The present application is based on, and claims priority from JP Application Serial Number 2019-179651, filed Sep. 30, 2019, the disclosure of which is hereby incorporated by reference herein in its entirety.
The present disclosure relates to a liquid ejecting apparatus and a control method thereof.
A liquid ejecting apparatus that ejects a liquid such as ink onto a medium such as printing paper has been offered in the related art. In the liquid ejecting apparatus, the characteristics such as the viscosity of the liquid may change due to, for example, the water content of the ink solvent evaporating from the nozzle. JP-A-2004-299341 discloses a technique in which the viscosity of a liquid is detected by analyzing the vibration that remains in the pressure chamber when the pressure of the liquid in the pressure chamber is changed (hereinafter referred to as a “residual vibration”).
In the technique of JP-A-2004-299341, when an abnormality is detected according to the viscosity detected from the residual vibration, a recovery process is executed to eliminate the cause of the abnormality. Therefore, in the period before the execution of the recovery process, there is a possibility that the error relating to the ejection characteristics of the liquid may not be sufficiently reduced.
According to an aspect of the present disclosure, in a method of controlling a liquid ejecting apparatus, where the liquid ejecting apparatus includes a pressure chamber that communicates with a nozzle that ejects a liquid, a drive element that changes a pressure of the liquid in the pressure chamber, and a drive circuit that supplies the drive element with an ejection pulse that generates a change in the pressure that ejects the liquid from the nozzle, the method includes specifying a viscosity of the liquid in the nozzle and a surface tension of the liquid in the nozzle from a residual vibration when the pressure of the liquid in the pressure chamber is changed, and controlling a waveform of the ejection pulse according to the viscosity and the surface tension.
According to another aspect of the present disclosure, a liquid ejecting apparatus includes a pressure chamber that communicates with a nozzle that ejects a liquid, a drive element that changes a pressure of the liquid in the pressure chamber, a drive circuit that supplies the drive element with an ejection pulse that generates a change in the pressure that ejects the liquid from the nozzle, a specifying unit that specifies a viscosity of the liquid in the nozzle and a surface tension of the liquid in the nozzle from a residual vibration when the pressure of the liquid in the pressure chamber is changed, and a controller that controls a waveform of the ejection pulse according to the viscosity and the surface tension.
A: Embodiment
As shown in
As illustrated in
The movement mechanism 40 reciprocates the liquid ejection head 50 along the X axis under the control of the control unit 20. The movement mechanism 40 of the present embodiment includes a substantially box-shaped transport body 41 that houses the liquid ejection head 50, and a transport belt 42 to which the transport body 41 is fixed. A configuration in which a plurality of the liquid ejection heads 50 is mounted on the transport body 41, or a configuration in which the liquid container 12 together with the liquid ejection heads 50 is mounted on the transport body 41 may be adopted.
The liquid ejection head 50 ejects the ink supplied from the liquid container 12 from each of a plurality of nozzles N onto the medium 11 under the control of the control unit 20. The liquid ejection head 50 ejects the ink onto the medium 11 in parallel with the transport of the medium 11 by the transport mechanism 30 and the repeated reciprocal movement of the transport body 41, so that an image is formed on the surface of the medium 11.
The liquid ejection head 50 according to the present embodiment includes a flow path structure 51, a housing 52, a plurality of piezoelectric elements 53, a sealing body 54, and a wiring substrate 55. In
The nozzle plate 64 is provided with the plurality of nozzles N. Each nozzle N is a circular through hole through which the ink is ejected.
As illustrated in
As illustrated in
An elastically deformable diaphragm 63 is laminated on the second substrate 62. The second substrate 62 is located between the first substrate 61 and the diaphragm 63. The pressure chamber 621 is a space located between the first substrate 61 and the diaphragm 63. That is, the diaphragm 63 constitutes the wall surface of each pressure chamber 621. As illustrated in
The housing 52 is a case that stores the ink supplied to the plurality of pressure chambers 621, and is formed by ejection molding of a resin material, for example. The housing 52 has a supply port 521 and a space 522. The supply port 521 is a conduit through which the ink is supplied from the liquid container 12, and communicates with the space 522. As illustrated in
As illustrated in
Each piezoelectric element 53 is deformed according to the voltage applied between the first electrode 531 and the second electrode 533 to change the pressure of the ink in the pressure chamber 621. The ink in the pressure chamber 621 is ejected from the nozzle N when the piezoelectric element 53 changes the pressure of the ink in the pressure chamber 621. The sealing body 54 is a structure that protects the plurality of piezoelectric elements 53.
