Liquid hydrocarbon slug containing vapor recovery system

Information

  • Patent Grant
  • 8900343
  • Patent Number
    8,900,343
  • Date Filed
    Thursday, August 8, 2013
    10 years ago
  • Date Issued
    Tuesday, December 2, 2014
    9 years ago
Abstract
A liquid hydrocarbon slug-containing vessel for incorporation into a system integrating a low-pressure separator with a vapor recovery process system, and a method for regulating the temperature of a gas to be compressed by a two stage compressor so as to prevent liquification of the gas and to prevent over-heating of the compressor.
Description
BACKGROUND OF THE INVENTION

1. Field of the Invention (Technical Field)


The present invention relates to a stand-alone, liquid hydrocarbon slug-containing vapor recovery process system for application on natural gas well pads having either single or multiple wells.


2. Background Art


Natural gas production units can be can be integrated with the components (e.g., engine, emissions separator, circulating pump, educator, compressor, and controls) of a vapor recovery process system (referred to herein as a “VRSA”) such as that described in U.S. patent application Ser. No. 11/677,985, now abandoned, entitled “Natural Gas Vapor Recovery Process System”, filed Feb. 22, 2007 (the specification and claims of which are incorporated herein by reference). In such an integrated system, a vessel can be incorporated to contain a liquid hydrocarbon slug to relieve the VRSA from having to handle vapors derived from liquid hydrocarbons beyond its instant capacity to do so. Such a slug-containing vessel operates at the flowing line pressure and captures a liquid hydrocarbon slug upstream of the high pressure separator. Such an integrated system requires a slug-containing vessel for each well that produces liquid hydrocarbon slugs greater than the instant capacity of the VRSA.


However, because many of the applications of a VRSA are on well pads that have several natural gas wells, and the wells are already equipped with production units of various designs, a design is needed for a stand-alone, slug-containing VRSA that (limited only by the gas capacity of the compressor) could recover all the hydrocarbon vapors from the liquids produced by multiple wells on a well pad.


Note that where the discussion herein refers to a number of publications by author(s) and year of publication, that, due to recent publication dates, certain publications are not to be considered as prior art vis-à-vis the present invention. Discussion of such publications herein is given for more complete background and is not to be construed as an admission that such publications are prior art for patentability determination purposes.


BRIEF SUMMARY OF THE INVENTION

An embodiment of the present invention relates to a method for operating a two stage compressor including providing a compressor having a first stage and second stage, connecting an inlet of the first stage to a heater, and connecting an outlet of the first stage through a cooler that relies on external power. The cooler can include a heat exchanger that is at least partially immersed in produced fluids. In one embodiment, heat is generated, at least in part, by the first stage of the compressor. The heater and the cooler can be contained within a single unit.


In one embodiment, the heater maintains a temperature range for a gas passing through and/or entering the compressor at a temperature sufficient to prevent condensation and/or liquification of the gas in the compressor. Further, the cooler can maintain a temperature range for a gas passing through the compressor at a temperature sufficient to prevent thermal damage from occurring to the compressor. In one embodiment, the cooler can cool via conduction to produced fluids at a lower temperature. The effects of ambient air temperature on the heater and/or cooler can be reduced and/or eliminated.


An embodiment of the present invention relates to a method for handling a liquid hydrocarbon slug including a liquid hydrocarbon slug-containing vessel in communication with a natural gas well for receiving produced liquids, and a liquid level control in communication with a vapor recovery process system to cause the produced liquids to flow to the vapor recovery process system when the vapor recovery process system can accommodate vapors derived from the liquid hydrocarbons. The method can further include disposing a high pressure separator between, and in communication with, the natural gas well and the liquid hydrocarbon slug-containing vessel and/or disposing a low pressure separator between, and in communication with, the liquid hydrocarbon slug-containing vessel and the vapor recovery process system.


An embodiment of the present invention relates to an apparatus for containing a slug of liquid hydrocarbons collected in a natural gas well production unit or separator having a vessel, a liquid accumulator section of the vessel for communication with a low pressure separator, a liquid level control connected to the liquid accumulator section, the liquid level control including a valve for sending liquid hydrocarbons to the low pressure separator when a vapor recovery process system can receive gaseous hydrocarbons, and a gas container in communication with a high pressure separator. The apparatus can also have a first pipe in said low pressure separator, the first pipe heating a gas entering a first stage of a compressor when the gas temperature is cooler than desired. The apparatus can also have an output signal component in communication with the gas entering the first stage of the compressor. The output signal component can include a transducer, which can include a thermostat.


