Patent Application
20220136885
The present disclosure relates to a water sensor for sensing the level of water in a fuel storage tank and a method of using such sensor to facilitate appropriate implementation of systems to limit acidic corrosion, and/or to limit the accumulation of water and particulate matter in stored fuel. More particularly, the present disclosure relates to a water sensor particularly adapted to sense very low water levels in fuel storage tanks.
A fuel delivery system typically includes one or more underground storage tanks that store various fuel products and one or more fuel dispensers that dispense the fuel products to consumers. The underground storage tanks may be coupled to the fuel dispensers via corresponding underground fuel delivery lines.
In the context of an automobile fuel delivery system, for example, the fuel products may be delivered to consumers' automobiles. In such systems, the fuel products may contain a blend of gasoline and alcohol, specifically ethanol. Blends having about 2.5 vol. % ethanol (“E-2.5”), 5 vol. % ethanol (“E-5”), 10 vol. % ethanol (“E-10”), or more, in some cases up to 85 vol. % ethanol (“E-85”), are now available as fuel for cars and trucks in the United States and abroad. Other fuel products include diesel and biodiesel, for example.
Sumps (i.e., pits) may be provided around the equipment of the fuel delivery system. Such sumps may trap liquids and vapors to prevent environmental releases. Also, such sumps may facilitate access and repairs to the equipment. Sumps may be provided in various locations throughout the fuel delivery system. For example, dispenser sumps may be located beneath the fuel dispensers to provide access to piping, connectors, valves, and other equipment located beneath the fuel dispensers. As another example, turbine sumps may be located above the underground storage tanks to provide access to turbine pump heads, piping, leak detectors, electrical wiring, and other equipment located above the underground storage tanks.
Underground storage tanks and sumps may experience premature corrosion. Efforts have been made to control such corrosion with fuel additives, such as biocides and corrosion inhibitors. However, the fuel additives may be ineffective against certain microbial species, become depleted over time, and cause fouling, for example. Efforts have also been made to control such corrosion with rigorous and time-consuming water maintenance practices, which are typically disfavored by retail fueling station operators.
Water and/or particulate matter sometimes also contaminates the fuel stored in underground storage tanks. Because these contaminants are generally heavier than the fuel product itself, any water or particulate matter found in the storage tank is generally confined to a “layer” of fuel mixed with contaminants at bottom of the tank. Because dispensation of these contaminants may have adverse effects on vehicles or other end-use applications, efforts have been made to timely detect and remediate such contaminants.
The present disclosure relates to a method and apparatus for controlling a fuel delivery system to limit acidic corrosion. An exemplary control system includes a controller, at least one monitor, an output, and a remediation system. The monitor of the control system may collect and analyze data indicative of a corrosive environment in the fuel delivery system. The output of the control system may automatically warn an operator of the fueling station of the corrosive environment so that the operator can take preventative or corrective action. The remediation system of the control system may take at least one corrective action to remediate the corrosive environment in the fuel delivery system.
The present disclosure further relates to a method and apparatus for filtration of fuel contained in a storage tank, in which activation of a fuel dispensation pump concurrently activates a filtration system. In particular, a portion of pressurized fuel delivered by the dispensation pump is diverted to an eductor designed to create a vacuum by the venturi effect. This vacuum draws fluid from the bottom of the storage tank, at a point lower than the intake for the dispensation pump so that any water or particulate matter at the bottom of the storage tank is delivered to the eductor before it can reach the dispensation pump intake. The eductor delivers a mix of the diverted fuel and the tank-bottom fluid to a filter, where any entrained particulate matter or water is filtered out and removed from the product stream. Clean, filtered fuel is then delivered back to the storage tank.
The present disclosure further provides a probe combining flow and water level detection.
The present disclosure additionally provides a low level water sensor capable of registering low levels of water contamination in a fuel tank.
In another form thereof, the disclosure provides a low-level water float, comprising: a float base; a frame extending upwardly from the float base; and a float magnet spaced a distance from the float base by the frame.
In embodiments, the distance is at least about 3.0 inches.
In embodiments, the low level water float is provided in combination with a magnetostrictive probe shaft, the low-level water float reciprocatable through a float travel on the magnetostrictive probe shaft, the magnetostrictive probe shaft having a datum magnet positioned at a distal end of the magnetostricitve probe shaft, the frame spacing the float magnet a minimum distance from the datum magnet throughout the travel of the low-level water float.
In embodiments, the frame further comprises at least one frame spacer creating a nominal point contact between the low-level water float and the magnetostrictive probe shaft.
In embodiments, the frame comprises a ballast receiver sized to secure at least one ballast to the low-level water float.
In embodiments, the ballast receiver includes a plurality of ballast receiver dimensions including a ballast receiver height, and the at least one ballast has at least one ballast dimension complementary to at least one of the plurality of ballast receiver dimensions.
In embodiments, the low level water float is provided in combination with a magnetostrictive probe shaft having a foot secured to the magnetostrictive probe shaft, the low-level water float reciprocatable along the probe shaft through a float travel, the foot defining an end point of the float travel of the low-level water float, the low-level water float having a foot recess, the foot insertable into the foot recess of the low-level water float, the low-level water float have at least one float foot creating a nominal point contact with the foot when the float is at the end point of travel.
In embodiments, the combination further comprises: a foot secured to the magnetostrictive probe shaft, the foot defining an end point of the float travel of the low-level water float, the low-level water float having a foot recess, the foot insertable into the foot recess of the low-level water float, the low-level water float have at least one float foot creating a nominal point contact with the foot when the float is at the end point of travel.
In a further form thereof, the present disclosure provides a low-level water probe, comprising: a probe shaft; a low-level water float reciprocatable along the probe shaft through a travel; and a foot, the foot defining an end point of the travel of the low-level water float, the low-level water float having a foot recess, the foot insertable into the foot recess of the low-level water float.
In embodiments, the low-level water float comprises at least one float foot creating a nominal point contact with the foot when the float is at the end point of travel.
In embodiments, the probe shaft comprises a magnetostrictive probe shaft and wherein the low-level water float comprises a magnet.
In embodiments, the foot recess has a foot recess inner diameter and the foot has a foot outer diameter, the foot outer diameter smaller than the foot recess inner diameter.
In embodiments, the low-level water float further comprises at least one float spacer creating a nominal point contact between the low-level water float and the magnetostrictive probe shaft.
In a further form thereof, the present disclosure provides a method of configuring a low-level water float for use, comprising: accessing a ballast receiver formed in the low-level water float, the ballast receiver having a plurality of ballast receiver dimensions including a ballast receiver height; testing the buoyancy of the low-level water float relative to a desired buoyancy; and adjusting the buoyancy of the low-level water float by securing to the low-level water float with the ballast receiver at least one ballast having at least one ballast dimension complementary to one of the ballast receiver dimensions.
In embodiments, the testing step comprises testing the buoyancy of the low level water float on a low-level of water, the low level of water comprising a level of water having a depth of ¼ inch.
In embodiments, the adjusting step comprises: detaching a first portion of the water float from a second portion of the water float to provide access to the ballast receiver, wherein the securing step comprises positioning the at least one ballast radially inward of the low-level water float; and attaching the first portion of the water float to the second portion of the water float.
In embodiments, the ballast receiver comprises a cylindrical recess formed in the water float and the ballast receiver dimensions further include a radius, and wherein the adjusting step comprises: detaching a first half of the water float from a second half of the water float to provide access to the ballast receiver, wherein the securing step comprises positioning the at least one ballast radially inward of the low-level water float; and attaching the first portion of the water float to the second portion of the water float.
In embodiments, the ballast dimension comprises a ballast height, and wherein the adjusting step comprises: determining a determined ballast height required to achieve the desired buoyancy.
In embodiments, the securing step comprises: selecting a plurality of ballasts of the at least one ballast having a total height substantially equal to the determined ballast height.
In a further form thereof, the disclosure provides a low-level water float, comprising: a float body comprising a ballast receiver including a plurality of ballast receiver dimensions including a ballast receiver height; and at least one ballast having at least one ballast dimension complementary to at least one of the plurality of ballast receiver dimensions, the ballast secured by the ballast receiver. According to an embodiment of the present disclosure, a fuel delivery system is provided including a storage tank containing a fuel product, a fuel delivery line in communication with the storage tank, at least one monitor that collects data indicative of a corrosive environment in the fuel delivery system, a controller in communication with the at least one monitor to receive collected data from the at least one monitor, and a remediation system configured to take at least one corrective action to remediate the corrosive environment when activated by the controller in response to the collected data.
According to another embodiment of the present disclosure, a fuel delivery system is provided including a storage tank containing a fuel product, a fuel delivery line in communication with the storage tank, a monitor including a light source, a corrosive target material exposed to a corrosive environment in the fuel delivery system, and a detector configured to detect light from the light source through the target material, and a controller in communication with the monitor.
According to yet another embodiment of the present disclosure, a fuel delivery system is provided including a storage tank containing a fuel product, a sump, a pump having a first portion positioned in the sump and a second portion positioned in the storage tank, and a water filtration system. The water filtration system includes a water filter positioned in the sump and configured to separate the fuel product into a filtered fuel product and a separated water product, a fuel inlet passageway in fluid communication with the storage tank and the water filter via the pump to direct the fuel product to the water filter, a fuel return passageway in fluid communication with the water filter and the storage tank to return the filtered fuel product to the storage tank, and a water removal passageway in fluid communication with the water filter to drain the separated water product from the water filter.
