1. Field of the Inventions
Embodiments of the present invention generally relate to the transportation of hydrocarbons. More particularly, embodiments of the present invention relate to an integrated design for a liquefied natural gas transportation vessel. In addition, embodiments of the present invention relate to a method for combining liquefaction, transportation and regasification processes.
2. Description of Related Art
Clean burning natural gas has become the fuel of choice in many industrial and consumer markets around the world. However, natural gas sources are often located in remote locations relative to the commercial markets desiring the gas. This means that the natural gas must sometimes be produced in remote geographic locations, and then transported across oceans using large-volume marine vessels.
To maximize gas volumes for transportation, the gas may be taken through a liquefaction process. The liquefied natural gas (“LNG”) is formed by chilling very light hydrocarbons, e.g., gases containing methane, to approximately −160° C. The liquefied gas may be stored at ambient pressure in special, cryogenic tanks disposed on large ships. Alternatively, LNG may be liquefied at an increased pressure and at a warmer temperature, i.e., above −160° C., in which case it is known as Pressurized LNG (“PLNG”). For purposes of the present disclosure, PLNG and LNG may be referred to collectively as “LNG.”
The transportation of LNG to the importing nation or locale is expensive. As currently developed, gas is taken through a liquefaction process at a location proximate the point of production. This means that a large gathering and liquefaction center is erected in the producing country. Alternatively, the liquefaction process may take place offshore on a platform or vessel, such as a floating production, storage and offloading (FPSO) vessel. From there, the hydrocarbon product is loaded in its liquefied state onto marine transport vessels. Such vessels are known as LNG tankers.
Upon arrival at a destination country, the LNG product is offloaded at a receiving terminal. The receiving terminal may be onshore or “near shore” relative to the importing nation. In some cases, the gas is temporarily maintained in storage in its chilled and liquefied state. Liquefaction enables larger volumes of gas to be stored in insulated tanks until introduced into the gas grid, or delivered to a customer. In some instances, the chilled gas is transported in specially insulated vessels on the back of a trailer and hauled over-the-road to markets. In some instances, the imported LNG is “vaporized” into the grid for the market.
LNG technology generally requires large investments of capital and resources at the export and import terminals. It also requires cryogenic transfer of liquids at each end. In many locations, natural gas resources are present in insufficient quantities to justify the expense of building a gas liquefaction processing facility in the producing country or at the producing site. In addition, the transfer of cryogenic material, particularly from an FPSO, is difficult. Alternatively, consumer demand at the importing location may not economically justify the fabrication of a regasification facility. Therefore, there is a need for an integrated vessel that is capable of receiving a light hydrocarbon product at an export terminal of a producing country, chilling the gas to a liquefied state, and then transporting the gas to a location in greater proximity to the desired market. In addition, there is a need for a vessel that is capable of regasifying the light hydrocarbon upon arrival at a location for offloading, or import terminal. There is further a need for such a vessel that travels the oceans, on a river, or over the road.
Additional information relating to LNG liquefaction, transportation, and/or regasification technology can be found in U.S. Pat. No. 5,878,814 (to Breivik et al.), DE 32 00 958 (Linde A G), U.S. Pat. No. 5,025,860 (to Mandrin et al.), U.S. Pat. No. 6,517,286 (to Latchem), WO 2004/081441 (Conversion Gas Imports), US2003/185631 (Bliault et al.), WO 2004/000638 (ABB Lummus Global, Inc.), U.S. Pat. No. 3,766,583 (to Phelps), US2003/182948 (Nierenberg), US 2002/174662 (Frimm et al.), and U.S. Pat. No. 6,089,022 (to Zednik et al.).
First, a method for transporting liquefied natural gas is provided. The method includes the steps of on-loading natural gas in a substantially gaseous phase onto a vessel at a first location; cooling the natural gas on the vessel so as to convert it substantially into liquefied natural gas; storing the liquefied gas in an insulated container; transporting the liquefied natural gas on the vessel from the first location to a second location; heating the liquefied natural gas on the vessel so as to reconvert it back into a substantially gaseous phase; and off-loading the natural gas from the vessel at the second location. Preferably, the steps of cooling the natural gas and heating the liquefied natural gas are each accomplished by using a gas processing facility. More preferably, the same gas processing facility is used for both cooling (liquefying) the natural gas and heating the liquefied natural gas.
