LIQUID-LIQUID EXTRACTION COLUMN WITH VARIABLE INTER-TRAY SPACE

Abstract

Liquid-liquid extraction column (1) comprising injection points for feedstock (2), for washing (3) and for backwashing (4), two withdrawal points (5, 6), trays (Pi) located along the column and defining 2 to 30 zones each comprising at least two trays, the n zones comprising: at least one extraction zone Zi comprising the zones from Z1 to Zx, x being greater than or equal to 1, and at least one backwash zone comprising the zones from Zx+1 to Zn, n being greater than x; in which the trays of one and the same zone exhibit one and the same height H of inter-tray space (10); in which, when x>1, the height H of the zones Zi increases when i increases; and, when x=1, the height H of the at least one backwash zone is less than the height H of zone Z1.

Description

TECHNICAL FIELD

The field of the invention relates to a column (extractor) for the liquid-liquid separation of hydrocarbon compounds, such as aromatic (e.g. A6-A11) compounds originating from broad hydrocarbon cuts (e.g. C6-C11 cut, such as originating from a catalytic cracking unit (FCC, Fluid Catalytic Cracking).

PRIOR ART

A liquid-liquid extraction operation is a key building block of processes performing the separation of hydrocarbon cuts, such as the separation of a mixture of aromatic and non-aromatic compounds. The operating principle is based on the differences in solubility of the compounds of a homogeneous liquid feedstock in an appropriate solvent (e.g. a polar aprotic solvent, such as sulfolane or DMSO). The addition to the feedstock of a partially miscible solvent causes the appearance of a second phase to which a portion of the compounds (e.g. the aromatic compounds), which are the most soluble constituents, is preferentially transferred.

Typically, the liquid-liquid extraction technology employs a liquid-liquid separation column comprising a plurality of perforated trays equipped with one or more weirs per tray, depending on the targeted capacities (reference is made to one-pass or two-pass tray or to multi-pass tray when there are more than three weirs).

The design rules for a conventional liquid-liquid extraction column consider a reference tray sized according to the maximum flow rates of each phase and their physicochemical properties. This design is subsequently employed for the whole of the column by the stacking of a plurality of trays, the trays thus all being substantially identical.

The Applicant Company has identified, on the other hand, that the operation of a liquid-liquid extraction column can give rise to substantial variability, depending in particular:

• • on the flow rate of each of the phases along the column-this phenomenon is linked, first, to the material transfer of solutes from the feedstock to the solvent and, secondly, to the possibility of modulating the backwash flow rate according to the nature of the feedstock and the targeted specifications; and
  • on the physicochemical properties and in particular on the interfacial tension between the feedstock and the solvent linked to the gradual enrichment in compounds extracted from the feedstock to the solvent.

The object of the present invention is to overcome the abovementioned deficiencies.

SUMMARY OF THE INVENTION

In the context described above, a first object of the present description is to provide a liquid-liquid extraction column which makes possible:

• • the retention of a range of between 5% and 20% of the average volume fraction of dispersed phase (i.e., solvent/heavy phase) in a compartment (i.e., zone comprising a perforated tray and an adjacent inter-tray space);
  • the non-entrainment of the droplets of dispersed phase into the weirs by the continuous phase (i.e. feedstock/light phase), in order to limit the axial mixing of the dispersed phase;
  • a height of coalesced layer of the dispersed phase on each tray which is sufficient to prevent the passage of the continuous phase through the perforated tray (and to force the exclusive passage of the continuous phase into the weirs);
  • a suitable continuous phase transverse velocity, which does not perturb the flow of the dispersed phase.

Surprisingly, the Applicant Company has identified that specific characteristics of perforated trays, such as the height of the inter-tray spaces, make it possible to control the hydrodynamics along the entire column, while limiting the axial mixing. This technical solution makes it possible to retain a satisfactory material transfer efficiency on each tray.

