Information
-
Patent Grant
-
6527377
-
Patent Number
6,527,377
-
Date Filed
Tuesday, January 18, 200025 years ago
-
Date Issued
Tuesday, March 4, 200322 years ago
-
Inventors
-
Original Assignees
-
Examiners
Agents
- Fitzpatrick, Cella, Harper & Scinto
-
CPC
-
US Classifications
Field of Search
US
- 347 20
- 347 44
- 347 47
- 347 54
-
International Classifications
-
Abstract
A liquid discharge head having plural liquid paths and plural discharge openings is formed by joining an adhesion face of an orifice plate with an adhesion face of a head main body. The liquid paths are provided in the head main body, and the adhesion face of the head main body has apertures of the liquid paths. The adhesion face of the orifice plate has recessed portions and protruding portions. The protruding portions have a shape corresponding to the cross-sectional shape of the liquid paths, and the discharge openings are provided in the protruding portions. The protruding portions or parts thereof fit into the liquid paths, and are inserted into the liquid paths for joining the adhesion face of the orifice plate with the adhesion face of the head main body.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a liquid discharge head for discharging liquid and forming a flying liquid droplet thereby effecting recording, and formation of discharge opening (also called orifice) for discharging liquid. The present invention is applicable to an apparatus such as a printer for recording on a recording medium such as paper, yarn, fiber, fabrics, leather, metal, plastics, glass, timber, ceramics etc., a copying apparatus, a facsimile apparatus having communicating function, or a word processor having a printer unit, or an industrial recording apparatus combined in complex manner with various processing apparatus.
In the present invention, “recording” means not only providing the recording medium with a meaningful image such as a character or graphics but also providing with a meaningless image such as a pattern.
2. Related Background Art
The ink jet recording apparatus, effecting recording by discharging recording liquid (ink) from the orifice of the liquid discharge head, is already known to be excellent in low noise and high speed recording.
Such ink jet recording method has been proposed in various systems, some of which are already commercialized and some are still under development for commercialization.
The liquid discharge head for such recording method is for example composed, as shown in
FIGS. 6 and 7
, of an orifice plate
40
having an orifice for discharging the liquid, a ceiling plate
400
for forming a liquid path
401
communicating with the orifice, and a substrate
100
constituting a part of the liquid path and provided with an energy generating element
101
(hereinafter called heater) for generating energy for ink discharge.
The orifice plate
40
is provided with a small orifice
41
for discharging ink, and the orifice
41
constitutes an important element governing the discharging performance of the liquid discharge head. The orifice plate
41
of the liquid discharge head
40
is required to be satisfactorily workable in order to form the small orifice, and to have satisfactory ink resistance as it is in direct contact with the ink.
For meeting these requirements, there has conventionally been employed a metal plate such as of SUS, Ni, Cr or Al, or a resinous film material easily and inexpensively available in a desired thickness such as of polyimide, polysulfone, polyethersulfone, polyphenylene oxide, polyphenylene sulfide or polypropylene.
On the other hand, with the recent progress in the recording technology, there has been required recording with a higher speed and a higher definition, and, for this reason, the orifices
41
are being formed with a smaller size (orifice diameter) and with a higher density. As a result, there have been devised various methods for forming the orifice
41
, and, in case of using the resinous film, the orifice is formed with a laser beam which is suitable for fine working. Also in case of employing a metal plate, the orifice
41
is formed for example by electroforming.
However, it is extremely difficult to adjoin the orifice plate
40
having a small orifice and the corresponding liquid path
401
without a gap to the (neighboring orifice
41
.
For this reason, there has been employed a method of adhering the resinous film for forming the orifice to the main body of the head and then forming the orifice with the laser beam as disclosed in the Japanese Patent Application Laid-open No. 2-187342, or of employing a dry film or the like for the orifice plate, pressing the dry film in a softened state by heating into the adhering face of the main body of the head thereby pressing the softened orifice plate into the liquid path and forming the orifice by a photolithographic process or with a laser beam, as disclosed in the Japanese Patent Application Laid-open No. 2-204048.
The orifice of the liquid discharge head preferably has so-called tapered shape in which the diameter gradually decreases from the liquid path side to the discharge opening side, but, if the orifice plate after formation of the orifice of such tapered shape is adhered by applying adhesive resin for example by transfer method, such adhesive resin may intrude into the orifice to very the tapered shape thereof, thereby resulting in a drawback such as fluctuation in the direction of discharge. Also a bubble inclusion caused by defective contact induces insufficient adhesion in the partition to the neighboring orifice, thus resulting in defective liquid discharge.
Consequently, there is also adopted a method of forming a step in the vicinity of the orifice, in order that the adhesive resin does not intrude into the liquid path and the orifice, as disclosed in the Japanese Patent Application Laid-open No. 5-330061.
Furthermore, in case of adhering the orifice plate having the orifice to the adhering face of the main body of the head, the positional aberration may take place by the contraction of the adhesive resin at the hardening thereof. Therefore, as disclosed in the Japanese Patent Application Laid-open No. 2-78560, there is also adopted a method of forming surface irregularities on the adhering face of the orifice plate, in order to prevent the influence caused by the contraction of the adhesive resin at the hardening.
Also the main body of the liquid discharge head, to be adhered to the above-mentioned orifice plate, can be prepared for example by the following-method. On a silicon substrate, discharge energy generating elements are formed, and photosensitive resin for forming the liquid path walls is laminated thereon. Thereafter the photosensitive resin is patterned to form the desired liquid path walls. After the formation of the liquid path walls, a ceiling plate, composed for example of a glass plate, is laminated thereon to complete the liquid paths. Then the obtained laminated body is cut for example with a diamond blade to separate the liquid paths and to adjust the length thereof. Then the orifice plate is adhered for example an adhesive material in such a manner that the orifices communicate with the liquid paths to obtain the desired liquid discharge head.
FIG. 39
is a perspective view showing a conventional example of the liquid discharge head and
FIG. 40
is a plan view thereof.
In the liquid discharge head shown in
FIGS. 39 and 40
, liquid path walls
1301
and electrothermal converting elements
1303
serving as the discharge energy generating elements are formed on a silicon substrate
1309
, and a ceiling plate
1310
composed for example of a silicon substrate is adhered thereon. The laminated body is cut off with a diamond blade for the purpose of adjusting the position of the liquid paths
1302
, and an orifice plate
1307
is adhered with adhesive
1306
for example epoxy resin.
Also in such liquid discharge head, there has been a drawback that the adhesive employed for adhering the orifice plate enter and clog the liquid path. For this reason, there is adopted the method of forming a step in the vicinity of the orifice thereby preventing intrusion of the adhesive into the liquid and the orifice as disclosed in the Japanese Patent Application Laid-open No. 5-330061.
However, the above-described conventional configurations have been associated with the following drawbacks.
In pressing the softened resin into the liquid path at the adhering operation of the orifice plate to the main body of the head, the intruding amount of resin into the liquid path is difficult to control. As the orifices become smaller in diameter and higher in density, the resin intruding into the liquid path significantly influences the discharge performance, resulting in fluctuations of the discharge amount among the nozzles.
Also, with an increase in the density of the orifices and With the recovery operation of the orifice face surface, the distance between the orifices becomes shorter and, if the step structure is formed in the vicinity of the orifices in order to prevent intrusion of the adhesive resin therein, the adhesive strength between the orifices is lowered thereby deteriorating the durability of the liquid discharge head.
Also, with an increase in the density of the orifices, with the use of various inks and with the recovery operation of the orifice face, the adhesive strength between the orifice plate and the main body of the head unless the grooved portion is adhered, thereby deteriorating the durability of the liquid discharge head.
Also in case the resin film is employed for the orifice plate, the laser beam is advantageous for fine working such as orifice formation. However, if the laser working is executed after the orifice plate is adhered, dust such as carbon powder generated by the laser ablation enters the nozzles, thereby resulting in clogging of the orifice or solid deposition on the heater, leading to the defective liquid discharge.
Also in the conventional configuration where the length of the liquid path is adjusted by cutting the adhesion face, to the orifice plate, of the main body of the head, there may result intrusion of cut power and dusts into the liquid path and chipping or cracking of the cut face. Also if the step structure is formed in the vicinity of the orifice, the adhesion strength between the orifices is lowered thereby deteriorating the durability of the liquid discharge head.
SUMMARY OF THE INVENTION
In consideration of the foregoing, an object of the present invention is to provide a liquid discharge head and a producing method therefor, capable of resolving the aforementioned drawbacks in the conventional configurations, preventing the intrusion of the adhesive material into the orifice and the trapping of bubble in the vicinity of the orifice, improving the adhesion strength between the orifice plate and the main body of the head, and preventing the intrusion of dusts, such as carbon powder generated by laser ablation, into the liquid path.
Another object of the present invention is to provide a liquid discharge head and a producing method therefor, capable, in adjusting the length of the liquid path by cutting the adhesion face of the head main body with the orifice plate, of preventing intrusion of dusts and chipping of the cut face at the cutting operation, thereby ensuring a high process yield and improved print quality.
The above-mentioned objects can be attained, according to the present invention, by a liquid discharge head including:
an orifice plate having plural discharge openings for discharging liquid droplets, and
a head main body provided with plural liquid paths for respectively communicating with the plural discharge openings, a liquid chamber for liquid supply to the plural liquid paths, a supply aperture for liquid supply to the liquid chamber, and plural energy generating elements provided corresponding to the plural liquid paths and adapted to generate energy for discharging the liquid droplet, and formed by adjoining the orifice plate with an adhesion face of the head main body on which the apertures of the liquid paths for communicating with the discharge openings of the orifice plate;
wherein the orifice plate comprises a recessed portion and a protruding portion on the adhesion face with the head main body, and the protruding portion has a shape corresponding to the cross-sectional shape of the liquid path and is provided the discharge opening therein, and the protruding portion or a part thereof is made to enter and to fit with the liquid path of the head main body and the adhesion face of said orifice plate is adjoined with the adhesion face of the head main body.