The wiring substrate 55 is a mounting component at which a plurality of wirings (not shown) that electrically couples the control unit 20 and the liquid ejection head 50 is formed. For example, the flexible wiring substrate 55 such as a flexible printed circuit (FPC) or a flexible flat cable (FFC) is preferably adopted. A drive circuit 56 that drives each of the plurality of piezoelectric elements 53 is mounted on the wiring substrate 55.
The ejection pulse Pa is a waveform for driving the piezoelectric element 53 by the inverse piezoelectric effect so that the ink is ejected from the nozzle N. Specifically, the ejection pulse Pa includes a section Qa1, a section Qa2, a section Qa3, a section Qa4, and a section Qa5. The section Qa1 is a section in which the potential rises from the predetermined reference potential Vbs to a higher potential VaH. The section Qa2 subsequent to the section Qa1 is a section in which the potential of the drive signal D is maintained at the potential VaH. The section Qa3 subsequent to the section Qa2 is a section in which the potential of the drive signal D decreases from the high potential VaH to a low potential VaL below the reference potential Vbs. The section Qa4 subsequent to the section Qa3 is a section in which the potential of the drive signal D is maintained at the potential VaL. The section Qa5 subsequent to the section Qa4 is a section in which the potential of the drive signal D rises from the potential VaL to the reference potential Vbs. The pressure chamber 621 expands due to the change in potential in the section Qa1. Further, the pressure chamber 621 contracts due to the change in the potential in the section Qa3, so that the ink is ejected from the nozzle N. That is, when the piezoelectric element 53 is deformed by a supply of the ejection pulse Pa, the ink is ejected from the nozzle N corresponding to the piezoelectric element 53. The waveform of the ejection pulse Pa is not limited to the example shown in
The micro-vibration pulse Pb is a waveform that micro-vibrates the ink in the pressure chamber 621 to the extent that the ink is not ejected from the nozzle N. In particular, the micro-vibration pulse Pb includes a section Qb1, a section Qb2 and a section Qb3. The section Qb1 is a section in which the potential rises from the predetermined reference potential Vbs to a higher potential VbH. The potential VbH is less than the potential VaH in the ejection pulse Pa. The section Qb2 subsequent to the section Qb1 is a section in which the potential of the drive signal D is maintained at the potential VbH. The section Qb3 subsequent to the section Qb2 is a section in which the potential of the drive signal D decreases from the potential VbH to the reference potential Vbs. When the piezoelectric element 53 is deformed by a supply of the micro-vibration pulse Pb, a micro-vibration of the ink in the pressure chamber 621 corresponding to the piezoelectric element 53 is generated. The micro-vibration pulse Pb is also referred to as a waveform that vibrates the meniscus of the ink in the nozzle N. The waveform of the micro-vibration pulse Pb is not limited to the example shown in
In the operation of ejecting the ink onto the surface of the medium 11 (hereinafter referred to as a “printing operation”), the drive circuit 56 supplies the ejection pulse Pa to the piezoelectric element 53 corresponding to the nozzle N which is instructed by the control signal C to perform the ejection of the ink. On the other hand, the drive circuit 56 supplies the micro-vibration pulse Pb to the piezoelectric element 53 which is instructed by the control signal C to perform the no-ejection of the ink.
Due to various causes such as evaporation of water or the like of the solvent of the ink from the meniscus in the nozzle N, the characteristics of the ink in each nozzle N change with time. In consideration of the above circumstances, the liquid ejecting apparatus 100 according to the present embodiment controls the waveform of the ejection pulse Pa according to the characteristics of the ink in the nozzle N.
As illustrated in
The signal generation circuit 23 generates the drive signal D according to an instruction from the control device 21. The drive signal D generated by the signal generation circuit 23 together with the control signal C generated by the control device 21 is supplied to the drive circuit 56.
The vibration detection circuit 24 detects a residual vibration V for each of the plurality of pressure chambers 621. The residual vibration V is a fluctuation in the pressure remaining in the ink in the pressure chamber 621 after the signal is supplied to the piezoelectric element 53. The vibration detection circuit 24 generates an electromotive force generated by the piezoelectric effect in the piezoelectric element 53 when, for example, the residual vibration V in each pressure chamber 621 propagates to the piezoelectric element 53, as a detection signal R1 representing the waveform of the residual vibration V. That is, the detection signal R1 is a voltage signal representing the waveform of the residual vibration V.
