor will be described in more detail. As shown in FIG. 3, the device is subjected to pattern exposure from the direction of the above in the drawing while applying a voltage across the upper and lower electrodes 15. Carriers are generated in a pattern form in 14', and charges transported by a charge transport layer 14" are discharged in a space 19 and reach the surface of an information recording layer 11.

The information recording layer is, for example, a liquid crystal/polymer composite layer formed of a composite of a smectic liquid crystal and a polymer. The liquid crystal is aligned in a pattern form in an electric field of accumulated charges and accumulated, enabling optical recording to be performed.

In the embodiment shown in FIG. 4, exposure with a voltage being applied may be carried out in the same manner as described above in connection with the embodiment shown in FIG. 3. The generated charges (image) are accumulated on the top surface of a dielectric layer 20, and the liquid crystal is aligned in a pattern form in an electric field of charges accumulated in the same manner as described above in connection with the embodiment shown in FIG. 3 and accumulated, enabling optical reading to be performed.

Further, the liquid crystalline charge transport material according to the present invention can be used also in a pace optical light modulating device schematically shown in FIG. 5. Furthermore, the liquid crystalline charge transport materials of the present invention can also be used as an active layer of a thin film transistor. For example, as shown in FIG. 6, the liquid crystalline material may be disposed on a substrate having thereon source, drain, and gate electrodes.

Thus, the liquid crystalline charge transport materials according to the present invention are useful for various applications such as photosensors, electroluminescence devices, photoconductors, space modulating devices, and thin film transistors.