In one embodiment, the apparatus can include a second pipe in the low pressure separator, the second pipe cooling a gas discharged from the first stage of the compressor when the gas discharge temperature is hotter than desired. The apparatus can also include second output signal component in communication with the discharge gas exiting the first stage of the compressor and sensing whether the discharge gas is too hot. The second output signal component can include a transducer, which can include a thermostat. In the apparatus, the first pipe heats the gas entering the first stage of the compressor if the temperature of the gas is less than or about the same as a temperature at which the gas liquefies and/or condenses. In the apparatus, the second pipe cools the gas discharged from the first stage of the compressor if the temperature of the gas is greater than or about at a temperature at which compression of the gas by the second stage of the compressor would result in a temperature at or above that which would cause thermal damage to the compressor. Either or both of first and second pipes can include a heat exchanger incorporated therein or attached thereto.


An embodiment of the present invention also relates to a method for reducing energy consumption by heating a gas with thermal energy from produced fluids instead of another heat source.


Embodiments of the present invention provides for a vessel, and related components, for containing a slug of liquid hydrocarbons that are received from a natural gas well or wells of a natural gas production unit until a vapor recovery process system integrated into the production unit has the capacity to receive the liquid hydrocarbons and handle vapors that emanate from the liquid hydrocarbons.


Thus, an embodiment of the present invention provides a system having a vapor recovery process system in combination with a low-pressure separator, the system comprising a liquid hydrocarbon slug-containing vessel in communication with a high pressure separator installed on a natural gas well for receiving produced liquids and a liquid level control in communication with the vapor recovery process system and in communication with the liquid hydrocarbon slug-containing vessel to effect the flow of the produced liquids to the low-pressure separator and the evolved gases to the missions separator of the vapor recovery process system when the vapor recovery process system can accommodate vapors derived from the liquid hydrocarbons. The system further comprises a high pressure separator disposed between, and in communication with, the natural gas well and the liquid hydrocarbon slug-containing vessel. The system further comprises a low pressure separator disposed between, and in communication with, the liquid hydrocarbon slug-containing vessel and the vapor recovery process system.


Another embodiment of the present invention provides an apparatus for containing a slug of liquid hydrocarbons collected by a natural gas well high pressure separator, the apparatus comprising a vessel, a first boot (i.e., a liquid accumulator section) extending from a bottom of the vessel for immersion into the heated liquids contained in a low pressure separator and in communication with a vapor recovery process system, a liquid level control disposed in the first boot and in communication with a logic controller, a second boot (i.e., a gas dome) extending above a top of the vessel for communication with a high pressure separator in communication with a natural gas well, and a valve in communication with the liquid level control, the valve opening to send liquid hydrocarbons to the low pressure separator when the logic controller indicates that the vapor recovery process system can receive the liquid hydrocarbons. The apparatus further comprises a first pipe coil in the low pressure separator and immersed in produced liquids contained in the low pressure separator, the first pipe coil controlling a gas discharge temperature of a first stage of a compressor when the gas discharge temperature is cooler than desired. The apparatus further comprises an output signal component in communication with the discharge gas exiting the first compressor stage and sensing whether the discharge gas is too cool, the output signal component sending an output signal to control a first three-way splitter valve. The output signal component may comprise a transducer controlling an I/P or a thermostat. The apparatus further comprises a second pipe coil in the low pressure separator and immersed in liquids contained in the low pressure separator, the second pipe coil controlling a gas discharge temperature of the second stage of a compressor when the gas discharge temperature is hotter than desired. The apparatus has a second output signal component in communication with the discharge gas exiting the compressor and sensing whether the discharge gas is too hot, the second output signal component sending an output signal to a second three-way splitter valve. The second output signal component may comprise a transducer controlling an I/P or a thermostat.


Objects, advantages and novel features, and further scope of applicability of the present invention are set forth in part in the detailed description to follow, taken in conjunction with the accompanying drawings, and in part will become apparent to those skilled in the art upon examination of the following, or may be learned by practice of the invention. The objects and advantages of the invention may be realized and attained by means of the instrumentalities and combinations particularly pointed out in the appended claims.





BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

The accompanying drawings, which are incorporated into and form a part of the specification, illustrate one or more embodiments of the present invention and, together with the description, serve to explain the principles of the invention. The drawings are only for the purpose of illustrating one or more preferred embodiments of the invention and are not to be construed as limiting the invention.



