LIQUID-CRYSTALLINE MEDIUM

Abstract

Liquid-crystalline (LC) media or LC materials and to energy saving liquid-crystal displays (LCDs) containing these media, especially gaming displays and AR/VR headsets addressed by an active matrix and in particular LC displays of the TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-FFS, SA-HB-FFS, SA-XB-FFS, polymer stabilised SA-HB-FFS, polymer stabilised SA-XB-FFS, positive VA or positive PS-VA type.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS

This application filed under 35 U.S.C. § 111(a) claims priority benefit under 35 U.S.C. § 119(a) of and to EP Patent Application No. 23218161.0, filed Dec. 19, 2023, the entire contents of which are incorporated herein by reference in their entirety and for all purposes.

BACKGROUND OF THE INVENTION

The present invention relates to liquid-crystalline (LC) media and to energy saving liquid-crystal displays (LCDs) containing these media, especially to high contrast, fast switching gaming displays and AR/VR headsets having reduced short term image sticking and reduced long term image sticking especially after light load and/or temperature load. In particular, it relates to LC displays of the TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-FFS, SA-HB-FFS, SA-XB-FFS, polymer stabilised SA-HB-FFS, polymer stabilised SA-XB-FFS, positive VA or positive PS-VA type. In a preferred embodiment, the LC media have positive dielectric anisotropy.

LCDs are used in many areas for the display of information. LCDs are used both for direct-view displays and for projection-type displays. The electro-optical modes used are, for example, the twisted nematic (TN), super twisted nematic (STN), optically compensated bend (OCB) and electrically gontrolled birefringence (ECB) modes together with their various modifications, as well as others. All these modes utilise an electric field which generated substantially perpendicular to the substrates and the LC layer.

Besides these modes, there are also electro-optical modes that utilise an electric field which is substantially parallel to the substrates or the LC layer. For example, WO 91/10936 discloses a LC display in which the electric signals are generated in such a way that the electric fields have a significant component parallel to the LC layer, and which has since then become known as “in-plane switching” (IPS) display. The principles of operating such a display are described, for example, by R. A. Soref in Journal of Applied Physics, Vol. 45, No. 12, pp. 5466-5468 (1974).

IPS displays contain an LC layer between two substrates with planar orientation, where the two electrodes are arranged on only one of the two substrates and preferably have interdigitated, comb-shaped structures. On application of a voltage to the electrodes an electric field with a significant component parallel to the LC layer is generated between them. This causes realignment of the LC molecules in the layer plane.

EP 0 588 568, for example, discloses various possibilities for the design of the electrodes and for addressing an IPS display. DE 198 24 137 likewise describes various embodiments of such IPS displays.

LC materials for IPS displays of this type are described, for example, in DE 195 28 104.

Furthermore, so-called “fringe-field switching” (FFS) displays have been reported (see, inter alia S. H. Jung et al., Jpn. J. Appl. Phys., Volume 43, No. 3, 2004, 1028), which contain two electrodes on the same substrate, one of which is structured in a comb-shaped manner and the other is unstructured. A strong, so-called “fringe field” is thereby generated, i.e. a strong electric field close to the edge of the electrodes, and, throughout the cell, an electric field which has both a strong vertical component and also a strong horizontal component. FFS displays have a low viewing-angle dependence of the contrast. FFS displays usually contain an LC medium with positive dielectric anisotropy, and an alignment layer, usually of polyimide, which provides planar alignment to the molecules of the LC medium.

LCDs of the IPS and FFS electro-optical mode are, in particular, suitable for use in modern desktop monitors, TV sets and multimedia applications. The LC media according to the present invention are preferably used in displays of this type. In general, dielectrically positive LC media having rather lower values of the dielectric anisotropy are used in FFS displays, but in some cases LC media having a dielectric anisotropy of only about 3 or even less are also used in IPS displays.

A further improvement has been achieved by the HB-FFS mode. One of the unique features of the HB-FFS mode in contrast to the traditional FFS technology is that it enables higher transmittance which allows operation of the panel with less energy consumption.

Another recently developed mode is the XB-FFS mode, wherein the LC medium additionally contains a polar liquid crystal compound with low dielectric anisotropy.

FFS and IPS displays can be operated as active-matrix displays (AMD) or passive-matrix displays (PMD). In the case of active-matrix displays individual pixels are usually addressed by integrated, non-linear active elements such as, for example, thin-film transistors (TFTs), while in the case of passive-matrix displays individual pixels are usually addressed by the multiplex method as known from the prior art.

The displays according to the present invention are preferably addressed by an active matrix, preferably by a matrix of TFT. However, the LC media according to the invention can also advantageously be used in displays having other known addressing means.

Typical applications of IPS and FFS technologies are monitors, notebooks, televisions, mobile telephones, tablet PCs, etc. Both the IPS and the FFS technology have certain advantages over other LCD technologies, such as, for example, the vertical alignment (VA) technology, e.g. a broad viewing angle dependency of the contrast.

Provision of LC media and the use thereof in a display having a particularly low short-term image sticking and low long-term image-sticking in combination with short response times is a central challenge for modern FFS and IPS applications.

In addition, modern applications also require good low-temperature stability and stability against UV radiation and increased temperatures.

The present invention has the object of providing LC media, in particular for FFS and IPS displays, but also for TN, positive VA or STN displays, and in particular for active-matrix displays like those addressed by TFTs, which have low short-term image sticking and low long-term image-sticking as well as short response times.

This object was achieved by providing LC media as described and claimed hereinafter.

SUMMARY OF THE INVENTION

The LC media according to the present invention are especially suitable for use in LC displays of the FFS, HB-FFS, XB-FFS and IPS mode based on dielectrically positive liquid crystals, and polymer stabilised variants thereof.

Surprisingly, the above technical problem is solved by providing LC media as described and claimed hereinafter.

It has now been surprisingly found that LC media according to the present invention which contain one or more compounds of the Formula I

• • in combination with one or more antioxidant and, optionally, one or more light stabilizer,
  • show several remarkable improvements like low short-term image sticking and low long-term image-sticking and enable short response times, especially when being used in FFS mode displays. The compounds of formulae I as such have been known in the prior art.

Additionally, the LC media according to the present invention have high clearing points, an excellent low temperature stability (LTS) and provide a best motion picture quality and an improved overall image quality, in particular a high contrast.

The present invention relates to a LC medium, characterised in that it comprises one or more compounds of the Formula I

• • in which the individual substituents, on each occurrence identically or differently, and each, independently of one another, have the following meanings:
  • R⁰ an alkyl group having 1 to 12 C atoms or an alkenyl group having 2 to 12 C atoms in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  -O—, —CO-O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a halogen atom;
  • X⁰ a halogen atom, —CN, —SCN, —NCS or an alkyl or an alkoxy group having 1 to 6 C atoms or an alkenyl or an alkenyloxy group having 2 to 6 C atoms in which one or more H atoms has been substituted by a halogen atom;
  • L¹ and L² each, independently of one another, H, F or C, wherein L¹ and L² do not simultaneously denote H;
  • Y⁰ H or CH₃,
  • one or more antioxidant and, optionally, one or more light stabilizer.

The antioxidants for use in the present invention are per se known in the prior art and are not particularly limited. The inventors found that an antioxidant described by the formula ST shown below in combination with the compound of Formula I allows achieving a particularly low rotational viscosity γ₁ and low short-term image sticking and low long-term image sticking, especially after a high radiation exposure or thermal stress:

• • in which in which the individual substituents have the following meanings:
  • X²¹ and X²² each, independently of one another, denote —O—, —CH₂—, —CHR²³— or —N—R²³—;
  • R²¹ and R²² each, independently of one another, denote a H atom or an alkyl- or alkoxy group having 1 to 12 C atoms, an alkenyl, alkinyl, alkenyloxy or alkoxyalkyl group having 2 to 12 C atoms or a cycloalkyl group having 3 to 12 C atoms, in which one or more non-adjacent CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a halogen atom or a cycloalkyl or a cycloalkoxy group having 3 to 12 C atoms, in which one or more H atoms may be substituted by a halogen atom;
  • R²³ denotes a H atom, an alkyl or alkoxy group having 1 to 10 C atoms;
  • r denotes 0 or 1.

In addition to the compound of Formula I and an antioxidant, the LC medium of the present invention may comprise a light stabilizer. The presence of a light stabilizer synergistically increases the stabilizing effect of the antioxidant in terms of reduced short-term image sticking and reduced long-term image sticking resulting in significant reduction of mura defects such as star mura or edge mura. Use of one or more light stabilizer of the following Formula H showed to be particularly advantageous:

• •  in which
  • R¹¹ each, independently of one another, denote a H atom, F, an alkyl group having 1 to 20 C atoms, in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—,
  • —CO—O—, —O—CO—, —NR¹³—, —CO—NR¹³— or —NR¹³—CO— in such a way that O and N atoms are not linked directly to one another and in which one H atom or a plurality of H atoms may be substituted by F, OR¹³, N(R¹³)(R¹⁴) or R¹⁵
  • R¹² each, independently of one another, denote a H atom, an alkyl group having 1 to 20 C atoms, in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—,
  • CO—O—, —O—CO—, —NR¹³—, —CO—NR¹³— or —NR¹³—CO— in such a way that O atoms are not linked directly to one another, a hydrocarbon group which contains a cycloalkyl or alkylcycloalkyl group and in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  , —O—, —CO—O—, —O—CO—, —NR¹³—, —CO—NR¹³—
    • or —NR¹³—CO— in such a way that O atoms are not linked directly to one another, and in which one H atom or a plurality of H atoms may be substituted by F, OR¹³, N(R¹³)(R¹⁴) or R¹⁵, or an aromatic or heteroaromatic hydrocarbon group, in which one H atom or a plurality of H atoms may be substituted by OR¹³, N(R¹³)(R¹⁴) or R¹⁵;
  • R¹³, R¹⁴ each, independently of one another, denote an alkyl or acyl group
  • and R¹⁵ having 1 to 10 C atoms or an aromatic hydrocarbon or carboxylic acid group having 6 to 12 C atoms in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—,
  • CO—O—, —O—CO—, —NR¹³—, —CO—NR¹³— or —NR¹³—CO— in such a way that O atoms are not linked directly to one another;
  • R¹⁶ each, independently of one another, denote a H atom, an alkyl group or an alkoxy group having 1 to 10 C atoms in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—,
  • —CH═CH—,

• •  , —O—, —CO—O—, —O—CO—, —NR¹³—, —CO—NR¹³— or
  • NR¹³—CO— in such a way that O atoms are not linked directly to one another, O-cycloalkyl group having 3 to 12 C atoms, O^• or OH;
  • R¹⁷ each, independently of one another, a H atom, an alkyl group or an alkoxy group having 1 to 10 C atoms, or an alkylene group or a single bond, wherein R¹⁷ together with S¹¹ may form a ring structure;
  • S¹¹ and S¹² each, independently of one another, denote an alkylene group having 1 to 20 C atoms, in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—,
  • —CO—O—, —O—CO—, —NR¹³—, —CO—NR¹³— or —NR¹³—CO— in such a way that O and N atoms are not linked directly to one another and in which one H atom or a plurality of H atoms may be substituted by F, OR¹³, N(R¹³)(R¹⁴) or R¹⁵, or a single bond;
  • Y¹¹ to Y¹⁴ each, independently of one another, denote methyl or ethyl;
  • X¹¹ C;
  • Z¹¹ to Z¹⁴ each, independently of one another, denote —O—, —(C=O)—, —O—(C═O)—
  • (C=O)—O—, —O—(C=O)—O—, —(NR¹³)—, —NR¹³—(C=O)—, —(C=O)—NR¹³— or a single bond and if S¹¹ is a single bond, both Z¹¹ and Z¹² do not simultaneously denote —O—; if S¹² is a single bond, both Z¹³ and Z¹⁴ do not simultaneously denote —O—; and, if q denotes —O—, both Z¹² and Z¹³ do not simultaneously denote —O—;
  • p 1 or 2;
  • q 0 or 1;
  • (3-p);
  • n an integer from 1 to 10;
  • m an integer from 0 to 8; wherein
  • n*p an integer from 1 to 10, preferably from 2 to 8, and

• •  an organic moiety having (m+n) bonding sites.

The LC media according to the present invention are especially suitable for use in energy saving LC displays of the FFS, HB-FFS, XB-FFS and IPS mode for gaming based on dielectrically positive liquid crystals, and polymer stabilised variants thereof.

The invention further relates to the use of a LC medium as described above and below for electro-optical purposes, in particular for the use in LC displays, shutter glasses, LC windows, 3D applications, preferably in TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-HB-FFS, PS-XB-FFS, SA-HB-FFS, SA-XB-FFS, polymer stabilised SA-HB-FFS, polymer stabilised SA-XB-FFS, positive VA and positive PS-VA displays, very preferably in FFS, HB-FFS, IPS, PS-HB-FFS and PS-IPS displays.

The invention further relates to an electro-optical LC display containing a LC medium as described above and below, in particular a TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-HB-FFS, PS-XB-FFS, SA-HB-FFS, SA-XB-FFS, polymer stabilised SA-HB-FFS, polymer stabilised SA-XB-FFS, positive VA or positive PS-VA display, preferably a FFS, HB-FFS, IPS, PS—HB—FFS or PS-IPS display.

In the present application, all atoms may optionally include their isotopes. In some embodiments, one or more hydrogen atoms (H) may be optionally replaced by deuterium (D); a high degree of deuteration enables or simplifies analytical determination of compounds, in particular in the case of low concentrations.

In the Formula I, ST and H, if R⁰, R²¹, R²², R¹¹, R¹² or R¹³ to R¹⁷ denote an alkyl group and/or an alkoxy group, this may be straight-chain or branched. It is preferably straight-chain, has 2, 3, 4, 5, or 6 C atoms and preferably denotes ethyl, propyl, butyl, pentyl, hexyl, ethoxy, propoxy, butoxy, pentoxy, or hexyloxy, furthermore methyl, methoxy. R⁰ preferably denotes straight-chain alkyl having 1 to 6 C atoms or an alkenyl group having 2 to 6 C atoms.

Oxaalkyl preferably denotes straight-chain 2-oxapropyl (=methoxymethyl), 2-(=ethoxymethyl) or 3-oxabutyl (=2-methoxyethyl), 2-, 3- or 4-oxapentyl, 2-, 3-, 4- or 5-oxahexyl.

If R⁰, R²¹, R²², R¹¹, R¹² or R¹³ to R¹⁷ denotes an alkoxy or oxaalkyl group it may also contain one or more additional oxygen atoms, provided that oxygen atoms are not linked directly to one another.

In another preferred embodiment, one or more of R⁰, R²¹, R²², R¹¹, R¹² or R¹³ to R¹⁷ are selected from the group consisting of

—S¹—F, —O—S¹—F, —O—S₁—O—S₂, wherein S¹ is C_1-12-alkylene or C_2-12-alkenylene and S² is H, C_1-12-alkyl or C_2-12-alkenyl, and very preferably one or more of R⁰, R²¹, R²², R¹¹, R¹² or R¹³ to R¹⁷ are selected from the group consisting of

—OCH₂—OCH₃, —O(CH₂)₂OCH₃, —O(CH₂)₃OCH₃, —O(CH₂)₄OCH₃, —O(CH₂)₂F, —O(CH₂)₃F, —O(CH₂)₄F.

If R⁰, R²¹, R²², R¹¹, R¹² or R¹³ to R¹⁷ denotes an alkenyl group, this may be straight-chain or branched. It is preferably straight-chain and has 2 to 10 C atoms. Accordingly, it denotes, in particular, vinyl, prop-1- or -2-enyl, but-1-, -2- or -3-enyl, pent-1-, -2-, -3- or -4-enyl, hex-1-, -2-, -3-, -4- or -5-enyl, hept-1-, -2-, -3-, -4-, -5- or -6-enyl, oct-1-, -2-, -3-, -4-, -5-, -6- or -7-enyl, non-1-, -2-, -3-, -4-, -5-, -6-, -7- or -8-enyl, dec-1-, -2-, -3-, -4-, -5-, -6-, -7-, -8- or -9-enyl.

If R⁰, R²¹, R²², R¹¹, R¹² or R¹³ to R¹⁷ denotes an alkyl or alkenyl group which is at least monosubstituted by halogen, this group is preferably straight-chain, and halogen is preferably F or Cl. In the case of polysubstitution, halogen is preferably F. The resultant groups also include perfluorinated groups. In the case of mono-substitution, the fluorine or chlorine substituent may be in any desired position, but is preferably in the w-position.

Particularly preferred group R⁰ in the Formula I denotes alkyl, alkenyl, alkynyl or alkoxy having up to 12, preferably up to 8 C atoms, each of which is optionally substituted by halogen, in particular by F, particularly preferred are H, F, alkyl, alkenyl or alkynyl having up to 8 C atoms.

Preferred alkyl groups are, for example, methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl and n-octyl. Preferred alkenyl groups are, for example, ethenyl, propenyl, butenyl and pentenyl. Preferred alkynyl groups are, for example, ethynyl, propynyl, butynyl, pentynyl, hexynyl, heptynyl and octynyl. Preferred alkoxy groups are, for example, methoxy, ethoxy, n-propoxy, n-butoxy, n-pentoxy, n-hexoxy, n-heptoxy, n-octoxy. Halogen preferably denotes F or Cl, F being mostly preferred.

The one or more compounds of the Formula I is preferably selected from one of the following structures:

• • in which in which R⁰, X⁰ and Y⁰ have the meanings indicated in general Formula I.

In a more preferred embodiment, R⁰, X⁰ and Y⁰ are as follows:

• • R⁰ an alkyl group having 1 to 6 C atoms or an alkenyl group having 2 to 6 C atoms in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a halogen atom, very preferably methyl, ethyl or propyl, most preferably n-propyl;
  • X⁰ a F atom or an alkyl or an alkoxy group having 1 to 3 C atoms or an alkenyl or an alkenyloxy group having 2 or 3 C atoms in which one or more H atoms are substituted by a F atom; and
  • Y⁰ H or CH₃.

Particularly preferred compounds of Formula I-1 are those selected from the group consisting of the following subformulae

Very preferred are the compounds of formulae 1-1-1, 1-1-2, 1-1-3 and 1-1-4, most preferred is the compound formula 1-1-2.

Preferred compounds of Formulae 1-2 and 1-3 are as follows:

The proportion of the compounds of Formula I or its subformulae in the LC medium is preferably from 2 to 35%, very preferably from 3 to 30%, most preferably from 4 to 20% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of Formula I or its subformulae.

DETAILED DESCRIPTION OF THE INVENTION

Antioxidant

The term “antioxidant” as used in the present application is well known to a skilled person and refers to a compound added to a LC medium which is capable of retarding autooxidation. The antioxidants for use in the present invention are not particularly limited as long as they do not substantially deteriorate physical properties of the LC medium, in particular, in terms of their voltage holding ratio and mesogenic behaviour.

In one preferred embodiment, the antioxidant in the LC medium of the present invention is described by the general Formula ST as specified above. LC media comprising compounds of the following sub-formulae ST-1, ST-2 and ST-3 showed a particularly high long-term thermal and UV stability:

in which

• • R²¹ and R²² each, independently of one another, denote a H atom or an alkyl or alkoxy group having 1 to 7 C atoms.

In particularly preferred embodiments, the compounds of the general Formula ST can be selected from the following specific structures:

In a further preferred embodiment, the LC medium according to the present invention may comprise at least one further sterically hindered phenol as an additional antioxidant, which is mentioned in Table B below.

The preferred content of the one or more compounds of Formula ST in the LC medium depends inter alia on the inherent chemical stability of the LC medium as well as on the nature of the compound of Formula ST. They are preferably used in proportion ranging from 10 ppm to 10000 ppm, more preferably from 20 ppm to 2000 ppm, based on the weight of the LC medium.

Compounds of Formula H

The term “light stabilizer” as used in the present application is well known to a skilled person and refers to a compound added to a LC medium which is capable of protecting it against degradation resulting from a long term exposure to UV radiation. Suitable light stabilizers include, inter alia, hindered amine light stabilizers (HALS) and ultraviolet (UV) absorbers as well as a combination thereof. The light stabilizers for use in the present invention are not particularly limited as long as they do not substantially deteriorate physical properties of the LC medium, in particular, in terms of voltage holding ratio and mesogenic behaviour.

In one preferred embodiment, the light stabilizer in the LC medium of the present invention is described by the general Formula H as described above. In some preferred embodiments of the present invention, in the compounds of the Formula H,

• • ethane-1,2-diyl, propane-1,3-diyl, butane-1,4-diyl, pentane-1,5-diyl, hexane-1,6-diyl, heptane-1,7-diyl, octane-1,8-diyl,

• •  and/or
  • wherein
  • —Z¹²—S¹¹—Z¹¹— on each occurrence, independently of one another, denotes —O—, —S¹¹—O—, —O—S¹¹—O—, —(C=O)—O—S¹¹—O—, —O—(C=O)—S¹¹—O—, —O—(C=O)—S¹¹-(C=O)—O—, —O—S¹¹—(C=O)—O—, —(C=O)—O—S¹¹—C, —(C=O)—O—S¹¹—O—(C=O)— or —(N—R¹³)—S¹¹—O—, —(N—R¹³—C(═O)—S¹¹—(C=O)—O or a single bond,
    • preferably —O—, —S¹¹—O—, —O—S¹¹—O—, —(C=O)—O—S¹¹—O—, —O—(C=O)—S¹¹—O— or —O—S¹¹—(C═O₀)—O—, and/or
  • S¹¹ preferably denotes an alkylene group having 1 to 20 C atoms, and/or
  • R¹¹ if present, denotes alkyl, alkoxy or H, preferably H or alkyl, and/or
  • R¹² denotes H, methyl, ethyl, propyl, isopropyl or 3-heptyl, or cyclohexyl.

In a preferred embodiment of the present application, in the compounds of the Formula H,

• • denotes a group selected from the group of the formulae:

In a further preferred embodiment of the present application, in the compounds of the Formula H,

• • denotes a group selected from the group of the formulae

In yet a further preferred embodiment of the present invention, in the compounds of the Formula H in which p preferably denotes 1,

• • denotes

• •  preferably —O—S¹¹—O—, —S¹¹—O— or —O—S¹¹, particularly preferably —O—S¹¹—O— or —S¹¹—O—.

In a further preferred embodiment of the present invention, in the compounds of the Formula H, the group

• • denotes a group selected from the group of the formulae

In a further preferred embodiment of the present invention, in which p is 2, which may be identical to or different from those described above, in the compounds of the Formula H,

• • denotes a group selected from the group of the formulae

In yet a further preferred embodiment of the present invention, which may be identical to or different from those described above, in the compounds of the Formula H, the group

• • on each occurrence, independently of one another, denotes

Compounds of the following general Formulae H-1-1, H-1-2 and H-1-3, showed to be particularly efficient UV stabilisers in LC mixtures, in particular, in terms of VHR stability:

• • wherein ZG, R¹⁶ and n are as defined above and n denotes an integer from 1 to 8. These compounds are highly suitable as stabilisers in LC mixtures and stabilise the VHR of the mixtures upon UV exposure.

In a particularly preferred embodiment, the one or more compounds of the Formula H may be selected from the group consisting of the compounds the following Formulae H-2-1 to H-2-6:

• • in which
  • R¹¹ each, independently of one another, denotes an H atom, an alkyl group having 1 to 20 C atoms, in which one —CH₂— group or, if present, a plurality of —CH₂— groups may be replaced by —O— or
  • —C(═O)—, but two adjacent —CH₂— groups cannot be replaced by —O—, and one or, if present, a plurality of —CH₂— groups may be replaced by —CH═CH— or —C≡C—, and in which one H atom or a plurality of H atoms may be replaced by F, OR¹³, N(R¹³)(R¹⁴) or R¹⁵,
  • R¹⁶ denotes a H atom or O*,
  • n denotes an integer from 0 to 12, and
  • S¹¹ and S¹² each, independently of one another, denote an alkylene group having 1 to 20 C atoms, in which one —CH₂— group or, if present, a plurality of —CH₂— groups may be replaced by —O— or —C(═O)—, but two adjacent —CH₂— groups cannot be replaced by —O—, and in which one H atom or a plurality of H atoms may be replaced by F, OR¹³, N(R¹³)(R¹⁴) or R¹⁵, or denote a single bond.

In a preferred embodiment of the present invention, the LC media according to the invention comprise in each case one or more compounds of the Formula H selected from the following group of the compounds of the formulae:

The preferred content of the one or more compounds of Formula H in the LC medium depends inter alia on the inherent chemical stability of the LC medium as well as on the nature of the compound of Formula H. Compounds of Formula H in which R¹⁶ denotes O•, which are known as NO radical type HALS are preferably used in proportion ranging from 50 ppm to 1000 ppm, based on the weight of the LC medium. Compounds of Formula H in which R¹⁶ denotes an H atom, which are known as NH radical type HALS are advantageously used in proportion ranging from 50 ppm to 2000 ppm, based on the weight of the LC medium.

