As used herein, the term “natural gas” or “natural gas stream” shall denote any stream principally comprised of methane, which originates in major portion from a natural gas feed stream. A natural gas stream typically contains at least 85 mole percent methane, with the balance being ethane, higher hydrocarbons, nitrogen, carbon dioxide, and minor amounts of other contaminates such as, for example, mercury, hydrogen sulfide, and mercaptans. As used herein, the terms “principally,” “predominately,” “primarily,” and “in major portion,” when used to describe the presence of a particular component of a fluid stream, shall mean that the fluid stream contains at least 50 mole percent of the stated component. For example, a “predominately” methane stream, a “primarily” methane stream, a stream “principally” comprised of methane, or a stream comprised “in major portion” of methane, each denote a stream containing at least 50 mole percent methane. As used herein, the terms “upstream” and “downstream” shall be used to describe the relative positions of various components of a natural gas liquefaction plant along the main flow path of natural gas through the plant.
One of the most efficient and effective methodologies for natural gas liquefaction is a cascade-type operation in combination with expansion-type cooling. Cascaded processes utilize one or more refrigerants to transfer heat energy from the natural gas stream to the refrigerant and ultimately to the environment. In essence, the refrigeration system functions as a heat pump by removing thermal energy from the natural gas stream as the stream is progressively cooled to lower and lower temperatures. In so doing, the thermal energy removed from the natural gas stream is ultimately rejected (pumped) to the environment via energy exchange with one or more refrigerants.
In a preferred embodiment, the present invention employs a cascaded refrigerant system that cools the natural gas stream at an elevated pressure (e.g., about 650 psia), by sequentially passing the natural gas stream through an initial refrigeration cycle, an intermediate refrigeration cycle, and a final refrigeration cycle. In a preferred embodiment of the invention, the initial and intermediate refrigeration cycles are closed refrigeration cycles, while the final refrigeration cycle is an open refrigeration cycle that utilizes a portion of the feed gas as a source of refrigerant and which includes therein a multi-stage expansion cycle to further cool the feed gas and reduce its pressure to near-atmospheric pressure.
The refrigerants employed in the initial, intermediate, and final refrigeration cycles preferably have their own distinct compositions. In other words, it is preferred for pure component refrigerants, rather than mixed refrigerants, to be employed in the initial, intermediate, and final refrigeration cycles of the present invention. As used herein, the term “mixed refrigerant” denotes a refrigerant that does not contain more than 80 mole percent of any single refrigerant component. As used herein, the term “pure component refrigerant” denotes a refrigerant that is not a mixed refrigerant. Preferably, a pure component refrigerant comprises at least about 80 mole percent of a single refrigerant component, more preferably at least about 90 mole percent of a single hydrocarbon refrigerant component, and most preferably at least 95 mole percent of a single hydrocarbon refrigerant component. In the system of the present invention, it is preferred for the refrigerant having the highest boiling point to be utilized in the initial refrigeration cycle, followed by a refrigerant having an intermediate boiling point employed in the intermediate refrigeration cycle, and finally a refrigerant having the lowest boiling point is employed in the final refrigeration cycle.
In a preferred embodiment of the present invention, the initial refrigerant employed in the initial refrigeration cycle contains primarily propane, propylene, and/or carbon dioxide. More preferably, the initial refrigerant comprises predominately propane, most preferably, the initial refrigerant consists essentially of propane. The intermediate refrigerant preferably comprises predominately ethane and/or ethylene. More preferably, the intermediate refrigerant comprises predominately ethylene. Most preferably, the intermediate refrigerant consists essentially of ethylene. The final refrigerant preferably comprises predominately methane. Most preferably, the final refrigerant consists essentially of methane.
Preferably, each of the initial, intermediate, and final refrigeration cycles employs a plurality of distinct cooling steps carried out in one or more heat exchangers. In a preferred embodiment of the present invention, less than about 10 percent of the natural gas mechanical cooling duty of the initial, intermediate, and/or final refrigeration cycles is provided by core-in-kettle and/or spiral-wound heat exchangers, more preferably less than about 5 percent of the natural gas mechanical cooling duty of the initial, intermediate, and/or final refrigeration cycles is provided by core-in-kettle and/or spiral-wound heat exchangers, still more preferably less than 2 percent of the natural gas mechanical cooling duty of the initial, intermediate, and/or final refrigeration cycles is provided by core-in-kettle and/or spiral-wound heat exchangers. Most preferably, none of the natural gas-cooling heat exchangers employed in the initial, intermediate, and final refrigeration cycles are core-in-kettle heat exchangers and/or spiral-wound heat exchangers. Rather, it is preferred that at least about 90 percent of the natural gas mechanical cooling duty of the initial, intermediate, and/or final refrigeration cycles is provided by plate-fin heat exchangers, more preferably at least about 95 percent of the natural gas mechanical cooling duty of the initial, intermediate, and/or final refrigeration cycles is provided by plate-fin heat exchangers, still more preferably at least 98 percent of the natural gas mechanical cooling duty of the initial, intermediate, and/or final refrigeration cycles is provided by plate-fin heat exchangers. Most preferably, all of the natural gas-cooling heat exchangers employed in the initial, intermediate, and final refrigeration cycles are plate-fin heat exchangers. It is particularly preferred for the plate-fin heat exchangers to be brazed aluminum plate-fin heat exchangers.