As illustrated in
The specifying unit 211 specifies the characteristics of the ink in the nozzle N. There is a tendency that the characteristics of the ink in the nozzle N correlate with the characteristics of the residual vibration V generated in the pressure chamber 621. Against the background of the above tendency, the specifying unit 211 of the present embodiment specifies the characteristics of the ink in the nozzle from the residual vibration V detected by the vibration detection circuit 24. Specifically, the specifying unit 211 analyzes the detection signal R1 generated by the vibration detection circuit 24 to specify a viscosity η and a surface tension γ of the ink. The viscosity η is an index relating to the degree of a viscosity of the ink. The surface tension γ is an index relating to the magnitude of a tension acting along the surface of the ink.
The controller 212 controls the waveform of the ejection pulse Pa according to the characteristics of the ink specified by the specifying unit 211. Specifically, the controller 212 controls an amplitude value δ of the ejection pulse Pa according to the viscosity η and the surface tension γ specified by the specifying unit 211. As illustrated in
The relationship between the viscosity η and the amplitude value δ is not limited to the example shown in
The relationship between the surface tension γ and the amplitude value δ is not limited to the example shown in
Specifically, the storage device 22 stores a table in which respective combinations of the numerical value of the viscosity η and the numerical value of the surface tension γ, and respective numerical values of the amplitude value δ are associated with each other. The relationship of
When the adjustment operation is started, the control device 21 controls the drive circuit 56 to supply the micro-vibration pulse Pb to each of the plurality of piezoelectric elements 53 (S1). After the micro-vibration pulse Pb is supplied to the piezoelectric element 53, the residual vibration V is generated in each pressure chamber 621. The residual vibration V may be generated in each pressure chamber 621 by supplying the ejection pulse Pa.
The vibration detection circuit 24 generates the detection signal R1 representing the waveform of the residual vibration V generated in each pressure chamber 621 (S2). The specifying unit 211 specifies the viscosity η and the surface tension γ from the detection signal R1 (S3). For example, the specifying unit 211 firstly specifies the viscosity η and the surface tension γ from the detection signal R1 for each pressure chamber 621. Secondly, the specifying unit 211 calculates a representative value (for example, an average value) of the viscosities η in the plurality of pressure chambers 621 as the final viscosity η, and calculates a representative value (for example, an average value) of the surface tensions γ in the plurality of pressure chambers 621 as the final surface tension γ.
The controller 212 sets the amplitude value δ of the ejection pulse Pa according to the viscosity η and the surface tension γ specified by the specifying unit 211 (S4). In the printing operation after executing the adjustment operation described above, the signal generation circuit 23 generates the drive signal D including the ejection pulse Pa having the amplitude value δ set by the controller 212.
As understood from the above description, in the present embodiment, the waveform of the ejection pulse Pa is controlled according to the viscosity η and the surface tension γ of the ink in the nozzle N. Therefore, even when the characteristics of the ink in the nozzle N change, the error relating to the ink ejection characteristics can be reduced. The ejection characteristic is, for example, an ejection amount, an ejection speed or an ejection direction. In addition, it is possible to optimize the shape of the ink droplet such as the amount of tailing and to suppress the mist.
As described above, in this embodiment, it is possible to measure the physical properties of the ink (viscosity η and surface tension γ) at the meniscus for each nozzle N of the liquid ejection head 50. In a nozzle row in which a plurality of nozzles N is disposed, there is a tendency that the meniscus of the peripheral nozzle N tends to dry easily, compared to that of the central nozzle N, due to a difference in the environment such as a humidity or a temperature. That is, it can be said that the viscosity η of the ink in the peripheral nozzle N of the nozzle row tends to increase. According to this embodiment, since the nozzle N having the increased ink viscosity η is identified, it is possible to make the ink ejection speed uniform for the entire nozzle row by increasing the ink ejection pressure in the identified nozzle N. Therefore, it is possible to perform uniform printing.