Further Components

In one preferred embodiment, the LC medium may additionally comprise one or more compounds selected from the following Formulae II and Ill:

• • wherein the individual substituents, independently of each other and on each occurrence identically or differently, have the following meanings:

• • R⁰ one of the meanings given for R⁰ in Formula I,
  • X⁰ independently of one another F, Cl, an alkyl group, an alkenyl group, an alkoxy group or an alkenyloxy group having up to 6 C atoms, in which one or more H atoms has been substituted by a halogen atom,
  • L^1-8 independently of one another H, F or Cl, and
  • Y⁰ H or CH₃.

Preferred compounds of the Formula II and Ill are those wherein Y⁰ is H.

Further preferred compounds of the Formula II and Ill are those wherein R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl and X⁰ denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F.

In a preferred embodiment, the LC medium comprises one or more compounds of the Formula II selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings given in the Formula II.

Preferred compounds are those of the Formula II-1, ∥-2 and 11-3, very preferred those of the Formula II-1 and 11-2.

In the compounds of the Formulae II-1 to 11-7 R⁰ preferably denotes R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl and X⁰ denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F.

In one embodiment, the LC medium contains one or more compounds of the Formula II or their subformulae as described above and below, wherein Y⁰ is CH₃. Very preferably, the LC medium according to this preferred embodiment comprises one or more compounds of the Formula II selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings given in the Formula II.

Preferred compounds are those of the Formula IIA-1, IIA-2 and IIA-3, very preferred are those of Formula IIA-1 and IIA-2.

In the compounds of the Formulae IIA-1 to IIA-7 R⁰ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl and X⁰ denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F.

The proportion of the compounds of the Formula II in the LC medium is typically from 0 to 20%, very preferably from 1 to 15%, most preferably from 2 to 10% by weight.

In a further preferred embodiment, the LC medium comprises one or more compounds of the Formula III selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings given in the Formula II.

Particularly preferred compounds are those of the Formulae Ill-1, Ill-4, Ill-6, Ill-16, Ill-19 and Ill-20.

In the compounds of the Formulae Ill-1 to Ill-22 R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl and X⁰ denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F, and Y⁰ preferably denotes H.

The LC medium may contain one or more compounds of the Formula III or their subformulae as described above and below wherein Y⁰ is CH₃. Very preferably, the LC medium according to this preferred embodiment comprises one or more compounds of the Formula III selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings given in the Formula III.

Preferred compounds are those of the Formula IIIA-1, IIIA-4, IIIA-6, IIIA-16, IIIA-19 and IIIA-20.

In the compounds of the Formulae IIIA-1 to IIIA-21 R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl and X⁰ denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F.

The proportion of the compounds of the Formula III in the LC medium is preferably from 5 to 60%, very preferably from 10 to 50%, most preferably from 20 to 40% by weight.

In a further preferred embodiment, the LC medium may additionally comprise one or more compounds selected from the following formulae:

• • in which
  • R⁰, X⁰, L^1-4 and Y⁰ have the meanings indicated in the Formulae II and III,
  • Z⁰ denotes —C₂H₄—, —(CH₂)₄—, —CH═CH—, —CF=CF—, —C₂F₄—, —CH₂CF₂—, —CF₂CH₂—, —CH₂O—, —OCH₂—, —COO—, —CF₂O—, or —OCF₂—, in the Formulae V and VI also a single bond; and
  • s denotes 0 or 1.

The compounds of the Formula IV are preferably selected from the following formulae:

• • in which R⁰ and X⁰ have the meanings indicated in the Formulae II and III.

R⁰ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. X⁰ preferably denotes F or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl.

The compounds of the Formula IVa are preferably represented by the following subformulae:

The compounds of the Formula IVb are preferably represented by the following formulae:

The compounds of the Formulae IVc are preferably represented by the following subformulae:

• • in which R⁰ has the meanings indicated in the Formula II and is preferably alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, n-propyl, n-butyl or n-pentyl.

The compound(s) of the Formula IVc, in particular of the Formula IVc-1, is (are) preferably employed in the LC media according to the invention in amounts of 1-20% by weight, particularly preferably 2-15% by weight.

The compounds of the Formula V are preferably selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings indicated in the Formula II.
  • R⁰ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. X⁰ preferably denotes F and OCF₃, furthermore OCHF₂, CF₃, OCF=CF₂, OCHFCF₃ and OCH═CF₂.

The compounds of the Formula VI are preferably selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings indicated in the Formula II.

R⁰ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, n-propyl, n-butyl or n-pentyl. X⁰ preferably denotes F, furthermore OCF₃, CF₃, CF=CF₂, OCHF₂, OCHFCF₃ and OCH═CF₂;

Preferred compounds of the Formulae Via to Vie are those selected from the following subformulae:

• • “alkyl” being an alkyl group with 1 to 6 C atoms.

The compounds of the Formula VII are preferably selected from the following subformulae:

• • in which R⁰ and X⁰ have the meanings indicated in the Formula II.

R⁰ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. X⁰ preferably denotes F, furthermore OCF₃, OCHF₂, OCHFCF₃ and OCH═CF₂.

In some embodiments, the LC medium additionally comprises one or more compounds selected from the following formulae:

• • in which
  • R⁰ and X⁰ each, independently of one another, have one of the meanings indicated in the Formula II,
  • L^1-4 each, independently of one another, denote H or F,
  • Y⁰ denotes H or CH₃, preferably H,
  • X⁰ is preferably F, Cl, CF₃, OCF₃ or OCHF₂, OCF=CF₂, OCHFCF₃,
  • R⁰ preferably denotes alkyl, alkoxy, oxaalkyl, cycloalkyl, fluoroalkyl or alkenyl, each having up to 6 C atoms.

Very preferably, the LC medium according to the invention comprises one or more compounds of the Formula XXa:

• • in which R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl and X⁰ denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F. R⁰ preferably denotes straight-chain alkyl, in particular ethyl, n-propyl, n-butyl or n-pentyl and very particularly preferably n-propyl.

The compound(s) of the Formula XX, in particular of the Formula XXa, is (are) preferably employed in the LC media according to the invention in amounts of 0-15% by weight, particularly preferably 1-10% by weight.

Very preferably, the LC medium according to the invention comprises one or more compounds of the Formula XXIa:

• • in which R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. R⁰ preferably denotes straight-chain alkyl, in particular ethyl, n-propyl, n-butyl or n-pentyl and very particularly preferably n-propyl.

The compound(s) of the Formula XXI, in particular of the Formula XXIa, is (are) preferably employed in the LC media according to the invention in amounts of 1-15% by weight, particularly preferably 2-10% by weight.

Further preferably, the LC medium according to the invention comprises one or more compounds of the Formula XXIIIa:

• • in which R⁰ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms. R⁰ preferably denotes straight-chain alkyl, in particular ethyl, n-propyl, n-butyl or n-pentyl and very particularly preferably n-propyl or cycloalkyl, in particular cyclopentyl.

Preferred specific compounds of Formula XXIIIa include, in particular

The compound(s) of the Formula XXIII, in particular of the Formula XXIIIa, is (are) preferably employed in the LC media according to the invention in amounts of 0.5-5% by weight, particularly preferably 0.5-2% by weight.

The LC medium may additionally comprise one or more compounds of the Formula XXIV:

• • in which R⁰, X⁰ and L^1-6 have the meanings indicated in the Formula III, s denotes 0 or 1, and

In the Formula XXIV, X⁰ may also denote an alkyl group having 1 to 6 C atoms or an alkoxy group having 1 to 6 C atoms. The alkyl or alkoxy group is preferably straight-chain.

R⁰ preferably denotes alkyl having 1 to 6 C atoms. X⁰ preferably denotes F.

The compounds of the Formula XXIV are preferably selected from the following subformulae:

• • in which R⁰, X⁰ and L¹ have the meanings indicated in the Formula III. R⁰ preferably denotes alkyl having 1 to 6 C atoms. X⁰ preferably denotes F, and L¹ is preferably F;

• •  is preferably

• • R⁰ is straight-chain alkyl or alkenyl having 2 to 6 C atoms;

The LC medium may further comprise one or more compounds of the following formulae:

• • in which R¹ and X⁰ have the meanings indicated in the Formula II for R⁰ and X⁰, respectively. R¹ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. X⁰ preferably denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F. In the Formula XXIV, X⁰ very particularly preferably denotes Cl.

The LC medium may further optionally comprise one or more compounds of the following formulae:

• • in which
  • and R¹, X⁰ and Y⁰ have the meanings indicated in the Formula II for R⁰, X⁰ and Y⁰, respectively. R¹ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. X⁰ preferably denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F, and Y⁰ preferably denotes H. In some embodiments, the LC medium according to the invention preferably comprises one or more compounds of the Formula XXIX in which X⁰ preferably denotes F.

The compounds of the Formula XXVIII are preferably selected from the subformulae XXVIIIa, wherein XXVIIIa-1 and XXVIIIa-2 are mostly preferred:

• • “alkyl” being an alkyl group with 1 to 6 C atoms.

The compound(s) of the Formulae XXVII-XXX is (are) preferably employed in the LC media according to the invention in amounts of 1-20% by weight, particularly preferably 1-15% by weight. Particularly preferred LC media comprise at least one compound of the Formula XXIX and/or the Formula XXX.

Very preferably, the LC medium according to the invention comprises one or more compounds of the Formulae XXIXa and/or XXXa:

• • in which R¹ and Y⁰ have the meanings indicated for R⁰ and Y⁰ in the Formula II, and preferably R¹ denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl.

The compound(s) of the Formulae XXIXa and/or XXXa is/are preferably employed in the LC media according to the invention in amounts of 1-15% by weight, particularly preferably 2-10% by weight.

The LC medium may further comprise one or more compounds of the following pyrimidine or pyridine compounds of the following formulae:

• • in which R¹, X⁰ and Y⁰ have the meanings indicated in the Formula II for R⁰, X⁰ and Y⁰, respectively. R¹ preferably denotes alkyl having 1 to 6 C atoms or cycloalkyl having 3 to 6 C atoms, very preferably ethyl, propyl, butyl or pentyl. X⁰ preferably denotes F, CF₃ or OCF₃, furthermore OCF=CF₂, OCHFCF₃ or Cl, very preferably F and Y⁰ preferably denotes H. The medium according to the invention particularly may optionally comprise one or more compounds of the Formula XXXI-1, in which X⁰ preferably denotes F. The compound(s) of the Formulae XXXI-1 to XXXI-3 may be employed in the LC media according to the invention in amounts of 1-20% by weight, particularly preferably 1-15% by weight.

Preferably, in addition to the compounds of the Formula I, an antioxidant and, optionally, a light stabilizer, the LC medium contains one or more compounds of the Formulae N1 and N2:

• • in which
  • R⁴¹ and R⁴² independently of one another, have the meaning indicated above for R⁰ under Formula I, preferably R⁴¹ denotes alkyl and R⁴² denotes alkyl or alkoxy or R⁴¹ denotes alkenyl and R⁴² denotes alkyl, wherein one —CH₂— group may be replaced by cyclopropylene, 1,3-cyclobutylene, 1,3-cyclopentylene, 1,3-cyclopentenylene, preferably by cyclopropylene or 1,3-cyclopentylene,

• •  independently of one another and, if

• •  occurs twice,
  •  also these independently of one another, denote

• •  preferably one or more of

• •  denotes or denote,

• • Z⁴¹ and Z⁴², independently of one another and, if Z⁴¹ occurs twice, also these independently of one another, denote —CH₂CH₂—, —COO—, trans-CH═CH—, trans-CF=CF—, —CH₂O—, —CF₂O—, —C≡C— or a single bond, preferably one or more thereof denotes/denote a single bond, and
  • p denotes 0, 1 or 2, preferably 0 or 1, and
  • R⁵¹ and R⁵², independently of one another, have one of the meanings given for R⁴¹ and R⁴² and preferably denote alkyl having 1 to 7 C atoms, preferably n-alkyl, particularly preferably n-alkyl having 1 to 5 C atoms, alkoxy having 1 to 7 C atoms, preferably n-alkoxy, particularly preferably n-alkoxy having 2 to 5 C atoms, alkoxyalkyl, alkenyl or alkenyloxy having 2 to 7 C atoms, preferably having 2 to 4 C atoms, preferably alkenyloxy,
    • wherein one —CH₂— group may be replaced by cyclopropylene, 1,3-cyclobutylene, 1,3-cyclopentylene, 1,3-cyclopentenylene, preferably by cyclopropylene or 1,3-cyclopentylene,

• • •  if present, each, independently of one another, denote

• • preferably

• • preferably

• • and, if present,

• •  preferably denotes,

• • Z⁵¹ to Z⁵³ each, independently of one another, denote —CH₂—CH₂—, —CH₂—O—, —CH═CH—, —C≡C—, —COO— or a single bond, preferably —CH₂—CH₂—, —CH₂—O— or a single bond and particularly preferably a single bond,
  • i and j each, independently of one another, denote 0 or 1,
  • (i+j) preferably denotes 0, 1 or 2, more preferably 0 or 1 and, most preferably, 1, and
  • wherein the one or more, preferably one, of the aromatic rings present may optionally be substituted by an alkyl group, preferably by methyl.

In some embodiments, the LC medium contains one or more compounds selected from the following formulae:

• • wherein
  • “alkyl” and “alkyl*” each, independently from one another, denote an alkyl group having 1 to 6 C atoms;
  • “alkenyl” and “alkenyl*” each, independently of one another, denote an alkenyl group having 2 to 6 C atoms.

Very preferred are compounds of the Formula Z¹ and Z².

Preferred compounds of the Formulae Z¹ to Z⁶ are those selected from the following subformulae:

In another preferred embodiment, the LC medium contains one or more compounds of the Formula Z1 or its preferred subformulae and/or one or more compounds selected from the Formulae Z2, Z3, Z4 and Z5 or their preferred subformulae.

Preferably, the total proportion of compounds of the Formula Z1, Z2, Z3, Z4, Z5 and Z6 or their subformulae, such as CC-3-V in the medium is from 10 to 65%, very preferably from 20 to 60%, most preferably from 25 to 55% by weight. In yet a more preferred embodiment, the compound of the Formula Z1-1 is used in concentrations ranging from 10 wt.-% to 60 wt.-%, more preferably 25 wt.-% to 50 wt.-%, based on the total weight of the LC medium. In a further preferred embodiment, the LC medium comprises 50 wt.-% to 70 wt.-% of compounds represented by the Formulae Z1-1 and Z4-2 in total.

Preferably, the medium contains 1, 2 or 3 compounds selected from the Formulae Z1, Z2, Z3 and Z4 or their subformulae.

The LC medium may additionally comprise one or more compounds of the following general formulae:

• • in which
  • R¹ and R² each, independently from one another, denote C_1-6-alkyl, C_1-6-alkoxy or C_2-6-alkenyl.

The compounds of the Formula XII are preferably selected from the following subformulae:

wherein “alkyl” and “alkyl*” each, independently from one another, denote methyl, ethyl, propyl, butyl, pentyl or hexyl.

Particular preference is given to the compounds of the Formulae XIIa and XIIc. In the Formula XIIb, “alkyl” preferably, independently of one another, denotes n-C₃H₇, n-C₄H₉ or n-C₅H₁₁, in particular n-C₃H₇. In the Formula XIIc, “alkyl” preferably denotes n-C₃H₇ and “alkyl” is preferably CH₃ or n-C₃H₇.

Particularly preferred compounds of the Formula XII are described by the following structures:

The LC medium may additionally comprise one or more compounds selected from the following formulae:

in which L¹ and L² have the meanings indicated in the Formula III, and R¹ and R² each, independently of one another, denote n-alkyl, cycloalkyl, alkoxy, oxaalkyl, fluoroalkyl or alkenyl, each having up to 6 C atoms, and preferably each, independently of one another, denote alkyl having 1 to 6 C atoms; in the compound of the Formula XIV, at least one of the substituents R¹ and R² preferably denotes alkenyl having 2 to 6 C atoms.

The LC medium may further optionally comprise one or more compounds of the Formula XIV in which at least one of the substituents R¹ and R² denotes alkenyl having 2 to 6 C atoms, preferably those selected from the following subformulae:

in which “alkyl” and “alkyl*” have the meaning indicated above, and each, independently of one another, preferably denote methyl, ethyl or propyl.

The compounds of the Formulae XIV are preferably selected from the following subformulae:

Very preferred are compounds of the Formulae XIVd-1, XIVe-1, XIVe-2 and XIVe-3.

The LC medium may further optionally comprise one or more compounds of the Formula XV in which at least one of the substituents R¹ and R² denotes alkyl or alkoxy having 2 to 6 C atoms, preferably those selected from the following subformulae:

• • in which “alkyl” and “alkyl*” has the meaning indicated above, and each, independently of one another, preferably denote methyl, ethyl or propyl.

In yet a further embodiment, the LC medium comprises one or more compounds of the Formula XVI:

in which R¹ and R² have the meanings indicated for R⁰ in the Formula II, and preferably each, independently of one another, denote alkyl having 1 to 6 C atoms. L denotes H or F.

Particularly preferred compounds of the Formula XVI are those of the subformulae:

• • in which
  • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms, in particular ethyl, propyl or pentyl, and
  • “alkenyl” and “alkenyl*” each, independently of one another, denote a straight-chain alkenyl group having 2 to 6 C atoms, in particular CH₂=CHC₂H₄, CH₃CH═CHC₂H₄, CH₂=CH and CH₃CH═CH.

Particular preference is given to the compounds of the Formulae XVIb and XVIc. Very particular preference is given to the compounds of the following subformulae:

In yet a further embodiment, the LC medium comprises one or more compounds of the Formula XIII:

in which R¹ and R² have the meanings indicated for R⁰ in the Formula II, and preferably each, independently of one another, denote alkyl having 1 to 6 C atoms. L denotes H, F or Cl.

Particularly preferred compounds of the Formula XIII are those of the subformulae:

• • in which
  • “alkyl” and “alkyl*” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms, in particular ethyl, propyl or pentyl, and
  • “alkenyl” and “alkenyl*” each, independently of one another, denote a straight-chain alkenyl group having 2 to 6 C atoms, in particular CH₂=CHC₂H₄, CH₃CH═CHC₂H₄, CH₂=CH and CH₃CH═CH.

Particular preference is given to the compounds of the Formulae XIIla and XIIlb. Very particular preference is given to the compounds of the following subformulae:

In yet a further embodiment, the LC medium comprises one or more compounds of the Formula XIII:

• • in which R¹ and R² have the meanings indicated for R⁰ in the Formula II, and preferably each, independently of one another, denote alkyl having 1 to 6 C atoms. L denotes H, F or Cl.

Particularly preferred compounds of the Formula XIII are those of the subformulae:

• • in which
  • “alkyl” and “alkyl*” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms, in particular ethyl, propyl or pentyl, and
  • “alkenyl” and “alkenyl*” each, independently of one another, denote a straight-chain alkenyl group having 2 to 6 C atoms, in particular CH₂=CHC₂H₄, CH₃CH═CHC₂H₄, CH₂=CH and CH₃CH═CH.

Particular preference is given to the compounds of the Formulae XIIla and XIIlb. Very particular preference is given to the compounds of the following subformulae:

The LC medium may optionally comprise one or more compounds of the following formulae:

• • in which
  • R¹ and R² have the meanings indicated in the Formula G, respectively, and preferably each, independently of one another, denote alkyl having 1 to 6 C atoms. L denotes H or F.

Very preferred are compounds of the Formula XVIIa, wherein L is H or F. Very preferred are compounds of the Formula XVIIb, wherein L is F.

The LC medium may additionally comprise one or more compounds of the following formula:

• • in which L, R¹ and R² have the meanings indicated in the Formula I for L¹ and R⁰, respectively. R¹ and R² preferably denote alkyl, alkoxy, oxaalkyl, fluoroalkyl or alkenyl, each having up to 6 C atoms.

Particularly preferred compounds of the Formula XXXII are those of the subformulae:

in which

• • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms, in particular ethyl, propyl or pentyl, and
  • “alkenyl” denotes a straight-chain alkenyl group having 2 to 6 C atoms, in particular CH₂=CHC₂H₄, CH₃CH═CHC₂H₄, CH₂=CH and CH₃CH═CH.

Very particular preference is given to the compounds of the following subformulae:

In some further embodiments, the LC medium comprises one or more compounds of the following formulae:

• • in which R¹ and R² each, independently from one another, have the meanings indicated in the Formula I for R⁰ and preferably each, independently of one another, denote alkyl having 1 to 6 C atoms.

Very particular preference is given to the compounds of the following subformulae:

Advantageously, the LC medium of the present invention may comprise one or more compounds of the Formula LP1

• • and/or one or more compounds of the Formula LP2

• • in which the individual substituents have the following meanings:
  • R⁰ has one of the meanings given in for R¹ in the Formula I;
  • R² denote an alkyl or an alkoxy group having 1 to 12 C atoms or an alkenyl or an alkenyloxy group having 2 or 12 C atoms in which one or more non-adjacent CH₂ groups are optionally substituted by —C≡C—,
  • —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a cycloalkyl or a cycloalkoxy group having 3 to 12 C atoms;
  • X⁰ has one of the meanings given in for X⁰ in the Formula I;
  • Y⁰ denote H or CH₃; and
  • m and n denote 0 or 1.

The one or more compounds of the Formulae LP1 and LP2 may be preferably described by the following Formulae:

• • in which
  • R⁰ is an alkyl or an alkoxy group having 1 to 6 C atoms or an alkenyl group having 2 to 6 C atoms in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—
  • —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a halogen atom;
  • R² is an alkyl group having 1 to 6 C atoms, in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—
  •  —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a halogen atom;
  • X⁰ a F atom or an alkyl or an alkoxy group having 1 to 3 C atoms or an alkenyl or an alkenyloxy group having 2 or 3 C atoms in which one or more H atoms are replaced by a F atom; and
  • Y⁰ H or CH₃.

The compounds of the general Formulae LP1 and LP2 can also be represented by one of the following structures:

• • in which
  • R⁰ is an alkyl or an alkoxy group having 1 to 12 C atoms in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—,

• •  —O—
  • —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be substituted by a halogen atom, preferably an alkyl group having 1 to 4 C atoms, alkenyl or an alkenyloxy group having 2 to 6 C atoms or a cycloalkyl or a cycloalkyloxy group having 3 to 6 C atoms, wherein vinyl, allyl or cyclopentyl are particularly preferable;
  • n denotes 1, 2, 3, 4 or 5; and
  • m denotes 1, 2, 3 or 4.

Particularly preferred compounds of the Formula LP1 are those selected from the group consisting of the following subformulae:

• • wherein Y⁰ is H or CH₃, preferably H.

Particularly preferred compounds of the Formula LP2 are those selected from the group consisting of the following subformulae:

• • wherein Y⁰ is H or CH₃, preferably H.

Very preferred are compounds of the Formulae LP2-1a, LP2-1b, LP2-1c, LP2-1d, and LP2-1 i, LP2-2b, LP2-3a, LP2-3c mostly preferred is the compound Formula LP2-1 b.

Preferably, the LC medium comprises one or more compounds of the Formula LP1 and one or more compounds of the Formula LP2.

The total proportion of the compounds of the Formula LP1 or its subformulae in the LC medium is preferably from 2 to 35%, very preferably from 3 to 25%, mostly preferred from 4 to 15% by weight. The total proportion of the compounds of the Formula LP2 or its subformulae in the LC medium is preferably from 2 to 35%, very preferably from 3 to 25%, mostly preferred from 4 to 15% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of the Formula LP1 or their subformulae. In a particularly preferred embodiment, the LC medium comprises at least one compound of the Formula LP1.

In addition to the compounds of the Formula I, an antioxidant and, optionally, a light stabilizer, the LC medium may optionally contain one or more compounds selected from the Formulae Y and B:

• • in which the individual substituents, on each occurrence identically or differently, and each, independently of one another, have the following meanings:

• • wherein
  • R¹, R² each, independently from one another, have one of the meanings given for R⁰ in the Formula I,
  • R³ one of the meanings given for R¹,
  • Z^x, Z^y —CH₂CH₂—, —CH═CH—, —CF₂O—, —OCF₂—, —CH₂O—, —OCH₂—, —CO—O—,
  • —O—CO—, —C₂F₄—, —CF=CF—, —CH═CH—CH₂O—, or a single bond, preferably a single bond,
  • Z^z —CH₂O—, —O—, —C₂H₄—, —OCH₂—, or a single bond,
  • Y¹ —CH₂—, —O— or —S—,
  • L^1-4 H, F or Cl, preferably H or F, very preferably F,
  • x, y 0, 1 or 2, with x+y<3,
  • z 0 or 1,
  • wherein in the Formula B the dibenzofuran or dibenzothiophene group may also be further substituted by a methyl or methoxy group, and
  • wherein the compounds of the Formula Y contain at least one substituent L^1-4 that is F or Cl, preferably F.

