This disclosure generally relates to the field of batteries and more particularly to lithium-ion batteries.
Electrochemical cells in the form of batteries are widely used to power electronic devices. In certain applications, small size, high energy density, and reliable power supply capability are highly desirable. One such application is in medical devices. It can also be highly desirable to include rechargeable lithium-ion batteries in devices, such that the batteries do not have to be removed from and replaced within the device. Furthermore, such power supplies should be reliably sealed to prevent leakage of electrochemical cell material. Sealing of the power supplies can include welding or other processes that can damage the components enclosed within the housing of the power supply.
Some aspects, in accordance with principles of the present disclosure, relate to a lithium-ion battery including an electrode assembly, a battery case, and an insulator. The electrode assembly includes a plurality of stacked electrodes. The battery case includes a cover and a housing. The housing includes a bottom, a perimeter side, and an open top. The cover is configured to extend across the open top. The cover and the housing form an interior enclosure, or cavity, to house the electrode assembly with the cover and the housing sealingly coupled at the lip. The insulator includes a body and a profiled portion. The body being generally planar and the profiled portion extending from the body at an angle. The body is disposed between the electrode assembly and the cover of the battery case. The profiled portion extends between the electrode assembly and the lip of the housing. The insulator is to provide a barrier between the electrode assembly and the sealed lip
Other aspects, in accordance with principles of the present disclosure, relate to a lithium-ion battery including an electrode assembly, a battery case, and an insulator. The electrode assembly includes a plurality of electrodes including positive and negative electrodes alternatingly arranged one atop another in a stack. Each of the plurality of electrodes is generally planar and encased in a separator. The battery case includes a cover and a housing. The housing includes a bottom, a perimeter side terminating at a lip, and an open top. The cover to extend across the open top and engage with the lip. The cover and the housing form an enclosure to house the electrode assembly. The insulator includes a body and a profiled portion. The body being generally planar and the profiled portion extending from the body at an angle. The insulator is assembled within the enclosure of the battery case with the body disposed between the electrode assembly and the cover and the profiled portion extending between the electrode assembly and the perimeter side. The insulator provides a thermal barrier between the electrode assembly and the sealed lip.
Other aspects, in accordance with principles of the present disclosure, relate to a method of assembling a lithium-ion battery including inserting an electrode assembly into an opening of a battery case, the electrode assembly comprising a plurality of stacked plate electrodes. The method also including inserting an insulator over the electrode assembly, the insulator including a body and a profiled portion extending from the body, the body positioned over a top of the electrode assembly, the profiled portion to extend between a perimeter of the electrode assembly and a side of the battery case. The method also including positioning a cover of the battery case over the opening of the battery case, and hermetically sealing the cover to a housing of the battery case to enclose the electrode assembly. The insulator provides a barrier between the electrode assembly during the hermetic sealing of the cover to the housing.
The details of one or more aspects of the disclosure are set forth in the accompanying drawings and the description below. Other features, objects, and advantages of the techniques described in this disclosure will be apparent from the description and drawings, and from the claims.
Power supplies, such as lithium-ion batteries, can include one or more positive electrodes, one or more negative electrodes, and an electrolyte provided within a battery case. Separators made from a porous polymer or other suitable material can be provided intermediate or between the positive and negative electrodes to prevent direct contact between adjacent electrodes. When assembled, the separators can interfere with the sealing of the battery case by being inadvertently positioned between a cover and a housing of the battery case during assembly. The separator can thus impede full contact and sealing between the cover and the housing and cause defects in the seal or weld of the battery case and/or cause damage to (e.g., tear) the separator which in turn can cause damage to the electrodes. Even when fully disposed within the interior cavity of the battery case, the thermal damage to the electrode assembly can occur during a welding process used to seal the cover and housing together. Thermal damage to the electrode assembly (or other components) can occur due to being disposed against or closely proximal to the battery case adjacent the weld location, or weld zone, that is heated during welding. Aspects of the present disclosure can provide protection to the electrode assembly during the welding process employed to hermetically seal the cover to the case and form the battery case.
The battery 100 will be described further with additional reference to the cross-sectional view of the example assembled battery 100 illustrated in
In one example, the housing 110 can include an inner shell, or liner, 110a and an outer shell 110b (see, e.g.,
With continued reference to
In some examples, the welding process is performed by laser welding, however, other methods of attachment are also acceptable. For example, resistance welding, brazing, soldering and other techniques can be employed to couple the cover 108 to the housing 110. The term welding can encompass many types of attachment such as resistance welding and brazing. It is also contemplated that many other types of attachment could be utilized without departing from the spirit of the disclosure. The insulator 106 can provide protection to the electrode assembly 102 and other components during the welding process and reduce the likelihood of a portion of radiation emitted from the laser beam from penetrating the battery case 104 and damaging radiation and heat sensitive components, such as the electrode assembly 102, housed inside, as discussed further below.