On the other hand, the vibration of the ink in the pressure chamber 621 includes a swing mode (sloshing mode) component and a expansion/contraction mode (Helmholtz mode) component. The swing mode is a vibration mode in which the ink in the pressure chamber 621 reciprocates along the X axis. The expansion/contraction mode is a vibration mode in which the ink in the pressure chamber 621 expands/contracts along the X axis. The expansion/contraction mode is dominant in the residual vibration V generated in the pressure chamber 621. From the viewpoint of making the expansion/contraction mode dominant, it is desirable to suppress the propagation of vibration from the pressure chamber 621 and the supply flow path 612 to the space 611.
There is a tendency that as illustrated in
The inventors of the present application have studied the formulation about the behavior of the ink ejected from the nozzle N. First, the inventors of the present application have carried out a perturbation expansion on the Navier-Stokes equation defining the motion of a fluid with respect to the vibration relating to the meniscus, which is the interface between a gas and a liquid. The basic analysis of the meniscus by perturbation theory is described in detail in Shuzo Hirahara, Haruyuki Minatani, “Effect of Aggregation of Pigment Ink Surface on Ink Jet Properties.”, Proceedings of the Japan Society of Mechanical Engineers, 70-695 B (2004), pp. 75. The characteristic equation is derived by applying the boundary condition regarding the ink ejection in the liquid ejecting apparatus 100 to the solution of the perturbation equation derived by the perturbation expansion. The characteristic equation is a expression representing the relationship between a swing wavelength λ and a wave growth rate n. The swing wavelength λ is a wavelength of a wave motion (hereinafter, referred to as a “liquid surface swing”) in which the meniscus in the nozzle N undulates in the membrane vibration mode. The wave growth rate n is a speed at which the liquid column of the ink projects from the meniscus due to the liquid surface swing. The ink ejection speed depends on the wave growth rate n. Specifically, the larger the wave growth rate n, the higher the ink ejection speed.
Specifically, the characteristic equation expressed by the following Expression (1) is derived.
Respective variables in Expression (1) are defined as follows.
The symbol k in Expression (1) is the wave number of the liquid surface swing (hereinafter referred to as the “swing wave number”), and corresponds to the square root of the sum of the squares of the wave number kx in the X axis direction and the wave number ky in the Y axis direction, that is, k2=kx2+ky2. The symbol a is the distance between the nozzle N and the surface of the medium 11. The symbol ka is a dimensionless wave number. The symbol S is a dimensionless wave growth rate and the symbol 1 is a dimensionless viscosity. The symbol b is a nozzle length as described above. The symbol ρ is a density of the ink, and the symbol ρ′ is a density of the gas that contacts the meniscus.
By setting the element in the first parenthesis of the third term on the left side of Expression (1) to zero, the following Expression (2) expressing the relationship between the wave number k of the liquid surface swing and the dimensionless wave growth rate S is derived.
Expression (2) is a relational expression between the swing wave number k and the dimensionless wave growth rate S when the dimensionless viscosity l is set to infinity in Expression (1), that is, when the viscosity η is caused to approach zero.
When Expression (2) is modified by focusing on the relationship between the swing wave number k and the swing wavelength λ, that is, λ=2π/k, the following Expression (3) expressing the relationship between the wave growth rate n and the swing wavelength λ is derived. The symbol α in Expression (3) is a predetermined constant, and the symbol P is a ejection pressure.
As understood from Expression (4), the square of the limit value λcut is inversely proportional to the ejection pressure P, and is proportional to the nozzle length b and the surface tension γ.
As can be understood from
As understood from
For example, attention is paid to a numerical value β1 and a numerical value β2 with respect to the attenuation factor β. The numerical value β2 is greater than the numerical value β1. As understood from
In this embodiment, the storage device 22 stores a table in which the respective numerical values of the attenuation factor η and the respective numerical values of the viscosity η are associated with each other (hereinafter referred to as an “attenuation factor-viscosity table”). In the attenuation factor-viscosity table, the relationship of
As described above, the vibration of the expansion/contraction mode in the pressure chamber 621 is coupled to the vibration of the membrane vibration mode in the nozzle N. Therefore, the frequency f of the residual vibration V generated in the pressure chamber 621 corresponds to the natural frequency F02 of Expression (5). That is, the frequency f is proportional to the square root √γ of the surface tension γ, as can be understood from
For example, attention is paid to a numerical value f1 and a numerical value f2 with respect to the frequency f. The numerical value f2 is greater than the numerical value f1. As understood from
In this embodiment, the storage device 22 stores a table in which the respective numerical values of the frequency f and the respective numerical values of the surface tension γ are associated with each other (hereinafter referred to as a “frequency-surface tension table”). In the frequency-surface tension table, the relationship of
B: Modification
The embodiments illustrated above may be variously modified. Specific aspects of modifications that can be applied to the above-described embodiment will be illustrated below. Two or more aspects optionally selected from the following exemplifications can be appropriately merged within a range not inconsistent with each other.