The LC medium according to this first preferred embodiment may contain one or more compounds of the Formula I, one or more antioxidants, one or more light stabilizers, one or more compounds selected from the Formulae Z1, Z2 and Z3, and one or more compounds selected from the Formulae Y and B.

The LC media according to this first preferred embodiment are especially suitable for use in LC displays of the HB-FFS or PS-HB-FFS mode.

In the compounds of the Formula Y and its subformulae, R¹ and R² preferably denote straight-chain alkyl or alkoxy having 1 to 6 C atoms, furthermore alkenyl having 2 to 6 C atoms, in particular vinyl, 1E-propenyl, 1E-butenyl, 3-butenyl, 1E-pentenyl, 3E-pentenyl or 4-pentenyl.

In the compounds of the Formula Y and its subformulae, preferably both substituents L¹ and L² denote F. In another preferred embodiment of the present invention, in the compounds of the Formula Y and its subformulae one of the substituents L¹ and L² denotes F and the other denotes Cl.

In a preferred embodiment of the present invention, the LC medium contains one or more compounds of the Formula Y selected from the following subformulae:

• • wherein R¹, R², Z^x and Z^y have the meanings given in the Formula Y,
  • a denotes 1 or 2,
  • b denotes 0 or 1,
  • L¹, L² denote F or Cl, preferably F, and
  • L⁵ denotes a H atom or CH₃,

Preferably, in the compounds of the Formula Y¹ and Y² both L¹ and L² denote F or one of L¹ and L² denotes F and the other denotes C₁, or both L¹ and L² denote F or one of L¹ and L² denotes F and the other denotes Cl.

Preferably, the LC medium comprises one or more compounds of the Formula Y¹ selected from the group consisting of the following subformulae:

• • in which
  • a denotes 1 or 2,
  • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms,
  • “alkenyl” denotes a straight-chain alkenyl group having 2 to 6 C atoms, and
  • L⁵ denotes a H atom or CH₃.
  • “alkenyl” preferably denotes CH₂=CH—, CH₂=CHCH₂CH₂—, CH₃—CH═CH—, CH₃—CH₂—CH═CH—, CH₃—(CH₂)₂—CH═CH—, CH₃—(CH₂)₃—CH═CH— or CH₃—CH═CH—(CH₂)₂—.

Very preferably, the LC medium contains one or more compounds of the Formula Y1 selected from the Formulae Y1-1, Y1-2, Y1-7, Y1-12, Y1-17, Y1-22, Y1-40, Y1-41, Y1-42, Y1-44, Y1-50 and Y1-68. L⁵ preferably denotes a H atom.

Further preferably, the LC medium comprises one or more compounds of the Formula Y² selected from the group consisting of the following subformulae:

• • which
  • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms, and
  • “alkenyl” denotes a straight-chain alkenyl group having 2 to 6 C atoms, (O) denotes an oxygen atom or a single bond, and
  • L⁵ denotes a H atom or CH₃, preferably a H atom.
  • “alkenyl” preferably denotes CH₂=CH—, CH₂=CHCH₂CH₂—, CH₃—CH═CH—, CH₃—CH₂—CH═CH—, CH₃—(CH₂)₂—CH═CH—, CH₃—(CH₂)₃—CH═CH— or CH₃—CH═CH—(CH₂)₂—.

Very preferably, the LC medium contains one or more compounds of the Formula Y2 selected from Formulae Y2-2 and Y2-10.

The proportion of the compounds of the Formula Y1 or its subformulae in the LC medium is preferably from 0 to 10% by weight.

The proportion of the compounds of the Formula Y2 or its subformulae in the LC medium is preferably from 0 to 10% by weight.

The total proportion of the compounds of the Formula Y1 and Y2 or their subformulae in the medium is preferably from 1 to 20%, very preferably from 2 to 15% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of the Formula Y1 and Y2 or their subformulae, very preferably selected from the Formulae Y1-2, Y1-22, Y1-66, Y1-70, Y2-6 and Y2-22.

In another preferred embodiment of the present invention, the LC medium contains one or more compounds of the Formula Y of the following subformula:

• • wherein L¹, L², L⁵, R¹ and R² have one of the meanings given in the Formula I for L¹, L², Y⁰ and R⁰, respectively.

Preferred compounds of the Formula Y3 are selected from the group consisting of the following subformulae:

• • in which,
  • “alkyl” and “alkyl*” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms;
  • “alkenyl” and “alkenyl*” each, independently of one another, denote a straight-chain alkenyl group having 2 to 6 C atoms; and
  • (O) denotes an oxygen atom or a single bond.
  • “alkenyl” and “alkenyl*” preferably denote CH₂=CH—, CH₂=CHCH₂CH₂—, CH₃—CH═CH—, CH₃—CH₂—CH═CH—, CH₃—(CH₂)₂—CH═CH—, CH₃—(CH₂)₃—CH═CH— or CH₃—CH═CH—(CH₂)₂—.

Particularly preferred compounds of the Formula Y3 are selected from the group consisting of following subformulae:

• • wherein “alkoxy” and “alkoxy*” each, independently of one another, preferably denote straight-chain alkoxy with 3, 4, or 5 C atoms.

Preferably, in the compounds of the Formula Y3 and its subformulae both L¹ and L² denote F. Further preferably in the compounds of the Formula Y3 one of the substituents L¹ and L² denotes F and the other denotes Cl.

The proportion of the compounds of the Formula Y3 or its subformulae in the LC medium is preferably from 0 to 10%, very preferably from 1 to 6% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of the Formula Y3 or its subformulae, more preferably of the Formula Y3-6, very preferably of the Formula Y3-6A.

In yet another preferred embodiment of the present invention, the LC medium contains one or more compounds of the Formula Y of the subformula Y4:

• • in which R¹ and R² each, independently of one another, have one of the meanings indicated above in the Formula Y, and

• • each, independently of one another, denote

• • in which L⁵ denotes F or Cl, preferably F, and L⁶ denotes F, Cl, OCF₃, CF₃, CH₃, CH₂F or CHF₂, preferably F, and preferably at least one of the rings G, I and K is different from unsubstituted benzene.

Mostly preferred compounds of the Formula Y4 are selected from the group consisting of the following subformulae:

• • in which
  • R denotes a straight-chain alkyl or alkoxy group having 1-7 C atoms,
  • (O) denotes an oxygen atom or a single bond, and
  • m denotes an integer from 1 to 6.

R preferably denotes methyl, ethyl, propyl, butyl, pentyl, hexyl, methoxy, ethoxy, propoxy, butoxy or pentoxy.

The proportion of the compounds of the Formula Y4 or its subformulae in the medium is preferably from 0 to 10%, very preferably from 1 to 6% by weight.

Particularly preferred compounds are those of the subformulae

in which

• • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms, in particular ethyl, propyl or pentyl.

Use of the following compounds is particularly advantageous:

In another preferred embodiment of the present invention, the LC medium contains one or more compounds of the Formula Y selected from the group consisting of the following subformulae:

• • in which R⁵ has one of the meanings indicated above in the Formula Y for R¹, “alkyl” denotes a straight-chain alkyl group having 1 to 6 C atoms, d denotes 0 or 1, and z and m each, independently of one another, denote an integer from 1 to 6.

R⁵ in these compounds is particularly preferably C₂-6-alkyl or -alkoxy or C_2-6-alkenyl, d is preferably 1. The LC medium according to the invention preferably comprises one or more compounds of the above-mentioned formulae in amounts of >5% by weight.

Further preferred embodiments are indicated below:

• • The LC medium comprises one or more compounds of the Formula Y of the following subformula

• • wherein R¹, R², L¹, L², X, x and Z^x have the meanings given in the Formula Y, and wherein at least one of the rings X is cyclohexenylene.

Preferably, both substituents L¹ and L² denote F. Further preferably, one of the substituents L¹ and L² denotes F and the other denotes Cl.

The compounds of the Formula LY are preferably selected from the group consisting of the following subformulae:

• • in which
  • R¹ has the meaning indicated in the Formula Y above,
  • (O) denotes an oxygen atom or a single bond, and
  • v denotes an integer from 1 to 6.

R¹ preferably denotes straight-chain alkyl having 1 to 6 C atoms or straight-chain alkenyl having 2 to 6 C atoms, in particular CH₃, C₂H₅, n-C₃H₇, n-C₄H₉, n-C₅H₁₁, CH₂=CH—, CH₂=CHCH₂CH₂—, CH₃—CH═CH—, CH₃—CH₂—CH═CH—, CH₃—(CH₂)₂—CH═CH—, CH₃—(CH₂)₃—CH═CH— or CH₃—CH═CH—(CH₂)₂—.

Very preferred are compounds of the Formula LY4.

Preferably, the medium contains 1, 2 or 3 compounds of the Formula LY, very preferably of the Formula LY4.

The proportion of the compounds of the Formula LY or its subformulae in the medium is preferably from 1 to 10% by weight.

• • The medium comprises one or more compounds of the Formula Y represented by the following subformula:

• • wherein R¹, R², L¹, L², Y, y and Z^y have the meanings given in the Formula Y, and wherein at least one of the rings Y is tetrahydropyrane.

The compounds of the Formula AY are preferably selected from the group consisting of the following subformulae:

• • in which
  • R¹ has the meaning indicated above,
  • “alkyl” denotes a straight-chain alkyl group having 1 to 6 C atoms,
  • (O) denotes an oxygen atom or a single bond, and
  • v denotes an integer from 1 to 6.

R¹ preferably denotes straight-chain alkyl having 1 to 6 C atoms or straight-chain alkenyl having 2 to 6 C atoms, in particular CH₃, C₂H₅, n-C₃H₇, n-C₄H₉, n-C₅H₁₁, CH₂=CH—, CH₂=CHCH₂CH₂—, CH₃—CH═CH—, CH₃—CH₂—CH═CH—, CH₃—(CH₂)₂—CH═CH—, CH₃—(CH₂)₃—CH═CH— or CH₃—CH═CH—(CH₂)₂—.

In the compounds of the Formula B and its subformulae, R¹ and R³ preferably denote straight-chain alkyl or alkoxy having 1 to 6 C atoms, in particular methoxy, ethoxy, propoxy or butoxy, furthermore alkenyl having 2 to 6 C atoms, in particular vinyl, 1E-propenyl, 1E-butenyl, 3-butenyl, 1E-pentenyl, 3E-pentenyl or 4-pentenyl.

In a preferred embodiment of the present invention, the medium contains one or more compounds of the Formula B selected from the following subformulae:

• • wherein Y1, L¹, L², R¹ and R³ have the meanings given in the Formula B.

Preferred compounds of the Formula B1 are selected from the following subformulae:

• • wherein R¹ and R³ independently denote a straight-chain alkyl group having 1 to 6 C atoms, in which one or more CH₂ groups are optionally substituted by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be replaced by a halogen atom.

Very preferred are compounds of the Formula B1-1 and B1-2 wherein both groups (O) denote an oxygen atom and R¹ and R³ independently denote an alkyl group being methyl, ethyl, propyl, butyl, pentyl or hexyl, which are preferably straight-chained. Very preferably one “alkyl” is ethyl and the other “alkyl” is n-pentyl.

Particularly preferred are compounds of the Formula B1-2.

Preferably, the compounds of the Formula B1-1 are selected from the group of compounds of the Formulae B1-1-1 to B1-1-11, preferably of the Formula B1-1-6:

• • in which
  • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms,
  • “alkenyl” and “alkenyl*” each, independently of one another, denote a straight-chain alkenyl group having 2 to 6 C atoms,
  • “alkoxy” and “alkoxy*” each, independently of one another, denote a straight-chain alkoxy group having 1 to 6 C atoms.

Preferably, the compounds of the Formula B1-2 are selected from the group of compounds of Formulae B1-2-1 to B1-2-10, preferably of Formula B1-2-6:

• • in which
  • “alkyl” and “alkyl” each, independently of one another, denote a straight-chain alkyl group having 1 to 6 C atoms,
  • “alkenyl” and “alkenyl*” each, independently of one another, denote a straight-chain alkenyl group having 2 to 6 C atoms,
  • “alkoxy” and “alkoxy*” each, independently of one another, denote a straight-chain alkoxy group having 1 to 6 C atoms.

Optionally, the LC medium comprises one or more compounds of the Formula B1-1A and/or B1-2A:

• • in which
  • (O) denotes O or a single bond,
  • R^IIIA denotes alkyl or alkenyl having up to 7 C atoms or a group Cy-C_mH_2m+1—,
  • m and n are, identically or differently, 0, 1, 2, 3, 4, 5 or 6, preferably 1, 2 or 3, very preferably 1,
  • Cy denotes a cycloaliphatic group having 3, 4 or 5 ring atoms, which is optionally substituted with alkyl or alkenyl each having up to 3 C atoms, or with halogen or CN, and preferably denotes cyclopropyl, cyclobutyl or cyclopentyl.

The compounds of the Formulae B1-1A and/or B1-2A are contained in the medium either alternatively or in addition to the compounds of the Formulae B1-1 and B1-2, preferably additionally.

Preferred compounds of the Formulae B1-1A and/or B1-2A are also the following:

• • in which alkoxy denotes a straight-chain alkoxy group having 1 to 6 C atoms or alternatively —(CH₂)_nF in which n is 2, 3, 4, or 5, preferably C₂H₄F.

The proportion of the compounds of the Formula B1 or its subformulae in the LC medium is preferably from 1 to 20%, very preferably from 1 to 15% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of the Formula B1 or its subformulae.

In a preferred embodiment of the present invention, the LC medium may comprise one or more compounds of the Formula B2-2

• • in which
  • R¹, R³ identically or differently, denote H, an alkyl or alkoxy group having 1 to 6 C atoms, in which one or more CH₂ groups in these groups are optionally replaced, independently of one another, by —C≡C—, —CF₂O—, —OCF₂—, —CH═CH—,

• •  —O—, —CO—O— or —O—CO— in such a way that atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by halogen.

The compounds of the Formula B2-2 are preferably selected from the group of compounds of the Formulae B2-2-1 to B2-2-10:

• • in which R³ denotes alkyl having 1 to 6 C-atoms, preferably ethyl, n-propyl or n-butyl, or alternatively cyclopropylmethyl, cyclobutylmethyl or cyclopentylmethyl or alternatively —(CH₂)_nF in which n is 2, 3, 4, or 5, preferably C₂H₄F.

Particularly preferred compounds of the Formula B2 are selected from the following subformulae:

The proportion of the compounds of the Formula B2 or its subformulae in the LC medium is preferably from 1 to 20%, very preferably from 1 to 15% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of the Formula B2 or its subformulae.

Preferred compounds of the Formula B3 are selected from the following subformulae:

• • wherein R¹ has one of the meanings given in the Formula B3 and preferably denotes straight-chain alkyl having 1 to 6 C atoms, very preferably methyl, ethyl, propyl, butyl, pentyl or hexyl, more preferably ethyl or propyl, most preferably propyl, and X¹ has one of the meanings given in the Formula B3 and preferably denotes CF₃ or OCF₃.

Preferred compounds of the Formula B3 are selected from the following subformulae:

• • wherein R¹ has one of the meanings given in the Formula B3 and preferably denotes straight-chain alkyl having 1 to 6 C atoms, very preferably methyl, ethyl, propyl, butyl, pentyl or hexyl, more preferably ethyl or propyl, most preferably propyl.

Most preferred are compounds of the Formulae B3-1-1 and B3-2-2.

In a preferred embodiment, the LC medium contains one or more compounds of the Formula B or its subformulae B1, B2, B3, B1-1, B1-2, B2-1, B2-2, B2-3, B3-1, B3-2, B3-1-1, B3-1-2, B3-2-1 and B3-2-2 wherein the dibenzofuran or dibenzothiophene group is substituted by a methyl or methoxy group, preferably by a methyl group, preferably in p-position to the substituent F, very preferably in p-position to the substituent F (i.e. in m-position to the terminal group R² or X¹).

The proportion of the compounds of the Formula B3 or its subformulae in the LC medium is preferably from 1 to 20%, very preferably from 1 to 10% by weight.

Preferably, the LC medium contains 1, 2 or 3 compounds of the Formula B3 or its subformulae.

Preferably, the total proportion of compounds of the Formula Y and B or their subformulae in the LC medium is from 2 to 25%, very preferably from 3 to 20% by weight.

Further preferred LC media are selected from the following preferred embodiments, including any combination thereof:

• • a compound of the Formula I in combination with a compound of the Formula ST, H and Z1 to Z7
  • a compound of the Formula I in combination with a compound of the Formula ST, Z1 to Z7 and II and/or III
  • a compound of the Formula I in combination with a compound of the Formula ST, LP1, IV to VIII and a compound of the Formula Z1 and Z4
  • a compound of the Formula I in combination with a compound of the Formula LP1 and/or LP2
  • a compound of the Formula I in combination with a compound of the Formula XXX and/or XXIX
  • a compound of the Formula I in combination with a compound of the Formula IVb-1
  • a compound of the Formula I in combination with a compound of the Formula IVc-1
  • a compound of the Formula I in combination with a compound of the Formula XXXV
  • a compound of the Formula I in combination with a compound of the Formula XIVc-1
  • a compound of the Formula I in combination with a compound of the Formula XIIa-1
  • a compound of the Formula I in combination with a compound of the Formula XVIc
  • a compound of the Formula I in combination with a compound of the Formula VIb
  • a compound of the Formula I in combination with a compound of the Formula XXVIIIa
  • The LC medium comprises one or more compounds of the Formula I or its subformulae, ST and, optionally, H, II and/or III and one or more compounds selected from the group consisting of the Formulae Z1, Z2, Z3, Z4, Z5, V, VI, VII, VIII, XIV, XV, XVI, XVIIa, XVIIb, XVIIc, XVIII, XIX, XX, XXI, XXIII, XXIV, XXV, XXVI, XXVII, XXVIII, XXIX, XXX, XXX-1, XXX-2, XXX-3, XXXII, XXXIII and S and their subformulae.
  • The LC medium comprises one or more compounds of the Formulae I or its subformulae and ST and/or H, II and/or III and one or more compounds selected from the group consisting of the Formulae Z1, Z2, Z3, Z4, Z5, IV, VI, XII, XIV, XVI, XVIIa, XVIIb, XVIIc, XX, LP1-1, XXIII, XXIX and S and their subformulae.
  • The LC medium comprises one or more compounds selected from the group consisting of the Formula II-1, 11-2 and 11-3, very preferably from the Formula II-1 and 11-2. The individual concentration of each of these compounds is preferably from 2 to 15% by weight. The total concentration of these compounds is preferably from 5 to 25% by weight.
  • The LC medium comprises one or more compounds selected from the group consisting of the Formula III-1, 111-4, 111-6, 111-16, 111-19 and 111-20, very preferably from the group consisting of the Formula III-1, 111-6, 111-16 and 111-20. The individual concentration of each of these compounds is preferably from 2 to 15% by weight. The total concentration of these compounds is preferably from 5 to 30% by weight.
  • The LC medium comprises one or more compounds of the Formula IV, preferably selected from the Formula Va or IVc, very preferably from the Formula IVa-1 or IVc-1, most preferably of the Formula IVc-1. The individual concentration of each of these compounds is preferably from 2 to 15% by weight. The total concentration of these compounds is preferably from 5 to 20% by weight.
  • The LC medium comprises one or more compounds of the Formula VI, preferably selected from the Formula VIb. The individual concentration of each of these compounds is preferably from 1 to 20% by weight. The total concentration of these compounds is preferably from 5 to 20% by weight.
  • The LC medium comprises one or more compounds of the Formula Z1, preferably selected from the Formula Z1-1. The total concentration of these compounds is preferably from 1 to 60% by weight, more preferably 5 to 50% by weight.
  • The LC medium comprises one or more compounds of the Formula Z2, preferably selected from the Formulae Z2-1 and Z2-2. The total concentration of these compounds is preferably from 2 to 35%, very preferably from 3 to 25% by weight.
  • The LC medium comprises from 5 to 20% by weight of compounds of the Formula Z3, preferably of the Formula Z3-1.
  • The LC medium comprises from 5 to 20% by weight of compounds of the Formula Z4, preferably of the Formula Z4-1.
  • The LC medium comprises from 10 to 65%, very preferably from 20 to 60% by weight of compounds of Formula Z5.
  • The LC medium comprises one or more compounds of the Formula LP1-1, preferably of the Formula LP1-1a, very preferably of the Formula LP1-1a. The concentration of these compounds is preferably from 2 to 15% by weight.
  • The LC medium comprises one or more compounds of the Formula XII, preferably of the Formula XIIa or XIIb, very preferably of the Formula XIIa, most preferably of the Formula XIIa-1. The concentration of these compounds is preferably from 2 to 15% by weight.
  • The LC medium comprises from 1 to 15% by weight of compounds of the Formula XIIb.
  • The LC medium comprises one or more compounds of the Formula XIV, preferably of the Formula XIVd, very preferably of the Formula XIVd-1. The concentration of these compounds is preferably from 2 to 10% by weight.
  • The LC medium comprises one or more compounds of the Formula XVIb, preferably of the Formula XVIb-1, XVIb-2 and/or XVIb-3. The concentration of these compounds is preferably from 2 to 15% by weight.
  • The LC medium comprises one or more compounds of the Formula XVIc, preferably of the Formula XVIc-1, XVIc-2 and/or XVIc-3. The concentration of these compounds is preferably from 2 to 20% by weight.
  • The LC medium comprises one or more compounds selected from the group consisting of the Formulae XVIIa, XVIIb and XVIIc, very preferably of the Formula XVIIa wherein L is H and of the Formula XVIIb wherein L is F. The total concentration of these compounds is preferably from 0.5 to 5% by weight.
  • The LC medium comprises one or more compounds of the Formula XX, preferably of the Formula XXa. The concentration of these compounds is preferably from 2 to 10% by weight.
  • The LC medium comprises one or more compounds of the Formula XXI, preferably of the Formula XXIa. The concentration of these compounds is preferably from 2 to 10% by weight.
  • The LC medium comprises one or more compounds of the Formula XXIII, preferably of the Formula XXIIIa. The concentration of these compounds is preferably from 0.5 to 5% by weight.
  • The LC medium comprises one or more compounds of the Formula XXIX, preferably of the Formula XXIXa. The concentration of these compounds is preferably from 2 to 10% by weight.
  • The LC medium comprises one or more compounds of the Formula XXX. The concentration of these compounds is preferably from 2 to 10% by weight.
  • The LC medium comprises one or more compounds of the Formula XII. The concentration of these compounds is preferably from 2 to 10% by weight.
  • The LC medium comprises one or more compounds of the Formula I, ST, H, II and/or III, one or more compounds selected from the group consisting of the Formulae Z1, Z2 and Z3 or their subformulae, one or more compounds selected from the group consisting of the Formula XIV, one or more compounds selected from the group consisting of the Formulae IV, VI, XX, XXIII and XXIX or their subformulae, and one or more compounds selected from the group consisting of the Formulae XVI, XVIIa, XVIIb, XVIIc or their subformulae.
  • The LC medium comprises one or more compounds of Formula I, ST, II and/or III, one or more compounds selected from the group consisting of the Formulae Z1, Z2, Z3, Z4 and Z5 or their subformulae, one or more compounds selected from the group consisting of the Formula XIVd or their subformulae, one or more compounds selected from the group consisting of the Formulae IVc, VIb, XXa, XXIIIa and XXIXa or their subformulae, and one or more compounds selected from the group consisting of the Formulae LP1-1b, XVIb, XVIc, XVIIa, XVIIb, XVIIc or their subformulae.
  • The LC medium comprises one or more compounds of the Formula I, ST, II and/or III, one or more compounds selected from the group consisting of the Formulae Z1, Z2 and Z3 or their subformulae, one or more compounds of the Formula Y, preferably selected from the group consisting of the Formulae Y1 and Y2, one or more compounds selected from the group consisting of the Formula XIV, one or more compounds selected from the group consisting of the Formulae II, III, IV, VI, XX, XXIII and XXIX or their subformulae, and one or more compounds selected from the group consisting of the Formulae XVI, XVIIa, XVIIb, XVIIc or their subformulae.
  • The LC medium comprises one or more compounds of the Formula I one or more compounds selected from the group consisting of the Formulae Z1, Z2, Z3, Z4 and Z5 or their subformulae, one or more compounds of Formula B, preferably selected from the group consisting of the Formulae B1, B2 and B3, one or more compounds of the Formula XIVd or their subformulae, one or more compounds selected from the group consisting of the Formulae II, III, IVc, VIb, XXa, XXIIIa and XXIXa or their subformulae, and one or more compounds selected from the group consisting of the Formulae LP1-1 b, XVIb, XVIc, XVIIa, XVIIb, XVIIc or their subformulae.
  • Besides the compounds of the Formula I, the LC medium comprises further compounds selected from the group of the compounds of the Formula Z1, Z2, Z3, IV, LP1-1, XIV, XVI, XVIIa, XVIIb, XVIIc, XXI, XXIII, XXIX, XXX and XXIV or their subformulae.
  • Besides the compounds of the Formula I, the LC medium comprises further compounds selected from the group of the compounds of the Formulae Z1, Z2, Z3, IV, XIV, XVI, XVIIa, XVIIb, XVIIc, XXI, XXIII, XXIX, XXX and XXIV or their subformulae.
  • The proportion of compounds of the Formula I or its subformulae in the LC medium is from 1 to 30%, very preferably from 2 to 25%, most preferably from 2 to 20% by weight.
  • The proportion of compounds of the Formulae Z1, Z2, Z3, Z4 and Z5 or their subformulae in the LC medium as a whole is from 10 to 65%, very preferably from 20 to 60% by weight.
  • The proportion of compounds of the Formula Y or its subformulae in the LC medium as a whole is from 0 to 15%, very preferably from 2 to 10% by weight.
  • The proportion of compounds of the Formula B or its subformulae in the LC medium as a whole is from 0 to 15%, very preferably from 2 to 10% by weight.
  • The proportion of compounds of the Formulae II, III, IV—VIII, XVIII-XXIII and XXVII-XXX in the LC medium as a whole is 30 to 60% by weight.
  • The proportion of compounds of the Formulae XIV and XV in the LC medium as a whole is 40 to 70% by weight.
  • The proportion of compounds of the Formulae XIV, XVIIa-c and XXXII in the LC medium as a whole is 0.5 to 15% by weight.