As used herein, the term “natural gas mechanical cooling duty” denotes a responsibility for extracting heat from natural gas via indirect heat exchange, expressed in terms of energy per units of time (e.g., BTU/hr). As used herein, the term “core-in-kettle heat exchanger” denotes a heat exchange device comprising an outer vessel shell and an inner core disposed in the vessel shell. A core-in-kettle heat exchanger facilitates indirect heat transfer between a first fluid contained in the vessel shell and a second fluid flowing through the core while the core is at least partly submerged in the first fluid. As used here, the term “spiral-wound heat exchanger” denotes a heat exchange device comprising an outer vessel shell and an inner core of wound tubes disposed in the shell. As used herein, the term “plate-fin heat exchanger” denotes a device that defines a plurality of distinct fluid passageways separated by plates. A plate-fin heat exchanger facilitates indirect heat transfer between a first fluid flowing through a first group of fluid passageways and a second fluid flowing through a second group of fluid passageways. Heat is transferred between the first and second fluids via heat flux through the plates. Thus, plate-fin heat exchangers do not require the use of large containment vessels because the first and second fluids are contained in the fluid passageways during heat transfer. As used herein, the term “brazed aluminum plate-fin heat exchanger” denotes a plate-fin heat exchanger constructed of multiple aluminum plates brazed to one another.
In a preferred embodiment of the present invention, the natural gas stream is delivered to the initial refrigeration cycle at an elevated pressure or is compressed to an elevated pressure, that being a pressure greater than about 500 psia, preferably about 500 to about 900 psia, still more preferably about 550 to about 675 psia, still yet more preferably about 575 to about 650 psia, and most preferably about 600 psia. The stream temperature is typically near ambient to slightly above ambient. A representative temperature range being about 60° F. to about 120° F.
Generally, the natural gas feed stream will contain such quantities of C2+ components so as to result in the formation of a C2+ rich liquid in one or more of the cooling stages of the initial and/or intermediate refrigeration cycles. This liquid is removed via gas/liquid separation means, preferably one or more conventional gas/liquid separators. Generally, the sequential cooling of the natural gas in each stage of the initial and/or intermediate refrigeration cycles is controlled so as to remove as much as possible of the C2 and higher molecular weight hydrocarbons from the gas to produce a first gas stream predominating in methane and a second liquid stream containing significant amounts of ethane and heavier components. An effective number of gas/liquid separation means are located at strategic locations downstream of the cooling stages for the removal of liquids streams rich in C2+ components. The exact locations and number of gas/liquid separation means will be dependent on a number of operating parameters, such as the C2+ composition of the natural gas feed stream, the desired BTU content of the final product, the value of the C2+ components for other applications, and other factors routinely considered by those skilled in the art of LNG plant and gas plant operation. The C2 hydrocarbon stream or streams may be demethanized via a single stage flash or a fractionation column. In the former case, the methane-rich stream can be repressurized and recycled or can be used as fuel gas. In the latter case, the methane-rich stream can be directly returned at pressure to the liquefaction process. The C2+ hydrocarbon stream or streams or the demethanized C2+ hydrocarbon stream may be used as fuel or may be further processed such as by fractionation in one or more fractionation zones to produce individual streams rich in specific chemical constituents (e.g., C2, C3, C4 and C5+)
In the last cooling stage of the intermediate refrigeration cycle, the processed natural gas stream, which is predominantly methane (typically greater than 95 mole percent methane and more typically greater than 97 mole percent methane), is condensed (i.e., liquefied) in major portion, preferably in its entirety. The cooled and condensed natural gas stream exiting the intermediate refrigeration cycle is then further cooled in the final refrigeration cycle via indirect heat exchange with the final refrigerant. In a preferred embodiment of the present invention, the final refrigeration cycle is an open methane refrigeration cycle employing a predominantly-methane refrigerant that originates from the natural gas feed stream.