According to still another embodiment of the present disclosure, a fuel delivery system is provided including a water filtration system. The water filtration system includes a filter configured to separate a fuel product into a filtered fuel product and a separated water product, an eductor configured to receive a flow of fuel from a fuel delivery pump and send the flow of fuel to the filter, and a vacuum port on the eductor configured to be operably connected to a source of contaminated fuel, such that the vacuum port draws the contaminated fuel into the flow of fuel through the eductor and delivers a mixture of fuel and contaminated fuel to the filter.
According to still another embodiment of the present disclosure, a fuel delivery system is disclosed including a storage tank containing a fuel product, a dispenser, a water filter, a fuel uptake line in fluid communication with the storage tank and the dispenser to deliver the fuel product to the dispenser, a filtration uptake line in fluid communication with the storage tank and the water filter to deliver the fuel product to the water filter, the water filter being configured to separate the fuel product into a filtered fuel product and a separated water product, a fuel return passageway in fluid communication with the water filter and the storage tank to return the filtered fuel product to the storage tank, and a water removal passageway in fluid communication with the water filter to drain the separated water product from the water filter.
According to another embodiment, a probe is disclosed, the probe comprising: a water float buoyant on a quantity of water; a probe shaft having a longitudinal axis, the water float restrained for displacement along a longitudinal axis of the probe shaft, the probe capable of communicating a position of the water float along the probe shaft to signal an amount of the quantity of water; an isolator fixed along the longitudinal axis of the probe shaft, whereby the isolator maintains a fixed position relative to the probe shaft along the longitudinal axis of the probe shaft; a flow sensing shuttle restrained by the probe shaft for displacement along the longitudinal axis of the probe shaft, the isolator interposed between the water float and the flow sensing shuttle, whereby the isolator isolates the flow sensing shuttle from the water float; and a stop secured to the probe shaft, the flow sensing shuttle displaceable along the longitudinal axis of the probe shaft between the isolator and the stop; the flow sensing shuttle moveable by a fluid flow between a no-flow position and a flow position, the probe capable of communicating the presence of the fluid flow in the flow position, the probe capable of communicating the absence of the fluid flow in the no-flow position.
According to yet another embodiment, a probe is disclosed, the probe comprising: a probe shaft; a flow sensing shuttle restrained by the probe shaft for displacement along the longitudinal axis of the probe shaft; the flow sensing shuttle displaceable along the longitudinal axis of the probe shaft; the flow sensing shuttle moveable by a fluid defining a fluid flow, the flow sensing shuttle is not buoyant on the fluid, the flow sensing shuttle moveable by a fluid flow along a flow sensing shuttle travel between a no-flow position and a flow position, the probe capable of communicating the presence of the fluid flow in the flow position, the probe capable of communicating the absence of the fluid flow in the no-flow position.
According to a further yet embodiment, a prove is disclosed, the probe comprising: a water float buoyant on a quantity of water, the water float having a retracted position defining a retracted float width, the water float having an extended position defining an extended float width greater than the retracted float width; and a probe shaft having a longitudinal axis, the water float restrained for displacement along a longitudinal axis of the probe shaft, the probe capable of communicating a position of the water float along the probe shaft to signal an amount of the quantity of water.
According to an additional embodiment, a method of mitigating acidic corrosion in a fuel storage tank is provided, the method comprising: measuring a low level of water in the fuel storage tank, the low level of water defining a layer of water having a height of less than 1 inch from a floor of the fuel storage tank; and employing an acetic corrosion mitigation system to remove the layer of water responsive to measuring the low level of water in the fuel storage tank.
The above-mentioned and other features and advantages of this disclosure, and the manner of attaining them, will become more apparent and the invention itself will be better understood by reference to the following description of embodiments of the invention taken in conjunction with the accompanying drawings, wherein:
Corresponding reference characters indicate corresponding parts throughout the several views. The exemplifications set out herein illustrate exemplary embodiments of the invention and such exemplifications are not to be construed as limiting the scope of the invention in any manner.
An exemplary fuel delivery system 10 is shown in
Fuel delivery system 10 of
Fuel delivery system 10 of
According to an exemplary embodiment of the present disclosure, fuel delivery system 10 is an automobile fuel delivery system. In this embodiment, fuel product 14 may be a gasoline/ethanol blend that is delivered to consumers' automobiles, for example. The concentration of ethanol in the gasoline/ethanol blended fuel product 14 may vary from 0 vol. % to 15 vol. % or more. For example, fuel product 14 may contain about 2.5 vol. % ethanol (“E-2.5”), about 5 vol. % ethanol (“E-5”), about 7.5 vol. % ethanol (“E-7.5”), about 10 vol. % ethanol (“E-10”), about 15 vol. % ethanol (“E-15”), or more, in some cases up to about 85 vol. % ethanol (“E-85”). As discussed in U.S. Publication No. 2012/0261437, the disclosure of which is expressly incorporated herein by reference in its entirety, the ethanol may attract water into the gasoline/ethanol blended fuel product 14. The water in fuel product 14 may be present in a dissolved state, an emulsified state, or a free water state. Eventually, the water may also cause phase separation of fuel product 14.
In addition to being present in storage tank 16 as part of the gasoline/ethanol blended fuel product 14, ethanol may find its way into other locations of fuel delivery system 10 in a vapor or liquid state, including dispenser sump 30 and turbine sump 32. In the event of a fluid leak from dispenser 12, for example, some of the gasoline/ethanol blended fuel product 14 may drip from dispenser 12 into dispenser sump 30 in a liquid state. Also, in the event of a vapor leak from storage tank 16, vapor in the ullage of storage tank 16 may escape from storage tank 16 and travel into turbine sump 32. In certain situations, turbine sump 32 and/or components contained therein (e.g., metal fittings, metal valves, metal plates) may be sufficiently cool in temperature to condense the ethanol vapor back into a liquid state in turbine sump 32. Along with ethanol, water from the surrounding soil, fuel product 14, or another source may also find its way into sumps 30, 32 in a vapor or liquid state, such as by dripping into sumps 30, 32 in a liquid state or by evaporating and then condensing in sumps 30, 32. Ethanol and/or water leaks into sumps 30, 32 may occur through various connection points in sumps 30, 32, for example. Ethanol and/or water may escape from ventilated sumps 30, 32 but may become trapped in unventilated sumps 30, 32.
In the presence of certain bacteria and water, ethanol that is present in fuel delivery system 10 may be oxidized to produce acetate, according to Reaction I below.
CH3CH2OH+H2O→CH3COO−+H++2H2 (I)
The acetate may then be protonated to produce acetic acid, according to Reaction II below.
CH3COO−+H+→CH3COOH (II)
The conversion of ethanol to acetic acid may also occur in the presence of oxygen according to Reaction III below.
2CH3CH2OH+O2→2CH3COOH+2H2O (III)
Acetic acid producing bacteria or AAB may produce acetate and acetic acid by a metabolic fermentation process, which is used commercially to produce vinegar, for example. Acetic acid producing bacteria generally belong to the Acetobacteraceae family, which includes the genera Acetobacter, Gluconobacter, and Gluconacetobacter. Acetic acid producing bacteria are very prevalent in nature and may be present in the soil around fuel delivery system 10, for example. Such bacteria may find their way into sumps 30, 32 to drive Reactions I-III above, such as when soil or debris falls into sumps 30, 32 or when rainwater seeps into sumps 30, 32.
The products of Reactions I-III above may reach equilibrium in sumps 30, 32, with some of the acetate and acetic acid dissolving into liquid water that is present in sumps 30, 32, and some of the acetate and acetic acid volatilizing into a vapor state. In general, the amount acetate or acetic acid that is present in the vapor state is proportional to the amount of acetate or acetic acid that is present in the liquid state (i.e, the more acetate or acetic acid that is present in the vapor state, the more acetate or acetic acid that is present in the liquid state).
Even though acetic acid is classified as a weak acid, it may be corrosive to fuel delivery system 10, especially at high concentrations. For example, the acetic acid may react to deposit metal oxides (e.g., rust) or metal acetates on metallic fittings of fuel delivery system 10. Because Reactions I-III are microbiologically-influenced reactions, these deposits in fuel delivery system 10 may be tubular or globular in shape.
To limit corrosion in fuel delivery system 10, a control system 100 and a corresponding monitoring method are provided herein. As shown in
Controller 102 of control system 100 illustratively includes a microprocessor 110 (e.g., a central processing unit (CPU)) and an associated memory 112. Controller 102 may be any type of computing device capable of accessing a computer-readable medium having one or more sets of instructions (e.g., software code) stored therein and executing the instructions to perform one or more of the sequences, methodologies, procedures, or functions described herein. In general, controller 102 may access and execute the instructions to collect, sort, and/or analyze data from monitor 104, determine an appropriate response, and communicate the response to output 106 and/or remediation system 108. Controller 102 is not limited to being a single computing device, but rather may be a collection of computing devices (e.g., a collection of computing devices accessible over a network) which together execute the instructions. The instructions and a suitable operating system for executing the instructions may reside within memory 112 of controller 102, for example. Memory 112 may also be configured to store real-time and historical data and measurements from monitors 104, as well as reference data. Memory 112 may store information in database arrangements, such as arrays and look-up tables.