TABLE 1__________________________________________________________________________ ##STR9##No L R Cr LC__________________________________________________________________________7109 O.sub.2 N COC.sub.10 H.sub.20Si.sub.4 O.sub.4 Me.sub.7 -cy K? A58 I7122 NCCHCH C.sub.4 H.sub.9 K61.1 A57.7 N113.8 I7123 NCCHCH C.sub.5 H.sub.11 K61.8 A93.3 N122.2 I7124 NCCHCH C.sub.6 H.sub.13 K79.7 A113 N120.6 I7125 NCCHCH C.sub.7 H.sub.15 K70.2 A125 I7126 NCCHCH C.sub.8 H.sub.17 K59.3 A127.4 I7127 NCCHCH C.sub.9 H.sub.19 K55 A131 I7130 C.sub.5 H.sub.13 C.sub.9 H.sub.19 K42.5 B65.5 I7131 C.sub.7 H.sub.16 C.sub.7 H.sub.15 K52.5 B68 I7132 C.sub.2 H.sub.5OOCCHCH C.sub.4 H.sub.9 K96.3 S104 S153.9 I7133 C.sub.2 H.sub.5OOCCHCH C.sub.5 H.sub.11 K88.8 S88.5 S149.1 I7134 C.sub.2 H.sub.5OOCCHCH C.sub.6 H.sub.13 K74.2 S81 S146.2 I7135 C.sub.2 H.sub.5OOCCHCH C.sub.7 H.sub.15 K61 S74 S142.5 I7136 C.sub.2 H.sub.5OOCCHCH C.sub.8 H.sub.17 K62 S75 S143 I7137 C.sub.2 H.sub.5OOCCHCH C.sub.9 H.sub.19 K60 S73 S141.4 I7138 CH.sub.3O C.sub.3 H.sub.7 K51.9 S27.9 A33.6 I7139 CH.sub.3O C.sub.4 H.sub.9 K38.7 S26.2 A36.7 I7140 CH.sub.3O C.sub.5 H.sub.11 K38 S23.5 A31.2 I7141 CH.sub.3O C.sub.6 H.sub.13 K31.6 S14 A28.7 I7142 CH.sub.3O C.sub.7 H.sub.15 K36.1 S23.8 A27.7 N33.6 I7148 C.sub.2 H.sub.5O C.sub.4 H.sub.9 K49.3 A67.1 I7149 C.sub.4 H.sub.9O C.sub.4 H.sub.9 K7.4 S76 A96.2 I7150 C.sub.4 H.sub.9O C.sub.5 H.sub.11 K11.3 S53.4 I7151 C.sub.4 H.sub.9O C.sub.6 H.sub.13 K20.8 S54.5 A83.4 I7152 C.sub.5 H.sub.11O C.sub.3 H.sub.7 K36.5 S74 S76.5 I7153 C.sub.5 H.sub.11O C.sub.4 H.sub.9 K59.5 S61.5 S81.2 I7154 C.sub.5 H.sub.11O C.sub.5 H.sub.11 K39.5 S54 S84.8 I7155 C.sub.5 H.sub.11O C.sub.6 H.sub.13 K40.5 S46.5 S85.5 I__________________________________________________________________________ TABLE 2______________________________________ ##STR10##No L R Cr LC______________________________________7156 C.sub.5 H.sub.11 O C.sub.7 H.sub.15 K35.4 S84.8 I7157 C.sub.5 H.sub.11 O C.sub.8 H.sub.17 K39.5 S84 I7158 C.sub.5 H.sub.11 O C.sub.9 H.sub.19 K42.5 S82.5 I7159 C.sub.6 H.sub.13 O C.sub.4 H.sub.9 K18.2 S43.4 A74.1 I7160 C.sub.6 H.sub.13 O C.sub.9 H.sub.19 K35 B87 I7161 C.sub.7 H.sub.15 O C.sub.3 H.sub.7 K47 B72 I7162 C.sub.7 H.sub.15 O C.sub.7 H.sub.15 K53.5 B85.5 I7163 C.sub.5 H.sub.11 CO C.sub.5 H.sub.11 K75.5 S104.5 I7164 C.sub.5 H.sub.11 CO C.sub.6 H.sub.13 K80.5 S102 S103 I7165 C.sub.5 H.sub.11 CO C.sub.7 H.sub.15 K71 S95 S101 I7166 C.sub.5 H.sub.11 CO C.sub.8 H.sub.17 K87 S95.3 S98 I7167 C.sub.5 H.sub.11 CO C.sub.9 H.sub.19 K84.5 S93.8 S99.6 I7168 C.sub.6 H.sub.13 CO C.sub.8 H.sub.17 K72 S101.8 S105.8 I7169 C.sub.7 H.sub.15 CO C.sub.8 H.sub.17 K86.6 S97 S104.5 I______________________________________ TABLE 3______________________________________ ##STR11##No L R Cr LC______________________________________26206 C.sub.3 H.sub.7 C.sub.3 H.sub.7 K90 P120 P190 I26207 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K57 P119 P190 I26208 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K41 P114 P190 I26209 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K55 P184 I26210 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K28 P180 I26211 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K39 P173 I26212 C.sub.9 H.sub.19 C.sub.9 H.sub.19 K45 P165 I26213 C.sub.10 H.sub.21 C.sub.10 H.sub.21 K62 P160 I26217 C.sub.2 H.sub.5 OC.sub.2 H.sub.5 K166 S182 I26221 C.sub.3 H.sub.7 O OC.sub.3 H.sub.7 K210 P215 I26222 C.sub.4 H.sub.9 O OC.sub.4 H.sub.9 K197 P227 I26223 C.sub.5 H.sub.11 O OC.sub.5 H.sub.11 K185 P218 I26224 C.sub.6 H.sub.13 O OC.sub.6 H.sub.13 K172 P218 I26225 C.sub.7 H.sub.15 O OC.sub.7 H.sub.15 K166 P209 I26226 C.sub.8 H.sub.17 O OC.sub.8 H.sub.17 K163 P203 I26227 C.sub.9 H.sub.19 O OC.sub.9 H.sub.19 K162 P194 I26228 C.sub.10 H.sub.21O OC.sub.10 H.sub.24 K161 P189 I26230 CH.sub.3 O OOCC.sub.2 H.sub.5 K148 S155 N193 I______________________________________ ##STR12##No L R Cr LC______________________________________28692 C.sub.3 H.sub.7 C.sub.3 H.sub.7 K163.3 B171.5 I28693 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K36.3 E106.9 S113.4 B179.5 I28694 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K50 B155.9 U28695 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K30 E76.7 S107.9 B182.8 I28696 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K27.7 E82 S100.4 B175.5 I28697 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K58.1 E64.5 S93.4 B178.3 I28698 C.sub.9 H.sub.19 C.sub.9 H.sub.19 K52.6 E75.3 S87.3 B174.1 I______________________________________ TABLE 4__________________________________________________________________________ ##STR13##No L R Cr LC__________________________________________________________________________22075 C.sub.6 H.sub.13 CHMeOOC OC.sub.10 H.sub.21 1 K? A? I22076 C.sub.2 H.sub.5 CHMeCH.sub.2 OOC OC.sub.10 H.sub.21 1 K22 A48 I22077 C.sub.6 H.sub.13 CHCF.sub.3 OOC OC.sub.10 H.sub.21 1 K-13 A-6 I__________________________________________________________________________ ##STR14##No L R Cr LC__________________________________________________________________________8085 C.sub.8 H.sub.17 O C.sub.5 H.sub.11 K36 C44.5 A75 N83.5 I__________________________________________________________________________ TABLE 5__________________________________________________________________________ ##STR15##No L R Cr LC__________________________________________________________________________22305 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K83.1 C58 N109.5 I22307 C.sub.6 H.sub.13 O C.sub.5 H.sub.11 K81 A85 N120 I22309 C.sub.8 H.sub.17 O C.sub.7 H.sub.15 K73 A106.1 N111.3 I22317 C.sub.7 H.sub.15 OC.sub.7 H.sub.15 K83.1 C58 N109.5 I22318 C.sub.8 H.sub.17 OC.sub.6 H.sub.13 K70 C73 N109 I22320 C.sub.6 H.sub.13 O OC.sub.7 H.sub.15 K82 C88.4 N133.4 I22321 C.sub.6 H.sub.13 O OC.sub.8 H.sub.17 K85.1 C89.1 N133.3 I22322 C.sub.7 H.sub.15 O OC.sub.7 H.sub.15 K88.9 C94.7 A105.5 N129.8 I22323 C.sub.7 H.sub.15 O OC.sub.8 H.sub.17 K82.5 C103.8 A110.7 N132.2 I22324 C.sub.7 H.sub.15 O OC.sub.9 H.sub.19 K90.4 C103 A113.8 N128 I22325 C.sub.8 H.sub.17 O OC.sub.7 H.sub.15 K84.7 C93.8 A115.7 N129.7 I22326 C.sub.8 H.sub.17 O OC.sub.8 H.sub.17 K85.5 C101.8 A119.8 N131 I22327 C.sub.8 H.sub.17 O OC.sub.9 H.sub.19 K90 C104.2 A122.4 N131.8 I__________________________________________________________________________ TABLE 6__________________________________________________________________________ ##STR16##No L R Cr LC__________________________________________________________________________22328 C.sub.9 H.sub.19 O OC.sub.8 H.sub.17 K87 C106.3 A122.5 N129.8 I22329 C.sub.9 H.sub.19 O OC.sub.9 H.sub.19 K89.4 C115.5 A125.7 N128.4 I22333 C.sub.4 H.sub.9 COC.sub.4 H.sub.9 K116 S120 N130 I22334 C.sub.10 H.sub.21 O COOCH(C.sub.3 H.sub.6 /C.sub.2 H.sub.5).sub.2 R K<30 A25 I22337 C.sub.8 H.sub.17 O COOCHMeC.sub.6 H.sub.13 R K69.3 A62.1 I22338 C.sub.10 H.sub.21 O COOCHMeC.sub.6 H.sub.13 R K60 A20 U22341 C.sub.10 H.sub.21 O COOCH.sub.2 CHMeC.sub.2 H.sub.5 1 K85.2 A103.6 I22342 C.sub.9 H.sub.19 O CHCHCOOCHCF.sub.3 C.sub.6 H.sub.13 R K51 CA63 A69 I22343 C.sub.10 H.sub.21 O CHCHCOOCHCF.sub.3 C.sub.6 H.sub.13 R K50 CA56 A66 I22344 C.sub.11 H.sub.23 O CHCHCOOCHCF.sub.3 C.sub.6 H.sub.13 R K45 CA52 A61 I22345 C.sub.10 H.sub.21 O COOCHCF.sub.3 C.sub.6 H.sub.13 1 K<-30 A25 I22346 C.sub.10 H.sub.21 O COOCHCF.sub.3 C.sub.8 H.sub.17 1 K? S6 A13.3 I22347 C.sub.10 H.sub.21 O COOCHCF.sub.3 C.sub.6 H.sub.13 2 K52 A61 I__________________________________________________________________________ TABLE 7__________________________________________________________________________ ##STR17##No L R Cr LC__________________________________________________________________________35478 C.sub.4 H.sub.9 O CN K158 N>300 Z35479 C.sub.7 H.sub.15 O CN K132 N292 Z35481 C.sub.8 H.sub.17 O CHMeCOSC.sub.6 H.sub.13 1 K89.2 C*120 A140.7 I35482 C.sub.9 H.sub.19 O CHMeCOSC.sub.6 H.sub.13 1 K86.7 C*125.3 A135.7 I35483 C.sub.10 H.sub.21 O CHMeCOSC.sub.6 H.sub.13 1 K85.4 C*127.5 A133.6 I35484 C.sub.11 H.sub.23 O CHMeCOSC.sub.6 H.sub.13 1 K83.3 S112.8 C*128.2 A131.1 I35485 C.sub.12 H.sub.25 O CHMeCOSC.sub.6 H.sub.13 1 K86.9 S104.8 C*128.6 A129.1 I35486 C.sub.13 H.sub.27 O CHMeCOSC.sub.6 H.sub.13 1 K81.9 S102.6 C*128.8 I35487 C.sub.14 H.sub.29 O CHMeCOSC.sub.6 H.sub.13 1 K77.4 S103 C*124.4 I35488 C.sub.7 H.sub.15 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K98 C*100.8 A141.8 N*151 I35489 C.sub.8 H.sub.17 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K94.1 C*101.6 A139.1 N*147.9 I35490 C.sub.9 H.sub.19 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K79.1 C*105.9 A134.1 A#? N*142.8 I35491 C.sub.10 H.sub.21 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K66.9 C*108.4 A#138.6 N*147.9 I35492 C.sub.11 H.sub.23 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K73.3 C*114.1 A#127.5 N*134.3 I35493 C.sub.12 H.sub.25 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K69 C*113.4 A#126.4 N*132.6 I35494 C.sub.13 H.sub.27 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K68.6 C*119.7 A#133.7 N*138.5 I35495 C.sub.14 H.sub.29 O CHMeCOOCHMeC.sub.3 H.sub.7 5 K71.7 C*119.4 A#132.8 N*136.5 I35496 C.sub.8 H.sub.17 O COOCHCF.sub.3 C.sub.6 H.sub.13 1 K93.5 S147.4 C*150.7 A176.4 I35497 C.sub.8 H.sub.17 O COOCHCF.sub.3 C.sub.8 H.sub.17 1 K84 S133 C*135.6 A163.8 I35498 C.sub.6 H.sub.13 CHCF.sub.3 OOC OC.sub.10 H.sub.21 1 K? S10 S75 C*106 A150.5 I__________________________________________________________________________ TABLE 8__________________________________________________________________________ ##STR18##No L R Cr LC__________________________________________________________________________46421 C.sub.8 H.sub.17 C.sub.5 H.sub.11 K54 S142.5 N178 I__________________________________________________________________________ ##STR19##No L R Cr LC__________________________________________________________________________35500 C.sub.7 H.sub.15 F K114.9 S187.9 N229.7 I35501 C.sub.7 H.sub.15 O CN K136 N304 Z35502 H.sub.2 CCHCOOC.sub.5 H.sub.12 O NO.sub.2 K134 S>180 Z35503 C.sub.6 H.sub.13 CHCF.sub.3 OOC C.sub.10 H.sub.21 1 K49.5 A127.7 I35504 C.sub.6 H.sub.13 CHCF.sub.3 OOC OC.sub.10 H.sub.21 1 K35 S100.4 C*124.5 A152.5 I35505 C.sub.6 H.sub.13 CHCF.sub.3 OOC COOC.sub.10 H.sub.21 1 K40 S96 C*97.7 A123.7 I35506 C.sub.6 H.sub.13 CHCF.sub.3 OOC OOCC.sub.10 H.sub.21 1 K75 S120 C*156.9 A184.2 I35507 C.sub.10 H.sub.21 O COOCHCF.sub.3 C.sub.6 H.sub.13 1 K? S97 C*120 A151.9 I35508 C.sub.8 H.sub.17 OOC COOCHCF.sub.3 C.sub.6 H.sub.13 1 K? S64.1 C*66 A108.4 I__________________________________________________________________________ ##STR20##No L R Cr LC__________________________________________________________________________22447 C.sub.5 F.sub.11 CH.sub.2 O OC.sub.8 H.sub.17 K? A92 I22448 C.sub.5 F.sub.11 CH.sub.2 O OC.sub.3 H.sub.6 CHMeC.sub.2 H.sub.5 1 K? C*37 A80 I__________________________________________________________________________ TABLE 9__________________________________________________________________________ ##STR21##No L R Cr LC__________________________________________________________________________7534 C.sub.8 H.sub.17 C.sub.6 H.sub.13 K39.9 C23 A25.5 I7538 C.sub.6 H.sub.13 O C.sub.4 H.sub.9 K68.7 C45.1 A55.8 I7539 C.sub.10 H.sub.21 O C.sub.8 H.sub.17 K57.7 C71.5 A77.3 I7542 C.sub.10 H.sub.21 O OC.sub.8 H.sub.17 K60.1 C81.7 A89.1 I7543 C.sub.8 H.sub.17 O COC.sub.10 H.sub.21 K106.9 C103.8 A120.4 I7545 C.sub.10 H.sub.21 O COOC.sub.8 H.sub.17 K103.6 A88.2 I7548 C.sub.6 H.sub.13 COO C.sub.8 H.sub.17 K51.8 A64.3 N49.8 U7549 C.sub.6 H.sub.13 CHFCH.sub.2 O C.sub.8 H.sub.17 1 K77.9 A69.6 I__________________________________________________________________________ ##STR22##No L R Cr LC__________________________________________________________________________8788 C.sub.10 H.sub.21 O C.sub.4 H.sub.9 K90.1 A109.9 I__________________________________________________________________________ ##STR23##No L R Cr LC__________________________________________________________________________27629 C.sub.8 H.sub.17 C.sub.12 H.sub.25 K76.6 C99.4 N128.2 I__________________________________________________________________________ TABLE 10__________________________________________________________________________ ##STR24##No L R Cr LC__________________________________________________________________________28106 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K77.8 C101.4 N121.8 I__________________________________________________________________________ ##STR25##No L R Cr LC__________________________________________________________________________26603 C.sub.10 H.sub.21 C.sub.8 H.sub.17 K77.5 C114.9 N123.8 I26604 C.sub.10 H.sub.21 OC.sub.10 H.sub.21 K92.2 C132.8 A135.9 N143.4 I__________________________________________________________________________ ##STR26##No L R Cr LC__________________________________________________________________________8726 C.sub.4 H.sub.9 C.sub.6 H.sub.13 K90 A96 N106 I__________________________________________________________________________ TABLE 11______________________________________ ##STR27##No L R Cr LC______________________________________27356 H OC.sub.4 H.sub.9 K211 A207 N240 I27357 H OC.sub.6 H.sub.13 K183 B225 A228 U______________________________________ ##STR28##No L R Cr LC______________________________________27633 C.sub.4 H.sub.9 H K75 S96 I27634 C.sub.5 H.sub.11 H K65 S106 I27635 C.sub.6 H.sub.13 H K55 S103 I27636 C.sub.7 H.sub.15 H K48 S100 S103 S107 I27637 C.sub.8 H.sub.17 H K42 S102 I27638 C.sub.4 H.sub.9 O H K106 S136 I27639 C.sub.5 H.sub.11 O H K62 S133 I27640 C.sub.6 H.sub.13 O H K76 S133 I27641 C.sub.7 H.sub.15 O H K63 S136 I27642 C.sub.8 H.sub.17 O H K54 S137 I______________________________________ ##STR29##No L R Cr LC______________________________________8268 C.sub.4 H.sub.9 S Br K? I8269 C.sub.4 H.sub.9 S CN K30.3 N-63 E8270 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K56 I8278 C.sub.7 H.sub.15 COOC.sub.2 H.sub.5 K84 S47 I8279 C.sub.4 H.sub.9 O COOC.sub.2 H.sub.5 K87 S86 I8280 C.sub.5 H.sub.11 O COOC.sub.2 H.sub.5 K72 S90 I8281 C.sub.6 H.sub.13 O COOC.sub.2 H.sub.5 K60 S82 I8282 C.sub.7 H.sub.15 O COOC.sub.2 H.sub.5 K86 S82 I8283 C.sub.8 H.sub.17 O COOC.sub.2 H.sub.5 K72 S84 I______________________________________ TABLE 12__________________________________________________________________________ ##STR30##No L R Cr LC__________________________________________________________________________29065 C.sub.3 H.sub.7 C.sub.3 H.sub.7 K50 S74 I29066 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K50 S75 I29067 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K53 S77 I29068 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K51 S82 I29069 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K55 G78 F83 C89 I29070 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K65 G72 F87 C91 I29071 C.sub.9 H.sub.19 C.sub.9 H.sub.12 K64 G62 F91 C95 I29072 C.sub.10 H.sub.21 C.sub.10 H.sub.21 K71 F95 C96 I29074 C.sub.4 H.sub.9 COC.sub.3 H.sub.7 K148.3 A155.7 I29075 C.sub.5 H.sub.11 COC.sub.4 H.sub.9 K137.2 A163 I29076 C.sub.6 H.sub.13 COC.sub.5 H.sub.11 K138.4 A162 I29077 C.sub.7 H.sub.15 COC.sub.6 H.sub.13 K132 C138.9 A161.829078 C.sub.8 H.sub.17 COC.sub.7 H.sub.15 K133 C151 A159.7 I29079 C.sub.9 H.sub.19 COC.sub.8 H.sub.17 K129.4 C154.2 A158.7 I29080 C.sub.10 H.sub.21 COC.sub.9 H.sub.19 K127 C152 I__________________________________________________________________________ ##STR31##No L R Cr LC__________________________________________________________________________5713 Br COC.sub.7 H.sub.15 K116.1 A123.8 I5719 NC C.sub.8 H.sub.17 K49.9 A20.8 N22.2 I5723 NC SC.sub.4 H.sub.9 K32.6 N-52 E5727 C.sub.4 H.sub.9 SiMe.sub.2 C.sub.3 H.sub.6 O C.sub.10 H.sub.21 K57 S43 I5730 C.sub.4 H.sub.9 S CN K55.7 N5 E5732 C.sub.2 H.sub.5 O COC.sub.7 H.sub.15 K120.8 A123.1 I5733 C.sub.3 H.sub.7 O COC.sub.7 H.sub.15 K124.4 A122.8 I5734 C.sub.4 H.sub.9 O COC.sub.7 H.sub.15 K127.6 A130.9 I5735 C.sub.5 H.sub.11 O COC.sub.7 H.sub.15 K120.5 A127.4 I5736 C.sub.6 H.sub.13 O COC.sub.7 H.sub.15 K120 A129.8 I5737 C.sub.7 H.sub.15 O COC.sub.7 H.sub.15 K113 A127.4 I5738 C.sub.8 H.sub.17 O COC.sub.7 H.sub.15 K109.5 A126.2 I5739 C.sub.9 H.sub.19 O COC.sub.7 H.sub.15 K107.5 A123.8 I5740 C.sub.12 H.sub.25 O COC.sub.7 H.sub.15 K100.6 S93.8 A122.2 I__________________________________________________________________________ TABLE 13______________________________________ ##STR32##No L R Cr LC______________________________________36004 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K21.5 B88.4 A96.7 I36005 C.sub.6 H.sub.13 C.sub.5 H.sub.11 K22.5 B94.7 A97.2 I36006 C.sub.7 H.sub.15 C.sub.5 H.sub.11 K20.5 B96.2 A99.8 I36007 C.sub.8 H.sub.17 C.sub.5 H.sub.11 K21 B96.8 A99.1 I36008 C.sub.9 H.sub.19 C.sub.5 H.sub.11 K23.7 B97.2 A100.1 I36009 C.sub.10 H.sub.21 C.sub.5 H.sub.11 K55 B98.4 I______________________________________ ##STR33##No L R Cr LC______________________________________27648 C.sub.4 H.sub.9 O H K128 S150 I27649 C.sub.6 H.sub.13 C.sub.2 H.sub.5 K56 S155 I27650 C.sub.4 H.sub.9 O C.sub.2 H.sub.5 K102 S180 I27651 C.sub.4 H.sub.9 O C.sub.5 H.sub.11 K61 S176 I______________________________________ ##STR34##No L R Cr LC______________________________________27643 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K42.4 C47.9 A62 N97.8 I27644 C.sub.5 H.sub.11 COC.sub.4 H.sub.9 K74.9 A186.8 I______________________________________ TABLE 14__________________________________________________________________________ ##STR35##No L R Cr LC__________________________________________________________________________25783 C.sub.6 H.sub.3 OC.sub.6 H.sub.13 K148 A152 N155 I__________________________________________________________________________ ##STR36##No L R Cr LC__________________________________________________________________________25800 C.sub.6 H.sub.13 O OC.sub.6 H.sub.13 K110.8 C130.6 N161 I25801 C.sub.7 H.sub.15 O OC.sub.7 H.sub.15 K109.8 C139.4 N155.8 I25802 C.sub.8 H.sub.17 O OC.sub.8 H.sub.17 K107.3 C149 N157.3 I25803 C.sub.10 H.sub.21 O OC.sub.10 H.sub.21 K98.6 C147.4 I25805 H.sub.2 CCHC.sub.4 H.sub.8 O OC.sub.4 H.sub.8 CHCH.sub.2 K99 A114 N144 I25806 H.sub.2 CCHC.sub.9 H.sub.18 O OC.sub.9 H.sub.18 CHCH.sub.2 K92 A145 I__________________________________________________________________________ ##STR37##No L R Cr LC__________________________________________________________________________25816 Me.sub.3 SiC.sub.3 H.sub.6 O C.sub.6 H.sub.13 K96 C109 I25817 C.sub.4 H.sub.9 SiMe.sub.2 C.sub.3 H.sub.6 COO C.sub.6 H.sub.13 K51 C90 I25818 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K68.8 A116.5 N120.1 I25819 C.sub.9 H.sub.19 C.sub.6 H.sub.13 K61 C72.2 A126.8 I25828 C.sub.3 H.sub.7 O C.sub.6 H.sub.13 K79 C70 A101 N147.5 I25841 C.sub.3 H.sub.7 O OC.sub.8 H.sub.17 K78 C98 N161 I25842 C.sub.4 H.sub.9 COO C.sub.6 H.sub.13 K101.9 C128.5 N149.4 I__________________________________________________________________________ TABLE 15__________________________________________________________________________ ##STR38##No L R Cr LC__________________________________________________________________________25843 C.sub.6 H.sub.13 COO C.sub.6 H.sub.13 K73.1 S83.2 C139.3 N148.7 I25844 C.sub.8 H.sub.17 COO C.sub.6 H.sub.13 K58 S75.8 C146.4 N148.1 I25845 C.sub.8 H.sub.17 COO C.sub.8 H.sub.17 K59.4 S74.5 S78.5 C148.5 I25846 C.sub.10 H.sub.21 COO C.sub.6 H.sub.13 K74.9 S86.2 C147 I__________________________________________________________________________ ##STR39##No L R Cr LC__________________________________________________________________________26979 C.sub.6 H.sub.13 C.sub.9 H.sub.19 K134.2 S166.3 S167.3 I__________________________________________________________________________ ##STR40##No L R Cr LC__________________________________________________________________________26980 C.sub.4 H.sub.9 C.sub.7 H.sub.15 K76 S130 N137 I__________________________________________________________________________ ##STR41##No L R Cr LC__________________________________________________________________________25848 C.sub.10 H.sub.21 OCH.sub.3 K95 N154 U25849 C.sub.10 H.sub.21 OC.sub.6 H.sub.13 K43 C53 A142 U25850 C.sub.10 H.sub.21 OC.sub.7 H.sub.15 K54 B64 C110 A143 U25851 C.sub.10 H.sub.21 OC.sub.8 H.sub.17 K59 B73 C120 A146 U25852 C.sub.10 H.sub.21 OC.sub.10 H.sub.21 K66 B84 C137 A144.6 I__________________________________________________________________________ TABLE 16__________________________________________________________________________ ##STR42##No L R Cr LC__________________________________________________________________________7226 NC C.sub.8 H.sub.17 K48 A91.5 N113 I7227 NC C.sub.9 H.sub.19 K44 A95 N104 I7235 NC OC.sub.8 H.sub.17 K85 A94 N140 I7243 NC OOCCHCHCH.sub.3 K139 N259 Z7244 NC OOCCHCHC.sub.2 H.sub.5 K113 N229 Z__________________________________________________________________________ ##STR43##No L R Cr LC__________________________________________________________________________8776 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K146.5 E145.5 A163.5 N171.5 I8777 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K138 E135.5 A156.5 I8778 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K125.5 E135.5 A163 I8779 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K123 E129 A156.5 I8780 C.sub.9 H.sub.19 C.sub.9 H.sub.19 K113.5 E110 A148 I8783 C.sub.3 H.sub.7 O OC.sub.3 H.sub.7 K194 A237 N278 I8784 C.sub.4 H.sub.9 O OC.sub.4 H.sub.9 K136 E190 A241 N256 I8785 C.sub.5 H.sub.11 O OC.sub.9 H.sub.11 K136 E178 A236 N244 I8786 C.sub.6 H.sub.13 O OC.sub.6 H.sub.13 K141 E170 A229 I8787 C.sub.7 H.sub.15 O OC.sub.7 H.sub.15 K130 E163 N225 I__________________________________________________________________________ TABLE 17__________________________________________________________________________ ##STR44##No L R Cr LC__________________________________________________________________________22138 NC OC.sub.8 H.sub.17 K128 A122 N156 I22139 NC OC.sub.9 H.sub.19 K125 A140 N152 I22140 NC OC.sub.10 H.sub.21 K125 A146 N149 I22141 NC OC.sub.11 H.sub.23 K122.5 A149 I22142 NC OC.sub.12 H.sub.25 K123 A151 I22146 O.sub.2 N OC.sub.8 H.sub.17 K98 A109 N136 I22147 O.sub.2 N OC.sub.9 H.sub.19 K94 A127.5 N135 I22148 O.sub.2 N OC.sub.10 H.sub.21 K93 A135 N135.5 I22149 O.sub.2 N OC.sub.11 H.sub.23 K92 A136.5 I22150 O.sub.2 N OC.sub.12 H.sub.25 K92 A136.5 I22161 C.sub.9 H.sub.19 CN K74 A105.9 N131.11__________________________________________________________________________ ##STR45##No L R Cr LC__________________________________________________________________________22168 C.sub.10 H.sub.21O CN K78 R72 A139 N152 I22169 C.sub.11 H.sub.23O CN K79 A146 N149.5 I22172 C.sub.8 H.sub.17S CN K99 A109.5 N129.5 I22173 C.sub.9 H.sub..sub.19S CN K107 A122 N127 I22174 C.sub.10 H.sub.21S CN K100 A128.5 I22175 C.sub.11 H.sub.23S CN K100 A130.5 I22176 C.sub.12 H.sub.25S CN K104 A133 I22181 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O CN S K80 A122 N*135 I22182 C.sub.9 H.sub..sub.19O COOC.sub.3 H.sub.6SiMe.sub.2 C.sub.4 H.sub.9 K48 C67 A81 I22184 C.sub.6 H.sub.13O C.sub.5 H.sub.11 K81 A84.9 N120 I22185 C.sub.8 H.sub.17O C.sub.7 