According to a first aspect, the abovementioned objects, and also other advantages, are obtained by a liquid-liquid extraction column, comprising the following elements:

• • a first injection point for a first phase located at an intermediate position between the top and the bottom of the column;
  • a second injection point for a second phase and a third injection point for a backwash liquid, one (of the second and third injection points) being located at the top of the column and the other being located at the bottom of the column;
  • a first withdrawal point for an extract and a second withdrawal point for a raffinate, one (of the first and second withdrawal points) being located at the bottom of the column and the other being located at the top of the column;
  • a plurality of trays located in the column (for example from the top of the column to the bottom of the column or from the bottom of the column to the top of the column) and defining n zones, each zone comprising at least two trays, n being between 2 and 30, preferably between 3 and 30;

in which the n zones comprise:

• • at least one extraction zone Z_i included between a zone (e.g. column top zone) Z₁ comprising the second injection point for the second phase (and the second withdrawal point for the raffinate) and a feed zone Z_x comprising the first injection point for the first phase, x being greater than or equal to 1 (preferably x is greater than 1); and
  • at least one backwash zone included between a zone Z_x+1 and a zone (e.g. column bottom zone) Z_n comprising the third injection point for the backwash liquid (and the first withdrawal point for the extract), n being greater than x;

in which the trays of one and the same zone exhibit substantially one and the same height H of inter-tray space; and in which:

• • when x is greater than 1, the height H of the inter-tray spaces of the zones Z_i increases when the value i increases; and
  • when x is equal to 1, the height H of the inter-tray spaces of the at least one backwash zone is less than the height H of the inter-tray spaces of the zone Z₁.

According to one or more embodiments, n is between 3 and 30, and x is greater than 1.

According to one or more embodiments, the liquid-liquid extraction column comprises the following elements:

• • a first injection point for a first phase located at an intermediate position between the top and the bottom of the column;
  • a second injection point for a second phase located at the top of the column;
  • a third injection point for a backwash liquid located at the bottom of the column;
  • a first withdrawal point for an extract located at the bottom of the column;
  • a second withdrawal point for a raffinate located at the top of the column;
  • a plurality of trays located in the column, for example from the top of the column to the bottom of the column or from the bottom of the column to the top of the column, and defining n zones, each zone comprising at least two trays, n being between 3 and 30;

in which the n zones comprise:

• • a plurality of extraction zones Z_i included between a column top zone Z₁ comprising the second injection point for the second phase (and the second withdrawal point for the raffinate) and a feed zone Z_x comprising the first injection point for the first phase, x being greater than 1; and
  • at least one backwash zone included between a zone Z_x+1 and a column bottom zone Z_n comprising the third injection point for the backwash liquid (and the first withdrawal point for the extract), n being greater than x;

in which the trays of one and the same zone exhibit substantially one and the same height H of inter-tray space; and

in which the height H of the inter-tray spaces of the zones Z_i increases when the value i increases.

According to one or more embodiments, the liquid-liquid extraction column comprises the following elements:

• • a first injection point for a first phase located at an intermediate position between the top and the bottom of the column;
  • a second injection point for a second phase located at the bottom of the column;
  • a third injection point for a backwash liquid located at the top of the column;
  • a first withdrawal point for an extract located at the top of the column;

a second withdrawal point for a raffinate located at the bottom of the column;

• • a plurality of trays located in the column, for example from the top of the column to the bottom of the column or from the bottom of the column to the top of the column, and defining n zones, each zone comprising at least two trays, n being between 3 and 30;

in which the n zones comprise:

• • a plurality of extraction zones Z_i included between a column bottom zone Z₁ comprising the second injection point for the second phase (and the second withdrawal point for the raffinate) and a feed zone Z_x comprising the first injection point for the first phase, x being greater than 1; and
  • at least one backwash zone included between a zone Z_x+1 and a column top zone Z_n comprising the third injection point for the backwash liquid (and the first withdrawal point for the extract), n being greater than x;

in which the trays of one and the same zone exhibit substantially one and the same height H of inter-tray space; and

in which the height H of the inter-tray spaces of the zones Z_i increases when the value i increases.

According to one or more embodiments, in the extraction zones Z_i where i varies from 1 to x (i.e., x greater than 1), the ratio of the height H of an inter-tray space of a zone Z_i to the height H of an inter-tray space of a zone Z_i+1 is between 0.20 and 0.95.

According to one or more embodiments, in the extraction zones Z_i where i varies from 1 to x (i.e., x greater than 1), the ratio of the height H of an inter-tray space of a zone Z_i to the height H of an inter-tray space of a zone Z_i+1 is between 0.40 and 0.90.

According to one or more embodiments, in the extraction zones Z_i where i varies from 1 to x (i.e., x greater than 1), the ratio of the height H of an inter-tray space of a zone Z_i to the height H of an inter-tray space of a zone Z_i+1 is between 0.75 and 0.85.