According to the present invention there is also provided a method for producing a liquid discharge head formed by adjoining an orifice plate having plural discharge openings for discharging liquid droplets, and an adhesion face of a head main body provided with plural liquid paths for respectively communicating with the plural discharge openings, the method comprising steps of:
forming, on an adhesion face of the orifice plate with the head main body, a recess portion and a protruding portion of a shape matching the cross-sectional shape of the liquid path; and
inserting and fitting the protruding portion of the orifice plate or a part thereof into the liquid path of the head main body, and adjoining the orifice plate with the head main body thereby forming the liquid discharge head.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1
is a schematic cross-sectional view showing an example of the liquid discharge head embodying the present invention;
FIG. 2
is a schematic perspective view showing an example of the liquid discharge head embodying the present invention;
FIGS. 3A-1
,
3
A-
2
,
3
B-
1
,
3
B-
2
,
3
C-
1
,
3
C-
2
,
3
D-
1
and
3
D-
2
are schematic cross-sectional views showing an example of steps for forming the orifice plate in a first embodiment of the present invention;
FIGS. 4A-1
,
4
A-
2
,
4
B-
1
,
4
B-
2
,
4
C-
1
,
4
C-
2
,
4
D-
1
,
4
D-
2
,
4
E-
1
and
4
E-
2
are schematic cross-sectional views showing an example of steps for forming the orifice plate in a second embodiment of the present invention;
FIGS. 5A-1
,
5
A-
2
,
5
B-
1
,
5
B-
2
,
5
C-
1
and
5
C-
2
are schematic cross-sectional views showing an example of steps for forming the orifice plate in a third embodiment of the present invention;
FIG. 6
is an exploded perspective view showing an example of a conventional liquid discharge head;
FIG. 7
is a schematic cross-sectional view showing an example of a conventional liquid discharge head;
FIGS. 8A-1
,
8
A-
2
,
8
B-
1
,
8
B-
2
,
8
C-
1
and
8
C-
2
are schematic cross-sectional views showing an example of steps for forming the orifice plate of the present invention;
FIG. 9
is a schematic view of an apparatus embodying the present invention;
FIG. 10
is a perspective view of a liquid discharge head constituting a fourth embodiment of the present invention;
FIGS. 11A
,
11
B and
11
C are cross-sectional views showing steps for forming the orifice plate in a fourth embodiment of the present invention;
FIGS. 12A
,
12
B and
12
C are cross-sectional views showing steps for forming the liquid path in a fourth embodiment of the present invention;
FIG. 13
is a schematic cross-sectional view showing the configuration of the liquid discharge head of a sixth embodiment of the present invention;
FIGS. 14A
,
14
B and
14
C are views showing steps of forming the orifice plate shown in
FIG. 13
;
FIGS. 15A
,
15
B and
15
C are views showing steps of assembling the liquid discharge head shown in
FIG. 13
;
FIGS. 16A
,
16
B and
16
C are views showing steps for forming the orifice plate in a seventh embodiment of the present invention;
FIG. 17
is a partially broken schematic perspective view of the liquid discharge head of an eighth embodiment of the present invention;
FIG. 18
is a view of the head main body shown in
FIG. 17
, seen from a face where the orifice plate is to be adhered;
FIGS. 19A and 19B
are views showing the orifice plate shown in
FIG. 17
, respectively a view seen from the back side, and a cross-sectional view along a line
19
B—
19
B in
FIG. 19A
in a state coated with adhesive resin;
FIGS. 20A and 20B
are views showing the fitting structure of a protruding portion and a liquid path in a state where the head main body and the orifice plate are adhered in the liquid discharge head shown in
FIG. 17
, respectively a view seen from the common liquid chamber and a cross-sectional view along a line
20
B—
20
B in
FIG. 20A
;
FIG. 21
is a cross-sectional view of an orifice plate subjected to water-repellent treatment on the surface;
FIG. 22
is a cross-sectional view in a configuration where the adhesive resin is applied to the head main body, prior to the adhesion thereof to the orifice plate;
FIGS. 23A-1
,
23
A-
2
,
23
B-
1
,
23
B-
2
,
23
C-
1
, and
23
C-
2
are schematic views showing steps for forming the orfice plate in a ninth embodiment of the present invention;
FIGS. 24A
,
24
B,
24
C are schemetic cross-sectional views showing steps of adhesion of the orfice plate and the head main body in the ninth embodiment of the present invention;
FIGS. 25A and 25B
are schematic views showing steps for adhering the orifice plate and the head main body having a stepped portion;
FIGS. 26A-1
,
26
A-
2
,
26
B-
1
,
26
B-
2
,
26
C-
1
and
26
C-
2
are schematic views showing an example of steps for forming the orifice plate in a tenth embodiment of the present invention;
FIGS. 27A
,
27
B and
27
C are schematic cross-sectional views showing steps of adhesion of the orifice plate and the head main body in the tenth embodiment of the present invention;
FIGS. 28A-1
,
28
A-
2
,
28
B-
1
,
28
B-
2
,
28
C-
1
and
28
C-
2
are schematic views showing steps for forming the orifice plate of the present invention;
FIGS. 29A-1
,
29
A-
2
,
29
B-
1
,
29
B-
2
,
29
C-
1
and
29
C-
2
are schematic views showing an example of steps for forming the orifice plate in an eleventh embodiment of the present invention;
FIG. 30
is a schematic perspective view showing the configuration of the liquid discharge head in a twelfth embodiment of the present invention;
FIG. 31
is a schematic cross-sectional view showing the features of the liquid discharge head of the twelfth embodiment of the present invention;
FIG. 32
is a schematic view of a diamond blade and a fixing flange unit therefor in a dicing machine for the IC's generally formed on a silicon wafer;
FIGS. 33A
,
33
B and
33
C are views comparing examples of the adhesion face, to be adhered to the orifice plate, of the head main body prepared by the method according to the twelfth embodiment of the present invention;
FIGS. 34A-1
,
34
A-
2
,
34
B-
1
,
34
B-
2
,
34
C-
1
,
34
C-
2
,
34
D-
1
and
34
D-
2
are views showing steps of forming the orifice plate shown in
FIGS. 30 and 31
;
FIGS. 35A
,
35
B,
35
C and
35
D are schematic cross-sectional views showing steps for forming the liquid discharge head in a variation of the twelfth embodiment of the present Invention;
FIG. 36
is a perspective view showing an example of the head cartridge utilizing the liquid discharge head of the present invention;
FIG. 37
is a schematic perspective view of a liquid discharge recording apparatus of serial type utilizing the liquid discharge head of the present invention;
FIG. 38
is a schematic perspective view of a liquid discharge recording apparatus of full-line type utilizing the liquid discharge head of the present invention, and
FIGS. 39 and 40
are perspective views of conventional liquid discharge heads.
For ease of reference hereinbelow, drawings labeled such as
FIGS. 3A-1
and
3
A-
2
,
FIGS. 3B-1
and
3
B-
2
, etc. are referred to collectively as
FIG. 3A
,
FIG. 3B
, etc.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
[First Embodiment]
According to the present invention, a protruding portion is provided around the orifice, extending in the direction of the liquid path and having a cross section matching that of the liquid path, and such protruding portion or a part thereof is made to enter the liquid path to prevent the flow of the adhesive resin into the orifice portion. Also the adhesion face of the orifice plate, to be adhered to the main body of the head, is formed as a recess to prevent the flow of the adhesive resin into the liquid path and the inclusion of bubbles. Furthermore, the adhesive resin is made to enter the above-mentioned groove or a part thereof thereby improving the adhesion force between the orifice plate and the main body of the head.
Also, as the orifice formation can be executed prior to the adhesion to the main body of the head, there can be prevented intrusion of dusts, generated by laser ablation etc., into the liquid path. Furthermore, the present invention can drastically reduce the positional aberration between the liquid path and the orifice, resulting from the difference in the thermal expansion ratio when the orifice plate and the main body of the head are heated to a high temperature.
Furthermore, according to the present invention, the communication aperture of the liquid path, to communicate with the discharge opening port of the orifice plate, is formed by at first cutting the adhesion face of the main body of the head for adhesion with the orifice plate in consideration of the distance to the liquid path, and then forming such communication aperture to be adhered to the orifice plate, thereby dust intrusion or chipping of the communication aperture at the cutting operation.
In the following there will be schematically explained the configuration of the liquid discharge head of the present invention.
FIG. 1
is a schematic cross-sectional view of the liquid discharge head constituting a first embodiment of the present invention, and
FIG. 2
is a schematic perspective view thereof.
The liquid discharge head shown in
FIGS. 1 and 2
is provided with a head main body (not shown) formed by adhering a ceiling plate
400
integrally having a liquid path
401
and a liquid chamber
402
, and a substrate (hereinafter called heater board)
100
bearing an energy generating element (hereinafter called heater)
100
for generating discharge energy and Al wirings for supplying the element with an electrical signal, both formed by the film forming technology on a silicon substrate, and an orifice plate
40
to be explained later is adhered as illustrated to an aperture face (hereinafter called adhesion face for the head main body)
44
formed by the above-mentioned adhesion and having an aperture of the liquid path
401
for each unit. The orifice plate
401
is preferably composed of a metal film such as of stainless steel or Ni, or of a plastic film of satisfactory ink resistance such as of polyimide, polysulfone, polyethersulfone, polyphenylene oxide, polyphenylene sulfide or polypropylene.
The orifice plate
40
is provided with a protruding portion
45
matching the Cross section of the liquid path in the direction of arrangement of the liquid paths, and such protruding portion
45
is fitted in the liquid path
401
. In such configuration, the protruding portion
45
limits the positional aberration between the orifice and the liquid path, generated in the setting step of the adhesive material or resulting from the temperature change when the heater is activated.
In the present embodiment, the orifice plate was composed of a PSF film of a thickness of 50 μm.
Also in the present embodiment, for adhering the orifice plate and the main body of the head, there was employed epoxy adhesive resin which is shifted to the B-stage with completed shrinkage under UV irradiation while maintaining the tackiness and is hardened by additional UV irradiation or heating. This adhesive material can also achieve adhesion by heating and pressing only.
In the following the first embodiment of the present invention will be explained with reference to
FIGS. 3A
to
3
D.
The orifice plate
40
was worked with the laser light of a KrF laser with a wavelength of 248 nm, and the recess, groove and orifice were formed by an apparatus shown in
FIG. 9
, in which provided are an excimer laser
10
, a lens
11
for condensing the laser beam
12
emitted from the excimer laser
10
, a mask
13
positioned between the excimer laser
10
and the orifice plate
40
, and an orifice plate
40
on which the recess, groove and orifice are to be formed.
In the following there will be explained steps for forming the liquid discharge head of the present embodiment.
At first a recess
46
was formed on the orifice plate
40
with a depth of 10 μm in such a manner that plural protruding portions
45
are arranged linearly with a pitch of 600 dpi and with a size of 30×30 μm, and grooves
43
were formed with a width of 20 μm and a depth of 20 μm from the bottom of the recess
46
, at a position separated by 30 μm from the protruding portions
45
, thereby forming the adhesion face, having the recess
46
and the grooves
43
, for adhesion with the main body of the head (FIG.
3
B).
Then epoxy adhesive material, which is shifted to the B-stage with completed shrinkage under UV irradiation while maintaining the tackiness and can be adhered by heating and pressing, was uniformly sprayed on thus worked adhesion face of the orifice plate
40
for adhesion with the main body of the head. Then ultraviolet irradiation was conducted with a power of 1 mW/cm
2
for 60 seconds to shift the adhesive to the B-stage thereby completing the setting and shrinkage of the adhesive (FIG.
3
C).
Subsequently the irradiation with the excimer laser beam was conducted from the side of the adhesion face of the orifice plate
40
, thereby forming an orifice
41
of a diameter of 22 μm in each protruding portion (FIG.
3
D). The protruding portion
45
provided around the orifice was made to enter the liquid path of the head main body, including the liquid paths
401
, the element substrate
100
and the ceiling plate
400
and the orifice plate
40
was adjoined at the recess
46
.
Then the orifice plate
40
was maintained in close contact with the main body of the head by applying a pressure of 1 kg/cm
2
from the orifice face, and heating was made to 60° C. while such pressed state was maintained to complete the hardening of the adhesive.
The liquid discharge head after the adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate. The observation, made through the orifice plate, of the adhesion state of the main body of the head and the orifice plate proved the absence of trapped bubble in the adhesion face around the orifice. Also the liquid discharge head, when disassembled and observed, proved absence of any undesirable substance in the orifice or in the liquid path.
[Second Embodiment]
A second embodiment of the present invention will be explained with reference to
FIGS. 4A
to
4
E.
The orifice plate
40
was worked with the KrF excimer laser of a wavelength of 248 nm as in the first embodiment, and the recess, groove and orifice were formed by the apparatus shown in FIG.
9
.
At first a recess
46
was formed on the orifice plate
40
with a depth of 10 μm in such a manner that plural protruding portions
45
are arranged linearly with a pitch of 1200 dpi and with a size of 15 μm×15 μm, thereby forming the adhesion face, having the recess
46
, for adhesion with the main body of the head (FIG.
4
B).
Then epoxy adhesive material, which is shifted to the B-stage with completed shrinkage under UV irradiation while maintaining the tackiness and can be adhered by heating and pressing, was uniformly sprayed on thus worked adhesion face of the orifice plate
40
for adhesion with the main body of the head. Then ultraviolet irradiation was conducted with a power of 1 mW/cm
2
for 60 seconds to shift the adhesive to the B-stage thereby completing the setting and shrinkage of the adhesive (FIG.
4
C).
Subsequently the irradiation with the excimer laser beam was conducted from the side of the adhesion face of the orifice plate
40
, thereby forming an orifice
41
of a diameter of 11 μm in each protruding portion and a groove
43
of a width of 20 μm and a depth of 20 μm from the bottom of the recess
46
in a position in the recess
46
at a distance of 20 μm from the protruding portion (FIG.
4
E). In the present embodiment, the orifice
41
and the groove
43
were formed simultaneously, but they can also be formed separately. The protruding portion
45
provided around the orifice was made to enter the liquid path of the head main body, including the liquid paths
401
, the element substrate
100
and the ceiling plate
400
and the orifice plate
40
was adjoined at the recess
46
.
Then the orifice plate
40
was maintained in close contact with the main body of the head by applying a pressure of 1 kg/cm
2
from the orifice face, and heating was made to 60° C. while such pressed state was maintained to complete the hardening of the adhesive.
The sample thus obtained was subjected to evaluation as in the first embodiment. The liquid discharge head after adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate. The observation, made through the orifice plate, of the adhesion state of the main body of the head and the orifice plate proved the absence of trapped bubble in the adhesion face around the orifice. Also the liquid discharge head, when disassembled and observed, proved absence of any undesirable substance in the orifice or in the liquid path.
[Third Embodiment]
A third embodiment of the present invention will be explained with reference to
FIGS. 5A
to
5
C.
The orifice plate
40
was worked with the KrF excimer laser of a wavelength of 248 nm as in the first embodiment, and the recess, groove and orifice were formed by the apparatus shown in FIG.