H.sub.15 K73 A106.1 N111.3 I22186 C.sub.10 H.sub.21O C.sub.4 H.sub.9CHMeOOCC.sub.2 H.sub.5 1 K22.1 A9.1 I22187 C.sub.10 H.sub.21O OC.sub.2 H.sub.4OC.sub.4 H.sub.9 K63 C72.3 N98.3 I22188 C.sub.10 H.sub.21O OCH.sub.2CHMeOC.sub.2 H.sub.5 1 K49 C*59 A64 N*73 I__________________________________________________________________________ TABLE 18__________________________________________________________________________ ##STR46##No L R Cr LC__________________________________________________________________________22305 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K83.1 C58 N109.5 I22307 C.sub.6 H.sub.13O C.sub.5 H.sub.11 K81 A85 N120 I22309 C.sub.8 H.sub.17O C.sub.7 H.sub.15 K73 A106.1 N111.3 I22317 C.sub.7 H.sub.15 OC.sub.7 H.sub.15 K83.1 C58 N109.5 I22318 C.sub.8 H.sub.17 OC.sub.6 H.sub.13 K70 C73 N109 I22320 C.sub.6 H.sub.13O OC.sub.7 H.sub.15 K82 C88.4 N133.4 I22321 C.sub.6 H.sub.13O OC.sub.8 H.sub.17 K85.1 C89.1 N133.3 I22322 C.sub.7 H.sub.15O OC.sub.7 H.sub.15 K88.9 C94.7 A105.5 N129.8 I22323 C.sub.7 H.sub.15O OC.sub.8 H.sub.17 K82.5 C103.8 A110.7 N132.2 I22324 C.sub.7 H.sub.15O OC.sub.9 H.sub.19 K90.4 C103 A113.8 N128 I22325 C.sub.8 H.sub.17O OC.sub.7 H.sub.15 K84.7 C93.8 A115.7 N129.7 I22326 C.sub.8 H.sub.17O OC.sub.8 H.sub.17 K85.5 C101.8 A119.8 N131 I22327 C.sub.8 H.sub.17O OC.sub.9 H.sub.19 K90 C104.2 A122.4 N131.8__________________________________________________________________________ I ##STR47##No L R Cr LC__________________________________________________________________________35500 C.sub.7 H.sub.15 F K114.9 S187.9 N229.7 I35502 H.sub.2 CCHCOOC.sub.6 H.sub.12O NO.sub.2 K134 S>180 Z35503 C.sub.6 H.sub.13CHCF.sub.3OOC C.sub.10 H.sub.21 1 K49.5 A127.7 I35504 C.sub.6 H.sub.13CHCF.sub.3OOC OC.sub.10 H.sub.21 1 K35 S100.4 C*24.5 A152.5 I35505 C.sub.6 H.sub.13CHCF.sub.3OOC COOC.sub.10 H.sub.21 1 K40 S96 C*97.7 A123.7 I35506 C.sub.6 H.sub.13CHCF.sub.3OOC OOCC.sub.10 H.sub.21 1 K75 S120 C*156.9 A184.2 I35507 C.sub.10 H.sub.21O COOCHCF.sub.3C.sub.6 H.sub.13 1 K? S97 C*120 A151.9 I35508 C.sub.8 H.sub.17OOC COOCHCF.sub.3C.sub.6 H.sub.13 1 K? S64.1 C*66 A108.4 I__________________________________________________________________________ TABLE 19______________________________________ ##STR48##No L R Cr LC______________________________________24420 C.sub.8 H.sub.17 C.sub.5 H.sub.11 K44.5 S65 N84 I24421 C.sub.8 H.sub.17 C.sub.6 H.sub.13 K46.5 S36.5 N69.5 I______________________________________ ##STR49##No L R Cr LC______________________________________8289 C.sub.6 H.sub.13 OC.sub.6 H.sub.13 K107.4 C114.1 I8290 C.sub.6 H.sub.13 CC.sub.10 H.sub.21 K92.8 C116.5 I8291 C.sub.6 H.sub.13 OOCC.sub.6 H.sub.13 K81.7 C106.7 A110.9 I______________________________________ ##STR50##No L R Cr LC______________________________________28262 C.sub.6 H.sub.13 OC.sub.4 H.sub.9 K79.5 C155.1 N230.7 I28263 C.sub.10 H.sub.21 OC.sub.10 H.sub.21 K80.3 C198.2 I28265 C.sub.6 H.sub.13 OOCC.sub.6 H.sub.13 K82.3 C199.4 N225.2 I______________________________________ TABLE 20______________________________________ ##STR51##No L R Cr LC______________________________________8292 C.sub.6 H.sub.13 C.sub.8 H.sub.17 K87.3 S118.6 A186.4 I8293 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K82.4 S92.7 C149 A181.2 I______________________________________ ##STR52##No L R Cr LC______________________________________8294 C.sub.6 H.sub.13 C.sub.8 H.sub.17 K84.6 S119.5 A147.5 I8295 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K34.8 S117.5 A155.2 I______________________________________ TABLE 21__________________________________________________________________________ ##STR53##No L R Cr LC__________________________________________________________________________25914 C.sub.5 H.sub.11 H K76 N56 U25915 C.sub.6 H.sub.13 H K75 S60 N80 I25916 C.sub.7 H.sub.15 H K79 S64 N86 I25917 C.sub.12 H.sub.25 H K84 A95 I25918 C.sub.2 H.sub.5O H K120 N165 U25919 C.sub.3 H.sub.7O H K110 N101 U25920 C.sub.4 H.sub.9O H K84 N140 U25921 C.sub.5 H.sub.11O H K80 N134 U25922 C.sub.6 H.sub.13O H K80.5 N134 U25923 C.sub.7 H.sub.15O H K73.5 N149.5 U25924 C.sub.8 H.sub.17O H K83 N142.5 U25925 C.sub.9 H.sub.19O H K96 A126 I25926 C.sub.10 H.sub.21O H K99 A126 I25931 C.sub.6 H.sub.13O F K97 A198 I25932 C.sub.6 H.sub.13O Cl K132 A244 I25933 C.sub.6 H.sub.13O Br K135 A239 I25934 C.sub.6 H.sub.13 CN K118 A220 N233 I25935 C.sub.5 H.sub.11O CN K142 A246 N265 I25936 C.sub.6 H.sub.13O CN K146 A258 N264 I25937 C.sub.6 H.sub.13O NO.sub.2 K123 A241 I25938 C.sub.10 H.sub.21 OC.sub.4 H.sub.6SiMe.sub.2 C.sub.4 H.sub.9 K46 C122 E25943 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K93 C123 N164 I25944 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K89 C137 N154 B25945 C.sub.6 H.sub.13 C.sub.10 H.sub.21 K66 C168 N172.9 I25946 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K81 C149 N158 I25947 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K78 C151 N152 B__________________________________________________________________________ TABLE 22__________________________________________________________________________ ##STR54##No L R Cr LC__________________________________________________________________________25949 C.sub.2 H.sub.5 OC.sub.7 H.sub.15 K67 A142 N178 I25952 C.sub.5 H.sub.11 CC.sub.6 H.sub.13 K55 C158 N186 I25953 C.sub.5 H.sub.11 OC.sub.8 H.sub.17 K80 C167 N182 I25954 C.sub.6 H.sub.13 OC.sub.4 H.sub.9 K80.6 C141 N183.5 I25955 C.sub.6 H.sub.13 OC.sub.7 H.sub.15 K69 A166 N179 I25956 C.sub.6 H.sub.13 OC.sub.9 H.sub.19 K77 C171 N175 I25957 C.sub.7 H.sub.15 OC.sub.8 H.sub.17 K79 C174 N178 I25958 C.sub.8 H.sub.17 OC.sub.7 H.sub.15 K72 A170 N177 I25960 C.sub.10 H.sub.21 OC.sub.7 H.sub.15 K76 C171 N181 B25961 C.sub.10 H.sub.21 OC.sub.6 H.sub.17 K79 C173 I25962 C.sub.10 H.sub.21 OC.sub.10 H.sub.21 K78 A154 I25963 C.sub.12 H.sub.25 OC.sub.9 H.sub.19 K74 C169 I25965 C.sub.10 H.sub.21 COOCH.sub.3 K140 A224 I25966 C.sub.6 H.sub.13 OOCC.sub.8 H.sub.17 K58.2 S68.1 C172.6 N176.1 I25967 C.sub.10 H.sub.21 OOCCH.sub.3 K117 C134 N183 I25968 C.sub.10 H.sub.21 OOCC.sub.2 H.sub.5 K107 C153 N181 I25969 C.sub.10 H.sub.21 OOCCHMeCCH.sub.3 1 K108 C*139 N*140 I25970 C.sub.10 H.sub.21 OOCCHMeCC.sub.6 H.sub.13 1 K110 C*121 I25971 C.sub.10 H.sub.21 OCOOC.sub.4 H.sub.9 K64 C146 A147 N166 I25972 C.sub.10 H.sub.21 OCOOC.sub.7 H.sub.15 K80 C153 N157 I25974 CH.sub.3O CC.sub.6 H.sub.13 K93 A109 N215 I25977 C.sub.4 H.sub.9O CC.sub.4 H.sub.9 K145 A156 N222 I__________________________________________________________________________ TABLE 23__________________________________________________________________________ ##STR55##No L R Cr LC__________________________________________________________________________27803 NC C.sub.6 H.sub.13 K128 A169 N199 I27804 C.sub.4 H.sub.9 C.sub.3 H.sub.7 K76 A96 N150 I27805 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K71 A120 N146 I27806 C.sub.4 H.sub.9 C.sub.5 H.sub.11 K52 A115 N138 I27807 C.sub.4 H.sub.9 C.sub.6 H.sub.13 K58 A117 N151 I27808 C.sub.6 H.sub.13 C.sub.2 H.sub.5 K50 A77 N115 I27809 C.sub.6 H.sub.13 C.sub.3 H.sub.7 K61 A126 N146 I27810 C.sub.6 H.sub.13 C.sub.4 H.sub.9 K47 A133 N139 I27811 C.sub.6 H.sub.13 C.sub.5 H.sub.11 K50 A148 N150 I27812 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K50 A145 I27815 C.sub.9 H.sub.19O C.sub.4 H.sub.9 K111 A166 N167 I27816 C.sub.9 H.sub.19O C.sub.6 H.sub.13 K108 C130 N169 I27817 C.sub.10 H.sub.21O C.sub.6 H.sub.13 K105 C122 N165 I27818 C.sub.10 H.sub.21O C.sub.7 H.sub.15 K87 C143 A169 I27819 C.sub.12 H.sub.25O C.sub.6 H.sub.13 K58 C136 A146 I27820 C.sub.4 H.sub.9CMe.sub.2C.sub.4 H.sub.9O C.sub.6 H.sub.13 K93 C101 A111 N112 I27821 C.sub.4 H.sub.9CMe.sub.2C.sub.6 H.sub.12O C.sub.6 H.sub.13 K90 C117 A129 N129 I27823 C.sub.6 H.sub.13OCHMeCOO C.sub.2 H.sub.5 1 K75 A61 I27824 H.sub.2 C/CH.sub.2 CHC.sub.11 H.sub.22O C.sub.5 H.sub.11 K111 C113 A156 N157 I__________________________________________________________________________ ##STR56##No L R Cr LC__________________________________________________________________________28262 C.sub.6 H.sub.13 OC.sub.4 H.sub.9 K79.5 C155.1 N230.7 I28263 C.sub.10 H.sub.21 OC.sub.10 H.sub.21 K80.3 C198.2 I28265 C.sub.6 H.sub.13 OOCC.sub.6 H.sub.13 K82.3 C199.4 N225.2 I__________________________________________________________________________ TABLE 24______________________________________ ##STR57##No L R Cr LC______________________________________32163 H OC.sub.9 H.sub.19 K105 S126 I32165 C.sub.6 H.sub.13 OC.sub.4 H.sub.9 K68 S115 N165 I32166 C.sub.6 H.sub.13 OC.sub.9 H.sub.19 K83 S167 N177 I32167 C.sub.4 H.sub.9O OC.sub.4 H.sub.9 K103 S117 N210 I32168 C.sub.4 H.sub.9O OC.sub.9 H.sub.19 K105 S141 N195 I32170 C.sub.6 H.sub.13O OC.sub.5 H.sub.11 K95 S145 N199 I______________________________________ ##STR58##No L R Cr LC______________________________________32162 C.sub.5 H.sub.13 C.sub.4 H.sub.9 K56 C89 A123 I______________________________________ ##STR59##No L R Cr LC______________________________________27671 C.sub.6 H.sub.13 H K82 S128 I27672 C.sub.6 H.sub.13O H K95 S152 I27673 C.sub.4 H.sub.9 C.sub.5 H.sub.11 K47 S143 I______________________________________ TABLE 25__________________________________________________________________________ ##STR60##No L R Cr LC__________________________________________________________________________8296 C.sub.6 H.sub.13 C.sub.8 H.sub.17 K50.9 A126.6 I8297 C.sub.10 H.sub.21 C.sub.8 H.sub.17 K37.1 A128.7 I8299 C.sub.8 H.sub.13CHF C.sub.8 H.sub.17 1 K63.4 A132.9 I__________________________________________________________________________ ##STR61##No L R Cr LC__________________________________________________________________________37286 C.sub.3 H.sub.7 C.sub.7 H.sub.15 K95.5 S88 G99.5 C118 A154 N174.5 I37287 C.sub.3 H.sub.7 C.sub.10 H.sub.21 K76.5 S94.5 S95.5 C120.9 A159.7 N164.4 I37288 C.sub.4 H.sub.9 C.sub.9 H.sub.19 K81 S87 S98 C102 A103 N164 I37289 C.sub.5 H.sub.11 C.sub.7 H.sub.15 K50 G101 C105 A173 N176 I37290 C.sub.5 H.sub.11 C.sub.10 H.sub.21 K69.2 S98.4 S107.3 S119.9 S170.6 I37291 C.sub.6 H.sub.13 C.sub.7 H.sub.15 K52 G83 C126 A159 N166 I37292 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K50 G101 B133 A173 I37293 C.sub.8 H.sub.17 C.sub.7 H.sub.15 K62 G94 B134 A172 I37294 C.sub.5 H.sub.11 CHMeC.sub.2 H.sub.5 2 K55.1 S103.8 A114.7 N120.6 I__________________________________________________________________________ TABLE 26______________________________________ ##STR62##No L R Cr LC______________________________________36949 C.sub.3 H.sub.7O C.sub.7 H.sub.15 K94 C136 A144 N153 I36950 C.sub.4 H.sub.9O C.sub.7 H.sub.15 K68 C144 A147 N154 I36951 C.sub.4 H.sub.5O C.sub.11 H.sub.23 K90 C145 A155 I36952 C.sub.6 H.sub.13O C.sub.7 H.sub.15 K68 C103 A171 I______________________________________ ##STR63##No L R Cr LC______________________________________37296 C.sub.2 H.sub.5 C.sub.9 H.sub.19 K76 G94 C117 A124 I37297 C.sub.3 H.sub.7 C.sub.9 H.sub.19 K83 G105 C112 A130 I37298 C.sub.4 H.sub.9 C.sub.9 H.sub.19 K72 G110 C119 A142 I______________________________________ ##STR64##No L R Cr LC______________________________________26651 C.sub.8 H.sub.17O OC.sub.8 H.sub.17 K? G259 C339.5 N344 I26652 C.sub.12 H.sub.25O OC.sub.12 H.sub.25 K? H235 C308 I26653 C.sub.16 H.sub.33O OC.sub.16 H.sub.33 K? H229 F272 C290 I______________________________________ TABLE 27______________________________________ ##STR65##No L R Cr LC______________________________________26625 Cl Cl K298 C258 N313 I26628 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K145 C166 N244 I26629 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K142 E135 C194 N225 I26633 C.sub.4 H.sub.9O OC.sub.4 H.sub.9 K197.7 C210.6 N294.2 I26634 C.sub.5 H.sub.11O OC.sub.5 H.sub.11 K179.8 1224.1 C270.7 I26635 C.sub.6 H.sub.13O OC.sub.6 H.sub.13 K167.4 1232.6 C262.7 I26636 C.sub.7 H.sub.15O OC.sub.7 H.sub.15 K160.7 1236.1 C250.3 I26637 C.sub.8 H.sub.17O OC.sub.8 H.sub.17 K153.1 1237.1 C244 I26638 C.sub.9 H.sub.19O OC.sub.9 H.sub.19 K147.6 1233.7 I26639 C.sub.10 H.sub.21O OC.sub.10 H.sub.21 K140.6 1226.8 I26640 C.sub.12 H.sub.25O OC.sub.12 H.sub.25 K129 1221.1 I______________________________________ ##STR66##No L R Cr LC______________________________________43323 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K319 S340 A? Z______________________________________ TABLE 28______________________________________ ##STR67##No L R Cr LC______________________________________3978 C.sub.6 H.sub.13O SC.sub.5 H.sub.11 K24 A71.5 I3979 C.sub.6 H.sub.13O SC.sub.6 H.sub.13 K30 A74.5 I3980 C.sub.6 H.sub.13O SC.sub.7 H.sub.15 K39.5 A72.5 I3981 C.sub.6 H.sub.13O SC.sub.8 H.sub.17 K27 A73 I3982 C.sub.6 H.sub.13O SC.sub.9 H.sub.19 K42.5 A72 I3983 C.sub.6 H.sub.13O SC.sub.10 H.sub.21 K31.5 A71.5 I3984 C.sub.7 H.sub.15O SCH.sub.3 K62.5 A73 I3985 C.sub.7 H.sub.15O SC.sub.6 H.sub.13 K40 A74.5 I3986 C.sub.7 H.sub.15O SC.sub.7 H.sub.15 K41 C42 A73 I3987 C.sub.7 H.sub.15O SC.sub.10 H.sub.21 K53 A71 I3988 C.sub.7 H.sub.15O SC.sub.11 H.sub.23 K61 A69.5 I3989 C.sub.8 H.sub.17O SC.sub.6 H.sub.13 K47 A76 I3990 C.sub.8 H.sub.17O SC.sub.7 H.sub.15 K39 G34 C51 A75 I3991 C.sub.8 H.sub.17O SC.sub.8 H.sub.17 K51 G40 C55 A75 I3992 C.sub.8 H.sub.17O SC.sub.9 H.sub.19 K47.6 G40.5 C54.5 A74.1 I3993 C.sub.8 H.sub.17O SC.sub.10 H.sub.21 K54.8 G42.2 C59.7 A74 I3994 C.sub.8 H.sub.17O SC.sub.11 H.sub.23 K61.4 C53.4 A74.5 I3995 C.sub.9 H.sub.19O SCH.sub.3 K73 A77.5 I3996 C.sub.9 H.sub.19O SC.sub.6 H.sub.13 K48 A76 I3997 C.sub.9 H.sub.19O SC.sub.8 H.sub.17 K52 G38.1 C58 A75.8 I3998 C.sub.9 H.sub.19O SC.sub.9 H.sub.19 K48.5 G38.5 C57 A74.8 I3999 C.sub.9 H.sub.19O SC.sub.10 H.sub.21 K54.7 G42.2 C59.7 A73.9 I4000 C.sub.9 H.sub.19O SC.sub.11 H.sub.23 K60 C54.7 A73.4 I4001 C.sub.10 H.sub.21O SC.sub.6 H.sub.13 K56 A76.5 I4002 C.sub.10 H.sub.21O SC.sub.9 H.sub.19 K58.8 G54 C69.3 A75.7 I4003 C.sub.10 H.sub.21O SC.sub.10 H.sub.21 K62.1 G57.8 C71 A75 I4004 C.sub.10 H.sub.21O OC.sub.11 H.sub.23 K62 558.6 C70.9 A74.8 I4005 C.sub.11 H.sub.23O SC.sub.10 H.sub.21 K64.5 G61.8 C73.9 A75 I4006 C.sub.11 H.sub.23O OC.sub.11 H.sub.23 K65 S63 C74.2 A74.7 I4016 C.sub.6 H.sub.13S C.sub.6 H.sub.13 K50 A57.5 I______________________________________ TABLE 29__________________________________________________________________________ ##STR68##No L R Cr LC__________________________________________________________________________4017 C.sub.4 H.sub.9S SC.sub.6 H.sub.13 K42.5 A42 I4018 C.sub.6 H.sub.13S SC.sub.6 H.sub.13 K40 A48.5 I4019 CH.sub.3CMe.sub.2C.sub.5 H.sub.10O C.sub.8 H.sub.17 K73 C64 A71 W4020 CH.sub.3CMe.sub.2C.sub.5 H.sub.10O OC.sub.9 H.sub.19 K86 C80 A82 W4021 CH.sub.3CMe.sub.2C.sub.5 H.sub.10O SC.sub.10 H.sub.21 K60 C53 A55 W4023 C.sub.6 H.sub.13OC.sub.2 H.sub.4OC.sub.2 H.sub.4O OC.sub.9 H.sub.19 K48 A44 I4028 C.sub.5 H.sub.11COO C.sub.6 H.sub.13 K79 B85.5 A95 I4030 C.sub.10 H.sub.21O OCH.sub.2CHMeC.sub.2 H.sub.5 S K63 A69 I4031 C.sub.8 H.sub.17 OC.sub.3 H.sub.6CHMeC.sub.2 H.sub.5 1 K51.8 A55 I4032 C.sub.10 H.sub.21O OC.sub.3 H.sub.6CHMeC.sub.2 H.sub.5 1 K63 C*57.5 A82 I4033 C.sub.10 H.sub.21O OC.sub.2 H.sub.4CHMeC.sub.3 H.sub.6CHMeCH.sub.3 1 K45 C*37 A58 I4034 C.sub.8 H.sub.17 OC.sub.5 H.sub.10CHMeC.sub.2 H.sub.5 1 K46 C*35 A60 I4035 C.sub.8 H.sub.17O C.sub.5 H.sub.10CHMeC.sub.2 H.sub.5 S K36 S46 C*55 A71 I4036 C.sub.10 H.sub.21O OC.sub.5 H.sub.10CHMeC.sub.2 H.sub.5 1 K77 C*76 A86 I4037 C.sub.8 H.sub.17O SC.sub.5 H.sub.10CHMeC.sub.2 H.sub.5 S K55.8 S24 C*55.6 A64.3 I4041 C.sub.5 H.sub.11 SCF.sub.2H K50.8 N-17 E4042 C.sub.10 H.sub.21O OC.sub.9 H.sub.18CH/CH.sub.2 CH.sub.2 K88 S70.6 C84 A87.6 I4049 CH.sub.3CHMeCHFCOO OC.sub.9 H.sub.18CH/CH.sub.2 CH.sub.2 S K78 A64 I4051 C.sub.2 H.sub.5CHMeCH.sub.2O C.sub.8 H.sub.17 1 K51 A66 I4053 C.sub.2 H.sub.5CMeCH.sub.2O OC.sub.10 H.sub.21 1 K82 A63 I4055 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.12 H.sub.25 1 K46 A62 I4056 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O SC.sub.8 H.sub.17 2 K24 C36 A49.8 I4058 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.8 H.sub.17 S K40.2 G*43.4 C*57.8 A72.3 I4059 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.12 H.sub.25 1 K57.1 C*58 A68 I4060 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O OC.sub.8 H.sub.17 1 K73 C*78 A86 I4061 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O OC.sub.9 H.sub.19 S K77.7 C*79.2 A84.7 I4062 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O SC.sub.6 H.sub.13 S K46 C*51.5 A63 I4063 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O SC.sub.7 H.sub.15 S K44.6 C*52.5 A59.8 I4064 C.sub.2 H.sub.5CMMeC.sub.5 H.sub.10O SC.sub.8 H.sub.17 1 K43 C*55 A60 I4065 C.sub.2 H.sub.5CMMeC.sub.5 H.sub.10O SC.sub.9 H.sub.19 S K28.1 C*53.5 A60.5__________________________________________________________________________ I TABLE 30__________________________________________________________________________ ##STR69##No L R Cr LC__________________________________________________________________________4178 Me.sub.3 SiC.sub.5 H.sub.10O OC.sub.8 H.sub.17 K69 C88 A93 E4179 Me.sub.3 SiC.sub.6 H.sub.12O C.sub.8 H.sub.17 K25 C47 A56.6 I4180 Me.sub.3 SiC.sub.10 H.sub.20O OC.sub.8 H.sub.17 K41 C84 A92 E4181 Me.sub.3 SiC.sub.11 H.sub.22O C.sub.8 H.sub.17 K56.7 C63.8 I4182 Me.sub.3 SiC.sub.11 H.sub.22O OC.sub.8 H.sub.17 K70 C92 E4183 C.sub.4 H.sub.9 SiMe.sub.2C.sub.3 H.sub.6O OC.sub.8 H.sub.17 K45 C65 A68 E4184 C.sub.4 H.sub.9 SiMe.sub.2C.sub.4 H.sub.8O C.sub.8 H.sub.17 K16.7 C22.3 A25.9 I4185 C.sub.4 H.sub.9 SiMe.sub.2C.sub.4 H.sub.8O OC.sub.8 H.sub.17 K16.5 C63.1 A64 I4186 C.sub.4 H.sub.9 SiMe.sub.2C.sub.5 H.sub.10O OC.sub.8 H.sub.17 K38 C74 A82 E4187 C.sub.4 H.sub.9 SiMe.sub.2C.sub.6 H.sub.12O OC.sub.8 H.sub.17 K22 C72 A78.5 E4188 EtMe.sub.2 SiC.sub.4 H.sub.8O C.sub.8 H.sub.17 K35.2 C30.6 A32.3 I4189 EtMe.sub.2 SiC.sub.4 H.sub.8O OC.sub.8 H.sub.17 K49.4 C71 A71.3 I4190 EtMe.sub.2 SiC.sub.6 H.sub.12O C.sub.8 H.sub.17 K22.6 C41.6 A50.4 I4191 EtMe.sub.2 SiC.sub.6 H.sub.12O OC.sub.8 H.sub.17 K38.6 C78 A84 I4192 EtMe.sub.2 SiC.sub.11 H.sub.22O C.sub.8 H.sub.17 K45.7 C58.6 A58.9 I4211 C.sub.5 H.sub.11 CN K94 A93.5 N109 I4212 C.sub.6 H.sub.13 CN K86.5 A101.5 N103 I4213 C.sub.7 H.sub.15 CN K96.5 A109 I4214 C.sub.9 H.sub.19 CN K90 A107 I4219 C.sub.5 H.sub.11O CN K97 A102.5 N133 I4220 C.sub.6 H.sub.13O CN K93.5 A121 N134 I4221 C.sub.7 H.sub.15O CN K102.5 A127 N129.5 I4222 C.sub.8 H.sub.17O CN K102 A133 I4223 C.sub.9 H.sub.19O CN K? X? I__________________________________________________________________________ TABLE 31__________________________________________________________________________ ##STR70##No L R Cr LC__________________________________________________________________________4229 C.sub.6 H.sub.13OCOO CN K83 A96 N121 I4230 C.sub.8 H.sub.17O OC.sub.6 H.sub.12SiMe.sub.3 K38.7 C64.5 I4231 C.sub.8 H.sub.17O OC.sub.11 H.sub.22SiMe.sub.3 K69.4 C92 I4232 C.sub.12 H.sub.25O OC.sub.11 H.sub.22SiMe.sub.3 K81.6 C89.9 I4233 C.sub.8 H.sub.17O OC.sub.4 H.sub.8SiMe.sub.2 C.sub.4 H.sub.9 K36.4 A30.6 N30.7 I4234 C.sub.8 H.sub.17O OC.sub.6 H.sub.12SiMe.sub.2 Et K28.7 C56 I4235 C.sub.12 H.sub.25O OC.sub.11 H.sub.22SiMe.sub.2 Et K75.4 C84.9 I4236 C.sub.5 H.sub.11 C.sub.6 H.sub.13 K10 A26.5 I4237 C.sub.5 H.sub.11 C.sub.7 H.sub.15 K30.6 S47.7 I4239 C.sub.6 H.sub.13 C.sub.7 H.sub.15 K21.1 A47.3 I4240 C.sub.6 H.sub.13 C.sub.8 H.sub.17 K20.5 A48.4 I4241 C.sub.7 H.sub.15 C.sub.6 H.sub.13 K15 A29 I4242 C.sub.7 H.sub.15 C.sub.8 H.sub.17 K23.4 A50.3 I4243 C.sub.7 H.sub.15 C.sub.9 H.sub.19 K41.1 F24 A59.7 I4244 C.sub.7 H.sub.15 C.sub.10 H.sub.21 K29.8 F33.8 C43.3 A60.6 I4245 C.sub.7 H.sub.15 C.sub.11 H.sub.23 K39.2 F48.4 C53.5 A64.7 I4246 C.sub.7 H.sub.15 C.sub.12 H.sub.25 K41.4 F53.8 C58 A65.2 I4247 C.sub.7 H.sub.15 C.sub.14 H.sub.29 K38.5 F62.7 A67.2 I4248 C.sub.8 H.sub.17 C.sub.6 H.sub.13 K18 A29.5 I4249 C.sub.8 H.sub.17 C.sub.7 H.sub.15 K18.5 A48.1 I4250 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K31.5 A50.2 I4251 C.sub.8 H.sub.17 C.sub.9 H.sub.19 K29 F24.6 A59.8 I4252 C.sub.8 H.sub.17 C.sub.10 H.sub.21 K33.6 F36.7 C46.2 A59.8 I4253 C.sub.8 H.sub.17 C.sub.11 H.sub.23 K41 F50.8 C55.4 A64.2 I4254 C.sub.8 H.sub.17 C.sub.12 H.sub.25 K47.5 F55.6 C62.2 A64.2 I4255 C.sub.8 H.sub.17 C.sub.14 H.sub.29 K57.7 F64.5 C66.3 I__________________________________________________________________________ TABLE 32______________________________________ ##STR71##No L R Cr LC______________________________________4256 C.sub.8 H.sub.17 C.sub.16 H.sub.33 K56 F67 I4257 C.sub.9 H.sub.19 C.sub.6 H.sub.13 K23.5 A30.5 N33 I4258 C.sub.9 H.sub.19 C.sub.8 H.sub.17 K27.3 A51.2 I4259 C.sub.9 H.sub.19 C.sub.10 H.sub.21 K32.5 F36.5 C44 A60.7 I4260 C.sub.9 H.sub.19 C.sub.12 H.sub.25 K41 F56.8 C63.2 A65.6 I4261 C.sub.10 H.sub.21 C.sub.6 H.sub.13 K31 A29.3 N31 I4262 C.sub.10 H.sub.21 C.sub.8 H.sub.17 K35.5 A49.7 I4263 C.sub.10 H.sub.21 C.sub.10 H.sub.21 K46.3 C45 A59.8 I4264 C.sub.10 H.sub.21 C.sub.11 H.sub.23 K41.2 F52.6 C54.8 A64.6 I4265 C.sub.10 H.sub.21 C.sub.12 H.sub.25 K48.8 F58 C64 A65 I4266 C.sub.12 H.sub.25 C.sub.8 H.sub.17 K46.8 A48.3 I4267 C.sub.12 H.sub.25 C.sub.11 H.sub.23 K52.9 F52.2 A63.6 I4268 C.sub.12 H.sub.25 C.sub.12 H.sub.25 K59.9 F59.7 C64 A64.7 I4269 C.sub.4 H.sub.9 OC.sub.6 H.sub.13 K42 A72 I4271 C.sub.6 H.sub.13 OC.sub.4 H.sub.9 K40 A56.5 N60.5 I4272 C.sub.6 H.sub.13 OC.sub.5 H.sub.11 K48 A62 I4273 C.sub.6 H.sub.13 OC.sub.6 H.sub.13 K49 A77 I4274 C.sub.6 H.sub.13 OC.sub.7 H.sub.15 K32.5 C50.6 A76.6 I4275 C.sub.6 H.sub.13 OC.sub.8 H.sub.17 K29 C68 A85 I4276 C.sub.6 H.sub.13 OC.sub.9 H.sub.19 K47.7 C77.2 A83.6 I4277 C.sub.6 H.sub.13 OC.sub.10 H.sub.21 K38 S35 C82 A87 I4278 C.sub.6 H.sub.13 OC.sub.11 H.sub.23 K38.8 S42.3 C84.3 A86.4 I4279 C.sub.6 H.sub.13 OC.sub.12 H.sub.25 K35 S47.4 C85.6 A87.1 I4280 C.sub.6 H.sub.13 OC.sub.14 H.sub.29 K34.4 S54.9 C85.2 A86.6 I4281 C.sub.6 H.sub.13 OC.sub.15 H.sub.31 K49.9 S56.7 C83.3 A85.2 I4283 C.sub.7 H.sub.15 OC.sub.5 H.sub.11 K46 A64 N66 I4284 C.sub.7 H.sub.15 OC.sub.6 H.sub.13 K51 A78 I4285 C.sub.7 H.sub.15 OC.sub.7 H.sub.15 K32.2 C45 A77.5 I______________________________________ TABLE 33__________________________________________________________________________ ##STR72##No L R Cr LC__________________________________________________________________________4286 C.sub.7 H.sub.15 OC.sub.8 H.sub.17 K32 C64 A87 I4287 C.sub.7 H.sub.15 OC.sub.9 H.sub.19 K34.2 C76.3 A85.1 I4288 C.sub.7 H.sub.15 OC.sub.10 H.sub.21 K32 S33 C83 A88 I4289 C.sub.7 H.sub.15 OC.sub.11 H.sub.23 K38.7 S45.2 C86.8 A88.6 I4290 C.sub.7 H.sub.15 OC.sub.12 H.sub.25 K46 S54 C88 A89 I4292 C.sub.8 H.sub.17 OC.sub.5 H.sub.11 K47 A61 I4293 C.sub.8 H.sub.17 OC.sub.6 H.sub.13 K46 A76 I4294 C.sub.8 H.sub.17 OC.sub.7 H.sub.15 K46.5 C39 A77.5 I4295 C.sub.8 H.sub.17 OC.sub.8 H.sub.17 K39 C58 A84 I4296 C.sub.8 H.sub.17 OC.sub.9 H.sub.19 K40.5 C76 A84.6 I4297 C.sub.8 H.sub.17 OC.sub.10 H.sub.21 K42 C84 A88 I4298 C.sub.8 H.sub.17 OC.sub.11 H.sub.23 K54.3 C87.2 I4299 C.sub.8 H.sub.17 OC.sub.12 H.sub.25 K57 S58 C89 I4300 C.sub.8 H.sub.17 OC.sub.14 H.sub.29 K59.8 S67.2 C88.3 I4301 C.sub.8 H.sub.17 OC.sub.15 H.sub.31 K57.9 S69.6 C87.5 I4303 C.sub.9 H.sub.19 OC.sub.5 H.sub.11 K49 