The liquefied gas entering the final refrigeration cycle preferably has a pressure of at least about 250 psia, more preferably at least about 400 psia, and most preferably in the range of from 500 to 800 psia. It is preferred that the expansion section of the final refrigeration cycle is operable to reduce the pressure of the liquefied gas stream by at least about 100 psi, more preferably at least about 250 psi, and most preferably at least 400 psi. The pressure reduction in the expansion section of the final refrigeration cycle is preferably accomplished via a plurality of sequential expansion steps carried out in a plurality of expansion devices. Each expansion device can be a Joule-Thomson expansion valve or a hydraulic expander. As used herein, the term “hydraulic expander” is not limited to an expander which receives and produces liquid streams but is inclusive of expanders which receive a predominantly liquid-phase stream and produce a two-phase (gas/liquid) stream. When a hydraulic expander is employed and properly operated, the greater efficiencies associated with the recovery of power, a greater reduction in stream temperature, and the production of less vapor during the expansion step will frequently be cost-effective even in light of increased capital and operating costs associated with the expander. The pressure of the liquid product entering the final refrigeration cycle is preferably reduced to near atmospheric pressure so that the final LNG product has a near-atmospheric pressure and a temperature of −240° F. to −260° F.
One embodiment of the present invention provides a final refrigeration cycle having a reduced number of process vessels compare to similar refrigeration cycles employing multi-step expansion cooling of the liquefied gas stream. In particular, in one embodiment of the present invention, the expansion section of the final refrigeration cycle employs less than three vapor/liquid separation vessels (e.g., flash drums), most preferably less than two vapor/liquid separation vessels.
The flow schematic and apparatus set forth in
To facilitate an understanding of
Referring to
Also fed to plate-fin heat exchanger 2 are the natural gas stream via conduit 100, a gaseous ethylene stream via conduit 202, and a methane-rich stream via conduit 152. These streams in flow passages 6, 8, and 4 and the propane refrigerant stream in passage 10 flow countercurrent, more preferably counterflow, to the propane stream in passage 12. Indirect heat exchange occurs between such streams. The streams respectively flowing in passages 4, 6, and 8 are produced via conduits 154, 102, and 204. The stream in conduit 204 will be referred to as a first cooled ethylene stream.
The cooled natural gas stream in conduit 102, the first cooled ethylene stream in conduit 204, and the fourth propane refrigerant stream in conduit 307 respectively flow through passages 22, 24, and 25 in brazed aluminum plate-fin heat exchanger 20 countercurrent, more preferably counterflow, to a yet to be identified refrigeration stream thereby producing a further cooled natural gas stream, a second cooled ethylene stream, and a fifth propane refrigerant stream which are produced via conduits 110, 206, and 308. The fifth propane refrigerant stream is then split via a splitting or separation means (illustrated but not numbered) into two portions, the sixth and seventh propane refrigerant streams, and respectively produced via conduits 309 and 312. The sixth propane refrigerant stream flows via conduit 309 to a pressure reduction means, illustrated as expansion valve 27. In expansion valve 27, the pressure of the liquefied propane is reduced, thereby evaporating or flashing a portion thereof and producing a intermediate-stage propane refrigeration stream. This stream then flows through conduit 310 and through core passage 26 wherein said stream flows countercurrent to the streams in passages 22, 24, and 25 and wherein indirect heat exchange occurs. The resulting stream is produced as an intermediate-stage propane recycle stream via conduit 311. This stream is returned to the intermediate-stage inlet port of propane compressor 18, again preferably after passing through a suction scrubber.
The further cooled natural gas stream and the second cooled ethylene stream are respectively routed via conduits 110 and 206 to respective passages 36 and 38 in brazed aluminum plate-fin heat exchanger 34 wherein the natural gas stream is yet further cooled. The natural gas and ethylene streams are produced from plate-fin heat exchanger 34 via conduits 112 and 208, respectively.