The term “alkyl” or “alkyl” in this application encompasses straight-chain and branched alkyl groups having 1 to 6 carbon atoms, in particular the straight-chain groups methyl, ethyl, propyl, butyl, pentyl and hexyl. Groups having 2 to 5 carbon atoms are generally preferred.

The term “alkenyl” or “alkenyl*” encompasses straight-chain and branched alkenyl groups having 2 to 6 carbon atoms, in particular the straight-chain groups. Preferred alkenyl groups are C_2-7-1E-alkenyl, C₄-C₆-3E-alkenyl, in particular C₂-C₆-1E-alkenyl. Examples of particularly preferred alkenyl groups are vinyl, E-propenyl, 1E-butenyl, 1E-pentenyl, 1E-hexenyl, 3-butenyl, 3E-pentenyl, 3E-hexenyl, 4-pentenyl, 4Z-hexenyl, 4E-hexenyl and 5-hexenyl. Groups having up to 5 carbon atoms are generally preferred, in particular CH₂═CH, CH₃CH═CH.

The term “fluoroalkyl” preferably encompasses straight-chain groups having a terminal fluorine, i.e. fluoromethyl, 2-fluoroethyl, 3-fluoropropyl, 4-fluorobutyl, 5-fluoropentyl, 6-fluorohexyl and 7-fluoroheptyl. However, other positions of the fluorine are not excluded.

The term “oxaalkyl” or “alkoxy” preferably encompasses straight-chain groups of the Formula C_nH_2n+1—O—(CH₂)_m, in which n and m each, independently of one another, denote 1 to 6. m may also denote 0. Preferably, n=1 and m=1 to 6 or m=0 and n=1 to 3. Further preferably the alkoxy or oxaalkyl group can also contain one or more further O atoms such that oxygen atoms are not directly linked to one another.

Through a suitable choice of the meanings of R⁰ and X⁰ in Formulae II and III, the addressing times, the threshold voltage, the steepness of the transmission characteristic lines, etc., can be modified in the desired manner. For example, 1E-alkenyl groups, 3E-alkenyl groups, 2E-alkenyloxy groups and the like generally result in shorter addressing times, improved nematic tendencies and a higher ratio between the elastic constants K₃ (bend) and K₁ (splay) compared with alkyl and alkoxy groups. 4-Alkenyl groups, 3-alkenyl groups and the like generally give lower threshold voltages and lower values of K₃/K₁ compared with alkyl and alkoxy groups. The LC media according to the invention are distinguished, in particular, by high Δε values and thus have significantly faster response times than the LC media from the prior art.

The optimum mixing ratio of the compounds of the above-mentioned formulae depends substantially on the desired properties, on the choice of the components of the above-mentioned formulae and on the choice of any further components that may be present.

Suitable mixing ratios within the range indicated above can easily be determined from case to case.

The total amount of compounds of the above-mentioned formulae in the LC media according to the invention is not crucial. The LC media can therefore comprise one or more further components for the purposes of optimisation of various properties.

However, the observed effect on the desired improvement in the properties of the medium is generally greater, the higher the total concentration of compounds of the above-mentioned formulae.

In a particularly preferred embodiment, the LC media according to the invention comprise compounds of the Formulae IV to VIII (preferably IV and V) in which X⁰ denotes F, OCF₃, OCHF₂, OCH═CF₂, OCF=CF₂ or OCF₂—CF₂H. A favourable synergistic action with the compounds of the Formula I, an antioxidant and, if present, a light stabilizer results in particularly advantageous properties. In particular, LC media comprising compounds of the Formula I, an antioxidant, a light stabilizer, II and/or III are distinguished by their low threshold voltage.

The individual compounds of the above-mentioned formulae and the subformulae thereof which can be used in the LC media according to the invention are either known or can be prepared analogously to the known compounds.

The invention also relates to a process for the preparation of a LC medium as described above and below, by mixing one or more compounds of the Formula I, an antioxidant, a light stabilizer and one or more compounds selected from the group consisting of the Formulae II, III, Z1, Z2, Z3, Z4, IV, VI, XIV, XVI, XVIIa, XVIIb, XVIIc, XX, XXIII, XXIX.

The LC medium of the present invention may optionally comprise one or more polymerisable compounds. The polymerisable compounds are preferably selected from the Formula M

R^a—B¹—(Z^b—B²)_m—R^b  M

• • in which the individual substituents, on each occurrence identically or differently, and each, independently of one another, have the following meaning:
  • NCSOCNR^a and R^b P, P-Sp-, H, F, Cl, Br, I, —CN, —NO₂, —NCO, -, -, —SCN, SF₅ or straight-chain or branched alkyl having 1 to 25 C atoms, in which, in addition, one or more non-adjacent CH₂ groups may each be replaced, independently of one another, by —C(R⁰)═C(R⁰⁰)—, —C═C—,
  • NCSOCN—N(R⁰⁰)—, —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O— in such a way that O and/or S atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by F, C, Br, I, CN, P or P-Sp-, where, if B¹ and/or B² contain a saturated C atom, R^a and/or R^b may also denote a group which is spiro-linked to this saturated C atom,
  • wherein at least one of the substituents R^a and R^b denotes or contains a group P or P-Sp-,
  • P a polymerisable group,
  • Sp a spacer group or a single bond,
  • B¹ and B² an aromatic, heteroaromatic, alicyclic or heterocyclic group, preferably having 4 to 25 ring atoms, which may also contain fused rings, and which is unsubstituted, or mono- or polysubstituted by L,
  • Z^b —O—, —S—, —CO—, —CO—O—, —OCO—, —O—CO—O—, —OCH₂—, —CH₂O—, —SCH₂—,
    • —CH₂S—, —CF₂O—, —OCF₂—, —CF₂S—, —SCF₂—, —(CH₂)_n1—, —CF₂CH₂—, —CH₂CF₂—, —(CF₂)_n1—, —CH═CH—, —CF=CF—, —C≡C—, —CH═CH—COO—, —OCO—CH═CH—, CR⁰R⁰⁰ or a single bond,
  • R⁰ and R⁰⁰ each, independently of one another, denote H or alkyl having 1 to 12 C atoms,
  • m denotes 0, 1, 2, 3 or 4,
  • n1 denotes 1, 2, 3 or 4,
  • L P, P-Sp-, OH, CH₂OH, F, Cl, Br, I, —CN, —NO₂, —NCO, —NCS, —OCN, —SCN, —C(═O)N(R^x)₂, —C(═O)Y¹, —C(═O)R^x, —N(R^x)₂, optionally substituted silyl, optionally substituted aryl having 6 to 20 C atoms, or straight-chain or branched alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 25 C atoms, in which, in addition, one or more H atoms may be replaced by F, C, P or P-Sp-,
  • P and Sp have the meanings indicated in the Formula M above,
  • Y¹ denotes halogen,
  • R^x denotes P, P-Sp-, H, halogen, straight-chain, branched or cyclic alkyl having 1 to 25 C atoms, in which, in addition, one or more non-adjacent CH₂ groups may be replaced by —O—, —S—, —CO—, —CO—O—,
  • —O—CO—, —O—CO—O— in such a way that O and/or S atoms are not linked directly to one another, and in which, in addition, one or more H atoms may be replaced by F, C, P or P-Sp-, an optionally substituted aryl or aryloxy group having 6 to 40 C atoms, or an optionally substituted heteroaryl or heteroaryloxy group having 2 to 40 C atoms.

Further preferably, the LC media according to the present invention comprise one or more polymerisable compounds selected from Table H below.

Preferably, the proportion of polymerisable compounds in the LC medium, preferably selected from the Formula M and Table H, is from 0.01 to 5%, very preferably from 0.05 to 1%, most preferably from 0.1 to 0.5%.

It was observed that the addition of one or more polymerisable compounds to the LC medium, like those selected from the Formula M and Table H, leads to advantageous properties like fast response times. Such a LC medium is especially suitable for use in PSA displays where it shows low image sticking, a quick and complete polymerisation, the quick generation of a low pretilt angle which is stable after UV exposure, a high reliability, high VHR value after UV exposure, and a high birefringence. By appropriate selection of the polymerisable compounds it is possible to increase the absorption of the LC medium at longer UV wavelengths, so that it is possible to use such longer UV wavelengths for polymerisation, which is advantageous for the display manufacturing process.

The polymerisable group P is a group which is suitable for a polymerisation reaction, such as, for example, free-radical or ionic chain polymerisation, polyaddition or polycondensation, or for a polymer-analogous reaction, for example addition or condensation onto a main polymer chain. Particular preference is given to groups for chain polymerisation, in particular those containing a C═C double bond or —C≡C— triple bond, and groups which are suitable for polymerisation with ring opening, such as, for example, oxetane or epoxide groups.

Preferred groups P are selected from the group consisting of CH₂═CW¹—CO—O—, CH₂=CW¹—CO—,

CH₂=CW²—(O)_k3—, CW¹═CH—CO—(O)_k3—, CW¹═CH—CO—NH—, CH₂=CW¹—CO—NH—, CH₃—CH═CH—O—, (CH₂═CH)₂CH—OCO—, (CH₂═CH—CH₂)₂CH—OCO—, (CH₂═CH)₂CH—O—, (CH₂═CH—CH₂)₂N—, (CH₂═CH—CH₂)₂N—CO—, HO—CW²W³—, HS—CW²W³—, HW²N—, HO—CW²W³—NH—, CH₂=CW¹—CO—NH—, CH₂═CH—(COO)_k1-Phe-(O)_k2—, CH₂═CH—(CO)_k1-Phe-(O)_k2—, Phe-CH═CH—, HOOC—, OCN— and W⁴W⁵W⁶Si—, in which W¹ denotes H, F, Cl, CN, CF₃, phenyl or alkyl having 1 to 5 C atoms, in particular H, F, C₁ or CH₃, W² and W³ each, independently of one another, denote H or alkyl having 1 to 5 C atoms, in particular H, methyl, ethyl or n-propyl, W⁴, W⁵ and W⁶ each, independently of one another, denote Cl, oxaalkyl or oxacarbonylalkyl having 1 to 5 C atoms, W⁷ and W⁸ each, independently of one another, denote H, Cl or alkyl having 1 to 5 C atoms, Phe denotes 1,4-phenylene, which is optionally substituted by one or more substituents L as defined for the Formula M above which are other than P-Sp-, k₁, k₂ and k₃ each, independently of one another, denote 0 or 1, k₃ preferably denotes 1, and k₄ denotes an integer from 1 to 10.

Very preferred groups P are selected from the group consisting of CH₂═CW¹—CO—O—, CH₂=CW¹—CO—,

CH₂=CW²—O—, CH═CW²—, CW¹═CH—CO—(O)_k3—, CW¹═CH—CO—NH—, CH₂=CW¹—CO—NH—, (CH₂═CH)₂CH—OCO—, (CH₂═CH—CH₂)₂CH—OCO—, (CH₂═CH)₂CH—O—, (CH₂═CH—CH₂)₂N—, (CH₂═CH—CH₂)₂N—CO—, CH₂=CW¹—CO—NH—, CH₂═CH—(COO)_k1-Phe-(O)_k2—, CH₂═CH—(CO)_k1-Phe-(O)_k2—, Phe-CH═CH— and W⁴W⁵W⁶Si—, in which W¹ denotes H, F, Cl, CN, CF₃, phenyl or alkyl having 1 to 5 C atoms, in particular H, F, Cl or CH₃, W² and W³ each, independently of one another, denote H or alkyl having 1 to 5 C atoms, in particular H, methyl, ethyl or n-propyl, W⁴, W⁵ and W⁶ each, independently of one another, denote Cl, oxaalkyl or oxacarbonylalkyl having 1 to 5 C atoms, W⁷ and W⁸ each, independently of one another, denote H, C or alkyl having 1 to 5 C atoms, Phe denotes 1,4-phenylene, k₁, k₂ and k₃ each, independently of one another, denote 0 or 1, k₃ preferably denotes 1, and k₄ denotes an integer from 1 to 10.

Very particularly preferred groups P are selected from the group consisting of CH₂═CW¹—CO—O—, in particular CH₂═CH—CO—O—, CH₂=C(CH₃)—CO—O— and CH₂=CF—CO—O—, furthermore CH₂═CH—O—, (CH₂═CH)₂CH—O—CO—, (CH₂═CH)₂CH—O—,

Further preferred polymerisable groups P are selected from the group consisting of vinyloxy, acrylate, methacrylate, fluoroacrylate, chloroacrylate, oxetane and epoxide, most preferably from acrylate and methacrylate.

If Sp is different from a single bond, it is preferably of the Formula Sp″-X″, so that the respective substituent P-Sp- conforms to the Formula P-Sp″-X″—, wherein

• • Sp″ denotes alkylene having 1 to 20, preferably 1 to 12, C atoms, which is optionally mono- or polysubstituted by F, C, Br, I or CN and in which, in addition, one or more non-adjacent CH₂ groups may each be replaced, independently of one another, by —O—, —S—, —NH—, —N(R⁰)—, —Si(R⁰R⁰⁰)—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —S—CO—, —CO—S—, —N(R⁰⁰)—CO—O—, —O—CO—N(R⁰)—, —N(R⁰)—CO—N(R⁰⁰)—, —CH═CH— or —C═C— in such a way that O and/or S atoms are not linked directly to one another,
  • X″ denotes —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CO—N(R⁰)—, —N(R⁰)—CO—, —N(R⁰)—CO—N(R⁰⁰)—, —OCH₂—, —CH₂O—, —SCH₂—, —CH₂S—, —CF₂O—, —OCF₂—, —CF₂S—, —SCF₂—, —CF₂CH₂—, —CH₂CF₂—, —CF₂CF₂—, —CH═N—, —N═CH—, —N═N—, —CH═CR⁰—, —CY²=CY³—, —C≡C—, —CH═CH—CO—O—, —O—CO—CH═CH— or a single bond,
  • R⁰ and R⁰⁰ each, independently of one another, denote H or alkyl having 1 to 20 C atoms, and
  • Y² and Y³ each, independently of one another, denote H, F, Cl or CN.
  • X″ is preferably —O—, —S—, —CO—, —COO—, —OCO—, —O—COO—, —CO—NR⁰—, —NR⁰—CO—, —NR⁰—CO—NR⁰⁰— or a single bond.

Typical spacer groups Sp and -Sp″-X″— are, for example, —(CH₂)_p1—, —(CH₂CH₂O)_g1—CH₂CH₂—, —CH₂CH₂—S—CH₂CH₂—, —CH₂CH₂—NH—CH₂CH₂— or —(SiR⁰R⁰⁰—O)_p1—, in which p1 is an integer from 1 to 12, q1 is an integer from 1 to 3, and R⁰ and R⁰⁰ have the meanings indicated in the Formula M above.

Particularly preferred groups Sp and -Sp″-X″— are —(CH₂)_p1—, —(CH₂)_p1—O—, —(CH₂)_p1—O—CO—, —(CH₂)_p1—CO—O—, —(CH₂)_p1—O—CO—O—, in which p1 and q1 have the meanings indicated above.

Particularly preferred groups Sp″ are, in each case straight-chain, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, octadecylene, ethyleneoxyethylene, methyleneoxybutylene, ethylenethioethylene, ethylene-N-methyliminoethylene, 1-methylalkylene, ethenylene, propenylene and butenylene.

For the production of PSA displays, the polymerisable compounds contained in the LC medium are polymerised or crosslinked (if one compound contains two or more polymerisable groups) by in-situ polymerisation in the LC medium between the substrates of the LC display, optionally while a voltage is applied to the electrodes.

The structure of the PSA displays according to the invention corresponds to the usual geometry for PSA displays, as described in the prior art cited at the outset. Geometries without protrusions are preferred, in particular those in which, in addition, the electrode on the colour filter side is unstructured and only the electrode on the TFT side has slots. Particularly suitable and preferred electrode structures for PS-VA displays are described, for example, in US 2006/0066793 A1.

The combination of compounds of the preferred embodiments mentioned above with the polymerised compounds described above causes low threshold voltages, low rotational viscosities and very good low-temperature stabilities in the LC media according to the invention at the same time as constantly high clearing points and high VHR values.

The use of LC media containing polymerisable compounds allows the rapid establishment of a particularly low pretilt angle in PSA displays. In particular, the LC media exhibit significantly shortened response times, in particular also the grey-shade response times, in PSA displays compared with the media from the prior art.

Preference is generally given to LC media which have a nematic LC phase, and preferably have no chiral liquid crystal phase.

The invention also relates to the use of a LC medium according to the present invention as described above and below for electro-optical purposes, in particular for the use is in shutter glasses, for 3D applications, in TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-FFS, positive VA and positive PS-VA displays, and to electro-optical displays, in particular of the aforementioned types, containing a LC medium according to the present invention as described above and below, in particular a TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-FFS, positive VA (vertically aligned) or positive PS-VA display.

The invention also relates to electro-optical displays, such as, for example, STN or matrix LC (MLC) displays, having two plane-parallel outer plates, which, together with a frame, form a cell, integrated non-linear elements for switching individual pixels on the outer plates, and a nematic LC medium having positive dielectric anisotropy and high specific resistance located in the cell, wherein the nematic LC medium is a LC medium according to the present invention as described above and below.

The LC media according to the invention enable a significant broadening of the available parameter latitude. The achievable combinations of clearing point, rotational viscosity, thermal- and UV stability and high optical anisotropy are far superior to previous materials from the prior art.

In particular, the combination of compounds of the Formula I with at least one antioxidant, at least one light stabilizer and, optionally, with compounds selected from the Formulae II-XXXII or their subformulae, leads to LC media which show a reduced short-term image sticking and reduced long-term image sticking as well as low rotational viscosity resulting in fast response times. This enables fast energy saving LC displays, especially of the FFS, HB-FFS, XB-FFS and IPS mode.

The LC media according to the invention are suitable for mobile applications and TFT applications, such as, for example, mobile telephones and PDAs. Furthermore, the LC media according to the invention are particularly suitably for use in FFS, HB-FFS, XB-FFS and IPS displays based on dielectrically positive liquid crystals.

The LC media according to the present invention, while retaining the nematic phase down to −20° C. and preferably down to −30° C., particularly preferably down to −40° C., and the clearing point ≥75° C., preferably 80° C., at the same time allow rotational viscosities γ₁ of ≤120 mPa·s, particularly preferably ≤100 mPa-s, to be achieved, enabling excellent MLC displays having fast response times to be achieved. The rotational viscosities are determined at 20° C.

The dielectric anisotropy Δε of the LC media according to the invention at 20° C. and 1 kHz is preferably ≥+1.5, very preferably from +3 to +18, most preferred from +5 to +15.

The birefringence Δn of the LC media according to the invention at 20° C. is preferably from 0.08 to 0.2, very preferably from 0.09 to 0.15.

The rotational viscosity γ₁ of the LC media according to the invention is preferably ≤120 mPa·s, more preferably ≤110 mPa·s, very preferably 90 mPa·s.

The ratio γ₁/K₁ (wherein γ₁ is the rotational viscosity and K₁ is the elastic constant for splay deformation) of the LC media according to the invention is preferably 7 mPa·s/pN, very preferably 6 mPa·s/pN, most preferably ≤5.5 mPa·s/pN.

The average elasticity constant ratio Kav of the LC media according to the invention is preferably at least 14.0 pN, very preferably at least 15.0 pN, most preferably at least 16.0 pN. Kav can be calculated according to the following formula: Kav=(K₁+K₂+K₃)/3≈(K₁+1/2%2*K₁+K₃)/3.

The nematic phase range of the LC media according to the invention preferably has a width of at least 90° C., more preferably of at least 100° C., in particular at least 110° C. This range preferably extends at least from −25° C. to +90° C.

It goes without saying that, through a suitable choice of the components of the LC media according to the invention, it is also possible for higher clearing points (for example above 100° C.) to be achieved at higher threshold voltages or lower clearing points to be achieved at lower threshold voltages with retention of the other advantageous properties. At viscosities correspondingly increased only slightly, it is likewise possible to obtain LC media having a higher Δε and thus low thresholds. The MLC displays according to the invention preferably operate at the first Gooch and Tarry transmission minimum [C. H. Gooch and H. A. Tarry, Electron. Lett. 10, 2-4, 1974; C. H. Gooch and H. A. Tarry, Appl. Phys., Vol. 8, 1575-1584, 1975], where, besides particularly favourable electro-optical properties, such as, for example, high steepness of the characteristic line and low angle dependence of the contrast (German patent 30 22 818), lower dielectric anisotropy is sufficient at the same threshold voltage as in an analogous display at the second minimum. This enables significantly higher specific resistance values to be achieved using the LC media according to the invention at the first minimum than in the case of LC media comprising cyano compounds. Through a suitable choice of the individual components and their proportions by weight, the person skilled in the art is able to set the birefringence necessary for a pre-specified layer thickness of the MLC display using simple routine methods.

Measurements of the voltage holding ratio (VHR) [S. Matsumoto et al., Liquid Crystals 5, 1320 (1989); K. Niwa et al., Proc. SID Conference, San Francisco, June 1984, p. 304 (1984); G. Weber et al., Liquid Crystals 5, 1381 (1989)]have shown that LC media according to the invention exhibit a significantly smaller decrease in the VHR on UV exposure than analogous LC media comprising cyanophenylcyclohexanes of the Formula

or esters of the Formula.

The light stability and UV stability of the LC media according to the invention are considerably better, i.e. they exhibit a significantly smaller decrease in the HR on exposure to light, heat or UV.

The construction of the MLC display according to the invention from polarisers, electrode base plates and surface-treated electrodes corresponds to the usual design for displays of this type. The term usual design is broadly drawn here and also encompasses all derivatives and modifications of the MLC display, in particular including matrix display elements based on poly-Si TFTs or MIM.

A significant difference between the displays according to the invention and the hitherto conventional displays based on the twisted nematic cell consists, however, in the choice of the LC parameters of the LC layer.

The LC media which can be used in accordance with the invention are prepared in a manner conventional per se, for example by mixing compounds of Formula I with one or more compounds of the Formulae II-XXXII or with further LC compounds and/or additives. In general, the desired amount of the components used in lesser amount is dissolved in the components making up the principal constituent, advantageously at elevated temperature. It is also possible to mix solutions of the components in an organic solvent, for example in acetone, chloroform or methanol, and to remove the solvent again, for example by distillation, after thor-ough mixing.

The LC media may also comprise further additives known to the person skilled in the art and described in the literature, such as, for example, polymerisation initiators, inhibitors, surface-active substances, microparticles, free-radical scaven-gers, nanoparticles, etc. For example, 0 to 15% of pleochroic dyes or chiral dopants or initiators like Irgacure®651 or Irgacure®907 can be added. Suitable stabilisers and dopants are mentioned below in Tables F and G. In a preferred embodiment, the LC medium comprises one or more stabilisers selected from Table G. Preferably, the proportion of antioxidants and light stabilisers, like those of the Formula ST and H, as described above or listed in Table G, in the LC medium is from 10 to 2000 ppm, very preferably from 30 to 1000 ppm.