A62 N63 I4304 C.sub.9 H.sub.19 OC.sub.6 H.sub.13 K48 A77 I4305 C.sub.9 H.sub.19 OC.sub.7 H.sub.15 K40 A78 I4306 C.sub.9 H.sub.19 OC.sub.8 H.sub.17 K36 C53 A85 I4307 C.sub.9 H.sub.19 OC.sub.9 H.sub.19 K39 C73.9 A84.9 I4308 C.sub.9 H.sub.19 OC.sub.10 H.sub.21 K37 532 C83 A87 I4309 C.sub.9 H.sub.19 OC.sub.11 H.sub.23 K45 S46 C87 I4310 C.sub.9 H.sub.19 OC.sub.12 H.sub.25 K47 S59 C89 I4311 C.sub.10 H.sub.21 OC.sub.9 H.sub.19 K46.6 C71.4 A83.8 I4312 C.sub.10 H.sub.21 OC.sub.11 H.sub.23 K51.4 S47 C86.5 I4326 C.sub.8 H.sub.17 OOCC.sub.7 H.sub.15 K79.4 A74.4 I4334 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.8 H.sub.17 K8 C47 A69 I4335 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OOCC.sub.7 H.sub.15 K70__________________________________________________________________________ TABLE 34__________________________________________________________________________ ##STR73##No L R Cr LC__________________________________________________________________________4336 C.sub.6 H.sub.13OC.sub. HMe OC.sub.10 H.sub.21 1 K<-40 C*-40 A-23 I4337 C.sub.2 H.sub.5OC.sub. HMeC.sub.5 H.sub.10 OC.sub.6 H.sub.13 1 K-22 C*-21 A48 I4338 C.sub.2 H.sub.5OC.sub. HMeC.sub.5 H.sub.10 OC.sub.8 H.sub.17 1 K? S8 C*49 A55 I4339 C.sub.2 H.sub.5OC.sub. HMeC.sub.5 H.sub.10 OC.sub.10 H.sub.21 1 K? S10 C*55 I4340 C.sub.2 H.sub.5OC.sub. HMeC.sub.5 H.sub.10 OC.sub.11 H.sub.23 1 K27 C*56 I4341 C.sub.2 H.sub.5C.sub. HMeC.sub.5 H.sub.10 OC.sub.12 H.sub.25 1 K13 C*56 I4342 C.sub.3 H.sub.7OC.sub. HMeC.sub.5 H.sub.10 OC.sub.8 H.sub.17 1 K? S-6 C*46 A52 I4343 C.sub.5 H.sub.11OC.sub. HMeC.sub.5 H.sub.10 OC.sub.8 H.sub.17 1 K? S-4 C*37 A44 I4346 C.sub. H.sub.3O C.sub.9 H.sub.19 K40 S31 N41 I4349 C.sub.2 H.sub.5O C.sub.8 H.sub.17 K42.5 A43.5 N58.5 I4353 C.sub.3 H.sub.7O C.sub.7 H.sub.15 K42 A43.5 N52 I4354 C.sub.3 H.sub.7O C.sub.8 H.sub.17 K45 A49.5 I4358 C.sub.4 H.sub.9O C.sub.7 H.sub.15 K40.5 A42 N64 I4359 C.sub.4 H.sub.9O C.sub.8 H.sub.17 K35 A53.5 N60 I4363 C.sub.5 H.sub.11O C.sub.7 H.sub.15 K49 C48.5 A52 N66 I4364 C.sub.5 H.sub.11O C.sub.8 H.sub.17 K38 A54 N58 I4365 C.sub.5 H.sub.11O C.sub.9 H.sub.19 K41 A65.5 I4366 C.sub.5 H.sub.11O C.sub.10 H.sub.21 K47.5 A67 I__________________________________________________________________________ TABLE 35______________________________________ ##STR74##No L R Cr LC______________________________________4370 C.sub.6 H.sub.13O C.sub.7 H.sub.15 K45.5 A33 N69.5 I4371 C.sub.6 H.sub.13O C.sub.8 H.sub.17 K27.5 C44.5 A57.5 N65 I4372 C.sub.6 H.sub.13O C.sub.9 H.sub.19 K33.5 C49.5 A71 N71.5 I4373 C.sub.6 H.sub.13O C.sub.10 H.sub.21 K32.5 C62 A74.5 I4377 C.sub.7 H.sub.15O C.sub.7 H.sub.15 K44 C44 A49 N68 I4378 C.sub.7 H.sub.15O C.sub.8 H.sub.17 K46 C49 A61 N66 I4379 C.sub.7 H.sub.15O C.sub.9 H.sub.19 K35 C51.5 A71.5 I4380 C.sub.7 H.sub.15O C.sub.10 H.sub.21 K46 C62.5 A72 I4384 C.sub.8 H.sub.17O C.sub.7 H.sub.15 K49 A44 N69.5 I4385 C.sub.8 H.sub.17O C.sub.8 H.sub.17 K35 C57 A64 N70 I4386 C.sub.8 H.sub.17O C.sub.9 H.sub.19 K33 C60 A74.5 I4387 C.sub.8 H.sub.17O C.sub.10 H.sub.21 K37 C68.5 A73.5 I4391 C.sub.9 H.sub.19O C.sub.7 H.sub.15 K48 C51 A57 N70 I4392 C.sub.9 H.sub.19O C.sub.8 H.sub.17 K33 C56 A65 N68.5 I4393 C.sub.9 H.sub.19O C.sub.9 H.sub.19 K34 C61 A75 I4394 C.sub.9 H.sub.19O C.sub.11 H.sub.23 K45 C78 A80 I4397 C.sub.10 H.sub.21O C.sub.7 H.sub.15 K53 A54.5 N71.5 I______________________________________ TABLE 36__________________________________________________________________________ ##STR75##No L R Cr LC__________________________________________________________________________4398 C.sub.10 H.sub.21O C.sub.8 H.sub.17 K32 C59.5 A65.5 N69.5 I4399 C.sub.10 H.sub.21O C.sub.10 H.sub.21 K41 C74 A77 I4401 C.sub.11 H.sub.23O C.sub.7 H.sub.15 K55 C54.5 A62.5 N70 I4402 C.sub.11 H.sub.23O C.sub.8 H.sub.17 K44.5 C60 A67 N69 I4405 C.sub.12 H.sub.25O C.sub.7 H.sub.15 K59.5 C57.5 A63 N71 I4406 C.sub.12 H.sub.25O C.sub.8 H.sub.17 K42 C61.5 A68.5 N70 I4408 C.sub.10 H.sub.21O C.sub.5 H.sub.10CHMeOC.sub.2 H.sub.5 1 K43 C*13 N*27 I4409 C.sub.3 H.sub.7O OC.sub.7 H.sub.15 K68.6 C65 A78.7 N83.6 I4410 C.sub.3 H.sub.7O OC.sub.8 H.sub.17 K49.8 C70.5 A88.2 N88.7 I4411 C.sub.3 H.sub.7O OC.sub.9 H.sub.19 K43.7 C72 A89.4 I4412 C.sub.3 H.sub.7O OC.sub.10 H.sub.21 K45.6 C71 A92.6 I4413 C.sub.3 H.sub.7O OC.sub.11 H.sub.23 K41.9 C68 A93 I4414 C.sub.3 H.sub.7O OC.sub.12 H.sub.25 K43.4 C61.6 A94.1 I4415 C.sub.4 H.sub.9O OC.sub.7 H.sub.15 K53.4 C75.1 A82.4 N92.1 I4416 C.sub.4 H.sub.9O OC.sub.8 H.sub.17 K54.4 C84 A94.7 N96.6 I4417 C.sub.4 H.sub.9O OC.sub.9 H.sub.19 K44.4 C87.7 A96.6 I4418 C.sub.4 H.sub.9O OC.sub.10 H.sub.21 K41.8 C90 A99.4 I4419 C.sub.4 H.sub.9O OC.sub.11 H.sub.23 K42.3 C89 A99.8 I4420 C.sub.4 H.sub.9O OC.sub.12 H.sub.25 K41.8 C88.4 A101 I4422 C.sub.5 H.sub.11O OC.sub.6 H.sub.13 K62 C65.9 A76.6 N92.7 I4423 C.sub.5 H.sub.11O OC.sub.7 H.sub.15 K54.4 C77.4 A84.2 N91.3 I4424 C.sub.5 H.sub.11O OC.sub.8 H.sub.17 K50.2 C85.9 A93.9 N94.8 I4425 C.sub.5 H.sub.11O OC.sub.9 H.sub.19 K66.7 C90 A95 I4426 C.sub.5 H.sub.11O OC.sub.10 H.sub.21 K41.4 C93.9 A97.2 I4427 C.sub.5 H.sub.11O OC.sub.11 H.sub.23 K51.4 C95.9 A98.2 I4428 C.sub.5 H.sub.11O OC.sub.12 H.sub.25 K41.7 C96.2 A98.6 I__________________________________________________________________________ TABLE 37______________________________________ ##STR76##No L R Cr LC______________________________________4429 C.sub.6 H.sub.13O OC.sub.6 H.sub.13 K62 A68 N69 I4430 C.sub.6 H.sub.13O OC.sub.7 H.sub.15 K45.8 C80.6 A84.7 N94.9 I4431 C.sub.6 H.sub.13O OC.sub.8 H.sub.17 K42.6 C89.8 A96.6 N98.7 I4432 C.sub.6 H.sub.13O OC.sub.9 H.sub.19 K49.9 C94.4 A97.9 I4433 C.sub.6 H.sub.13O OC.sub.10 H.sub.21 K43.8 C98.7 A100.3 I4434 C.sub.6 H.sub.13O OC.sub.11 H.sub.23 K55.4 C100.4 A101 I4435 C.sub.6 H.sub.13O OC.sub.12 H.sub.25 K52.2 C102.2 I4436 C.sub.7 H.sub.15O OC.sub.6 H.sub.13 K60.8 C68.2 A79.4 N94.6 I4437 C.sub.7 H.sub.15O OC.sub.7 H.sub.15 K59.2 C79.9 A87.6 N93.6 I4438 C.sub.7 H.sub.15O OC.sub.8 H.sub.17 K51.6 C87.2 A96.4 N97.1 I4439 C.sub.7 H.sub.15O OC.sub.9 H.sub.19 K56 C94.9 A97.8 I4440 C.sub.7 H.sub.15O OC.sub.10 H.sub.21 K55.6 C99.6 A100.3 I4441 C.sub.7 H.sub.15O OC.sub.11 H.sub.23 K67.4 C100.1 I4442 C.sub.7 H.sub.15O OC.sub.12 H.sub.25 K54.8 C100.3 I4444 C.sub.8 H.sub.17O OC.sub.6 H.sub.13 K59.3 C73 A80 N96.2 I4445 C.sub.8 H.sub.17O OC.sub.7 H.sub.15 K53.4 C81.5 A88.3 N95.4 I4446 C.sub.8 H.sub.17O OC.sub.8 H.sub.17 K51 C92.3 A99.5 N100.3 I4447 C.sub.8 H.sub.17O OC.sub.9 H.sub.19 K48.2 C96.4 A99 I4448 C.sub.8 H.sub.17O OC.sub.10 H.sub.21 K51.7 C101.7 A102.1 I4449 C.sub.8 H.sub.17O OC.sub.11 H.sub.23 K59.9 C101.7 I4450 C.sub.8 H.sub.17O OC.sub.12 H.sub.25 K57.1 C102.9 I4451 C.sub.9 H.sub.19O OC.sub.6 H.sub.13 K61.6 C68.9 A83.2 N93.7 I4452 C.sub.9 H.sub.19O OC.sub.7 H.sub.15 K55.2 C78.7 A89.6 N93.6 I4453 C.sub.9 H.sub.19O OC.sub.8 H.sub.17 K55.1 C87.5 A96.2 I4454 C.sub.9 H.sub.19O OC.sub.9 H.sub.19 K65 C97 A101 I4455 C.sub.9 H.sub.19O OC.sub.10 H.sub.21 K52.5 C101.1 I4456 C.sub.9 H.sub.19O OC.sub.11 H.sub.23 K62 C101 I4457 C.sub.9 H.sub.19O OC.sub.12 H.sub.25 K60.3 C100.3 I4458 C.sub.10 H.sub.21O OC.sub.6 H.sub.13 K62.3 C71.6 A83.8 N93.6 I______________________________________ TABLE 38__________________________________________________________________________ ##STR77##No L R Cr LC__________________________________________________________________________4459 C.sub.10 H.sub.21O OC.sub.7 H.sub.15 K50.4 C79.7 A90.1 N93.6 I4460 C.sub.10 H.sub.21O OC.sub.8 H.sub.17 K50 C89 A99.6 I4461 C.sub.10 H.sub.21O OC.sub.9 H.sub.19 K52.3 C96.2 A99 I4462 C.sub.10 H.sub.21O OC.sub.10 H.sub.21 K52.7 C101.4 I4463 C.sub.10 H.sub.21O OC.sub.11 H.sub.23 K62.9 C101.2 I4464 C.sub.10 H.sub.21O OC.sub.12 H.sub.25 K65.4 C102.8 I4465 C.sub.10 H.sub.21O OC.sub.14 H.sub.29 K67 C103 I4466 C.sub.11 H.sub.23O OC.sub.6 H.sub.13 K69.3 C69 A86.2 N91.8 I4467 C.sub.11 H.sub.23O OC.sub.7 H.sub.15 K58.2 C77 A90.1 N91.9 I4468 C.sub.11 H.sub.23O OC.sub.8 H.sub.17 K56 C84.9 A97.1 I4469 C.sub.11 H.sub.23O OC.sub.9 H.sub.18 K56.2 C92.7 A96.1 I4470 C.sub.11 H.sub.23O OC.sub.10 H.sub.21 K53.1 C100.6 I4471 C.sub.11 H.sub.23O OC.sub.11 H.sub.23 K69.8 C99.8 I4472 C.sub.11 H.sub.23O OC.sub.12 H.sub.25 K65.6 C101 I4473 C.sub.11 H.sub.23O OC.sub.16 H.sub.33 K71.3 S75.6 C100.9 I4474 C.sub.12 H.sub.25O OC.sub.6 H.sub.13 K70.3 C70.7 A86.2 N91.4 I4475 C.sub.12 H.sub.25O OC.sub.7 H.sub.15 K57.1 C77.2 A89.4 N90.9 I4476 C.sub.12 H.sub.25O OC.sub.8 H.sub.17 K50 C86 A98 I4477 C.sub.12 H.sub.25O OC.sub.9 H.sub.19 K53.8 C93.5 A96.9 I4478 C.sub.12 H.sub.25O OC.sub.10 H.sub.21 K54.6 C100.3 I4479 C.sub.12 H.sub.25O OC.sub.11 H.sub.23 K59.5 C100.7 I4480 C.sub.12 H.sub.25O OC.sub.12 H.sub.25 K63.7 C104.3 I4481 C.sub.12 H.sub.25O OC.sub.16 H.sub.33 K71.2 S73.7 C99 I4484 C.sub.8 H.sub.17O OC.sub.4 H.sub.8CMe.sub.2C.sub.4 H.sub.9 K54 C34 N37 I4485 C.sub.8 H.sub.17O OC.sub.6 H.sub.12CMe.sub.2C.sub.4 H.sub.9 K43 C55 I4498 C.sub.7 H.sub.15O OOC.sub.C.sub.6 H.sub.13 K64.9 C66.2 N85.8 I4499 C.sub.7 H.sub.15O OOC.sub.C.sub.9 H.sub.19 K74.8 C96.5 I4500 C.sub.7 H.sub.15O OOC.sub.C.sub.13 H.sub.27 K81 S73 C101 I4501 C.sub.8 H.sub.17O OOC.sub.C.sub.6 H.sub.13 K63.4 C69.7 N89.7 I4502 C.sub.8 H.sub.17O OOC.sub.C.sub.7 H.sub.15 K75 C74.4 N91.3 I__________________________________________________________________________ TABLE 39__________________________________________________________________________ ##STR78##No L R Cr LC__________________________________________________________________________4614 C.sub.7 H.sub.15COO C.sub.7 H.sub.15 K54 A40 N57 I4615 C.sub.7 H.sub.15COO C.sub.8 H.sub.17 K51 C52 A54 N56 I4616 C.sub.7 H.sub.15COO C.sub.9 H.sub.19 K53 C64 A65 I4619 C.sub.8 H.sub.17COO C.sub.8 H.sub.17 K49 C53.5 A54.8 N56.5 I4620 C.sub.8 H.sub.17COO C.sub.10 H.sub.21 K53 S50 C70 I4623 C.sub.9 H.sub.19COO C.sub.8 H.sub.17 K42 C55.5 N59.8 I4626 C.sub.10 H.sub.21COO C.sub.8 H.sub.17 K57 C56.5 A56.7 N59 I4629 C.sub.11 H.sub.23COO C.sub.8 H.sub.17 K56 C57.5 N60.8 I4630 C.sub.7 H.sub.15COO OC.sub.8 H.sub.17 K73 C89 A92 N93 I4636 C.sub.4 H.sub.9CMe.sub.2CH.sub.2COO OC.sub.8 H.sub.17 K53 C49 N50 I4637 C.sub.6 H.sub.13CMe.sub.2CH.sub.2COO OC.sub.8 H.sub.17 K45 C42 N46 I4643 C.sub.5 H.sub.11OCOO C.sub.12 H.sub.25 K48 A524645 C.sub.9 H.sub.19OCOO C.sub.12 H.sub.25 K46 C59 I4647 C.sub.12 H.sub.25OCOO C.sub.12 H.sub.25 K57 C60 I4661 C.sub.8 H.sub.17O C.sub.3 H.sub.6C.sub. HMeC.sub.2 H.sub.5 1 K33.5 N*19U4662 C.sub.9 H.sub.19O C.sub.3 H.sub.6C.sub. HMeC.sub.2 H.sub.5 1 K35 N*20U4663 C.sub.10 H.sub.21O C.sub.3 H.sub.6C.sub. HMeC.sub.2 H.sub.5 1 K38 N*21.5U4664 C.sub.12 H.sub.25O C.sub.3 H.sub.6C.sub. HMeC.sub.2 H.sub.5 1 K43.5 N*40.5U4665 C.sub.8 H.sub.17 OC.sub.5 H.sub.10C.sub. HMeC.sub.2 H.sub.5 1 K-13 S10 S18 C*51 A51.4 I4666 C.sub.8 H.sub.17 OC.sub.5 H.sub.10C.sub. HMeC.sub.2 H.sub.5 2 K16 C57.5 A59 I__________________________________________________________________________ TABLE 40__________________________________________________________________________ ##STR79##No L R Cr LC__________________________________________________________________________4697 C.sub.8 H.sub.17O OCH.sub.2CHFC.sub.8 H.sub.17 1 K62.5 C*92 A97 I4698 C.sub.9 H.sub.19O OCH.sub.2CHFC.sub.6 H.sub.13 1 K61 C*90.3 A96.2 I4699 C.sub.10 H.sub.21O OCH.sub.2CHFC.sub.6 H.sub.13 1 K47 C*90 A97 I4700 C.sub.12 H.sub.25O OCH.sub.2CHFC.sub.6 H.sub.13 1 K66 C*89 A96 I4701 C.sub.8 H.sub.17 C.sub.2 H.sub.4CHFC.sub.6 H.sub.13 1 K31 C*25 A62 I4702 C.sub.8 H.sub.17O C.sub.2 H.sub.4CHFC.sub.6 H.sub.13 S K74 A82 I4703 C.sub.10 H.sub.21O C.sub.2 H.sub.4CHFC.sub.6 H.sub.13 1 K71 C*69 A82 I4704 C.sub.10 H.sub.21O C.sub.2 H.sub.4CHFC.sub.8 H.sub.17 S K85 C*84 A86 I4705 C.sub.12 H.sub.25O C.sub.2 H.sub.4CHFC.sub.6 H.sub.13 S K74 A82 I4706 C.sub.10 H.sub.21O OC.sub.2 H.sub.4CHFC.sub.6 H.sub.13 1 K50 C*96 N*97 I4707 C.sub.10 H.sub.21O OC.sub.3 H.sub.6CHFC.sub.6 H.sub.13 1 K61 C*102 A103 I4715 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OOCCH.sub.CHC.sub.7 H.sub.15 K63 C61 N69 I4716 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OOCCH.sub.CHC.sub.8 H.sub.17 K53 C62 A64 N68 I4717 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OOCCH.sub.CHC.sub.9 H.sub.19 K63 C73 I4718 C.sub.6 H.sub.13 OCH.sub.2CH.sub.CHC.sub.2 H.sub.5 K57 A63 I4719 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.3 H.sub.7 K67 A76 I4720 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.4 H.sub.9 K62 C65 A71 I4721 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.5 H.sub.11 K61 C76 A80 I4722 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.6 H.sub.13 K74 C78 I4723 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.7 H.sub.15 K65 C82 I4724 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.8 H.sub.17 K73 C82 I4725 C.sub.6 H.sub.13 OCH.sub.2CHCHC.sub.9 H.sub.19 K56 S72 C84 I4726 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.2 H.sub.5 K53 A66 I4727 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.3 H.sub.7 K69 A78 I4728 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.4 H.sub.9 K60 C61 A73 I4729 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.5 H.sub.11 K59 C75 A82 I4730 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.6 H.sub.13 K67 C80 I__________________________________________________________________________ TABLE 41__________________________________________________________________________ ##STR80##No L R Cr LC__________________________________________________________________________4731 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.7 H.sub.15 K64 C86 I4732 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.8 H.sub.17 K72 C85 I4733 C.sub.7 H.sub.15 OCH.sub.2CHCHC.sub.9 H.sub.19 K67 S74 C87 I4734 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.2 H.sub.5 K53 A65 I4735 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.3 H.sub.7 K68 A77 I4736 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.4 H.sub.9 K57 A73 I4737 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.5 H.sub.11 K56 C69.5 A81 I4738 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.6 H.sub.13 K67 C79 I4739 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.7 H.sub.15 K39 S62 C84 I4740 C.sub.8 H.sub.17 CCH.sub.2CHCHC.sub.8 H.sub.17 K51 S67 C85 I4741 C.sub.8 H.sub.17 OCH.sub.2CHCHC.sub.9 H.sub.19 K66 S74 C86 I4742 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.2 H.sub.5 K57 A66 I4743 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.3 H.sub.7 K70 A77 I4744 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.4 H.sub.9 K57 C48 A73 I4745 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.5 H.sub.11 K56 C65 A82 I4746 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.6 H.sub.13 K62 C78 A80 I4747 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.7 H.sub.15 K60 S58 C84 I4748 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.8 H.sub.17 K50 S63 C86 I4749 C.sub.9 H.sub.19 OCH.sub.2CHCHC.sub.9 H.sub.19 K61 S74 C87 I4750 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.3 H.sub.7 K47 A56 I4751 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.4 H.sub.9 K20 A41 I4752 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.5 H.sub.11 K36 C58 A63 I4753 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.6 H.sub.13 K51 C60 I4754 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.7 H.sub.15 K44 C65 I4755 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.8 H.sub.17 K50 S49 C68 I4756 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OCH.sub.2CHCHC.sub.9 H.sub.19 K53 S59 C71 I4760 C.sub.6 H.sub.13 OC.sub.3 H.sub.6CHCH.sub.2 K39 A69 I4761 C.sub.6 H.sub.13 OC.sub.3 H.sub.6CHCHC.sub.3 H.sub.7 K57 C68 A80 I4762 C.sub.7 H.sub.15 OC.sub.3 H.sub.6CHCH.sub.2 K48 A72 I__________________________________________________________________________ TABLE 42__________________________________________________________________________ ##STR81##No L R Cr LC__________________________________________________________________________4763 C.sub.7 H.sub.15 OC.sub.3 H.sub.6CHCHC.sub.3 H.sub.7 K57 C66 A82 I4764 C.sub.8 H.sub.17 OC.sub.3 H.sub.6CHCH.sub.2 K43 A69 I4765 C.sub.8 H.sub.17 OC.sub.3 H.sub.6CHCHC.sub.3 H.sub.7 K53 C55 A82 I4766 C.sub.9 H.sub.19 OC.sub.3 H.sub.6CHCH.sub.2 K50 A70 I4767 C.sub.9 H.sub.19 OC.sub.3 H.sub.6CHCHC.sub.3 H.sub.7 K47 C52 A82 I4769 C.sub.6 H.sub.13 OC.sub.4 H.sub.8CHCH.sub.2 K35 A64 I4770 C.sub.7 H.sub.15 OC.sub.4 H.sub.8CHCH.sub.2 K37 A67 I4771 C.sub.8 H.sub.17 OC.sub.4 H.sub.8CHCH.sub.2 K33 A64 I4772 C.sub.9 H.sub.19 OC.sub.4 H.sub.8CHCH.sub.2 K33 A65 I4774 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.4 H.sub.8CHCH.sub.2 K18 A55 I4776 C.sub.6 H.sub.13 OC.sub.5 H.sub.10CHCH.sub.2 K34 A79 I4777 C.sub.6 H.sub.13 OC.sub.5 H.sub.10CHCHCH.sub.3 K45 C50 A85 I4778 C.sub.7 H.sub.15 OC.sub.5 H.sub.10CHCH.sub.2 K35 A81 I4779 C.sub.7 H.sub.15 OC.sub.5 H.sub.10CHCHCH.sub.3 K48 A87 I4780 C.sub.8 H.sub.17 OC.sub.5 H.sub.10CHCH.sub.2 K37 A80 I4781 C.sub.8 H.sub.17 OC.sub.5 H.sub.10CHCHCH.sub.3 K44 A85 I4782 C.sub.9 H.sub.19 OC.sub.5 H.sub.10CHCH.sub.2 K38 A81 I4783 C.sub.9 H.sub.19 OC.sub.5 H.sub.10CHCHCH.sub.3 K51 A86 I4785 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.5 H.sub.10CHCH.sub.2 K10 A59 I4786 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.5 H.sub.10CHCHCH.sub.3 K21 A70 I4788 C.sub.6 H.sub.13 OC.sub.6 H.sub.12CHCH.sub.2 K26 C54 A75 I4789 C.sub.7 H.sub.15 OC.sub.6 H.sub.12CHCH.sub.2 K24 C50 A78 I4790 C.sub.8 H.sub.17 OC.sub.6 H.sub.12CHCH.sub.2 K42 C43 A76 I4791 C.sub.9 H.sub.19 OC.sub.6 H.sub.12CHCH.sub.2 K34 C38 A77 I4792 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.6 H.sub.12CHCH.sub.2 K15 C35 A60 I4793 C.sub.6 H.sub.13 OC.sub.7 H.sub.14CHCH.sub.2 K20 C65 A81 I4794 C.sub.7 H.sub.15 OC.sub.2 H.sub.14CHCH.sub.2 K16 S23 C62 A84 I4795 C.sub.8 H.sub.17 OC.sub.7 H.sub.14CHCH.sub.2 K20 C60 A83 I4796 C.sub.9 H.sub.19 OC.sub.7 H.sub.14CHCH.sub.2 K30 C53 A84 I4797 C.sub.3 H.sub.7OC.sub.9 H.sub.10 OC.sub.7 H.sub.14CHCH.sub.2 K-30 C30 A61 I__________________________________________________________________________ TABLE 43__________________________________________________________________________ ##STR82##No L R Cr LC__________________________________________________________________________4798 C.sub.6 H.sub.13 OC.sub.8 H.sub.16CHCH.sub.2 K33 S35 C73 A80 I4799 C.sub.7 H.sub.15 OC.sub.8 H.sub.16CHCH.sub.2 K32 S33 C72 A82 I4800 C.sub.8 H.sub.17 OC.sub.8 H.sub.16CHCH.sub.2 K36 C72 A81 I4801 C.sub.9 H.sub.19 OC.sub.8 H.sub.16CHCH.sub.2 K35 C71 A82 I4802 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.8 H.sub.16CHCH.sub.2 K-3 C57 A64 I4803 C.sub.6 H.sub.13 OC.sub.9 H.sub.18CHCH.sub.2 K29 S28 C76 A82 I4804 C.sub.6 H.sub.13 OC.sub.10 H.sub.20CHCH.sub.2 K33 S35 C76 A81 I4805 C.sub.7 H.sub.15 OC.sub.9 H.sub.18CHCH.sub.2 K28 S29 C77 A85 I4806 C.sub.7 H.sub.15 OC.sub.10 H.sub.20CHCH.sub.2 K38 S40 C79 A84 I4807 C.sub.8 H.sub.17 OC.sub.9 H.sub.18CHCH.sub.2 K38 C78 A84 I4808 C.sub.8 H.sub.17 OC.sub.10 H.sub.20CHCH.sub.2 K43 C80 A82 I4809 C.sub.9 H.sub.19 OC.sub.9 H.sub.18CHCH.sub.2 K38 C78 A85 I4810 C.sub.9 H.sub.19 OC.sub.10 H.sub.20CHCH.sub.2 K43 C82 A83 I4811 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.9 H.sub.18CHCH.sub.2 K0 C55 A65 I4812 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.10 H.sub.20CHCH.sub.2 K19 S36 S59 C70 I4817 C.sub.8 H.sub.17 OC.sub.2 H.sub.4CH%CHC.sub.4 H.sub.9 K52 A43 I4818 C.sub.9 H.sub.19 OC.sub.2 H.sub.4CH%CHC.sub.4 H.sub.9 K52 A44 I4822 C.sub.6 H.sub.13 OC.sub.4 H.sub.8CH%CHC.sub.2 H.sub.5 K45 C52 A55 I4823 C.sub.7 H.sub.15 OC.sub.4 H.sub.8CH%CHC.sub.2 H.sub.5 K42 C52 A55 I4824 C.sub.8 H.sub.17 OC.sub.4 H.sub.8CH%CHC.sub.2 H.sub.5 K38 C46 A57 I4825 C.sub.9 H.sub.19 OC.sub.4 H.sub.8CH%CHC.sub.2 H.sub.5 K38 C44 A58 I4826 C.sub.3 H.sub.7OC.sub.5 H.sub.10 OC.sub.4 H.sub.8CH%CHC.sub.2 H.sub.5 K10 C33 A37 I4828 C.sub.9 H.sub.19O OC.sub.4 H.sub.8 OCH.sub.2CH/CH.sub.2 CH.sub.2 K72.4 C58.4 N72 I4829 C.sub.6 H.sub.13O OC.sub.4 H.sub.8CH/CH.sub.2 CH.sub.2 K64 C48 N88 U4830 C.sub.4 H.sub.9OC.sub.4 H.sub.8O OC.sub.4 H.sub.8CH/CH.sub.2 CH.sub.2 K42 C45 A47 N64 I4831 C.sub.6 H.sub.13O OC.sub.5 H.sub.10CH/CH.sub.2 CH.sub.2 K53 C73 A75 N86 I4832 C.sub.4 H.sub.9OC.sub.4 H.sub.8O OC.sub.5 H.sub.10CH/CH.sub.2 CH.sub.2 K39 C63 A65 N67 I4833 C.sub.8 H.sub.17O OC.sub.6 H.sub.12CH/CH.sub.2 CH.sub.3 K56 C78 A84 N89 I4834 C.sub.8 H.sub.19O OC.sub.6 H.sub.12CH/CH.sub.2 CH.sub.2 K56.5 C79 A85 N89.5 I__________________________________________________________________________ TABLE 44__________________________________________________________________________ ##STR83##No L R Cr LC__________________________________________________________________________4835 C.sub.11 H.sub.23O OC.sub.6 H.sub.12CH/CH.sub.2 CH.sub.2 K57.5 C76.5 A86.7 N87 I4836 C.sub.12 H.sub.25O OC.sub.6 H.sub.12CH/CH.sub.2 CH.sub.2 K61 C>70 A87 I4837 C.sub.4 H.sub.9OC.sub.4 H.sub.8O OC.sub.6 H.sub.12CH/CH.sub.2 CH.sub.2 K46 C66 A67 N69 I4838 C.sub.6 H.sub.13O OC.sub.7 H.sub.14CH/CH.sub.2 CH.sub.2 K51.8 C86.5 A89.6 N89.8 I4839 C.sub.9 H.sub.19O OC.sub.7 H.sub.14CH/CH.sub.2 CH.sub.2 K60 C87.9 A90.4 I4840 C.sub.10 H.sub.21O OC.sub.7 H.sub.14CH/CH.sub.2 CH.sub.2 K55.7 C90 A92.5 I4841 C.sub.11 H.sub.23O OC.sub.7 H.sub.14CH/CH.sub.2 CH.sub.2 K53.4 C87.6 A90.5 I4842 C.sub.12 H.sub.25O OC.sub.7 H.sub.14CH/CH.sub.2 CH.sub.2 K67.4 C86.1 A90.5 I4843 C.sub.4 H.sub.9OC.sub.4 H.sub.8O OC.sub.7 H.sub.14CH/CH.sub.2 CH.sub.2 K43 C73 I4844 C.sub.4 H.sub.9O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K55.4 C81 A87.8 I4845 C.sub.6 H.sub.13O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K54.1 C88.2 A90.8 I4846 C.sub.8 H.sub.17O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K56.4 C91.7 A92.9 I4847 C.sub.9 H.sub.19O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K56.2 C91.8 A93 I4848 C.sub.10 H.sub.21O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K58.5 C91.6 A92 I4849 C.sub.11 H.sub.23O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K53.6 C92.3 A93.1 I4850 C.sub.l2 H.sub.25 O OC.sub.8 H.sub.16CH/CH.sub.2 CH.sub.2 K54.9 C92.3 A93 I4851 C.sub.7 H.sub.15O OC.sub.9 H.sub.18CH/CH.sub.2 CH.sub.2 K64.7 C91 I4852 C.sub.6 H.sub.17O OC.sub.9 H.sub.18CH/CH.sub.2 CH.sub.2 K63.7 C93.2 I4853 C.sub.12 H.sub.25O OC.sub.11 H.sub.22CH/CH.sub.2 CH.sub.2 K64.6 C73.8 I4854 C.sub.8 H.sub.17 OCH.sub.2CH/O CH(t)C.sub.3 H.sub.7 1 K55 B90 A102 I4855 C.sub.8 H.sub.17 OCH.sub.2CH/O CH(t)C.sub.5 H.sub.11 1 K70 F*101 A104 I4857 C.sub.2 H.sub.5CMe.sub.2C.sub.4 H.sub.8O OCH.sub.2CH/O CH(t)C.sub.4 H.sub.9 1 K83 S87 A92 I4858 C.sub.2 H.sub.5CMe.sub.2C.sub.6 H.sub.12O OCH.sub.2CH/O CH(t)C.sub.4 H.sub.9 1 K90 C*96 A106 I4859 C.sub.2 H.sub.5CHMeOCH.sub.2 C.sub.10 H.sub.21 1 K15.6 S15.2 I4861 C.sub.6 H.sub.13CHMeOCH.sub.2 C.sub.10 H.sub.21 2 K16.9 A-8.5 I4869 C.sub.2 H.sub.5CHMeCOO C.sub.11 H.sub.23 S K52.2 S40.7 I4871 C.sub.2 H.sub.5CHMeCOO OC.sub.8 H.sub.17 S K66 C*62.2 I4872 C.sub.2 H.sub.5CHMeCOO OC.sub.11 H.sub.23 S K43 C*64.1 S67.2 I4873 CH.sub.3CHMeCHClCOO C.sub.7 H.sub.15 S K64 X-10 I4875 C.sub.2 H.sub.5CHMeCHClCOO C.sub.7 H.sub.15 3 K59 X-20 I__________________________________________________________________________ TABLE 45__________________________________________________________________________ ##STR84##No L R Cr LC__________________________________________________________________________4919 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.8 H.sub.17 S K31.2 B16.8 C*46.8 A50.8 I4920 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.9 H.sub.19 S K23 S28 C*30 A51.5 N*52 I4921 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.10 H.sub.21 S K33 S38.5 C*58 I4922 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.11 H.sub.23 S K35.9 C*60 I4923 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.12 H.sub.25 S K41 S23.8 C*62.2 I4924 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.14 H.sub.29 S K32 B45 C*59.8 I4925 C.sub.3 H.sub.7CHMeC.sub.3 H.sub.6O C.sub.9 H.sub.19 2 K15.5 C44.5 A54.5 I4926 C.sub.5 H.sub.11CHMeC.sub.3 H.sub.6O C.sub.8 H.sub.17 2 K15 C9 A42.5 I4927 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6CHMeCH.sub.2O C.sub.8 H.sub.17 7 K37 A34 I4928 CH.sub.3CHMeC.sub.3 H.sub.5CHMeC.sub.2 H.sub.4O C.sub.9 H.sub.19 S K27 A40 I4931 CH.sub.3CHMeC.sub.3 H.sub.5CHMeCH.sub.2COO C.sub.9 H.sub.19 S K44 C*<7 I4932 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.6 H.sub.13 S K-5 A27 N*42 I4933 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.7 H.sub.15 S K-6 A46.3 N*49 I4934 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.8 H.sub.17 S K12 C*34.7 A49.5 I4935 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.9 H.sub.19 S K10 C*46 A59 I4936 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.10 H.sub.21 S K17 C*53.8 A63 I4937 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.11 H.sub.23 S K20 C*59 I4938 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.12 H.sub.25 S K23 S16 C*61.5 I4939 C.sub.3 H.sub.7CHMeC.sub.4 H.sub.8O C.sub.8 H.sub.17 2 K3.5 S31.5 A47.5 I4940 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8CO C.sub.8 H.sub.17 S K67 C*69 A79.3 I4941 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8COO C.sub.8 H.sub.17 S K38.5 S24 C*44.8 I4942 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8COO C.sub.11 H.sub.23 S K62.3 S46.5 C*60 I4943 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8COO C.sub.14 H.sub.29 S K46 S50 C*62.8 I4944 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8COO OC.sub.8 H.sub.17 S K76 C*79.5 I4945 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.6 H.sub.13 S K12 C*23.8 N*45.6 I4946 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.7 H.sub.15 S K10 S16 C*39 A54 N*61 I4947 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.8 H.sub.17 S K3 B14.2 C*48.6 A56.3 I4948 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.9 H.sub.19 S K16 C*49.1 A61 I4949 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.10 H.sub.21 S K41 S<? C*61 I4950 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.11 H.sub.23 S K? B36.7 C*68 I__________________________________________________________________________ TABLE 46__________________________________________________________________________ ##STR85##No L R Cr LC__________________________________________________________________________4951 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.12 H.sub.25 S K40.5 C*70 I4952 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.14 H.sub.29 S K43 B45 C*66 I4953 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.8 H.sub.17 2 K3 C47.5 A58 I4954 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O OC.sub.8 H.sub.17 S K40.7 C*82.8 A89.1 I4955 C.sub.2 H.sub.0CHMeC.sub.5 H.sub.10O COOC.sub.8 H.sub.17 S K76.5 C*79.7 I4956 CH.sub.3CHMeC.sub.6 H.sub.12 C.sub.9 H.sub.19 K29.5 F31 A58.2 I4957 CH.sub.3CHMeC.sub.5 H.sub.12 C.sub.10 H.sub.21 K38.6 F41.3 C51.4 A58.4 I4962 C.sub.2 H.sub.5CHFCOO C.sub.9 H.sub.19 1 K70 S58 I4964 C.sub.2 H.sub.5CHFCOO C.sub.12 H.sub.25 1 K69 A59 I4965 C.sub.4 H.sub.9CHFCOO C.sub.10 H.sub.21 S K46 S30 A49 I4966 C.sub.4 H.sub.9CHFCOO C.sub.12 H.sub.25 S K59 C*45 A52 I4968 C.sub.5 H.sub.11CHFCOO C.sub.12 H.sub.25 S K14 S? A50 I4969 C.sub.6 H.sub.13CHFCOO C.sub.8 H.sub.17 1 K56 A38 I4970 C.sub.6 H.sub.13CHFCOO C.sub.9 H.sub.19 1 K53 A46 I4971 C.sub.6 H.sub.13CHFCOO C.sub.10 H.sub.21 1 K57 S32 C*45 I4972 C.sub.6 H.sub.13CHFCOO C.sub.12 H.sub.25 1 K62 C*52 I4973 C.sub.7 H.sub.15CHFCOO C.sub.10 H.sub.21 S K59 A46 I4974 C.sub.7 H.sub.15CHFCOO C.sub.12 H.sub.25 S K22 S? A61 I4976 C.sub.8 H.sub.17CHFCOO C.sub.9 H.sub.19 1 K64 A46 I4977 C.sub.8 H.sub.17CHFCOO C.sub.10 H.sub.21 1 K59 C*43 A46 N*48 I4978 C.sub.8 H.sub.17CHFCOO C.sub.12 H.sub.25 S K23 S87 I4979 C.sub.4 H.sub.9CHFCH.sub.2O C.sub.10 H.sub.21 S K48 C*43 A66 I4980 C.sub.4 H.sub.9CHFCH.sub.2O C.sub.12 H.sub.25 S K59 S37 S39 C*43 A71 I4981 C.sub.5 H.sub.11CHFCH.sub.2O C.sub.8 H.sub.17 S K24 A35 I4982 C.sub.5 H.sub.11CHFCH.sub.2O C.sub.10 H.sub.21 S K49 C*60 A66 I4983 C.sub.5 H.sub.11CHFCH.sub.2O C.sub.12 H.sub.25 S K60 S49 C*61 A72 I4984 C.sub.6 H.sub.13CHFCH.sub.2O C.sub.8 H.sub.17 S K62 A59 I4985 C.sub.6 H.sub.13CHFCH.sub.2O C.sub.9 H.sub.19 S K63 A67 I4986 C.sub.6 H.sub.13CHFCH.sub.2O C.sub.10 H.sub.21 S K61 S49 C*62 A71 I4987 C.sub.6 H.sub.13CHFCH.sub.2O C.sub.12 H.sub.25 S K56 C*70 A74 I__________________________________________________________________________ TABLE 47__________________________________________________________________________ ##STR86##No L R Cr LC__________________________________________________________________________5039 CF.sub.3O C.sub.3 H.sub.7 K43.1 S48.2 N-17 E5040 CF.sub.3O C.sub.5 H.sub.11 K32 A45.2 N- 65041 CF.sub.3O C.sub.7 H.sub.15 K25 A34 N-20 E5042 C.sub.9 F.sub.19O C.sub.8 H.sub.17 K65.1 A115.1 I5043 C.sub.3 F.sub.7CH.sub.2O C.sub.10 H.sub.21 K36 C52 A64 I5044 C.sub.5 F.sub.11CH.sub.2O C.sub.10 H.sub.21 K47 C73 A84 I5045 C.sub.6 F.sub.13CH.sub.2O C.sub.7 H.sub.15 K? C? A? I5046 C.sub.7 F.sub.15CH.sub.2O C.sub.6 H.sub.13 K50 C56 A133 I5047 C.sub.7 F.sub.15CH.sub.2O C.sub.7 H.sub.15 K54 C67 A125 I5048 C.sub.7 F.sub.15CH.sub.2O C.sub.8 H.sub.17 K71 C80 A117 I5049 C.sub.7 F.sub.15CH.sub.2O C.sub.9 H.sub.19 K71 C85 A112 I5050 C.sub.7 F.sub.15CH.sub.2O C.sub.10 H.sub.21 K75 C87 A104 I5051 C.sub.8 F.sub.17CH.sub.2O C.sub.7 H.sub.15 K? C? A? I5052 C.sub.9 F.sub.19CH.sub.2O C.sub.7 H.sub.15 K? C? A? I5053 C.sub.10 F.sub.21CH.sub.2O C.sub.3 H.sub.7 K? C? A? I5054 C.sub.10 F.sub.21CH.sub.2O C.sub.5 H.sub.11 K? C? A? I5055 C.sub.6 F.sub.13C.sub.3 H.sub.6O C.sub.8 H.sub.17 K63 C95 A132 I5056 C.sub.4 F.sub.9C.sub.4 H.sub.8O C.sub.8 H.sub.17 K66 A114 I5057 C.sub.4 F.sub.9C.sub.4 H.sub.8O C.sub.10 H.sub.21 K58 C80 A106 I5061 HCF.sub.2O C.sub.3 H.sub.7 K41 NO E5062 HCF.sub.2O C.sub.5 H.sub.11 K21 A26 NO E5063 HCF.sub.2O C.sub.7 H.sub.15 K26 A32 NO E5064 HCF.sub.2O C.sub.8 H.sub.17 K26.3 S31.6 N-3 E5065 HC.sub.2 F.sub.4O C.sub.7 H.sub.15 K46 X43 I5066 HCF.sub.2S C.sub.3 H.sub.7 K53.2 N-16 E5067 HCF.sub.2S C.sub.5 H.sub.11 K43.1 N-6 E5068 C.sub.6 H.sub.13CHCF.sub.3OCH.sub.2 C.sub.10 H.sub.21 1 K56.8 S18.4 I5070 C.sub.4 H.sub.9CHCF.sub.3CH.sub.2COO C.sub.10 H.sub.21 1 K28 S1 S7 I5072 H.sub.2 CCHCOOC.sub.6 H.sub.12O C.sub.8 H.sub.17 K50 S52.5 N53 I__________________________________________________________________________ TABLE 48__________________________________________________________________________ ##STR87##No L R Cr LC__________________________________________________________________________5106 CH.sub.3 CHCHCH.sub.2 O C.sub.9 H.sub.19 K59 A65 N75 I5107 C.sub.2 H.sub.5 CHCHCH.sub.2 O C.sub.7 H.sub.15 K31 C30 N62 I5108 C.sub.2 H.sub.5 CHCHCH.sub.2 O C.sub.8 H.sub.17 K53 C49 A55 N61 I5109 C.sub.2 H.sub.5 CHCHCH.sub.2 O C.sub.9 H.sub.19 K56 C42 A68 I5111 C.sub.3 H.sub.7 CHCHCH.sub.2 O C.sub.9 H.sub.17 K43 C51 N66 I5112 C.sub.3 H.sub.7 CHCHCH.sub.2 O C.sub.8 H.sub.19 K49 C63 A70 N72 I5113 C.sub.3 H.sub.7 CHCHCH.sub.2 O C.sub.10 H.sub.21 K30 C53 A65.5 I5114 C.sub.4 H.sub.9 CHCHCH.sub.2 O C.sub.7 H.sub.15 K22 C33 N63 I5115 C.sub.4 H.sub.9 CHCHCH.sub.2 O C.sub.8 H.sub.17 K30 C55 N64 I5116 C.sub.4 H.sub.9 CHCHCH.sub.2 O C.sub.9 H.sub.19 K46 C66 A70 I5117 C.sub.5 H.sub.11 CHCHCH.sub.2 O C.sub.7 H.sub.15 K38 C35 N68 I5118 C.sub.5 H.sub.11 CHCHCH.sub.2 O C.sub.8 H.sub.17 K24 C56 N68 I5119 C.sub.5 H.sub.11 CHCHCH.sub.2 O C.sub.9 H.sub.19 K42 C70 A72 N73 I5120 C.sub.6 H.sub.13 CHCHCH.sub.2 O C.sub.7 H.sub.15 K40 C41 N66 I5121 C.sub.6 H.sub.13 CHCHCH.sub.2 O C.sub.8 H.sub.17 K29 C58 N66 I5122 C.sub.6 H.sub.13 CHCHCH.sub.2 O C.sub.9 H.sub.19 K20 C70 A71 N72 I5123 C.sub.7 H.sub.15 CHCHCH.sub.2 O C.sub.7 H.sub.15 K49 C42 N68 I5124 C.sub.7 H.sub.15 CHCHCH.sub.2 O C.sub.8 H.sub.17 K31 C59 N68 I5125 C.sub.7 H.sub.15 CHCHCH.sub.2 O C.sub.9 H.sub.19 K37 C72 A73 N74 I5126 C.sub.8 H.sub.17 CHCHCH.sub.2 O C.sub.7 H.sub.15 K43 C47 N66 I5127 C.sub.8 H.sub.17 CHCHCH.sub.2 O C.sub.8 H.sub.17 K40 C60 N66 I5128 C.sub.8 H.sub.17 CHCHCH.sub.2 O C.sub.9 H.sub.19 K36 C72 A73 I5129 C.sub.9 H.sub.19 CHCHCH.sub.2 O C.sub.7 H.sub.15 K55 C49 N68 I5130 C.sub.9 H.sub.19 CHCHCH.sub.2 O C.sub.8 H.sub.17 K44 C62 N68 I5131 C.sub.9 H.sub.19 CHCHCH.sub.2 O C.sub.9 H.sub.19 K42 C74 I5132 H.sub.2 CCHC.sub.2 H.sub.4 O C.sub.4 H.sub.9 K37.3 N12.5 U5133 H.sub.2 CCHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K38 A41 N49 I5134 H.sub.2 CCHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K34 A46 I5135 H.sub.2 CCHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K55 A56 I__________________________________________________________________________ TABLE 49__________________________________________________________________________ ##STR88##No L R Cr LC__________________________________________________________________________5139 C.sub.3 H.sub.7 CHCHC.sub.2 H.sub.4 COO C.sub.8 H.sub.17 K54 A45 N50 I5140 C.sub.3 H.sub.7 CHCHC.sub.2 H.sub.4 COO C.sub.9 H.sub.19 K67 A61 I5142 H.sub.2 CCHC.sub.3 H.sub.6 O C.sub.7 H.sub.15 K46 A45 N63 I5143 H.sub.2 CCHC.sub.3 H.sub.6 O C.sub.8 H.sub.17 K38 A54 N58 I5144 H.sub.2 CCHC.sub.3 H.sub.6 O C.sub.9 H.sub.19 K40 A65 I5145 CH.sub.3 CHCHC.sub.3 H.sub.6 O C.sub.9 H.sub.19 K48 C35 A70 N72 I5146 C.sub.3 H.sub.7 CHCHC.sub.3 H.sub.6 O C.sub.7 H.sub.15 K39 C45 N65 I5147 C.sub.3 H.sub.7 CHCHC.sub.3 H.sub.6 O C.sub.8 H.sub.17 K32 C56 A59 N63 I5148 C.sub.3 H.sub.7 CHCHC.sub.3 H.sub.6 O C.sub.9 H.sub.19 K42 C64 A73 I5151 H.sub.2 CCHC.sub.4 H.sub.8 O C.sub.7 H.sub.15 K27 A43 N57 I5152 H.sub.2 CCHC.sub.4 H.sub.8 O C.sub.8 H.sub.17 K44 A51 N55 I5153 H.sub.2 CCHC.sub.4 H.sub.8 O C.sub.9 H.sub.19 K48 A62 I5154 H.sub.2 CCHC.sub.4 H.sub.8 O C.sub.10 H.sub.21 K55.5 C33 A62 I5155 CH.sub.3 CHCHC.sub.4 H.sub.8 COO C.sub.7 H.sub.15 K51 A34 N55 I5156 CH.sub.3 CHCHC.sub.4 H.sub.8 COO C.sub.8 H.sub.17 K48 C39 A46 N52 I5157 CH.sub.3 CHCHC.sub.4 H.sub.8 COO C.sub.9 H.sub.19 K56 C48 A60 I5160 H.sub.2 CCHC.sub.5 H.sub.10 O C.sub.7 H.sub.15 K56 C34 A47 N67 I5161 H.sub.2 CCHC.sub.5 H.sub.10 O C.sub.8 H.sub.17 K37 C30 A58 N64 I5162 H.sub.2 CCHC.sub.5 H.sub.10 O C.sub.9 H.sub.19 K31 A69 I5163 CH.sub.3 CHCHC.sub.5 H.sub.10 O C.sub.7 H.sub.15 K39 C45 A65 I5164 CH.sub.3 CHCHC.sub.5 H.sub.10 O C.sub.8 H.sub.17 K40 C52 A57 N67 I5165 CH.sub.3 CHCHC.sub.5 H.sub.10 O C.sub.9 H.sub.19 K39 C53 A71 N72 I5166 H.sub.2 CCHC.sub.5 H.sub.10 COO C.sub.7 H.sub.15 K43 A36 N46 I5167 H.sub.2 CCHC.sub.5 H.sub.10 COO C.sub.8 H.sub.17 K37 C34 A43 N44 I5168 H.sub.2 CCHC.sub.5 H.sub.10 COO C.sub.9 H.sub.19 K48 C42 A56 I5169 H.sub.2 CCHC.sub.5 H.sub.10 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K35 C*29 N*46 I5170 H.sub.2 CCHC.sub.5 H.sub.10 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K7 C*19 N*39 I__________________________________________________________________________ TABLE 50__________________________________________________________________________ ##STR89##No L R Cr LC__________________________________________________________________________5171 H.sub.2 CCHC.sub.6 H.sub.12 O C.sub.7 H.sub.15 K36 C33 A48 N62 I5172 H.sub.2 CCHC.sub.6 H.sub.12 O C.sub.8 H.sub.17 K19.2 C33.3 A56.1 N60.2 I5173 H.sub.2 CCHC.sub.6 H.sub.12 O C.sub.9 H.sub.19 K37 A67 I5174 H.sub.2 CCHC.sub.6 H.sub.12 O C.sub.10 H.sub.21 K38.2 C49.6 A67.9 I5175 H.sub.2 CCHC.sub.6 H.sub.12 O OC.sub.8 H.sub.17 K48.5 C76.3 A92 N92.6 I5176 H.sub.2 CCHC.sub.6 H.sub.12 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K29 C*28 N*40 I5177 H.sub.2 CCHC.sub.6 H.sub.12 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K4 C*15 N*32 I5178 H.sub.2 CCHC.sub.7 H.sub.14 O C.sub.7 H.sub.15 K52 C43 A54 N67 I5179 H.sub.2 CCHC.sub.7 H.sub.14 O C.sub.8 H.sub.17 K27 C45 A62 N66 I5180 H.sub.2 CCHC.sub.7 H.sub.14 O C.sub.9 H.sub.19 K19 C39 A71 I5181 H.sub.2 CCHC.sub.7 H.sub.14 O C.sub.10 H.sub.21 K32.5 C55 A72 I5182 H.sub.2 CCHC.sub.7 H.sub.14 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K16 C*35 N*48 I5183 H.sub.2 CCHC.sub.7 H.sub.14 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K-1 C*28 N*42 I5184 H.sub.2 CCHC.sub.8 H.sub.16 O C.sub.7 H.sub.15 K43 C42 A55 N64 I5185 H.sub.2 CCHC.sub.8 H.sub.16 O C.sub.8 H.sub.17 K24 C46 A60 N63 I5186 H.sub.2 CCHC.sub.8 H.sub.16 O C.sub.9 H.sub.19 K35 C45 A70 I5187 H.sub.2 CCHC.sub.8 H.sub.16 O C.sub.10 H.sub.21 K33 C57 A70 I5188 H.sub.2 CCHC.sub.8 H.sub.16 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K17 C*34 N*44 I5189 H.sub.2 CCHC.sub.8 H.sub.16 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K12 C*27 N*38 I5191 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.7 H.sub.15 K49 C46 A59 N67 I5192 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.8 H.sub.17 K33.9 C53 A64.4 N66.2 I5193 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.9 H.sub.19 K31.3 C52.8 A71.7 I5194 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.10 H.sub.21 K39.9 C65.2 A72.5 I5195 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.12 H.sub.25 K45.9 C75.5 A76.5 I5196 H.sub.2 CCHC.sub.10 H.sub.20 O C.sub.7 H.sub.15 K50 C45 A60 N65 I5197 H.sub.2 CCHC.sub.10 H.sub.20 O C.sub.8 H.sub.17 K36 C50 A63 N64 I5198 H.sub.2 CCHC.sub.10 H.sub.20 O C.sub.9 H.sub.19 K46 C50 A70 I5199 H.sub.2 CCHC.sub.9 H.sub.18 O OC.sub.8 H.sub.17 K44.1 C78.5 A94.5 I5200 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K20 C*40 N*49 I5201 H.sub.2 CCHC.sub.10 H.sub.20 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K35 C*40 N*47 I__________________________________________________________________________ TABLE 51__________________________________________________________________________ ##STR90##No L R Cr LC__________________________________________________________________________5202 H.sub.2 CCHC.sub.9 H.sub.18 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K17 C*36 N*45 I5203 H.sub.2 CCHC.sub.10 H.sub.20 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K33 C*37 N*43 I5204 C.sub.3 H.sub.7 CH%CHCH.sub.2 O C.sub.9 H.sub.19 K32 A17 I5208 CH.sub.3 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K45 A41 N47 I5209 CH.sub.3 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K34 A45 I5210 CH.sub.3 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K48 C25 A55 I5211 C.sub.2 H.sub.5 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K43 A45 N48 I5212 C.sub.2 H.sub.5 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K42 C32 A47 I5213 C.sub.2 H.sub.5 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K58 C41 A56 I5214 C.sub.3 H.sub.7 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K20 A44 I5215 C.sub.3 H.sub.7 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K33 C35 A46 I5216 C.sub.3 H.sub.7 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K34 C45 A54 I5217 C.sub.4 H.sub.9 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K28 A43 N44 I5218 C.sub.4 H.sub.9 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K25 C34 A46 I5219 C.sub.4 H.sub.9 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K24 C43 A54 I5220 C.sub.5 H.sub.11 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K25 A40 I5221 C.sub.5 H.sub.11 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K12 C30 A42 I5222 C.sub.5 H.sub.11 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K6 C38 A51 I5223 C.sub.6 H.sub.13 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K33 A39 I5224 C.sub.6 H.sub.13 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K22 C25 A41 I5225 C.sub.6 H.sub.13 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K19 C34 A49 I5226 C.sub.7 H.sub.15 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K40 A37 I5227 C.sub.7 H.sub.15 CH%CHC.sub.2 H.sub.4 O C.sub.8 H.sub.17 K30 C20 A39 I5228 C.sub.7 H.sub.15 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K26 C24 A47 I5229 C.sub.8 H.sub.17 CH%CHC.sub.2 H.sub.4 O C.sub.7 H.sub.15 K31 A35 I5230 C.sub.8 H.sub.17 CH%CHC.sub.7 H.sub.4 O C.sub.8 H.sub.17 K32 C14 A41 I5231 C.sub.8 H.sub.17 CH%CHC.sub.2 H.sub.4 O C.sub.9 H.sub.19 K29 C14 A50 I5232 CH.sub.3 CH%CHC.sub.3 H.sub.6 O C.sub.9 H.sub.19 K22 A46 I5233 C.sub.2 H.sub.5 CH%CHC.sub.3 H.sub.6 COO C.sub.7 H.sub.15 K26 A31 I__________________________________________________________________________ TABLE 52__________________________________________________________________________ ##STR91##No L R Cr LC__________________________________________________________________________27740 ClCF.sub.2 O C.sub.4 H.sub.9 K30 S130.6 N135.2 I27749 NC C.sub.7 H.sub.15 K82 A158 N223 I27750 NC OC.sub.2 H.sub.5 K144.5 N232 B27751 NC OC.sub.3 H.sub.7 K114.5 N223.5 B27752 NC OC.sub.5 H.sub.11 K93 N205 B27753 NC CH.sub.2 CHMeC.sub.2 H.sub.5 1 K76 S125 N*178 I27754 NC C.sub.2 H.sub.4 CHMeC.sub.2 H.sub.5 1 K101 S159 N*189.5 I27755 C.sub.2 H.sub.5 C.sub.7 H.sub.15 K68 S179 N182 I27756 C.sub.3 H.sub.7 C.sub.2 H.sub.5 K125.5 S128.5 N167 I27757 C.sub.3 H.sub.7 C.sub.3 H.sub.7 K116.5 S175 N194.5 I27758 C.sub.3 H.sub.7 C.sub.5 H.sub.11 K51 S190 I27759 C.sub.4 H.sub.9 C.sub.2 H.sub.5 K108.5 S140 N163.5 I27760 C.sub.4 H.sub.9 C.sub.5 H.sub.11 K37.5 S187 I27761 C.sub.5 H.sub.11 C.sub.2 H.sub.5 K101 S139 N167 I27762 C.sub.5 H.sub.11 C.sub.3 H.sub.7 K93.5 S179 N190 I27763 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K39.5 S189.2 I27764 C.sub.5 H.sub.11 C.sub.7 H.sub.15 K122.5 S186.5 I27765 C.sub.7 H.sub.15 C.sub.2 H.sub.5 K80 S136.5 N157 I27768 C.sub.6 H.sub.13 CHMeOCH.sub.2 C.sub.7 H.sub.15 1 K36.5 A98.4 I27769 C.sub.2 H.sub.5 CHMeCH.sub.2 O OC.sub.8 H.sub.17 S K64.6 B104.9 A160.5 I27770 C.sub.2 H.sub.5 CHMeCH.sub.2 O OC.sub.5 H.sub.19 S K61.7 B108.2 A156 I27771 C.sub.2 H.sub.5 CHMeC.sub.3 H.sub.6 O OC.sub.8 H.sub.17 S K68 B101 A160.9 I27772 C.sub.2 H.sub.5 CHMeC.sub.3 H.sub.6 O OC.sub.9 H.sub.19 S K63.5 B103 A157.4 I__________________________________________________________________________ TABLE 53__________________________________________________________________________ ##STR92##No L R Cr LC__________________________________________________________________________28508 C.sub.5 H.sub.11 OOCC.sub.10 H.sub.21 K118 C133 N172 I28509 C.sub.5 H.sub.11 OOCC.sub.11 H.sub.23 K120 C138 N169 I28510 C.sub.4 H.sub.9 CHFCOO C.sub.6 H.sub.13 S K34 B98 A137 I28511 C.sub.4 H.sub.9 CHFCOO C.sub.7 H.sub.15 S K53 B101 A143 I28512 C.sub.4 H.sub.9 CHFCOO C.sub.8 H.sub.17 S K41 B109 A143 I28513 C.sub.4 H.sub.9 CHFCOO C.sub.9 H.sub.19 S K49 B113 A145 I28514 C.sub.4 H.sub.9 CHFCOO C.sub.10 H.sub.21 S K48 B116 A145 I28515 C.sub.4 H.sub.9 CHFCOO OC.sub.6 H.sub.13 R K58 C*81 A161 N*165 I28516 C.sub.4 H.sub.9 CHFCOO OC.sub.7 H.sub.15 R K44 B78 C*95 A162 N*163 I28517 C.sub.4 H.sub.9 CHFCOO OC.sub.8 H.sub.17 R K53 B88 C*102 A162 I28518 C.sub.4 H.sub.9 CHFCOO OC.sub.9 H.sub.19 R K60 B92 C*106 A163 I28519 C.sub.4 H.sub.9 CHFCOO OC.sub.10 H.sub.21 R K35 S70 B98 C*108 A165 I28522 C.sub.5 H.sub.11 OCH.sub.2 CHCHC.sub.5 H.sub.11 K97 C115 N176 I28523 C.sub.5 H.sub.11 OCH.sub.2 CHCHC.sub.6 H.sub.13 K94 C125 N170 I28524 C.sub.5 H.sub.11 OCH.sub.2 CHCHC.sub.7 H.sub.15 K86 C135 N167 I28525 C.sub.5 H.sub.11 OCH.sub.2 CHCHC.sub.8 H.sub.17 K93 C140 N163 I28526 C.sub.5 H.sub.11 OC.sub.3 H.sub.6 CHCHC.sub.3 H.sub.7 K87 C93 N184 I28528 C.sub.5 H.sub.11 OC.sub.5 H.sub.10 CHCH.sub.2 K55 C65 A112 N185 I28529 C.sub.5 H.sub.11 OC.sub.5 H.sub.10 CHCHCH.sub.3 K81 C111 A130 N185 I28530 C.sub.5 H.sub.11 OC.sub.6 H.sub.12 CHCH.sub.2 K67 C96 A121 N176 I28531 C.sub.5 H.sub.11 OC.sub.7 H.sub.14 CHCH.sub.2 K59 C91 A142 N176 I28532 C.sub.5 H.sub.11 OC.sub.8 H.sub.16 CHCH.sub.2 K55 C103 A145 N169 I28533 C.sub.5 H.sub.11 OC.sub.9 H.sub.18 CHCH.sub.2 K57 C97 A151 N168 I28535 C.sub.5 H.sub.11 OC.sub.4 H.sub.8 CH%CHC.sub.2 H.sub.5 K86 C85 N168 I28536 C.sub.5 H.sub.11 OC.sub.4 H.sub.8 CH/CH.sub.2 .backslash.CH.sub.2 K81 S75 N180 I28537 C.sub.3 H.sub.7 OC.sub.6 H.sub.12 CH/CH.sub.2 .backslash.CH.sub.2 K80 S70 C84 N174 I__________________________________________________________________________ TABLE 54______________________________________ ##STR93##No L R Cr LC______________________________________28896 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K33.4 S121.2 I______________________________________ ##STR94##No L R Cr LC______________________________________28548 C.sub.8 H.sub.17O C.sub.6 H.sub.17 K51 C63 A113 N121 I______________________________________ ##STR95##No L R Cr LC______________________________________33521 C.sub.5 H.sub.11 C.sub.6 H.sub.13 K72 S65 N104 I33522 C.sub.5 H.sub.11 C.sub.7 H.sub.15 K76 S86 N109 I33523 C.sub.5 H.sub.11 C.sub.9 H.sub.19 K52 S107 N113 I33524 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K61 S76 N100.8 I33525 C.sub.6 H.sub.13 C.sub.7 H.sub.15 K48 S92 N107 I33526 C.sub.6 H.sub.13 C.sub.9 H.sub.19 K66 S109 N110 I33527 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K73 F66 C103.5 I______________________________________ TABLE 55__________________________________________________________________________ ##STR96##No L R Cr LC__________________________________________________________________________33600 C.sub.4 H.sub.9 OCHMeCOO C.sub.8 H.sub.17 S K44 C*60 N*96 I33601 C.sub.4 H.sub.9 OCHMeCOO OC.sub.8 H.sub.17 S K68 C*103 N*138 I33603 C.sub.6 H.sub.13 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K56 C*54 N*152 I33604 C.sub.7 H.sub.15 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K64 C*65 N*148 I33605 C.sub.8 H.sub.17 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K71 C*70 N*142 I33606 C.sub.9 H.sub.19 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K78 C*77 N*142 I33607 C.sub.10 H.sub.21 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K74 C*82 N*141 I33608 C.sub.11 H.sub.23 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K78 C*85 N*136 I33609 C.sub.12 H.sub.25 O C.sub.4 H.sub.8 CHMeC.sub.2 H.sub.5 S K83 C*88 N*133 I33610 C.sub.6 H.sub.13 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K72 C*50 N*148 I33611 C.sub.7 H.sub.15 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K56 C*64 N*144 I33612 C.sub.8 H.sub.17 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K56 C*72 N*142 I33613 C.sub.9 H.sub.19 O C.sub.8 H.sub.10 CHMeC.sub.2 H.sub.5 S K68 C*80 N*138 I33614 C.sub.10 H.sub.21 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K86 C*84 N*137 I33615 C.sub.11 H.sub.23 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K83 C*90 N*132 I33616 C.sub.12 H.sub.25 O