According to one or more embodiments, when x is equal to 1, the ratio of the height H of an inter-tray space of the at least one backwash zone to the height H of the inter-tray space of the zone Z₁ is between 0.20 and 0.95.

According to one or more embodiments, the at least one backwash zone is a plurality of zones, from a zone Z_x+1 to the (e.g. column bottom) zone Z_n, and in which the height H of the inter-tray spaces increases, is constant, or decreases from the zone Z_x+1 to the zone Z_n.

According to one or more embodiments, the at least one backwash zone is a plurality of zones subdivided into:

• • a plurality of zones Z_j included between the zone Z_x+1 and a zone Z_y, y being greater than x+1; and
  • a plurality of zones Z_k included between the zone Z_y+1 and the (e.g. column bottom) zone Z_n, and

in which:

• • in the zones Z_j where j varies from x+1 to y, the height H of the inter-tray spaces increases, is constant, or decreases when the value j increases; and/or
  • in the zones Z_k where k varies from y+1 to n, the height H of the inter-tray spaces increases, is constant, or decreases when the value k increases.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y, the ratio of the height H of the inter-tray spaces of a zone Z_j to the height H of the inter-tray spaces of a zone Z_j+1 is between 0.20 and 0.95.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y, the ratio of the height H of the inter-tray spaces of a zone Z_j to the height H of the inter-tray spaces of a zone Z_j+1 is between 1.10 and 2.0.

According to one or more embodiments, in the zones Z_k where k varies from y+1 to n, the ratio of the height H of the inter-tray spaces of a zone Z_k to the height H of the inter-tray spaces of a zone Z_k+1 is between 0.20 and 0.95.

According to one or more embodiments, in the zones Z_k where k varies from y+1 to n, the ratio of the height H of the inter-tray spaces of a zone Z_k to the height H of the inter-tray spaces of a zone Z_k+1 is between 1.10 and 2.0.

According to one or more embodiments, the number of zones Z_i is between 2 and 10 and/or the number of backwash zones is between 1 and 10.

According to one or more embodiments, the number of zones Z_j is between 2 and 10 and/or the number of zones Z_k is between 2 and 10.

According to one or more embodiments, the height H of the inter-tray spaces of the backwash zone Z_x+1 is less than, equal to or greater than the height H of the inter-tray spaces of the extraction zone Z_x.

According to one or more embodiments, the height H of the inter-tray spaces of the backwash zone Z_x+1 is less than the height H of the inter-tray spaces of the extraction zone Z_x.

According to one or more embodiments, the height H of each inter-tray space is between 0.2 m and 1.2 m.

Embodiments of the liquid-liquid extraction column according to the first aspect and also other characteristics and advantages will become apparent on reading the description which will follow, which is given purely by way of non-limiting illustration, and with reference to the following drawings.

LIST OF THE FIGURES

The FIG. 1 diagrammatically shows a cross-sectional view of a liquid-liquid extraction column according to the present invention.

The FIG. 2 diagrammatically shows a cross-sectional view of the flow of the dispersed phase and of the continuous phase in a liquid-liquid extraction column according to the present invention.

The FIG. 3 diagrammatically shows a cross-sectional view of a liquid-liquid extraction column according to the present invention defined by a plurality of zones Z_i included between the column top zone 1 and the feed zone Z_x, a plurality of zones Z_j included between the zone Z_x+1 and a zone Z_y, and a plurality of zones Z_k included between the zone Z_y+1 and the column bottom zone Z_n.

The FIG. 4 is a graph showing the change in the inter-tray transverse velocity of the continuous phase along a liquid-liquid extraction column according to the present invention, in which the height H of the inter-tray spaces is variable.

The FIG. 5 and the FIG. 6 are graphs showing the change in the inter-tray transverse velocity of the continuous phase along reference liquid-liquid extraction columns, in which the height H of the inter-tray spaces is constant.

DESCRIPTION OF THE EMBODIMENTS

Embodiments of the invention will now be described in detail. In the following detailed description, many specific details are presented in order to provide a deeper understanding of the invention. However, it will be apparent to a person skilled in the art that the invention can be implemented without these specific details. In other cases, well-known characteristics have not been described in detail in order to avoid unnecessarily complicating the description.