9
.
At first a recess
46
was formed on the orifice plate
40
with a depth of 10 μm in such a manner that plural protruding portions
45
are arranged linearly with a pitch of 1200 dpi and with a size of 15 μm×15 μm, thereby forming the adhesion face, having the recess
46
, for adhesion with the main body of the head (FIG.
5
B).
Subsequently the irradiation with the excimer laser beam was conducted from the side of the adhesion face of the orifice plate
40
, thereby forming an orifice
41
of a diameter of 11 μm in each protruding portion and grooves
43
of a width of 20 μm and a depth of 20 μm from the bottom of the recess
46
in a position in the recess
46
at a distance of 20 μm from the protruding portion (FIG.
5
C).
Then epoxy adhesive material, which is shifted to the B-stage with completed shrinkage under UV irradiation while maintaining the tackiness and can be adhered by heating and pressing, was uniformly applied by transfer method onto thus worked adhesion face of the orifice plate
40
for adhesion with the main body of the head. Then ultraviolet irradiation was conducted with a power of 1 mw/cm
2
for 60 seconds to shift the adhesive to the B-stage thereby completing the setting and shrinkage of the adhesive (FIG.
4
C).
The protruding portion
45
provided around the orifice was made to enter the liquid path of the head main body, including the liquid paths
401
, the element substrate
100
and the ceiling plate
400
and the orifice plate
40
was adjoined at the recess
46
.
Then the orifice plate
40
was maintained in close contact with the main body of the head by applying a pressure of 1 kg/cm
2
from the orifice face, and heating was made to 60° C. while such pressed state was maintained to complete the hardening of the adhesive.
The sample thus obtained was subjected to evaluation as in the first embodiment. The liquid discharge head after adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate. The observation, made through the orifice plate, of the adhesion state of the main body of the head and the orifice plate proved the absence of trapped bubble in the adhesion face around the orifice. Also the liquid discharge head, when disassembled and observed, proved absence of any undesirable substance in the orifice or in the liquid path.
The present embodiment may be so modified that the groove is formed in a pattern (circle, rectangle or tetragon) as shown in
FIGS. 8A
to
8
C, or that the external periphery of the protruding portion of the orifice plate is tapered as shown in
FIG. 8C
, or that a groove is formed between the discharge openings as shown in FIG.
8
A.
[Fourth Embodiment]
FIG. 10
is a perspective view of a liquid discharge head, constituting a fourth embodiment of the present invention.
In
FIG. 10
there are shown a silicon substrate
1009
constituting the recording head and provided with an electrothermal converting element
1003
for discharging ink; an orifice plate
1007
, a projection
1005
formed on the orifice plate; an orifice
1008
; a liquid path wall
1001
formed by patterning photosensitive resin laminated on the silicon substrate
1009
; a ceiling plate
1010
consisting of a silicon substrate; a liquid path
1002
; and a communication aperture
1004
to be used for adhesion with the orifice plate and formed by laser beam irradiation after cutting with the diamond blade. The present embodiment will be explained in detail with reference to the attached drawings.
FIGS. 11A
to
11
C are views showing steps for forming the above-described orifice plate, wherein shown are a resin film
1101
, a projection
1102
and an orifice
1103
.
At first the resinous film
1101
having satisfactory ink resistance and rigidity such as of polysulfone or polyimide is subjected to the irradiation with the excimer laser beam to form the projection
1102
. The irradiation was executed by the imaging method through a mask defining the dimension of the projection, but there may also be utilized the focusing method utilizing a galvanometer. In the laser working, it is already known that a tapered shape of an angle of several degrees is obtained by the by products formed at the working, and such tapered shape is utilized for effecting adhesion with the liquid path to be explained later. In the present embodiment, the projections were formed with an external diameter of 28 μm, a height of 23 μm and with a pitch of 70.5 μm.
Then an orifice
1103
is formed to obtain the orifice plate shown in FIG.
11
C. The formation of the orifice
1103
can be formed without positional aberration with respect to the projection, after the formation thereof, with the above-mentioned excimer laser beam without varying the relative position to the optical axis thereof but simply replacing the mask only. In the present embodiment the entrance diameter of the laser beam was selected as 26 μm and the orifice
1103
could be formed on the projection with a tolerance of ±1 μm.
FIGS. 12A
to
12
C are views showing steps for producing the above-described liquid discharge head.
As shown in
FIG. 12A
, liquid paths
1202
are defined by liquid path walls
1201
formed by patterning photosensitive resin on a silicon substrate. Subsequently the liquid paths are cut with a diamond blade into a desired size. As apertures
1204
for communication with an orifice plate
1207
are not formed in this state, there is not observed burrs or chipping generated at the cutting operation, or intrusion of cut powder or dusts into the liquid paths
1202
. Then, for adhering the orifice plate
1207
, adhesive material
1206
consisting of epoxy resin is coated by transfer method on the entire surface of the front end of the liquid paths. Also in this state, as the communication apertures
1204
are not yet formed, the adhesive material does not enter the liquid paths
1202
.
Then the front end portion of the liquid path is irradiated with the excimer laser beam through a mask, as in the formation of the orifice
1208
and the projection
1205
of the orifice plate
1207
, thereby forming the communication aperture
1204
to be used for adhesion with the orifice plate
1207
. The size of the communication aperture
1204
is selected as about 10 μm, in consideration of the size of the projection
1205
. As the adhesive material
1207
is coated prior to the formation of the communication aperture
1204
, there can be removed the excessive adhesive entering the liquid path. As a result, there can be obtained a shape as shown in FIG.
12
B.
Thereafter the projection
1205
of the orifice plate
1207
is aligned with the communication aperture
1204
at the front end of the liquid path and is adhered by the adhesive material
1206
. The alignment can be easily achieved by mutually fitting the projection
1205
of the orifice plate
1207
with the communication aperture
1204
at the front end of the liquid path. The adhesion was executed by heating for temporary adhesion after pressurizing so as to avoid bubble inclusion, followed by main hardening. Such adhering operation allowed to obtain the liquid discharge head as shown in
FIG. 12C
, without intrusion of the adhesive material. The recording operation with thus obtained liquid discharge head provided satisfactory result, without failure in the liquid discharge induced by the intrusion of the adhesive material or by dusts generated at the cutting operation, and without defective printing caused by burrs or chipping.
[Fifth Embodiment]
In the following there will be explained a fifth embodiment of the present invention.
At first a resinous material with satisfactory ink resistance or rigidity, such as polysulfone or polyimide, is injection molded to obtain a thin plate of a shape as shown in
FIG. 11B
or
11
C. In the injection molding method, the mold is provided with a tapered shape of several degrees, called the extracting inclination, and the molded thin plate is released by such tapered shape. The tapered shape is transferred to the molded article and is utilized for adjoining with the liquid path.
Also the aforementioned orifice formation can be dispensed with if the orifice plate is molded in the shape shown in
FIG. 11C
by the injection molding.
In the present embodiment, there could be obtained the orifice plate of a thickness of 75 μm, with a mold temperature of 160° C. and an injection speed of 400 mm/sec.
Thereafter the formation of the liquid path and the adhesion of the orifice plate are conducted in the same manner as in the foregoing embodiments.
The recording operation with thus obtained liquid discharge head provided satisfactory result, without failure in the liquid discharge induced by the intrusion of the adhesive material or by dusts generated at the cutting operation, and without defective printing caused by burrs or chipping.
[Sixth Embodiment]
FIG. 13
is a schematic cross-sectional view showing the configuration of a liquid discharge head constituting a sixth embodiment of the present invention.
As shown in
FIG. 13
, the liquid discharge head of the present embodiment is provided with a main body formed by adhering a ceiling plate
400
integrally having grooves for forming the liquid path
401
and the liquid chamber (not shown), and a substrate (heater board)
100
. The heater board
100
is obtained by forming, on an Si substrate, an energy generating element (heater)
101
for generating discharge energy and Al wirings (not shown) for supplying the element with an electrical signal, by film forming technology.
On an aperture face
44
(called adhesion face to the head main body) of the main body of the head, where the liquid path is opened, the orifice plate
40
is adjoined with adhesive resin
42
. The orifice plate
40
is provided with plural orifices (discharge openings)
41
for discharging ink. Each orifice is so positioned as to communicate with a corresponding liquid path
401
. Also in the present embodiment, a face of the orifice plate
40
to be adhered to the main body of the head is provided with an insertion portion
45
which, including the orifice
41
, is inserted into the liquid path
401
. The external shape of the inserting portion
45
is so formed as to spread from the base part to the end part thereof.
The orifice plate
40
is preferably composed of a metal film such as of stainless steel or Ni, or a plastic film of satisfactory ink resistance such as of polyimide, polysulfone (PSF), polyethersulfone, polyphenylene oxide, polyphenylene sulfide or polypropylene. Otherwise the orifice plate
40
may be formed with silicon (Si) or a ceramic material. In the present embodiment, the orifice plate
40
is composed of a PSF film of a thickness of 50 μm.
Also in the present embodiment, a beveled portion
47
is provided on the edge of the aperture of the liquid path
401
in the head main body. Also in the present embodiment, as the adhesive resin
42
for adhering the orifice plate
40
, there is employed epoxy resin of photosetting or thermo-setting that can be hardened by ultraviolet (UV) irradiation, infrared irradiation or heating.
FIGS. 14A
to
14
C are views showing steps for forming the orifice plate shown in FIG.
13
.
The formation of the orifice plate
40
is executed by the apparatus shown in
FIG. 9
, by at first irradiating a face of an orifice plate base member
48
, for constituting the adhesion face with the head main body, with a laser beam
12
(
FIG. 14A
) to form a recess, excluding the inserting portion
45
of the orifice plate
40
, with a depth of 10 μm from the top of the inserting portion
45
, thereby forming the adhesion face
35
with the head main body (FIG.
14
B).
Then the excimer laser beam
12
is directed from the side of the adhesion face of the orifice plate
40
to form an orifice
41
in each inserting portion
45
(FIG.
14
C).
In this manner the orifice plate
40
shown in
FIG. 13
is obtained by laser working. In the present embodiment, the plural inserting portions
45
are formed linearly with a pitch of 600 dpi, on the adhesion face of the orifice plate
40
with the head main body.
In the following there will be explained the assembling steps of the liquid discharge head shown in
FIG. 13
, with reference to
FIGS. 15A
to
15
C.
In assembling the liquid discharge head, as shown in
FIG. 15A
, at first the epoxy adhesive resin is uniformly coated on a resin sheet or a rubber sheet (both not shown), and the adhesive resin on the sheet is transferred onto the adhesion face (adhesion face
44
) of the head main body with the orifice plate
40
. Then the adhesive resin
42
, coated on the adhesion face
44
of the main body of the head, is irradiated with ultraviolet light, whereby the adhesive resin
42
is shifted to the B-stage and completes setting and shrinkage.
Then the inserting portion
45
, provided around the orifice
41
in the orifice plate
40
, is inserted into the liquid path
401
of the main body of the head, formed by the element substrate
100
and the ceiling plate
400
.
As the edge portion of the liquid path
401
has a beveled portion
47
(cf. FIG.
15
A), even if the front end of the inserting portion
45
interferes with the edge of the liquid path
401
, the inserting portion
45
can be smoothly inserted into the liquid path
401
by pressing in the orifice plate
40
. Consequently the inserting portion
45
can be inserted into the liquid path
401
in a state in which the end of the inserting portion
45
is maintained in contact with the internal surface of the liquid path
401
. It is therefore possible to prevent intrusion of the adhesive resin
42
into the orifice
41
and the liquid path
401
, at the adhering step of the orifice plate
40
.
Finally, the orifice plate
40
is pressed to the main body of the head by a pressure of 1 kg/cm
2
on the orifice plate
40
, and heating is executed at 60° C. in such pressed state, thereby hardening the adhesive resin
42
.
The liquid discharge head of the present embodiment can be prepared through the above-described steps.
In the liquid discharge head of the present embodiment, the inserting portion
45
including the orifice
41
is inserted into the liquid path
401
and the end part of the inserting portion
45
is in contact with the internal wall of the liquid path
401
, so that the liquid (ink) flow from the liquid path
401
to the orifice
41
is hardly hindered and satisfactory liquid discharge can be realized in stable manner.