Furthermore, it is possible to add to the LC media, for example, 0 to 15% by weight of pleochroic dyes, furthermore nanoparticles, conductive salts, preferably ethyldimethyldodecylammonium 4-hexoxybenzoate, tetrabutylammonium tetraphenylborate or complex salts of crown ethers (cf., for example, Haller et al., Mol. Cryst. Liq. Cryst. 24, 249-258 (1973)), for improving the conductivity, or substances for modifying the dielectric anisotropy, the viscosity and/or the alignment of the nematic phases. Substances of this type are described, for example, in DE-A 22 09 127, 22 40 864, 23 21 632, 23 38 281, 24 50 088, 26 37 430 and 28 53 728.

For the present invention and in the following examples, the structures of the LC compounds are indicated by means of acronyms, with the transformation into chemical formulae taking place in accordance with Tables A to C below. All substituents C_mH_2m+1, C_nH_2n+1, and C_lH_2l+1 or C_mH_2m−1, C_nH_2n−1 and C_lH_2l−1 are straight-chain alkyl groups or alkylene groups, in each case having n, m and I C atoms respectively. Preferably, n, m and l are independently of each other 1, 2, 3, 4, 5, 6, or 7. Table A shows the codes for the ring elements of the nuclei of the compound, Table B lists the bridging units, and Table C lists the meanings of the symbols for the left- and right-hand end groups of the molecules. The acronyms are composed of the codes for the ring elements with optional linking groups, followed by a first hyphen and the codes for the left-hand end group, and a second hyphen and the codes for the right-hand end group. Table D shows illustrative structures of compounds together with their respective abbreviations.

TABLE A
Ring elements
C
D         Dl
A         Al
P
G         Gl
U         Ul
Y         U(1)
P(F, Cl)Y P(Cl, F)Y
np
n3f       nN3fl
th        thl
tH2f      tH2fl
o2f       o2fl
dh
B         B(S)
O         S
K         Kl
L         Ll
F         Fl
Bh        Bh(S)
Bf        Bf(S)
Bfi       Bfi(S)

TABLE B
Bridging units
	E	—CH2—CH2—
	V	—CH═CH—
	T	—C≡C—
	W	—CF2—CF2—
	B	—CF═CF—
	Z	—CO—O—	ZI	—O—CO—
	X	—CF═CH—	XI	—CH═CF—
	O	—CH2—O—	OI	—O—CH2—
	Q	—CF2—O—	QI	—O—CF2—

TABLE C
End groups
On the left individually or in	On the right individually or in
combination	combination
-n-	CnH2n+1—	-n	—CnH2n+1
-nO—	CnH2n+1—O—	—On	—O—CnH2n+1
—V—	CH2═CH—	—V	—CH═CH2
-nV—	CnH2n+1—CH═CH—	-nV	—CnH2n—CH═CH2
—Vn-	CH2═CH—CnH2n—	—Vn	—CH═CH—CnH2n+1
-nVm-	CnH2n+1—CH═CH—	-nVm	—CnH2n—CH═CH—
	CmH2m—		CmH2m+1
—N—	N≡C—	—N	—C≡N
—S—	S═C═N—	—S	—N═C═S
—F—	F—	—F	—F
—CL—	Cl—	—CL	—Cl
—M—	CFH2—	—M	—CFH2
—D—	CF2H—	—D	—CF2H
—T—	CF3—	—T	—CF3
—MO—	CFH2O—	—OM	—OCFH2
—DO—	CF2HO—	—OD	—OCF2H
—TO—	CF3O—	—OT	—OCF3
—A—	H—C≡C—	—A	—C≡C—H
-nA—	CnH2n+1—C≡C—	—An	—C≡C—CnH2n+1
—NA—	N≡C—C≡C—	—AN	—C≡C—C≡N
-(cn)-		-(cn)
-(cn)m-		-m(cn)
On the left only in combination	On the right only in combination
- ... n ... -	—CnH2n—	- ... n ...	—CnH2n—
- ... M ... -	—CFH—	- ... M ...	—CFH—
- ... D ... -	—CF2—	- ... D ...	—CF2—
- ...V ... -	—CH═CH—	- ... V ...	—CH═CH—
- ... Z ... -	—CO—O—	- ... Z ...	—CO—O—
- ... Zl ... -	—O—CO—	- ... ZI ...	—O—CO—
- ... K ... -	—CO—	- ... K ...	—CO—
- ... W ... -	—CF═CF—	- ... W ...	—CF═CF—

• • in which n and m are each integers, and the three dots “ . . . ” are placeholders for other abbreviations from this table.

The following abbreviations are used:

• • (n, m, k and l are, independently of one another, each an integer, preferably 1 to 12 preferably 1 to 6, k and l possibly may be also 0 and preferably are 0 to 4, more preferably 0 or 2 and most preferably 2, n preferably is 1, 2, 3, 4 or 5, in the combination “-nO—” it preferably is 1, 2, 3 or 4, preferably 2 or 4, m preferably is 1, 2, 3, 4 or 5, in the combination “-Om” it preferably is 1, 2, 3 or 4, more preferably 2 or 4. The combination “—IVm” preferably is “2V1”.)

Preferred components of the LC medium are shown in Tables D and E.

TABLE D
PYP
PYRP
MEnF•F
MEnm
MEnN
MEnN•F
MEnO•m
MEn•Om
MEnON•F
MEnOOm
MEnOOm•F
MEnS
HP-nN•F
HP-nF•F
HP-nF
HP-nN
BCH
CBC
CCH
CCP
CPTP
CEPTP
ECCP
CECP
EPCH
PCH
CH
PTP
CCPC
CP
BECH
EBCH
CPC
B
FET-nF
CGG
CGU
CFU

TABLE E
In the following formulae, n and m each, independently of one another, denote 0,
1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, in particular 2, 3, 5, furthermore 0, 4, 6.
APU-n-OXF
ACQU-n-F
APUQU-n-F
BCH-n•Fm
CFU-n-F
CBC-nmF
ECCP-nm
CCZU-n-F
PGP-n-m
CGU-n-F
PGP-n-NA
CDUQU-n-F
CLUQU-n-F
CLUQU(1)-n-F
CLP-V-n
CDU-n-F
DCU-n-F
CGG-n-F
CPZG-n-OT
CC-nV-Vm
CCP-Vn-m
CCG-V-F
CCP-nV-m
CC-n-V
CCC-n-m
CCC-n-V
CCQU-n-F
CC-n-Vm
CLUQU-n-F
CPPC-nV-Vm
CCQG-n-F
CQU-n-F
CP-1V-m
CLP-n-T
CLP-n-OT
CP-2V-m
CP-V2-m
Dec-U-n-F
CWCU-n-F
CPGP-n-m
CWCG-n-F
CLU-n-F
CLU-n-F(1)
CCOC-n-m
CPTU-n-F
GPTU-n-F
PQU-n-F
PUQU-n-F
PGU-n-F
CGZP-n-OT
CCGU-n-F
CCQG-n-F
DPGU-n-F
DPGU-n-OT
CUQU-n-F
CCCQU-n-F
CGUQU-n-F
CPGU-n-OT
PYP-nF
CPGU-n-F
CCVC-n-m
CCVC-n-V
CCVC-n-IV
CVCP-1V-OT
GGP-n-Cl
DLGU-n-F
DLGU-n-m
PP-nV-Vm
PP-1-nVm
CWCQU-n-F
PPGU-n-F
PPGU-(c5)-F
PGUQU-n-F
PGUQU-(c5)-F
PGUQU(1)-n-F
GPQU-n-F
MPP-n-F
MUQU-n-F
NUQU-n-F
PGP-n-kVm
PP-n-kVm
PCH-nCl
GP-n-Cl
GGP-n-F
PGIGI-n-F
PGU-n-OXF
CPU-n-OXF
PUS-n-m
PGS-n-m
PGS(1)-n-m
PGS(1)-n-Om
PUS(1)-n-m
PUS(1)-n-Om
PUS-n-Om
PGS-n-Om
PUS-(c5)-m
PGS-(c5)-m
PUS(1)-(c5)-m
PGS(1)-(c5)-m
CCQU-n-F(1)
DUQU-n-F(1)
PUQU-n-F(1)
APUQU-n-F(1)
CDUQU-n-F(1)
CPPQU-n-F(1)
DGUQU-n-F(1)
DPUQU-n-F(1)
PGUQU-n-F(1)
PYP-n-m

Particular preference is given to LC media which, besides the compounds of the Formulae I, an antioxidant and a light stabilizer comprise at least one, two, three, four or more compounds from Table E.

TABLE F
Table F indicates possible dopants which are generally added to the LC media
according to the invention. The LC media preferably comprise 0-10% by weight, in
particular 0.01-5% by weight and particularly preferably 0.01-3% by weight of
dopants.
C 15
CB 15
CM 21
R/S-811
CM 44
CM 45
CM 47
CN
R/S-2011
R/S-3011
R/S-4011
R/S-5011
R/S-1011

TABLE G
Antioxidants and light stabilizers, which can additionally be added, for example, to
the LC media according to the invention in amounts of 0 to 10% by weight, are
mentioned below.
n = 1, 2, 3, 4, 5, 6 or 7
n = 1, 2, 3, 4, 5, 6 or 7
n = 1, 2, 3, 4, 5, 6 or 7
q = 1, 2, 3, 4, 5, 6 or 7
q = 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10

TABLE H
Table H shows illustrative reactive mesogenic compounds (RMs) which can be
used in the LC media in accordance with the present invention.
RM-1
RM-2
RM-3
RM-4
RM-5
RM-6
RM-7
RM-8
RM-9
RM-10
RM-11
RM-12
RM-13
RM-14
RM-15
RM-16
RM-17
RM-18
RM-19
RM-20
RM-21
RM-22
RM-23
RM-24
RM-25
RM-26
RM-27
RM-28
RM-29
RM-30
RM-31
RM-32
RM-33
RM-34
RM-35
RM-36
RM-37
RM-38
RM-39
RM-40
RM-41
RM-42
RM-43
RM-44
RM-45
RM-46
RM-47
RM-48
RM-49
RM-50
RM-51
RM-52
RM-53
RM-54
RM-55
RM-56
RM-57
RM-58
RM-59
RM-60
RM-61
RM-62
RM-63
RM-64
RM-65
RM-66
RM-67
RM-68
RM-69
RM-70
RM-71
RM-72
RM-73
RM-74
RM-75
RM-76
RM-77
RM-78
RM-79
RM-80
RM-81
RM-82
RM-83
RM-84
RM-85
RM-86
RM-87
RM-88
RM-89
RM-90
RM-91
RM-92
RM-93
RM-94
RM-95
RM-96
RM-97
RM-98
RM-99
RM-100
RM-101
RM-102
RM-103
RM-104
RM-105
RM-106
RM-107
RM-108
RM-109
RM-110
RM-111
RM-112
RM-113
RM-114
RM-115
RM-116
RM-117
RM-118
RM-119
RM-120
RM-121
RM-122
RM-123
RM-124
RM-125
RM-126
RM-127
RM-128
RM-129
RM-130
RM-131
RM-132
RM-133
RM-134
RM-135
RM-136
RM-137
RM-138
RM-139
RM-140
RM-141
RM-142
RM-143
RM-144
RM-145
RM-146
RM-147
RM-148
RM-149
RM-150
RM-151
RM-152
RM-153
RM-154
RM-155
RM-156
RM-157
RM-158
RM-159
RM-160
RM-161
RM-162
RM-163
RM-164
RM-165
RM-166
RM-167
RM-168
RM-169
RM-170
RM-171
RM-172
RM-173
RM-174
RM-175
RM-176
RM-177
RM-178
RM-179
RM-180
RM-181
RM-182
RM-183
RM-184
The LC media according to the invention may optionally comprise one or more polymerizable compounds, preferably selected from the polymerizable compounds of the Formulae RM-1 to RM-184. Of these, compounds RM-1, RM-4, RM-8, RM-17, RM-19, RM-35, RM-37, RM-39, RM-40, RM-41, RM-48, RM-52, RM-54, RM-57, RM-58, RM-64, RM-74, RM-76, RM-88, RM-91, RM-102, RM-103, RM-109, RM-116, RM-117, RM-120, RM-121, RM-122, RM-139, RM-140, RM-142, RM-143, RM-145, RM-146, RM-147, RM-149, RM-156 to RM-163, RM-169, RM-170 and RM-171 to RM-184 are particularly preferred.

TABLE I
Table I shows self-alignment additives for vertical alignment which can be used in
LC media for SA-FFS, SA-HB-FFS and SA-XB-FFS displays according to the
present invention:
SA-1
SA-2
SA-3
SA-4
SA-5
SA-6
SA-7
SA-8
SA-9
SA-10
SA-11
SA-12
SA-13
SA-14
SA-15
SA-16
SA-17
SA-18
SA-19
SA-20
SA-21
SA-22
SA-23
SA-24
SA-25
SA-26
SA-27
SA-28
SA-29
SA-30
SA-31
SA-32
SA-33
SA-34
SA-35
SA-36
SA-37
SA-38
SA-39
SA-40
SA-41
SA-42
SA-43
SA-44
SA-45
SA-46
SA-47
SA-48
SA-49

In a preferred embodiment, the LC media, SA-VA and SA-FFS displays according to the present invention com¬prise one or more SA additives selected from the Formulae SA-1 to SA-49, preferably from the Formulae SA-14 to SA-49, very preferably from the Formulae SA-20 to SA-34 and SA-44, in combination with one or more RMs.

The following examples are intended to explain the invention without limiting it.

Above and below, percentage data denote percent by weight. All temperatures are indicated in degrees Celsius. m.p. denotes melting point, cl.p.=clearing point. Furthermore, C=crystalline state, N=nematic phase, S=smectic phase and I=isotropic phase. The data between these symbols represent the transition temperatures. Furthermore, the following symbols are used

V0        Freedericks threshold voltage, capacitive [V] at 20° C.,
V10       voltage [V] for 10% transmission,
ne        extraordinary refractive index measured at 20° C. and 589 nm,
n0        ordinary refractive index measured at 20° C. and 589 nm,
Δn        optical anisotropy measured at 20° C. and 589 nm,
ε⊥        dielectric susceptibility (or “dielectric constant”) perpendicular
          to the to the longitudinal axes of the molecules at 20° C.
          and 1 kHz,
ε∥        dielectric susceptibility (or “dielectric constant”) parallel
          to the to the longitudinal axes of the molecules at 20° C.
          and 1 kHz,
Δε        dielectric anisotropy at 20° C. and 1 kHz,
cl. p. or clearing point [° C.],
T(N, I)
ν         flow viscosity measured at 20° C. [mm2 · s−1],
γ1        rotational viscosity measured at 20° C. [mPa · s],
K1        elastic constant, “splay” deformation at 20° C. [pN],
K2        elastic constant, “twist” deformation at 20° C. [pN],
K3        elastic constant, “bend” deformation at 20° C. [pN], and
VHR       voltage holding ratio.

All physical properties are determined in accordance with “Merck Liquid Crystals, Physical Properties of Liquid Crystals”, status November 1997, Merck KGaA, Germany, and apply for a temperature of 20° C., unless explicitly indicated otherwise.

EXAMPLES

Example M1

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 80.7° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1121
3	CC-3-V1	6.0	ε∥ (1 kHz, 20° C.): = 10.1
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
6	PGP-2-3	5.0	γ1 (20° C.): = 61 mPa · s
7	PGP-2-4	2.0	K1 (20° C.): = 13.2 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.5 pN
9	PGUQU-4-F	6.0	V0 (20° C.): = 1.47 V
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5

Mixture Example S1 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M1                 99.935 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  150 ppm
ST-2-3
H-3-3

Example M2

A nematic L⁹ medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 78.8° C.
2	CC-3-V	39.5	Δn (589 nm, 20° C.): = 0.1141
3	CC-3-V1	6.5	ε∥ (1 kHz, 20° C.): = 10.2
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.1
5	CLU-3-F	9.5	Δε (1 kHz, 20° C.): = 7.2
6	PGP-2-3	2.5	γ1 (20° C.): = 64 mPa · s
7	PGP-2-4	5.0	K1 (20° C.): = 13.7 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.6 pN
9	PGUQU-4-F	5.0	V0 (20° C.): = 1.46 V
10	PGUQU-5-F	3.5
11	PPGU-3-F	1.0
12	PUQU-3-F	8.5

Mixture Example S² (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M2                 99.935 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  150 ppm

Example M3

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	5.5	T(N, I) = 76.3° C.
2	CC-3-V	35.0	Δn (589 nm, 20° C.): = 0.1097
3	CC-3-V1	4.5	ε∥ (1 kHz, 20° C.): = 15.2
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 3.5
5	CCP-30CF3	5.5	Δε (1 kHz, 20° C.): = 11.7
6	CLP-3-T	1.0	γ1 (20° C.): = 76 mPa · s
7	CLU-3-F	11.0	K1 (20° C.): = 12.2 pN
8	PGU-2-F	5.0	K3 (20° C.): = 13.1 pN
9	PGU-3-F	1.0	V0 (20° C.): = 1.07 V
10	PGUQU-3-F	5.5
11	PGUQU-4-F	7.5
12	PGUQU-5-F	2.5
13	PPGU-3-F	1.0
14	PUQU-3-F	8.0

Mixture Example S3 (Stabilised with Compounds of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M3                 99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S3a (Stabilised with Compounds of Formula ST-1-8)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M3                 99.95 wt.- %
Compound of Formula ST-1-8 500 ppm
ST-1-8

Example M4

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-2V1	4.0	T(N, I) = 93.3° C.
2	CC-3-V	30.0	Δn (589 nm, 20° C.): = 0.1120
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): = 2.9
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 6.3
5	CCP-30CF3	3.0	Δε (1 kHz, 20° C.): = 6.8
6	CCP-V2-1	3.0	γ1 (20° C.): = 76 mPa · s
7	CDUQU-3-F	6.0	K1 (20° C.): = 18.5 pN
8	CLP-3-T	5.0	K3 (20° C.): = 17.7 pN
9	CLP-V-1	5.0	V0 (20° C.): = 1.81 V
10	CLU-3-F	5.0
11	DGUQU-4-F	5.0
12	DLGU-3-F	2.0
13	DPGU-4-F	3.0
14	PGP-2-2V	6.0
15	PP-1-2V1	8.5
16	PGUQU-3-F	1.5

Mixture Example S4 (Stabilised with Compounds of Formulae ST-2-3 and H-3-11)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M4                 99.955 wt.-%
Compound of Formula ST-2-3 400 ppm
Compound of Formula H-3-11 50 ppm
H-3-11

Example M5

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-2V1	4.0	T(N, I) = 93.2° C.
2	CC-3-V	30.0	Δn (589 nm, 20° C.): = 0.1096
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): = 9.6
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.0
5	CCP-30CF3	3.0	Δε (1 kHz, 20° C.): = 6.7
6	CCP-V2-1	3.0	γ1 (20° C.): = 79 mPa · s
7	CDUQU-3-F	6.0	K1 (20° C.): = 18.7 pN
8	CLP-3-T	5.0	K3 (20° C.): = 18.1 pN
9	CLP-V-1	5.0	V0 (20° C.): = 1.77 V
10	CLU-3-F	5.0
11	DGUQU-4-F	5.0
12	DLGU-3-F	2.0
13	DPGU-4-F	3.0
14	PGP-2-2V	5.0
15	PP-1-2V1	8.5
16	APUQU-3-F	2.5

Mixture Example S5 (Stabilised with Compounds of Formulae ST-2-3 and H-3-11)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M5                 99.955 wt.-%
Compound of Formula ST-2-3 400 ppm
Compound of Formula H-3-11 50 ppm

Example M6

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-2V1	4.0	T(N, I) = 93.1° C.
2	CC-3-V	30.0	Δn (589 nm, 20° C.): = 0.1092
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): = 9.8
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-30CF3	3.0	Δε (1 kHz, 20° C.): = 6.9
6	CCP-V2-1	3.0	γ1 (20° C.): = 81 mPa · s
7	CDUQU-3-F	7.5	K1 (20° C.): = 18.6 pN
8	CLP-3-T	5.0	K3 (20° C.): = 18.1 pN
9	CLP-V-1	5.0	V0 (20° C.): = 1.74 V
10	CLU-3-F	5.0
11	DGUQU-4-F	5.0
12	DLGU-3-F	2.0
13	DPGU-4-F	3.0
14	PGP-2-2V	4.5
15	PGUQU-3-F	1.5
16	PP-1-2V1	8.5

Mixture Example S6 (Stabilised with Compounds of Formulae ST-2-3 and H-3-11)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M6                 99.955 wt.-%
Compound of Formula ST-2-3 400 ppm
Compound of Formula H-3-11 50 ppm

Example M7

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	4.9	T(N, I) = 106° C.
2	CC-3-2V1	2.0	Δn (589 nm, 20° C.):=
3	CC-3-V	22.5	ε∥ (1 kHz, 20° C.):=
4	CC-3-V1	7.4	ε⊥ (1 kHz, 20° C.):=
5	CCP-V-1	15.0	Δε (1 kHz, 20° C.):=
6	CCP-V2-1	6.6	γ1 (20° C.): = mPa · s
7	CCVC-3-V	4.2	K1 (20° C.): = pN
8	CDUQU-3-F	10.0	K3 (20° C.): = pN
9	CLP-V-1	6.0	V0 (20° C.): = V
10	PCH-302	3.0
11	PGP-1-2V	6.0
12	PGP-3-2V	3.9
13	PP-1-2V1	8.5

Mixture Example S7 (Stabilised with Compounds of Formula ST-1-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M7                 99.97 wt.-%
Compound of Formula ST-1-3 300 ppm
ST-1-3

Example M8

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	5.0	T(N, I) = ° C.
2	BCH-32	6.0	Δn (589 nm, 20° C.):=
3	BCH-3F.F	1.0	ε∥ (1 kHz, 20° C.):=
4	CC-3-V	48.0	ε⊥ (1 kHz, 20° C.):=
5	CCP-V-1	14.0	Δε (1 kHz, 20° C.):=
6	PGU-2-F	2.3	γ1 (20° C.): = mPa · s
7	PGUQU-3-F	4.6	K1 (20° C.): = pN
8	PGUQU-4-F	2.1	K3 (20° C.): = pN
9	PP-1-2V1	2.5	V0 (20° C.): = V
10	PUQU-3-F	7.5
11	PYP-2-3	4.0
12	CLU-3-F	3.0

Mixture Example S8 (Stabilised with Compounds of Formula ST-1-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M8                 99.97 wt.-%
Compound of Formula ST-1-3 300 ppm

Example M9

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-3F.F	2.5	T(N, I) = ° C.
2	CC-3-V	50.0	Δn (589 nm, 20° C.):=
3	CCP-V-1	14.0	ε∥ (1 kHz, 20° C.):=
4	CLU-3-F	9.5	ε⊥ (1 kHz, 20° C.):=
5	PGU-2-F	6.0	Δε (1 kHz, 20° C.):=
6	PGUQU-3-F	6.0	γ1 (20° C.): = mPa · s
7	PGUQU-4-F	6.0	K1 (20° C.): = pN
8	PP-1-2V1	1.5	K3 (20° C.): = pN
9	PYP-2-3	4.5	V0 (20° C.): = V

Mixture Example S9 (Stabilised with Compounds of Formula ST-1-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M9                 99.97 wt.-%
Compound of Formula ST-1-3 300 ppm

Example M10

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.5	T(N, I) = ° C.
2	BCH-3F.F	8.0	Δn (589 nm, 20° C.):=
3	CC-3-V	49.0	ε∥ (1 kHz, 20° C.):=
4	CCP-V-1	2.5	ε⊥ (1 kHz, 20° C.):=
5	CLU-3-F	13.0	Δε (1 kHz, 20° C.):=
6	PGU-2-F	1.0	γ1 (20° C.): = mPa · s
7	PGUQU-3-F	6.5	K1 (20° C.): = pN
8	PGUQU-4-F	6.5	K3 (20° C.): = pN
9	PP-1-2V1	3.0	V0 (20° C.): = V
10	PYP-2-3	2.0

Mixture Example S10 (Stabilised with Compounds of Formula ST-1-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M10                99.97 wt.-%
Compound of Formula ST-1-3 300 ppm

Example M11

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-3F.F	5.0	T(N, I) = 81° C.
2	CC-3-V	48.5	Δn (589 nm, 20° C.):=
3	CCP-3-1	10.5	ε∥ (1 kHz, 20° C.): = 5.9
4	CLU-3-F	10.0	ε⊥ (1 kHz, 20° C.): = 3.5
5	CPY-2-O2	7.0	Δε (1 kHz, 20° C.): = 2.5
6	CPY-3-O2	7.5	γ1 (20° C.): = 67 mPa · s
7	PGUQU-3-F	6.0	K1 (20° C.): = 14.2 pN
8	PP-1-2V1	5.5	K3 (20° C.): = 15.5 pN
			V0 (20° C.): = 2.54 V

Mixture Example S11 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M11                99.92 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  300 ppm

