The present application claims priority to Japanese Application(s) No(s). P2004-045720 filed Feb. 23, 2004, which application(s) is/are incorporated herein by reference to the extent permitted by law.
1. Field of the Invention
The present invention relates to a liquid ejection head used for a thermal inkjet-printer head for ejecting liquid using thermal energy, a liquid ejection apparatus having the liquid ejection head, and a manufacturing method of the liquid ejection head. In detail, the invention relates to a technique in that the strain of liquid-ejection head components due to temperature variation is minimized so as to suppress characteristic degradation produced in the liquid ejection head.
2. Description of the Related Art
Among liquid ejection heads, in an inkjet-printer head employing a thermal system for an inkjet printer, a head chip is used having several hundreds of heater elements formed on a semiconductor substrate. While one head chip is used in the case of monochrome, in a color head, a two-block structure may be often adopted that is composed of a three-color head of Y (yellow), M (magenta), and C (cyan) integrally constructed at equal intervals and a K (black) head separately provided.
For increasing the printing speed, a number of liquid ejection parts (including nozzles, heater elements, and liquid chambers) may be provided within one head as many as possible, as one method. The liquid ejection part must have nozzles, heater elements, and liquid chambers as well as flow paths for communicating the entire liquid chambers together, so that the minimal area therefor is required.
Thus, at present, about 600 DPI (pitch of 42.3 μm) is assumed to be a limit. For example, a head having 256 liquid ejection parts at 600 DPI has a length of 10.8 mm. With increasing liquid ejection part size, the handling becomes difficult, reducing yield and increasing cost.
Accordingly, a thermal line head technique has been known in that a plurality of head chips are arranged so as to form one large line head as disclosed in Japanese Unexamined Patent Application Publication No. 2002-127427. By the structure mentioned above, a chip head having 320 heater elements at 600 DPI (15.4 mm length) is made, for example, so as to form a line head by arranging the 64 chip heads, which can record images over the width of an A-4 size sheet (Japanese Standard, 210 mm) at one time.
The nozzle plate 3 has an arrangement of nozzle openings 3a formed therein at positions corresponding to those of the heater elements 4b of the head chip 4.
In the example shown in
Furthermore, the dummy chips 5A and 5F among the dummy chips 5A to 5F are arranged at both ends of the head chips 4A to 4D in the longitudinal direction, so that a liquid supply path 2a is surrounded with the head chips 4A to 4D and the dummy chips 5A to 5F. Also, the head chips 4A to 4D and the dummy chips 5A to 5F form a flat surface on which the flow path plate 2 is bonded.
The flow path plate 2 includes a liquid inlet 2b formed at the upper center and the liquid supply path 2a formed inside the flow path plate 2 so as to communicate the liquid inlet 2b and the head chips 4.
Referring to
The heat in the head chip 4 is almost generated from the heater element 4b. Furthermore, even on the side of the heater element 4b, with which liquid is not brought into contact, the heat produced from the heater element 4b is transferred because the heater element 4b comes contact with the semiconductor substrate 4a.
The heat produced in the head chip 4 is transferred to the liquid moving every ejection of liquid droplets. In other places, the bottom surface of the head chip 4, for example, the heat is transferred to the flow path plate 2 via an adhesion layer 6 between the head chip 4 and the flow path plate 2, and in the front surface of the head chip 4, the heat is transferred to the nozzle plate 3 via the barrier layer 4c of the head chip 4.
However, the conventional technique described above has the following problems in a practical application.
As the single head chip 4 is about 20 mm in size as mentioned above, even when the head chip 4 has the nozzle plate 3 with the nozzle opening 3a and the flow path plate 2 bonded thereon, if strain is generated by the thermal stress between components due to thermal expansion, the stain is not at the level to a failure in a serial system.
On the other hand, when a number of the head chips 4 are connected together like in the line head 1, as the length in the longitudinal direction is increased, the expansion difference due to thermal expansion, i.e., the difference between linear expansion coefficients becomes a problem depending on materials arranged on the front surface of the head chip 4 (the side of the nozzle plate 3) and on the bottom surface (the side of the flow path plate 2).
If materials of the flow path plate 2, the head chip 4, and the nozzle plate 3 have substantially the same linear expansion coefficient, the thermal expansion problem does not arise. However, upon selecting materials of the flow path plate 2, the head chip 4, and the nozzle plate 3, characteristics or functions required for each member are different, so that each member must satisfy the required characteristics or functions.