Also in the present embodiment, the external shape of the inserting portion
45
provided on the orifice plate
40
is so formed as to expand from the base part to the end part. Consequently the adhesive resin
42
is filled in the gap between the base part of the inserting portion
45
, inserted into the liquid path
401
, and the internal walls of the liquid path
401
to increase the adhesion strength between the orifice plate
40
and the main body of the head in the vicinity of the orifice
41
. In addition, even if the linear expansion coefficient of the orifice plate
40
is larger than that of the main body of the head, no force is generated in a direction to expel the inserting portion
45
from the liquid path
401
of the head main body when the inserting portion
45
expands at the thermal hardening step of the adhesive resin
42
, so that there can be prevented the positional aberration between the orifice plate
40
and the main body of the head at the adhering step, resulting from the difference in the linear expansion coefficient therebetween. Therefore, the liquid discharge head of the present embodiment can execute the liquid discharge in satisfactory and stable manner.
The liquid discharge head after adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate. Also the liquid discharge head, when disassembled and observed, proved absence of any undesirable substance such as adhesive resin
42
in the orifice
41
or in the liquid path
401
.
In the present embodiment, there has been explained the method of irradiating the adhesive resin
42
with ultraviolet light thereby shifting it to the B-stage, but there may also be employed resin which is shifted to the B-stage by infrared irradiation of a predetermined wavelength. Otherwise, the adhesive resin
42
may also be composed of resin which is shifted to the B-stage by heating.
[Seventh Embodiment]
FIGS. 16A
to
16
C are views showing steps for forming the orifice plate in the liquid discharge head of a seventh embodiment of the present invention.
The orifice plate
140
in the present embodiment is formed at first by laminating photosensitive resin
146
of negative working type with satisfactory ink resistance, on a face of an orifice plate base member
148
consisting of a polysulfone sheet, for constituting the adhesive face with the main body of the head. Then, on the photosensitive resin
146
, there is formed a resist
142
having the pattern for forming an inserting portion
145
in the photosensitive resin
146
(FIG.
16
A).
Then the orifice plate
140
is irradiated with a laser beam
112
(
FIG. 16B
) and the photosensitive resin
146
is exposed and developed to form the inserting portion
145
therein.
Then the excimer laser beam is irradiated from the side of the adhesion face of the orifice plate
140
with the main body of the head, thereby forming an orifice
141
in each inserting portion
145
(FIG.
16
C). The orifice
141
is formed, with the apparatus shown in
FIG. 9
, by irradiation of the KrF excimer laser beam of a wavelength of 248 nm. Thus the orifice plate
140
of the present embodiment is formed through the photolithographic process.
The orifice plate
140
thus obtained is adhered to the main body of the head, through a process same as the assembling process explained with reference to
FIGS. 15A
to
15
C.
Also in the liquid discharge head of the present embodiment, as in the sixth embodiment, the inserting portion
145
including the orifice
141
is inserted into the liquid path (not shown) and the end part of the inserting portion
145
is in contact with the internal wall of the liquid path, so that the liquid (ink) flow from the liquid path to the orifice
141
is hardly hindered and satisfactory liquid discharge can be realized in stable manner.
Further, also in the present embodiment, the external shape of the inserting portion
145
is so formed as to expand from the base part to the end part. Consequently the adhesive resin (not shown) is filled in the gap between the base part of the inserting portion
145
, inserted into the liquid path, and the internal walls of the liquid path to increase the adhesion strength between the orifice plate
140
and the main body of the head in the vicinity of the orifice
141
. In addition, there can be prevented the positional aberration between the orifice plate
140
and the main body of the head at the adhering step, resulting from the difference in the linear expansion coefficient therebetween.
In the foregoing embodiments, the orifice plate
40
,
140
is formed by a laser working process or a photolithographic process, but the orifice plate of the present invention may also be formed for example by press molding utilizing a mold.
[Eighth Embodiment]
In the above-described configuration of providing the orifice plate with a protruding portion and fitting the protruding portion into the liquid path, the fitting may not be achieved satisfactorily depending on the environmental temperature, in case the head main body and the orifice plate having different linear expansion coefficients are adjoined. Such situation becomes conspicuous when thermosetting adhesive is employed. Also in the above-described configuration, the fitting may not be achieved satisfactorily with an increase in the density of the orifices, as the tolerance of the fitting becomes stricter. Particularly in case a large number of orifices are formed linearly as in the full-line head, the amount of positional aberration increases at both ends, so that the defective fitting tends to occur.
In the present embodiment, therefore, there is provided a liquid discharge head and a producing method therefor, capable of securely adjoining the orifice plate and the main body of the head even in the presence of a change in the environmental temperature, while adopting a configuration for preventing the intrusion of the adhesive resin into the liquid path at the adhesion of the orifice plate and the main body of the head with adhesive resin.
The liquid discharge head of the present embodiment, provided with a head main body in which plural liquid paths, respectively provided with energy generating elements for generating energy for liquid discharge and arranged in mutually parallel manner, are opened on an end face, and an orifice plate, which is adhered to the above-mentioned end face of the head main body with an adhesive material, and is provided with orifices communicating with the liquid paths and with plural protruding portions fitting with the liquid paths, in positions respectively corresponding to the liquid path:
wherein pitch A of arrangement of the liquid paths, width B of the liquid path, width C of the protruding portion in the direction of arrangement, height D of the liquid path, width E of the protruding portion in a direction perpendicular to the direction of arrangement thereof, linear expansion coefficient a of the head main body, linear expansion coefficient b of the orifice plate, number n of the liquid paths, and environmental temperature difference Δt between before and after the adhesion of the head main body and the orifice plate satisfy the following two conditions:
(
B−C
)/2≧|(
a−b
)
×n×A×Δt|,
and
(
D−E
)/2≧|(
a−b
)
×D×Δt|.
Also the method of the present embodiment for producing the liquid discharge head comprises:
a step of preparing a head main body in which plural liquid paths, respectively provided with energy generating elements for generating energy for liquid discharge and arranged in mutually parallel manner, are opened on an end face;
a step of forming, on an adhesion face to be adhered to the head main body of an orifice plate to be adhered to the end face of the head main body, plural protruding portions adapted to fit with the liquid paths in such a manner that pitch A of arrangement of the liquid paths, width B of the liquid path, width C of the protruding portion in the direction of arrangement, height D of the liquid path, width E of the protruding portion in a direction perpendicular to the direction of arrangement thereof, linear expansion coefficient a of the head main body, linear expansion coefficient b of the orifice plate, number n of the liquid paths, and environmental temperature difference Δt between before and after the adhesion of the head main body and the orifice plate satisfy the following two conditions:
(
B−C
)/2≧|(
a−b
)
×n×A×Δt|,
and
(
D−E
)/2≧|(
a−b
)
×D×Δt|;
a step of coating adhesive resin on the adhesion face of the orifice plate, having the protruding portions, with the head main body or on the adhesive face of the orifice plate with the head main body,
a step of forming an orifice in each protruding portion;
a step of fitting the protruding portions respectively with the liquid paths thereby contacting the head main body with the orifice plate under pressure; and
a step of hardening the adhesive resin in a state where the head main body and the orifice plate are in contact under pressure.
In the above-described configuration, protruding portions containing orifices are formed in the adhesion face of the orifice plate with the main body of the head and are fitted in the liquid path to adjoin the main body of the head and the orifice plate. Therefore, even when the liquid paths are arranged with a high density, the orifice plate and the main body of the head can be adjoined with satisfactory alignment between the liquid paths and the orifices and without intrusion of the adhesive resin into the orifices or liquid paths. In the liquid discharge head of the present embodiment, the materials constituting the orifice plate and the main body of the head and the dimensions of the fitting portions thereof are so determined as to satisfy the foregoing two conditions in consideration of the change in environmental temperature between before and after the adhesion of he head main body and the orifice plate, so that there can be prevented the failure in the fitting of the protruding portions and the liquid paths resulting from the difference in the linear expansion coefficient between the main body of the head and the orifice plate.
Also in the method for producing the liquid discharge head, the orifice is preferably formed by laser working in case the orifice plate is composed of a resinous film, and, in the present invention, there is adopted a configuration of forming a protruding portion on the orifice plate and fitting such protruding portion into the liquid path. Therefore, by forming the orifice in such protruding portion, the orifice and the liquid path can be aligned even after the formation of the orifice, and the formation of the orifice by laser working can be executed prior to the adhesion of the orifice plate and the main body of the head thereby preventing the intrusion of undesired substances, generated at the laser working, into the liquid path.
The present embodiment will be clarified further in the following, with reference to the attached drawings.
FIG. 17
is a partially-broken schematic perspective view showing the liquid discharge head of the present embodiment.
As shown in
FIG. 17
, the liquid discharge head of the present embodiment has a head main body
203
provided with plural heat generating elements
205
constituting the energy generating elements for generating discharge energy to be given to the ink and with plural liquid paths
206
respectively corresponding to the heat generating elements
205
, and an orifice plate
204
adjoined to the head main body
203
. As shown in
FIG. 18
, the liquid paths
206
have apertures on an end face of the main body
203
, and the orifice plate
204
is adjoined to such end face. The orifice plate
204
is provided with plural orifices
212
respectively communicating with the liquid paths
206
.
The main body
203
is composed of a substrate
201
and a ceiling plate
202
adjoined to the upper face of the substrate
201
. On the substrate
201
, there are formed the above-mentioned heat generating elements
205
and Al wirings for supplying the heat generating elements
205
with electrical signals, by film forming technology. On the ceiling plate
202
, there is integrally formed a liquid chamber frame
210
for forming liquid path walls
209
defining the liquid paths
206
and a common liquid chamber
207
for temporarily storing the ink to be supplied to the liquid path
206
, and the liquid paths
206
and the common liquid chamber
207
are formed by adjoining the ceiling plate
202
to the substrate
201
. In the ceiling plate
202
, there is opened an Ink supply aperture
211
for supplying the common liquid chamber
207
with ink from the exterior. On the substrate
201
, grooves
208
are formed, in positions between the heat generating elements
205
, for receiving the liquid path walls
209
of the ceiling plate
202
, and the ceiling plate
202
and the substrate
201
are mutually aligned at the adjoining thereof by fitting the liquid path walls
209
into the grooves
208
.
In the above-described liquid discharge head, the ink supplied from the common liquid chamber
207
into the liquid path
206
is filled therein, forming a meniscus at the orifice
212
. When heat is generated by activating the heat generating element in this state, the ink thereon is rapidly heated to generate a bubble by the film boiling phenomenon in the liquid path
206
, and the ink is discharged from the orifice
212
by the pressure generated by the growth of such bubble.
The orifice plate
204
will be explained further in the following. The orifice plate
204
is adhered to the main body
203
of the head with adhesive resin
214
to be explained later, and an adhering face (rear face) of the orifice plate
204
, adhered to the main body
203
, is provided with protruding portions
213
to respectively fit into the liquid paths
206
of the main body
203
. As shown in
FIGS. 19A and 19B
, the protruding portions
213
are arranged with a predetermined pitch on the rear face of the orifice plate
204
, and the orifices
212
are opened on such protruding portions
212
. Thus, by fitting the protruding portions
213
in the liquid paths
206
of the main body
203
and adjoining the orifice plate
204
and the main body
203
, it is rendered possible to align the orifices
212
with the liquid paths
206
in the adjoining of the orifice plate
204
and the main body
203
even if the liquid paths
206
are arranged with a high density.
The orifice plate
204
is preferably composed of a metal film such as of stainless steel or Ni, or a resinous film with satisfactory ink resistance such as of polyimide, polysulfone, polyethersulfone, polyphenylene oxide, polyphenylene sulfide or polypropylene. In the present embodiment, the orifice plate
204
was composed of a PSF film of a thickness of 50 μm.
The adhesive resin
214
for adhering the orifice plate
204
and the main body
203
of the head is composed of epoxy adhesive resin which is shifted to the B-stage with completed shrinkage by ultraviolet irradiation, infrared irradiation, heating or a combination of these processes, while maintaining the tackiness and is hardened by additionally executing the above-mentioned processes. In the present embodiment there is employed epoxy resin which is shifted to the B-stage by ultraviolet irradiation and is hardened by additional ultraviolet irradiation or heating. This adhesive material can also achieve adhesion by heating and pressing only.
In the following there will be explained an example of the method for producing the above-described liquid discharge head.
At first the substrate
201
and the ceiling plate
202
are prepared and are mutually adjoined. The method of preparing and adjoining the substrate
201
and the ceiling plate
202
is same as in the prior art and will not, therefore, be explained further.
Then the protruding portions
213
and the orifices
212
are formed on the orifice plate
204
. The formation can be achieved by laser working with an apparatus as shown in FIG.
9
.