(1) In the above embodiment, although the residual vibration V when the micro-vibration pulse Pb is supplied to each of the plurality of piezoelectric elements 53 is detected from each pressure chamber 621, the residual vibration V when the micro-vibration pulse Pb is supplied to one piezoelectric element 53 may be detected to specify the viscosity η and the surface tension γ of the ink from the detected residual vibration V. That is, the operation of detecting the residual vibration V for the plurality of pressure chambers 621 is omitted.
(2) In the above embodiment, although the amplitude value δ of the ejection pulse Pa is controlled according to the viscosity η and the surface tension γ, the control target of the controller 212 is not limited to the amplitude value δ. For example, the controller 212 may control the time length of each of the sections Qa1 to Qa5 of the ejection pulse Pa or the rate of change in the potential in the ejection pulse Pa according to the viscosity η and the surface tension γ. As understood from the above examples, the controller 212 is comprehensively expressed as an element that controls the waveform of the ejection pulse Pa.
(3) In the above embodiment, although the drive signal D including one ejection pulse Pa and one micro-vibration pulse Pb is exemplified, the waveform of the drive signal D is not limited to the above example. The drive signal D including a plurality of ejection pulses Pa or the drive signal D including a plurality of micro-vibration pulses Pb may be used. In the configuration in which the drive signal D includes a plurality of ejection pulses Pa within the cycle U, one or more ejection pulses Pa of the plurality of ejection pulses Pa are controlled according to the viscosity η and the surface tension γ. Further, a plurality of drive signals D having different waveforms of the ejection pulse Pa may be selectively supplied to the piezoelectric element 53.
(4) The drive element that changes the pressure of the ink in the pressure chamber 621 is not limited to the piezoelectric element 53 illustrated in the above-described embodiment. For example, a heating element that fluctuates the pressure of the ink by generating air bubbles inside the pressure chamber 621 by heating may be used as the drive element.
(5) In the above-mentioned embodiment, although the serial type liquid ejecting apparatus 100 in which the transport body 41 on which the liquid ejection head 50 is mounted is reciprocated is exemplified, the present disclosure is also applied to a line type liquid ejecting apparatus in which a plurality of nozzles N is distributed over the entire width of the medium 11.
(6) The liquid ejecting apparatus 100 exemplified in the above embodiment can be adopted not only in a device dedicated to printing but also in various devices such as a facsimile machine and a copying machine. Further, the application of the liquid ejecting apparatus of the disclosure is not limited to printing. For example, the liquid ejecting apparatus that ejects a solution of a coloring material is used as a manufacturing apparatus that forms a color filter of a display device such as a liquid crystal display panel. The liquid ejecting apparatus that ejects a solution of a conductive material is used as a manufacturing apparatus that forms wirings and electrodes of a wiring substrate. The liquid ejecting apparatus that ejects a solution of an organic substance relating to a living body is used as a manufacturing apparatus that manufactures a biochip, for example.
C: Appendix
For example, the following configurations can be grasped from the embodiments exemplified above.
In a method of controlling a liquid ejecting apparatus according to one aspect (first aspect), where the liquid ejecting apparatus includes a pressure chamber that communicates with a nozzle that ejects a liquid, a drive element that changes a pressure of the liquid in the pressure chamber, and a drive circuit that supplies the drive element with an ejection pulse that generates a change in the pressure that ejects the liquid from the nozzle, the method includes specifying a viscosity of the liquid in the nozzle and a surface tension of the liquid in the nozzle from a residual vibration when the pressure of the liquid in the pressure chamber is changed, and controlling a waveform of the ejection pulse according to the viscosity and the surface tension. In the above aspect, the waveform of the ejection pulse is controlled according to the viscosity of the liquid in the nozzle and the surface tension of the liquid. Therefore, even when the physical properties of the liquid in the nozzle are changed, it is possible to reduce the error relating to the ejection characteristic of the liquid. The ejection characteristic is, for example, the ejection amount, the ejection speed or the ejection direction.