For example, for the flow path plate 2, cast aluminum is given at first. This is because of its excellent workability and thermal conductivity. Then, an injection-molded acrylic resin is given. This is because of its excellent wettability and workability as well as lower Young's modulus in comparison with aluminum.
Furthermore, for the barrier layer 4c, a high-polymeric material, typified by a photosensitive cyclized-rubber resist or an exposure-curing dry-film resist, is shown. This is because of its strong adhesive force, higher hardness after cured than that an acrylic resin, and low cost.
Also, as the nozzle plate 3, electrocasting nickel is given because the nozzle opening 3a is comparatively simply constructed by that, its thermal expansion is comparatively small, as well as its wettability and cost are within a practical application.
As described above, each member must select a material as well as a fabricating method so as to satisfy characteristics or functions required for each member. When materials of the flow path plate 2, the head chip 4, and the nozzle plate 3 are selected in such view, linear expansion coefficients thereof are to be different from each other.
When the line head 1 is warped like an arrow in such a manner, the distance between a recording medium and each head chip is changed. For example, in the head chips 4 located at both ends, the distance between the nozzle plate 3 and the recording medium is not so changed; however, the head chip 4 is inclined (not in parallel) to the recording medium. On the other hand, in the head chips 4 located in the central portion, with the line head 1 warped like an arrow, although the parallel is not so changed, the position of the head chip 4 is moved upward, so that the distance to the recording medium is elongated.
Then, in order to prevent the deformation like an arrow, the positional relationship between the line head 1 and a recording medium is maintained by applying a force to the line head 1.
As shown in
In this case, however, shear stresses are produced between the flow path plate 2 and the head chips 4 and between the head chips 4 and the nozzle plate 3, as shown by arrows in the drawing, and the closer to both the ends, magnitudes of the shear stresses are increased.
In particular, on the head chip 4, the barrier layer 4c is laid as mentioned above so as to form a liquid chamber and an individual flow path with the barrier layer 4c. The strength of these portions is smaller than that of the semiconductor substrate 4a of the head chip 4 or the nozzle plate 3 so as to cause elastic deformation and plastic deformation due to the shear stress, so that it may be difficult for the liquid chamber and the individual flow path to satisfy the required characteristics.
As shown in
For reducing such effect, in a general operating proof temperature range of a printer, such as a range between 15 to 35° C., changes in ejection characteristics need to be further reduced to temperature changes.
Accordingly, it is a problem to be solved by the present invention to suppress changes in ejection characteristics due to temperature changes when a line head is configured by arranging a plurality of head chips.
Thus, the present invention solves the problems described above by the following solving means:
A liquid ejection head according to the present invention includes a nozzle plate having nozzle holes formed thereon for ejecting liquid droplets; a frame-shaped first support base; a head chip having a plurality of heater elements arranged on a semiconductor substrate; and a second support base, at least part of which being arranged within a region inside the frame of the first support base, the liquid ejection head having a plurality of the head chips joined onto the nozzle plate in a line so that the heater elements oppose the nozzle holes, respectively, wherein the linear expansion coefficient of the head chip is substantially the same as that of the first support base; the linear expansion coefficient of the nozzle plate is larger than that of the first support base; and the linear expansion coefficient of the second support base is larger than that of the first support base, wherein the nozzle plate is joined onto the first support base while under the circumstance of temperature at which a thermal stress is not generated on the junction surface between the first support base and the second support base, a tensile stress is produced in the nozzle plate by the first support base, wherein the second support base is joined onto the first support base so that at least parts of external side faces at both ends of the second support base in a longitudinal direction are fitted between at least parts of internal side faces of the first support base, and wherein when the second support base thermally expands relative to the first support base, a compression stress is produced in the second support base while a strain of the second support base is restricted by the first support base.
According to the present invention, the nozzle plate is joined onto the first support base while the linear expansion coefficient of the nozzle plate is larger than that of the first support base. Thereby, when the nozzle plate is joined onto the first support base at high temperature, the nozzle plate expands/contracts corresponding to expansion/contraction of the first support base at normal temperature. Since the linear expansion coefficient of the head chip is substantially the same as that of the first support base, and the head chips are joined onto the nozzle plate, the head chip expands/contracts following the first support base.