FIG. 1 is a flow diagram of a stand-alone, slug containing VRSA of an embodiment of the present invention;



FIG. 2 is a schematic of a configuration of the intermediate pressure slug containing vessel of an embodiment of the present invention; and



FIG. 3 is a schematic showing the operation of pipe coils of an embodiment of the present invention.





DETAILED DESCRIPTION OF THE INVENTION

An embodiment of the present invention provides for a vessel and system, for use with a vapor recovery process system (a “VRSA”), for containing a liquid hydrocarbon slug for those instances where the VRSA does not have the capacity to handle vapors, derived from liquid hydrocarbons, above a given amount.


As used herein, the words “a”, “an”, and “the” mean one or more. The same number labels in the figures are used consistently throughout for better understanding although such consistent use of numbering does not imply restriction to one embodiment.


Turning to the figures, FIG. 1 is a flow diagram of an embodiment of the stand-alone, slug-containing VRSA of the present invention. One or more natural gas wells may produce a liquid hydrocarbon slug that could exceed the capacity of VRSA 24 to handle the instantaneous volume of vapors created by the liquid hydrocarbon slug. In the embodiment illustrated in FIG. 1, natural gas wells 1 and 2 are in communication with high pressure separators 7 and 8 via well flow lines 5 and 6. High pressure separators 7 and 8 separate the produced natural gas from the produced liquids and may stand alone or be a part of a production unit. Liquids collected in high pressure separators 7 and 8 are transferred via dump line 10 to intermediate pressure liquid slug-containing vessel 9. Gases that evolve from the liquids being dumped into intermediate pressure slug containing vessel 9 are transferred to the inlet of backpressure regulator 12 via flow line 11.


Gases and/or liquids exiting backpressure regulator 12 are transferred into low pressure separator 14 (which, in this embodiment, is heated) via flow line 13 (the complete operation of backpressure regulator 12 is further illustrated in FIG. 2).


Liquid level control 15 sends a pressure signal through tubing line 17 to open motor valve 16 and transfers produced liquids from intermediate pressure slug containing vessel 9 through line 18 into low pressure separator 14. Line 21 transfers produced liquids from low pressure separator 14 into storage tank 22. Line 23 transfers gases evolved from the liquids in storage tank 22 into the emissions separator (not shown) of VRSA 24.


Line 32 transfers the gases from low pressure separator 14 to the inlet of backpressure valve 33. Line 25 transfers the gases exiting back pressure valve 33 into the emissions separator (not shown) of VRSA 24. Line 26 preferably transfers the gases collected and compressed by VRSA 24 to the inlet of one of the high pressure separators. Transducer 27 measures the pressure in storage tank 22. Transducer 29 measures the pressure in emissions separator (not shown) of VRSA 24. Electrical line 30 connects transducer 27 to programmable logic controller (“PLC”) 28. Electrical line 31 connects transducer 29 to PLC 28. I/P transducer (converting current input to pressure output) 34 may be installed to control the pressure signal either upstream of liquid level control 15 (as shown) or downstream of liquid level control 15 on tubing line 17. Electrical line 35 connects PLC 28 to I/P transducer 34. Tubing line 36 (see FIG. 2) carries a controlled pressure signal from I/P transducer 34 to the supply gas inlet of liquid level control 15.



FIG. 2 is a schematic of a configuration of an embodiment of intermediate pressure slug containing vessel 9. Intermediate pressure vessel 9 is illustrated as a horizontal vessel (the preferred design) with liquid accumulator section 42 (a first boot) and gas dome 43 (a second boot).


Liquid accumulator section 42 extends downwardly from the bottom of intermediate pressure slug-containing vessel 9, through the top of low pressure separator 14 and into heated liquid contained in low pressure separator 14. Liquid accumulator section 42 contains liquid level control 15 and internal dump line 37 which extends downwardly from outlet connection 48 located at the top of intermediate pressure vessel 9 to a distance (e.g., approximately 2 inches) from the bottom of liquid accumulator section 42. Gas dome 43 extends upwardly a distance (e.g., approximately two feet) above the top of intermediate pressure vessel 9. Gas dome 43 has inlet connection 47 connected to line 10. Line 10 transfers the produced liquids from the high pressure separators to intermediate pressure slug containing vessel 9. Internally, gas dome 43 has line 44 which extends downwardly from outlet connection 46 to terminate at point 50. In a most preferred embodiment, point 50 is approximately four inches below inlet connection 47 and approximately four inches above the top of intermediate pressure slug containing vessel 9. The outlet of connection 46 is connected by line 11 to the inlet of back pressure regulator 12. Back pressure regulator 12 senses, through tubing line 38, the gas pressure contained in intermediate pressure slug containing vessel 9.