Example M12

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	3.5	T(N, I) = 80° C.
2	BCH-3F.F	6.0	Δn (589 nm, 20° C.):=
3	CC-3-V	49.0	ε∥ (1 kHz, 20° C.): = 6.4
4	CCP-3-1	4.5	ε⊥ (1 kHz, 20° C.): = 3.6
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 2.7
6	CPY-2-O2	5.5	γ1 (20° C.): = 66 mPa · s
7	CPY-3-O2	10.0	K1 (20° C.): = 13.7 pN
8	PCH-302	1.5	K3 (20° C.): = 14.8 pN
9	PGUQU-3-F	5.5	V0 (20° C.): = 2.37 V
10	PGUQU-4-F	1.5	LTS bulk (−20° C.): 1000 h
11	PP-1-2V1	3.0

Mixture Example S12 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M12                99.92 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  300 ppm

Example M13

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 78.8° C.
2	CC-3-V	39.5	Δn (589 nm, 20° C.): = 0.1141
3	CC-3-V1	6.5	ε∥ (1 kHz, 20° C.): = 10.2
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.1
5	CLU-3-F	9.5	Δε (1 kHz, 20° C.): = 7.2
6	PGP-2-3	2.5	γ1 (20° C.): = 64 mPa · s
7	PGP-2-4	5.0	K1 (20° C.): = 13.7 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 14.6 pN
9	PGUQU-4-F	5.0	V0 (20° C.): = 1.46 V
10	PGUQU-5-F	3.5
11	PPGU-3-F	1.0
12	PUQU-3-F	8.5

Mixture Example S13 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M13                99.935 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  150 ppm

Mixture Example S13a (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M13                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M14

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	41.5	T(N, I) = 79.5° C.
2	PUQU-3-F	6.0	Δn (589 nm, 20° C.): = 0.1145
3	CCP-V-1	5.0	ε∥ (1 kHz, 20° C.): = 10.2
4	CLU-3-F	15.0	ε⊥ (1 kHz, 20° C.): = 3.1
5	CCP-3-1	2.5	Δε (1 kHz, 20° C.): = 7.1
6	BCH-32	5.0	γ1 (20° C.): = 68 mPa · s
7	PGP-2-3	5.0	K1 (20° C.): = 13.6 pN
8	PGP-2-4	5.0	K3 (20° C.): = 13.6 pN
9	APUQU-3-F	4.0	V0 (20° C.): = 1.46 V
10	PGUQU-3-F	5.0
11	PGUQU-4-F	4.0
12	PPGU-3-F	1.0
13	PP-1-2V1	1.0

Mixture Example S14 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M14                99.935 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  150 ppm

Example M15

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	CC-3-V	41.5	T (N, I) = 80.0° C.
	2	PUQU-3-F(1)	6.0	Δn (589 nm, 20° C.): = 0.1117
	3	CCP-V-1	5.0	ϵ∥ (1 kHz, 20° C.): = 10.1
	4	CLU-3-F	15.0	ϵ⊥ (1 kHz, 20° C.): = 3.1
	5	CCP-3-1	2.5	Δϵ (1 kHz, 20° C.): = 7.0
	6	BCH-32	5.0	γ1 (20° C.): = 77 mPa · s
	7	PGP-2-3	5.0	K1 (20° C.): = 13.4 pN
	8	PGP-2-4	5.0	K3 (20° C.): = 13.8 pN
	9	APUQU-3-F(1)	4.0	V0 (20° C.): = 1.49 V
	10	PGUQU-3-F(1)	5.0
	11	PGUQU-4-F(1)	4.0
	12	PPGU-3-F	1.0
	13	PP-1-2V1	1.0
APUQU-3-F(1)
PGUQU-3-F(1)
PGUQU-4-F(1)

Mixture Example S15 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M15                99.935 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  150 ppm

Example M16

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	5.0	T(N, I) = 81.4° C.
2	BCH-3F.F	6.0	Δn (589 nm, 20° C.): = 0.0998
3	CC-3-V	45.0	ε∥ (1 kHz, 20° C.): = 6.4
4	CCH-23	4.0	ε⊥ (1 kHz, 20° C.): = 3.5
5	CCP-3-1	10.0	Δε (1 kHz, 20° C.): = 2.9
6	CLU-3-F	5.0	γ1 (20° C.): = 67 mPa · s
7	CPY-2-O2	10.0	K1 (20° C.): = 13.8 pN
8	CPY-3-O2	2.5	K3 (20° C.): = 14.5 pN
9	PGUQU-3-F	6.0	V0 (20° C.): = 2.30 V
10	PUQU-3-F	4.0	LTS bulk (−20° C.): = 1000 h
11	PYP-2-3	2.5

Mixture Example S16 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M16                99.92 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  300 ppm

Example M17

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	5.0	T(N, I) = 81.3° C.
2	BCH-3F.F	5.0	Δn (589 nm, 20° C.): = 0.0993
3	CC-3-V	45.0	ε∥ (1 kHz, 20° C.): = 6.5
4	CCH-23	1.5	ε⊥ (1 kHz, 20° C.): = 3.5
5	CCP-3-1	10.0	Δε (1 kHz, 20° C.): = 3.0
6	CLU-3-F	10.0	γ1 (20° C.): = 67 mPa · s
7	CPY-2-O2	10.0	K1 (20° C.): = 13.8 pN
8	CPY-3-O2	2.0	K3 (20° C.): = 14.4 pN
9	PGUQU-3-F	3.5	V0 (20° C.): = 2.27 V
10	PUQU-3-F	5.0	LTS bulk (−20° C.): = 1000 h
11	PYP-2-3	3.0

Mixture Example S17 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M17                99.92 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  300 ppm

Example M18

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	42.0	T(N, I) = 79.4° C.
2	CC-3-V1	5.0	Δn (589 nm, 20° C.): = 0.1121
3	CCP-V-1	4.5	ε∥ (1 kHz, 20° C.): = 10.3
4	CLU-3-F	10.5	ε⊥ (1 kHz, 20° C.): = 3.2
5	CPGU-3-OT	5.0	Δε (1 kHz, 20° C.): = 7.1
6	APUQU-2-F	5.0	γ1 (20° C.): = 66 mPa · s
7	APUQU-3-F	7.5	K1 (20° C.): = 13.5 pN
8	PGP-2-3	6.0	K3 (20° C.): = 13.6 pN
9	PGP-2-4	8.0	V0 (20° C.): = 1.46 V
10	PPGU-3-F	0.5
11	PUQU-3-F	6.0

Mixture Example S18 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M18                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M19

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	CC-3-V	42.0	T (N, I) = 79.6° C.
	2	CC-3-V1	5.0	Δn (589 nm, 20° C.): = 0.1095
	3	CCP-V-1	4.5	ϵ∥ (1 kHz, 20° C.): = 10.2
	4	CLU-3-F	10.5	ϵ⊥ (1 kHz, 20° C.): = 3.2
	5	CPGU-3-OT	5.0	Δϵ (1 kHz, 20° C.): = 7.0
	6	APUQU-2-F(1)	5.0	γ1 (20° C.): = 75 mPa · s
	7	APUQU-3-F(1)	7.5	K1 (20° C.): = 13.4 pN
	8	PGP-2-3	6.0	K3 (20° C.): = 13.7 pN
	9	PGP-2-4	8.0	V0 (20° C.): = 1.47 V
	10	PPGU-3-F	0.5
	11	PUQU-3-F(1)	6.0

Mixture Example S19 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M19                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M20

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	40.5	T(N, I) = 78.8° C.
2	CC-3-V1	2.0	Δn (589 nm, 20° C.): = 0.1122
3	PUQU-3-F	7.0	ε∥ (1 kHz, 20° C.): = 10.3
4	CCP-V-1	6.0	ε⊥ (1 kHz, 20° C.): = 3.1
5	CLU-3-F	15.0	Δε (1 kHz, 20° C.): = 7.2
6	CCP-3-1	3.0	γ1 (20° C.): = 67 mPa · s
7	BCH-32	4.0	K1 (20° C.): = 13.1 pN
8	PGP-2-3	4.0	K3 (20° C.): = 13.8 pN
9	PGP-2-4	5.0	V0 (20° C.): = 1.42 V
10	PGUQU-3-F	5.0
11	PGUQU-4-F	5.0
12	PGUQU-5-F	3.0
13	PPGU-3-F	0.5

Mixture Example S20 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M20                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M21

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	40.5	T(N, I) = 78.5° C.
2	CCP-3-1	5.0	Δn (589 nm, 20° C.): = 0.1112
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): = 10.3
4	CCP-V-1	2.0	ε⊥ (1 kHz, 20° C.): = 3.1
5	CCPC-33	2.0	Δε (1 kHz, 20° C.): = 7.1
6	CLU-3-F	10.0	γ1 (20° C.): = 67 mPa · s
7	PGU-2-F	5.5	K1 (20° C.): = 13.2 pN
8	PGUQU-3-F	7.0	K3 (20° C.): = 13.9 pN
9	PGUQU-4-F	7.0	V0 (20° C.): = 1.44 V
10	PUQU-3-F	4.0
11	PGP-2-3	3.0
12	PGP-2-4	6.0

Mixture Example S21 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M21                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M22

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.5	T(N, I) = 85.3° C.
2	CC-3-V	32.0	Δn (589 nm, 20° C.): = 0.1135
3	CC-3-V1	9.0	ε∥ (1 kHz, 20° C.): = 11.1
4	CCP-30CF3	2.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CLP-3-T	10.0	Δε (1 kHz, 20° C.): = 8.2
6	CLP-V-1	8.0	γ1 (20° C.): = 82 mPa · s
7	CLU-3-F	13.0	K1 (20° C.): = 17.1 pN
8	PGUQU-3-F	7.0	K3 (20° C.): = 17.4 pN
9	PGUQU-4-F	5.0	V0 (20° C.): = 1.53 V
10	PGUQU-5-F	4.0
11	PP-1-2V1	7.0
12	PPGU-3-F	0.5

Mixture Example S22 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M22                99.935 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-3  150 ppm

Example M23

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	36.0	T(N, I) = 78.4° C.
2	PP-1-2V1	12.0	Δn (589 nm, 20° C.): = 0.1134
3	CC-3-V1	10.0	ε∥ (1 kHz, 20° C.): = 6.5
4	CLU-3-F	11.0	ε⊥ (1 kHz, 20° C.): = 2.7
5	CLP-3-T	6.0	Δε (1 kHz, 20° C.): = 3.9
6	CCP-30CF3	5.0	γ1 (20° C.): = 56 mPa · s
7	CLP-V-1	5.0	K1 (20° C.): = 17.0 pN
8	PGP-2-2V	9.0	K3 (20° C.): = 15.9 pN
9	PGUQU-3-F	3.0	V0 (20° C.): = 2.21 V
10	PGUQU-4-F	3.0

Mixture Example S23 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M23                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M24

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	20.0	T(N, I) = 102.7° C.
2	CC-3-V1	15.0	Δn (589 nm, 20° C.): = 0.0864
3	CC-3-2V1	8.0	ε∥ (1 kHz, 20° C.): = 8.2
4	CCQU-3-F	7.0	ε⊥ (1 kHz, 20° C.): = 2.7
5	CLP-3-T	6.0	Δε (1 kHz, 20° C.): = 5.5
6	CLU-3-F	15.0	γ1 (20° C.): = 102 mPa · s
7	CCP-V-1	8.0	K1 (20° C.): = 19.3 pN
8	CLP-V-1	5.0	K3 (20° C.): = 22.8 pN
9	CCP-V2-1	8.0	V0 (20° C.): = 2.00 V
10	CDUQU-3-F	6.0
11	DGUQU-4-F	2.0

Mixture Example S24 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M24                99.955 wt.-%
Compound of Formula ST-2-3 300 ppm
Compound of Formula H-3-3  150 ppm

Example M25

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	20.0	T(N, I) = 103° C.
2	CC-3-V1	15.0	Δn (589 nm, 20° C.): = 0.0848
3	CC-3-2V1	8.0	ε∥ (1 kHz, 20° C.): = 8.1
4	CCQU-3-F(1)	7.0	ε⊥ (1 kHz, 20° C.): = 2.7
5	CLP-3-T	6.0	Δε (1 kHz, 20° C.): = 5.5
6	CLU-3-F	15.0	γ1 (20° C.): = 111 mPa · s
7	CCP-V-1	8.0	K1 (20° C.): = 19.1 pN
8	CLP-V-1	5.0	K3 (20° C.): = 22.9 pN
9	CCP-V2-1	8.0	V0 (20° C.): = 2.02 V
10	CDUQU-3-F(1)	6.0
11	DGUQU-4-F(1)	2.0

Mixture Example S25 (Stabilised with Compounds of Formulae ST-2-3 and H-3-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M25                99.955 wt.-%
Compound of Formula ST-2-3 300 ppm
Compound of Formula H-3-3  150 ppm

Example M26

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	3.0	T(N, I) = ° C.
2	CC-3-V	34.6	Δn (589 nm, 20° C.):=
3	CC-3-V1	6.0	ε∥ (1 kHz, 20° C.):=
4	CCH-23	3.0	ε⊥ (1 kHz, 20° C.):=
5	CCH-34	3.0	Δε (1 kHz, 20° C.):=
6	CCP-V-1	11.0	γ1 (20° C.): = mPa · s
7	CCP-V2-1	8.3	K1 (20° C.): = pN
8	CCVC-3-V	6.0	K3 (20° C.): = pN
9	CDUQU-3-F	4.8	V0 (20° C.): = V
10	CLP-V-1	6.0
11	CLU-3-F	3.0
12	CPGU-3-OT	3.3
13	DGUQU-4-F	3.0
14	DLGU-3-F	4.0
15	PP-1-2V1	1.0

Mixture Example S26 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M26                99.96 wt.-%
Compound of Formula ST-2-3 400 ppm

Example M27

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	1.6	T(N, I) = ° C.
2	BCH-32	3.0	Δn (589 nm, 20° C.):=
3	CC-3-V	37.5	ε∥ (1 kHz, 20° C.):=
4	CC-3-V1	6.0	ε⊥ (1 kHz, 20° C.):=
5	CCP-V-1	12.0	Δε (1 kHz, 20° C.):=
6	CCP-V2-1	8.0	γ1 (20° C.): = mPa · s
7	CCVC-3-V	6.0	K1 (20° C.): = pN
8	CDUQU-3-F	6.0	K3 (20° C.): = pN
9	CLP-V-1	6.0	V0 (20° C.): = V
10	CLU-3-F	3.0
11	CLY-3-O2	3.0
12	DGUQU-4-F	3.0
13	DLGU-3-F	3.5
14	PP-1-2V1	1.4

Mixture Example S27 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M26                99.96 wt.-%
Compound of Formula ST-2-3 400 ppm

Example M28

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.5	T(N, I) = 99.7° C.
2	CC-3-V	27.5	Δn (589 nm, 20° C.): = 0.1090
3	CC-3-V1	3.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	6.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-3F.F.F	1.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V-1	10.0	K1 (20° C.): = 17.5 pN
8	CCPC-33	2.0	K3 (20° C.): = 18.4 pN
9	CLP-3-T	8.0	V0 (20° C.): = 1.82 V
10	CLU-3-F	5.0
11	PCH-302	10.0
12	PGUQU-3-F	7.0
13	PGUQU-4-F	7.0
14	PGUQU-5-F	2.0

Mixture Example S28 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M28                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S28a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M28                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm
H-3-1

Example M29

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	3.0	T(N, I) = 99.9° C.
2	BCH-3F.F	8.0	Δn (589 nm, 20° C.): = 0.1092
3	CC-3-V	25.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	6.0	ε⊥ (1 kHz, 20° C.): = 3.0
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.7
6	CCP-V-1	7.5	γ1 (20° C.):112 mPa · s
7	CCPC-33	2.0	K1 (20° C.): = 17.5 pN
8	CCPC-34	2.0	K3 (20° C.): = 18.5 pN
9	CLP-3-T	8.0	V0 (20° C.): = 1.84 V
10	CLU-3-F	11.5
11	PCH-302	10.0
12	PGUQU-3-F	7.5
13	PGUQU-4-F	3.0
14	PP-1-2V1	1.5

Mixture Example S29 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M29                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S29a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M29                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M30

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	4.5	T(N, I) = 100.9° C.
2	BCH-3F.F	10.0	Δn (589 nm, 20° C.): = 0.1104
3	CC-3-V	24.0	ε∥ (1 kHz, 20° C.): = 8.9
4	CCH-35	4.0	ε⊥ (1 kHz, 20° C.): = 3.0
5	CCP-3-1	6.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-3-3	5.0	γ1 (20° C.): = 111 mPa · s
7	CCP-V-1	5.0	K1 (20° C.): = 18.1 pN
8	CCPC-33	2.0	K3 (20° C.): = 18.4 pN
9	CCPC-34	2.0	V0 (20° C.): = 1.83 V
10	CLP-3-T	8.0
11	CLU-3-F	6.0
12	PCH-302	10.0
13	PGUQU-3-F	7.5
14	PGUQU-4-F	5.5
15	PP-1-2V1	0.5

Mixture Example S30 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M30                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S30a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M30                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M31

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = ° C.
2	CC-3-V	24.5	Δn (589 nm, 20° C.): =
3	CC-3-V1	7.0	ε∥ (1 kHz, 20° C.): =
4	CCP-3-1	6.5	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): =
6	CCP-V-1	9.0	γ1 (20° C.): = mPa · s
7	CCPC-33	1.0	K1 (20° C.): = pN
8	CLP-3-T	6.0	K3 (20° C.): = pN
9	CLU-3-F	6.5	V0 (20° C.): = V
10	PCH-302	9.0
11	PGUQU-3-F	6.0
12	PGUQU-4-F	7.0
13	PGUQU-5-F	3.5

Mixture Example S31 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M31                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S31a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M31                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M32

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.0	T(N, I) = 100.2° C.
2	CC-3-V	22.0	Δn (589 nm, 20° C.): = 0.1115
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	13.0	γ1 (20° C.): = 97 mPa · s
7	CLP-3-T	6.0	K1 (20° C.): = 17.9 pN
8	CLU-3-F	5.0	K3 (20° C.): = 18.8 pN
9	PCH-302	10.0	V0 (20° C.): = 1.84 V
10	PGUQU-3-F	6.0
11	PGUQU-4-F	7.0
12	PGUQU-5-F	4.0

Mixture Example S32 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M32                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S32a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M32                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M33

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = ° C.
2	BCH-3F.F	2.0	Δn (589 nm, 20° C.): =
3	CC-3-V	28.0	ε∥ (1 kHz, 20° C.): =
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-3	3.5	Δε (1 kHz, 20° C.): =
6	CCP-V-1	12.5	γ1 (20° C.): = mPa · s
7	CLP-3-T	8.0	K1 (20° C.): = pN
8	CLU-3-F	9.0	K3 (20° C.): = pN
9	PCH-302	7.0	V0 (20° C.): = V
10	PGUQU-3-F	6.0
11	PGUQU-4-F	7.0
12	PGUQU-5-F	1.0

Mixture Example S33 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M33                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S33a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M33                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M34

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.0	T(N, I) = 100.4° C.
2	CC-3-V	26.5	Δn (589 nm, 20° C.): = 0.1112
3	CC-3-V1	1.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-V-1	13.0	γ1 (20° C.): = 99 mPa · s
7	CCPC-33	0.5	K1 (20° C.): = 17.8 pN
8	CLP-3-T	8.0	K3 (20° C.): = 18.7 pN
9	CLU-3-F	6.0	V0 (20° C.): = 1.83 V
10	PCH-302	10.0
11	PGUQU-3-F	5.0
12	PGUQU-4-F	7.0
13	PGUQU-5-F	4.0

Mixture Example S34 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M34                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S34a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M34                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M35

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.0	T(N, I) = 100° C.
2	CC-3-V	25.5	Δn (589 nm, 20° C.): = 0.1101
3	CC-3-V1	4.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	7.5	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	4.5	Δε (1 kHz, 20° C.): = 5.9
6	CCP-V-1	9.0	γ1 (20° C.): = 98 mPa · s
7	CCPC-33	1.5	K1 (20° C.): = 17.7 pN
8	CLP-3-T	6.0	K3 (20° C.): = 18.6 pN
9	CLU-3-F	7.5	V0 (20° C.): = 1.82 V
10	PCH-302	10.0
11	PGUQU-3-F	5.5
12	PGUQU-4-F	7.0
13	PGUQU-5-F	3.5

Mixture Example S35 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M35                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S35a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M35                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M36

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.0	T(N, I) = ° C.
2	BCH-3F.F	0.5	Δn (589 nm, 20° C.): =
3	CC-3-V	24.5	ε∥ (1 kHz, 20° C.): =
4	CC-3-V1	6.5	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): =
6	CCP-3-3	5.0	γ1 (20° C.): = mPa · s
7	CCP-V-1	8.5	K1 (20° C.): = pN
8	CCPC-33	1.5	K3 (20° C.): = pN
9	CLP-3-T	6.0	V0 (20° C.): = V
10	CLU-3-F	6.0
11	PCH-302	10.0
12	PGUQU-3-F	4.0
13	PGUQU-4-F	7.0
14	PGUQU-5-F	5.5

Mixture Example S36 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M36                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S36a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M36                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M37

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.5	T(N, I) = ° C.
2	BCH-3F.F	0.5	Δn (589 nm, 20° C.): =
3	CC-3-V	24.5	ε∥ (1 kHz, 20° C.): =
4	CC-3-V1	7.0	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): =
6	CCP-3-3	4.0	γ1 (20° C.): = mPa · s
7	CCP-V-1	9.0	K1 (20° C.): = pN
8	CCPC-33	2.0	K3 (20° C.): = pN
9	CLP-3-T	6.0	V0 (20° C.): = V
10	CLU-3-F	6.0
11	PCH-302	10.0
12	PGUQU-3-F	4.5
13	PGUQU-4-F	7.0
14	PGUQU-5-F	5.0

Mixture Example S37 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M37                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S37a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M37                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M38

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.5	T(N, I) = 101° C.
2	CC-3-V	26.5	Δn (589 nm, 20° C.): = 0.1097
3	CC-3-V1	3.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	6.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-3F.F.F	1.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V-1	11.0	K1 (20° C.): = 17.8 pN
8	CCPC-33	2.0	K3 (20° C.): = 18.9 pN
9	CLP-3-T	8.0	V0 (20° C.): = 1.83 V
10	CLU-3-F	5.0
11	PCH-302	10.0
12	PGUQU-3-F	7.0
13	PGUQU-4-F	7.0
14	PGUQU-5-F	2.0

Mixture Example S38 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M38                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M39

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.0	T(N, I) = 100.4° C.
2	CC-3-V	28.5	Δn (589 nm, 20° C.): = 0.1109
3	CC-3-V1	0.5	ε∥ (1 kHz, 20° C.): = 8.8
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-V-1	10.5	γ1 (20° C.): = 98 mPa · s
7	CCPC-33	2.0	K1 (20° C.): = 18.0 pN
8	CLP-3-T	7.0	K3 (20° C.): = 18.6 pN
9	CLU-3-F	5.0	V0 (20° C.): = 1.84 V
10	PCH-302	10.5
11	PGUQU-3-F	5.0
12	PGUQU-4-F	7.0
13	PGUQU-5-F	5.0

Mixture Example S39 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M39                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M40

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 101.1° C.
2	BCH-32	8.0	Δn (589 nm, 20° C.): = 0.1110
3	CC-3-V	25.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	6.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-30CF3	5.5	γ1 (20° C.): = 97 mPa · s
7	CCP-V-1	12.5	K1 (20° C.): = 18.0 pN
8	CLP-3-T	6.5	K3 (20° C.): = 18.6 pN
9	CLU-3-F	3.5	V0 (20° C.): = 1.84 V
10	PCH-302	11.5
11	PGUQU-3-F	3.0
12	PGUQU-4-F	6.0
13	PGUQU-5-F	5.5

Mixture Example S40 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M40                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M41

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.5	T(N, I) = 101.4° C.
2	CC-3-V	25.0	Δn (589 nm, 20° C.): = 0.1108
3	CC-3-V1	0.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	2.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-30CF3	5.5	γ1 (20° C.): = 97 mPa · s
7	CCP-V-1	14.0	K1 (20° C.): = 17.8 pN
8	CLP-3-T	6.5	K3 (20° C.): = 18.5 pN
9	CLU-3-F	5.0	V0 (20° C.): = 1.83 V
10	DGUQU-4-F	1.0
11	PCH-302	10.5
12	PGUQU-3-F	3.0
13	PGUQU-4-F	6.0
14	PGUQU-5-F	5.5

Mixture Example S41 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M41                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M42

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	CC-3-V	24.0	T(N, I) = 100.4° C.
2	CCP-3-1	7.0	Δn (589 nm, 20° C.): = 0.1110
3	CCP-3-3	3.0	ε∥ (1 kHz, 20° C.): = 8.8
4	CCP-30CF3	8.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3F.F.F	3.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-50CF3	1.5	γ1 (20° C.): = 98 mPa · s
7	CCP-V-1	13.5	K1 (20° C.): = 17.5 pN
8	CLP-3-T	7.5	K3 (20° C.): = 18.7 pN
9	CLU-3-F	3.0	V0 (20° C.): = 1.81 V
10	PCH-302	11.0
11	PGP-2-3	4.5
12	PGUQU-3-F	8.0
14	PGUQU-4-F	6.0