C.sub.5 H.sub.10 CHMeC.sub.2 H.sub.5 S K69 C*94 N*132 I33618 C.sub.6 H.sub.13 CHMeO OC.sub.8 H.sub.17 1 K72 C*48 N*115 I33620 CH.sub.3 CHMeCHClCOO C.sub.7 H.sub.15 S K70 C*96 N*202 I33621 CH.sub.3 CHMeCHClCOO C.sub.9 H.sub.19 S K62 C*69 N*157 I33622 C.sub.2 H.sub.5 CHMeCHClCOO C.sub.8 H.sub.17 3 K? C*77 N*124 I__________________________________________________________________________ TABLE 56__________________________________________________________________________ ##STR97##No L R Cr LC__________________________________________________________________________36376 C.sub.4 H.sub.9 OC.sub.9 H.sub.19 2 K66 S190 I__________________________________________________________________________ ##STR98##No L R Cr LC__________________________________________________________________________37030 C.sub.2 H.sub.5 CN K137 S136 N243 I37031 C.sub.5 H.sub.11 CN K117 S192 N248 I37033 CH.sub.3 C.sub.10 H.sub.21 K76 C77 N124 I37035 C.sub.2 H.sub.5 C.sub.10 H.sub.21 K82 C82 N142 I37038 C.sub.3 H.sub.7 C.sub.10 H.sub.21 K76 C89 N161 I37039 C.sub.3 H.sub.7 C.sub.12 H.sub.25 K64.9 S76.3 C108.1 N152.8 I37041 C.sub.4 H.sub.9 C.sub.10 H.sub.21 K40 B82 C99 N160 I37042 C.sub.4 H.sub.9 C.sub.12 H.sub.25 K80 S82 S83.8 C115.3 N152.7 I37046 C.sub.5 H.sub.11 C.sub.10 H.sub.21 K64 B85 C104 N161 I37047 C.sub.5 H.sub.11 C.sub.11 H.sub.23 K70 S80 S82.7 C114.5 N160.5 I37048 C.sub.5 H.sub.11 C.sub.12 H.sub.25 K67 S83 S87.2 C121.5 N156 I37051 C.sub.7 H.sub.15 C.sub.10 H.sub.21 K78 B89 C116 N158 I37052 C.sub.9 H.sub.19 C.sub.10 H.sub.21 K77 S85 C123 N153 I37053 C.sub.10 H.sub.21 C.sub.10 H.sub.21 K77 S87 C125 N150 I37054 C.sub.5 H.sub.11 OC.sub.8 H.sub.17 K72.1 S68 S74 C100 N193 I37055 C.sub.5 H.sub.11 OC.sub.9 H.sub.19 K74.3 G69 C117.7 N189 I37056 C.sub.5 H.sub.11 OC.sub.10 H.sub.21 K74.7 G72.5 C129.8 N186.5 I37058 H.sub.2 CCHC.sub.2 H.sub.4 C.sub.10 H.sub.21 K71 C92 N162 I37059 CH.sub.3 CHCHC.sub.2 H.sub.4 C.sub.10 H.sub.21 K52 S56 S64 S69 C92 N170 I__________________________________________________________________________ TABLE 57__________________________________________________________________________ ##STR99##No L R Cr LC__________________________________________________________________________37078 (Me).sub.2 CCHC.sub.2 H.sub.4 C.sub.10 H.sub.21 2 K40 C83 N106 I37079 (Me).sub.2 CCHC.sub.2 H.sub.4 OC.sub.10 H.sub.21 2 K82 C112 N138 I37080 CH.sub.3 C.sub.10 H.sub.21 2 K50 S54 C68 N107 I__________________________________________________________________________ ##STR100##No L R Cr LC__________________________________________________________________________37109 H C.sub.6 H.sub.13 K44 N53 W37110 H C.sub.8 H.sub.17 K41.3 C51 A57.6 N60.2 W37111 H C.sub.9 H.sub.19 K52.8 C56.8 A67.2 W37112 H C.sub.10 H.sub.21 K44 C64.9 A67.7 W37113 H C.sub.11 H.sub.23 K48 C70.2 A71.6 W37114 H C.sub.12 H.sub.25 K52 C72.3 W37115 H OC.sub.7 H.sub.15 K56.4 C71.3 A83.4 N85.1 W37116 H OC.sub.8 H.sub.17 K69.2 C75.8 A90.2 W37117 H OC.sub.11 H.sub.23 K68 C95 W37118 C.sub.2 H.sub.5 OOC C.sub.8 H.sub.17 1 K38 C*36 I__________________________________________________________________________ TABLE 58__________________________________________________________________________ ##STR101##No L R Cr LC__________________________________________________________________________9165 C.sub.2 H.sub.5 CHMeCH.sub.2 OOC OC.sub.11 H.sub.22 OH S K80 C*58.9 A72.8 I9179 C.sub.5 H.sub.11 Cl K69 N37 E9182 C.sub.10 H.sub.21 O Cl K85.5 C86.5 I9200 CH.sub.3 CN K160 N65 E9201 C.sub.2 H.sub.5 CN K110 N62 E9209 C.sub.10 H.sub.21 CN K64.4 A47.9 N62.1 B9210 C.sub.11 H.sub.23 CN K64 A61.4 N66.7 I9211 C.sub.12 H.sub.25 CN K72 A64.7 N66 I9221 C.sub.14 H.sub.29 O CN K96 A91 I9226 C.sub.7 H.sub.15 OC.sub.3 H.sub.6 CN K85.5 A70 N77 I__________________________________________________________________________ ##STR102##No L R Cr LC__________________________________________________________________________9227 C.sub.7 H.sub.15 O OC.sub.3 H.sub.6 CN K105.5 N102.5 U9228 C.sub.5 H.sub.11 OC.sub.5 H.sub.10 CN K63.4 A53 N70 I9230 C.sub.2 H.sub.5 CHMeC.sub.2 H.sub.4 CN S K81 N*23.5 B9237 H.sub.2 CCHCH.sub.2 O CN K115.2 N104.1 I9243 CH.sub.3 NMe NO.sub.2 K217 X220 Z9256 C.sub.4 H.sub.9 C.sub.7 H.sub.15 K6.2 S-2.5 N17.5 I9257 C.sub.4 H.sub.9 C.sub.8 H.sub.17 K14.2 S10.3 N16.5 I9258 C.sub.4 H.sub.9 C.sub.9 H.sub.19 K30 S20.5 N27 I9259 C.sub.5 H.sub.11 C.sub.6 H.sub.13 K31.2 S21 I9260 C.sub.5 H.sub.11 C.sub.7 H.sub.15 K27.3 S17.5 N39.1 I9261 C.sub.5 H.sub.11 C.sub.8 H.sub.17 K8.6 S30.5 N33.7 I9262 C.sub.5 H.sub.11 C.sub.9 H.sub.19 K28 S37 N44.9 I9263 C.sub.6 H.sub.13 C.sub.7 H.sub.15 K19.3 S20 N30 I9264 C.sub.6 H.sub.13 C.sub.8 H.sub.17 K22.2 S27.8 I9265 C.sub.6 H.sub.13 C.sub.9 H.sub.19 K23.7 S31.7 I9266 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K41.6 S35.2 N40.8 I9267 C.sub.7 H.sub.15 C.sub.9 H.sub.19 K20 S43.8 I9271 CH.sub.3 OCH.sub.3 K124.8 N32.1 E__________________________________________________________________________ TABLE 59__________________________________________________________________________ ##STR103##No L R Cr LC__________________________________________________________________________5352 C.sub.12 H.sub.25 CN K87 A81 I5353 C.sub.13 H.sub.27 CN K87 S80 B5355 C.sub.8 H.sub.17 O CN K84 A112 I5356 C.sub.10 H.sub.21 O CN K70 A111 I5357 C.sub.12 H.sub.25 O CN K85 A111 I5358 C.sub.12 H.sub.25 OC.sub.4 H.sub.9 K48 S43 I5360 CH.sub.3 O C.sub.8 H.sub.17 K68 A63 I5361 CH.sub.3 O C.sub.12 H.sub.25 K90 A83 I5362 C.sub.8 H.sub.17 O C.sub.8 H.sub.17 K65 C64 A79 I5367 C.sub.12 H.sub.25 O OCH.sub.2 CHMeC.sub.2 H.sub.5 S K63 A45 I5369 C.sub.8 H.sub.17 O COOCH.sub.2 CHMeC.sub.2 H.sub.5 S K41 S52 A60 I5370 C.sub.12 H.sub.25 O COOCH.sub.2 CHMeC.sub.2 H.sub.5 S K42 A60 I5371 C.sub.8 H.sub.17 O OC.sub.3 H.sub.6 CHMeC.sub.2 H.sub.5 S K42 C*61 A66 I5372 C.sub.12 H.sub.25 O OC.sub.3 H.sub.6 CHMeC.sub.2 H.sub.5 S K50 C*63 A72 I5374 C.sub.2 H.sub.5 CHMeCH.sub.2 O OC.sub.12 H.sub.25 S K56 A46 I5376 C.sub.2 H.sub.5 CHMeCH.sub.2 OOC OC.sub.12 H.sub.25 S K58 C*45 A49 I5377 C.sub.2 H.sub.5 CHMeC.sub.3 H.sub.6 OOC OC.sub.12 H.sub.25 1 K? A<? I5378 C.sub.3 H.sub.7 CHMeC.sub.4 H.sub.8 O C.sub.8 H.sub.17 2 K48 C56.5 I5379 C.sub.2 H.sub.5 CHMeC.sub.5 H.sub.10 O C.sub.8 H.sub.17 2 K49 C62 I__________________________________________________________________________ ##STR104##No L R Cr LC__________________________________________________________________________5381 C.sub.5 H.sub.11 CHCHCH.sub.2 O C.sub.8 H.sub.17 K48 C77 I__________________________________________________________________________ TABLE 60__________________________________________________________________________ ##STR105##No L R Cr LC__________________________________________________________________________5352 C.sub.12 H.sub.25 CN K87 A81 I5353 C.sub.13 H.sub.27 CN K87 S80 B5355 C.sub.8 H.sub.17 O CN K84 A112 I5356 C.sub.10 H.sub.21 O CN K70 A111 I5357 C.sub.12 H.sub.25 O CN K85 A111 I5358 C.sub.12 H.sub.25 OC.sub.4 H.sub.9 K48 S43 I5360 CH.sub.3 O C.sub.8 H.sub.17 K68 A63 I5361 CH.sub.3 O C.sub.12 H.sub.25 K90 A83 I5362 C.sub.8 H.sub.17 O C.sub.8 H.sub.17 K65 C64 A79 I5367 C.sub.12 H.sub.25 O OCH.sub.2 CHMeC.sub.2 H.sub.5 S K63 A45 I5369 C.sub.8 H.sub.17 O COOCH.sub.2 CHMeC.sub.2 H.sub.5 S K41 S52 A60 I5370 C.sub.12 H.sub.25 O COOCH.sub.2 CHMeC.sub.2 H.sub.5 S K42 A60 I5371 C.sub.8 H.sub.17 O OC.sub.3 H.sub.6 CHMeC.sub.2 H.sub.5 S K42 C*61 A66 I5372 C.sub.12 H.sub.25 O OC.sub.3 H.sub.6 CHMeC.sub.2 H.sub.5 S K50 C*63 A72 I5374 C.sub.2 H.sub.5 CHMeCH.sub.2 O OC.sub.12 H.sub.25 S K56 A46 I5376 C.sub.2 H.sub.5 CHMeCH.sub.2 OOC OC.sub.12 H.sub.25 S K58 C*45 A49 I5377 C.sub.2 H.sub.5 CHMeC.sub.3 H.sub.6 OOC OC.sub.12 H.sub.25 1 K? A<? I5378 C.sub.3 H.sub.7 CHMeC.sub.4 H.sub.8 O C.sub.8 H.sub.17 2 K48 C56.5 I5379 C.sub.2 H.sub.5 CHMeC.sub.5 H.sub.10 O C.sub.5 H.sub.17 2 K49 C62 I__________________________________________________________________________ TABLE 61__________________________________________________________________________ ##STR106##No L R Cr LC__________________________________________________________________________25427 CH.sub.3 CN K196 A221 N296 I25428 C.sub.2 H.sub.5 CN K190 A197 N278 I25429 C.sub.3 H.sub.7 CN K169 A179 N277 I25430 C.sub.4 H.sub.9 CN K129 A139 N256 I25431 C.sub.5 H.sub.11 CN K131 A140 N263 I25432 C.sub.6 H.sub.13 CN K107 A125 N225 U25433 C.sub.7 H.sub.15 CN K110 A132 N242 I25434 C.sub.8 H.sub.17 CN K125 A133 N240 I25435 C.sub.9 H.sub.19 CN K105 A107 N232 I25436 C.sub.12 H.sub.25 CN K109 C119 A227 I25437 C.sub.16 H.sub.33 CN K106 C119 A221 I25438 CH.sub.3 O CN K182 S169 N321 I25439 C.sub.7 H.sub.15O CN K97 X267 I25440 C.sub.8 H.sub.17 O CN K96 X270 I25441 C.sub.9 H.sub.19 O CN K102 X263 I25442 C.sub.10 H.sub.21 O CN K104 X252 I25443 C.sub.11 H.sub.23 O CN K109 X263 I25444 C.sub.12 H.sub.25 O CN K105 X252 I25445 C.sub.13 H.sub.27 O CN K103 X246 I25450 C.sub.4 H.sub.9 C.sub.4 H.sub.9 K161.3 C166.4 N181.9 I25451 C.sub.5 H.sub.11 C.sub.5 H.sub.11 K134.3 C173.6 A182.2 N191.3 I25452 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K116.1 C172.3 A179.2 I__________________________________________________________________________ TABLE 62__________________________________________________________________________ ##STR107##No L R Cr LC__________________________________________________________________________25453 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K109.6 C175 A187 I25454 C.sub.8 H.sub.17 C.sub.8 H.sub.17 K104.6 C178 A187 I25455 C.sub.9 H.sub.19 C.sub.9 H.sub.19 K108.8 C177 I25456 C.sub.10 H.sub.21 C.sub.10 H.sub.21 K112 S106 C170.5 I25458 C.sub.2 H.sub.5 OCH.sub.3 K162 A163 N229 I25460 C.sub.4 H.sub.9 OCH.sub.3 K138 A139 N230 I25462 C.sub.6 H.sub.13 OCH.sub.3 K137 A138 N206 U25464 C.sub.8 H.sub.17 OCH.sub.3 K135 A136 N225 U25466 C.sub.12 H.sub.25 OCH.sub.3 K131 A169 N180 I25467 C.sub.16 H.sub.33 OCH.sub.3 K127 A175 I25469 C.sub.5 H.sub.11 OOCC.sub.3 H.sub.7 K158 S200 N219 I25473 C.sub.4 H.sub.9 O OC.sub.4 H.sub.9 K170.3 C218 N246 I25474 C.sub.5 H.sub.11 O OC.sub.5 H.sub.11 K153.4 C211 N224 I25475 C.sub.6 H.sub.13 O OC.sub.6 H.sub.13 K135.7 B139.6 C212 N220 I25476 C.sub.7 H.sub.15 O OC.sub.7 H.sub.15 K126 B128.5 C211 N212 I25477 C.sub.8 H.sub.17 O OC.sub.8 H.sub.17 K118.8 B121.1 C209 I25478 C.sub.9 H.sub.19 O OC.sub.9 H.sub.19 K118.7 C204 I25479 C.sub.10 H.sub.21 O OC.sub.10 H.sub.21 K113 C201 I25481 C.sub.8 H.sub.17 O COOCHMeC.sub.2 H.sub.5 1 K11 C*161 A184 I25482 C.sub.10 H.sub.21 O COOCHMeC.sub.6 H.sub.13 1 K138 C*139 A162 I__________________________________________________________________________ TABLE 63__________________________________________________________________________ ##STR108##No L R Cr LC__________________________________________________________________________25483 C.sub.12 H.sub.25 OCH.sub.2CHMeC.sub.2 H.sub.5 S K67 S100 C*155 A157 I25484 C.sub.10 H.sub.21 COOCH.sub.2CHMeC.sub.2 H.sub.5 S K85 C*120 A166 I25485 C.sub.12 H.sub.25 COOCH.sub.2CHMeC.sub.2 H.sub.5 S K95 C*130 A162 I25486 C.sub.16 H.sub.33 COOCH.sub.2CHMeC.sub.2 H.sub.5 S K95 C*100 A165 I25487 C.sub.7 H.sub.15O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K126 C*175 A200 I25488 C.sub.8 H.sub.17O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K109 C*131 A182 I25489 C.sub.9 H.sub.19O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K113 C*171 A199 I25490 C.sub.10 H.sub.21O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K98 C*168 A187 I25491 C.sub.11 H.sub.23O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K90 C*160 A193 I25492 C.sub.12 H.sub.25O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K110 C*166 A186 I25493 C.sub.13 H.sub.27O COOCH.sub.2CHMeC.sub.2 H.sub.5 S K100 C*160 A185 I25494 C.sub.10 H.sub.21O COOC.sub.3 H.sub.6CHMeC.sub.2 H.sub.5 S K68 C*168 A199 I__________________________________________________________________________ ##STR109##No L R Cr LC__________________________________________________________________________26944 F OC.sub.4 H.sub.9 K118.7 A202.3 I26945 F OC.sub.5 H.sub.11 K120 A204 I26946 F OC.sub.6 H.sub.13 K110.5 A195.5 I26947 F OC.sub.7 H.sub.15 K117.1 A191.1 I26948 F OC.sub.8 H.sub.17 K115.6 A188 I26949 F OC.sub.9 H.sub.19 K116.2 A179.4 I26950 F OC.sub.10 H.sub.21 K117.1 A178.6 I26951 F OC.sub.12 H.sub.25 K121.3 A170.5 I26952 C.sub.3 H.sub.7 OC.sub.4 H.sub.9 K91.7 E149.2 B161 A198.7 N201.3 I26953 C.sub.3 H.sub.7 OC.sub.5 H.sub.11 K92.4 E143 B156 A191.2 N192.5 I26954 C.sub.3 H.sub.7 OC.sub.6 H.sub.13 K92.6 E135.9 B149.8 A191.4 N192.1 I26955 C.sub.3 H.sub.7 OC.sub.7 H.sub.15 K77.3 E132.7 B147.8 A187.9 I26956 C.sub.3 H.sub.7 OC.sub.8 H.sub.17 K86.8 E130.5 B149.9 A198.5 U26957 C.sub.3 H.sub.7 OC.sub.9 H.sub.19 K91.8 E120.7 B138.3 N180.5 I26958 C.sub.3 H.sub.7 OC.sub.10 H.sub.21 K93.2 E118 B135 N181 I26959 C.sub.3 H.sub.7 OC.sub.12 H.sub.25 K105.4 E108 B128.4 N171.7 I__________________________________________________________________________ TABLE 64______________________________________ ##STR110##No L R Cr LC______________________________________5543 C.sub.4 H.sub.9 C.sub.6 H.sub.13 K57.5 A56.5 I5544 C.sub.6 H.sub.13 C.sub.4 H.sub.9 K45 A61.5 I5545 C.sub.6 H.sub.13 C.sub.5 H.sub.11 K31 A68 I5546 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K44 A68 I5547 C.sub.6 H.sub.13 C.sub.7 H.sub.15 K43 A69.5 I5548 C.sub.7 H.sub.15 C.sub.7 H.sub.15 K41 A72 I5549 C.sub.8 H.sub.17 C.sub.4 H.sub.9 K36.5 A64.5 I5550 C.sub.8 H.sub.17 C.sub.5 H.sub.11 K37 B46 A71 I5551 C.sub.8 H.sub.17 C.sub.6 H.sub.13 K44 B49 A72 I5552 C.sub.8 H.sub.17 C.sub.7 H.sub.15 K50 B51.5 A73.5 I5553 C.sub.9 H.sub.19 C.sub.4 H.sub.9 K37 A63.5 I5554 C.sub.9 H.sub.19 C.sub.5 H.sub.11 K42 A78 I5555 C.sub.9 H.sub.19 C.sub.6 H.sub.13 K34 A73 I5556 C.sub.9 H.sub.19 C.sub.7 H.sub.15 K44 A73 I5560 C.sub.5 H.sub.11O C.sub.4 H.sub.9 K55 A101 I5561 C.sub.5 H.sub.11O C.sub.6 H.sub.13 K58 A103 I5562 C.sub.6 H.sub.13O CH.sub.3 K99 A101 I5563 C.sub.6 H.sub.13O C.sub.4 H.sub.9 K57 A100 I5564 C.sub.6 H.sub.13O C.sub.6 H.sub.13 K55 A103 I______________________________________ TABLE 65__________________________________________________________________________ ##STR111##No L R Cr LC__________________________________________________________________________5567 C.sub.2 H.sub.5CHMeCH.sub.2O C.sub.8 H.sub.17 S K57.8 A53.9 I5568 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.4 H.sub.9 S K42.5 C*66.2 A77.3 I5569 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.5 H.sub.11 S K50.5 C*76.5 A82 I5570 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.6 H.sub.13 S K49 C*75.1 A80.1 I5571 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.7 H.sub.15 S K55 C*77.1 A82 I5572 C.sub.2 H.sub.5CHMeC.sub.3 H.sub.6O C.sub.8 H.sub.17 S K48 C*72.1 A76.9 I5573 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.6 H.sub.13 S K34.5 C*70.7 A78.1 I5574 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8O C.sub.8 H.sub.17 S K52.5 C*70 A73 I5575 C.sub.2 H.sub.5CHMeC.sub.4 H.sub.8COO C.sub.8 H.sub.17 S K68 C*79.6 A80.8 I5576 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.2 H.sub.5 S K33 A85.4 I5577 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.3 H.sub.7 S K34.5 A93.4 I5578 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.4 H.sub.9 S K29.8 C*57.1 A85 I5579 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.5 H.sub.11 S K44 C*76.5 A89.5 I5580 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.6 H.sub.13 S K37 C*79.3 A85.7 I5581 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.7 H.sub.15 S K50.5 C*86.9 A88.8 I5582 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.8 H.sub.19 S K44.5 C*81.2 A84.6 I5583 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.9 H.sub.19 S K59.5 C*86 I5584 C.sub.2 H.sub.5CHMeC.sub.5 H.sub.10O C.sub.10 H.sub.21 S K51.5 C*81.2 I__________________________________________________________________________ TABLE 66__________________________________________________________________________ ##STR112##No L R Cr LC__________________________________________________________________________5654 C.sub.5 H.sub.11O C.sub.6 H.sub.13 K65 C58.5 I5655 C.sub.5 H.sub.11O C.sub.7 H.sub.15 K49 C52.5 N63 I5656 C.sub.6 H.sub.13O C.sub.5 H.sub.11 K55 A68 I5657 C.sub.6 H.sub.13O C.sub.7 H.sub.15 K58 C67 A74 N76 I5658 C.sub.4 H.sub.9O OC.sub.4 H.sub.9 K75.5 S57.5 N74 I5659 C.sub.4 H.sub.9O OC.sub.6 H.sub.13 K70 S68.5 N80 I5660 C.sub.5 H.sub.11O OC.sub.4 H.sub.9 K53.5 S61 N71 I5661 C.sub.5 H.sub.11O OC.sub.6 H.sub.13 K55.5 S70 S72.5 N82 I5676 C.sub.7 H.sub.15COO C.sub.6 H.sub.13 K56 C50.5 A65 I__________________________________________________________________________ ##STR113##No L R Cr LC__________________________________________________________________________7081 O.sub.2 N OOCC.sub.10 H.sub.20Si.sub.4 O.sub.4 Me.sub.7 -cy K? A50 I7083 F C.sub.2 H.sub.5 K<20 N-36.2 I7084 F C.sub.3 H.sub.7 K<20 N-14.6 I7089 NC C.sub.6 H.sub.13 K29.7 N14.5 I7097 C.sub.4 H.sub.9 C.sub.6 H.sub.13 K20 B44 I7098 C.sub.4 H.sub.9O C.sub.6 H.sub.13 K40 B78 I7099 CH.sub.3OOC C.sub.5 H.sub.11 K86.5 A90.5 I7100 C.sub.3 H.sub.7OOC C.sub.5 H.sub.11 K37.8 A68 I7101 C.sub.4 H.sub.9OOC C.sub.5 H.sub.11 K42 A57.8 I7102 C.sub.5 H.sub.11OOC C.sub.5 H.sub.11 K45.5 A59 I__________________________________________________________________________ TABLE 67______________________________________ ##STR114##No L R Cr LC______________________________________7260 C.sub.5 H.sub.11 OC.sub.8 H.sub.17 K72 A114 I7261 C.sub.4 H.sub.9O C.sub.4 H.sub.9 K79 C96 N108 I7262 C.sub.5 H.sub.11O C.sub.4 H.sub.9 K86 C101 N106.5 I7264 C.sub.4 H.sub.9O OC.sub.4 H.sub.9 K104 C112 N142 N150 I7265 C.sub.4 H.sub.9O OC.sub.8 H.sub.17 K92 C95 A140 N142.5 I7266 C.sub.9 H.sub.19O OCH.sub.3 K99 A116 N127 I7267 C.sub.9 H.sub.19O OC.sub.8 H.sub.17 K74.5 C135.5 A144 I7268 C.sub.4 H.sub.9S OC.sub.8 H.sub.17 K71.8 A119 I______________________________________ TABLE 68______________________________________ ##STR115##No L R Cr LC______________________________________7276 C.sub.2 H.sub.5O CN K150 S144 N189 I7277 C.sub.8 H.sub.17 C.sub.6 H.sub.13 K68 C106 N116 I7281 C.sub.5 H.sub.11 OC.sub.4 H.sub.9 K77 S76 N118 I7285 C.sub.5 H.sub.11O C.sub.5 H.sub.11 K73 C77 N118 I7286 C.sub.5 H.sub.11O C.sub.6 H.sub.13 K73 C88 N114 I7287 C.sub.5 H.sub.11O C.sub.7 H.sub.15 K71 C96 A98 N118 I7288 C.sub.5 H.sub.11O C.sub.8 H.sub.17 K73 C92 A105 N112 I7289 C.sub.6 H.sub.13O C.sub.5 H.sub.11 K68 C93 N125 I7290 C.sub.6 H.sub.13O C.sub.6 H.sub.13 K66 C98 N117 I7291 C.sub.6 H.sub.13O C.sub.7 H.sub.15 K65 C104 A106 N121 I7292 C.sub.6 H.sub.13O C.sub.8 H.sub.17 K69 C104 A113 N117 I7293 C.sub.7 H.sub.15O C.sub.5 H.sub.11 K73 C98 N121 I7294 C.sub.7 H.sub.15O C.sub.6 H.sub.13 K70 C105 N116 I7295 C.sub.7 H.sub.15O C.sub.7 H.sub.15 K70 C109 A113 N120 I7296 C.sub.7 H.sub.15O C.sub.8 H.sub.17 K71 C109 A115 N116 I7297 C.sub.8 H.sub.17O C.sub.5 H.sub.11 K72 C104 N120 I7298 C.sub.8 H.sub.17O C.sub.6 H.sub.13 K68 C106 N116 I7299 C.sub.8 H.sub.17O C.sub.7 H.sub.15 K70 C109 A117 N120 I______________________________________ ##STR116##No L R Cr LC______________________________________7260 C.sub.5 H.sub.11 OC.sub.8 H.sub.17 K72 A114 I7261 C.sub.4 H.sub.9O C.sub.4 H.sub.9 K79 C96 N108 I7262 C.sub.5 H.sub.11O C.sub.4 H.sub.9 K86 C101 N106.5 I7264 C.sub.4 H.sub.9O OC.sub.4 H.sub.9 K104 C112 A142 N150 I7265 C.sub.4 H.sub.9O OC.sub.8 H.sub.17 K92 C95 A140 N142.5 I7266 C.sub.9 H.sub.19O OCH.sub.3 K99 A116 N127 I7267 C.sub.9 H.sub.19O OC.sub.8 H.sub.17 K74.5 C135.5 A144 I7268 C.sub.4 H.sub.9S OC.sub.8 H.sub.17 K71.8 A119 I______________________________________ TABLE 69__________________________________________________________________________ ##STR117##No L R Cr LC__________________________________________________________________________7300 C.sub.8 H.sub.17O C.sub.8 H.sub.17 K69 C113 A118 I7301 C.sub.9 H.sub.19O C.sub.5 H.sub.11 K76 C107 A109 N118 I7302 C.sub.9 H.sub.19O C.sub.6 H.sub.13 K76 C111 A113 N116 I7303 C.sub.9 H.sub.19O C.sub.7 H.sub.15 K76 C113 A119 I7304 C.sub.9 H.sub.19O C.sub.8 H.sub.17 K75 C114 A117 I7305 C.sub.10 H.sub.21O C.sub.5 H.sub.11 K77 C107 A113 N118 I7306 C.sub.10 H.sub.21O C.sub.6 H.sub.13 K75 C110 A114 N116 I7307 C.sub.10 H.sub.21O C.sub.7 H.sub.15 K74 C114 A119 I7308 C.sub.10 H.sub.21() C.sub.8 H.sub.17 K68 C114 A116 I7309 C.sub.11 H.sub.23O C.sub.5 H.sub.11 K83 C105 A114 N116 I7310 C.sub.11 H.sub.23O C.sub.6 H.sub.13 K82 C110 A115 I7311 C.sub.11 H.sub.23O C.sub.7 H.sub.15 K81 C113 A118 I7312 C.sub.11 H.sub.23O C.sub.8 H.sub.17 K80 C115 A117 I7313 C.sub.12 H.sub.25O C.sub.5 H.sub.11 K83 C104 A114 N116 I7314 C.sub.12 H.sub.25O C.sub.6 H.sub.13 K103 C108 A113 I7315 C.sub.12 H.sub.25O C.sub.7 H.sub.15 K79 C112 A118 I7316 C.sub.12 H.sub.25O C.sub.8 H.sub.17 K79 C113 A115 I7317 C.sub.5 H.sub.11CFMeCOO C.sub.8 H.sub.17 1 K65.3 S63.5 I__________________________________________________________________________ TABLE 70__________________________________________________________________________ ##STR118##No L R Cr LC__________________________________________________________________________27333 CH.sub.3 H K153 A151.5 N163.5 I27334 C.sub.2 H.sub.5 H K142 A164 I27335 C.sub.3 H.sub.7 H K125 A175.5 I27336 C.sub.4 H.sub.9 H K120.5 A170 I27337 C.sub.5 H.sub.11 H K113 A175 I27338 C.sub.6 H.sub.13 H K99.5 A176 I27339 C.sub.7 H.sub.15 H K86 E88 A170 I27340 C.sub.8 H.sub.17 H K60 E82 A176 I27341 C.sub.9 H.sub.19 H K61 S82 A173 I27342 C.sub.10 H.sub.21 H K53 E83 A171 I27343 CH.sub.3O H K169 A163 N203 I27344 C.sub.2 H.sub.5O H K175 A202 N216 I27345 C.sub.3 H.sub.7O H K157 A204 I27346 C.sub.5 H.sub.11O H K145 E130 A206 I27347 C.sub.8 H.sub.17O H K96 E115 A195 I27348 C.sub.10 H.sub.21O H K98 E120 A194 I27349 C.sub.16 H.sub.33O H K109 E106 A182.5 I27351 C.sub.5 H.sub.11 -Oxazolldinyl-N-oxy-C.sub.4 H.sub.8O H 2 K118 C101 A108 I27352 C.sub.8 H.sub.17 -Oxazolldinyl-N-oxy-C.sub.7 H.sub.14O H 2 K79 E99 C119 A134 I27353 CH.sub.3 -Oxazolldinyl-N-oxy-C.sub.8 H.sub.16O H 2 K113 C123 A158.5 I__________________________________________________________________________ ##STR119##No L R Cr LC__________________________________________________________________________8797 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K170 S172 A236 I__________________________________________________________________________ TABLE 71______________________________________ ##STR120##No L R Cr LC______________________________________8797 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K170 S172 A236 I______________________________________ ##STR121##No L R Cr LC______________________________________28635 C.sub.5 H.sub.11 C.sub.6 H.sub.13 K67 S125 A204 N214 I______________________________________ ##STR122##No L R Cr LC______________________________________7557 C.sub.8 H.sub.17O F K71.5 A128.5 I7558 C.sub.8 H.sub.17O Cl K72 E94.5 A164 I7559 C.sub.8 H.sub.17O Br K75.5 E107.5 A149.5 I7561 C.sub.6 H.sub.13 C.sub.6 H.sub.13 K54 A45 N56 I7562 C.sub.8 H.sub.17 C.sub.6 H.sub.13 K62 A69 I7563 C.sub.8 H.sub.17O C.sub.6 H.sub.13 K55 C106 I7570 C.sub.8 H.sub.17O OC.sub.4 H.sub.9 K70.8 S99.8 N123.1 I7572 C.sub.12 H.sub.25O OCH.sub.3 K90.7 S96.9 N113.4 I______________________________________