The specific operation of intermediate pressure slug containing vessel 9 is as follows. The operation of intermediate pressure slug containing vessel 9 begins when produced liquids are dumped from high pressure separators 7 and 8 into intermediate pressure slug containing vessel 9. The pressure in intermediate pressure slug containing vessel 9 is controlled by backpressure regulator 12 to maintain an intermediate pressure of, for example, from approximately 75 to 150 psig between the operating pressure of high pressure separators 7 and 8 and low pressure separator 14. The pressure settings of backpressure regulators 12 and 33 are determined by the lowest expected flowing line pressure in the high pressure separators. The change of pressure between the high pressure separators and intermediate pressure slug containing vessel 9 causes entrained gases and some liquid flashing to occur in intermediate pressure slug containing vessel 9.


As soon as the gas pressure in intermediate pressure slug containing vessel 9 reaches the set pressure of back pressure regulator 12, gas will begin to flow through back pressure regulator 12 into low pressure separator 14. The produced liquids entering intermediate pressure slug containing vessel 9 will fall to the bottom and begin filling liquid accumulator section 42.


If the output through electric line 35 from PLC 28 to I/P transducer 34 (such transducers convert current input to a proportional pressure output) shows that VRSA 24 can handle the vapors generated by the liquids entering intermediate pressure slug containing vessel 9, liquid level control 15 will open dump valve 16, and through lines 37, 49, and 18, cause the produced liquids to flow into low pressure separator 14.


If the volume of vapors from the produced liquids entering intermediate pressure vessel 9 begin to overload the vapor capacity of VRSA 24, PLC 28 will send a signal to I/P transducer 34 to begin closing dump valve 16. As long as the volume of produced liquids entering intermediate pressure slug containing vessel 9 continue to generate enough vapors to overload the capacity of VRSA 24, PLC 28 through I/P transducer 34 will continue to close dump valve 16.


Keeping dump valve 16 closed will cause intermediate pressure slug containing vessel 9 to begin filling with produced liquids. Intermediate pressure slug containing vessel 9 preferably has several barrels of fluid capacity and is designed to store excess produced liquids so they can be dumped over an extended period of time to match the vapor capacity of VRSA 24. In case of a mechanical failure or other unexpected occurrence, line 44 is designed to prevent overfilling of intermediate pressure slug containing vessel 9. Anytime bottom 50 of line 44 becomes covered with produced liquids, the produced liquids will flow with the released vapors through lines 44, 11, and 13 and back pressure valve 12 into low pressure separator 14. Produced liquids flowing through back pressure valve 12 would be an upset operating condition.


Referring again to FIG. 2, low pressure separator 14, can be either two or three-phased. Low pressure separator 14 has fire tube 39 to provide heat to the system. The bottom end of emission separator 45 (a component of VRSA 24) is immersed in the heated liquids contained in low pressure separator 14. Also, two pipe coils 40 and 41 are immersed in the liquids contained in low pressure separator 14. As required to control the temperature of control gas entering the emissions separator or the stages of compression, additional coils could be installed in the low-pressure separator.



FIG. 3 is a schematic illustrating the operation of pipe coils 40 and 41. As previously described, both pipe coils 40 and 41 are immersed in the produced liquids contained in low pressure separator 14. The purpose of pipe coils 40 and 41 is to control the gas discharge temperature of both stages of two-stage compressor 51. Controlling the gas discharge temperatures of two-stage compressor 51 provides successful operation of VRSA 24. If the gas discharge temperature is too low (below, for example, 170 degrees Fahrenheit after the first stage of compression), condensation of the collected vapors could occur in the first stage compressor cylinder and lead to rapid mechanical failure of the compressor. If the discharge gas temperature is too high (for example, 300 degrees Fahrenheit or above after the second stage of compression), mechanical failure of the compressor could also occur.


Referring again to FIG. 3, pipe coil 40 is a heating coil immersed in the produced liquids contained in low pressure separator 14. Pipe coil 40 is designed to heat, if necessary, the collected vapors exiting emission separator 45 prior to the vapors entering first compression stage 62 of two-stage compressor 51. Flow line 53 splits at point 54 into flow lines 55 and 56. Flow line 55 connects from point 54 to one inlet port 57 of three-way valve 52 (commonly referred to as a splitter valve). Flow line 56 connects from point 54 to inlet 64 of heating coil 40. Flow line 65 connects from outlet connection 66 of heating coil 40 to a second inlet port 58 of three-way valve 52. Flow line 60 connects from common port 59 of three-way valve 52 to inlet port 61 of first stage of compressor 51. Component 63 may be either a transducer utilized to control an I/P or a throttling indirect acting thermostat (as temperature falls, output increases) that senses the temperature of the discharge gas exiting the first stage of compression 62. Instrument gas supply line 64 is illustrated leading to component 63. Tubing line 68 carries the output signal from component 63 (in this embodiment, a throttling thermostat) to the diaphragm of three-way valve 52.