Controller 102 of control system 100 may be part of a larger controller that controls the rest of fuel delivery system 10. In this embodiment, controller 102 may be capable of operating and communicating with other components of fuel delivery system 10, such as dispenser 12 (
Monitor 104 of control system 100 is configured to automatically and routinely collect data indicative of a corrosive environment in fuel delivery system 10. In operation, monitor 104 may draw in a liquid or vapor sample from fuel delivery system 10 and directly test the sample or test a target material that has been exposed to the sample, for example. In certain embodiments, monitor 104 operates continuously, collecting samples and measuring data approximately once every second or minute, for example. Monitor 104 is also configured to communicate the collected data to controller 102. In certain embodiments, monitor 104 manipulates the data before sending the data to controller 102. In other embodiments, monitor 104 sends the data to controller 102 in raw form for manipulation by controller 102. The illustrative monitor 104 is wired to controller 102, but it is also within the scope of the present disclosure that monitor 104 may communicate wirelessly (e.g., via an internet network) with controller 102.
Depending on the type of data being collected by each monitor 104, the location of each monitor 104 in fuel delivery system 10 may vary. Returning to the illustrated embodiment of
Output 106 of control system 100 may be capable of communicating an alarm or warning from controller 102 to an operator. Output 106 may include a visual indication device (e.g., a gauge, a display screen, lights, a printer), an audio indication device (e.g., a speaker, an audible alarm), a tactile indication device, or another suitable device for communicating information to the operator, as well as combinations thereof. Controller 102 may transmit information to output 106 in real-time, or controller 102 may store information in memory 112 for subsequent transmission or download to output 106.
Remediation system 108 of control system 100 may be capable of taking at least one corrective action to remediate the corrosive environment in fuel delivery system 10. Various embodiments of remediation system 108 are described below.
The illustrative output 106 and remediation system 108 are wired to controller 102, but it is also within the scope of the present disclosure that output 106 and/or remediation system 108 may communicate wirelessly (e.g., via an internet network) with controller 102. For example, to facilitate communication between output 106 and the operator, output 106 may be located in the operator's control room or office.
In operation, and as discussed above, controller 102 collects, sorts, and/or analyzes data from monitor 104, determines an appropriate response, and communicates the response to output 106 and/or remediation system 108. According to an exemplary embodiment of the present disclosure, output 106 warns the operator of a corrosive environment in fuel delivery system 10 and/or remediation system 108 takes corrective action before the occurrence of any corrosion or any significant corrosion in fuel delivery system 10. In this embodiment, corrosion may be prevented or minimized. It is also within the scope of the present disclosure that output 106 may alert the operator to the occurrence of corrosion in fuel delivery system 10 and/or remediation system 108 may take corrective action to at least avoid further corrosion.
Various factors may influence whether controller 102 issues an alarm or warning from output 106 that a corrosive environment is present in fuel delivery system 10 or becoming more likely to develop. Similar factors may also influence whether controller 102 instructs remediation system 108 to take corrective action in response to the corrosive environment. As discussed further below, these factors may be evaluated based on data obtained from one or more monitors 104.
One factor indicative of a corrosive environment includes the concentration of acidic molecules in fuel delivery system 10, with controller 102 issuing an alarm or warning from output 106 and/or activating remediation system 108 when the measured concentration of acidic molecules in fuel delivery system 10 exceeds an acceptable concentration of acidic molecules in fuel delivery system 10. The concentration may be expressed in various units. For example, controller 102 may activate output 106 and/or remediation system 108 when the measured concentration of acidic molecules in fuel delivery system 10 exceeds 25 ppm, 50 ppm, 100 ppm, 150 ppm, 200 ppm, or more, or when the measured concentration of acidic molecules in fuel delivery system 10 exceeds 25 mg/L, 50 mg/L, 100 mg/L, 150 mg/L, 200 mg/L, or more. At or beneath the acceptable concentration, corrosion in fuel delivery system 10 may be limited. Controller 102 may also issue an alarm or warning from output 106 and/or activate remediation system 108 when the concentration of acidic molecules increases at an undesirably high rate.
Another factor indicative of a corrosive environment includes the concentration of hydrogen ions in fuel delivery system 10, with controller 102 issuing an alarm or warning from output 106 and/or activating remediation system 108 when the measured concentration of hydrogen ions in fuel delivery system 10 exceeds an acceptable concentration of hydrogen ions in fuel delivery system 10. For example, controller 102 may activate output 106 and/or remediation system 108 when the hydrogen ion concentration causes the pH in fuel delivery system 10 to drop below 5, 4, 3, or 2, for example. Within the acceptable pH range, corrosion in fuel delivery system 10 may be limited. Controller 102 may also issue an alarm or warning from output 106 and/or activate remediation system 108 when the concentration of hydrogen ions increases at an undesirably high rate.
Yet another factor indicative of a corrosive environment includes the concentration of bacteria in fuel delivery system 10, with controller 102 issuing an alarm or warning from output 106 and/or activating remediation system 108 when the measured concentration of bacteria in fuel delivery system 10 exceeds an acceptable concentration of bacteria in fuel delivery system 10. At or beneath the acceptable concentration, the production of corrosive materials in fuel delivery system 10 may be limited. Controller 102 may also issue an alarm or warning from output 106 and/or activate remediation system 108 when the concentration of bacteria increases at an undesirably high rate.
Yet another factor indicative of a corrosive environment includes the concentration of water in fuel delivery system 10, with controller 102 issuing an alarm or warning from output 106 and/or activating remediation system 108 when the measured concentration of water in fuel delivery system 10 exceeds an acceptable concentration of water in fuel delivery system 10. At or beneath the acceptable concentration, the production of corrosive materials in fuel delivery system 10 may be limited. Controller 102 may also issue an alarm or warning from output 106 and/or activate remediation system 108 when the concentration of water increases at an undesirably high rate. The water may be present in liquid and/or vapor form. Liquid water in storage tank 16 may be measured with the low level water sensor described hereinbelow.
Controller 102 may be programmed to progressively vary the alarm or warning communication from output 106 as the risk of corrosion in fuel delivery system 10 increases. For example, controller 102 may automatically trigger: a minor alarm (e.g., a blinking light) when monitor 104 detects a relatively low acid concentration level (e.g., 5 ppm) in fuel delivery system 10 or a relatively steady acid concentration level over time; a moderate alarm (e.g., an audible alarm) when monitor 104 detects a moderate acid concentration level (e.g., 10 ppm) in fuel delivery system 10 or a moderate increase in the acid concentration level over time; and a severe alarm (e.g., a telephone call or an e-mail to the gas station operator) when monitor 104 detects a relatively high acid concentration level (e.g., 25 ppm) in fuel delivery system 10 or a relatively high increase in the acid concentration level over time.
The alarm or warning communication from output 106 allows the operator to manually take precautionary or corrective measures to limit corrosion of fuel delivery system 10. For example, if an alarm or warning communication is signaled from turbine sump 32 (
Even if no immediate action is required, the alarm or warning communication from output 106 may allow the operator to better plan for and predict when such action may become necessary. For example, the minor alarm from output 106 may indicate that service should be performed within about 2 months, the moderate alarm from output 106 may indicate that service should be performed within about 1 month, and the severe alarm from output 106 may indicate that service should be performed within about 1 week.
As discussed above, control system 100 includes one or more monitors 104 that collect data indicative of a corrosive environment in fuel delivery system 10. Each monitor 104 may vary in the type of data that is collected, the type of sample that is evaluated for testing, and the location of the sample that is evaluated for testing, as exemplified below.
In one embodiment, monitor 104 collects electrical data indicative of a corrosive environment in fuel delivery system 10. An exemplary electrical monitor 104a is shown in
In use, energy source 120 directs an electrical current through target material 122. When target material 122 is intact, sensor 124 senses the electrical current traveling through target material 122. However, when exposure to sample S causes target material 122 to corrode and potentially break, sensor 124 will sense a decreased electrical current, or no current, traveling through target material 122. It is also within the scope of the present disclosure that the corrosion and/or breakage of target material 122 may be detected visually, such as by using a camera as sensor 124. First monitor 104a may share the data collected by sensor 124 with controller 102 (
Another exemplary electrical monitor 104b is shown in
In another embodiment, monitor 104 collects elecrochemical data indicative of a corrosive environment in fuel delivery system 10. An exemplary electrochemical monitor (not shown) performs potentiometric titration of a sample that has been withdrawn from fuel delivery system 10. A suitable potentiometric titration device includes an electrochemical cell with an indicator electrode and a reference electrode that maintains a consistent electrical potential. As a titrant is added to the sample and the electrodes interact with the sample, the electric potential across the sample is measured. Potentiometric or chronopotentiometric sensors, which may be based on solid-state reversible oxide films, such as that of iridium, may be used to measure potential in the cell. As the concentration of acetate or acetic acid in the sample varies, the potential may also vary. The potentiometric titration device may share the collected data with controller 102 (
In yet another embodiment, monitor 104 collects optical data indicative of a corrosive environment in fuel delivery system 10. An exemplary optical monitor 104c is shown in
Optical monitor 104c may enable real-time, continuous monitoring of fuel delivery system 10 by installing light source 140, target material 142, and detector 144 together in fuel delivery system 10. To enhance the longevity of this real-time monitor 104c, light source 140 and/or detector 144 may be protected from any corrosive environment in fuel delivery system 10, unlike target material 142. For example, light source 140 and/or detector 144 may be contained in a sealed housing, whereas target material 142 may be exposed to the surrounding environment in fuel delivery system 10.
