Patent Grant
9534342
The present invention relates to an iron sole plate having improved surface characteristics. The invention particularly relates to an iron sole plate having a silane-based coating layer for improving friction, abrasion and other desirable properties of the plate material.
Improving surface properties of iron sole plates for ensuring more comfortable ironing has always been a challenge in the relevant industry. For improving the surface properties, various coating materials such as Al—TiN, Teflon®, ferrous alloys, and other inorganic materials such as silanes and various ceramics have been proposed in the current state of the technical field. Al—TiN and Teflon, inter alia became preferable coatings for iron sole plates with allegedly low friction and non-sticking properties. It is well known in the art that these materials are applied to the external surface of the sole plates by various techniques such as PVD, CVD, spray coating and dip coating.
The present invention provides an alternative iron sole plate having a silane based coating layer which is advantageously produced by way sol-gel techniques. The inventive iron sole plate according to the invention is noted to be at least comparable with state of the art sole plates, and showing considerably improved characteristics in terms of cleaning, friction, fabric protection etc.
Sol-gel concept is known as a process comprising typically application of hydrolysable precursors such as oxides and alkoxides and a following heat treatment to obtain mechanically stable coating material with an enhanced density and hardness.
A coating method for glass, ceramic and metal surfaces using sol-gel technique aiming alkali-resistance, wear-resistance and dishwasher-safety for household, specifically kitchen appliances is introduced by the application WO 2010-072814-A1. The document explains a composite coating system applied on a metal surface to be protected, which are preferably aluminum and/or its alloys. The coating requires a porous base, which is an oxide layer, e.g. aluminum oxide layer established on the metallic base which is made of aluminum and/or its alloys. The said oxide layer is to be coated with two additional layers which require repetitive applications and heat treatments including cooling to the room temperature. First of them contains polydimethyl siloxane (PDMS) to obtain an elastic base to the second layer, which contains alkali metal compounds for alkali resistance. All those interlayers require additional process steps with their own costs including time-costs. Besides, this document is not concerned in acquiring low-friction and cleaning convenience at iron sole plates, instead the main concern of this document is stressed as chemical resistance by surfaces subjected to especially alkaline liquids.
Iron sole plates coated with sol-gel method is known per se by applications EP 0 998 604 B1 and US 2003/0074814 A1. Both of these documents explain methods using a plurality of coating layers applied to metal surfaces. Besides, the metallic base to be coated in both methods is essentially aluminum and/or its alloys, which requires a hard interlayer between the final coating layer and the base material itself. Therefore an oxide layer was employed as the interlayer, which means an additional process step with its own costs.
An iron sole plate which is made of aluminum and/or its alloys and coated using sol-gel method is presented in the document U.S. Pat. No. 6,901,687. This document does not clearly report the ingredients of coating solution, which also requires a porous aluminum oxide layer prior to the application of the liquid mixture. The dry thickness of the coating is 30-40 μm, which could readily cause potential cracks because of the great potential with inner tensions along this thick matrix.
An iron sole plate has its specific requirements to be used for a long lifespan without major problems. It is preferred for an iron sole plate to have an ironing surface with a rather high hardness which protects the sole plate from abrasive damages. Additionally, an iron sole plate should preferably cause low friction forces, thus a comfortable use during ironing. Moreover, because ironing is a high temperature application, there arises another expectation from an iron sole plate to have easy-to-clean properties due to accidental contamination of molten synthetic fabric materials which may stick, burn and cause burnt stains on the surface of the sole plate. The major objectives given hereinabove may generally be obtained by coating desired materials to the base surface. It is therefore, highly important for the industry of household appliances to have a coating composition that is applicable not only to limited kind of base materials (e.g. aluminum or aluminum alloys) but also other metallic structures such as stainless steel.
A primary object of the present invention is to provide a low-friction, abrasion resistant iron sole plate which is easy-to-clean.
Another object of the present invention is to provide a method for producing low-friction, abrasion resistant iron sole plates which is simple and cost effective by virtue of a monolayer coating with minimum process steps.
A further object of the present invention is to provide a method for producing an iron sole plate having a glass-like coating wherein the need for an additional oxide layer is eliminated.
Another object of the present invention is to provide a method for producing iron sole plates with glass coating, which coating is applicable to wide range of metallic base materials.
Still a further object of the present invention is to provide an ironing appliance including the base material of the invention.
The present invention proposes an iron sole plate for domestic or industrial purposes, and specifically an iron sole plate coated with an inorganic polymer using a sol-gel process.