The method for transporting LNG may be accomplished on a variety of vessels. Examples include a marine vessel, a barge vessel, and an over-the-road trailer vessel.
In another aspect, a method is provided for transporting liquefied natural gas on a vessel. The method generally comprises the steps of providing a gas transfer system for the vessel; on-loading the natural gas onto the vessel through the gas transfer system, the natural gas being in essentially a gaseous phase; providing a gas processing facility on the vessel, the gas processing facility selectively cooling and heating the natural gas; flowing the natural gas through the gas processing facility so as to cool the natural gas to a lower temperature where the natural gas is in a substantially liquefied phase, and providing a containment structure on the vessel for containing the liquefied natural gas during transport.
In addition, a vessel for transporting liquefied natural gas is provided. In one embodiment, the vessel includes a gas transfer system for on-loading and off-loading natural gas to and from the vessel in its essentially gaseous phase; a gas processing facility for selectively (i) cooling the natural gas from a temperature where the natural gas is in a gaseous phase, to a lower temperature where the natural gas is in a substantially liquefied phase; and (ii) heating the natural gas from a temperature where the natural gas is in a substantially liquefied phase, to a temperature where the natural gas is converted back to its gaseous phase; a power generator for providing power to the gas processing facility; and a containment structure for containing the liquefied natural gas during transport.
The vessel again may be any type of transport vessel, including for example a marine vessel, a barge vessel, or an over-the-road trailer vessel. Where the vessel is a marine vessel, the gas transfer system may further comprise a buoyed line for placing the gas processing facility in fluid communication with a marine jumper line. Where the vessel is a land-based vessel such as a vessel on a trailer, the gas transfer system may further comprise a line for placing the gas processing facility in fluid communication with a land hose.
Where the containment structure is a marine vessel, the containment structure may be one or more Moss sphere tanks, it may be a membrane tank, or it may be a plurality of pressurized bottles in fluid communication. The plurality of bottles maintain the LNG under pressures greater than ambient.
In one aspect, the gas processing facility comprises at least one heat exchanger through which the natural gas thermally contacts a heat exchanger fluid; and at least one fluid movement device. The fluid movement device may be either a compressor or a pump.
In one arrangement, the gas processing facility cools the natural gas by providing a first heat exchanger for cooling the natural gas by thermal contact between the natural gas and a heat exchanger fluid; a compressor wherein the heat exchanger fluid is compressed and temporarily warmed after flowing through the first heat exchanger; a second heat exchanger wherein the compressed heat exchanger fluid is cooled; and an expander wherein the compressed heat exchanger fluid is further cooled, and decompressed before returning through the first heat exchanger. Alternatively, the gas processing facility heats the natural gas by providing a first heat exchanger for warming the natural gas by thermal contact between the natural gas and a heat exchanger fluid; and a second heat exchanger wherein the heat exchanger fluid is warmed after flowing through the first heat exchanger. The heat exchanger fluid movement device may be a compressor wherein the heat exchanger fluid is compressed and further warmed after flowing through the second heat exchanger and before returning through the first heat exchanger. Alternatively, the fluid movement device is a pump disposed in line between the first and second heat exchangers for pressurizing the liquefied heat exchanger fluid.
Preferably, the power generator is configured to selectively provide power to propel the vessel when the natural gas is stored in the containment structure, and to provide power to the gas processing facility when the natural gas is being cooled or heated. Optionally, the vessel may further have an ancillary compressor for circulating and cooling the heat exchanger fluid while the vessel is transporting the LNG in order to recondense any natural gas that becomes vaporized during transport, or to generally keep the heat exchanger fluid and system equipment cool.
The following drawings are provided as an aid in understanding the various inventions described herein.
The following words and phrases are specifically defined for purposes of the descriptions and claims herein. To the extent that a term has not been defined, it should be given its broadest definition that persons in the pertinent art have given that term as reflected in printed publications, dictionaries and/or issued patents.
“Natural gas” means a light hydrocarbon gas or a mixture including two or more light hydrocarbon gases that includes greater than 25 molar percent methane on a hydrocarbon species basis. For example, natural gas may contain methane along with other hydrocarbon components such as, but not limited to, ethane, propane, butane, or isomers thereof. Natural gas may also include non-hydrocarbon contaminant species such as, for example, carbon dioxide, hydrogen sulfide, water, carbonyl sulfide, mercaptans and nitrogen.