Alternatively, optical monitor 104c may enable manual, periodic monitoring of fuel delivery system 10. During exposure, target material 142 may be installed alone in fuel delivery system 10. During testing, target material 142 may be periodically removed from fuel delivery system 10 and positioned between light source 140 and detector 144. In a first embodiment of the manual monitor 104c, light source 140 and detector 144 may be sold as a stand-alone, hand-held unit that is configured to receive the removed target material 142. In a second embodiment of the manual monitor 104c, light source 140 may be sold along with a software application to convert the operator's own smartphone or mobile device into a suitable detecor 144. Detector 144 of monitor 104c may transmit information to controller 102 (
One suitable target material 142 includes a pH indicator that changes color when target material 142 is exposed to an acidic pH with H+ protons, such as a pH less than about 5, 4, 3, or 2, for example. The optical properties of target material 142 may be configured to change before the equipment of fuel delivery system 10 corrodes. Detector 144 may use optical fibers as the sensing element (i.e., intrinsic sensors) or as a means of relaying signals to a remote sensing element (i.e., extrinsic sensors).
In use, light source 140 directs a beam of light toward target material 142. Before target material 142 changes color, for example, detector 144 may detect a certain reflection, transmission (i.e., spectrophotometry), absorbtion (i.e., densitometry), and/or refraction of the light beam from target material 142. However, after target material 142 changes color, detector 144 will detect a different reflection, transmission, absorbtion, and/or refraction of the light beam. It is also within the scope of the present disclosure that the changes in target material 142 may be detected visually, such as by using a camera (e.g., a smartphone camera) as detector 144. Third monitor 104c may share the data collected by detector 144 with controller 102 (
Another suitable target material 142 includes a sacrificial, corrosive material that corrodes (e.g., rusts) when exposed to a corrosive environment in fuel delivery system 10. For example, the corrosive target material 142 may include copper or low carbon steel. The corrosive target material 142 may have a high surface area to volume ratio to provide detector 144 with a large and reliable sample size. For example, as shown in
In use, light source 140 directs a beam of light along an axis A toward the corrosive target material 142. Before target material 142 corrodes, detector 144 may detect a certain amount of light that passes from the light source 140 and through the open pores 143 of the illuminated target material 142 along the same axis A. However, as target material 142 corrodes, the material may visibly swell as rust accumulates in and around some or all of the pores 143. This accumulating rust may obstruct or prevent light from traveling through pores 143, so detector 144 (e.g., a photodiode) will detect a decreasing amount of light through the corroding target material 142. It is also within the scope of the present disclosure that the changes in target material 142 may be detected visually, such as by using a camera or another suitable imaging device as detector 144. Detector 144 may capture an image of the illuminated target material 142 and then evaluate the image (e.g., pixels of the image) for transmitted light intensity, specific light patterns, etc. As discussed above, third monitor 104c may share the data collected by detector 144 with controller 102 (
Another exemplary optical monitor 104c′ is shown in
The illustrative optical monitor 104c′ is generally cylindrical in shape and has a longitudinal axis L. In the illustrated embodiment of
The illustrative optical monitor 104c′ includes a reflective surface 500′ positioned downstream of light source 140′ and upstream of optical detector 144′, wherein the reflective surface 500′ is configured to reflect incident light from light source 140′ toward optical detector 144′. In the illustrated embodiment of
The illustrative optical monitor 104c′ also includes at least one printed circuit board (PCB) 502′ that mechanically and electrically supports light source 140′ and optical detector 144′. PCB 502′ may also allow light source 140′ and/or optical detector 144′ to communicate with controller 102 (
The illustrative optical monitor 104c′ further includes a cover 510′, an upper housing 512′, and a lower housing 514′. Lower housing 514′ may be removably coupled to upper housing 512′, such as using a snap connection 515′, a threaded connection, or another removable connection.
Upper housing 512′ contains light source 140′, optical detector 144′, and circuit board 502′. Upper housing 512′ may be hermetically sealed to separate and protect its contents from the potentially corrosive environment in fuel delivery system 10 (
Lower housing 514′ contains target material 142′ and reflective surface 500′. Reflective surface 500′ may be formed directly upon lower housing 514′ (e.g., a reflective coating) or may be formed on a separate component (e.g., a reflective panel) that is coupled to lower housing 514′. In the illustrated embodiment of
In use, and as shown in
Optical monitor 104c′ may be configured to detect one or more errors. If the light intensity detected by detector 144′ is too high (e.g., at or near 100%), optical monitor 104c′ may issue a “Target Material Error” to inform the operator that target material 142′ may be missing or damaged. To avoid false alarms caused by exposure to ambient light, such as when opening turbine sump 32 (
Optical monitor 104c′ may be combined with one or more other monitors of the present disclosure. For example, in the illustrated embodiment of
In still yet another embodiment, monitor 104 collects spectroscopic data indicative of a corrosive environment in fuel delivery system 10. An exemplary spectrometer (not shown) operates by subjecting a liquid or vapor sample from fuel delivery system 10 to an energy source and measuring the radiative energy as a function of its wavelength and/or frequency. Suitable spectrometers include, for example, infrared (IR) electromagnetic spectrometers, ultraviolet (UV) electromagnetic spectrometers, gas chromatography-mass spectrometers (GC-MS), and nuclear magnetic resonance (NMR) spectrometers. Suitable spectrometers may detect absorption from a ground state to an excited state, and/or fluorescence from the excited state to the ground state. The spectroscopic data may be represented by a spectrum showing the radiative energy as a function of wavelength and/or frequency. It is within the scope of the present disclosure that the spectrum may be edited to hone in on certain impurites in the sample, such as acetate and acetic acid, which may cause corrosion in fuel delivery system 10, as well as sulfuric acid, which may cause odors in fuel delivery system 10. As the impurities develop in fuel delivery system 10, peaks corresponding to the impurities would form and/or grow on the spectrum. The spectrometer may share the collected data with controller 102 (
In still yet another embodiment, monitor 104 collects microbial data indicative of a corrosive environment in fuel delivery system 10. An exemplary microbial detector (not shown) operates by exposing a liquid or vapor sample from fuel delivery system 10 to a fluorogenic enzyme substrate, incubating the sample and allowing any bacteria in the sample to cleave the enzyme substrate, and measuring fluorescence produced by the cleaved enzyme substrate. The concentration of the fluorescent product may be directly related to the concentration of acetic acid producing bacteria (e.g., Acetobacter, Gluconobacter, Gluconacetobacter) in the sample. Suitable microbial detectors are commercially available from Mycometer, Inc. of Tampa, Fla. The microbial detector may share the collected data with controller 102 (
To minimize the impact of other variables in monitor 104, a control sample may be provided in combination with the test sample. For example, monitor 104c of
As discussed above, control system 100 of
In a first embodiment, remediation system 108 is configured to ventilate turbine sump 32 of fuel delivery system 10. In the illustrated embodiment of
The first ventilation passageway 160 illustratively includes an inlet 162 in communication with the surrounding atmosphere and an outlet 164 in communication with the upper vapor space (i.e., top) of turbine sump 32. In
The second ventilation or siphon passageway 170 is illustratively coupled to a siphon port 26 of pump 20 and includes an inlet 172 positioned in the lower vapor space (i.e., middle) of turbine sump 32 and an outlet 174 positioned in storage tank 16. A control valve 176 (e.g., automated valve, flow orifice, check valve, or combination thereof) may be provided in communication with controller 102 (
When pump 20 is active (i.e., turned on) to dispense fuel product 14, pump 20 generates a vacuum at siphon port 26. The vacuum from pump 20 draws vapor (e.g., fuel/air mixture) from turbine sump 32, directs the vapor to the manifold of pump 20 where it mixes with the circulating liquid fuel flow, and then discharges the vapor into storage tank 16 through the second ventilation passageway 170. As the vacuum in turbine sump 32 increases, control valve 166 may also open to draw fresh air from the surrounding atmosphere and into turbine sump 32 through the first ventilation passageway 160. When pump 20 is inactive (i.e., turned off), controller 102 (
The vapor pressure in turbine sump 32 and/or storage tank 16 may be monitored using the one or more pressure sensors (not shown) and controlled. To prevent over-pressurization of storage tank 16, for example, the vapor flow into storage tank 16 through the second ventilation passageway 170 may be controlled. More specifically, the amount and flow rate of vapor pulled into storage tank 16 through the second ventilation passageway 170 may be limited to be less than the amount and flow rate of fuel product 14 dispensed from storage tank 16. In one embodiment, control valve 176 may be used to control the vapor flow through the second ventilation passageway 170 by opening the second ventilation passageway 170 for limited durations and closing the second ventilation passageway 170 when the pressure sensor detects an elevated pressure in storage tank 16. In another embodiment, the restrictor (not shown) may be used to limit the vapor flow rate through the second ventilation passageway 170 to a level that will avoid an elevated pressure in storage tank 16.
Other embodiments of the first ventilation passageway 160 are also contemplated. In a first example, the first ventilation passageway 160 may be located in the interstitial space between a primary pipe and a secondary pipe (e.g., XP Flexible Piping available from Franklin Fueling Systems Inc. of Madison, Wis.) using a suitable valve (e.g., APT™ brand test boot valve stems available from Franklin Fueling Systems Inc. of Madison, Wis.). In a second example, the first ventilation passageway 160 may be a dedicated fresh air line into turbine sump 32. In a third example, the first ventilation passageway 160 may be incorporated into a pressure/vacuum (PV) valve system. Traditional PV valve systems communicate with storage tank 16 and the surrounding atmosphere to help maintain proper pressure differentials therebetween. One such PV valve system is disclosed in U.S. Pat. No. 8,141,577, the disclosure of which is expressly incorporated herein by reference in its entirety. In one embodiment, the PV valve system may be modified to pull fresh air through turbine sump 32 on its way into storage tank 16 when the atmospheric pressure exceeds the ullage pressure by a predetermined pressure differential (i.e., when a sufficient vacuum exists in storage tank 16). In another embodiment, the PV valve system may be modified to include a pair of tubes (e.g., coaxial tubes) in communication with the surrounding atmosphere, wherein one of the tubes communicates with storage tank 16 to serve as a traditional PV vent when the ullage pressure exceeds the atmospheric pressure by a predetermined pressure differential, and another of the tubes communicates with turbine sump 32 to introduce fresh air into turbine sump 32.