Also, the second support base is joined onto the first support base so that the second support base is fitted with the first support base, and the linear expansion coefficient of the second support base is larger than that of the first support base. When the second support base thermally expands relative to the first support base, a strain of the second support base is restricted by the first support base.
According to the present invention, when a line-system liquid ejection head is formed by connecting head chips, the strain due to the difference in thermal expansion coefficient between members can be minimized, so that printing quality is not affected by temperature change.
In addition, the liquid ejection head corresponds to a line head 10 according to following embodiments. A first support member corresponds to an outer frame 11; a second support member corresponds to a head support member 14 also serving as a flow path plate according to the embodiments.
An embodiment according to the present invention will be described below with reference to the drawings. In the following embodiments, an inkjet printer is exemplified as a liquid ejection apparatus; a thermal line head is exemplified as a liquid ejection head used in the liquid ejection apparatus.
The terms below in the specification and Claims mean as follows: “junction” means perpetual connection not assuming separation (or exfoliation) and including both (1) bonding components together with an adhesive and (2) junction (connection) by ultrasonic joining or welding by applying thermo-compression or ultrasonic vibration without using an adhesive (without interposing the adhesive between the components).
Furthermore, “bonding” is a kind of the junction and means to connect members together (bonding them together) with an adhesive (interposing the adhesive between the members) for perpetual connection not assuming separation (or exfoliation).
The line head 10 includes an outer frame 11 (corresponding to a first base according to the present invention), a nozzle plate 12, a head chip 13, and a head support member 14 (corresponding to a second base according to the present invention).
The outer frame 11 shaped in a substantially rectangular frame may be made of ceramics having a linear expansion coefficient within a range of 0.5 to 1.5 times higher than that of silicon monocrystal or polycrystal (powder sintered ceramics sintered from material powder especially according to the embodiment). In this case, the outer frame 11 (ceramics) has a linear expansion coefficient of about 3 to 3.5 ppm similar to (substantially the same as) that of the head chip 13 (semiconductor substrate), which has a silicon linear expansion coefficient of about 2.5 to 3.0 ppm. If the outer frame 11 is made of ceramics in such a manner, the Young's modulus of the outer frame 11 becomes similar to that of a metallic material. Also, the linear expansion coefficient can be adjusted by varying the composition and fabricating method of the ceramics.
The nozzle plate 12 is a very thin film with a thickness of about 10 to 20 μm and has a plurality of nozzle holes. In view of workability, cost, wettability, and the Young's modulus, the nozzle plate 12 uses electro-cast nickel as a metallic material and polyimide as a polymeric material.
The head chip 13 is composed of a silicon semiconductor substrate, heater elements formed on the substrate, and a barrier layer laid on the heater elements (the same structure as that of the head chip 4 in the conventional technique mentioned above). The barrier layer, made of a photosensitive cyclized-rubber resist or an exposure-curing dry-film resist, is formed by removing unnecessary portions by a photolithographic process after the entire surface, on which the heater elements are formed, of the semiconductor substrate is deposited with the layer. With the barrier layer, part of a liquid chamber (ink chamber) and a flow path for supplying ink to the liquid chamber (individual flow path for each liquid chamber) are constructed.
The head support member 14 serves as a flow path plate according to the embodiment, and as shown
The head support member 14 is required to withstand not only tension but also compression, bending, and twisting (not plastically deformed) differently from the thin-film nozzle plate 12. Thus, the head support member 14 is generally shaped in a plate or bar.
Then, the head support member 14 may be made of ceramics identically to the outer frame 11. Thereby, the linear expansion coefficient of the head support member 14 is equalized to that of the outer frame 11. However, the workability of the ceramics is not so excellent as to a metallic material or a polymeric material. Then, the head support member 14 is manufactured with the following materials and methods.
First, the head support member 14 may be made of a material with a linear expansion coefficient being 0.5 to 1.5 times higher than that of the outer frame 11. For example, as long as the head support member 14 has substantially the same linear expansion coefficient as that of the outer frame 11, the rigidity of the head support member 14 (expressed by E×I which is the product of the Young's modulus (modulus of longitudinal elasticity) E and the geometrical moment of inertia I for the flexural rigidity) has no limit. Whereas, if the linear expansion coefficient of the head support member 14 is larger than that of the outer frame 11 within the above range, the rigidity of the head support member 14 must be smaller than that of the outer frame 11.