EXAMPLE A1

44.6 g (0.34 mol) of 4-cyanobenzaldehyde and 54.4 g (0.64 mol) of o-aminobenzenethiol were dissolved in 300 ml of dimethyl sulfoxide, and the temperature of the solution was raised to 140.degree. C. The produced water and the dimethyl sulfoxide were distilled off. After heating for one hr, the residue was cooled, water was added thereto, and the resultant precipitate was collected by filtration and washed with ethanol. The crude crystal thus obtained was recrystallized from ethyl acetate to give 2-(4'-cyanophenyl)benzothiazole. 22.4 g (0.095 mol) of the compound was dissolved in 250 ml of acetic acid, and 18.6 g (0.116 mol) of bromine was dropwise added thereto. As soon as bromine was added, a yellow bromine adduct was produced. Subsequently, 150 ml of water was added, and the mixture was stirred at 80.degree. C. for 2 hr. It was then cooled, and the resultant precipitate was collected by filtration and washed with ethanol. The crude product thus obtained was recrystallized from ethyl acetate.

A 60% by weight dispersion of 0.8 g (0.02 mol) of sodium hydride in an oil was suspended in 50 ml of ether, 3.22 g (0.022 mol) of 1-octanethiol was dropwise added thereto, and the mixture was refluxed for 30 min. Thereafter, the ether was distilled off, 50 ml of N,N-dimethylimidazolidinone was added to the residue, and the temperature of the system was raised to 60.degree. C. 0.01 mol of 2-(4'-cyanophenyl)-6-bromobenzothiazole was added to the solution, and stirring was continued for one hr. The solution was cooled, water was added thereto, and the resultant precipitate was collected by filtration and washed with ethanol. The product thus obtained was recrystallized from a hexane/ethyl acetate mixed solution to give a compound represented by the following formula: ##STR123##

EXAMPLE A2

1.31 g (0.01 mol) of 4-cyanobenzaldehyde, 2.5 g (0.01 mol) of 2-amino-6-hexyloxybenzothiazole, and 30 ml of ethanol were heated at 70.degree. C. for 2 hr. The reaction mixture was then cooled to room temperature, and the resultant solid matter was collected by filtration and recrystallized from ethanol to give a compound represented by the following formula: ##STR124##

EXAMPLE A3

2.21 g (0.01 mol) of 2,5-diamino-1,4-benzenedithiol/dihydrochloric acid adduct, 5.34 g (0.024 mol) of 4-hexyloxybenzoic acid, 3 g of phosphorus pentaoxide, and 50 ml of methanesulfonic acid were allowed to react at 90.degree. C. for one hr and then heated at 80.degree. C. for 5 hr. The resultant product was collected by filtration and recrystallized from N-methylpyrrolidone to give a compound represented by the following formula: ##STR125##

EXAMPLE A4

2.56 g (0.01 mol) of 2,6-dimercaptobenzo(1,2-d: 5,6-d')bisthiazole, 4.54 g (0.02 mol) of 4-hexyloxybenzyl chloride, 1.2 g of potassium carbonate, and 15 ml of N-methylpyrrolidone were heated at 80.degree. C. for 3 hr. The reaction mixture was poured into water, and the resultant solid matter was collected by filtration and washed with water, methanol, and chloroform. It was then recrystallized from benzene to give a compound represented by the following formula: ##STR126## wherein R.dbd.CH.sub.3 (CH.sub.2).sub.5 O.