Other embodiments of the second ventilation passageway 170 are also contemplated. In a first example, instead of venting the fuel/air mixture from turbine sump 32 into storage tank 16 as shown in
In a second embodiment, remediation system 108 is configured to irradiate bacteria in turbine sump 32 of fuel delivery system 10. In the illustrated embodiment of
In a third embodiment, remediation system 108 is configured to filter water from fuel product 14. An exemplary water filtration system 200 is shown in
Water filter 204 is configured to separate water, including emulsified water and free water, from fuel product 14. Water filter 204 may also be configured to separate other impurities from fuel product 14. Water filter 204 may operate by coalescing the water into relatively heavy droplets that separate from the relatively light fuel product 14 and settle at the lower end of water filter 204. Incoming fuel pressure drives fuel radially outwardly through the sidewall of filter element 207 (
The illustrative water filtration system 200 also includes one or more inlet valves 203 to selectively open and close the fuel inlet passageway 202 and one or more drain valves 209 to selectively open and close the water removal passageway 208. In certain embodiments, valves 203, 209 are solenoid valves that are controlled through controller 102. In other embodiments, valves 203, 209 are manual valves that are manually controlled by a user. In the embodiment of
In operation, water filtration system 200 circulates fuel product 14 through water filter 204. Water filtration system 200 may operate at a rate of approximately 15 to 20 gallons per minute (GPM), for example. When pump 20 operates with inlet valve 203 open, pump 20 directs some or all of fuel product 14 from storage tank 16, through port 27 of pump 20, through the open fuel inlet passageway 202, and through water filter 204. If a customer is operating dispenser 12 (
The clean or filtered fuel product 14 that is discharged by water filter 204, such as rising to the upper end of water filter 204, may be returned continuously to storage tank 16 via the fuel return passageway 206. The filtered fuel product 14 may be returned to storage tank 16 in a dispersed and/or forceful manner that promotes circulation in storage tank 16, which prevents debris from settling in storage tank 16 and promotes filtration of such debris. By returning the filtered fuel product 14 to storage tank 16, water filtration system 200 may reduce the presence of water and avoid formation of a corrosive environment in fuel delivery system 10 (
The separated water product that is discharged by water filter 204, such as by settling at the lower end of water filter 204, may be drained via the water removal passageway 208 when drain valve 209 is open. The separated water product may be directed out of turbine sump 32 and above grade for continuous removal, as shown in
Referring to
The illustrative water filtration systems 200, 200′ of
Turning to
As fuel is withdrawn from tank 16 by operation of pump 20, a portion of the fuel which would otherwise be delivered to dispenser 12 via delivery line 18 is instead diverted to fuel inlet passageway 202. In an exemplary embodiment, this diverted flow may be less than 15 gallons/minute, such as between 10 and 12 gallons/minute. This diverted flow of pressurized fuel passes through eductor 230, as shown in
Filtration uptake line 234 is connected to vacuum port 232 and extends downwardly into tank 16, such that filtration uptake line 234 draws fuel from the bottom of tank 16. In an exemplary embodiment, gap G2 between the inlet of line 234 and the bottom surface of tank 16 is zero or near-zero, such that all or substantially all water or sediment which may be settled at the bottom of tank 16 is accessible to filtration uptake line 234. For example, line 234 may be a rigid or semi-rigid tube with an inlet having an angled surface formed, e.g., by a cut surface forming a 45-degree angle with the longitudinal axis of the tube. This angled surface forms a point at the inlet of line 234 which can be lowered into abutting contact with the lower surface of tank 16, while the open passageway exposed by the angled surface allows the free flow of fuel into line 234. Other inlet configuration may also be used for line 234, including traditional inlet openings close to, but not abutting, the lower surface of the tank.
By contrast to the zero or near-zero gap G2 for filtration uptake line 234, a larger gap G1 is formed between the intake of fuel uptake line 19 and the bottom surface of tank 16. For example, the intake opening to submersible pump 24 (
The illustrative filtration system 200′ also achieves this dual mitigation/prevention functionality with low-maintenance operation, by using eductor 230 to convert the operation of pump 20 into the motive force for the operation of system 200′. In particular, a single only pump 20 used in conjunction with system 200′ both provides clean fuel to dispenser(s) 12 via delivery line 18, while also ensuring that any accumulation of contaminated fuel at the bottom of tank 16 is remediated by uptake into filtration line 234 and subsequent delivery to filter 204. The lack of a requirement of extra pumping capacity lowers both initial cost and running costs. Moreover, the additional components of system 200′, such as eductor 230, filter 204, valves 203, 209 and water tank 210, all require little to no regular maintenance.
Filtration system 200′ also achieves its dual mitigation/prevention function in an economically efficient manner by using an existing pump to power the filtration process, while avoiding the need for large-capacity filters. As described in detail above, filtration system 200′ is configured to operate in conjunction with the normal use of fuel delivery system 10 (
An alternative water filtration system 200A is shown in
However, filtration system 200A includes filter 204A utilizing an oil/water separation tank 205A to accomplish the primary removal of water from fuel product 14, rather than a filter element 207 as described above with respect to filtration system 200′. In addition, the routing of fuel flows and the use of eductor 230A in generating the motive force for fuel filtration contrasts with system 200′, as described in further detail below.
Similar to system 200′, filtration system 200A uses a diverted flow of fuel from submersible turbine pump 20 as the primary driver of fluid flows through eductor 230, such that pump 20 provides the primary motive force for filtration. In the illustrated embodiment of
As best seen in
In operation, filter 204A will operate in a steady state in which tank 205A is always filled with fluid drawn from tank 16. New fluid received from uptake line 234A is deposited at the bottom of filter 204A via dip tube 214A, and an equal flow of fluid is discharged from the top of filter 204A via return passageway 216. In an exemplary embodiment, the flow rate through filter 204A is slow enough, relative to the internal volume of filter 204A, to allow for natural separation and stratification of water and fuel within the volume of filter 204A, such that any water contained in the incoming fuel remains at the bottom of filter 204A and only clean fuel is present at the top of filter 204A.
In an exemplary embodiment, the flow rate through filter 204A is controlled with a combination of vacuum pressure from eductor 230A and the cross-sectional size of the channel defined by dip tube 214A. These two variables may be controlled to produce a nominal flow rate (i.e., throughput) through filter 204A, as well as a fluid velocity through dip tube 214A. In particular, the vacuum level produced by eductor 230A is positively correlated with both flow rate and fluid velocity, while the cross-section of dip tube 214A is positively correlated with flow rate but negatively correlated with fluid velocity. To preserve the ability for natural fluid stratification and avoid turbulence at the bottom of filter 204A, flow rate should be kept low enough to allow incoming fuel to remain coagulated as a volume of fuel separate from any surrounding water, rather than separating out into smaller droplets that would need to re-coagulate before “floating” out of the water layer. For example, an exemplary fluid velocity which produces such favorable fluid mechanics for filter 204A may be as high as 1.0, 2.0, 3.0 or 4.0 ft/second, such as about 3.3 ft/second.
In one exemplary arrangement, oil/water separation tank 205A has a nominal volume of 1.1 gallons, dip tube 214A defines a fluid flow cannula with an internal diameter of 0.25 inches, and vacuum level generated by eductor 230A is maintained between 12-15 inHg. This configuration produces a flow rate of about 0.50 gallons per minute (gpm) and an incoming fluid velocity (at the exit of dip tube 214A into the lower portion of filter 204A) of about 3.27 ft/sec. In this arrangement, throughput of filter 204A is maximized while preventing unfavorable fluid flow characteristics as described above. Moreover, if vacuum is increased to 18 inHg, aeration of the incoming fuel can create unfavorable effects, such as foaming of diesel fuel.
Additional elements may be provided create operator control (or control via controller 102, shown in
The size of filter 204A may be scaled up or down to accommodate any desired filtration capacity, and the particular configuration of filtration system 200A can be modified in keeping with the principles articulated above. For example, increasing the cross-section of dip tube 214A decreases fluid velocity, such that the nominal flow rate through filtration uptake line 234A may be increased without producing an unfavorable fluid velocity. Similarly, the nominal volume of tank 205A may be decreased if no turbulence is experienced in the stratification of the contained fluids, or may be increased in order to accommodate a modest level of turbulence.
If water is present in the fluid drawn from the bottom of storage tank 16 through uptake line 234A (
If sufficient water accumulates within filter 204A, the water reaches high-level water sensor 220A (
When contacted with water, sensor 220A activates and sends a signal to controller 102 (
In an exemplary embodiment, check valve 218A may be provided in uptake line 234 between tank 16 and uptake valve 212A, in order to provide additional insurance against a backflow of water into tank 16 during water withdrawal. Check valve 218A also guards against any potential siphoning of water from filter 204A, which may be located physically above tank 16, into tank 16 via dip tube 214A and filtration uptake line 234A.