“LNG” or “liquefied natural gas” means natural gas or a portion thereof that has been liquefied. The term collectively includes any light hydrocarbon or mixture of two or more light hydrocarbons in substantially liquid form that includes greater than 25 molar percent methane on a hydrocarbon species molar basis. LNG includes, for example, natural gas induced into a liquid form through cooling at about atmospheric pressure and by both cooling and application of increased pressure over ambient pressure such as “PLNG.”
“Vessel” means any fluid transportation structure. Non-limiting examples of a vessel include a marine vessel, a barge vessel, or a trailer vessel.
“Marine vessel” means a vessel configured to transport volumes of fluids such as LNG over an ocean or other large water body.
“Barge vessel” means a vessel configured to transport volumes of fluids such as LNG over a river or within a marine inlet or bay.
“Trailer vessel” means a vessel configured to transport volumes of fluids such as LNG on a trailer. The trailer is pulled by a truck, a rig, or other mechanized vehicle over-the-road.
The terms “on-loading” and “off-loading” refer to the movement of fluids onto and off of a vessel, respectively. The terms are not limited as to the manner in which fluid movement is accomplished.
“Gas transfer system” means a system for on-loading or off-loading of fluids in at least a partially gaseous phase. Non-limiting examples of features for a gas transfer system include compressors, valves, conduits and pumps.
“Ambient temperature” refers to the temperature prevailing at any particular location.
“Expander” means any device capable of reducing pressure in a fluid line, including but not limited to an expansion valve or turboexpander.
Some embodiments of the invention include apparatus and methods for liquefying natural gas. In some embodiments natural gas includes a light hydrocarbon gas or a mixture including two or more light hydrocarbon gases that includes greater than 25 molar percent methane. Alternatively, natural gas may include greater than 40 molar percent methane or greater than 70 molar percent methane on a hydrocarbon species basis.
Some embodiments of the invention include apparatus and methods for liquefying natural gas to form LNG or regasifying LNG to reform natural gas. In some embodiments LNG includes natural gas or a portion thereof that has been liquefied. LNG may include any light hydrocarbon or mixture of two or more light hydrocarbons in substantially liquid form that includes greater than 25 molar percent methane on a hydrocarbon species basis. Alternatively, LNG may include greater than 40 molar percent methane or greater than 70 molar percent methane on a hydrocarbon species basis.
The following provides a description of specific embodiments shown in the drawings:
The marine vessel 100 includes a bridge 20. The bridge 20 is typically at either the fore or aft sections of the vessel. The bridge 20 is seen in both
The marine vessel 100 further includes a cargo storage area 30, or “containment structure.” The containment structure 30 is shown schematically in
Selected sets of bottles 30A are in fluid communication with one another to form a “tank.” The bottles 30A have appropriate valving 32 for moving LNG into and out of the bottles 30A. In one aspect, four-inch piping connections are provided for moving cryogenic fluids into and out of the containers 30A, though it is understood that other dimensions may be employed. The containers 30A may be at ambient pressure or slightly higher, and contain natural gas chilled to a temperature of approximately −160° F. (−106.7° C.) or less to provide liquefaction. Alternately the natural gas may be chilled to a temperature of approximately −190° F. (−123.3° C.) or less. Alternatively, the containers may be at ambient pressure or slightly higher, and contain natural gas chilled to a temperature of between approximately −200° F. to −270° F. (−128.9° C. to −167.8° C.). The containers 30A may alternatively be stored at a higher pressure above approximately 150 psi, and at temperature of approximately −193° F. (−125° C.) or more. Alternatively, the containers may be stored at a pressure in the range of approximately 250-450 psi, and at temperature between about −175° F. and −130° F. (−115° C. to −90° C.). Those of ordinary skill in the art will understand that the liquefaction temperature of a hydrocarbon will depend upon its pressure and composition.
The bottles 30A are preferably cylindrical in shape, and are typically fabricated from a steel material. Where the containers 30A serve as a pressure vessel, they are preferably fabricated from a steel material having walls of appropriate thickness. One or more bottles 30A in fluid communication together form a single “tank.”