EXAMPLE A5

The procedure of Example A1 was repeated to prepare liquid crystalline compounds represented by the general formula (A) wherein R.sub.1 and R.sub.2 represent the following groups. The liquid crystalline compounds thus obtained had the same properties as the liquid crystalline compound prepared in Example A1.

______________________________________Example R.sub.1 R.sub.2______________________________________A5-1 CH.sub.3 (CH.sub.2).sub.9 O CNA5-2 CH.sub.3 CH.sub.3 C*H(CH.sub.3)CH.sub.2 O CNA5-3 CH.sub.3 (CH.sub.2).sub.5 O O(CH.sub.2).sub.9 CH.sub.3A5-4 NO.sub.2 S(CH.sub.2).sub.7 CH.sub.3A5-5 NO.sub.2 O(CH.sub.2).sub.7 CH.sub.3A5-6 F O(CH.sub.2).sub.9 CH.sub.3______________________________________

EXAMPLE A6

The procedure of Example A2 was repeated to prepare liquid crystalline compounds represented by the general formula (B) wherein R.sub.1 and R.sub.2 represent the following groups. The liquid crystalline compounds thus obtained had the same properties as the liquid crystalline compound prepared in Example A2.

______________________________________Example R.sub.1 R.sub.2 Z______________________________________A6-1 NO.sub.2 O(CH.sub.2).sub.9 CH.sub.3 CH.dbd.NA6-2 CH.sub.3 (CH.sub.2).sub.5 O O(CH.sub.2).sub.5 CH.sub.3 COOA6-3 CH.sub.3 CH.sub.2 C*H(CH.sub.3)CH.sub.2 O O(CH.sub.2).sub.7 CH.sub.3 CH.dbd.CHA6-4 CN O(CH.sub.2).sub.8 CH.sub.3 CH.dbd.CHA6-5 CH.sub.3 (CH.sub.2).sub.9 O O(CH.sub.2).sub.3 CH.sub.3 C.tbd.CA6-6 CH.sub.3 (CH.sub.2).sub.5 O O(CH.sub.2).sub.5 CH.sub.3 N.dbd.N______________________________________

EXAMPLE A7

The procedure of Example A3 was repeated to prepare liquid crystalline compounds represented by the general formula (C) wherein R.sub.1 represents the following groups. The liquid crystalline compounds thus obtained had the same properties as the liquid crystalline compound prepared in Example A3.

______________________________________Example R.sub.1______________________________________A7-1 CH.sub.3 (CH.sub.2).sub.9 OA7-2 CH.sub.3 (CH.sub.2).sub.9A7-3 CH.sub.3 (CH.sub.2).sub.9 SA7-4 CH.sub.3 (CH.sub.2).sub.5 SA7-5 CH.sub.3 (CH.sub.2).sub.8 SA7-6 CH.sub.3 CH.sub.2 C*H(CH.sub.3)CH.sub.2 O______________________________________

EXAMPLE A8

The procedure of Example A3 was repeated to prepare liquid crystalline compounds represented by the general formula (D) wherein R.sub.1 represents the following group. The liquid crystalline compounds thus obtained had the same properties as the liquid crystalline compound prepared in Example A4.

______________________________________Example R.sub.1 Z______________________________________A8-1 CH.sub.3 (CH.sub.2).sub.5 O COOA8-2 CH.sub.3 (CH.sub.2).sub.5 O CH.dbd.NA8-3 CH.sub.3 CH.sub.2 C*H(CH.sub.3)CH.sub.2 O CH.dbd.CHA8-4 CH.sub.3 (CH.sub.2).sub.5 S CH.dbd.NA8-5 CH.sub.3 (CH.sub.2).sub.3 O N.dbd.NA8-6 CH.sub.3 (CH.sub.2).sub.9 O COO______________________________________

According to the present invention, novel liquid crystalline compounds are provided which exhibit liquid crystallinity and, in addition, photoconductivity and fluorescence. The novel liquid crystalline compounds are useful as materials for liquid crystal displays, photosensitive materials for electrophotography and the like.

EXAMPLE B

�Synthesis of 2-(4'-heptyloxyphenyl)benzothiazole!74.2 g (0.34 mol) of 4-heptyloxybenzaldehyde and 54.4 g (0.46 mol) of o-aminobenzenethiol were dissolved in 300 ml of dimethyl sulfoxide, and the temperature of the solution was raised to 140.degree. C. The produced water and the dimethyl sulfoxide were distilled off. After heating for one hr, the residue was cooled, water was added thereto, and the resultant precipitate was collected by filtration and washed with ethanol. The crude crystal thus obtained was recrystallized from ethyl acetate. The yield was 90%.

The above compound exhibited the following peaks in NMR spectrum:

.sup.1 H NMR (CDCl.sub.3) .delta.=0.90 (3H, t, J=6.6 Hz), 1.25-1.47 (8H, m), 1.81 (2H, quint, J=6.6 Hz), 4.01 (2H, t, J=6.5 Hz), 6.97 (2H, d, J=8.5 Hz), 7.33 (1H, d, J=8.9 Hz), 7.45 (1H, t, J=8.5 Hz), 7.86 (1H, d, J=7.9 Hz), 8.01 (1H, d, J=8.9 Hz), 8.02 (2H, d, J=8.5 Hz)

Further, it exhibited the following peaks in IR (KBr disc) spectrum: 506, 568, 622, 648, 698, 730, 968, 1010, 1037, 1300, 1316, 1394, 1417, 1441, 1470, 1483, 1520, 1603, 2852, 2912 cm.sup.-1

�Synthesis of 2-(4'-heptyloxyphenyl)-6-bromobenzothiazole!

31.0 g (0.095 mol) of 2-(4'-heptyloxyphenyl)benzothiazole was dissolved in 250 ml of acetic acid, and 18.6 g (0.116 mol) of bromine was dropwise added thereto. As soon as bromine was added, a yellow bromine adduct was produced. Subsequently, 150 ml of water was added, and the mixture was stirred at 80.degree. C. for 2 hr. It was then cooled, and the resultant precipitate was collected by filtration and washed with ethanol. The crude product thus obtained was recrystallized from ethyl acetate. The yield was 68%.

The above compound exhibited the following peaks in NMR spectrum:

.sup.1 H NMR (CDCl.sub.3) .delta.=0.90 (3H, t, J=6.6 Hz), 1.33-1.50 (8H, m), 1.81 (2H, quint, J=6.6 Hz), 4.03 (2H, t, J=6.6 Hz), 6.98 (2H, d, J=8.6 Hz), 7.55 (1H, d, J=2.0 and J2=8.6 Hz), 7.85 (1H, d, J=8.6 Hz), 7.98 (1H, d, J=2.0 Hz), 7.99 (2H, d, J=8.6 Hz)

Further, it exhibited the following peaks in IR (KBr disc) spectrum: 520, 563, 622, 666, 695, 723, 748, 859, 1015, 1040, 1090, 1115, 1224, 1393, 1438, 1474, 1488, 1520, 1541, 2855, 2922, 2937 cm.sup.-1

�General process for synthesizing 2-(4'-alkoxyphenyl)-6-alkylthiobenzothiazole derivatives!

A 60% by weight dispersion of 0.8 g (0.02 mol) of sodium hydride in an oil was suspended in 50 ml of ether, 0.022 mol of a corresponding alkanethiol was dropwise added thereto, and the mixture was refluxed for 30 min. Thereafter, the ether was distilled off, 50 ml of N,N'-dimethylimidazolidinone was added to the residue, and the temperature of the system was raised to 600.degree. C. 0.01 mol of 2-(4'-heptyloxyphenyl)-6-bromobenzothiazole was added to the solution, and stirring was continued for one hr. The solution was cooled, water was added thereto, and the resultant precipitate was collected by filtration and washed with ethanol. The crude product thus obtained was recrystallized from hexane.

2-(4'-alkoxyphenyl)-6-alkylthiobenzothiazole, having the same R (heptyl group) and different R', had the following properties.

�2-(4'-heptyloxyphenyl)-6-hexylthiobenzothiazole! (yield 65%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.89 (3H, t, J=6.6 Hz), 0.90 (3H, t, J=6.6 Hz), 1.27-1.47 (14H, m), 1.67 (2H, quint, J=7.2 Hz), 1.82 (2H, quint, J=6.6 Hz), 2.98 (2H, t, J=7.2 Hz), 4.02 (2H, t, J=6.6 Hz), 6.98 (2H, d, J=8.6 Hz), 7.43 (1H, dd, J1 1.7 and J2=Hz), 7.82 (1H, d, J=1.7 Hz), 7.91 (1H, d, J=8.3 Hz), 7.99 (2H, d, J=8.6 Hz)

IR (KBr disc) 520, 570, 621, 701, 727, 966, 1010, 1040, 1112, 1276, 1306, 1396, 1418, 1441, 1474, 1485, 1520, 1543, 1575, 1606, 2855, 2956 cm.sup.-1

Heating: Cryst (80.5.degree. C.)--SmA (103.7.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (103.2.degree. C.)--SmA (83.9.degree. C.)--Cryst (5.degree. C./min)

�2-(4'-heptyloxyphenyl)-6-octylthiobenzothiazole! (yield 54%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.87 (3H, t, J=6.9 Hz), 0.90 (3H, t, J=6.6 Hz), 1.18-1.47 (18H, m), 1.67 (2H, quint, J=7.3 Hz), 1.81 (2H, quint, J=6.6 Hz), 2.97 (2H, t, J=7.3 Hz), 4.02 (2H, t, J=6.6 Hz), 6.98 (2H, d, J=8.9 Hz), 7.42 (1H, dd, J1=1.6 and J2=8.6 Hz), 7.81 (1H, d, J=1.6 Hz), 7.90 (1H, d, J=8.6 Hz), 7.98 (2H, d, J=8.9 Hz)

IR (KBr disc) 520, 570, 621, 702, 727, 774, 843, 967, 1017, 1041, 1112, 1176, 1276, 1306, 1396, 1441, 1474, 1486, 1520, 1543, 1575, 1607, 2855, 2956 cm.sup.-1

Heating: Cryst (94.0.degree. C.)--SmA (102.0.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (100.3.degree. C.)--SmA (89.8.degree. C.)--Sm? (78.2.degree. C.)--Cryst (5.degree. C./min)

�2-(4'-heptyloxyphenyl)-6-decylthiobenzothiazole! (yield 63%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.87 (3H, t, J=6.9 Hz), 0.90 (3H, t, J=6.6 Hz), 1.25-1.47 (22H, m), 1.66 (2H, quint, J=7.3 Hz), 1.81 (2H, quint, J=6.6 Hz), 2.96 (2H, t, J=7.3 Hz), 4.02 (2H, t, J=6.6 Hz), 6.97 (2H, d, J=8.9 Hz), 7.43 (1H, dd, J1=2.0 and J2=8.6 Hz), 7.81 (1H, d, J=2.2 Hz), 7.89 (1H, d, J=8.6 Hz), 7.98 (2H, d, J=8.9 Hz)

IR (KBr disc) 570, 812, 842, 967, 1018, 1041, 1112, 1177, 1306, 1393, 1441, 1474, 1485, 1519,1575, 1607, 2853, 2957 cm.sup.-1

Heating: Cryst (95.5.degree. C.)--SmA (100.9.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (100.6.degree. C.)--SmA (93.1.degree. C.)--Cryst (5.degree. C./min)

�2-(4'-heptyloxyphenyl)-6-dodecylthiobenzothiazole! (yield 67%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.87 (3H, t, J=7.0 Hz), 0.90 (3H, t, J=6.6 Hz), 1.28-1.46 (26H, m), 1.62(2H, quint, J=7.6 Hz), 1.78 (2H, quint, J=7.6 Hz), 2.97 (2H, t, J=7.6 Hz), 4.02 (2H, t, J=6.6 Hz), 6.97 (2H, d, J=8.6 Hz), 7.42 (1H, dd, J1=2.0 and J2=8.6 Hz), 7.81 (1H, d, J=2.0 Hz), 7.90 (1H, d, J=8.6 Hz), 7.98 (2H, d, J=8.6 Hz)

IR (KBr disc) 571, 812, 841, 967, 1018, 1111, 1178, 1306, 1395, 1474, 1486, 1519, 1607, 2852, 2920, 2956 cm.sup.-1

Heating: Cryst (90.0.degree. C.)--SmA (98.0.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (96.1.degree. C.)--SmA (85.7.degree. C.)--Cryst (5.degree. C./min)

UV-VIS .lambda.max=327 nm (10.sup.-6 M in CC1.sub.3)

PL (He--Cd Laser 324 nm) .lambda.max=420, 438 nm

EXAMPLE C

Synthesis Example 1 of Intermediate

�Synthesis of 2-(4'-heptyloxyphenyl)benzothiazole!

74.2 g (0.34 mol) of 4-heptyloxybenzaldehyde and 54.4 g (0.46 mol) of o-aminobenzenethiol were dissolved in 300 ml of dimethyl sulfoxide, and the temperature of the solution was raised to 140.degree. C. The produced water and the dimethyl sulfoxide were distilled off. After heating for one hr, the residue was cooled, water was added thereto, and the resultant precipitate was collected by filtration and washed with ethanol. The crude crystal thus obtained was recrystallized from ethyl acetate. The yield was 90%.

The above compound exhibited the following peaks in NMR spectrum:

.sup.1 H NMR (CDCl.sub.3) .delta.=0.90 (3H, t, J=6.6 Hz), 1.25-1.47 (8H, m), 1.81 (2H, quint, J=6.6 Hz), 4.01 (2H, t, J=6.5 Hz), 6.97 (2H, d, J=8.5 Hz), 7.33 (1H, d, J=8.9 Hz), 7.45 (1H, t, J=8.5 Hz), 7.86 (1H, d, J=7.9 Hz), 8.01 (1H, d, J=8.9 Hz), 8.02 (2H, d, J=8.5 Hz)

Further, it exhibited the following peaks in IR (KBr disc) spectrum: 506, 568, 622, 648, 698, 730, 968, 1010, 1037, 1300, 1316, 1394, 1417, 1441, 1470, 1483, 1520, 1603, 2852, 2912 cm.sup.-1

Synthesis Example 2 of Intermediate

�Synthesis of 2-(4'-heptyloxyphenyl)-6-bromobenzothiazole!

31.0 g (0.095 mol) of 2-(4'-heptyloxyphenyl)benzothiazole was dissolved in 250 ml of acetic acid, and 18.6 g (0.116 mol) of bromine was dropwise added thereto. As soon as bromine was added, a yellow bromine adduct was produced. Subsequently, 150 ml of water was added, and the mixture was stirred at 80.degree. C. for 2 hr. It was then cooled, and the resultant precipitate was collected by filtration and washed with ethanol. The crude product thus obtained was recrystallized from ethyl acetate. The yield was 68%.

The above compound exhibited the following peaks in NMR spectrum:

.sup.1 H NMR (CDCl.sub.3) .delta.=0.90 (3H, t, J=6.6 Hz), 1.33-1.50 (8H, m), 1.81 (2H, quint, J=6.6 Hz), 4.03 (2H, t, J=6.6 Hz), 6.98 (2H, d, J=8.6 Hz), 7.55 (1H, dd, J1=2.0 and J2=8.6 Hz), 7.85 (1H, d, J=8.6 Hz), 7.98 (1H, d, J=2.0 Hz), 7.99 (2H, d, J=8.6 Hz)

Further, it exhibited the following peaks in IR (KBr disc) spectrum: 520, 563, 622, 666, 695, 723, 748, 859, 1015, 1040, 1090, 1115, 1224, 1393, 1438, 1474, 1488, 1520, 1541, 2855, 2922, 2937 cm.sup.-1

EXAMPLES C1 to C4

�General process for synthesizing 2-(4'-alkoxyphenyl)-6-alkylthiobenzothiazole derivatives!

A 60% by weight dispersion of 0.8 g (0.02 mol) of sodium hydride in an oil was suspended in 50 ml of ether, 0.022 mol of a corresponding alkanethiol was dropwise added thereto, and the mixture was refluxed for 30 min. Thereafter, the ether was distilled off, 50 ml of N,N'-dimethylimidazolidinone was added to the residue, and the temperature of the system was raised to 60.degree. C. 0.01 mol of 2-(4'-heptyloxyphenyl)-6-bromobenzothiazole was added to the solution, and stirring was continued for one hr. The solution was cooled, water was added thereto, and the resultant precipitate was collected by filtration and washed with ethanol. The crude product thus obtained was recrystallized from hexane.

2-(4'-alkoxyphenyl)-6-alkylthiobenzothiazole, having the same R (heptyl group) and different R', had the following properties.

EXAMPLE C1

�2-(4'-heptyloxyphenyl)-6-hexylthiobenzothiazole! (yield 65%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.89 (3H, t, J=6.6 Hz), 0.90 (3H, t, J=6.6 Hz), 1.27-1.47 (14H, m), 1.67 (2H, quint, J=7.2 Hz), 1.82 (2H, quint, J=6.6 Hz), 2.98 (2H, t, J=7.2 Hz), 4.02 (2H, t, J=6.6 Hz), 6.98 (2H, d, J=8.6 Hz), 7.43 (1H, dd, J1=1.7 and J2=8.3 Hz), 7.82 (1H, d, J=1.7 Hz), 7.91 (1H, d, J=8.3 Hz), 7.99 (2H, d, J=8.6 Hz)

IR (KBr disc) 520, 570, 621, 701, 727, 966, 1010, 1040, 1112, 1276, 1306, 1396, 1418, 1441, 1474, 1485, 1520, 1543, 1575, 1606, 2855, 2956 cm.sup.-1

Heating: Cryst (80.5.degree. C.)--SmA (103.7.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (103.2.degree. C.)--SmA (83.9.degree. C.)--Cryst (5.degree. C./min)

Example C2

�2-(4'-heptyloxyphenyl)-6-octylthiobenzothiazole! (yield 54%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.87 (3H, t, J=6.9 Hz), 0.90 (3H, t, J=6.6 Hz), 1.18-1.47 (18H, m), 1.67 (2H, quint, J=7.3 Hz), 1.81 (2H, quint, J=6.6 Hz), 2.97 (2H, t, J=7.3 Hz), 4.02 (2H, t, J=6.6 Hz), 6.98 (2H, d, J=8.9 Hz), 7.42 (1H, dd, J1=1.6 and J2=8.6 Hz), 7.81 (1H, d, J=1.6 Hz), 7.90 (1H, d, J=8.6 Hz), 7.98 (2H, d, J=8.9 Hz)

IR (KBr disc) 520, 570, 621, 702, 727, 774, 843, 967, 1017, 1041, 1112, 1176, 1276, 1306, 1396, 1441, 1474, 1486, 1520, 1543, 1575, 1607, 2855, 2956 cm.sup.-1

Heating: Cryst (94.0.degree. C.)--SmA (102.0.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (100.3.degree. C.)--SmA (89.8.degree. C.)--Sm? (78.2.degree. C.) -Cryst (5.degree. C./min)

EXAMPLE C3

�2-(4'-heptyloxyphenyl)-6-decylthiobenzothiazole! (yield 63%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.87 (3H, t, J=6.9 Hz), 0.90 (3H, t, J=6.6 Hz), 1.25-1.47 (22H, m), 1.66 (2H, quint, J=7.3 Hz), 1.81 (2H, quint, J=6.6 Hz), 2.96 (2H, t, J=7.3 Hz), 4.02 (2H, t, J=6.6 Hz), 6.97 (2H, d, J=8.9 Hz), 7.43 (1H, dd, J1=2.0 and J2=8.6 Hz), 7.81 (1H, d, J=2.2 Hz), 7.89 (1H, d, J=8.6 Hz), 7.98 (2H, d, J=8.9 Hz)

IR (KBr disc) 570, 812, 842, 967, 1018, 1041, 1112, 1177, 1306, 1393, 1441, 1474, 1485, 1519,1575, 1607, 2853, 2957 cm.sup.-1

Heating: Cryst (95.5.degree. C.)--SmA (100.90.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (100.6.degree. C.)--SmA (93.1.degree. C.)--Cryst (5.degree. C./min)

EXAMPLE C4

�2-(4'-heptyloxyphenyl)-6-dodecylthiobenzothiazole! (yield 67%):

.sup.1 H NMR (CDCl.sub.3) .delta.=0.87 (3H, t, J=7.0 Hz), 0.90 (3H, t, J=6.6 Hz), 1.28-1.46 (26H, m), 1.62(2H, quint, J=7.6 Hz), 1.78 (2H, quint, J=7.6 Hz), 2.97 (2H, t, J=7.6 Hz), 4.02 (2H, t, J=6.6 Hz), 6.97 (2H, d, J=8.6 Hz), 7.42 (1H, dd, J1=2.0 and J2=8.6 Hz), 7.81 (1H, d, J=2.0 Hz), 7.90 (1H, d, J=8.6 Hz), 7.98 (2H, d, J=8.6 Hz)

IR (KBr disc) 571, 812, 841, 967, 1018, 1111, 1178, 1306, 1395, 1474, 1486, 1519, 1607, 2852, 2920, 2956 cm.sup.-1

Heating: Cryst (90.0.degree. C.)--SmA (98.0.degree. C.)--iso (2.degree. C./min)

Cooling: Iso (96.1.degree. C.)--SmA (85.7.degree. C.)--Cryst (5.degree. C./min)

UV-VIS .lambda.max=327 nm (10.sup.-6 M in CC1.sub.3)

PL (He--Cd Laser 324 nm) .lambda.max=420, 438 nm

EXAMPLES C5 to C10

Liquid crystalline compounds represented by the above general formula wherein R and R' represent the following groups were prepared in the same manner as in the above examples and comparative examples. All the liquid crystalline compounds thus obtained had the same properties as those prepared in Examples C1 to C4.

______________________________________Example R R'______________________________________Example C5 Hexyl group Heptyl groupExample C6 Octyl group Nonyl groupExample C7 Hexyl group Undecynyl groupExample C8 Decyl group Tetradecyl groupExample C9 Amyl group Tridecyl groupExample C10 Dodecyl group Heptyl group______________________________________

According to the present invention, novel liquid crystalline compounds which exhibit liquid crystallinity and, in addition, photoconductivity and fluorescence. The novel liquid crystalline compounds are useful as materials for liquid crystal displays, photosensitive materials for electrophotography and the like.

Claims

1. A process for producing a liquid crystalline compound represented by the general formula (C), comprising the step of: reacting 2 moles of a compound represented by the general formula (6) with one mole of a compound represented by the general formula (7) to obtain the liquid crystalline compound (C): ##STR127## wherein R.sub.1 is a C.sub.1 -C.sub.22 straight-chain or branched saturated or unsaturated alkyl or alkoxy group attached to the aromatic ring through an oxygen or sulfur.

2. A process for producing a liquid crystalline compound represented by the general formula (D), comprising the step of: reacting two moles of a compound represented by the general formula (8) with one mole of a compound represented by the general formula (9) to obtain the liquid crystalline compound (D): ##STR128## wherein R.sub.1 is a C.sub.1 -C.sub.22 straight-chain or branched saturated or unsaturated alkyl or alkoxy group attached to the aromatic ring through an oxygen or sulfur group; and X and Y are respectively groups which are reacted with each other to form Z selected from a --COO--, --OCO--, --N.dbd.N--, --CH.dbd.N--, --CH.sub.2 S--, --CH.dbd.CH--, or --C.tbd.C--group.

3. A process for producing a liquid crystalline compound represented by the following general formula (I), comprising the steps of: reacting a 4-alkoxybenzaldehyde with o-aminobenzenethiol to synthesize a 2-(4'-alkoxyphenyl)benzothiazole; brominating the 2-(4'-alkoxyphenyl)benzothiazole to synthesize a 2-(4'-alkoxyphenyl)-6-bromobenzothiazole; and reacting the resultant bromide with an alkanethiol to obtain the liquid crystalline compound (I): ##STR129## wherein R represents a C.sub.4 -C.sub.20 alkyl group; and R' represents a C.sub.4 -C.sub.20 alkyl group, provided that the total number of carbon atoms contained in R and R' is 10 or more.

4. A liquid crystalline compound represented by the following general formula (II): ##STR130## wherein R represents C.sub.7 H.sub.15 and R' represents C.sub.6 H.sub.13, C.sub.8 H.sub.17, C.sub.10 H.sub.21 or C.sub.12 H.sub.25.