In the present description, the term “to comprise” is synonymous with (means the same thing as) “to include” and “to contain”, and is inclusive or open-ended and does not exclude other unrecited elements. It is understood that the term “to comprise” includes the exclusive and closed term “to consist”. In addition, in the present description, the term “substantially” corresponds to an approximation of ±10%, preferably of ±5%, very preferably of ±2%, of a reference value, such as a distance, a velocity, a flow rate, a content of compounds, a temperature, a pressure, and the like.

With reference to FIG. 1, a liquid-liquid extraction column 1 comprises the following elements:

• • a first injection point for a first phase 2 (or liquid to be separated), such as a feedstock (e.g. a mixture of aromatic and non-aromatic C6-C11 compounds), located at an intermediate position between the top and the bottom of the column 1;
  • a second injection point for a second phase 3 (or separation liquid), such as a solvent (e.g. sulfolane), located at the top of column 1;
  • a third injection point for a backwash liquid 4, such as a recycle (e.g. a mixture comprising at least 50% by weight of light compounds (i.e., C5-C8, preferably C5-C6, compounds)), located at the bottom of column 1;
  • a first withdrawal point for an extract 5 (in liquid phase), such as a solvent enriched in extracted compounds (e.g. aromatic compounds), located at the bottom of column 1; and
  • a second withdrawal point for a raffinate 6 (in liquid phase), such as a feedstock depleted in extracted compounds, located at the top of column 1.

In addition, in order to increase the yield and the purity, two distinct operating zones are defined opposite the injection point for the liquid to be separated 2:

• • an extraction sector 7, extending substantially from the first injection point for the first phase 2 up to substantially the second injection point for the second phase 3, makes it possible in particular to extract compounds (e.g. aromatics) from the liquid to be separated 2 by counter-currentwise contacting with the separation liquid 3 (the “yield” zone), and
  • a backwash sector 8, adjacent to the extraction sector 7 and extending up to substantially the third injection point for the backwash liquid 4, makes it possible in particular to backwash undesired compounds (e.g. heavy non-aromatic compounds) contained in the extract 5 by the backwash liquid 4 in order to guarantee a high level of purity.

Specifically with reference to FIG. 1, the separation liquid exits from the column 1 while entraining advantageous compounds to be separated (e.g. aromatic compounds) to form the extract 5. The extract may also contain undesired compounds (e.g. light non-aromatic compounds, such as C6-C7 compounds) which can be separated downstream (e.g. by distillation and/or stripping). Advantageously, the extract 5 contains no (or very few) undesired compounds which are difficult to separate (e.g. heavier non-aromatic compounds, such as C8+ compounds), which are separated from the extract in the backwash sector 8. With reference to FIG. 1, the separation liquid 3 is heavier than the liquid to be separated 2 and is injected at the top of column 1, while the backwash liquid 4 is injected at the bottom of column 1. It is understood that the present invention also relates to liquid-liquid extraction columns, in which the separation liquid is lighter than the liquid to be separated 2, the injection point for the separation liquid 3 is at the bottom of column 1 and the injection point for the backwash liquid 4 is at the top of column 1.

With reference to FIG. 2, a two-pass liquid-liquid extraction column 1 comprises n perforated trays P_i, i being between 1 and n. Each perforated tray P_i is located so that the dispersed phase (i.e., the separation liquid 3 heavier than the liquid to be separated 2) flows through the holes 9 of the perforated tray P_i, the droplets of the dispersed phase recoalescing on the following perforated tray Pin to form a liquid volume preventing the passage of the continuous phase (i.e., the liquid to be separated 2 lighter than the separation liquid 3) through the perforated tray P_i+1. The liquid to be separated 2 flows counter-currentwise relative to the separation liquid 3, i.e. upwards through the central weirs 11 and the peripheral weirs 12 of cross-section S_C and S_P, respectively, and transversely in an inter-tray space 10 of height H. With reference to FIG. 2, the heavy phase is the dispersed phase and the light phase is the continuous phase. It is understood that a liquid-liquid extraction column 1 can comprise perforated trays which are adapted in order for the dispersed phase to be the light phase and the continuous phase to be the heavy phase.

According to one or more embodiments, the perforated trays P_i are one-pass (e.g. one type of weir) or two-pass (e.g. two types of weirs) or multi-pass trays.

