Claims
- 1. A low molecular weight crosslinker having a plurality of the same or different segments represented by the formula: ##STR15## wherein L groups of the ##STR16## units are the same or different, and the R.sup.1 and R.sup.2 groups in each of the L units are independently selected from a group consisting of hydrogen, fluoro, acyloxy, carboxy, cyano, chloro, alkoxy, acetoxy, acyl, aminocarbonyl, N-alklyaminocarbonyl, N,N-dialkylaminocarbonyl, aryl, alkyl or 1 to 20 carbon atoms, aralykl, alkoxycarbonyl of 1 to 20 carbon atoms, beta-hydroxyethoxycarbonyl, beta-hydroxypropoxycarbonyl, and gamma-hydroxypropoxycarbonyl groups; and wherein M groups of the ##STR17## units are the same or different; and the R.sup.3 group in each of the M units is independently selected from a group consisting of hydrogen, methyl, and phenyl; and the R.sup.4 and R.sup.5 groups in each of the M units are independently selected from a group consisting of hydrogen, alkyl of 1 to 20 carbon atoms, alkoxyalkyl, aralkyl, perfluoroalkyl, and aryl groups; and wherein L is from zero to about 100; and M is from one to about 50;
- with the proviso that the crosslinker has a weight average molecular weight of 10,000 or less.
- 2. The crosslinker of claim 1 wherein R.sup.3 is hydrogen and R.sup.4 and R.sup.5 are both methyl.
- 3. The crosslinker of claim 2 wherein R.sup.1 is hydrogen and R.sup.2 is normal butoxycarbonyl.
- 4. The crosslinker of claim 2 wherein R.sup.1 is methyl and R.sup.2 is methoxycarbonyl.
- 5. The crosslinker of claim 4 wherein the weight ratio of L groups of the ##STR18## units to M groups of the ##STR19## units in the crosslinker is from about 0.5:1 to about 10:1.
- 6. The crosslinker of claim 4 wherein the weight percent of M groups of the ##STR20## units in the crosslinker is from about 10 to about 66.
- 7. A low molecular weight acrylamidoglycolate polymer crosslinker derived from the copolymerization of: ##STR21## wherein R.sup.3 is selected from the group consisting of hydrogen, methyl, and phenyl; and R.sup.4 and R.sup.5 are independently selected from the group consisting of hydrogen, alkyl of 1 to 20 carbon atoms, alkoxyalkyl, aralkyl, perfluoroalkyl, and aryl groups; and ##STR22## wherein R.sup.1 and R.sup.2 are the same or different and are independently selected from the group consisting of hydrogen, carboxyl, cyano, chloro, fluoro, acyloxy, alkoxy, acetoxy, acyl, aminocarbonyl, N-alkaminocarbonyl, N,N-dialkylaminocarbonyl, aryl, alkyl of 1 to 20 carbon atoms, beta-hydroxyethoxycarbonyl, and gamma-hydroxypropoxycarbonyl groups, wherein the crosslinker has a weight average molecular weight of 10,000 or less. pg,22
- 8. The crosslinker of claim 7 wherein R.sup.3 is hydrogen and R.sup.4 and R.sup.5 are both methyl.
- 9. The crosslinker of claim 8 wherein R.sup.1 is hydrogen and R.sup.2 is normal butoxycarbonyl.
- 10. The crosslinker of claim 8 wherein R.sup.1 is methyl and R.sup.2 is methoxycarbonyl.
- 11. The crosslinker of claim 10 wherein the weight ratio of (ii) to (i) is from about 0.5:1 to about 10:1.
- 12. The crosslinker of claim 10 wherein the weight percent of (i) in the polymer is from about 10 to about 66.
- 13. A low molecular weight acrylamidoglycolate polymer crosslinker derived from the homopolymerization of: ##STR23## wherein R.sup.3 is selected from the group consisting of hydrogen, methyl, and phenyl; and R.sup.4 and R.sup.5 are independently selected from the group consisting of hydrogen, alkyl of 1 to 20 carbon atoms, alkoxyalkyl, aralkyl, perfluoroalkyl, and aryl groups; wherein the crosslinker has a weight average molecular weight of 10,000 or less.
- 14. The crosslinker of claim 13 wherein R.sup.3 is hydrogen and R.sup.4 and R.sup.5 are both methyl.
Parent Case Info
This application is a continuation of application Ser. No. 07/786.441 filed Nov. 1, 1991, now abandoned.
US Referenced Citations (16)
Foreign Referenced Citations (3)
Number |
Date |
Country |
224736 |
Jun 1987 |
EPX |
302588 |
Feb 1989 |
EPX |
3613082 |
Nov 1986 |
DEX |
Non-Patent Literature Citations (3)
Entry |
Proceedings of the ACS Division of Polymeric Materials: Science and Engineering, vol. 50, pp. 353-356 (1984). |
Proceedings of the ACS Division of Polymeric Materials, Science and Engineering, vol. 55, pp. 315-321 (1986). |
Proceedings of the Water-Borne Higher-Solids Coatings Symposium, vol. 16, pp. 505-520 (1989). |
Continuations (1)
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786441 |
Nov 1991 |
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