Secondly, the head support member 14 may be made of a polymeric material with substantially the same linear expansion coefficient as that of the ceramics. For example, liquid crystal plastics (also referred to as LCP or a liquid crystal polymer, specifically, VECTRA B230 made from Polyplastics Co., Ltd.) may be preferable. In addition, the linear expansion coefficient of the liquid crystal plastics is about 3.0 ppm. Since the polymeric material has a small linear expansion coefficient so as to have a linear expansion coefficient similar to that of the outer frame 11, the mechanical strength and further wettability are excellent.
Thirdly, the head support member 14 may be made of invar (iron 36% and a nickel alloy), titanium or a titanium alloy, nickel steel, nickel plate steel (wettability improved due to nickel plating), stainless steel, or aluminum nitride.
Moreover, as shown in
First, a method may be adopted in that the flat plate of the invar, nickel steel, nickel plate steel, or stainless steel mentioned above is plastically fabricated so as to form the liquid inlet 14a while a flow path communicating with the liquid inlet 14a is fabricated therein. For example, a space is formed inside the head support member 14 so as to fabricate a path equivalent to the conventional liquid supply path 2a shown in
Secondly, the liquid inlet 14a may be formed by injection-molding a polymeric material with substantially the same linear expansion coefficient as that of the ceramics (the LCP mentioned above, for example). Furthermore, a liquid supply path communicating with the liquid inlet 14a may also be formed in a similar manner (the liquid supply path 14b shown in
Thirdly, a method may be adopted, in which in the second method, a strain absorption plate is provided under the head support member 14.
The strain absorption plate 14c is a flat plate, and is bonded on the top surface of the head chip 13 when the strain absorption plate 14c is placed on the head chip 13. Also, the top surface of the strain absorption plate 14c is bonded on the bottom surface of the head support member 14A.
The strain absorption plate 14c is provided with a plurality of oval through-holes 14d. Through the through-holes 14d, the liquid supply path 14b is communicated to the head chip 13.
In this case, the strain absorption plate 14c may be formed from a flat plate of invar, nickel plate steel, stainless steel, or ceramics while part of the head support member 14A other than the strain absorption plate 14c may be formed of a polymeric material like in the second method. By fabricating the head support member 14A from such a composite material of a metallic material and a polymeric material, the linear expansion coefficient and compression are secured with the strain absorption plate 14c made of the metallic material while workability and cost are improved by injection-molding the polymeric material.
Next, a manufacturing method of the line head 10 will be described.
First, referring to
According to the embodiment, the linear expansion coefficient of the nozzle plate 12 is larger than that of the outer frame 11. When the nozzle plate 12 is made of nickel especially according to the embodiment, the linear expansion coefficient thereof is about 12 to 13 ppm. Whereas, when the outer frame 11 is made of ceramics, the linear expansion coefficient thereof is about 3 to 3.5 ppm.
When the nozzle plate 12 is bonded on the outer frame 11 under the circumstance of temperature 150° C., a force is applied to the nozzle plate 12 in a compressing direction if the temperature is below 150° C. That is, at a temperature below 150° C., a tensile stress is always produced in the nozzle plate 12. Thereby, under circumstances of temperature 150° C. or less, the nozzle plate 12 is maintained to have a tightly stretched state.
Then, the head chip 13 is bonded on the nozzle plate 12 (second process). The bonding between the head chip 13 and the nozzle plate 12 is performed under a circumstance of temperature T2 lower than the temperature T1. The temperature T2 according to the embodiment is 120° C. In order to bond the head chip 13 on the nozzle plate 12, the barrier layer of the head chip 13 needs to be bonded on the nozzle plate 12; the bonding temperature is caused by characteristics of the barrier layer, so that the barrier layer according to the embodiment is cured under the circumstance of temperature 120° C.
The nozzle plate 12 herein is provided with nozzle holes, and is bonded so that the nozzle holes correspond to the heater elements of the head chip 13 (so that the axis of each nozzle hole agrees to that of each heater element of the head chip 13 in the vertical direction). The nozzle holes are thereby arranged on the heater elements while around the heater element, a liquid chamber is formed with the barrier layer on the side and the nozzle plate 12 on the top.