As previously described, to prevent condensation of the collected vapors, it is necessary to maintain the temperature of the gas exiting first compression stage 62 at approximately 170 degrees Fahrenheit or above. If thermostat or transducer 63 senses that the discharge gas temperature in flow line 67 is too cool, it will send a pressure signal to first three-way valve 52 to begin closing the gas flow between inlet port 57 and common port 59. Decreasing the proportion of the gas flow between ports 57 and 59 will cause the balance of the gas flowing through line 53 to flow through heating coil 40 where it collects heat prior to entering port 58 of three-way valve 52. In three-way valve 52, the cool gas from port 57 will mix with the heated gas from port 58 to maintain an adequate temperature of the gas entering at inlet port 61 the first stage of compression 62 to provide the desired gas discharge temperature of approximately 170 degrees Fahrenheit or above in flow line 67. Under most operating conditions, it is anticipated that, because of compression, the temperature of the discharge gas in flow line 67 will be in the range of about 200 degrees Fahrenheit; therefore, heating coil 40 will only be required to provide heat to the gas in flow line 60 when very cold ambient temperatures are encountered.


Cooling coil 41 is immersed in the produced fluids contained in low pressure separator 14. Cooling coil 41 uses the fluids in low pressure separator 14 as a heat sink to cool, when required, the hot gases exiting from first stage of compression 62 before the hot gases enter the second stage of compression 69. As previously described to prevent damage to compressor 51, it is necessary to keep the maximum temperature of the gas exiting the second stage of compression 69 of compressor 51 below approximately 300 degrees Fahrenheit. Cooling coil 41 mirrors the operation of heating coil 40. The only change is that component 70 (a thermostat or transducer and I/P) which senses the temperature of the gas in discharge flow line 26 is direct acting (as temperature rises, output increases) and the action of second three-way valve 73 becomes the reverse of the action of first three-way valve 52. The gas flowing from port 74 to port 75 is hot. The gas flowing from port 76 to port 75 is cooled. Component 70 (which again, is a thermostat or transducer and I/P) opens and closes three-way valve 73 to maintain the desired temperature of approximately 270 degrees Fahrenheit in discharge flow line 26. Flow line 26 preferably transfers the collected and compressed vapors to the inlet of one of the high pressure separators. Unlike prior art systems, embodiments of the present invention thus provide the ability to accurately control the temperature of gas entering and passing through the compressor regardless of what the ambient temperature is or even if the ambient temperature fluctuates over a large range.


By pre-heating the gas flowing into the inlet to the first stage of the compression, the gas is maintained in a gaseous state. By cooling the gas after compression by the first stage, the gas is allowed to enter the second stage of compression at a temperature low enough to ensure that damage to the compressor does not occur because of excess gas temperature during compression of the gas in the second stage of the compressor. Thus, embodiments of the present invention not only ensure that the gas is maintained at a temperature that prevents condensation and/or liquification of the gas, but also maintains the gas at a temperature low enough to prevent thermal damage to the compressor.


The present invention not only provides more desirable results than prior art systems, but also provides desirable results using less energy because the heat transferred from the hot gas to the produced liquid decreases the amount of fuel, gas, or other energy source required to maintain the produced liquids at the desired bath temperature.


The preceding examples can be repeated with similar success by substituting the generically or specifically described components and/or operating conditions of this invention for those used in the preceding examples.


Although the invention has been described in detail with particular reference to these preferred embodiments, other embodiments can achieve the same results. Variations and modifications of the present invention will be obvious to those skilled in the art and it is intended to cover all such modifications and equivalents. The entire disclosures of all references, applications, patents, and publications cited above, and of the corresponding application(s), are hereby incorporated by reference.

