Claims
- 1. A process for the production of an aqueous coating composition which is crosslinkable at room temperature, comprising the steps of (i) applying a layer of an aqueous coating composition comprising:
- A) one or more resins having amino-reactive groups;
- B) one or more polyamine curing agents;
- C) one or more aminourethanes comprising reaction products of
- C1) oligomeric or polymeric compounds which contain at least one terminal 2-oxo-1,3-dioxolane groups (cyclic carbonate groups) said oligomeric or polymeric compounds being prepared by reaction of carbon dioxide and polyglycidyl ethers of compounds selected from the group consisting of polyhydric alcohols, phenols, hydrogenation products of said phenols and novolaks, whereby the molar mass of said polyglycidyl ether, divided by its number of epoxy groups, is between 100 and 2000 g/mol, and
- C2) amines containing at least one primary amino group,
- the ratio of numbers of functional groups in C1) and C2) being from 1:1 to 1:10; and
- D) emulsifier and optionally one or more of pigments, fillers, one or more organic solvents or water to a substrate, and
- (ii) curing the coating layer,
- wherein the reaction between said aminourethane C) and said polyamine curing agent B) is selected from the group consisting of
- (a) mixing the aminourethane C) with the polyamine curing agent B), and then reacting this mixture with an emulsifier D);
- (b) reacting the aminourethane C) with an emulsifier D), and then adding the amine curing agent B);
- (c) reacting the amine curing agent B) with an emulsifier D), and then adding the aminourethane C);
- (d) reacting a mixture of amines or amine curing agents B) with a substoichiometric amount of compounds containing 2-oxo-1,3-dioxolane groups to form an intermediate, and then reacting this intermediate with a substoichiometric amount of emulsifier D) and
- (e) reacting a mixture of amines or amine curing agents B) with a substoichiometric amount of emulsifier D) to form an intermediate, and then reacting this intermediate with a substoichiometric amount of compounds containing 2-oxo-1,3-dioxolane groups;
- wherein the emulsifier D) is an adduct of polyepoxides and polyalkylene ether polyols in a ratio of numbers of functional groups of from 2:0.1 to 2:1.5.
- 2. The process as claimed in claim 1 wherein the polyamine curing agents B) and aminourethane C) are present in the coating layer as a mixture.
- 3. The process as claimed in claim 1, wherein a chemical compound is formed from a reaction between the aminourethane C) and the polyamine curing agent B).
- 4. The process as claimed in claim 1, wherein the ratio of numbers of functional groups of polyamine curing agent B) aminourethane C) was from 5:95 to 95:5.
- 5. The process as claimed in claim 1 wherein the coating composition comprises one or more water-dilutable or water-soluble polyurethane resins having a number-average molar mass (M.sub.n) of 500-500,000 g/mol.
- 6. The process as claimed in claim 1, wherein the coating composition comprises:
- A) one or more water-soluble or water-dilutable epoxy resins;
- B) one or more water-soluble or water-dilutable polyamine curing agents;
- C) one or more aminourethanes comprising reaction products of
- C1) oligomeric or polymeric compounds containing at least one terminal 2-oxo-1,3-dioxolane group (cyclic carbonate groups), and
- C2) compounds containing at least one primary amino group, the ratio of numbers of functional groups in C1) and C2) being from 1:1 to 1:10; and
- D) water.
- 7. The process as claimed in claim 1, wherein said polyamine curing agent B) and aminourethane C) are present in a ratio of numbers of functional groups of polyamine curing agents:aminourethane of from 20:80 to 80:20.
- 8. The process as claimed in claim 1 wherein compound C1) have two or more terminal 2-oxo-1,3-dioxolane groups.
- 9. The process as claimed in claim 1, wherein compound C2) has two or more primary amino groups.
- 10. The process as claimed in claim 1 wherein compound C2) further includes secondary and tertiary amino groups.
- 11. The process as claimed in claim 1 wherein the ratio of numbers of functional groups in C1) and C2) is from 1:1.05 to 1:5.
- 12. The process as claimed in claim 1, wherein the ratio of numbers of functional groups in C1) and C2) is from 1:1.1 to 1:2.
- 13. The process as claimed in claim 1, wherein each of said one or more aminourethanes contains one or more free primary amino groups.
- 14. The process as claimed in claim 1, wherein said reaction between said aminourethane C) and said polyamine curing agent B) comprises the steps of:
- 1) mixing said aminourethane C) and said polyamine curing agent B) to produce a mixture, and;
- 2) reacting said mixture with said emulsifier.
- 15. The process as claimed in claim 1, wherein said reaction between said aminourethane C) and said polyamine curing agent B) comprises the steps of:
- 1) reacting said aminourethane C) with said emulsifier to produce a reaction product; and
- 2) mixing said polyamine curing agent with said reaction product.
- 16. The process as claimed in claim 1, wherein said reaction between said aminourethane C) and said polyamine curing agent B) comprises the steps of:
- 1) reacting said polyamine curing agent B) with said emulsifier to produce an amine reaction product; and
- 2) mixing said aminourethane C) with said amine reaction product.
Priority Claims (1)
Number |
Date |
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Kind |
43 44 510.1 |
Dec 1993 |
DEX |
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Parent Case Info
This application is a continuation of 08/457,111, filed Jun. 1, 1995 now U.S. Pat. No. 5,677,006; which is a divisional of Ser. No. 08/358,744, filed Dec. 19, 1994, now abandoned.
US Referenced Citations (13)
Foreign Referenced Citations (3)
Number |
Date |
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2073814 |
Jan 1993 |
CAX |
43 10 198 |
Oct 1994 |
DEX |
8403701 |
Sep 1984 |
WOX |
Divisions (1)
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Number |
Date |
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Parent |
358744 |
Dec 1994 |
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Continuations (1)
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Number |
Date |
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Parent |
457111 |
Jun 1995 |
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