Various other LNG containment structures are known for marine vessels. Examples are provided in
Each illustrative marine vessel 100, 100B, 100C also includes a gas processing facility. The gas processing facility is shown schematically at 40, and is intended to represent any facility that can selectively cool or heat fluids such as natural gas. Preferably, the gas processing facility 40 will first cool the natural gas from an essentially ambient temperature where the natural gas is in a gaseous phase, to a lower temperature where the natural gas is in a substantially liquefied phase. This occurs in connection with a procedure for on-loading of natural gas onto the vessel, e.g., vessel 100. In addition, the gas processing facility 40 will preferably also heat the natural gas from a temperature where the natural gas is in a substantially liquefied phase, to an essentially ambient temperature where the natural gas is converted back to its gaseous phase. This occurs in connection with a procedure for off-loading of natural gas from the vessel 100, 100B or 100C.
The gas processing facility of
The trailer vessel 500B is propelled by being pulled behind the rig 510B, or “truck.” The vessel 500B may be integral to the truck 510B, but is preferably on a separate trailer 520B that can be hitched and unhitched. The truck 510B, of course, includes an engine and shaft (not shown). The engine is typically diesel or gasoline powered, and operates to drive a shaft that transmits rotational motion to a transmission. The truck 510B also includes a battery (not shown) for powering electrical equipment. Preferably, the gas processing facility 504B is powered by the engine of the truck 510B, reducing equipment requirements. The engine may drive an electrical generator for creating electrical power for the gas processing facility 504B.
In practice, a volume of fluid such as natural gas is brought from the field to a gathering center. The gathering center may be on land, near shore, or offshore. The natural gas is stored at an essentially ambient temperature. In the case of a marine vessel such as vessels 100, 100B, and 100C, the vessel is offshore and receives natural gas pumped from the gathering facility (not shown) onto the vessel through the gas transfer system 50. The natural gas is not stored directly in the containment structure 30 of the vessel 100; rather, it is pumped through the gas processing facility 40 for liquefaction in accordance with
Referring again to
The gas process facility 40 includes a first heat exchanger 42. The first heat exchanger 42 acts to cool the natural gas by thermal contact between the natural gas and a heat exchanger fluid. The first heat exchanger 42 provides suitable adjacent fluid channels (not shown) for directing hydrocarbons and a heat exchanger fluid, respectively, so that the two channels are in thermal contact with one another. In this sequence, the heat exchanger fluid acts as a refrigerant flowing through lines “C.”
The gas process facility 40 also includes a compressor 44. The compressor 44 receives the heat exchanger fluid, or refrigerant, as it cycles from the first heat exchanger 42, and compresses the refrigerant. The process of compressing the refrigerant also acts to temporarily warm the refrigerant as it moves through the compressor 44. In one arrangement, the refrigerant is approximately 35° F. (1.7° C.) upon exiting the first heat exchanger 42, and is 300° F. (148.9° C.) upon exiting the compressor 44.
The gas process facility 40 also includes a second heat exchanger 46. The compressed refrigerant is cooled in the second heat exchanger 46. The second heat exchanger 46 provides adjacent fluid channels (not shown) through which the refrigerant and a coolant fluid flow. The coolant fluid acts to chill the refrigerant through thermal contact. In the context of a marine vessel such as the vessel 100 of
The gas process facility 40 also includes an expander 48. The expander 48 acts to expand the compressed refrigerant. The expander 48 may be an expansion valve, a turboexpander, or any other device for expanding fluid. The process of expanding the compressed refrigerant acts not only to decompress the refrigerant, but also to further chill it. In one arrangement, the refrigerant is at a temperature of approximately 65° F. upon exiting the second heat exchanger 46, but is −170° F. upon exiting the expander 48. The significantly chilled refrigerant is then cycled back through the first heat exchanger 42 where it again acts to refrigerate the natural gas. Ultimately, the natural gas is condensed into a substantially liquid phase. Thus, the gas process facility 40 of
Referring now to
The gas process facility 40 again includes a first heat exchanger 42. In this instance, however, the first heat exchanger 42 acts to warm the natural gas by thermal contact between the natural gas and the heat exchanger fluid. In this sequence, the heat exchanger fluid acts as a heating fluid flowing through lines “H.” The first heat exchanger 42 provides suitable fluid channels (not shown) for directing natural gas in its liquid phase, and a heat exchanger fluid, so that the two channels are in thermal contact with one another. In this sequence, the heat exchanger fluid acts as a heating fluid.