In laser working of the orifice plate
204
, at first the protruding portions
213
are formed in plural units in a linear array with a pitch of 600 dpi, and then the orifice
212
is formed in each protruding portion
213
. In the present embodiment, prior to the formation of the orifices
212
, the adhesive resin
214
is uniformly coated on the adhesion face with the main body
203
as shown in
FIGS. 19A and 19B
and is shifted to the B-stage state while maintaining the tackiness by UV irradiation.
The orifice
212
is opened by irradiation of the laser beam
12
from the side of the adhesion face with the main body
203
. Therefore the orifice
212
is so tapered that the diameter decreases toward the ink discharging direction, and the direction of ink discharge is stabilized when the orifice plate
204
is adjoined with the main body
203
of the head.
After the preparation of the orifice plate
204
, the protruding portions
213
thereof are fitted in the apertures of the liquid paths
206
of the main body
203
. Then the orifice plate
204
is brought into close contact with the main body
203
by pressing the orifice plate
204
thereto with a pressure of 10 kg/cm
2
. Both members are heated at 60° C. in such pressed state to complete the hardening of the adhesive resin
214
. Thus the main body
203
of the head and the orifice plate
204
are mutually adjoined across the adhesive resin
214
as shown in
FIGS. 20A and 20D
, whereupon the liquid discharge head is completed.
As shown in
FIGS. 20A and 20B
, the adhesive resin
214
partly enters the liquid path
206
by the pressed contact of the main body
203
and the orifice plate
204
, but, because of the presence of the protruding portion
213
thereon, the adhesive resin
214
does not enter the orifice
212
but the gap between the external periphery of the protruding portion
213
and the liquid path walls
206
. As a result, there can be prevented the defective ink discharge caused by the intrusion of the adhesive resin
214
into the orifice
212
. Also, as the formation of the orifice
212
by laser working is executed prior to the adjoining of the main body
203
and the orifice plate
204
, the liquid path
206
can be protected from the intrusion of undesirable substances such as carbon particles generated by the ablation in the laser working. Consequently there does not take place clogging of the orifice
212
by such substances or adhesion of such substances onto the heat generating element
205
, and there can be prevented the defective discharge resulting from these phenomena.
In the present embodiment, the orifice plate
204
and the main body
203
of the head are adhered with thermosetting adhesive resin
214
as explained in the foregoing, so that, if the orifice plate
204
and the main body
203
are mutually different in the linear expansion coefficient, there may be encountered a situation where the protruding portion
213
cannot be fitted in the liquid path
206
or the pitch of the protruding portions
213
becomes aberrated from that of the liquid paths
206
to hinder adequate adjoining of the orifice plate
204
and the main body
203
, depending on the change of the environmental temperature between before and after the adjoining operation.
In the present embodiment, therefore, the dimensions of the protruding portion
213
and the liquid path
206
are so designed that the difference in the thermal expansion amount between the orifice plate
204
and the main body
203
, in the direction of array of the liquid path
206
and in the direction of height thereof under the environmental temperature change, is smaller than the gap between the protruding portion
213
and the liquid path
206
when they are mutually fitted. More specifically, the materials of the orifice plate
204
and the main body
203
of the head and the dimensions of various parts are selected in such a manner that the lateral width C of the protruding portion
213
(width in the direction of array), vertical width E of the protruding portion
213
(in a direction perpendicular to the direction of array), and linear expansion coefficient b with respect to the orifice plate
204
; the pitch A of array of the liquid paths
206
, width B of the liquid path
206
, height D thereof and linear expansion coefficient a width respect to the main body
203
of the head; number n of the protruding portions
213
or the liquid paths
206
; and environmental temperature difference Δt between before and after the adhesion of the main body
203
and the orifice plate
204
satisfy the following two conditions;
(
B−C
)/2≧|(
a−b
)
×n×A×Δt|
(1)
and
(
D−E
)/2≧|(
a−b
)
×D×Δt|
(2).
The selection of the materials constituting the orifice plate
204
and the main body
203
of the head and of the dimensions of various parts so as to satisfy the foregoing conditions (1) and (2) avoids positional aberration between the protruding portions
213
of the orifice plate
204
and the liquid paths
206
of the main body
203
at the heated pressing of the two, even in the presence of a difference in the linear expansion coefficient therebetween, so that the failure in the adjoining of the two can be avoided. Also, since the condition (1) takes the pitch of array of the liquid paths
206
and the entire width thereof in the direction of array into consideration, the orifice plate
204
and the main body
203
can be securely adjoined even in case the liquid paths
206
are arranged with a high density or are provided in a large number as in the case of a full-line head. Also if the orifice plate
204
is composed of a light-transmitting material, the orifice plate
204
and the main body
203
are not positionally aberrated by heating, after the adhesive resin
214
is hardened by ultraviolet or infrared light.
In the following there will be explained specific examples of the parameters relating to the conditions (1) and (2) in the liquid discharge head of the present embodiment. For example, if the main body
203
of the head is composed of silicon and the orifice plate
204
is composed of polysulfone, the linear expansion coefficient a of the main body
203
is 2.42×10
−6
, while the linear expansion coefficient b of the orifice plate
204
is 5.5×10
−5
. Other parameters are selected as follows: the number n of the liquid paths as 1200; pitch A of array of the liquid paths as 0.0425 mm; width B of the liquid path as 0.033 mm; height D thereof as 0.05 mm; lateral width C of the protruding portion as 0.028 mm; vertical width E of the protruding portion as 0.048 mm; and environmental temperature difference Δt as 2° C.
These parameters, when applied to the conditions (1) and (2), satisfy the condition (2) as the left-hand term becomes 1×10
−3
mm while the right-hand term becomes 5.3×10
−6
mm, but does not satisfy the condition (1) as the left-hand term becomes 2.5×10
−3
mm while the right-hand term becomes 5.4×10
−3
mm. Stated differently, the configuration is satisfactory in the vertical direction of the liquid paths
206
, but, in the direction of array thereof, the positional aberration between the protruding portions
213
and the liquid paths
206
becomes excessively large by thermal expansion whereby the orifice plate
204
and the main body
203
of the head cannot be mutually adjoined.
Then, by changing the width B of the liquid path
206
of the main body
203
to 0.035 mm and the lateral width C of the protruding portion
213
of the orifice plate
204
to 0.024 mm while maintaining other parameters unchanged, the condition (2) is satisfied as the left-hand term becomes 5.5×10
−3
mm and the right-hand term becomes 5.4×10
−3
mm. Thus the orifice plate
204
and the main body
203
can be securely adjoined even if the dimensions of various parts thereof vary by the environmental temperature change.
As explained in the foregoing, the dimension of the protruding portions
213
of the orifice plate
204
and that of the liquid paths
206
of the main body
203
are subject to certain limitation by the materials constituting these members, and, in certain cases, the conditions (1) and (2) cannot be satisfied unless the gap between the protruding portion
213
and the liquid path
206
is increased, whereby the positional alignment between the main body
203
of the head and the orifice plate
204
shows a large fluctuation. Such situation can be resolved by suitable selection of the materials constituting the orifice plate
204
and the main body
203
of the head.
For example, the orifice plate
204
may be composed of polyimide (such as UPILEX-S (trade name) manufactured by Ube Kosan Co.) having the linear expansion rate b of 1.1×10
−5
which is smaller than that of polysulfone. Consequently the orifice plate
204
and the main body
203
of the head can be securely adjoined even if the gap between the protruding portion
213
and the liquid path
6
in the direction of array thereof is made smaller than in the case of utilizing polysulfone. More specifically, the width B of the liquid path
206
of the main body
203
is changed to 0.034 mm and the lateral width C of the protruding portion
213
of the orifice plate
204
is changed to 0.032 mm while other parameters remain unchanged, whereby the conditions (1) and (2) are satisfied as, for the condition (1), the left-hand term becomes 1×10
−3
mm and the right-hand term becomes 0.88×10
−3
mm, and, for the condition (2), the left-hand term becomes 1×10
−3
and the right-hand term becomes 8.6×10
−7
mm. Therefore the orifice plate
204
and the main body
203
of the head can be securely adjoined also under such conditions.
The above-described liquid discharge head provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate. Also the liquid discharge head, when disassembled and observed, proved absence of any undesirable substance in the orifice
212
or in the liquid path
206
.
The foregoing embodiment employed the orifice plate without any surface treatment, but there may also be employed an orifice plate
224
surfacially coated with a water-repelling material
225
as shown in FIG.
21
. Such water-repelling treatment on the surface avoids ink deposition onto the surface of the orifice plate
224
. Also, as shown in
FIG. 22
, the adhesive resin
244
for adhering the orifice plate
234
and the main body
233
of the head may be coated on the main body
233
instead of the orifice plate
234
. The orifice plate
234
and the main body
233
of the head can be adhered also by coating the adhesive resin
244
on the main body
233
, in a similar manner as the case of coating the adhesive resin on the orifice plate
234
.
[Ninth Embodiment]
In the foregoing embodiment, the shape of the orifice plate, particularly around the orifice, has to be flat as it significantly influences the direction of liquid discharge. In order to flatly adjoining the flat orifice plate to the main body of the head, the adhesion face of the main body of the head has also to be flat. In practice, however, the head main body usually involves a step difference as shown in
FIGS. 25A and 25B
as the liquid path is formed by adjoining the ceiling plate and the heater board.
In
FIGS. 25A and 25B
, there are shown the adhesion face
333
of the ceiling plate and the adhesion face
334
of the heater board, and
FIG. 25A
shows a step difference
331
in the negative direction while
FIG. 25B
shows a step difference
332
in the positive direction.
If the orifice plate is adhered to the main body of the head involving such step difference, the orifice plate is deformed by such step difference.
Also in the adjoining of the orifice plate and the main body of the head, in order to achieve close contact in the vicinity of the orifice, the step difference, if present on the adhesion face of the main body, has to be small enough so as to be absorbable for example by the adhesive material.
The coating thickness of the adhesive for adhering the main body of the head and the orifice plate has to be small in order to prevent intrusion of the adhesive into the orifice after the adhering operation, and is 10 to 20 μm at maximum in the orifice plate having the orifices with a density of 600 dpi.
However, it is extremely difficult to maintain the step difference at 10 μm or less, and there may be required a polishing operation or the like in order to reduce such step difference.
Also the adhesive material having a thickness less than 10 μm is difficult to provide the sufficient adhesion strength.
In consideration of the foregoing, the present embodiment is to provide a liquid discharge head capable, in adjoining the orifice plate and the head main body having a step difference on the adhesion face, of avoiding deformation of the orifice plate thereby achieving flat adjoining, also of preventing intrusion of the adhesive or sealant into the orifice at the adjoining operation and improving the close contact state around the orifice and the adhesion strength.
More specifically, the liquid discharge head of the present embodiment, formed by adjoining an orifice plate, having a discharge opening for discharging a liquid droplet, to a head main body provided with a liquid path communicating with the discharge opening, a liquid chamber for supplying the liquid path with liquid, a supply aperture for supplying the liquid chamber with the liquid and an energy generating element positioned corresponding to the liquid path and adapted to generate energy to be utilized for liquid discharge:
is featured by a fact that the orifice plate is provided, on the adhesion face with the head main body, with a projection that is deformable by adjoining with the head main body.
The liquid discharge head of the present embodiment is also featured by a fact that the orifice plate has a protruding portion in addition to the projection, that the discharge opening is formed on the protruding portion and that the protruding portion or a part thereof is made to enter the liquid path of the head main body and the projection is simultaneously made to be deformed, whereby the orifice plate is adjoined to the head main body.
In the present embodiment, at the adjoining of the orifice plate with the main body of the liquid discharge head, the above-described configuration allows to prevent deformation of the orifice plate and to achieve flat adjoining thereof even in the presence of a step difference in the adhesion face of the main body, also to prevent intrusion of the adhesive or sealant into the orifice at the adjoining operation, and to improve the close contact around the orifice and the adhesion strength.
In the following the present embodiment will be explained with reference to the attached drawings.
FIGS. 23A
to
23
C are views illustrating the orifice plate of the present embodiment.
In the present embodiment, the orifice plate was composed of a PSF film of a thickness of 50 μm (FIG.
23
A). Photosensitive resin was coated on the orifice plate and subjected to exposure and development to form a projection
340
as shown in FIG.
23
B.
Such projection may however be also formed by another method such as laser working on resin.
Then the orifice was formed by the apparatus shown in
FIG. 9
, employing the KrF excimer laser beam.
At first the projections
340
were formed with photosensitive resin in such a manner that the pattern shown in
FIG. 23B
is linearly repeated in plural units with a pitch of 600 dpi.
The projection had a width b
3
of 2 μm and a height b
4
of 10 μm, and widths b
1
, b
2
of 32 μm.