Mixture Example S42 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M42                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M43

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	4.0	T(N, I) = 100.5° C.
2	CC-3-V	26.0	Δn (589 nm, 20° C.): = 0.1109
3	CC-3-V1	4.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	4.5	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3F.F.F	3.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V-1	11.0	K1 (20° C.): = 17.3 pN
8	CCPC-33	3.0	K3 (20° C.): = 18.5 pN
9	CLP-3-T	6.0	V0 (20° C.): = 1.80 V
10	CLU-3-F	4.5
11	PCH-302	10.0
12	PGP-2-3	2.5
13	PGUQU-3-F	7.0
14	BCH-32	4.0
15	CC-3-V	26.0

Mixture Example S43 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M43                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M44

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.5	T(N, I) = 100.3° C.
2	BCH-32	8.0	Δn (589 nm, 20° C.): = 0.1105
3	CC-3-V	19.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	8.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	6.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	5.0	γ1 (20° C.): = 98 mPa · s
7	CCP-3F.F.F	3.5	K1 (20° C.): = 17.7 pN
8	CCP-V-1	13.0	K3 (20° C.): = 18.7 pN
9	CLP-3-T	4.5	V0 (20° C.): = 1.83 V
10	CLU-3-F	5.0
11	PCH-302	11.0
12	PGP-2-3	0.5
13	PGUQU-3-F	5.5
14	PGUQU-4-F	6.0
15	PGUQU-5-F	2.0

Mixture Example S44 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M44                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M45

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 100.7° C.
2	BCH-32	7.0	Δn (589 nm, 20° C.): = 0.1097
3	CC-3-V	26.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	1.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	5.0	γ1 (20° C.): = 100 mPa · s
7	CCP-V-1	13.0	K1 (20° C.): = 18.0 pN
8	CCPC-33	0.5	K3 (20° C.): = 18.7 pN
9	CLP-3-T	8.0	V0 (20° C.): = 1.84 V
10	CLU-3-F	6.0
11	PCH-302	10.0
12	PGUQU-3-F	3.0
13	PGUQU-4-F	5.0
14	PGUQU-5-F	6.0

Mixture Example S45 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M45                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M46

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	3.0	T(N, I) = ° C.
2	BCH-32	9.0	Δn (589 nm, 20° C.):=
3	CC-3-V	25.5	ε∥ (1 kHz, 20° C.):=
4	CCP-3-1	6.0	ε⊥ (1 kHz, 20° C.):=
5	CCP-3-3	3.0	Δε (1 kHz, 20° C.):=
6	CCP-30CF3	2.5	γ1 (20° C.): = mPa · s
7	CCP-3F.F.F	0.5	K1 (20° C.): = pN
8	CCP-V-1	14.0	K3 (20° C.): = pN
9	CCP-V2-1	1.0	V0 (20° C.): = V
10	CLP-3-T	6.5
11	CLU-3-F	6.0
12	PCH-302	10.0
13	PGUQU-3-F	3.0
14	PGUQU-4-F	5.0
15	PGUQU-5-F	5.0

Mixture Example S46 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M46                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M47

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = ° C.
2	CC-3-V	20.5	Δn (589 nm, 20° C.):=
3	CC-3-V1	7.0	ε∥ (1 kHz, 20° C.): =
4	CCP-3-1	6.0	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): =
6	CCP-30CF3	2.5	γ1 (20° C.): = mPa · s
7	CCP-V-1	11.5	K1 (20° C.): = pN
8	CLP-3-T	0.5	K3 (20° C.): = pN
9	CLU-3-F	13.5	V0 (20° C.): = V
10	DGUQU-4-F	1.0
11	PCH-302	10.0
12	PGU-2-F	0.5
13	PGUQU-3-F	3.0
14	PGUQU-4-F	5.0
15	PGUQU-5-F	4.0
16	PPGU-3-F	1.0

Mixture Example S47 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M47                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M48

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 100.4° C.
2	BCH-32	4.0	Δn (589 nm, 20° C.): = 0.1113
3	CC-3-V	18.5	ε∥ (1 kHz, 20° C.): = 8.6
4	CC-3-V1	8.5	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	5.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V-1	20.0	K1 (20° C.): = 16.8 pN
8	CCPC-33	0.5	K3 (20° C.): = 18.8 pN
9	CLP-3-T	1.5	V0 (20° C.): = 1.80 V
10	CLU-3-F	9.0
11	PCH-302	10.0
12	PGU-3-F	4.0
13	PGUQU-3-F	2.0
14	PGUQU-4-F	4.0
15	PGUQU-5-F	6.0

Mixture Example S48 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M48                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M49

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 101.2° C.
2	BCH-32	9.0	Δn (589 nm, 20° C.): = 0.1106
3	CC-3-V	25.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	3.5	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	5.5	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	14.5	γ1 (20° C.): = 99 mPa · s
7	CCPC-33	2.0	K1 (20° C.): = 17.6 pN
8	CLP-3-T	7.0	K3 (20° C.): = 18.6 pN
9	CLU-3-F	7.0	V0 (20° C.): = 1.82 V
10	PCH-302	10.0
11	PGUQU-3-F	3.0
12	PGUQU-4-F	5.0
13	PGUQU-5-F	6.0

Mixture Example S49 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M49                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M50

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 101.3° C.
2	BCH-32	9.0	Δn (589 nm, 20° C.):=
3	CC-3-V	19.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	8.5	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	1.5	γ1 (20° C.): = 100 mPa · s
7	CCP-3F.F.F	4.0	K1 (20° C.): = 18.1 pN
8	CCP-V-1	14.0	K3 (20° C.): = 19.0 pN
9	CLP-3-T	6.5	V0 (20° C.): = 1.85 V
10	CLU-3-F	4.5
11	PCH-302	10.0
12	PGUQU-3-F	3.0
13	PGUQU-4-F	5.0
14	PGUQU-5-F	5.5

Mixture Example S50 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M50                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example MP1

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 101° C.
2	BCH-32	5.0	Δn (589 nm, 20° C.): = 0.1114
3	CC-3-V	21.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	8.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	4.5	γ1 (20° C.): = 100 mPa · s
7	CCP-V-1	13.5	K1 (20° C.): = 18.0 pN
8	CCPC-33	1.5	K3 (20° C.): = 18.9 pN
9	CLP-3-T	6.5	V0 (20° C.): = 1.85 V
10	CLU-3-F	4.0
11	PCH-302	10.0
12	PGU-3-F	4.0
13	PGUQU-3-F	3.0
14	PGUQU-4-F	5.0
15	PGUQU-5-F	4.5

Mixture Example S51 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M51                99.85 wt. %
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M52

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 100.6° C.
2	BCH-32	9.0	Δn (589 nm, 20° C.): = 0.1107
3	CC-3-V	19.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	10.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	14.0	γ1 (20° C.): = 98 mPa · s
7	CCPC-33	1.0	K1 (20° C.): = 17.5 pN
8	CLP-3-T	2.5	K3 (20° C.): = 18.8 pN
9	CLU-3-F	11.5	V0 (20° C.): = 1.81 V
10	PCH-302	10.0
11	PGUQU-3-F	3.0
12	PGUQU-4-F	4.5
13	PGUQU-5-F	6.0

Mixture Example S52 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M52                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M53

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F(1)	2.0	T(N, I) = 101° C.
2	BCH-32	9.0	Δn (589 nm, 20° C.): = 0.1086
3	CC-3-V	19.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	10.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	14.0	γ1 (20° C.): = 107 mPa · s
7	CCPC-33	1.0	K1 (20° C.): = 17.2 pN
8	CLP-3-T	2.5	K3 (20° C.): = 19.0 pN
9	CLU-3-F	11.5	V0 (20° C.): = 1.83 V
10	PCH-302	10.0
11	PGUQU-3-F(1)	3.0
12	PGUQU-4-F(1)	4.5
13	PGUQU-5-F(1)	6.0

Mixture Example S53 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M53                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M54

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 101° C.
2	BCH-32	2.5	Δn (589 nm, 20° C.): = 0.1108
3	CC-3-V	22.5	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	6.5	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	4.0	γ1 (20° C.): = 103 mPa · s
7	CCP-V-1	13.0	K1 (20° C.): = 17.5 pN
8	CCP-V2-1	1.5	K3 (20° C.): = 18.9 pN
9	CCPC-33	3.0	V0 (20° C.): = 1.83 V
10	CLP-3-T	6.5
11	CLU-3-F	4.5
12	PCH-302	10.0
13	PGU-2-F	3.5
14	PGU-3-F	3.5
15	PGUQU-3-F	3.0
16	PGUQU-4-F	4.0

Mixture Example S54 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M54                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M55

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 100.7° C.
2	BCH-32	2.5	Δn (589 nm, 20° C.): = 0.1108
3	CC-3-V	22.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	5.0	γ1 (20° C.): = 104 mPa · s
7	CCP-V-1	13.0	K1 (20° C.): = 17.5 pN
8	CCP-V2-1	0.5	K3 (20° C.): = 18.8 pN
9	CCPC-33	3.0	V0 (20° C.): = 1.83 V
10	CLP-3-T	6.5
11	CLU-3-F	4.0
12	PCH-302	10.0
13	PGU-2-F	5.0
14	PGU-3-F	2.5
15	PGUQU-4-F	5.0
16	PGUQU-5-F	5.0

Mixture Example S55 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M55                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M56

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 99.7° C.
2	CC-3-V	31.5	Δn (589 nm, 20° C.): = 0.1104
3	CCG-V-F	4.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	9.5	γ1 (20° C.): = 91 mPa · s
7	CCPC-33	3.0	K1 (20° C.): = 16.4 pN
8	CDUQU-3-F	1.0	K3 (20° C.): = 17.4 pN
9	CLU-3-F	13.0	V0 (20° C.): = 1.77 V
10	DGUQU-4-F	1.0
11	PGU-2-F	2.5
12	PGUQU-3-F	3.5
13	PGUQU-4-F	4.0
14	PGUQU-5-F	3.0
15	PP-1-2V1	5.0

Mixture Example S56 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M56                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M57

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.0	T(N, I) = 103.6° C.
2	BCH-5F.F.F	2.5	Δn (589 nm, 20° C.): = 0.1116
3	CBC-33	0.5	ε∥ (1 kHz, 20° C.): = 8.6
4	CC-3-V	34.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CC-3-V1	1.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-1	10.0	γ1 (20° C.): = 97 mPa · s
7	CCP-30CF3	8.0	K1 (20° C.): = 17.8 pN
8	CCP-V-1	0.5	K3 (20° C.): = 18.5 pN
9	CCPC-33	2.0	V0 (20° C.): = 1.84 V
10	CCPC-35	4.0
11	CLU-3-F	9.0
12	PGUQU-3-F	8.0
13	PGUQU-4-F	4.0
14	PGUQU-5-F	2.0
15	PP-1-2V1	6.5

Mixture Example S57 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M57                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M58

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.5	T(N, I) = 100.3° C.
2	BCH-32	4.0	Δn (589 nm, 20° C.): = 0.1119
3	CC-3-V	22.0	ε∥ (1 kHz, 20° C.): = 8.8
4	CC-3-V1	8.0	ε⊥ (1 kHz, 20° C.): = 3.0
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-3-3	5.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V-1	12.0	K1 (20° C.): = 17.1 pN
8	CCP-V2-1	1.0	K3 (20° C.): = 18.6 pN
9	CCPC-33	2.5	V0 (20° C.): = 1.81 V
10	CLP-3-T	6.0
11	CLU-3-F	2.0
12	PCH-302	10.0
13	PGU-2-F	7.0
14	PGUQU-3-F	3.0
15	PGUQU-4-F	5.0
16	PGUQU-5-F	3.0

Mixture Example S58 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M58                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M59

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = 100.4° C.
2	BCH-32	4.0	Δn (589 nm, 20° C.): = 0.1113
3	CC-3-V	22.5	ε∥ (1 kHz, 20° C.): = 8.8
4	CC-3-V1	8.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-3	5.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V-1	12.0	K1 (20° C.): = 17.6 pN
8	CCP-V2-1	0.5	K3 (20° C.): = 18.7 pN
9	CCPC-33	2.5	V0 (20° C.): = 1.82 V
10	CLP-3-T	6.5
11	CLU-3-F	2.0
12	PCH-302	10.0
13	PGU-2-F	6.0
14	PGUQU-3-F	3.0
15	PGUQU-4-F	5.0
16	PGUQU-5-F	4.0

Mixture Example S59 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M59                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M60

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.5	T(N, I) = 101° C.
2	CC-3-V	27.0	Δn (589 nm, 20° C.): = 0.1115
3	CCG-V-F	4.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	8.0	γ1 (20° C.): = 98 mPa · s
7	CCPC-33	3.0	K1 (20° C.): = 17.5 pN
8	CDUQU-3-F	1.0	K3 (20° C.): = 18.5 pN
9	CLU-3-F	20.0	V0 (20° C.): = 1.82 V
10	DGUQU-4-F	1.0
11	PGUQU-3-F	3.0
12	PGUQU-4-F	2.5
13	PGUQU-5-F	3.5
14	PP-1-2V1	7.5

Mixture Example S60 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M60                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M61

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.5	T(N, I) = 100.2° C.
2	BCH-5F.F.F	3.5	Δn (589 nm, 20° C.): = 0.1119
3	CC-3-V	32.5	ε∥ (1 kHz, 20° C.): = 8.5
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-V-1	2.0	Δε (1 kHz, 20° C.): = 5.7
6	CCPC-33	2.5	γ1 (20° C.): = 100 mPa · s
7	CCPC-35	4.0	K1 (20° C.): = 17.4 pN
8	CLU-3-F	19.0	K3 (20° C.): = 17.7 pN
9	PGUQU-3-F	8.0	V0 (20° C.): = 1.83 V
10	PGUQU-4-F	2.5
11	PP-1-2V1	7.5

Mixture Example S61 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M61                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M62

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 102.8° C.
2	CC-3-V	30.0	Δn (589 nm, 20° C.): = 0.1117
3	CC-3-V1	1.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-V-1	10.5	Δε (1 kHz, 20° C.): = 5.8
6	CCPC-33	3.0	γ1 (20° C.): = 97 mPa · s
7	CLU-3-F	20.0	K1 (20° C.): = 17.5 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 18.5 pN
9	PGUQU-4-F	7.0	V0 (20° C.): = 1.81 V
11	PP-1-2V1	4.5

Mixture Example S62 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S62a (Stabilised with Compounds of Formulae ST-2-3 and H-3-7)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-7  1000 ppm
H-3-7

Mixture Example S62b (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.925 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  250 ppm

Mixture Example S62c (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.9 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  500 ppm

Mixture Example S62d (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.925 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-22 250 ppm
H-3-22

Mixture Example S62e (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.9 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-22 500 ppm

Mixture Example S62f (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-22 1000 ppm

Mixture Example S62q (Stabilised with Compounds of Formulae ST-2-3 and H-3-23)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-23 1000 ppm
H-3-23

Mixture Example S62h (Stabilised with Compound of Formulae ST-2-3

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S62i (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M62                99.875 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  750 ppm

Example M63

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 103.1° C.
2	CC-3-V	30.0	Δn (589 nm, 20° C.): = 0.1101
3	CC-3-V1	1.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-V-1	10.5	Δε (1 kHz, 20° C.): = 5.8
6	CCPC-33	3.0	γ1 (20° C.): = 105 mPa · s
7	CLU-3-F	20.0	K1 (20° C.): = 17.4 pN
8	PGUQU-3-F(1)	5.0	K3 (20° C.): = 18.6 pN
9	PGUQU-4-F(1)	7.0	V0 (20° C.): = 1.81 V
11	PP-1-2V1	4.5

Mixture Example S63 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.875 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  750 ppm

Mixture Example S63a (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.9 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  500 ppm

Mixture Example S63b (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.925 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  250 ppm

Mixture Example S63c (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S63d (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Mixture Example S63e (Stabilised with Compounds of Formulae ST-2-3 and H-3-23)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-23 1000 ppm

Mixture Example S63f (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-22 1000 ppm

Mixture Example S63q (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.9 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-22 500 ppm

Mixture Example S63h (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.925 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-22 250 ppm

Mixture Example S63i (Stabilised with Compounds of Formulae ST-2-3 and H-3-7)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M63                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-7  1000 ppm

Example M64

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	8.0	T(N, I) = 105.5° C.
2	BCH-5F.F.F	4.0	Δn (589 nm, 20° C.): = 0.1114
3	CC-3-V	27.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CC-3-V1	5.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-1	10.0	Δε (1 kHz, 20° C.): = 5.9
6	CCP-30CF3	8.0	γ1 (20° C.): = 97 mPa · s
7	CCP-V-1	9.5	K1 (20° C.): = 17.7 pN
8	CCPC-33	2.5	K3 (20° C.): = 18.6 pN
9	CLU-3-F	9.0	V0 (20° C.): = 1.81 V
10	PGU-2-F	3.0
11	PGUQU-3-F	5.0
12	PGUQU-4-F	5.0
13	PGUQU-5-F	1.5
14	PP-1-2V1	2.5

Mixture Example S64 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M64                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M65

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.5	T(N, I) = 102.3° C.
2	CC-3-V	27.0	Δn (589 nm, 20° C.): = 0.1115
3	CC-3-V1	4.0	ε∥ (1 kHz, 20° C.): = 8.5
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	4.5	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	7.0	γ1 (20° C.): = 99 mPa · s
7	CCPC-33	2.5	K1 (20° C.): = 18.5 pN
8	CLU-3-F	20.0	K3 (20° C.): = 18.1 pN
9	PGUQU-3-F	4.0	V0 (20° C.): = 1.85 V
10	PGUQU-4-F	6.0
11	PGUQU-5-F	2.0
12	PP-1-2V1	5.5

Mixture Example S65 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M65                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M66

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	4.0	T(N, I) = 103.3° C.
2	CC-3-V	24.5	Δn (589 nm, 20° C.): = 0.1118
3	CC-3-V1	7.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	5.5	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	13.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V2-1	3.0	K1 (20° C.): = 17.5 pN
8	CCPC-33	3.0	K3 (20° C.): = 18.9 pN
9	CLU-3-F	15.0	V0 (20° C.): = 1.82 V
10	PGU-2-F	2.0
11	PGU-3-F	4.0
12	PGUQU-3-F	3.0
13	PGUQU-4-F	4.0
14	PGUQU-5-F	3.0
15	PP-1-2V1	4.0

Mixture Example S66 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M66                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M67

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	4.0	T(N, I) = 102.8° C.
2	CC-3-V	24.5	Δn (589 nm, 20° C.): = 0.1123
3	CC-3-V1	7.5	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	13.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V2-1	3.0	K1 (20° C.): = 17.4 pN
8	CCPC-33	3.0	K3 (20° C.): = 18.8 pN
9	CLU-3-F	15.0	V0 (20° C.): = 1.82 V
10	PGU-2-F	2.0
11	PGU-3-F	4.0
12	PGUQU-3-F	3.0
13	PGUQU-4-F	4.0
14	PGUQU-5-F	3.0
15	PP-1-2V1	4.0

Mixture Example S67 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M67                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M68

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = ° C.
2	CC-3-V	17.5	Δn (589 nm, 20° C.): =
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): =
4	CCH-301	8.0	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-1	6.0	Δε (1 kHz, 20° C.): =
6	CCP-30CF3	7.5	γ1 (20° C.): = mPa · s
7	CCP-V-1	13.0	K1 (20° C.): = pN
8	CLP-3-T	5.0	K3 (20° C.): = pN
9	CLU-3-F	13.5	V0 (20° C.): = V
10	PGP-2-4	3.5
11	PGU-2-F	1.5
12	PGUQU-3-F	5.0
13	PGUQU-4-F	4.5
14	PPGU-3-F	1.0

Mixture Example S68 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M68                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S68a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M68                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M69

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = ° C.
2	CC-3-V	14.0	Δn (589 nm, 20° C.): =
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): =
4	CCH-301	8.0	ε⊥ (1 kHz, 20° C.): =
5	CCH-35	5.0	Δε (1 kHz, 20° C.): =
6	CCP-3-1	7.0	γ1 (20° C.): = mPa · s
7	CCP-30CF3	8.0	K1 (20° C.): = pN
8	CCP-V-1	13.0	K3 (20° C.): = pN
9	CLP-3-T	5.5	V0 (20° C.): = V
10	CLU-3-F	5.0
11	PGP-2-4	0.5
12	PGU-2-F	6.0
13	PGUQU-3-F	5.0
14	PGUQU-4-F	5.0
15	PPGU-3-F	1.0

Mixture Example S69 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M69                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S69a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M69                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M70

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = ° C.
2	CC-3-V	19.5	Δn (589 nm, 20° C.): =
3	CC-3-V1	5.0	ε∥ (1 kHz, 20° C.): =
4	CCH-23	5.0	ε⊥ (1 kHz, 20° C.): =
5	CCH-34	2.0	Δε (1 kHz, 20° C.): =
6	CCH-35	1.0	γ1 (20° C.): = mPa · s
7	CCP-3-1	7.0	K1 (20° C.): = pN
8	CCP-30CF3	3.0	K3 (20° C.): = pN
9	CCP-V-1	10.0	V0 (20° C.): = V
10	CCPC-33	2.0
11	CDUQU-3-F	7.0
12	CLP-3-T	5.0
13	CLU-3-F	10.0
14	PGP-2-4	5.5
15	PGU-2-F	6.5
16	PGUQU-3-F	2.5

Mixture Example S70 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M70                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S70a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M70                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M71

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	3.5	T(N, I)=	100.9	° C.
2	CC-3-V	25.5	Δn (589 nm, 20° C.):=	0.1104
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.):=	8.5
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.):=	2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.):=	5.7
6	CCP-V-1	13.0	γ1 (20° C.):=		mPa · s
7	CCP-V2-1	2.0	K1 (20° C.):=	17.1	pN
8	CCPC-33	3.0	K3 (20° C.):=	18.4	pN
9	CLU-3-F	15.0	V0 (20° C.):=	1.81	V
10	PGU-2-F	2.5
11	PGU-3-F	3.5
12	PGUQU-3-F	3.0
13	PGUQU-4-F	4.0
14	PGUQU-5-F	3.0
15	PP-1-2V1	4.0

Mixture Example S71 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M71                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S71a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M71                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M72

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I)=	101.6	° C.
2	CC-3-V	25.0	Δn (589 nm, 20° C.):=	0.1091
3	CC-3-V1	4.0	ε∥ (1 kHz, 20° C.):=	8.5
4	CCP-301	8.0	ε⊥ (1 kHz, 20° C.):=	3.0
5	CCP-35	2.0	Δε (1 kHz, 20° C.):=	5.5
6	CCP-30CF3	6.5	γ1 (20° C.):=	95	mPa · s
7	CCP-V-1	3.5	K1 (20° C.):=	17.3	pN
8	CCP-V2-1	5.5	K3 (20° C.):=	16.8	pN
9	CCPC-33	2.5	V0 (20° C.):=	1.85	V
10	CLU-3-F	13.5
11	CPGP-4-3	1.5
12	CPGP-5-3	1.0
13	DGUQU-4-F	4.5
14	DPGU-4-F	4.0
15	PGP-2-2V	3.0
16	PGUQU-3-F	2.0
17	PGUQU-4-F	1.0
18	PP-1-2V1	3.0
19	PPGU-3-F	0.5

Mixture Example S72 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M72                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S72a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M72                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M73

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I)=	103.4	° C.
2	CC-3-V	25.5	Δn (589 nm, 20° C.):=	0.1124
3	CC-3-V1	1.5	ε∥ (1 kHz, 20° C.):=	8.7
4	CCP-35	1.0	ε⊥ (1 kHz, 20° C.):=	2.8
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.):=	5.9
6	CCP-30CF3	6.5	γ1 (20° C.):=	96	mPa · s
7	CCP-V-1	10.0	K1 (20° C.):=	19.0	pN
8	CCPC-33	2.5	K3 (20° C.):=	18.4	pN
9	CDUQU-3-F	7.0	V0 (20° C.):=	1.88	V
10	CLU-3-F	14.5
11	PGP-2-4	2.0
12	PGU-2-F	1.5
13	PGUQU-3-F	3.0
14	PGUQU-4-F	2.0
15	PP-1-2V1	7.0

Mixture Example S73 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M73                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S73a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M73                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M74