The Applicant Company has identified that the operation of a liquid-liquid extraction column can give rise to significant variations in flow rate and in the physicochemical properties of the phases moving in the column, and that the use of trays which differ according to their position in the column can result in homogeneous efficiency of the column being guaranteed, unlike the prior art.

According to the invention, with reference to FIG. 3, a liquid-liquid extraction column 1 is also defined by:

• • at least one extraction zone Z_i and preferably a plurality of extraction zones Z_i defining the extraction sector 7, i.e. the extraction zone(s) Z_i are included between the column top zone Z₁ comprising the second injection point for the second phase 3, and the feed zone Z_x comprising the first injection point for the first phase 2, x being greater than or equal to 1, preferably x being greater than 1; and
  • at least one backwash zone defining the backwash sector 8, i.e. the backwash zone(s) is/are included between the zone Z_x+1 and the column bottom zone Zn comprising the third injection point for the backwash liquid 4, n being greater than x.

According to the invention, each extraction and backwash zone comprises at least two trays, each extraction and backwash zone defining the structural characteristics of the inter-tray spaces present in said extraction and backwash zones. Thus, according to the invention, the trays P_i of one and the same extraction or backwash zone exhibit substantially the same inter-tray space 10 height H.

According to one or more embodiments, with reference to FIG. 3, the at least one backwash zone is a plurality of zones, said plurality of zones starting from the zone Z_x+1 to the column bottom zone Z_n.

According to one or more embodiments, with reference to FIG. 3, the at least one backwash zone is a plurality of zones subdivided into:

• • a plurality of zones Z_j included between the zone Z_x+1 and a zone Z_y, y being greater than x+1; and
  • a plurality of zones Z_k included between the zone Z_y+1 and the column bottom zone Z_n.

Advantageously, the number of zones Z_i, Z_j and Z_k can be defined relative to the flow rate variability and the physicochemical properties of the phase passing through said zones Z_i, Z_j and Z_k.

According to one or more embodiments, the total number n of zones is between 2 and 30, preferably between 3 and 30, very preferably between 4 and 24, such as between 4 and 18, in particular between 4 and 8.

In the present description, i, j, k, x, y and n are natural integers.

The number of extraction zones Z_i can be defined relative to the phase which exhibits the most flow rate variability in the column. According to one or more embodiments, the number of zones Z_i (number of zones Z₁ to Z_x) is between 1 and 10, preferably between 2 and 10, very preferably between 2 and 6, such as between 2 and 4.

The number of backwash zones can be defined relative to the phase which exhibits the most flow rate variability in the column. According to one or more embodiments, the number of backwash zones (number of zones Z_x+1 to Z_n) is between 1 and 10, preferably between 1 and 6, very preferably between 1 and 4. According to one or more embodiments, the number of backwash zones (number of zones Z_x+1 to Z_n) is greater than or equal to 2.

The number of zones Z_j can be defined relative to the phase which exhibits the most flow rate variability in the column. According to one or more embodiments, the number of zones Z_j (number of zones Z_x+1 to Z_y) is between 2 and 10, preferably between 2 and 6, very preferably between 2 and 4.

The number of zones Z_k can be defined relative to the phase which exhibits the most flow rate variability in the column. According to one or more embodiments, the number of zones Z_k (number of zones Z_y+1 to Z_n) is between 2 and 10, preferably between 2 and 6, very preferably between 2 and 4.

According to one or more embodiments, the number of trays per zone Z_i, Z_j and Z_k can be determined by the number of actual stages required for the separation divided by the number of zones Z_i, Z_j and Z_k.

Control of the Flow Rate Variation of the Continuous Phase by Optimized Design of the Inter-Tray Space

Advantageously, the liquid-liquid extraction column 1 according to the invention comprises inter-tray spaces 10 having variable height H so that the transverse velocity (orthogonal to the central axis Z of the column) of the continuous phase remains substantially constant in the column. This is because, due to the fluctuation in the flow rate of the continuous phase during the passage through the column, the variation in the height H of the inter-tray spaces 10 makes possible a more homogeneous distribution of the continuous phase in the inter-tray space 10, preventing in particular recirculations and dead volumes, while limiting the distortion of the flow of the dispersed phase. This solution additionally makes it possible to reduce the axial mixing of the continuous phase and of the dispersed phase.

Specifically, in order to retain a substantially constant transverse velocity of the continuous phase, the liquid-liquid extraction column 1 according to the invention is divided into:

• • x extraction zones Z_i, and
  • n-x backwash zones.