Under the circumstance of temperature 120° C., a tensile stress is produced in the nozzle plate 12. That is, the nozzle plate 12 and the outer frame 11 are bonded together without strain under the circumstance of temperature 150° C., so that at the temperature 120° C., the nozzle plate 12 contracts more than the outer frame 11 due to the linear expansion coefficient difference between the nozzle plate 12 and the outer frame 11. However, since the contraction force of the nozzle plate 12 is smaller than the rigidity of the outer frame 11, even when the temperature is lowered from 150° C., the strain is scarcely produced in the outer frame 11 so that the contraction of the nozzle plate 12 agrees to that of the outer frame 11.
Although not shown in
Then, under the circumstance of temperature T3 lower than the temperature T2, the head support member 14 is bonded on the outer frame 11 and the head chips 13 (third process).
The relationship between ambient temperatures during assemble and the strain will be described.
Referring to
By taking only the range of the operating proof temperature into consideration, the strain during assembling can be minimized at the median temperature 25° C. (normal temperature) of the range.
However, when the printer is used in practice, the temperature of the line head 10 increases higher than the room temperature, becoming about 45° C. at the room temperature of 25° C.
Accordingly, during the assemble at 25° C. according to the straight line L1, the amount of the strain becomes Dave when the temperature of the operating line head 10 arrives at 45° C. Whereas, when the assemble temperature becomes 45° C., which is an average operating temperature (estimate) of the line head 10, the characteristics exhibit a straight line L2, so that the strain is zero at 45° C.
Then, according to the embodiment, the bonding temperature of the head support member 14 is established at 45° C. (within the range of 45±10° C. as a design value) so as to suppress the strain in the head support member 14 at an average operating temperature (45° C.). That is, the temperature T3 is 45±10° C.
When the printer is started after a long period of rest, the temperature of the line head 10 is reduced lower than the room temperature (25° C.), so that a strain may be produced in the head support member 14 at this time. In such a case, the line head 10 may be preliminarily heated when necessary.
Also, under the circumstance of temperature 45° C., as shown in
Then, as shown in
In the line head 10 structured as described above, the temperature in a stand-by period or during operating is 150° C. or less so that a tensile stress is always produced in the nozzle plate 12. At 150° C. or less, the nozzle plate 12 expands/contracts following expansion/contraction of the outer frame 11. Moreover, the head chips 13 are bonded on the nozzle plate 12: since the linear expansion coefficient of the head chip 13 is substantially the same as that of the outer frame 11 so that the nozzle plate 12 follows the expansion/contraction of the outer frame 11, even when temperature change occurs, the positional relationship between the heater elements of the head chip 13 and the nozzle holes of the nozzle plate 12 can be maintained.
Furthermore, at the average operating temperature (45° C.) of the line head 10, no thermal stress is produced in the head support member 14 and the outer frame 11 so as to have no strain. When the linear expansion coefficient of the head support member 14 is larger than that of the outer frame 11, a compression stress (arrows P1 in
In this case, the elongation of the head support member 14 exceeds that of the outer frame 11; however, the head support member 14 is clamped at its both ends in the longitudinal direction by the outer frame 11 while the junction surface rigidity of the outer frame 11 is established to be larger than that of the head support member 14. That is, when the temperature rises higher than 45° C., a compression stress is produced in the head support member 14 while the strain of the head support member 14 is restricted by the outer frame 11.
As shown in
For example, a polyurethane resin adhesive can include the flexibility (rubber elasticity) corresponding to the combination of materials. Also, an elastomer resin adhesive is made from a material having rubber elasticity after curing as a base, so that the cured adhesive has more or less rubber elasticity. For example in a silicone resin, owing to polysiloxane as its principal material, the cured resin exhibits the rubber elasticity in any one of room curing and hot setting types.
As described above, when the line head 10 is made from the combination of a plurality of materials with different linear expansion coefficients, the strain due to the temperature change can be suppressed to the minimum.
Then, the line head 10 is mounted on an inkjet printer body and is moved relative to a recording medium. For example, in a state that the line head 10 is fixed to the printer body, the recording medium is moved in a direction perpendicular to the longitudinal direction of the line head 10.
During the relative movement, liquid droplets are ejected from each head chip 13 of the line head 10. That is, the heater element arranged on the head chip 13 is heated such that a soaring force is applied to liquid on the heater element by the pressure change due to generation/dissipation of bubbles. By this soaring force, the liquid droplets are ejected from the nozzle hole so as to form images by the landing of the liquid droplets on a recording medium.