More specifically, the invention pertains to an iron sole plate comprising a base material having an ironing surface, and a coating layer covering said ironing surface wherein the coating is a hydrolysis and polycondensation product of a composition comprising the following:
In preferred embodiments, said composition further comprises an alkali hydroxide, more preferably KOH as a base catalyst. The inventors also noted that a metal precursor which is an alkoxide or hydroxide of Cesium makes positive contribution to mechanical properties of the final coating. Among these CsOH is particularly preferred.
The sol composition for use in preparation of the iron sole plate according to the present invention may further comprise an alcohol for solution homogeneity as a co-solvent.
The said sole plate lacks any interlayer between the inorganic polymer coating and the metallic base surface; metallic base surface and inorganic polymer coating are in direct contact with each other without requiring an additional porous layer for proper adhesion.
Hydrolyzable silicon compounds comprising at least one non-hydrolyzable moiety, preferably monoalkyl silanes, build a condensate network with other silicon compounds which do not comprise any non-hydrolyzable moieties. The coating composition as prepared for producing the iron sole plates of the present invention may be a condensation product of two groups of silanes. The first party of reacting compounds, which is a hydrolyzable silane compound comprises at least one non-hydrolyzable moiety, such as one of monoalkyl silanes, namely by methyl triethoxy silane (MTEOS). The second party of reacting compounds does not comprise any non-hydrolyzable moieties, because all of the moieties are to be hydrolyzable.
Polycondensation products of the silanes having different number of functional groups according to the present invention are prepared in the presence of an alkoxide or hydroxide of Cesium as precursor, whereas various metal alkoxides, metal salts or metal hydroxides may additionally be included as additional precursors. The inventors noted that Cesium compounds as precursor materials give best results for obtaining the desirable abrasion resistance and easy-to-clean properties in the sole plate of the present invention. In the context of the present invention the cesium compound is preferably CsOH. It was noted also that Cs compounds give good performance in adhering to base materials (sole plate) other than aluminum based materials such as stainless steel.
The hydrolysis and polycondensation reactions, as well known in the art with generic name of “sol-gel” can be catalyzed by suitable reagents. The method of the present invention preferably involves a sol-gel procedure which is base catalyzed, preferably by alkali hydroxides, and more preferably by KOH.
Referring now to
The color of the iron sole plate according to the present invention may be adjusted by way of colorants in specific amounts. The preferred colorants are typically selected from TiO2 and graphite although alternative inorganic colorants may also be employed depending on manufacturer's preference. The inventors noted that graphite, besides being a colorant, helps to improve mechanical strength of the coating.
To obtain a good adhesion between the metallic basis and the coating, it is highly desirable to carry out a surface treatment of the iron sole plate prior to coating. In a preferred embodiment it is subjected to sand blasting using glass sand or stainless steel grains. Then the surface can be cleaned from residues.
Sand blasting step has also an additional visual effect on the final product. The level of roughness depending on sandblasting material choice e.g. quartz sand, stainless steel balls and alumina adds variable optical effects on the surface. Afterwards, the surface is to be cleaned using solvents of gradual polarity chosen from e.g. water, ethanol and acetone, and then dried.
After cleaning the surface from residues, it is ready to be coated with the solution intended to form the abrasion-resistant and easy-to-clean organic polymer film. A mixture of methyl triethoxy silane (MTEOS), tetraethoxy silane (TEOS) and the metal precursor are mixed and heat treated for carrying out the hydrolysis and polycondensation reactions. The reactions are preferably base catalyzed with an alkali hydroxide as mentioned above. The reaction medium may further comprise an alcohol. In a preferred embodiment, where the alkali hydroxide is KOH and metal precursor is CsOH, the resulting composite coating is expected to have an empirical formula of KxCsySiz, where x, y and z will depend on the stoichiometric amounts of the reactants and catalyst.
In the preferred embodiment mentioned above, the sol of the coating mixture preferably comprises the following components in defined amounts based on the total weight of the mixture:
The preferable molar proportions between MTEOS:TEOS, KOH:CsOH and water:PMOH can be, for instance about 4:1, 1:2 and 1:3, respectively.
The mixture may also contain alkoxides of sodium, lithium, titanium, cerium, manganese, neodymium, praseodymium, promethium or samarium as initiation agents in mass percentages of 0.01-0.1%, preferably 0.03-0.08%, more preferably 0.05-0.07% mixed with chelat ligands e.g. acetyl acetone or ethyl acetate in molar ratios in the range of 1:1-1:3.
The preparation of Sol is preferably as follows: non-aqueous (solid) pellets of bases are added into the mixture of siloxanes and stirring continues until the solids completely dissolve in the liquid phase. Afterwards, the solution of PMOH in pure water is added dropwise into the solution whilst the temperature in the container is forced not to exceed the room temperature. It is possible to adjust the color and opacity of the mixture which will turn into transparent in its nature when finalized, by addition of graphite and titanium dioxide as colorants in several ratios amongst each other. These optional colorants can now be added to the mixture by up to 15 wt % with respect to total solid matters. Mechanical stirring and ultrasonic bath could be used successively for acquiring a proper dispersion of colorants in the liquid mixture.