The seventh propane refrigerant stream in conduit 312 is connected to brazed aluminum plate-fin heat exchanger 28 wherein the stream flows via passage 29 countercurrent, more preferably counterflow, to and in indirect heat exchange with a low-stage propane refrigerant flowing via passage 30 thereby producing an eighth propane refrigerant stream via conduit 314. The eighth propane refrigerant flows via conduit 314 to a pressure reduction means, illustrated as expansion valve 32, wherein the pressure of the liquefied propane is reduced thereby evaporating or flashing a portion thereof and producing a two-phase refrigerant stream. The expanded refrigerant stream is carried to brazed aluminum plate-fin heat exchanger 34 where it is employed as a cooling agent in passage 37. A low-stage propane refrigeration stream is removed from heat exchanger 34 via conduit 318. This conduit is connected to passage 30 in heat exchanger 28 wherein said stream flows countercurrent and is in indirect heat exchange with the seventh propane refrigerant stream in passage 29 thereby producing a low-stage propane recycle stream. The low-stage propane recycle stream is then returned to the low-stage inlet port of compressor 18, preferably after flow through a suction scrubber, via conduit 320. In compressor 18, the low-stage propane recycle stream is compressed, combined with the intermediate-stage propane recycle stream, and compressed to form a compressed intermediate-stage recycle stream. This stream is then combined with the high-stage propane recycle stream to form a combined high-stage propane recycle stream which is compressed to form the compressed propane refrigerant stream produced via conduit 300.
In one embodiment of the invention, the brazed aluminum plate-fin heat exchangers 2, 20, 28, and 34 of the initial (propane) refrigeration cycle are separate heat exchangers. In another embodiment, the heat exchangers are combined into one or more exchangers. Although resulting in a more complex heat exchanger which possesses intermediate headers, combined approach can offer advantages from a lay-out and cost perspective.
In the intermediate refrigeration cycle depicted in
The cooled natural gas stream produced from the initial refrigeration cycle via conduit 112 is combined with a yet to be described methane-rich stream provided via conduit 156. This combined stream in conduit 114 and the first refrigerant ethylene stream in conduit 209 are routed to a brazed aluminum plate fin-heat exchanger 42 wherein these streams flow through core passages 44 and 46 countercurrent, more preferably counterflow, to and in indirect heat exchange with a yet to be described high-stage ethylene refrigerant stream and optionally, a low-stage ethylene refrigerant stream respectively flowing in passages 48 and 50. A cooled stream referred to herein as a second ethylene refrigerant stream is produced from passage 46 via conduit 210. This stream is then split via a splitting or separation means (illustrated but not numbered) into two portions, third and fourth ethylene refrigerant streams, and produced via conduits 212 and 218. The third ethylene refrigerant stream flows via conduit 212 to a pressure reduction means, illustrated as expansion valve 52, wherein the pressure of the liquefied ethylene is reduced thereby evaporating or flashing a portion thereof and producing a high-stage ethylene refrigeration stream. This stream then flows through conduit 214 and through core passage 48 thereby producing a high-stage ethylene recycle stream which is transported via conduit 216 to the high-stage inlet port of compressor 40.
A further cooled natural gas stream is produced from passage 44 via conduit 116 and is optionally combined with a methane-rich recycle stream delivered via conduit 158. The resulting stream is routed via conduit 120 to a passage 59 of a brazed aluminum plate-fin heat exchanger 58 wherein the stream is cooled and liquefied in major portion and the resulting stream is produced via conduit 122.
The fourth ethylene refrigerant stream is transported via conduit 218 to a passage 54 in a brazed aluminum plate-fin heat exchanger 53. The fourth ethylene refrigerant stream flows countercurrent, more preferably counterflow, to and is in indirect heat exchange with a low-stage ethylene refrigerant flowing via passage 55 in heat exchanger 53, thereby producing a fifth ethylene refrigerant stream via conduit 220. The fifth ethylene refrigerant stream flows via conduit 220 to a pressure reduction means, illustrated as expansion valve 56, wherein the pressure of the liquefied ethylene is reduced, thereby evaporating or flashing a portion thereof and producing a two-phase ethylene refrigerant stream. The resulting two-phase ethylene refrigerant stream is carried via conduit 226 to heat exchanger 58 wherein the stream is employed as a cooling agent in passage 57. A low-stage ethylene refrigeration stream is removed from heat exchanger 58 via conduit 228. Conduit 228 is connected to passage 55 in heat exchanger 53 wherein said stream flows countercurrent and is in indirect heat exchange with the fluid in passage 54 thereby producing a low-stage ethylene recycle stream. This stream is returned to the low-stage inlet port of compressor 40 via conduit 232. Optionally, and as depicted in
In one embodiment of the invention, brazed aluminum plate-fin heat exchangers 42, 53, and 58 of the intermediate refrigeration cycle are separate heat exchangers. In another embodiment, the heat exchangers are combined into a single exchanger.