Claims
  • 1. A method for reducing energy consumption comprising: accepting a flow of produced fluids from a natural gas well into a high pressure separator;separating produced liquids from the produced fluids; passing the produced liquids from the high pressure separator to an intermediate pressure liquid slug-containing vessel;passing the produced liquids from the intermediate pressure liquid slug-containing vessel to a low pressure separator; andheating a gas with thermal energy from the produced liquids within the low pressure separator instead of another heat source before the gas is compressed in a compressor at a well site.
  • 2. The method of claim 1 further comprising providing liquid slug control by providing a liquid level control and configuring the liquid level control to permit evolved gases from the liquid slug to flow to a vapor recovery process system when the vapor recovery process system can accommodate a quantity of the evolved gases.
  • 3. The method of claim 2 further comprising providing the intermediate pressure liquid slug-containing vessel with a volumetric capacity of several barrels.
  • 4. The method of claim 2 wherein the intermediate pressure liquid slug-containing vessel is designed to store excess produced liquids so they can be dumped over an extended period of time to match the vapor capacity of the vapor recovery system.
  • 5. The method of claim 1 further comprising cooling the gas after it exits a first stage of compression by exchanging heat from the gas to the produced liquids.
  • 6. The method of claim 1 wherein the gas is heated at least in part from energy removed from the gas having exited a first stage of compression.
  • 7. The method of claim 1 wherein the produced liquids are passed from the low pressure separator to a vapor recovery process system.
  • 8. The method of claim 7 wherein a lower portion of an emissions separator of the vapor recovery process system is immersed in the produced liquids contained in the low pressure separator.
  • 9. The method of claim 8 wherein the gas being heated is gas that has evolved in the emissions separator of the vapor recovery process system.
  • 10. The method of claim 7 wherein the compressor at the well site is a portion of the vapor recovery system.
  • 11. The method of claim 1 further comprising positioning a firetube such that heat from the firetube heats the liquids within the low pressure separator.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional application of U.S. patent application Ser. No. 12/043,685, now issued as U.S. Pat. No. 8,529,215, entitled “Liquid Hydrocarbon Slug Containing Vapor Recovery System”, to Rodney T. Heath, et al., filed on Mar. 6, 2008, and the specification and claims thereof are incorporated herein by reference.