By such driving of the line head 10, the temperature of the line head 10 rises; however, the distance between the head chip 13 and a recording medium scarcely changes even when the temperature change is produced in the line head 10 (even if the thermal stress is generated inside the line head 10), resulting in high-quality printing.
Continuously, an example of the present invention will be described. In the example, the line head 10 was four-color line head (Y: yellow, M: magenta, C: cyan, and K: black).
First, the outer frame 11 was made of ceramics (powder sintered ceramics). As this was the outer frame 11 for the four-color line head, four grooves (ovals 11a, 11b, 11c, and 11d) were provided formed in parallel with each other (see
On both surfaces of the outer frame 11, electro-cast nickel thin films (thickness 13 μm) were laid under the circumstance of temperature 160° C. (in the example, the temperature was 160° C. more than 150° C.). The nozzle plate 12 was provided on the bottom surface, and on the top surface, a reinforcing plate 12h was provided for improving the tension balance. Applying tension on both surfaces reduces the difference between stresses applied on both the surfaces.
In the example, the number of bondings of each head chip 13 was large, and if long bonding work holes 12b were provided simultaneously, the strain of the nozzle plate 12 bonded at 160° C. was increased. A bonding terminal with a number of pads was provided, and as for the head chip 13, an electrode was divided into two divisions, so that the strain on the nozzle plate 12 was reduced by corresponding half of the oval to each division.
Between the head chips 13, the dummy chips D mentioned above were arranged, and bonded by the same method as that of the head chip 13. However, electrical connection was not provided to the dummy chips D.
The clearance between the head chip 13 and the dummy chip D was sealed up after being bonded on the nozzle plate 12 so as to prevent liquid from leaking out of a region surrounded by the head chip 13 and the dummy chip D.
Also, three kinds of the head support member 14 were manufactured. The first member was made of aluminum as a ground material covered with a polyimide resin on the surface. The second member was made of injection-molded liquid crystal plastics. The third member used a flat plate of stainless steel (thickness 0.3 mm). At both ends of the head support member 14, grooves were provided for making spaces (10 mm×0.9 mm) for inserting the bonding terminal thereinto.
The assemble process is as follows:
(1) Under the circumstance of temperature 160° C., the nozzle plate 12 and the reinforcing plate 12h were boned on the outer frame 11.
(2) The head chip 13 was bonded so as to align it with the nozzle holes 12a formed on the nozzle plate 12 with high accuracy by photochemical engraving in advance.
(3) The dummy chips D were bonded with reference to positions of the head chips 13.
(4) The clearance between the dummy chip D and the head chip 13 was sealed up.
(5) The head support member 14 was bonded to the head chip 13 by applying an adhesive on top surfaces of the head chip 13 and the dummy chip D, and dropping the head support member 14 through the groove formed on the outer frame 11 from the top.
(6) A predetermined position around the head support member 14 was filled with an adhesive, and the head support member 14 was pressurized with a fixing jig, and left to stand for a predetermined period (for curing the adhesive). This process was also tried at a normal temperature (25° C.) in addition to under the circumstance of temperature 45° C., which is the average operating temperature of the line head 10.
(7) After confirming the bonding of the head support member 14, the fixing jig was removed; and a terminal plate 16 (see
(8) Wire bonding was carried out through the bonding work holes 12b shown in
(9) The bonding work holes 12b were sealed up.
Using the line head 10 manufactured by the process mentioned above, images were printed. In addition, the head support member 14 was made of aluminum and polyimide, and the printing was performed at the room temperature 35° C. using both the head support members 14 bonded at the normal temperature 25° C. and bonded at the average operating temperature 45° C. As a result, in any of the samples, it was confirmed that the print quality was improved more than ever and the effect due to the thermal stress was reduced.
Number | Date | Country | Kind |
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P2004-045720 | Feb 2004 | JP | national |
P2004-110866 | Apr 2004 | JP | national |
Number | Name | Date | Kind |
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5971522 | Ono et al. | Oct 1999 | A |
20020067395 | Horii et al. | Jun 2002 | A1 |
20030156156 | Sakaida et al. | Aug 2003 | A1 |
Number | Date | Country | |
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20050195238 A1 | Sep 2005 | US |