The cover 108 and the housing 110 of the battery case 104 can be made of a biologically compatible material such as medical grade titanium, aluminum, or stainless steel, for example. The battery case 104 material is compatible with the chemistry of the cell electrolyte and other materials housed within the battery case 104 in order to prevent corrosion. The battery case 104 can be manufactured from a variety of process including, for example, machining, casting, stamping, milling, three-dimensional (3D) printing, thermoforming, injection molding, vacuum molding, or other suitable process.
With additional reference to
In one example, the each of the electrodes 132a-x can be generally planar and can be assembled, or stacked, to form a generally planar electrode assembly 102. Each electrode 132 has a generally flat body (e.g., having minimal thickness) and includes a current collector 138, indicated only on the bottom electrode 132a illustrated in
Each electrode 132 can be encased in a separator 140 with the current collector 138 extending through and outside of the separator 140 to electrically connect. The current collector 138 (e.g., aluminum such as an aluminum foil) can have an active material provided thereon (e.g., LiCoO2). The separator 140 can extend beyond an outer edge 142 of the electrode 132 to sealingly encase the electrode 132. The separator 140 can electrically insulate the adjacently disposed anode electrodes and cathode electrodes. The separator 140 is preferably formed of material that is wettable by cell electrolyte housed or contained within the battery case 104 and sufficiently porous to allow the electrolyte to flow through the material and maintain physical and chemical integrity within the electrode during operation. The separator 140 is formed of a flexible material and can have a thickness of 12 micrometers, for example. Other suitable thicknesses are also acceptable. Examples of suitable materials forming the separator 140 include, but are not limited to, polyethylenetetrafluoroethylene, ceramics, non-woven glass, glass fiber material, polypropylene, and polyethylene.
With continued reference to
The profiled portion 152 can be oriented at an angle downward from the cover 108 (e.g., away from the open second side 122 and toward the first side 118) between the lip 124 and the electrode assembly 102. More particularly, the insulator 106 is assembled with a first surface 154 extending over and contacting the top surface of a top electrode 132x and a second surface 156 opposite the first surface 154 disposed to face and be positioned against the inner surface 128 of the cover 108. The insulator 106 can engage with and reposition (e.g., push) the separator 140 covering the electrodes 132 downward and away from the lip 124 (e.g., the weld zone) such that the separator 140 does not interfere with the welding process sealing the cover 108 with the housing 110. The downward orientation of the profiled portion 152 can engage with and reposition, the separator 140 downward and away from the lip 124 as the insulator 106 is positioned over and a downward force is applied onto the insulator 106 during assembly. The insulator 106 can maximize a distance between the outer edge 142 of the separator 140 encased electrode 132x and the cover 108 and the perimeter side 120 of the housing 110 disposed adjacent the lip 124 within the interior cavity 112 to prevent mechanical and thermal damage during the assembly and sealing of the cover 108 to the housing 110.
The insulator 106 is formed of a sufficiently flexible material that can effectively create a spring-like force against the electrode assembly 102 when force is applied to the insulator 106, such as by the cover 108. The insulator 106 is capable of applying sufficient force against the separator 140 at the outer edge 142 of at least the top electrode 132x to position, or reposition, the separator 140 a distance from the lip 124. The insulator 106 can position the separator 140 at a suitable distance away from the weld to prevent thermal damage to the separation material and/or prevent the separator 140 from impeding full contact and sealing of the cover 108 and the housing 110. In one example, the insulator 106 provides a clearance distance of at least 760 micrometers from the weld to the nearest portion of the insulator 106. Other suitable distances that provide a weld zone suitable to prevent damage to the components are also acceptable.
In one example, the insulator 106 can be formed of Ethylene tetrafluoroethylene (ETFE). ETFE has a relatively high melting temperature, and chemical, electrical and high-energy radiation resistance properties. The insulator 106 can also be formed of polypropylene, polyethylene, or other suitable insulative and corrosion resistant material. The insulator 106 has a thickness suitable to withstand weld temperatures exposed to during the welding process of hermetically sealing the cover 108 to the housing 110 and to transfer and apply suitable force onto the separator 140 to cause movement of the separator. In one example, the insulator 106 has a material thickness that is approximately ten times the thickness of the material forming the separator 140. The insulator 106 can have a thickness of approximately 127 micrometers to approximately 254 micrometers. Other suitable thicknesses are also acceptable and the examples provided are not intended to be limiting.