The water withdrawal process may be calibrated, either by a human operator or controller 102 (
Turning now to
However, filter 204B of filtration system 200B includes sensor valve assembly 244, shown in
As best seen in
Like filtration systems 200, 200′ and 200A described above, filtration system 200B may also be applied to other sumps or parts of fuel delivery system 10, such as dispenser sump 30 (
Fuel flows downstream to fuel return passageway 206B to return to the underground storage tank 16 (
Turning now to
During the steady-state, low-water operation depicted by
In
The ceasing of fluid flow through passageway 216B also stops fluid flow at the vacuum port of eductor 230. In addition, the flow of fluid may reduce before ceasing completely. Sensor 242 detects the reduction and/or cessation of fluid flow, and issues a signal (or a lack of a signal) indicative of cessation of flow or of a reduction of flow below a predetermined threshold nominal value. Controller 102 may issue an alert and/or initiate remediation when sensor 242 indicates the high level of water W shown in
As noted above, water filter 204B may be located within a sump (e.g., sump 32 shown in
Turning now to
Like filtration system 200B, the components of filtration system 200C are sized and configured to fit within sump 32, together with a typical set of existing components including turbine pump 22, delivery lines 18 and associated shutoff valves and ancillary structures, although sump 32 is not illustrated with filtration system 200C. Unlike filtration system 200B, mounting bracket 240 is not needed, as filter 204C is directly supported atop cover 602 by rods 600 (see also,
Like filtration systems 200, 200′, 200A and 200B described above, filtration system 200C may also be applied to other sumps or parts of fuel delivery system 10, such as dispenser sump 30 (
Fuel flows downstream to fuel return passageway 206C to return to underground storage tank 16 (
Turning now to
In the embodiment of
Flow/water level sensor subassembly 608 includes water float 610 which, similar to float 248 described with reference to water filtration system 200B, has a density below that of water W, but above that of the hydrocarbon fuel stratified above water W as described above. Like float 248, float 610 can be made in accordance with U.S. Pat. No. 8,878,682, the entire disclosure of which is incorporated by reference above. Water float 610 is buoyant on water W, as described above; therefore, water float 610 can be utilized to provide an output indicative of the level of water W in tank 604 to allow a fueling station manager to timely schedule removal of water W from tank 604. In certain exemplifications thereof, water float 610 including a two-piece plastic housing held together with a low density float material. The float assembly will house magnet 616 (described below) and ballast washers used to set the correct buoyancy.
In the embodiment illustrated in
The water level output from probe 608 may be provided to a tank gauge (e.g., controller 102), which can be programmed to provide an indication to a fuel station manager of the water level in tank 604. The tank gauge may also provide an alarm when tank 604 is full of water. Water can be removed from tank 604 via water removal passageway 208C. In certain embodiments, water removal passageway 208C is a capped metal tube. To remove water, the cap is removed and a length of flexible tubing is inserted through the internal diameter of the metal tube. The flexible tubing could be connected to a hand pump or other pumping device to remove the water from tank 604. The metal tube can feature a breather hole to allow air to enter the top of the separator vessel as the water is pumped out.
In addition to providing an output indicative of the level of water W in tank 604, flow/water level sensor subassembly 608 is further operable to detect and report the presence or absence of flow through inlet 606. Specifically, flow/water level sensor subassembly 608 includes flow sensing shuttle 618 which cooperates with the magnetostrictive transducer of probe shaft 612 to alternatively signal flow and no-flow conditions through inlet 606.
Flow/water level sensor subassembly 608 includes isolator 622 fixed to probe shaft 612. Isolator 622 includes radially inward flange 624 (
Prior to placing washer 632 and E-Clip 634 in fixed position, as described above, flow sensing shuttle 618 is inserted into central opening 636 of isolator 622. Particularly, flow sensing shuttle 618 is positioned over interior wall 638 of isolator 622 such that flow sensing shuttle 618 is freely reciprocatable along longitudinal axis L (
In the use position of flow/water level sensor subassembly 608 shown in
Flow/water level sensor subassembly 608 is positioned for use with the distal end of isolator 622 indexing probe 608 to filter 204C. Specifically, probe 608 is inserted into tank 604 until the distal end of isolator 622 rests atop the floor of tank 604. In this position, flow from the inside of isolator 622 to the exterior of isolator 622 is allowed by passages 650 (
Flow sensing shuttle 618 carries magnet 620. In the exemplification shown, magnet 620 comprises a ring magnet. The magnetostrictive transducer of probe shaft 612 is able to sense the position of flow sensing shuttle 618 along probe shaft 612 via magnet 620 and provide the same in an output signal. This signal may be received by controller 102, for example, or may simply be received by an indicator such as bank of lights. In an exemplary embodiment, flow sensing shuttle 618 has a travel of ⅛ inch between the flow and no-flow positions. Spring 640 not only facilitates actuation of flow sensing shuttle 618, but also facilitates proper operative placement of probe 608 without requiring exacting tolerances. Specifically, placement of flow sensing shuttle 618 atop plunger 646 may release some of the compression of compression spring 640 when probe 608 is operatively positioned. In certain exemplary embodiments, flow sensing shuttle will work together with a tank gauge (e.g., controller 102) to alert a fuel station manager if the filter flow is not operating properly. Specifically, if fuel is flowing from UST 16 for dispensing through dispensers 12 such that educator 230 should be drawing flow through tank 604 (or filtration system 200C is otherwise running) and flow sensing shuttle 618 should thereby be actuated to its flow sensing position, the tank gauge (e.g., controller 102) or an indicator will indicate a fault if probe 608 does not detect flow sensing shuttle 618 in the flow sensing position. The fault may be an advisement that maintenance needs to be performed on the system.
Probe shaft 612 may further incorporate a temperature sensor 617, such as one or more thermistors to combat freezing within tank 604. As noted above, water filter 204C may be located within a sump (e.g., sump 32 shown in
Probe 608 provides a single device (i.e., subassembly) capable of monitoring all relevant operational parameters of filtration system 200C.
Controller 102 (
The use of the separator-type filters 204A, 204B allow filtration systems 200A, 200B to be virtually maintenance free, with the only regular maintenance task being the periodic removal of accumulated water from filter 204A, 204B. Even this maintenance task may be automated as noted above. In contrast to filtration system 200′, which uses a substrate-type filter 207 as described in detail above, filtration systems 200A, 200B have no substrate filters which would require replacement or service.
The separator-type filters 204A, 204B may also be sized to fit existing or newly-installed sumps, such as turbine sump 32 of fuel delivery system 10 (
However, it is contemplated that a filter substrate, such as filter 207, or any other coalescing filter element, particulate filter element, or a combination thereof may be used inside filters 204A, 204B, as required or desired for a particular application.
As discussed herein, filtration systems 200, 200′, 200A and 200B utilize submersible pump 20, already existing as a component of fuel delivery system 10, as a motive fuel flow source to power a vacuum generating device, illustrated with respect to the various embodiments as eductor 230. Although the illustrative filtration systems 200′, 200A, 200B use eductor 230 to draw the contaminated fuel from the bottom of tank 16, other equipment may be used to perform this operation, such as another type of venturi device or a supplemental pump (in addition to pump 20). For example, a flow from the pump 20, including a primary and/or diverted flow, may be used to drive an impeller which drives a separate pump for filtration, similar to the operation of a turbocharger system of an internal combustion engine, which uses exhaust gases to power an impeller. The dedicated filtration pump powered by the flow of the primary pump may then be used in place of eductor 230 to drive filtration flows as described herein.
Yet another alternative is to use a dedicated, electrically powered pump for filtration flows. This dedicated pump may be used in place of eductor 230 or 230A as shown in
In still another alternative arrangement, pump 20 may be configured as a diaphragm-type pump, in which a primary stroke of the pump is used for delivery of fuel to dispenser 12 via delivery line 18 (
Referring next to
In step 302 of method 300, controller 102 determines whether a predetermined start time has been reached. The start time may occur at a desired time, preferably outside of high-demand fuel dispensing hours (e.g., 4:30 to 7:30 AM), and with a desired frequency. For example, the start time may occur daily at about 8:00 PM. When the start time of step 302 is reached, method 300 continues to step 304. It is also within the scope of the present disclosure that method 300 may be initiated based on an input from one or more monitors 104 (
In step 304 of method 300, controller 102 operates water filter 204 to filter fuel product 14. As discussed above, this filtering step 304 may involve opening inlet valve 203 of fuel inlet passageway 202 and activating pump 20. After passing through water filter 204, the filtered fuel product 14 may be returned continuously to storage tank 16 via fuel return passageway 206.
In step 306 of method 300, controller 102 determines whether a predetermined cycle time has expired. The cycle time may vary. For example, the cycle time may be about 1-10 hours, more specifically about 7-9 hours, and more specifically about 8 hours. If the cycle time has expired, method 300 continues to step 307, in which controller 102 closes inlet valve 203 of fuel inlet passageway 202 to water filter 204 and resets the cycle time before returning to step 302 to await a new start time. If the cycle time has not yet expired, method 300 continues to step 308.
In step 308 of method 300, controller 102 determines whether a water level in water filter 204 is too high. Step 308 may involve communicating with the high-level water sensor 220 in water filter 204. If the high-level water sensor 220 detects water (i.e., activates), method 300 continues to steps 310 and 312. If the high-level water sensor 220 does not detect water (i.e., deactivates), method 300 skips steps 310 and 312 and continues to step 314.
In step 310 of method 300, controller 102 drains the separated water product from water filter 204. As discussed above, this draining step 310 may involve opening drain valve 209 of water removal passageway 208. From step 310, method continues to step 312.