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I)=		° C.
2	CC-3-V	25.0	Δn (589 nm, 20° C.):=
3	CCP-3-1	4.5	ε∥ (1 kHz, 20° C.):=
4	CCP-3-3	4.0	ε⊥ (1 kHz, 20° C.):=
5	CCP-V-1	13.0	Δε (1 kHz, 20° C.):=
6	CCPC-33	1.0	γ1 (20° C.):=		mPa · s
7	CDUQU-3-F	7.0	K1 (20° C.):=		pN
8	CLP-3-T	5.0	K3 (20° C.):=		pN
9	CLU-3-F	13.0	V0 (20° C.):=		V
10	PCH-302	7.0
11	PGP-2-3	3.0
12	PGU-2-F	1.5
13	PGUQU-3-F	2.5
14	PGUQU-4-F	2.5
15	PP-1-2V1	2.0

Mixture Example S74 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M74                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  1000 ppm

Mixture Example S74a (Stabilised with Compound of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M74                99.95 wt.-%
Compound of Formula ST-2-3 500 ppm

Example M75

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.5	T(N, I)=		° C.
2	CC-3-V	25.0	Δn (589 nm, 20° C.):=	0.1104
3	CCP-3-V1	9.0	ε∥ (1 kHz, 20° C.):=	8.6
4	CCG-V-F	3.0	ε⊥ (1 kHz, 20° C.):=	2.8
5	CCP-3-1	5.0	Δε (1 kHz, 20° C.):=	5.8
6	CCP-3-3	5.0	γ1 (20° C.):=		mPa · s
7	CCP-V-1	7.5	K1 (20° C.):=	17.2	pN
8	CCP-V2-1	2.0	K3 (20° C.):=	18.2	pN
9	CCPC-33	3.0	V0 (20° C.):=	1.82	V
10	CLU-3-F	15.0
11	PGU-2-F	1.0
12	PGU-3-F	3.0
13	PGUQU-3-F	3.0
14	PGUQU-4-F	4.0
15	PGUQU-5-F	4.0
16	PP-1-2V1	4.0

Mixture Example S75 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M75	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M76

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.0	T(N, I) = 102.2° C.
2	CC-3-V	28.0	Δn (589 nm, 20° C.): = 0.1109
3	CC-3-V1	2.5	ε∥ (1 kHz, 20° C.): = 8.5
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	3.5	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	8.0	γ1 (20° C.): = 99 mPa · s
7	CCP-V2-1	1.0	K1 (20° C.): = 17.7 pN
8	CCPC-33	2.5	K3 (20° C.): = 18.4 pN
9	CLU-3-F	20.0	V0 (20° C.): = 1.84 V
10	PGUQU-3-F	4.0
11	PGUQU-4-F	6.0
12	PGUQU-5-F	2.0
13	PP-1-2V1	5.5

Mixture Example S76 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M76	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M77

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.5	T(N, I) = 100.9° C.
2	CC-3-V	28.5	Δn (589 nm, 20° C.): = 0.1116
3	CC-3-V1	1.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	8.0	γ1 (20° C.): = 94 mPa · s
7	CCPC-33	2.0	K1 (20° C.): = 17.7 pN
8	CLU-3-F	20.0	K3 (20° C.): = 18.1 pN
9	PGUQU-3-F	4.0	V0 (20° C.): = 1.83 V
10	PGUQU-4-F	6.0
11	PGUQU-5-F	2.0
12	PP-1-2V1	6.0

Mixture Example S77 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M77	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M78

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 101.8° C.
2	CC-3-V	24.5	Δn (589 nm, 20° C.): = 0.1116
3	CC-3-V1	7.0	ε∥ (1 kHz, 20° C.): = 8.7
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 6.0
6	CCP-V-1	7.0	γ1 (20° C.): = 94 mPa · s
7	CCPC-33	1.0	K1 (20° C.): = 18.1 pN
8	CLU-3-F	20.0	K3 (20° C.): = 18.3 pN
9	PGU-2-F	1.5	V0 (20° C.): = 1.83 V
10	PGUQU-3-F	4.0	LTS (−20° C.) 936 h
11	PGUQU-4-F	6.0
12	PGUQU-5-F	1.5
13	PP-1-2V1	3.5

Mixture Example S78 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M78	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M79

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	7.5	T(N, I) = 104.9° C.
2	CC-3-V	24.0	Δn (589 nm, 20° C.): = 0.1117
3	CC-3-V1	8.0	ε∥ (1 kHz, 20° C.): = 8.6
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 2.8
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	13.5	γ1 (20° C.): = 99 mPa · s
7	CCPC-33	2.0	K1 (20° C.): = 17.6 pN
8	CLU-3-F	16.0	K3 (20° C.): = 18.5 pN
9	PGU-2-F	5.0	V0 (20° C.): = 1.82 V
10	PGU-3-F	0.5
11	PGUQU-3-F	3.0
12	PGUQU-4-F	4.0
13	PGUQU-5-F	3.0
14	PP-1-2V1	1.5

Mixture Example S79 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M79	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M80

A nematic LC medium is formulated as follows:

	Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	2.0	T(N, I) = ° C.
2	BCH-32	9.0	Δn (589 nm, 20° C.): =
3	CC-3-V	19.5	ε∥ (1 kHz, 20° C.): =
4	CC-3-V1	10.0	ε⊥ (1 kHz, 20° C.): =
5	CCP-3-1	7.0	Δε (1 kHz, 20° C.): =
6	CCP-V-1	14.0	γ1 (20° C.): = mPa · s
7	CCPC-33	1.0	K1 (20° C.): = pN
8	CLP-3-T	2.5	K3 (20° C.): = pN
9	CLU-3-F	11.5	V0 (20° C.): = V
10	PCH-302	10.0
11	PGUQU-3-F	3.0
12	PGUQU-4-F	4.5
13	PGUQU-5-F	6.0

Mixture Example S80 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M80	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M81

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	9.0	T(N, I) = 102.4° C.
2	CC-3-V	25.5	Δn (589 nm, 20° C.): = 0.1111
3	CC-3-V1	6.0	ε∥ (1 kHz, 20° C.): = 8.5
4	CCP-3-1	10.0	ε⊥ (1 kHz, 20° C.): = 2.7
5	CCP-3-3	5.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-V-1	6.5	γ1 (20° C.): = 97 mPa · s
7	CCPC-33	1.5	K1 (20° C.): = 18.3 pN
8	CLU-3-F	20.0	K3 (20° C.): = 18.5 pN
9	PGUQU-3-F	4.0	V0 (20° C.): = 1.87 V
10	PGUQU-4-F	6.0
11	PGUQU-5-F	2.0
12	PP-1-2V1	4.5

Mixture Example S81 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M81	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-1	1000	ppm

Example M82

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	5.0	T(N, I) = 79.6° C.
2	CC-3-V	37.5	Δn (589 nm, 20° C.): = 0.1099
3	CCP-3-1	10.0	ε∥ (1 kHz, 20° C.): = 15.3
4	CCP-3-3	1.0	ε⊥ (1 kHz, 20° C.): = 3.6
5	CCP-30CF3	1.0	Δε (1 kHz, 20° C.): = 11.7
6	CCP-3F.F.F	1.0	γ1 (20° C.): = 79 mPa · s
7	CCP-V-1	3.5	K1 (20° C.): = 12.2 pN
8	CCPC-33	2.0	K3 (20° C.): = 13.4 pN
9	CLU-3-F	5.5	V0 (20° C.): = 1.07 V
10	DGUQU-4-F	0.5
11	PGU-2-F	4.5
12	PGUQU-3-F	5.0
13	PGUQU-4-F	7.0
14	PGUQU-5-F	4.0
15	PUQU-3-F	12.5

Mixture Example S82 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M82	99.95	wt.-%
	Compound of Formula ST-2-3	500	ppm

Example M83

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	APUQU-3-F	5.5	T(N, I) = 76.3° C.
2	CC-3-V	35.0	Δn (589 nm, 20° C.): = 0.1097
3	CC-3-V1	4.5	ε∥ (1 kHz, 20° C.): = 15.2
4	CCP-3-1	7.0	ε⊥ (1 kHz, 20° C.): = 3.5
5	CCP-30CF3	5.5	Δε (1 kHz, 20° C.): = 11.7
6	CLP-3-T	1.0	γ1 (20° C.): = 76 mPa · s
7	CLU-3-F	11.0	K1 (20° C.): = 12.2 pN
8	PGU-2-F	5.0	K3 (20° C.): = 13.1 pN
9	PGU-3-F	1.0	V0 (20° C.): = 1.07 V
10	PGUQU-3-F	5.5
11	PGUQU-4-F	7.5
12	PGUQU-5-F	2.5
13	PPGU-3-F	1.0
14	PUQU-3-F	8.0

Mixture Example S83 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M83	99.95	wt.-%
	Compound of Formula ST-2-3	500	ppm

Example M84

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.5	T(N, I) = 100° C.
2	CC-3-V1	11.5	Δn (589 nm, 20° C.): = 0.1109
3	CCG-V-F	2.0	ε∥ (1 kHz, 20° C.): = 8.8
4	CCH-23	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCH-301	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-1	7.0	γ1 (20° C.): = 103 mPa · s
7	CCP-30CF3	8.0	K1 (20° C.): = 17.6 pN
8	CCP-V-1	13.5	K3 (20° C.): = 18.1 pN
9	CLU-3-F	14.0	V0 (20° C.): = 1.82 V
10	CPGP-4-3	1.0	LTS (−20° C.) 1000 h
11	PCH-302	7.0
12	PGUQU-3-F	7.0
13	PGUQU-4-F	5.5
14	PP-1-2V1	3.0

Mixture Example S84 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M84	99.95	wt.-%
	Compound of Formula ST-2-3	500	ppm

Mixture Example S84a (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M84	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-22	1000	ppm

Mixture Example S84b (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M84	99.925	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-22	250	ppm

Example M85

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.5	T(N, I) = 100.5° C.
2	CC-3-V1	11.5	Δn (589 nm, 20° C.): = 0.1092
3	CCG-V-F	2.0	ε∥ (1 kHz, 20° C.): = 8.8
4	CCH-23	7.0	ε⊥ (1 kHz, 20° C.): = 2.9
5	CCH-301	7.0	Δε (1 kHz, 20° C.): = 5.8
6	CCP-3-1	7.0	γ1 (20° C.): = 112 mPa · s
7	CCP-30CF3	8.0	K1 (20° C.): = 17.5 pN
8	CCP-V-1	13.5	K3 (20° C.): = 18.1 pN
9	CLU-3-F	14.0	V0 (20° C.): = 1.82 V
10	CPGP-4-3	1.0	LTS (−20° C.) 1000 h
11	PCH-302	7.0
12	PGUQU-3-F(1)	7.0
13	PGUQU-4-F(1)	5.5
14	PP-1-2V1	3.0

Mixture Example S85 (Stabilised with Compound of Formula ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M85	99.95	wt.-%
	Compound of Formula ST-2-3	500	ppm

Mixture Example S85a (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M85	99.85	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-22	1000	ppm

Mixture Example S85b (Stabilised with Compounds of Formulae ST-2-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M85	99.925	wt.-%
	Compound of Formula ST-2-3	500	ppm
	Compound of Formula H-3-22	250	ppm

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T (N, I) = 80.5° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1120
	3	CC-3-V1	6.0	ϵ∥ (1 kHz, 20° C.): = 10.1
	4	CCP-3-1	5.0	ϵ⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δϵ (1 kHz, 20° C.): = 6.8
	6	PGP-2-3	5.0	γ1 (20° C.): = 62 mPa · s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.2 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
	9	PGUQU-4-F	6.0	V0 (20° C.): = 1.47 V
	10	PGUQU-5-F	4.5
	11	PPGU-(c5)-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
PPGU-(c5)-F

Example M86

A nematic LC medium is formulated as follows:

	Mixture M86	99.95	wt.-%
	Compound of Formula ST-2-3	500	ppm

Example M87

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T (N, I) = 80.5° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1119
	3	CC-3-V1	6.0	ϵ∥ (1 kHz, 20° C.): = 10.1
	4	CCP-3-1	5.0	ϵ⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F(1)	10.0	Δϵ (1 kHz, 20° C.): = 6.8
	6	PGP-2-3	5.0	γ1 (20° C.): = 66 mPa · s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.1 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
	9	PGUQU-4-F	6.0
	10	PGUQU-5-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
CLU-3-F(1)

Mixture Example S87 (Stabilised with Compounds of Formulae ST-2-3)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M87	99.95	wt.-%
	Compound of Formula ST-2-3	500	ppm

Example M88

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T (N, I) = 81° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1098
	3	CC-3-V1	6.0	ϵ∥ (1 kHz, 20° C.): = 10.0
	4	CCP-3-1	5.0	ϵ⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δϵ (1 kHz, 20° C.): = 6.7
	6	PGP-2-3	5.0	γ1 (20° C.): = 63 mPa · s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.1 pN
	8	PGUQU-3-F	5.0	K3 (20 C.): = 13.5 pN
	9	PGUQU-4-F	6.0
	10	APUQU-(c5)-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
APUQU-(c5)-F

Mixture Example S88 (Stabilised with Compounds of Formulae ST-1-3)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M88	99.97	wt.-%
	Compound of Formula ST-1-3	300	ppm

Example M89

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 80.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1104
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 9.9
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.6
6	PGP-2-3	5.0	γ1 (20° C.): = 64 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 13.6 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.7 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-(c5)-F	6.0
13	CCP-3-3	2.5
PUQU-(c5)-F

Mixture Example S89 (Stabilised with Compounds of Formulae ST-1-3 and H-3-7)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M89	99.85	wt.-%
	Compound of Formula ST-1-3	500	ppm
	Compound of Formula H-3-7	1000	ppm

Example M90

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 80° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1091
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.4
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 7.1
6	PGP-2-3	5.0	γ1 (20° C.): = 64 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 12.8 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.2 pN
9	PGUQU-4-F	6.0
10	DGUQU-(c5)-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5
DGUQU-(c5)-F

Mixture Example S90 (Stabilised with Compounds of Formulae ST-1-3 and H-3-22)

A nematic LC mixture according to the invention is formulated as follows:

	Mixture M90	99.85	wt.-%
	Compound of Formula ST-1-3	500	ppm
	Compound of Formula H-3-22	1000	ppm

Example M91

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 83.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1123
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.0
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.7
6	PGP-2-3	5.0	γ1 (20° C.): = 65 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 13.7 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
9	PGUQU-4-F	6.0
10	DPGU-(c5)-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5
DPGU-(c5)-F

Mixture Example S91 (Stabilised with Compounds of Formulae ST-1-3 and H-3-23)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M91                99.85 wt.-%
Compound of Formula ST-1-3 500 ppm
Compound of Formula H-3-23 1000 ppm

Example M92

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 82.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1109
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 9.9
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.6
6	PGP-2-3	5.0	γ1 (20° C.): = 66 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 13.8 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
9	PGUQU-4-F	6.0
10	DLGU-(c5)-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5
DLGU-(c5)-F

Mixture Example S92 (Stabilised with Compounds of Formulae ST-1-3 and H-3-7)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M92                99.85 wt.-%
Compound of Formula ST-1-3 500 ppm
Compound of Formula H-3-7  1000 ppm

Example M93

A nematic LC medium is formulated as follows:

Composition
Nr.	Comp.	Conc., wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 79.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1131
3	CC-3-V1	6.0	ε∥ (1 kHz, 20° C.): = 10.1
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
6	PUS-3-2	5.0	γ1 (20° C.): = 57 mPa · s
7	PGP-2-4	2.0	K1 (20° C.): = 13.2 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.3 pN
9	PGUQU-4-F	6.0
10	DUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5

Mixture Example S93 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M93                99.925 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  250 ppm

Example M94

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T(N, I) = 80° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1133
	3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.1
	4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
	6	PUS-(c5)-2	5.0	γ1 (20° C.): = 60 mPa•s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.1 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 13.3 pN
	9	PGUQU-4-F	6.0
	10	PGUQU-5-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
	PUS-(c5)-2

Mixture Example S94 (Stabilised with Compounds of Formulae ST-1-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M94                99.925 wt.-%
Compound of Formula ST-1-3 500 ppm
Compound of Formula H-3-1  250 ppm

Example M95

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T(N, I) = 79.5° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1123
	3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.1
	4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
	6	PUS-3-(c5)	5.0	γ1 (20° C.): = 59 mPa•s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.1 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 13.0 pN
	9	PGUQU-4-F	6.0
	10	PGUQU-5-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
	PUS-3-(c5)

Mixture Example S95 (Stabilised with Compounds of Formulae ST-2-3 and H-3-23)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M95                99.85 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-23 1000 ppm

Example M96

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 78° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1108
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.1
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
6	PUS-3-1(c5)	5.0	γ1 (20° C.): = 59 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 12.7 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 12.5 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5
PUS-3-1(c5)

Mixture Example S96 (Stabilised with Compound of Formulae ST-1-3

A nematic LC mixture according to the invention is formulated as follows:

Mixture M96                99.95 wt.-%
Compound of Formula ST-1-3 500 ppm

Example M97

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T(N, I) = 79° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1123
	3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.0
	4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.7
	6	PUS-3-O(c5)	5.0	γ1 (20° C.): = 60 mPa•s
	7	PGP-2-4	2.0	K1 (20° C.): = 12.9 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 12.9 pN
	9	PGUQU-4-F	6.0
	10	PGUQU-5-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
	PUS-3-O(c5)

Mixture Example S97 (Stabilised with Compound of Formulae ST-2-3

A nematic LC mixture according to the invention is formulated as follows:

Mixture M97                99.96 wt.-%
Compound of Formula ST-2-3 400 ppm

Example M98

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 79.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1123
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.0
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.7
6	PUS-3-O1(c5)	5.0	γ1 (20° C.): = 61 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 12.9 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.3 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5
PUS-3-O1(c5)

Mixture Example S98 (Stabilised with Compound of Formulae ST-4-1

A nematic LC mixture according to the invention is formulated as follows:

Mixture M98                99.96 wt.-%
Compound of Formula ST-4-1 400 ppm
ST-4-1

Example M99

A nematic LC medium is formulated as follows:

Composition
Nr.	Comp.	Conc., wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 81.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1148
3	CC-3-V1	6.0	ε∥ (1 kHz, 20° C.): = 10.1
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
6	PGS-2-1	5.0	γ1 (20° C.): = 58 mPa · s
7	PGP-2-4	2.0	K1 (20° C.): = 13.7 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.5 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5

Mixture Example S99 (Stabilised with Compound of Formulae ST-4-2

A nematic LC mixture according to the invention is formulated as follows:

Mixture M99                99.96 wt.-%
Compound of Formula ST-4-2 400 ppm
ST-4-2

Example M100

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T(N, I) = 81.5° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1150
	3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.1
	4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
	6	PGS-(c5)-1	5.0	γ1 (20° C.): = 61 mPa•s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.5 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
	9	PGUQU-4-F	6.0
	10	PGUQU-5-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
	PGS-(c5)-1

Mixture Example S100 (Stabilised with Compounds of Formulae ST-4-2 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M100               99.85 wt.-%
Compound of Formula ST-4-2 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M101

A nematic LC medium is formulated as follows:

	Composition
			Conc.,
	Nr.	Comp.	wt.-%	Properties
	1	BCH-32	6.0	T(N, I) = 81° C.
	2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1141
	3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.1
	4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
	5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.8
	6	PGS-2-(c5)	5.0	γ1 (20° C.): = 60 mPa•s
	7	PGP-2-4	2.0	K1 (20° C.): = 13.5 pN
	8	PGUQU-3-F	5.0	K3 (20° C.): = 13.1 pN
	9	PGUQU-4-F	6.0
	10	PGUQU-5-F	4.5
	11	PPGU-3-F	1.0
	12	PUQU-3-F	6.0
	13	CCP-3-3	2.5
	PGS-2-(c5)

Mixture Example S101 (Stabilised with Compounds of Formulae ST-4-1 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M101               99.85 wt.-%
Compound of Formula ST-4-1 500 ppm
Compound of Formula H-3-1  1000 ppm

Example M102

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 80.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1139
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.0
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.7
6	PUS-2-O(c5)	5.0	γ1 (20° C.): = 61 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 13.3 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.0 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	PUQU-3-F	6.0
13	CCP-3-3	2.5
PGS-2-O(c5)

Mixture Example S102 (Stabilised with Compounds of Formulae ST-1-3 and H-3-7)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M102               99.85 wt.-%
Compound of Formula ST-1-3 500 ppm
Compound of Formula H-3-7  1000 ppm

Example M103

A nematic LC medium is formulated as follows:

Composition
Nr.	Comp.	Conc., wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 81.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1090
3	CC-3-V1	6.0	ε∥ (1 kHz, 20° C.): = 10.2
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.9
6	PGP-2-3	5.0	γ1 (20° C.): = 62 mPa · s
7	PGP-2-4	2.0	K1 (20° C.): = 13.5 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	DUQU-3-F	6.0
13	CCP-3-3	2.5

Mixture Example S103 (Stabilised with Compounds of Formulae ST-4-1 and H-3-7)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M103               99.85 wt.-%
Compound of Formula ST-4-1 500 ppm
Compound of Formula H-3-7  1000 ppm

Example M104

A nematic LC medium is formulated as follows:

Composition
		Conc.,
Nr.	Comp.	wt.-%	Properties
1	BCH-32	6.0	T(N, I) = 81.5° C.
2	CC-3-V	41.0	Δn (589 nm, 20° C.): = 0.1088
3	CC-3-V1	6.0	ε|| (1 kHz, 20° C.): = 10.2
4	CCP-3-1	5.0	ε⊥ (1 kHz, 20° C.): = 3.3
5	CLU-3-F	10.0	Δε (1 kHz, 20° C.): = 6.9
6	PGP-2-3	5.0	γ1 (20° C.): = 65 mPa•s
7	PGP-2-4	2.0	K1 (20° C.): = 13.4 pN
8	PGUQU-3-F	5.0	K3 (20° C.): = 13.4 pN
9	PGUQU-4-F	6.0
10	PGUQU-5-F	4.5
11	PPGU-3-F	1.0
12	DUQU-(c5)-F	6.0
13	CCP-3-3	2.5
DUQU-(c5)-F

Mixture Example S104 (Stabilised with Compounds of Formulae ST-2-3 and H-3-1)

A nematic LC mixture according to the invention is formulated as follows:

Mixture M104               99.925 wt.-%
Compound of Formula ST-2-3 500 ppm
Compound of Formula H-3-1  250 ppm

Claims

1. A liquid-crystalline medium, comprising one or more compounds of Formula I

2. The medium according to claim 1, wherein the one or more antioxidant is a compound of Formula ST:

3. The medium according to claim 1, wherein the one or more light stabilizers is a compound of Formula H:

4. The medium according to claim 1, wherein the one or more compounds of the Formula I is selected from one of the following:

5. The medium according to claim 3, wherein the one or more compounds of the Formula H is selected from one of the following:

6. The medium according to claim 1, wherein it comprises one or more compounds selected from the following formulae:

7. The medium according to claim 1, comprising one or more compounds selected from the group consisting of the following formulae:

8. The medium according to claim 1, comprising one or more compounds selected from the group consisting of the following formulae:

9. The medium according to claim 8, wherein the one or more compounds of Formula II are selected from the following subformulae:

10. The medium according to claim 8, wherein the one or more compounds of Formula III are selected from the following subformulae:

11. The medium according to claim 1, wherein it additionally comprises one or more compounds selected from the group consisting of the following formulae:

12. The medium according to claim 1, wherein it comprises one or more compounds selected from the group consisting of the following formulae

13. The medium according to claim 1, comprising one or more compounds selected from the group consisting of the following formulae:

14. The medium according to claim 1, wherein it comprises one or more compounds of Formula I, one or more antioxidants and, optionally, one or more light stabilizer and one or more compounds selected from the group consisting of the Formulae Z1, Z2, Z3, Z4, Z5, II, III, IV, VI, XIV, XX, XII, XXIII, XXIX, XVI, XVIIa, XVIIb, XVIIc.

15. The medium according to claim 1, comprising one or more compounds of Formula I, one or more antioxidants and, optionally, one or more light stabilizer and one or more compounds selected from the group consisting of the Formulae LP1 and/or LP2.

16. The medium according to claim 1, comprising one or more compounds of Formula I, one or more antioxidants and, optionally, one or more light stabilizer and one or more compounds selected from the group consisting of the Formulae XXIX, XXX and XXVIIIa.

17. A process for the preparation of a liquid-crystalline medium according to claim 1, wherein one or more antioxidants and one or more light stabilizers are mixed with one or more mesogenic compounds and optionally one or more polymerizable compounds and/or one or more additives.

18. An electro-optical liquid-crystal display or an AR/VR headset containing a liquid-crystalline medium according to claim 1.

19. The electro-optical liquid-crystal display according to claim 18, wherein it comprises a TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, HB-FFS, XB-FFS, PS-HB-FFS, PS-XB-FFS, SA-HB-FFS, SA-XB-FS, polymer stabilised SA-HB-FFS, polymer stabilised SA-XB-FFS, positive VA or positive PS-VA display.