Then the excimer laser beam was irradiated from the side of the adhesion face of the orifice plate with the main body of the head, to form the orifice
311
of a diameter of 22 μm in each projection (FIG.
23
C).
In the following there will be briefly explained the configuration of the liquid discharge head of the present embodiment.
The liquid discharge head is constituted, as shown in
FIG. 1
, by adjoining the ceiling plate, integrally provided with the liquid chamber frame and the liquid path walls for forming the liquid paths and the liquid chamber, with the substrate (heater board) on which the energy generating elements (heaters) for generating the discharge energy and the Al wirings for supplying the heaters with electrical signals are formed by the film forming technology.
The working method for the ceiling plate will not be explained since there have been proposed various methods such as a method of forming the liquid paths and the liquid chamber by etching a silicon substrate, or a method of forming the liquid paths and the liquid chamber by laser working or molding of resinous material.
At first, the main body of the head is formed by adjoining the heater board and the ceiling plate having the liquid chamber frame and the liquid path walls.
In the present embodiment, the liquid chamber frame and the liquid path walls for forming the liquid chamber and the liquid paths are formed on the ceiling plate, but the present invention is effective also in the head of a configuration where these members are formed on the heater board.
The method of forming the liquid chamber frame and the liquid path walls on the heater board will not be explained in detail, since there have been proposed various method, such as a method of forming these members by exposure and development of photosensitive resin.
Then, on the aperture face having the aperture of the liquid path formed for each unit (namely the adhesion face of the main body of the head), the orifice plate is adhered for example with an adhesive material.
In the present embodiment, the step difference (
FIGS. 25A and 25B
) in the adjoining between the ceiling plate and the heater board may be present if such step difference or precision of adjoining does not exceed dl+b
4
wherein b
4
is the height of the projection (
FIGS. 23A
to
23
C) and dl is the thickness of the adhesive material coated on the adhesion face of the main body.
Then an epoxy adhesive
322
, which is shifted to the B-stage to complete shrinkage by UV irradiation while maintaining the tackiness and which can thereafter be adhered by heating and pressing, is uniformly coated with a thickness of 2 μm (d
1
) by the transfer method onto the main body of the head.
Then the adhesive material is shifted to the B-stage with shrinkage, by ultraviolet irradiation of 1 mW/cm
2
for 60 seconds.
Then the head main body, formed by adjoining the heater board and the ceiling plate with the above-mentioned precision, is aligned with the orifice and adhered as shown in
FIGS. 24A
to
24
C.
Subsequently a pressure of 1 kg/cm
2
is applied by a flat pressing plate
360
placed on the orifice face in parallel to the adhesion face
333
of the main body to crush the projection, whereby the projections
340
of the orifice plate are maintained in close contact with the adhesion face
334
at the heater board side and that
333
at the ceiling plate side. Heating is conducted at 60° C. in such pressed state to complete the hardening of the adhesive. Then silicone sealant
361
is introduced, as shown in
FIG. 24C
, into the gap formed by the step difference between the adhesion face of the heater board side and the orifice plate, and is hardened by standing for 2 hours at the room temperature.
The liquid discharge head after the adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate.
Also the observation of the adhesion state of the main body of the head and the orifice plate proved that the adhesion face of the ceiling plate side was in close contact with the orifice plate across the adhesive material, and that the adhesion face of the heater board side was in close contact by crushing of the ends of the projections by the applied weight. Consequently the sealant was stopped at the projection and did not reach the orifice.
Also since the flat pressing plate was used to apply the pressure parallel to the heater board, thus controlling the crushed amount of the projections, the projections worked as pillars supporting the orifice plate thereby preventing the deformation of the orifice plate itself.
Also the use of the sealant significantly improved the adhesion strength.
The foregoing embodiment has been explained by the case of a step difference at the positive side as shown in
FIGS. 24A
to
24
C, but the present invention is likewise effective also in case of a step different at the negative side.
[Tenth Embodiment]
FIGS. 26A
to
26
C are views showing the orifice plate in the present embodiment.
In the present embodiment, the orifice plate is composed of a PSF film of a thickness of 50 μm (FIG.
26
A), and the protruding portion, projection and orifice are formed by the KrF excimer laser beam, utilizing the apparatus shown in FIG.
9
.
There are shown an excimer laser
350
, a laser beam
352
, a lens
351
for condensing the laser beam emitted from the excimer laser, a mask
353
positioned between the excimer laser and the orifice plate, and an orifice plate
310
on which the protruding portion, projection and orifice are to be formed.
At first a recess
321
is formed in such a manner that protruding portions
320
are linearly arranged in plural units at a pitch of 600 dpi and that projections
340
are formed in an area around the protruding portions and adapted to be adjoined to the main body of the head (FIG.
26
B).
On the orifice plate, the protruding portion had a dimension of 30 μm×30 μm, and the recess was formed with a depth of 15 μm excluding the protruding portions and the projections, in such a manner that the projections of a width of 2 μm were formed in a position distanced by 30 μm from the protruding portions.
Then the excimer laser beam was irradiated from the side of the adhesion face of the orifice plate with the main body of the head to form an orifice of a diameter of 22 μm in each protruding portion (FIG.
26
C).
In the present embodiment, the protruding portion and the projection are formed at first and the orifice is formed later, but it is also possible to form the orifice at first and then to form the protruding portion and the projection afterwards.
Subsequently the main body of the head is obtained by adjoining the heater board and the ceiling plate provided integrally with the liquid chamber frame and the liquid path walls, as in the fourth embodiment.
In the present invention, the step difference or the precision of adhesion between the ceiling plate and the heater board may be present in such a manner that the adhesion face of the ceiling plate is positioned within a range from dl in the negative direction to b
4
in the positive direction with respect to the adhesion face of the heater board, wherein dl is the thickness of the adhesive coated on the adhesion face of the main body of the head while b
4
is the height of the projection (
FIGS. 27A
to
27
C).
Then an epoxy adhesive
322
, which is shifted to the B-stage to complete shrinkage by UV irradiation while maintaining the tackiness and which can thereafter be adhered by heating and pressing, is uniformly coated with a thickness of 2 μm (d
1
) by the transfer method onto the main body of the head.
Then the adhesive material is shifted to the B-stage with shrinkage, by ultraviolet irradiation of 1 mW/cm
2
for 60 seconds.
Then the protruding portion formed around the orifice is made to proceed toward the head main body, formed by adjoining the heater board and the ceiling plate with the above-mentioned precision, and is adhered, as shown in FIG.
27
B.
Subsequently a pressure of 1 kg/cm
2
is applied by a flat pressing plate placed on the orifice face in parallel to the adhesion face of the ceiling plate side to bring the adhesion face of the ceiling plate side and the recess of the orifice plate in close contact, and heating is conducted at 60° C. in such pressed state to complete the hardening of the adhesive.
Then silicone sealant is introduced, as shown in
FIG. 27C
, into the gap formed by the step difference between the ceiling plate and the adhesion face of the orifice plate side, and is hardened by standing for 2 hours at the room temperature.
The liquid discharge head after the adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate.
Also the observation of the adhesion state of the main body of the head and the orifice plate proved that the flat pressing plate was used to apply the pressure parallel to the heater board, thus controlling the crushed amount of the projections, so that the projections worked as pillars thereby preventing the deformation of the orifice plate itself.
Also the observation of the adhesion state of the head main body and the orifice plate proved that the adhesion face of the ceiling plate side was in complete contact by the adhesive and that the adhesion face of the heater board side was in close contact by the sealant.
Also the use of the sealant significantly improved the adhesion strength.
Also there was no intrusion of the adhesive or sealant in the orifice and in the liquid path.
The foregoing embodiment has been explained by a case where the liquid path walls are formed on the ceiling plate, but they may also be formed on the heater board.
In such case, the adhesion face of the heater board side contacts the orifice plate by the adhesive material, and that of the ceiling plate side contact the orifice plate by deforming the projections.
More specifically, in the adjoining of the ceiling plate and the heater board, the step difference or the precision of adjoining may be present in such a manner that the adhesion face of the ceiling plate is positioned within a range from dl in the negative direction to b
4
in the positive direction with respect to the adhesion face of the heater board, and the effect of the present invention can be likewise obtained if the step difference is within such range.
In addition to the embodiment described above, the projection may be provided with a pattern (circle, rectangle or tetragon) as shown in
FIGS. 8A
to
8
C, or the external periphery of the protruding portion or projection on the orifice plate may have a tapered shape as shown in FIG.
28
C.
[Eleventh Embodiment]
FIG. 29A
to
29
C are views showing the orifice plate of an eleventh embodiment.
In case of adjoining the orifice plate and the main body of the head as in the tenth embodiment, the configuration of the present embodiment prevents the entry of the sealant into the orifice.
In the configuration of aligning the orifice plate, provided with a protruding portion and a recessed portion, with the liquid path of the head main body, causing the protruding portion provided around the orifice to enter the liquid path of the head main body, adjoining the adhesion face of the main body by adhesive material in the recessed portion and introducing sealant or the like into the gap for achieving close contact, there has to be employed sealant of low viscosity in a large amount in order to sufficiently deliver the sealant to the adhesion face, and such sealant may eventually enter the liquid path or the interior of the orifice in case the dimension of the protruding portion is significantly different from that of the aperture of the liquid path. However, according to the present embodiment, the projection and the adhesion face at the heater board side are in close contact to prevent the sealant from reaching the orifice.
In the present embodiment, the orifice plate is composed, as in the tenth embodiment, of a PSF film of a thickness of 50 μm, and the protruding and recessed portions, projection and orifice are formed by the KrF excimer laser beam, utilizing the apparatus shown in FIG.
9
.
On the orifice plate, the protruding portion
320
had a dimension of 30×30 μm, and the recess
321
was formed with a depth of 15 μm excluding the protruding portions and the projections, in such a manner that the projections of a width of 2 μm were formed in a position distanced by 30 μm from the protruding portions.
Then the excimer laser beam was irradiated from the side of the adhesion face of the orifice plate with the main body of the head to form an orifice of a diameter of 22 μm in each protruding portion.
In the present embodiment, the protruding portion and the projection are formed at first and the orifice is formed later, but it is also possible to form the orifice at first and then to form the protruding portion and the projection afterwards.
Subsequently, the main body of the head is obtained by adjoining the heater board and the ceiling plate provided integrally with the liquid chamber frame and the liquid path walls, as in the tenth embodiment.
In the present invention, the tolerance of the step difference or the precision of adhesion between the ceiling plate and the heater board is such that the adhesion face of the ceiling plate is positioned within a range from dl in the negative direction to b
4
in the positive direction with respect to the adhesion face of the heater board, wherein dl is the thickness of the adhesive material coated on the adhesion face of the main body of the head while b
4
is the height of the projection.
Then an epoxy adhesive, which is shifted to the B-stage to complete shrinkage by UV irradiation while maintaining the tackiness and which can thereafter be adhered by heating and pressing, is uniformly coated with a thickness of 2 μm (d
1
) by the transfer method onto the main body of the head.
Then the adhesive material is shifted to the B-stage with shrinkage, by ultraviolet irradiation of 1 mW/cm
2
for 60 seconds.
Then the protruding portion formed around the orifice is made to proceed toward the head main body, formed by adjoining the heater board and the ceiling plate with the above-mentioned precision, and is adhered.
Subsequently a pressure of 1 kg/cm
2
is applied by a flat pressing plate placed on the orifice face in parallel to the adhesion face of the ceiling plate side to bring the adhesion face of the ceiling plate side and the recess of the orifice plate in close contact, and heating is conducted at 60° C. in such pressed state to complete the hardening of the adhesive.
Then silicone sealant is introduced into the gap formed by the step difference between the ceiling plate and the adhesion face of the orifice plate side, and is hardened by standing for 2 hours at the room temperature.
The liquid discharge head after the adhesive hardening provided satisfactory printing without streaks of unevenness therein and without the peeling of the orifice plate.
Also the observation of the adhesion state of the main body of the head and the orifice plate proved that the adhesion face at the ceiling plate side was in close contact state with the adhesive, and that the adhesion face at the heater board side was in close contact, where the ends of the projections were crushed by the applied pressure and supported by the adhesive.
In order to sufficiently deliver the sealant over the adhesion face, there has to be employed sealant of low viscosity in a large amount.
Also the protruding portion around the orifice, introduced into the liquid path, may not be in close contact therewith, showing a gap thereto.
Even in such situation, however, the configuration of the present embodiment prevents the sealant from reaching the orifice, since the projection and the adhesion face of the heater board side are in close contact.