In step 312 of method 300, controller 102 determines whether a water level in water filter 204 is sufficiently low. Step 312 may involve communicating with the low-level water sensor 222 in water filter 204. If the low-level water sensor 222 still detects water (i.e., activates), method 300 returns to step 310 to continue draining water filter 204. Once the low-level water sensor 222 no longer detects water (i.e., deactivates), method 300 continues to step 314. Controller 102 may initiate an alarm if the draining step 310 is performed for a predetermined period of time without deactivating the low-level water sensor 222. Controller 102 may also initiate an alarm if a discrepancy exists between the high-level water sensor 220 and the low-level water sensor 222, specifically if the high-level water sensor 220 detects water (i.e., activates) but the low-level water sensor 222 does not detect water (i.e., deactivates).
In step 314 of method 300, controller 102 determines whether a water level in storage tank 210 is too high. Step 314 may involve communicating with the high-level water sensor 224 in storage tank 210. Step 314 may also involve calculating the volume of water contained in storage tank 210 based on prior draining steps 310 from water filter 204. This volume calculation may involve logging the number of draining steps 310 from water filter 204 triggered by the high water-level sensor 220 and determining the known volume of water drained between sensors 220 and 222 during each draining step 310. If the high-level water sensor 224 does not detect water (i.e., deactivates) or the calculated water volume inside storage tank 210 is lower than a predetermined limit, method 300 returns to step 304 to continue operating water filter 204. If the high-level water sensor 224 detects water (i.e., activates) or the calculated water volume inside storage tank 210 reaches the predetermined limit, method 300 continues to step 316.
In step 316 of method 300, controller 102 initiates an alarm or sends another communication requiring storage tank 210 to be emptied and replaced. Controller 102 also closes inlet valve 203 of fuel inlet passageway 202 and resets the cycle time. After storage tank 210 is emptied and replaced, controller 102 returns to step 302 to await a new start time.
In a fourth embodiment, remediation system 108 is configured to control the humidity in turbine sump 32 of fuel delivery system 10. In the illustrated embodiment of
The above-described embodiments of remediation system 108 may be provided individually or in combination, as shown in
Corrosion mitigation/prevention can be implemented with a water level sensor providing a signal to controller 102 to activate water filtration systems 200, 200′, 200A and/or 200B (e.g., implemented by method 300). Particularly, a threshold amount of water in storage tank 16 may trigger operation of a corrosion mitigation/prevention system such as one or more of the systems described in this document. Low level water sensors to trigger operation of a corrosion mitigation/prevention system are exemplified in
Water level sensors are sometimes used to prevent water from being pumped by pump 20 to a vehicle. In these circumstances, the water level sensor merely needs to signal a water level approaching the intake to pump 20. Typically, the pump intake is several inches above the floor of storage tank 16, allowing a relatively imprecise water sensor (for example one that is not triggered in less than 3 inches of water) to be used. So long as the water sensor triggers a shutdown of the system before the water can reach the pump intake, these systems successfully prevent transfer of water in storage tank 16 from entering a vehicle. Corrosion can be triggered by much less water, however.
Water level sensors implemented to prevent water from being taken-up by pump 20 cannot sense a water level in storage tank 16 of less than 1 inch; however, much lower levels can trigger acidic corrosion. The present disclosure provides embodiments of water sensor 700 capable of greater precision (i.e., able to sense lower water levels).
Referring to
Magnetostrictive probes installed in fuel tanks work on the principle that sound, moving down a nichrome wire positioned nominally down the center of the probe shaft, maintains a constant velocity despite any encountered temperature differences. Magnetic forces can act on the nichrome wire to cause a sound wave reaching a magnet, e.g., in a float, to generate electricity in the nichrome wire. The time between the start of the sound pulse and the triggered electrical pulse is used to determine the position of the magnet (for example, a magnet in a product or water float).
When using a float riding along a probe shaft such as the embodiment of
Float 704 includes base 708, which, in an exemplification thereof, carries the float magnet previously described. Base 708 comprises a toroid having a central aperture through which probe shaft 712 is positioned. Each wing 706 is pivotally secured to base 708 by a pivot pin 710 displaced radially outwardly from the central aperture through which probe shaft 712 is positioned. Owing to this positioning of pivot pins 710 and the geometry of wings 706, wings 706 cannot interfere with the travel of float 704 along probe shaft 712.
Each wing 706 has an extended position as illustrated in
Pivot pins 710 pivotally connect wings 706 to base 708 and allow wings 706 to rotate between the extended position of
Without a buoyant or other force acting on wings 706, gravity will position wings 706 in the retracted position illustrated in
In the extended position of wings 706, float 704 is placed adjacent to or atop the floor of storage tank 16 in a use position. The use position may correspond to float 704 abutting, at least in part (e.g., the radially distal portions of wings 706), the floor of storage tank 16 or being spaced a distance of ¼ inch or less from the bottom of storage tank 16. For example, float 704 may be spaced no more than 1/16, ⅛, 3/16 or ¼ inch from the floor of storage tank 16 in the use position, with these distances or any distances therebetween being considered to place float 704 “adjacent” to the floor of storage tank 16.
Referring to
In use, probe shaft 712 is communicatively connected to controller 102 or an indicator to relay a water measurement and/or alarm to a user. A threshold measured water level may signal actuation of filtration systems 200, 200′, 200A, or 200B. A threshold measured water level may also signal corrosion mitigation in the form of water removal from storage tank 16 by direct pumping from the floor of storage tank 16 or other mechanisms.
The embodiments of water float 1704, 1704′ illustrated in
Water float 1704, 1704′ is particularly useful with a datum magnet at distal end 1705 of magnetostrictive probe shaft 1712 because frame 1701, 1701′ ensures that water float magnet 1703, 1703′ is always spaced a minimum of about 3.0 inches from the datum magnet at distal end 1705 of magnetostrictive probe shaft 1712. If 2 magnets are closer than about 3.0 inches along magnetostrictive probe shaft 1712, then the probe will not be able to function properly by identifying the position of the 2 magnets. Frame 1701, 1701′ acts as a spacer to space water float magnet 1703, 1703′ from toroidal float base 1708, 1708′ to allow for measuring low levels of water (as that term is further described herein) in UST 16.
Both fuel float 1709 and water float 1704, 1704′ have features to facilitate ease in movement away from the positions illustrated in
Water float 1704, 1704′ similarly features water float feet 1725, 1725′ as illustrated in
In the embodiment of water float 1704′ illustrated in
With frame 1701, 1701′ secured to float base 1708, 1708′, water float feet 1725, 1725′ extend distally (along longitudinal axis L1, L1′) from float base 1708, 1708′ and each nominally present point contact with foot 1706. Foot 1706 can be positioned atop floor 1707 of UST 16 as illustrated, e.g., in
Frame 1701, 1701′ also includes frame spacers 1729, 1729′ extending radially inward therefrom. Frame spacers 1729, 1729′ nominally present point contact with magnetostrictive probe shaft 1712 to decrease friction between frame 1701, 1701′ and magnetostrictive probe shaft 1712. With each frame half 1701a, 1701b or 1701a′, 1701b′ presenting four frame spacers 1729, 1729′, frame 1701, 1701′ nominally contacts magnetostrictive probe shaft 1712 at four points during reciprocation along its travel.
Fuel float 1709 is designed to be buoyant in fuel, such as diesel fuel having a specific gravity of about 0.8 to 0.9. Water float 1704, 1704′ is designed to be buoyant in water, which has a specific gravity of 1.0, by definition. More specifically, the density of water float 1704 is such that is will sink in diesel fuel (and, of course, lower specific gravity motor fuel products such as gasoline), but will be buoyant in a low level of water, e.g., no more than 0.25 inches of water and, more particularly, in as little as 0.060 inches of water collected at the bottom of UST 16. In exemplary embodiments, UST 16 is a cylindrical tank, as illustrated in
To space water float magnet 1703, 1703′ about 3.0 inches from the datum magnet at distal end 1705 of mangetostrictive probe shaft 1712 and maintain the density necessary to be buoyant on no more than 0.25 inches of water, frame 1701, 1701′ is constructed of a low density material. In one exemplary embodiment, frame 1701 is constructed of Zytel HTN51G35HSL BK083 available from Dupont and described in detail on the spec sheet filed in an IDS on even date herewith, the entire contents of which are hereby expressly incorporated by reference herein. As illustrated in the
In an exemplification of the present disclosure, frame 1701, 1701′ has a total height of about 3.2 inches, with top end 1719, 1719′ and bottom end 1731, 1731′ each being about 0.32 inches and 0.44 inches high, respectively, with frame segments 1713, 1713′ spanning top end 1719, 1719′ and bottom end 1731, 1731′ and having a length of about 2.4 inches. Frame segments 1713, 1713′ extend about longitudinal axis L1, L1′ to a diameter of about 0.92 inches or about 1 inch. This diameter defines the lateral maximum extent of frame 1701, 1701′.
Frame 1701, 1701′ comprises two nominally identical frame halves 1701a, 1701b or 1701a′, 1701b′. Each frame half 1701a, 1701b or 1701a′, 1701b′ includes a central vertical frame segment 1713, 1713′ having a width of about 0.115 inches and a depth of about 0.1 inches. Each frame half 1701a, 1701b or 1701a′, 1701b′ also includes and a central horizontal frame segment 1713, 1713′ having a height of about 0.125 inches and a depth of about 0.1 inches. Each frame half 1701a, 1701b or 1701a′, 1701b′ also includes a pair of vertical segments 1713, 1713′, each accommodating one of attachment aperture 1717, 1717′ (described in more detail below) or attachment boss 1715, 1715′ (described in more detail below). The vertical segments 1713, 1713′, each have a width of about 0.09 inches and a depth of about 0.1 inches.