US Referenced Citations (211)
Number Name Date Kind
844694 Smith Feb 1907 A
1903481 Schweisthal Apr 1933 A
2225959 Miller Dec 1940 A
2726729 Williams Dec 1955 A
2738026 Glasgow Mar 1956 A
2765872 Hartman Oct 1956 A
2786543 Hayes et al. Mar 1957 A
2812827 Worley et al. Nov 1957 A
2815901 Hale Dec 1957 A
2853149 Gosselin Sep 1958 A
2937140 Stinson May 1960 A
2970107 Gilmore Jan 1961 A
2984360 Smith May 1961 A
3018640 Heller et al. Jan 1962 A
3025928 Heath Mar 1962 A
3027651 Nerge Apr 1962 A
3094574 Glasgow et al. Jun 1963 A
3105855 Meyers Oct 1963 A
3152753 Adams Oct 1964 A
3182434 Fryar May 1965 A
3237847 Wilson Mar 1966 A
3254473 Fryer et al. Jun 1966 A
3255573 Cox, Jr. et al. Jun 1966 A
3288448 Patterson Nov 1966 A
3321890 Barnhart May 1967 A
3347019 Barnhart Oct 1967 A
3360127 Wood, Jr. Dec 1967 A
3396512 McMinn et al. Aug 1968 A
3398723 Smalling Aug 1968 A
3407052 Huntress et al. Oct 1968 A
3528758 Perkins Sep 1970 A
3540821 Siegmund Nov 1970 A
3541763 Heath Nov 1970 A
3589984 Reid Jun 1971 A
3616598 Floral, Jr. Nov 1971 A
3648434 Graves, III et al. Mar 1972 A
3659401 Giammarco May 1972 A
3672127 Mayse et al. Jun 1972 A
3736725 Alleman et al. Jun 1973 A
3817687 Cavallero et al. Jun 1974 A
3829521 Green Aug 1974 A
3855337 Foral, Jr. et al. Dec 1974 A
3872682 Shook Mar 1975 A
3949749 Stewart Apr 1976 A
3989487 Peterson Nov 1976 A
4009985 Hirt Mar 1977 A
4010009 Moyer Mar 1977 A
4010065 Alleman Mar 1977 A
4058147 Stary et al. Nov 1977 A
4098303 Gammell Jul 1978 A
4108618 Schneider Aug 1978 A
4118170 Hirt Oct 1978 A
4134271 Datia Jan 1979 A
4162145 Alleman Jul 1979 A
4198214 Heath et al. Apr 1980 A
4270938 Schmidt et al. Jun 1981 A
4286929 Heath et al. Sep 1981 A
4305895 Heath et al. Dec 1981 A
4322265 Wood Mar 1982 A
4332643 Reid Jun 1982 A
4342572 Heath Aug 1982 A
4362462 Blotenberg Dec 1982 A
4369049 Heath Jan 1983 A
4396371 Lorenz et al. Aug 1983 A
4402652 Gerlach et al. Sep 1983 A
4421062 Padilla, Sr. Dec 1983 A
4431433 Gerlach et al. Feb 1984 A
4435196 Pielkenrood Mar 1984 A
4459098 Turek et al. Jul 1984 A
4462813 May et al. Jul 1984 A
4474549 Capone Oct 1984 A
4474550 Heath et al. Oct 1984 A
4493770 Moilliet Jan 1985 A
4501253 Gertsmann et al. Feb 1985 A
4505333 Ricks Mar 1985 A
4511374 Heath Apr 1985 A
4539023 Boley Sep 1985 A
4568268 Gerlach et al. Feb 1986 A
4579565 Heath Apr 1986 A
4583998 Reid et al. Apr 1986 A
4588372 Torborg May 1986 A
4588424 Heath et al. May 1986 A
4597733 Dean et al. Jul 1986 A
4615673 Heath et al. Oct 1986 A
4617030 Heath Oct 1986 A
4659344 Gerlach et al. Apr 1987 A
4674446 Padilla, Sr. Jun 1987 A
4676806 Dean et al. Jun 1987 A
4689053 Heath Aug 1987 A
4701188 Mims Oct 1987 A
4715808 Heath et al. Dec 1987 A
4737168 Heath Apr 1988 A
4778443 Sands et al. Oct 1988 A
4780115 Ranke Oct 1988 A
4824447 Goldsberry Apr 1989 A
4830580 Hata et al. May 1989 A
4919777 Bull Apr 1990 A
4948393 Hodson et al. Aug 1990 A
4949544 Hines Aug 1990 A
4978291 Nakai Dec 1990 A
4983364 Buck et al. Jan 1991 A
5080802 Cairo, Jr. et al. Jan 1992 A
5084074 Beer et al. Jan 1992 A
5129925 Marsala et al. Jul 1992 A
5130078 Dillman Jul 1992 A
5132011 Ferris Jul 1992 A
5163981 Choi Nov 1992 A
5167675 Rhodes Dec 1992 A
5191990 Fritts Mar 1993 A
5195587 Webb Mar 1993 A
5209762 Lowell May 1993 A
5249739 Bartels et al. Oct 1993 A
5269886 Brigham Dec 1993 A
5346537 Lowell Sep 1994 A
5377723 Hilliard Jan 1995 A
5419299 Fukasawa et al. May 1995 A
5453114 Ebeling Sep 1995 A
5476126 Hilliard et al. Dec 1995 A
5490873 Behrens et al. Feb 1996 A
5501253 Weiss Mar 1996 A
5513680 Hilliard et al. May 1996 A
5536303 Ebeling Jul 1996 A
5571310 Nanaji Nov 1996 A
5579740 Cotton et al. Dec 1996 A
5664144 Yanai et al. Sep 1997 A
5665144 Hill et al. Sep 1997 A
5678411 Matsumura et al. Oct 1997 A
5755854 Nanaji May 1998 A
5766313 Heath Jun 1998 A
5826433 Dube Oct 1998 A