After cycling through the first heat exchanger 42, the heat exchanger fluid moves to the second heat exchanger 46. The heat exchanger fluid bypasses the expander 48. It can be seen in
In the regasification process shown in
From the second heat exchanger 46, the heat exchanger fluid moves through the compressor 44. The compressor 44 compresses the heating fluid, and delivers it to the first heat exchanger 42 in a further warmed state. As noted above, the process of compressing the fluid also acts to warm the fluid as it moves through the compressor 44. In one arrangement, the heat exchanger fluid is approximately 55° F. upon exiting the second heat exchanger 46, but is approximately 300° F. upon exiting the compressor 44. The significantly warmed heat exchanger fluid is then cycled back through the first heat exchanger 42 where it again acts to warm the natural gas. Ultimately, the natural gas is vaporized into a substantially gaseous phase for offloading. Thus, the gas process facility 40 of
Specific temperatures have been provided in connection with certain components of the gas process facility 40. However, it is understood that the scope of the present inventions is not limited to any particular temperatures, so long as the temperature of the heat exchanger fluid as it enters the first heat exchanger is sufficiently low to liquefy the natural gas (or other fluid) in the liquefaction process, and sufficiently high to vaporize the natural gas (or other fluid) in the gasification process. It is noted, however, that the gas processing facility 40 operates more efficiently where water is available in the second heat exchanger 46 that is warm, i.e., five degrees Fahrenheit or more above freezing. In an environment that lacks a suitable ambient temperature warming medium, integration of the liquefaction and vaporization heat exchangers is difficult. In this scenario, the gas processing facility 40 would preferably employ a vaporization means heated through combustion of a portion of the natural gas product. The fired vaporization facilities would benefit from the integration of utilities like water supply and fuel gas systems with the liquefaction process.
As noted above,
The process of cycling the heat exchanger fluid through the first heat exchanger 42 has produced a cooling of the heat exchanger fluid, substantially liquefying it. To reheat the heat exchanger fluid, the heat exchanger fluid is first moved through a pump 49. The pump 49 serves as an alternate fluid movement device vis-à-vis the compressor 44. It can again be seen that the heat exchanger fluid again bypasses the expander 48. The pump 49 is provided after the first 42 heat exchanger in order to energize and warm the heat exchanger fluid. The pump 49 also transfers the liquid heat exchanger fluid, e.g., sea water, towards the second heat exchanger 46.
As with facility 40 of
From the second heat exchanger 46, the heat exchanger fluid returns directly to the first heat exchanger 42 where it again acts to warm the natural gas. It can be seen that the compressor 44 has been bypassed in
It can be seen from the arrangements of
In the gas process facility 40 shown in
The power generator 41 is preferably an engine. The engine may be gas-powered, with the gas being provided from either naturally-occurring boil-off of natural gas from the LNG stored in the containment structure 30, or from an independent fuel supply (not shown). Alternatively, the engine may be diesel powered. In this instance, a diesel supply (not shown) would be provided on the ship. In the arrangement of
It is preferred that the ship's propulsion system 43 be integrated with the power system for powering the gas processing facility 40 or 40′. Thus, when the ship is not in transit, the power generator may be used to drive separate motors 44m and 49m (49m not shown). The motors 44m and 49m, in turn, provide mechanical power to either the compressor 44 (in the arrangement of
In order for the gas processing facility 40 to share a power generator 41 with the ship's propulsion system 43, the power requirements should be generally comparable. With propulsion and gas processing power requirements being comparable, a single, integrated power generation plant and electric or hydrocarbon motor drive may be installed to provide the power needed for both operations. In this arrangement, the gas compression 44 and ship propulsion 43 are preferably not used at the same time so as to minimize the overall power generation needs for the ship. In one embodiment, the power generator 41 is a power generation plant that feeds a single variable frequency drive (VFD). The VFD is used to alternately control the ship's propulsion 43 and to power refrigeration motors 44m and 49m. It is understood that the present inventions are not limited to the way in which power is shared or transferred between the propulsion system 43 and the gas processing facility 40. Other power arrangements may be used, such as the modification of motor windings, or the use of a gear box system that employs mechanical shafts.