In the specific example of the first aspect (second aspect), the specifying the viscosity includes specifying the viscosity from an attenuation factor of the residual vibration. Since the viscosity correlates with the attenuation factor of the residual vibration, the viscosity of the liquid can be specified with high accuracy according to the above aspect.
In the specific example of the second aspect (third aspect), the viscosity specified when the attenuation factor is a first value is less than the viscosity specified when the attenuation factor is a second value that is greater than the first value. Since the attenuation factor of the residual vibration tends to monotonically increase with respect to the viscosity of the liquid in the nozzle the actual viscosity of the liquid can be specified with high accuracy according to the above aspect.
In the specific example of any of the first aspect to the third aspect (fourth aspect), the specifying the surface tension includes specifying the surface tension from a frequency of the residual vibration. Since the surface tension correlates with the frequency of the residual vibration, the surface tension of the liquid can be specified with high accuracy according to the above aspect. The configuration that specifies the surface tension from the cycle of the residual vibration is substantially the same as the configuration that specifies the surface tension from the frequency of the residual vibration.
In the specific example of the fourth aspect (fifth aspect), the surface tension specified when the frequency is a third value is less than the surface tension specified when the frequency is a fourth value that is greater than the third value. Since the frequency of residual vibration tends to increase monotonically with the surface tension of the liquid in the nozzle, the surface tension of liquid can be specified with high accuracy according to the above aspect.
In the specific example of any of the first aspect to the fifth aspect (sixth aspect), the nozzle has a total length, of a section having a smallest inner diameter in an axial direction of the nozzle, that is 30 μm or more. In the configuration in which the total length of the section having the smallest diameter of the nozzle is less than 30 μm, the change in the attenuation factor with respect to the total length is remarkable. Assuming the above circumstances, the attenuation factor of the residual vibration can be stably specified according to the configuration in which the total length of the section having the smallest diameter is 30 μm or more.
In the specific example of any of the first aspect to the sixth aspect (seventh aspect), the controlling the waveform of the ejection pulse includes controlling an amplitude value of the ejection pulse so that an amplitude value of the ejection pulse when the viscosity is a fifth value is less than an amplitude value of the ejection pulse when the viscosity is a sixth value that is greater than the fifth value. In the above aspect, the waveform of the ejection pulse is controlled such that the higher the viscosity of the liquid in the nozzle, the larger the amplitude value of the ejection pulse. Therefore, even when the viscosity of the liquid in the nozzle changes, it is possible to reduce the error relating to the ejection characteristic of the liquid.
In the specific example of any of the first aspect to the seventh aspect (eighth aspect), the controlling the waveform of the ejection pulse includes controlling an amplitude value of the ejection pulse so that an amplitude value of the ejection pulse when the surface tension is a seventh value is less than an amplitude value of the ejection pulse when the surface tension is an eighth value that is greater than the seventh value. In the above aspect, the waveform of the ejection pulse is controlled such that the higher the surface tension of the liquid in the nozzle, the larger the amplitude value of the ejection pulse. Therefore, even when the surface tension of the liquid in the nozzle changes, the error relating to the liquid ejection characteristic can be reduced.
A liquid ejecting apparatus according to another aspect (ninth aspect) includes a pressure chamber that communicates with a nozzle that ejects a liquid, a drive element that changes a pressure of the liquid in the pressure chamber, a drive circuit that supplies the drive element with an ejection pulse that generates a change in the pressure that ejects the liquid from the nozzle, a specifying unit that specifies a viscosity of the liquid in the nozzle and a surface tension of the liquid in the nozzle from a residual vibration when the pressure of the liquid in the pressure chamber is changed, and a controller that controls a waveform of the ejection pulse according to the viscosity and the surface tension.
Number | Date | Country | Kind |
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JP2019-179651 | Sep 2019 | JP | national |
Number | Name | Date | Kind |
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9782968 | Tobita | Oct 2017 | B2 |
20150258780 | Hayashi | Sep 2015 | A1 |
Number | Date | Country |
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2004-299341 | Oct 2004 | JP |
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IP.com search (Year: 2021). |
Number | Date | Country | |
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20210094292 A1 | Apr 2021 | US |