This solution can be applied directly onto the sandblasted and cleaned metal sole plate surface, which is an important cost drop not to requiring an additional interlayer. The solution can be applied onto the metallic surface by any convenient method e.g. brushing dip coating, spin coating, casting, and preferably using spray coating. Spray coating allows an overall homogeneous thickness of final solid coating layer. The wet thickness of the coating should preferably be between 1-10 μm, wherein preferable wet thickness is about 3-4 μm.
The coated wet sole plate is then preferably subjected to a partial drying at temperatures clearly below the boiling point of water, e.g. at 75° C. Afterwards the heat treatment starts in a furnace, which is operated at 300-500° C., preferably at 350-400° C. The furnace may also be operated with a temperature-programming, which provides a gradual temperature rise ending at said temperature interval. Since the condensation requires water in the reaction media, the furnace humidity should be kept around saturation in order to avoid evaporation losses from the surface. After a period of 17-20 minutes, the subject may be removed from the furnace to cool back to the ambient temperature.
Because thick brittle films are likely to crack during or after the heat treatment because of the inner tensions rising along the matrix, preferably a very thin dry film with the thickness of 1-10 μm, preferably 2-4 μm can be arranged in order to reduce this risk. Such a low thickness also provides high heat transmittance.
This coating provides a high mechanical and abrasive resistance, and low friction factor.
The technical effects achieved through the invention are demonstrated in the following comparative examples. Preparation of an iron sole plate according to a preferred embodiment of the invention is also explained in Example 1.
A sol comprising the following components is mixed about 12 hrs.
Then, 1.01 g TiO2 and 0.34 g graphite were added and the mixture was stirred for an additional couple of hours. The mixture is applied to a preprepared iron sole plate made of stainless steel which is sand blasted, by way of spray coating. The coated sole plate was then furnaced in an oven set to a temperature of 400° C. with gradual heating. The obtained coating was analyzed with Energy-dispersive X-ray spectroscopy (EDX), and elemental composition of the sample was consisting of K, Cs and Si along with some oxides as expected. The analysis is shown in
A sample of iron sole plate prepared according to Example 1 was treated with an abrasion test equipment (Elcometer 1720 washability abrasion tester) applying 1.2 kg pressure with Scotch Brite (ASTM D4213) at 50 rpm and 10.000 revolutions in total. Slightly visible scratches were observed without visible exfoliations of coating.
A sample of the sole plate as tested for abrasion properties was inspected with a Scanning Electron Microscope. The SEM views at various magnifications are shown in
An iron (Arcelik®) was tested with different sole plates wherein the sole plates are brought into contact with loundry starch and sole plates are allowed to be sticked with the same. Results are given below in Table I.
Various irons with different sole plates as commercially available in the market are tested for their detrimental cause to shining in ironed fabrics after several ironings. Each ironing was made by 25 repetitive back and forth movements of the iron on specified wearings. After the ironing procedure, each kind of fabric was graded with a definition among “no shining”, “very little shining”, “little shining” “shining” and “extremely shining”. Results are given below in Table II.
An iron adapted with the iron sole plate as prepared in Example 1 was tested and compared with irons having conventional coatings, i.e. Al—TiN and stainless steel. Each iron was placed on an inclined surface at average heated temperatures thereof, and the minimum angle of start of sliding on the surface was noted for said each iron. The results are shown in Table III.
Results & Discussions
An iron sole plate as prepared according to the procedure of Example 1 was adapted to conventional household irons and subjected to the tests as alluded in the foregoing examples. Irons with conventional coatings were also tested for comparative purposes. To summarize the results, the iron base material was found to be very resistant to abrasions even under severe conditions causing scratches without total loss of coating. It was also observed that easy-to-clean properties of the material were quite satisfactory. On the other hand the coating as tested with various kinds of fabrics had notable performance as compared to other coatings in terms of detrimental effects to the fabric (i.e. causing shining). This performance was even better than Teflon®. It was further observed that friction properties of the iron sole plate were considerably improved as demonstrated in the self sliding test (Table III). As a conclusive result, the coating according to the present invention has excellent performance with not only with aluminum base materials, but also with stainless steel unlike the conventional coatings which are hydrolysis and polycondensation products.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2012/058111 | 5/3/2012 | WO | 00 | 10/31/2014 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2013/164028 | 11/7/2013 | WO | A |
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| Number | Date | Country | |
|---|---|---|---|
| 20150135563 A1 | May 2015 | US |