Also since the flat pressing plate was used to apply the pressure parallel to the heater board, thus controlling the crushed amount of the projections, the projections worked as pillars supporting the orifice plate thereby preventing the deformation of the orifice plate itself.
Also the use of the sealant significantly improved the adhesion strength.
The foregoing embodiment has been explained by a case where the liquid path walls are formed on the ceiling plate, but they may also be formed on the heater board.
In such case, the adhesion face of the heater board side contacts the orifice plate by the adhesive material, and that of the ceiling plate side contact the orifice plate by deforming the projections.
More specifically, in the adjoining of the ceiling plate and the heater board, the tolerance for the step difference or the precision of adjoining is such that the adhesion face of the ceiling plate is positioned within a range from dl in the negative direction to b
4
in the positive direction with respect to the adhesion face of the heater board and the effect of the present invention can be likewise obtained if the step difference is within such range.
[Twelfth Embodiment]
The present embodiment related to a configuration of the liquid discharge head and a producing method therefor, capable of suppressing the aforementioned step difference on the orifice plate, preventing the entry of the adhesive, suppressing the cost of the manufacturing apparatus, being mass produced and showing high reliability.
The liquid discharge head of the present embodiment including an orifice plate provided with plural discharge openings for discharging liquid droplets and a head main body provided at least with plural liquid paths respectively corresponding to the plural discharge openings, and being formed by adjoining the orifice plate with the head main body in such a manner that the discharge openings communicate with the liquid paths, wherein, within the adhesion face of the head main body with the orifice plate, a portion corresponding to the liquid path protrudes more than in other areas and such protruding portion is adjoined with the adhesion face of the orifice plate.
The above-mentioned head main body is constituted by adjoining an element substrate and a ceiling substrate, wherein the ceiling substrate is provided with a supply aperture for liquid supply to the liquid paths while the element substrate is provided with plural liquid path walls for forming the plural liquid paths upon adjoining with the ceiling substrate and plural energy generating elements respectively positioned between the liquid path walls for generating energy for liquid droplet discharge.
The above-described liquid discharge head allows secure adhesion in the area around the discharge opening where the most stable adhesion is required, whereby it is rendered possible to prevent entry of the adhesive resin into the liquid path and the bubble inclusion in the adhesive resin.
According to the present invention, there is also provided a method for producing the liquid discharge head including a head main body formed by adjoining an element substrate provided with plural energy generating elements for generating energy for liquid droplet discharge and plural liquid path walls for forming plural liquid paths in which the energy generating elements are respectively provided, and a ceiling substrate provided with a supply aperture for liquid supply to the liquid paths thereby forming the liquid paths, and an orifice plate adjoined to the head main body and provided with plural discharge openings for discharging liquid droplets, the method comprising a step of inclining the adhesion face of the ceiling substrate with the orifice plate in such a manner that, within the adhesion face of the element substrate with the orifice plate, a ridge at the side of the energy generating elements protrudes; a step of preparing the head main body by aligning the protruding ridge of the adhesion face of the element substrate with the orifice plate and the protruding ridge of the adhesion face of the ceiling substrate with the orifice plate on a substantially same plane and adjoining the element substrate and the ceiling substrate; and a step of adjoining the orifice plate to the head main body in such a manner that the discharge openings and the liquid paths mutually communicate.
In such method, the step of inclining the adhesion face of the element substrate with the orifice plate and the step of inclining the adhesion face of the ceiling plate with the orifice plate are steps of diagonally cutting the element substrate and the ceiling substrate, and the method is featured by a fact that the cutting is executed with a diamond blade.
In the above-mentioned protruding method for the liquid discharge head, the head main body is constituted by the element substrate provided with the plural energy generating elements for generating energy for liquid droplet discharge and the plural liquid path walls for forming plural liquid paths in which the energy generating elements are respectively provided, and the ceiling substrate provided with the supply aperture for liquid supply to the liquid paths, and, in cutting each substrate, there is employed an apparatus to obtain an inclined cut face in such a manner that the ridge of the element bearing face of the element substrate at the orifice plate adhesion face and the ridge of the element substrate adhesion face of the ceiling substrate at the orifice plate adhesion face respectively protrude from the ridge at the opposite face, and the head main body is prepared by adjoining by mutually abutting the protruding ridges. Such preparing method allows to minimize the step difference on the adhesion face of the orifice plate, caused by small positional aberration in the adjoining of the ceiling substrate and the element substrate. Therefore, in the configuration of forming the protruding portion around the liquid discharge opening, corresponding to the cross sectional shape of the liquid path, and inserting such protruding portion or a part thereof into the liquid path, there can be achieved secure entry of the protruding portion into the liquid path and secure adjoining in the area close to the discharge opening where the most stable adjoining is required. It is therefore rendered possible to prevent the entry of adhesive resin into the liquid path and the bubble inclusion in the adhesive resin.
Also, as the orifice formation can be executed prior to the adjoining to the head main body, there can be prevented intrusion of dusts, generated by laser ablation, into the liquid path. The present embodiment can also significantly reduce the aberration of the orifice, resulting from the difference in the thermal expansion coefficient when the orifice plate and the head main body are heated to a high temperature.
According to the present invention, there is also provided a method for producing the liquid discharge head including a head main body formed by adjoining an element substrate provided with plural energy generating elements for generating energy for liquid droplet discharge and plural liquid path walls for forming plural liquid paths in which the energy generating elements are respectively provided, and a ceiling substrate provided with a supply aperture for liquid supply to the liquid paths thereby forming the liquid paths, and an orifice plate adjoined to the head main body and provided with plural discharge openings for discharging liquid droplets, the method comprising a step of adjoining a semiconductor wafer bearing a plurality of the element substrates and a semiconductor wafer bearing a plurality of the ceiling substrates thereby forming an adjoined member; a step of forming a notch with a first diamond blade on the ceiling substrate of the adjoined member; a step of inverting the adjoined member and forming a notch with the first diamond blade on the element substrate of the adjoined member; a step of cutting the remainder of cutting of the adjoined member with the first diamond blade, with a second diamond blade narrower in width than the first diamond blade thereby forming the head main body; and adjoining the orifice plate to the head main body in such a manner that the discharge openings respectively communicate with the liquid paths.
In such producing method, the semiconductor wafer bearing a plurality of the element substrates and the semiconductor wafer bearing a plurality of the ceiling substrates are mutually adjoined so as to form the liquid paths, thereby forming an adjoined member, which is then out into the head main body, whereby the adhesion face of the head main body with the orifice plate is free from the step difference so that no crosstalk is generated between the neighboring nozzles after the adjoining of the orifice plate. Also, in preparing the head main body, notches are formed with the first diamond blade of a larger width in succession on the element substrate and the ceiling substrate of the adjoined member, and the remainder of cutting is cut with the second diamond blade thinner than the first diamond blade, whereby the amount of wafer cutting with the diamond blade is limited so that the diamond blade of a smaller width can be employed to improve the productivity.
In the following, the present embodiment will be clarified further with reference to the attached drawings.
FIG. 30
is a schematic perspective view of the liquid discharge head of the twelfth embodiment, and
FIG. 31
is a schematic cross-sectional view best showing the features of the liquid discharge head thereof.
The liquid discharge head shown in
FIGS. 30 and 31
is provided with a main body
546
, constituted by adjoining a ceiling substrate
560
bearing step differences for forming a liquid chamber
562
, and an element substrate
550
on which provided are energy generating elements (heaters)
551
for generating discharge energy, and Al wirings for supplying electrical signals thereto, both being formed by a film forming technology on an Si substrate, and on which also provided are liquid path walls for constituting the ink paths
561
respectively corresponding to the heaters
551
. An orifice plate
540
is adjoined to a face (adhesion face
544
) on which arranged are the apertures of the liquid paths
561
, formed by the above-mentioned adjoining. Around the discharge opening
541
of the orifice plate
540
, there is formed a protruding portion
545
capable of entering the liquid path
561
, constituted by adjoining the ceiling substrate
560
and the element substrate
550
, and the protruding portion
545
is inserted into the liquid path
561
of the head main body when the orifice plate
540
is adhered to the head main body (FIG.
31
).
The orifice plate
540
is preferably composed of a metal film such as of stainless steel or Ni, or a plastic film of satisfactory ink resistance, such as of polyimide, polysulfone, polyethersulfone, polyphenylene oxide, polyphenylene sulfide or polypropylene.
In the following there will be briefly explained the method for producing the head main body. The ceiling substrate
560
and the element substrate
550
are respectively cut in advance in such a manner that the ridges, within the adhesion face
544
of the substrates
550
,
560
with the orifice plate, protrude more at the face of mutual adjoining of both substrates than the ridges at the opposite faces, and the substrates
550
,
560
are mutually adjoined under abutting alignment of the protruding ridges, thereby forming the head main body
546
. Then adhesive material
542
extended in advance is transferred onto the adhesion face
544
of the orifice plate of the main body
546
. The adhesive material
542
was composed of epoxy adhesive of cationic polymerization type, which could be shifted to the B-stage with completed shrinkage while retaining the tackiness under UV irradiation, and which could be hardened by further ultraviolet irradiation or by heating. The adhesive could achieve adhesion also by heating and pressing only.
The head main body
546
and the orifice plate
540
are adjoined with such adhesive material
542
. Around the orifices of the orifice plate
540
, there are formed protruding portions
545
of a shape matching the cross sectional shape of the liquid paths, along the direction of array of the liquid paths, and such protruding portions
545
enter the liquid paths
561
. In such configuration, the protruding portion
545
limits the positional aberration between the orifice (discharge opening)
541
and the liquid path
561
generated in the hardening step of the adhesive material or by the temperature change when the heater is activated. Also the adhesive
542
attached to the adhesion face
544
is in close contact with the peripheral area of the protruding portion
545
of the orifice plate
540
, and the orifice plate
540
and the head main body are adjoined in such peripheral area. The peripheral area is provided with a groove
543
for receiving the adhesive material
542
to improve the adhesion strength between the orifice plate
540
and the head main body.
In the present embodiment, the orifice plate was composed of a PSF film of a thickness of 50 μm.
As explained in the foregoing, the ridges, within the adhesion face
544
of the substrates
550
,
560
, are made to protrude more at the mutually adjoined face than the ridges on the opposite faces, thereby minimizing the step difference on the adhesion face of the orifice plate caused by the small positional aberration in the adjoining of the ceiling substrate
560
and the element substrate
550
, also achieving secure entry of the protruding portion
545
into the liquid path
561
and achieving secure adjoining in the vicinity of the discharge opening
541
where the most stable adjoining is required.
In the following there will be explained an example of the cutting operation of the ceiling substrate
560
and the element substrate
550
, with reference to FIG.
32
.
FIG. 32
is a diamond blade of a dicing machine for the IC's generally formed on the silicon wafer, and a flange unit for fixing such diamond blade.
In the present embodiment, in cutting the ceiling substrate
560
and the element substrate
550
, there was employed the diamond blade of the dicing machine generally utilized for semiconductor manufacture.
Referring to
FIG. 32
, a diamond blade
501
(thickness 0.05 mm, diamond particle size 2 to 3 μm), in installation on the dicing machine, is sandwiched between a rear flange
502
(at the machine side Y) and a front flange
503
(at the operator side X) on a spindle shaft
505
, and is fixed by tightening with a flange nut
504
.
If the flange nut is tightened with a torque of 5 kgf·cm or higher, and in particular with a torque of 10 kgf·cm or higher, the diamond blade
501
tends to be inclined toward the operator side because of a small deformation of the end of the flange. In ordinary situation, the tightening torque is maintained at 5 kgf·cm or less in order to avoid such inclination, but, in the present embodiment, the tightening torque was selected as 12 kgf·cm to cause an inclination of about 10 μm, in order to positively form an inclined cut face.
The diamond blade
501
thus fixed was used in dicing the element substrate
550
(or ceiling substrate
560
) formed on a silicon wafer of 6 inches, thereby obtaining the individual substrate.
Such dicing operation resulted in an inclination of 5 to 15 μm on the silicon wafer of the thickness of 0.625 mm.
In mounting the diamond blade on the dicing machine, the direction of inclination of the diamond blade is naturally aligned with the direction of the wafer, bearing a plurality of the element substrates
550
(or the ceiling substrates
560
), in such a manner that the ridges, within the adhesion face
544
of the substrate
550
or
560
with the orifice plate, protrude more on the mutual adjoining faces of the substrates
550
,
560
than the ridges on the opposite faces.