The insulator 206 is conformable to extend between the electrode assembly 102 the housing 104 when the battery 100 is assembled. The insulator 206 has a first surface 254, a second surface 256, and a terminal edge 258. The insulator 206 includes a body 250 and a profiled portion 252 that extends at a right angle, or substantially right angle, from the body 250. The body 250 of the insulator 206 can extend between the top surface of the top electrode 132x and the inner surface 128 of the cover 108 of the battery case 104. The profiled portion 252 can be positioned over the top and edge of the electrode assembly 102. The profiled portion 252 can be disposed along the perimeter side 120 and adjacent the lip 124. When assembled and fitted within the battery case 104, the profiled portion 252 is disposed to extend away from the cover 108 toward the first side 118. The profiled portion 252 can extend a distance less than “d” of the housing 110.
The profiled portion 252 can be oriented at an angle downward from the cover 108 (e.g., away from the open second side 122 and toward the first side 118) between the lip 124 and the electrode assembly 102. More particularly, the insulator 206 is assembled with a first surface 254 extending over and contacting the top surface of a top electrode 132x and a second surface 256 opposite the first surface 254 disposed to face and be positioned against the inner surface 228 of the cover 108. The insulator 206 can engage with and reposition (e.g., push) the separator 140 covering the electrodes 132 downward and away from the lip 124 such that the separator 140 does not interfere with the welding process sealing the cover 108 with the housing 110. The downward orientation of the profiled portion 252 can engage with and reposition, the separator 140 downward and away from the lip 124 as the insulator 206 is positioned over and a downward force is applied onto the insulator 206 during assembly. The insulator 206 can maximize a distance between the outer edge 142 of the separator 140 encased electrode 132x and the cover 108 and the perimeter side 120 of the housing 110 disposed adjacent the lip 124 within the interior cavity 112 to prevent mechanical and thermal damage during the assembly and sealing of the cover 108 to the housing 110.
The insulator 206 is formed of a sufficiently flexible material that can effectively create a spring-like force against the electrode assembly 102 when force is applied to the insulator 206, such as by the cover 108. The insulator 206 is capable of applying force sufficient force against the separator 140 at the outer edge 142 of at least the top electrode 132x to position, or reposition, the separator 140 to increase a distance from the lip 124. from the weld and preventing thermal damage to the separation 140 and/or impede full contact and sealing between the cover 108 and the housing 110. The insulator 206 has a thickness suitable to withstand weld temperatures exposed to during the welding process of hermetically sealing the cover 108 to the housing 110 and to transfer and apply suitable force onto the separator 140 to cause movement of the separator. In one example, the insulator 206 has a material thickness that is approximately ten times the thickness of the material forming the separator 140. In one example, the profiled portion 252 can be included to be disposed along the interior of the entire perimeter side 120 of the housing 110. In another example, the insulator 206 includes the profiled portion 252 suitable to be disposed along the interior of the perimeter side 120 where the electrode assembly 102 is positioned adjacent to the perimeter side 120 and is not included along sections where the electrode assembly is spaced away from the perimeter side 120, such as at the current collectors 138.
The lithium-ion batteries 100, 200 of the present disclosure can be assembled by inserting the electrode assembly 102 into the housing 110 through the opening at the second side 122 of the battery case 104. The insulator 106, 206 can be assembled within the battery case 104 to extend over the electrode assembly 102. The insulator 106, 206 can be inserted into the battery case 104 in the same manner. The body 150, 250 of the insulator 106, 206 is positioned over the top of the electrode assembly 102 and the profiled portion 152, 252 is positioned to extend between a perimeter, or stack side, of the electrode assembly 102 and the interior surface 114 of the battery case 104. The cover 108 can then be assembled over the insulator 106, 206. The cover 108 is positioned across the open second side 122 over the insulator 106, 206. The cover 108 and the housing 110 can then be hermetically sealed together with the insulator 106, 206 protectively extending between the electrode assembly 102 and the battery case 104 adjacent the seal. The insulator 106, 206 forces the separator 140 extending around the top electrode 132x of the plurality of stacked plate electrodes 132a-x into the interior cavity 112 and away from the lip 124 of the housing 110 by the profiled portion 152, 252 engaging the separator 140 and exerting a downward force on the insulator.
It should be understood that various aspects disclosed herein may be combined in different combinations than the combinations specifically presented in the description and accompanying drawings. It should also be understood that, depending on the example, certain acts or events of any of the processes or methods described herein may be performed in a different sequence, may be added, merged, or left out altogether (e.g., all described acts or events may not be necessary to carry out the techniques). In addition, while certain aspects of this disclosure are described as being performed by a single module or unit for purposes of clarity, it should be understood that the techniques of this disclosure may be performed by a combination of units or modules associated with, for example, a medical device.
Although the present disclosure has been described with reference to preferred embodiments, workers skilled in the art will recognize that changes can be made in form and detail without departing from the spirit and scope of the present disclosure.
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