5857616 Karnoff et al. Jan 1999 A
5878725 Osterbrink Mar 1999 A
5882486 Moore Mar 1999 A
5885060 Cunkelman et al. Mar 1999 A
5988232 Koch et al. Nov 1999 A
6004380 Landreau et al. Dec 1999 A
6010674 Miles et al. Jan 2000 A
6023003 Dunning et al. Feb 2000 A
6027311 Hill et al. Feb 2000 A
6095793 Greeb Aug 2000 A
6142191 Sutton et al. Nov 2000 A
6183540 Thonsgaard Feb 2001 B1
6193500 Bradt et al. Feb 2001 B1
6223789 Koch May 2001 B1
6224369 Moneyhun May 2001 B1
6238461 Heath May 2001 B1
6251166 Anderson Jun 2001 B1
6273937 Schucker Aug 2001 B1
6299671 Christensen Oct 2001 B1
6314981 Mayzou et al. Nov 2001 B1
6332408 Howlett Dec 2001 B2
6363744 Finn et al. Apr 2002 B2
6364933 Heath Apr 2002 B1
6425942 Forster Jul 2002 B1
6461413 Landreau et al. Oct 2002 B1
6478576 Bradt et al. Nov 2002 B1
6499476 Reddy Dec 2002 B1
6532999 Pope et al. Mar 2003 B2
6533574 Pechoux Mar 2003 B1
6537349 Choi et al. Mar 2003 B2
6537458 Polderman Mar 2003 B1
6551379 Heath Apr 2003 B2
6604558 Sauer Aug 2003 B2
6616731 Hillstrom Sep 2003 B1
6719824 Bowser Apr 2004 B1
6745576 Granger Jun 2004 B1
6931919 Weldon Aug 2005 B2
6984257 Heath et al. Jan 2006 B2
7005057 Kalnes Feb 2006 B1
7025084 Perry et al. Apr 2006 B2
7131265 Lechner Nov 2006 B2
RE39944 Heath Dec 2007 E
7350581 Wynn Apr 2008 B2
7481237 Jones et al. Jan 2009 B2
7497180 Karlsson et al. Mar 2009 B2
7531030 Heath et al. May 2009 B2
7575672 Gilmore Aug 2009 B1
7905722 Heath et al. Mar 2011 B1
8529215 Heath et al. Sep 2013 B2
20010008073 Finn et al. Jul 2001 A1
20020073843 Heath Jun 2002 A1
20020081213 Takahashi Jun 2002 A1
20020178918 Lecomte et al. Dec 2002 A1
20020185006 Lecomte et al. Dec 2002 A1
20030005823 LeBlanc et al. Jan 2003 A1
20030167690 Edlund et al. Sep 2003 A1
20040031389 Heath Feb 2004 A1
20040186630 Shier et al. Sep 2004 A1
20040211192 Lechner Oct 2004 A1
20050115248 Koehler et al. Jun 2005 A1
20050266362 Stone et al. Dec 2005 A1
20060144080 Heath et al. Jul 2006 A1
20060156744 Cusiter et al. Jul 2006 A1
20060156758 An et al. Jul 2006 A1
20060218900 Lechner Oct 2006 A1
20060254777 Wynn Nov 2006 A1
20060260468 Amin Nov 2006 A1
20070051114 Mahlanen Mar 2007 A1
20070084341 Heath et al. Apr 2007 A1
20070151292 Heath et al. Jul 2007 A1
20070175226 Karlsson et al. Aug 2007 A1
20070186770 Heath et al. Aug 2007 A1
20070199696 Walford Aug 2007 A1
20080008602 Pozivil Jan 2008 A1
20080120993 An et al. May 2008 A1
20090133578 Bras et al. May 2009 A1
20090223246 Heath Sep 2009 A1
20100040989 Heath et al. Feb 2010 A1
20120079851 Heath et al. Apr 2012 A1
20120261092 Heath et al. Oct 2012 A1
20130319844 Heath et al. Dec 2013 A1
Foreign Referenced Citations (17)
Number Date Country
011862 Sep 2000 AR
024366 Oct 2002 AR
2426071 Oct 2003 CA
2281610 Jun 2004 CA
2224389 Feb 2008 CA
2311440 Jun 2011 CA
2563747 May 2013 CA
2542039 Sep 1984 FR
370591 Apr 1932 GB
573819 Dec 1945 GB
58185990 Oct 1983 JP
2159913 Nov 2000 RU
1021809 Jun 1983 SU
1801092 Mar 1993 SU
WO2005068847 Jul 2005 WO
2010080040 Jul 2010 WO
2013170190 Nov 2013 WO
Non-Patent Literature Citations (6)
Entry
“Environmental Technology Verification Report”, Greenhouse Gas Technology Center Southern Research Institute.
“Natural Gas Dehydration”, The Environmental Technology Verification Program, Sep. 2003.
Archer, Phil , “TEG Regenerator Vapor Recovery in Amoco's Northwesern Business Unit”, Aug. 1992.
Archer, Phil , “TEG Regenerator Vapor Recovery in Amoco's Northwestern Business Unit”, Amoco Northwestern Business Unit, Aug. 1992.
Kirillov, , “RU 2159913 C1 ABSTARCT;Nov. 2000;Russian FederatION;Kirillov N G;”.
Reid, Laurance S. , “Coldfinger an Exhauster for Removing Trace Quantities of Water from Glycol Solutions Used for Gas Dehydration”, Ball-Reid Engineers, Inc., Oklahoma City, Oklahoma, 1975, 592-602.
Divisions (1)
Number Date Country
Parent 12043685 Mar 2008 US
Child 13962644 US