According to one or more embodiments, the backwash zones are divided into:

• • Y zones Z_j located starting from the zone Z_x+1 adjacent to the feed zone Z_x up to a zone Z_y, for example where the height ratio between two consecutive zones H_j/H_j+1 remains less than 1, and
  • N zones Z_k, including the zones Z_y+1 to Z_n.

According to the invention, when x is equal to 1, the height H of the inter-tray spaces 10 of the at least one backwash zone (e.g. the zone Z₂) is less than the height H of the inter-tray spaces 10 of the zone Z₁. According to one or more embodiments, when x is equal to 1, the ratio of the height H of an inter-tray space 10 of the at least one backwash zone (e.g. the zone Z₂) to the height H of the inter-tray space 10 of the zone Z₁ is between 0.20 and 0.95, preferably between 0.40 and 0.90, very preferably between 0.75 and 0.85.

According to the invention, when x is greater than 1, in the extraction zones Z_i where i varies from 1 to x (in the extraction sector 7), the height H of the inter-tray spaces 10 increases when the value i increases. According to one or more embodiments, in the zones Z_i where i varies from 1 to x, the ratio of the height H of an inter-tray space 10 of a zone Z_i to the height H of an inter-tray space 10 of a zone Z_i+1 is between 0.20 and 0.95, preferably between 0.40 and 0.90, very preferably between 0.75 and 0.85.

According to one or more embodiments, the at least one backwash zone comprises a plurality of zones, i.e. from the zone Z_x+1 to the column bottom zone Z_n, and the height H of an inter-tray space 10 increases from the zone Z_x+1 to the column bottom zone Z_n.

According to one or more embodiments, the at least one backwash zone comprises a plurality of zones, i.e. from the zone Z_x+1 to the column bottom zone Z_n, and the height H of an inter-tray space 10 is constant from the zone Z_x+1 to the column bottom zone Z_n.

According to one or more embodiments, the at least one backwash zone comprises a plurality of zones, i.e. from the zone Z_x+1 to the column bottom zone Z_n, and the height H of an inter-tray space 10 decreases from the zone Z_x+1 to the column bottom zone Z_n.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y (in the backwash zone 8), the height H of the inter-tray spaces 10 increases when the value j increases. According to one or more embodiments, in the zones Z_j where j varies from x+1 to y, the ratio of the height H of an inter-tray space 10 of a zone Z_j to the height H of an inter-tray space 10 of a zone Z_j+1 is between 0.20 and 0.95, preferably between 0.40 and 0.90, very preferably between 0.75 and 0.85.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y (in the backwash zone 8), the height H of the inter-tray spaces 10 is constant.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y (in the backwash zone 8), the height H of the inter-tray spaces 10 decreases when the value j increases. According to one or more embodiments, in the zones Z_j where j varies from x+1 to y, the ratio of the height H of an inter-tray space 10 of a zone Z_j to the height H of an inter-tray space 10 of a zone Z_j+1 is between 1.10 and 2.0, preferably between 1.20 and 1.60, very preferably between 1.25 and 1.50.

According to one or more embodiments, in the zones Z_k where k varies from y+1 to n (in the backwash sector 8), the height H of the inter-tray spaces 10 increases when the value k increases. According to one or more embodiments, in the zones Z_k where k varies from y+1 to n, the ratio of the height H of an inter-tray space 10 of a zone Z_k to the height H of an inter-tray space 10 of a zone Z_k+1 is between 0.20 and 0.95, preferably between 0.40 and 0.90, very preferably between 0.75 and 0.85.

According to one or more embodiments, in the zones Z_k where k varies from y+1 to n (in the backwash zone 8), the height H of the inter-tray spaces 10 is constant.

According to one or more embodiments, in the zones Z_k where k varies from y+1 to n (in the backwash sector 8), the height H of the inter-tray spaces 10 decreases when the value k increases. According to one or more embodiments, in the zones Z_k where k varies from y+1 to n, the ratio of the height H of an inter-tray space 10 of a zone Z_k to the height H of an inter-tray space 10 of a zone Z_k+1 is between 1.10 and 2.0, preferably between 1.20 and 1.60, very preferably between 1.25 and 1.50.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y, the height H of the inter-tray spaces 10 decreases when the value j increases; and, in the zones Z_k where k varies from y+1 to n, the height H of the inter-tray spaces 10 increases when the value k increases.