The element substrate
550
and the ceiling substrate
560
, separated by the above-described cutting operation, are aligned by mutual abutting of the ridges at the adhesion face with the orifice plate, and are adjoined in such a manner that the energy generating element
551
is positioned in the groove constituting the liquid path
561
. It is thus rendered possible to achieve stable adjoining, without step difference or recess, as shown in
FIGS. 33A
to
33
C, in the liquid path portion corresponding to the orifice of the orifice plate and with a step difference of ±2 μm (negative or positive sign respectively indicates that the ceiling substrate protrudes or is retracted from the element substrate) in a head of a width of 7 to 30 mm in the direction of array of the liquid paths, and also to achieve stable adjoining of the orifice plate in the next step.
The orifice
541
is formed on the orifice plate
540
with the KrF excimer laser beam of a wavelength of 248 nm, utilizing the apparatus shown in FIG.
9
.
In the following there will be explained steps for preparing the liquid discharge head of the present embodiment, with reference to
FIGS. 34A
to
34
D.
At first, on the orifice plate
540
, a recess
547
is formed with a depth of 10 μm in such a manner that protruding portions
545
are linearly arranged in plural units at a pitch of
600
dpi and have dimension of 30×30 μm, and that grooves
543
are formed at a position of 30 μm from the protruding portion
545
, with a width of 20 μm and a depth of 20 μm from the bottom of the recess
547
, thereby forming the recess
547
and the groove
543
constituting the adhesion face with the head main body (
FIGS. 33A
,
33
B).
Then an epoxy adhesive
542
, which is shifted to the B-stage to complete shrinkage by UV irradiation while maintaining the tackiness and which can thereafter be adhered by heating and pressing, is uniformly sprayed on the adhesion face of the orifice plate
540
with the head main body. Then the adhesive material is shifted to the B-stage with shrinkage, by ultraviolet irradiation of 1 mW/cm
2
for 60 seconds (FIG.
34
C). In the present embodiment, the adhesive
542
may also be applied, as shown in
FIG. 31
, to the adhesion face of the head main body, constituted by the ceiling substrate
560
and the element substrate
550
, to be adhered with the orifice plate
540
.
Then the excimer laser beam was irradiated from the side of the adhesion face of the orifice plate with the main body of the head to form an orifice of a diameter of 20 μm in each protruding portion (FIG.
34
D). Subsequently the protruding portion
545
, provided around the orifice
541
, is inserted into the liquid path
561
of the head main body obtained by adjoining the element substrate
550
and the ceiling substrate
560
, and the two members are adjoined at the recess
547
.
Subsequently a pressure of 1 kg/cm
2
is applied on the orifice face to maintain the orifice plate
540
and the head main body in close contact, and heating is conducted at 60° C. in such pressed state to complete the hardening of the adhesive.
The liquid discharge head after the adhesive hardening provided satisfactory printing without streaks or unevenness therein and without the peeling of the orifice plate
540
. Also the adhesion state of the main body of the head and the orifice plate, observed across the orifice plate proved absence of bubble inclusion on the adhesion face around the orifice. Also the liquid discharge head, disassembled and observed, proved absence of undesirable substances in the orifice and in the liquid path.
[Variation]
FIGS. 35A
to
35
D are schematic views showing a method of forming the adhesion face for the orifice plate, simultaneously at the time of cutting of the adjoined member, formed by adjoining the silicon wafer bearing a plurality of the element substrates
550
and a silicon wafer bearing a plurality of the ceiling substrates
560
.
If a diamond blade of a thickness not exceeding 0.1 mm in dicing the adjoined member formed by adjoining two silicon wafers of a standard thickness (0.625 mm), the diamond blade has to protrude by at least 1.3 mm from the flanges, thus showing insufficient rigidity or a significant inclination in the course of the dicing operation, whereby the blade is eventually broken or the working speed is limited. On the other hand, if the thickness of the diamond blade is increased in order to elevate the rigidity (0.2 mm or larger), the dicing streets on the wafer becomes wider to reduce the number of elements per wafer, thereby leading to an increase in the cost. There are also encountered drawbacks such as the smear of the element by the cut powder because of the increased amount of cutting and the protrusion of the lower end of the cut face of the wafer, resulting from the abrasion of the periphery of the diamond blade. Also the U.S. Pat. No. 5,057,853 discloses, in separating the above-mentioned adjoined member into the individual head main body by the dicing operation, a method of using the dicing blade in two steps on the adjoined member, by cutting about one and a half wafers within the two wafers constituting the adjoined member in a first cutting operation, and cutting the remainder of such cutting operation in a second cutting operation. This method also results in the aforementioned drawbacks in case the thickness of the dicing blade is same as explained above.
The present embodiment provides a producing method capable of resolving the above-mentioned drawbacks, and such producing method will be explained with reference to
FIGS. 35A
to
35
D.
At first, in the adjoined member shown in
FIG. 35A
, a groove is formed to a position of 50˜100 μm above the liquid path in the wafer
71
constituting the ceiling substrates, by means of a diamond blade
573
which is larger in width than the diamond blade
576
to be used for finally forming the adhesion face for the orifice plate (FIG.
35
B). The diamond blade employed has a thickness of 0.1 mm.
Then the adjoined member is inverted, and a groove is formed with the diamond blade of a same width as explained above, from the back surface of the wafer
572
constituting the ceiling substrate to a position of 50˜100 μm above the element bearing surface (
FIG. 35C
)
Then the adjoined member is inverted again, and a diamond blade
576
of a thickness of 0.07 mm to be used for forming the adhesion face to the orifice plate is used for cutting the adhesion face of the orifice plate and a perpendicular dicing line (not shown) to obtain the individual head main body. In such method, the adhesion face of the head main body, to be adhered to the orifice plate, can be formed without step difference and perpendicularly to the substrates constituting the head main body.
Thereafter the liquid discharge head is completed by adjoining the orifice plate, prepared in a similar manner as in the twelfth embodiment, to the adhesion face of the head main body. In such producing method, the adhesion face of the head main body to be adhered to the orifice plate is free from any step difference, so that the crosstalk cannot occur between the neighboring nozzles after the adjoining of the orifice plate. Also the amount of cutting of the wafer by the dicing blade is limited, so that a thinner dicing blade can be employed with improved productivity.
In the present embodiment, the groove is formed at first on the ceiling substrate, but it is also possible to form the groove at first on the element substrate.
In the following there will be explained a head cartridge and a liquid discharge recording apparatus utilizing the liquid discharge head described in the foregoing.
FIG. 36
is a perspective view of a head cartridge utilizing the liquid discharge head of the present invention. The head cartridge
2100
integrally includes a liquid discharge head
2101
according to any of the foregoing embodiments, and an ink container
2102
for containing the ink to be supplied to the liquid discharge head
2101
. The ink container
2102
may be re-used by ink refilling after the ink is consumed.
FIG. 37
is a schematic perspective view of a liquid discharge recording apparatus of serial type, utilizing the liquid discharge head of the present invention. As shown in
FIG. 37
, a frame
2201
rotatably supports a lead screw
2202
having a spiral groove
2203
and a guide shaft
2205
parallel to the lead screw
2202
. A carriage
2205
engages with the spiral groove
2203
by an unrepresented pin and slidably guided b the guide shaft
2204
, and the forward or reverse rotation of a motor
2206
is transmitted to the lead screw
2202
through gears
2207
,
2208
whereby the carriage
2205
is reciprocated in the directions a and b.
The carriage
2205
detachably supports a head cartridge
2220
that can be separated into a head unit
2221
including the liquid discharge head of the foregoing embodiments, and an ink container
2222
for ink supply to the liquid discharge head. The head cartridge
2220
can also be of an integral type, as shown in
FIGS. 8A
to
8
C, in which the liquid discharge head
2101
and the ink container
2102
are not separable.
A paper pressing plate
2210
presses the recording medium
2230
to a platen roller
2212
rotated by a paper feeding motor
2209
over the moving direction of the carriage
2205
, and the recording medium
2230
is conveyed by the friction between the platen roller
2212
and the recording medium
2230
upon rotation of the platen roller
2212
. Recording is executed on the recording medium
2230
by ink discharge from the liquid discharge head while the reciprocating motion of the carriage
2205
and the stepped advancement of the recording medium
2230
are repeated.
In a position opposed to the front face (surface of the orifice plate) of the liquid discharge head when the carriage
2205
is in a home position, there is provided a cap member
2211
for capping the front face of the liquid discharge head. The cap member
2211
is connected to suction means (not shown) which is activated when the front face of the liquid discharge head is capped to execute a suction recovery operation of forcedly sucking the undesirable substances or viscosified ink from the liquid discharge head, thereby maintaining the discharge characteristics thereof.
FIG. 38
is a schematic perspective view of a liquid discharge recording apparatus of full-line type employing the liquid discharge head of the present invention. In
FIG. 38
, the liquid discharge head
2320
is opposed to the recording medium
2330
conveying by two conveying rollers
2312
. The liquid discharge head
2320
is structured similarly to the foregoing embodiments, and is provided with orifices over the entire width of the recording area of the recording medium
2330
.
Claims
- 1. A liquid discharge head comprising:an orifice plate having plural discharge openings for discharging a liquid droplet; and a head main body provided with plural liquid paths for respectively communicating with said plural discharge openings, a liquid chamber for liquid supply to said plural liquid paths, a supply aperture for liquid supply to said liquid chamber, and plural energy generating elements provided corresponding to said plural liquid paths and adapted to generate energy for discharging the liquid droplet, said liquid discharge head being formed by adjoining said orifice plate with an adhesion face of said head main body on which are formed apertures of said liquid paths for communicating with said discharge openings of said orifice plate, wherein said orifice plate comprises a recessed portion and a protruding portion on an adhesion face of said orifice plate, said protruding portion has a shape corresponding to a cross-sectional shape of said liquid path and is provided with one of said discharge openings therein, said protruding portion or a part thereof is made to enter and to fit with one of said liquid paths of said head main body, and said adhesion face of said orifice plate is adjoined with said adhesion face of said head main body, and wherein pitch A of arrangement of said liquid paths, width B of each of said liquid paths, width C of said protruding portion in a direction of the arrangement of said liquid paths, height D of each of said liquid paths, width E of said protruding portion in a direction perpendicular to the direction of the arrangement of said liquid paths, linear expansion coefficient a of said head main body, linear expansion coefficient b of said orifice plate, number n of said liquid paths, and environmental temperature difference At between a temperature before and a temperature after the adjoining of said head main body and said orifice plate satisfy the following two conditions: (B−C)/2≧|(a−b)×n×A×Δt|, and(D−E)/2≧|(a−b)×D×Δt|.
- 2. A liquid discharge head according to claim 1, wherein said orifice plate is subjected at a surface thereof to water-repelling treatment.
- 3. A liquid discharge head according to claim 1, wherein said protruding portion has a tapered shape a diameter of which decreases in a discharging direction of the liquid droplet.
- 4. A liquid discharge head comprising:an orifice plate having plural discharge openings for discharging a liquid droplet; and a head main body provided with plural liquid paths for respectively communicating with said plural discharge openings, a liquid chamber for liquid supply to said plural liquid paths, a supply aperture for liquid supply to said liquid chamber, and plural energy generating elements provided corresponding to said plural liquid paths and adapted to generate energy for discharging the liquid droplet, said liquid discharge head being formed by adjoining said orifice plate with an adhesion face of said head main body on which are formed apertures of said liquid paths for communicating with said discharge openings of said orifice plate, wherein said orifice plate comprises a recessed portion and a protruding portion on an adhesion face of said orifice plate, said protruding portion has a shape corresponding to a cross-sectional shape of said liquid path and is provided with one of said discharge openings therein, said protruding portion or a part thereof is made to enter and to fit with one of said liquid paths of said head main body, and said adhesion face of said orifice plate is adjoined with said adhesion face of said head main body, and wherein, on said adhesion face of said head main body, a portion of said liquid path protrudes more than other portions and is adjoined with said adhesion face of said orifice plate.
Priority Claims (5)
Number |
Date |
Country |
Kind |
11-009440 |
Jan 1999 |
JP |
|
11-021627 |
Jan 1999 |
JP |
|
11-033267 |
Feb 1999 |
JP |
|
11-033268 |
Feb 1999 |
JP |
|
11-189622 |
Jul 1999 |
JP |
|
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EP |
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Dec 1992 |
EP |
0631869 |
Jan 1995 |
EP |
2-78560 |
Mar 1990 |
JP |
2-187342 |
Jul 1990 |
JP |
5-330061 |
Dec 1993 |
JP |
WO9842514 |
Jan 1998 |
WO |