The liquefied natural gas stream produced from plate-fin heat exchanger 58 via conduit 122 is generally at a temperature of about −125° F. and a pressure of about 600 psi. The liquefied stream in conduit 122 is introduced into the final refrigeration cycle where it undergoes cooling by indirect heat exchange with a methane refrigerant and by expansion. The stream in conduit 122 is initially cooled in a main methane economizer 74 via indirect heat exchange with methane refrigerant streams in passages 82, 95, and 96. In a preferred embodiment of the present invention, the methane refrigerant employed in the final refrigeration cycle is derived from the processed natural gas stream, thereby making the final refrigeration cycle an open methane refrigeration cycle. Main methane economizer 74 is preferably a plate-fin heat exchanger, most preferably a brazed aluminum plate-fin heat exchanger. The liquefied natural gas stream introduced into main methane economizer 74 via conduit 122 is cooled in passage 76 and then exits main methane economizer 74 via conduit 124. The cooled stream in conduit 124 is subsequently divided into a first refrigerant portion carried in conduit 125 and a first product portion carried in conduit 126. The first refrigerant portion in conduit 125 is transported to an expansion means (illustrated as expansion valve 78), wherein the stream is reduced in pressure to thereby produce a first expanded refrigerant portion in conduit 127. The first expanded refrigerant portion in conduit 127 is then introduced into passage 82 of main methane economizer 74 wherein it is employed as a refrigerant to cool the natural gas stream in passage 76. The warmed first refrigerant stream exits passage 82 and methane economizer 74 via conduit 128, and is introduced into the high-stage inlet port of methane compressor 83.
The first product portion in conduit 126 is carried to a second methane economizer 87 for further cooling. The second methane economizer 87 is preferably a plate-fin heat exchanger, most preferably a brazed aluminum plate-fin heat exchanger. In second methane economizer 87, the first product portion is cooled as it passes through passage 88 and indirectly exchanges heat with the refrigerant streams passing through passages 89 and 90, described in more detail below. A second cooled natural gas stream is produced from second methane economizer 87 via conduit 129. The second cooled natural gas stream in conduit 129 is subsequently divided into a second refrigerant portion carried in conduit 130 and a second product portion carried in conduit 131. The second refrigerant portion carried in conduit 130 is subsequently expanded in expansion valve 91 to thereby produce a second expanded refrigerant portion. The second product portion in conduit 131 is subsequently expanded in expansion valve 92 to thereby produce a two-phase second stream that is subsequently carried to a phase separator 93 via conduit 132. The second expanded refrigerant portion expander 91 is transported via conduit 133 to second methane economizer 87 wherein the second expanded refrigeration portion is employed as a refrigerant in passage 89 to cool the stream flowing in passage 88. After being employed as a cooling agent in passage 89, the warmed second refrigerant portion is removed from second methane economizer 87 via conduit 134 and subsequently introduced into a passage 95 of main methane economizer 74 wherein the warmed second refrigerant portion is used to cool the stream in passage 76. The further warmed second refrigerant portion exits methane economizer 74 via conduit 135 and is subsequently introduced into the intermediate-stage inlet port of methane compressor 83.
The two-phase in conduit 132 is separated in vapor/liquid separator 93 to thereby produce a gaseous third refrigerant portion via conduit 136 and a liquid third product portion via conduit 142. The gaseous third refrigerant stream in conduit 136 is combined with the compressed stream in conduit 138, described in further detail below. The resulting combined stream flows via conduit 139 to second methane economizer 87 wherein the combined stream is employed as a refrigerant in passage 90 to cool the stream in passage 88. The warmed third portion exits passage 90 of second methane economizer 87 via conduit 140 and is carried to passage 96 of main methane economizer 74 wherein the refrigerant stream is used to cool the stream in passage 76. The further warmed third refrigerant portion exits passage 96 and main methane economizer 74 via conduit 141 and is passed to the low-stage inlet port of methane compressor 83.
The liquid third product portion that exits separator 93 via conduit 142 is expanded in expansion valve 94 to thereby produce a two-phase expanded third product stream which is carried to LNG storage tank 99 via conduit 143. The vapor portion of the stream introduced in to LNG storage tank 99 and any boil-off vapors generated in tank 99 are removed from tank 99 via conduit 144. This vapor stream in conduit 144 is compressed in compressor 96 to produce the compressed gas stream in conduit 138 that is subsequently combined with the separated vapor stream in conduit 136 before being employed as a refrigerant in the second methane economizer 87 and the main methane economizer 74. The LNG in tank 99 can be stored and subsequently transported to a distant market where it is gasified for use as an energy source.
As shown in
With regard to the compressor/driver units employed in the process,
In one embodiment of the present invention, the LNG production system of
While specific cryogenic methods, materials, items of equipment and control instruments are referred to herein, it is to be understood that such specific recitals are not to be considered limiting but are included by way of illustration and to set forth the best mode in accordance with the present invention.