According to one or more embodiments, in the zones Z_j where j varies from x+1 to y, the height H of the inter-tray spaces 10 increases when the value j increases; and, in the zones Z_k where k varies from y+1 to n, the height H of the inter-tray spaces 10 decreases when the value k increases.

According to one or more embodiments, the height H of the inter-tray spaces 10 of the backwash zone Z_x+1 is greater than, equal to or less than the height H of the inter-tray spaces 10 of the extraction zone Z_x. According to one or more embodiments, the height H of the inter-tray spaces 10 of the backwash zone Z_x+1 is less than the height H of the inter-tray spaces 10 of the extraction zone Z_x. According to one or more embodiments, the ratio of the height H of the inter-tray space 10 of the zone Z_x+1 to the height H of the inter-tray space 10 of the zone Z_x is between 0.20 and 0.95, preferably between 0.40 and 0.90, very preferably between 0.75 and 0.85.

According to one or more embodiments, the height H of each inter-tray space 10 is between 0.2 m and 1.2 m, preferably between 0.3 m and 0.7 m, very preferably between 0.3 m and 0.5 m.

EXAMPLES

Example 1

Liquid-Liquid Extraction Column Having a Variable Inter-Tray Space

This example is targeted at describing the effect on the adjustment of the inter-tray space on the uniformity in the velocities of the continuous phase at this level.

The column exhibits a diameter of 4.9 m and comprises a succession of 118 perforated trays. The feedstock is injected at intermediate tray No. 71. The heavy solvent is injected at the top of the column at tray 1. The backwash solvent is injected at the bottom of the column at tray 118.

Three zones are defined for adjusting the inter-tray space to the variations in flow rate of the continuous phase along the column:

• • the first zone Z₁ is between trays 1 to 48: the inter-tray space is of height H1 of 0.37 m, the remainder of the geometry being unchanged;
  • the second zone Z₂ is between trays 49 to 71: the inter-tray space is increased to a height H2 of 0.44 m, relative to the increase in flow rate of the continuous phase, the zones Z₁ and Z₂ corresponding to the extraction sector 7; and
  • the third zone Z₃ is between trays 72 to 118: this zone corresponds to the backwash sector 8, the inter-tray space being of height H3 of 0.30 m.

In the extraction section 7 included between the top tray x=1 and the feed tray x=71, the height H of the inter-tray space 10 of the zone Z₁ is less than the height H of an inter-tray space 10 of the zone Z₂: the ratio of the height H of the inter-tray space 10 of the zone Z₁ to the height H of the inter-tray space 10 of the zone Z₂ is equal to 0.84.

FIG. 4 illustrates the technical effect of this adjustment: it makes it possible to guarantee uniformity of hydraulic operation along the column: the velocity of the inter-tray continuous phase is at every point in an optimum range. Such a solution makes it possible to guarantee unvarying performance qualities whatever the variations in flow rate of the continuous phase along the column, while guaranteeing an optimized column height.

Example 2

Liquid-Liquid Extraction Column Having a Constant Inter-Tray Space

The column exhibits a diameter of 4.9 m and a height of 42 m and is composed of a succession of 118 perforated trays. The feedstock is injected at intermediate tray No. 71. The heavy solvent is injected at the top of the column at tray 1. The backwash solvent is injected at the bottom of the column at tray 118.

No adjustment is employed: the inter-tray space is constant (H=0.3 m) and the characteristics of the trays are identical in every respect.

FIG. 5 illustrates that, without adjustment of the inter-tray space, the transverse velocity of the continuous phase can exceed the target maximum values and thus damage the effectiveness of trays 13 to 71, beyond which target maximum values the transverse velocity perturbs in particular the flow of the dispersed phase and entrains droplets of dispersed phase.

In order to remove the difficulty of transverse velocity exceeding the target maximum values, the height of the inter-tray space is increased (H of 0.44 m) at every point of the column: such a solution is illustrated in FIG. 6; it results in an increase in the column height of 25%.