In another embodiment, the ship's power generator 41 may be used for initial liquefaction of the natural gas, as described above in connection with
The use of a smaller, ancillary compressor 45 has many advantages. First, this arrangement allows reliquefaction of hydrocarbons during transit. This, in turn, accommodates a much higher boil-off gas rate from the containment structure 30. This also reduces the insulation requirements for the cryogenic storage. Further, the use of a smaller, ancillary compressor 45 keeps the heat exchanger fluid and system equipment cold during transit, allowing the vessel to be prepared more quickly to receive natural gas more quickly upon docking at an export terminal for liquefaction.
In yet another embodiment, two independent power generation systems are provided. One system operates to power the ship's propulsion system 43, while the other system operates the gas processing facility 40 along with the miscellaneous process equipment associated with liquefaction and vaporization. Such process equipment may include firefighting equipment, gas processing controls, fluid pumps, and drain valves.
A method for transporting liquefied natural gas on a vessel is also provided. The vessel may be a marine vessel such as vessel 100 of
As part of the method, the natural gas is on-loaded onto the outfitted vessel at an export terminal. The natural gas is on-loaded through a gas transfer system at essentially ambient temperature and in a gaseous phase. The transport vessel may optionally be integrated with the natural gas production system. The transport vehicle would receive raw fluids from the well, and provide the facilities to process the fluids into gas, ambient hydrocarbon liquid, and produced water. The production facilities would receive utility and operating benefits through integration with the liquefaction and vaporization facilities. The transport vehicle would also have the storage capacity to transport and deliver any ambient liquid hydrocarbon products created in the production system.
The natural gas flows through the first heat exchanger 42 of the gas processing facility 40 so as to cool the natural gas from its ambient temperature. The natural gas is brought to a lower temperature where it is in a substantially liquefied phase. Thus, the natural gas is “liquefied.” The liquefied natural gas is then stored in the containment structure 30, and is ready for transport on the vessel to an import terminal.
During the on-loading process, the ship's propulsion system 43 is preferably shut down. The ship's power generator 41 diverts power to the liquefaction process facilities 40. Once the ship cargo is full, the gas processing system 40 is shut down, and the ship propulsion system 43 is started. The vessel 100 then transports the cryogenic cargo to the import location.
Upon arrival at an import terminal, the gas is off-loaded. In order to off-load the gas, the gas is pumped through the gas processing facility 40 so as to heat the natural gas from a temperature where the natural gas is in its substantially liquefied phase, to a temperature where the natural gas is converted back to its gaseous phase. The natural gas is then off-loaded through the gas transfer system 50. While on station at the import location, the ship's propulsion system 43 is again shut down, and the cryogenic cargo is regasified as it is unloaded from the vessel 100. This allows for optionally an integrated power generator for both the ship's propulsion system 43 and the gas processing facility 40.
In one embodiment of the method invention, partially regasified fluids are pumped into a gas storage device on land. An example is a salt dome cavern facility. The gas storage device is integrated with the vessel to store pressurized gas off-loaded at the gas receiving terminal. The facility can be sized to supply continuous gas at the average delivery rate between deliveries. Pressurized gas storage is ideal because the cryogenic fluid can be inexpensively pumped to storage pressures before vaporization rather than having expensive gas compression with the storage facility.
It can thus be seen that an LNG transportation vessel is provided, and that a method for transporting LNG or other hydrocarbon fluids is also provided. The method of transporting, in one aspect, combines liquefaction, transportation and regasification processes. In addition, it can be seen that an integrated system is provided for transporting natural gas.
Conventional gas transportation means require large transfer rates over a period of 25-30 years to be economically attractive. As a result, many resources containing under approximately 5 TSCF (trillion standard cubic feet) of gas currently go undeveloped. The disclosed technology may allow an investor to monetize these smaller hydrocarbon reserves. The three functions of liquefaction, transport and regasification may be integrated into a single re-deployable unit for cost-effective transport of natural gas to consumer markets from remote locations. Stated another way, the integration of liquefaction, vaporization and transport means enables recovery of otherwise stranded hydrocarbon resources, and also decreases the overall manpower required for operations and maintenance, thus reducing operating expenses and crew requirements. The vessel allows monetization of small gas resources, and enables development of a series of small resources as it is re-deployable.
This application claims the benefit of U.S. Provisional Application 60/625,388, filed 5 Nov., 2004.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US05/37245 | 10/17/2005 | WO | 00 | 12/26/2007 |
Number | Date | Country | |
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60625388 | Nov 2004 | US |