Each frame half 1701a, 1701b or 1701a′, 1701b′ includes a pair of attachment bosses 1715, 1715′ and corresponding attachment apertures 1717, 1717′. The attachment bosses 1715, 1715′ of frame half 1701a, 1701a′ are positioned to be received in the attachment apertures 1717, 1717′ of frame half 1701b, 1701b′, while the attachment bosses 1715, 1715′ of frame half 1701b, 1701b′ are simultaneously received in the attachments apertures 1717, 1717′ of frame half 1701a, 1701a′. In one exemplary embodiment, attachment bosses 1715, 1715′ form an interference fit with the walls forming attachment apertures 1717, 1717′.
Top end 1719 of each frame half 1701a, 1701b or 1701a′, 1701b′ includes magnet carrier 1721, 1721′ comprising an annular channel sized to receive water float magnet 1703, 1703′. Water float magnet 1703, 1703′ is an annular ring having an inner diameter sized larger than the outer diameter of magnetostrictive probe shaft 1712. The outer diameter of water float magnet 1703, 1703′ is sized nominally congruent to the annular channel formed by magnet carriers 1721, 1721′ of frame halves 1701a, 1701b or 1701a′, 1701b′. Frame halves 1701a, 1701b or 1701a′, 1701b′ are assembled one to the other as described above, with water float magnet 1703, 1703′ positioned to be received by magnet carriers 1721, 1721′. When frame halves 1701a, 1701b or 1701a′, 1701b′ are assembled as illustrated, e.g., in
Bottom end 1731, 1731′ of each frame half 1701a, 701b or 1701a′, 1701b′ includes ballast receiver 1733, 1733′ sized to receive one or more of ballast rings 1735. Ballast receivers 1733, 1733′ cooperate to define an annular groove when frame halves 1701a, 1701b or 1701a′, 1701b′ are joined together to form frame 1701, 1701′. “Ballast receiver” is used herein to described the combined structure formed by the cooperation of both ballast receivers 1733, 1733′ identified in the illustrations. Ballast receiver 1733, 1733′ defines an inner diameter sized to accommodate one or more ballast rings 1735, 1735′. The outer diameter of each ballast ring 1735, 1735′ is nominally congruent to the inner diameter of ballast receiver 1733, 1733′, but just undersized enough to allow for easy insertion of ballast rings 1735, 1735′ into ballast receiver 1733, 1733′ in a radial direction. The inner diameters of ballast rings 1735, 1735′ are nominally equal in size, but each ballast ring may have a different height to impart a different mass of ballast.
Ballast receiver 1733, 1733′ also defines a height along longitudinal axis L1, L1′. The height of ballast receiver 1733, 1733′ is sufficient to accommodate a plurality of ballast rings 1735, 1735′. Because the specific gravity of certain motor fuels, e.g., light diesel, is close to 1.0 (the specific gravity of water), water float 1704 must have a very precise density to sink in the motor fuel above and be buoyant on the water below. Common manufacturing practices make this tightrope even more difficult to walk.
To ensure that water float 1704, 1704′ is sufficiently dense to sink in the motor fuel contained in UST 16, one or more ballast rings 1735, 1735′ can be added to frame 1701, 1701′. The chosen ballast rings are inserted into a ballast receiver on one of frame halves 1701a, 1701b or 1701a′, 1701b′ prior to joining the frame halves to form frame 1701, 1701′. Because ballast rings 1735, 1735′ have an outer diameter complementary to the inner diameter of ballast receiver 1733, 1733′, i.e., nominally substantially congruent—that is, of congruent shape, but with the outer diameter of ballast rings 1735, 1735′ undersized enough to allow for radial (orthogonal to longitudinal axis L1) insertion of ballast rings 1735, 1735′ into ballast receiver 1733, 1733′ and nominally the same inner diameter, only the necessary cumulative height of ballast rings 1735, 1735′ needs to be determined. The needed height of ballast rings 1735, 1735′ can be determined through trial and error. Alternatively, the needed height of ballast rings 1735, 1735′ can be calculated. After the required ballast height is determined, a plurality of ballast rings having a total height substantially equal (i.e., as close as the available ballast ring sizes will allow) to the determined ballast height can be chosen. An exemplary computation of the needed ballast ring height is shown below.
FB Diesel=Buoyant force from Diesel
FBall Diesel=Buoyant force from Diesel
The below table shows the specific gravity ranges that each part will have. The specific gravity of water is 1. All references to “density” in these calculations are in units of specific gravity.
Calculations below are what we will use to calculate the “height” of ballast needed for each float.
Float assembly without ballast buoyancy in diesel. (Float, Frame #=*2, Magnet)
Float assembly without ballast buoyancy in diesel. (Float, Frame #=*2, Magnet)
(−) Ballast buoyancy in diesel must be equal to or greater than the float assembly buoyancy above.
After determining the necessary ballast rings 1735, 1735′ and assembling frame halves 1701a, 1701b or 1701a′, 1701b′, with water float magnet 1703, 1703′ and ballast rings 1735, 1735′ secured in magnet carrier 1721, 1721′ and ballast receiver 1733, 1733′, respectively, frame 1701, 1701′ is secured to float base 1708, 1708′ as described above. Water float 1704, 1704′ can then receive magnetostrictive probe shaft 1712 through its central opening (and the central openings of magnet 1703, 1703′ and ballast rings 1735, 1735′) so that frame spacers 1729, 1729′ contact magnetostrictive probe shaft 1712 through the travel of water float 1704, 1704′ along magnetostrictive probe shaft 712. With fuel float 1709 and water float 1704, 1704′ positioned about magnetostricitve probe shaft 1712, foot 1706 can be secured to the distal end of magnetostrictive probe shaft 1712 with a snap ring.
When the probe is fully assembled, foot 1706 is positionable within foot recess 1737, 1737′ of float base 1708, 1708′ such that float base 1708, 1708′ can be positioned very close to floor 1707 of UST 16. In certain embodiments, float base 1708, 1708′ is spaced 0.0060 inches or less from floor 1707 of UST 16. Foot recess 1737, 1737′ has an inner diameter larger than the outer diameter of foot 1708.
In use, probe shaft 1712 is communicatively connected to controller 102 or an indicator to relay a water measurement and/or alarm to a user. A threshold measured water level may signal actuation of filtration systems 200, 200′, 200A, or 200B. A threshold measured water level may also signal corrosion mitigation in the form of water removal from storage tank 16 by direct pumping from the floor of storage tank 16 or other mechanisms.
Water sensor 800 may include standard water and fuel product floats as shown in
Various plain steel samples were prepared as summarized in Table 1 below. Each sample was cut into a 1-inch square.
The samples were placed in a sealed glass container together with a 5% acetic acid solution. The samples were suspended on a non-corrosive, stainless steel platform over the acetic acid solution for exposure to the acetic acid vapor in the container. Select samples were removed from the container after about 23, 80, and 130 hours. Other samples were reserved as control samples.
Each sample was placed inside a holder and illuminated with a LED light source inside a tube to control light pollution. An ambient light sensor from ams AG was used to measure the intensity of the light passing through each sample. The results are presented in
Sample No. 4 of Example 1 was placed inside a sealed plastic bag together with a paper towel that had been saturated with a 5% acetic acid solution. The sample was subjected to illumination testing in the same manner as Example 1, except that the sample remained inside the sealed bag during testing. The results are presented in
A turbine sump having a volume of 11.5 cubic feet and a stable temperature between about 65° F. and 70° F. was humidified to about 95% using damp rags. The rags were then removed from the humidified turbine sump. A desiccant bag was placed inside the humidified turbine sump, which was then sealed closed. The desiccant bag contained 125 g of calcium chloride with a gelling agent to prevent formation of aqueous calcium chloride.
The relative humidity and temperature in the turbine sump were measured over time, as shown in
While this invention has been described as having exemplary designs, the present invention can be further modified within the spirit and scope of this disclosure. This application is therefore intended to cover any variations, uses, or adaptations of the invention using its general principles. Further, this application is intended to cover such departures from the present disclosure as come within known or customary practice in the art to which this invention pertains and which fall within the limits of the appended claims.
This application is related to U.S. Provisional Patent Application Ser. No. 62/814,428 filed Mar. 6, 2019, U.S. patent application Ser. No. 16/557,363 filed Aug. 30, 2019, U.S. patent application Ser. No. 15/914,535 filed Mar. 7, 2018, U.S. Provisional Patent Application Ser. No. 62/468,033 filed Mar. 7, 2017, U.S., Provisional Patent Application Ser. No. 62/509,506 filed May 22, 2017, U.S., Provisional Patent Application Ser. No. 62/520,891 filed Jun. 16, 2017, U.S., Provisional Patent Application Ser. No. 62/563,596 filed Sep. 26, 2017, U.S., PCT Application No. PCT/US21/37089 filed Jun. 22, 2021, PCT Application No. PCT/US19/49104 filed Aug. 30, 2019, PCT Application No. PCT/US18/21350 filed Mar. 7, 2018, U.S. patent application Ser. No. 17/345,997 filed Jun. 11, 2021, and Provisional Patent Application Ser. No. 63/037,986 filed Jun. 11, 2020. The disclosures of all of the foregoing applications are hereby expressly incorporated by reference herein in their entireties. This application claims priority to U.S. Provisional Patent Application Ser. No. 63/108,387 filed Nov. 1, 2020 and also claims priority to U.S. Provisional Patent Application Ser. No. 63/221,432 filed Jul. 13, 2021, the disclosures of both of which are hereby expressly incorporated by reference herein in their entireties.
| Number | Date | Country | |
|---|---|---|---|
| 63221432 | Jul 2021 | US | |
| 63108387 | Nov 2020 | US |