Claims

1. Liquid-liquid extraction column (1) comprising the following elements: a first injection point for a first phase (2) located at an intermediate position between the top and the bottom of the column (1);a second injection point for a second phase (3) and a third injection point for a backwash liquid (4), one being located at the top of the column (1) and the other being located at the bottom of the column (1);a first withdrawal point for an extract (5) and a second withdrawal point for a raffinate (6), one being located at the bottom of the column (1) and the other being located at the top of the column (1);a plurality of trays (Pi) located in the column (1) and defining n zones, each zone comprising at least two trays (Pi), n being between 2 and 30;in which the n zones comprise:at least one extraction zone Zi included between a zone Z1 comprising the second injection point for the second phase (3), and a feed zone Zx comprising the first injection point for the first phase (2), x being greater than or equal to 1; andat least one backwash zone included between a zone Zx+1 and a zone Zn comprising the third injection point for the backwash liquid (4), n being greater than x;

2. Liquid-liquid extraction column (1) according to claim 1, in which n is between 3 and 30 and x is greater than 1.

3. Liquid-liquid extraction column (1) according to claim 1, in which, in the extraction zones Zi where i varies from 1 to x, the ratio of the height H of an inter-tray space (10) of a zone Zi to the height H of an inter-tray space (10) of a zone Zi+1 is between 0.20 and 0.95.

4. Liquid-liquid extraction column (1) according to claim 1, in which, in the extraction zones Zi where i varies from 1 to x, the ratio of the height H of an inter-tray space (10) of a zone Zi to the height H of an inter-tray space (10) of a zone Zi+1 is between 0.40 and 0.90.

5. Liquid-liquid extraction column (1) according to claim 1, in which, when x is equal to 1, the ratio of the height H of an inter-tray space (10) of the at least one backwash zone to the height H of the inter-tray space (10) of the zone Z1 is between 0.20 and 0.95.

6. Liquid-liquid extraction column (1) according to claim 1, in which the at least one backwash zone is a plurality of zones, from a zone Zx+1 to the zone Zn, and in which the height H of the inter-tray spaces (10) increases, is constant, or decreases from the zone Zx+1 to the zone Zn.

7. Liquid-liquid extraction column (1) according to claim 1, in which the at least one backwash zone is a plurality of zones subdivided into: a plurality of zones Zj included between the zone Zx+1 and a zone Zy, y being greater than x+1; anda plurality of zones Zk included between the zone Zy+1 and the zone Zn, and in which:in the zones Zj where j varies from x+1 to y, the height H of the inter-tray spaces (10) increases, is constant, or decreases when the value j increases; and/orin the zones Zk where k varies from y+1 to n, the height H of the inter-tray spaces (10) increases, is constant, or decreases when the value k increases.

8. Liquid-liquid extraction column (1) according to claim 7, in which, in the zones Zj where j varies from x+1 to y, the ratio of the height H of the inter-tray spaces (10) of a zone Zj to the height H of the inter-tray spaces (10) of a zone Zj+1 is between 0.20 and 0.95.

9. Liquid-liquid extraction column (1) according to claim 7, in which, in the zones Zj where j varies from x+1 to y, the ratio of the height H of the inter-tray spaces (10) of a zone Zj to the height H of the inter-tray spaces (10) of a zone Zj+1 is between 1.10 and 2.0.

10. Liquid-liquid extraction column (1) according to claim 7, in which, in the zones Zk where k varies from y+1 to n, the ratio of the height H of the inter-tray spaces (10) of a zone Zk to the height H of the inter-tray spaces (10) of a zone Zk+1 is between 0.20 and 0.95.

11. Liquid-liquid extraction column (1) according to claim 7, in which, in the zones Zk where k varies from y+1 to n, the ratio of the height H of the inter-tray spaces (10) of a zone Zk to the height H of the inter-tray spaces (10) of a zone Zk+1 is between 1.10 and 2.0.

12. Liquid-liquid extraction column (1) according to claim 1, in which the number of zones Zi is between 2 and 10 and/or the number of backwash zones is between 1 and 10.

13. Liquid-liquid extraction column (1) according to any one of Claims

7. claim 7, in which the number of zones Zj is between 2 and 10 and/or the number of zones Zk is between 2 and 10.

14. Liquid-liquid extraction column (1) according to claim 1, in which the height H of the inter-tray spaces (10) of the backwash zone Zx+1 is less than, equal to or greater than the height H of the inter-tray spaces (10) of the extraction zone Zx.

15. Liquid-liquid extraction column (1) according to Claim 1, in which the height H of each inter-tray space (10) is between 0.2 m and 1.2 m.