Patent Application
20190228883
The present invention relates to low-temperature superconducting wire, and more particularly, to a low-temperature superconducting wire having a low stabilizing matrix ratio.
A low-temperature superconducting wire, which is operated at a liquid helium temperature, uses a filament-type wire, which is made of a metal alloy, as a superconducting wire. The low-temperature superconducting wire generates a high magnetic field and the low-temperature superconducting wire is easily super-conductively joined, so that the low-temperature superconducting wire is widely used in Magnetic Resonance Imaging (MRI) or Nuclear Magnetic Resonance (NMR), a nuclear fusion device, a large collider, and the like. The superconducting wire in the form of a filament in the related art has a structure covered by a stabilizing matrix.
Referring to
The low-temperature superconducting wire in the related art has a very high metal stabilizing matrix ratio for protecting the wire from quench. For example, the low-temperature superconducting wire, in which a volume ratio of copper, which is a stabilizing matrix, and a superconducting wire is 7:1 or more, is used in a magnetic for MRI.
However, there is a problem in that a high stabilizing matrix ratio reduces a current density (Je) of the superconducting wire and increases manufacturing cost of the low-temperature superconducting wire.
In order to solve the problem in the related art, an object of the present invention is to present a superconducting wire structure, which is capable of achieving a low stabilizing matrix ratio.
Further, an object of the present invention is to provide a low-temperature superconducting wire having a high current density.
Further, an object of the present invention is to provide a low-temperature superconducting wire, which has a self-protecting function from a quench phenomenon generated during an operation of a superconducting magnet.
Further, an object of the present invention is to provide a superconducting coil including a low-temperature superconducting wire.
In order to achieve the technical problem, the present invention provides a superconducting wire, including: a low-temperature superconducting filament; a stabilizing matrix encompassing the filament; and a sheath of a Metal-Insulator Transition (MIT) material, which encompasses the stabilizing matrix on the exterior of the stabilizing matrix.
In the present invention, the MIT material may have a transition temperature of a room temperature or lower. The MIT material may include a vanadium oxide, for example, VO. Further, the MIT material may include a minimum of one kind of material selected from the group consisting of VnO2n-1 (herein, n=2 to 9). Further, the MIT material may include a minimum of one kind of material selected from the group consisting of Fe3O4, RNiO3 (R=La, Sm, Nd, or Pr). La1-xSrxNiO4 (herein, x<1), NiS1-xSex (herein, x−1), and BaVS3.
In the present invention, the low-temperature superconducting filament may include a minimum of one kind of material selected from the group consisting of NbTi, NbZr, Nb3Sn, V3Ga, Nb3Ge, and Nb3Al.
Further, in order to achieve another technical problem, the present invention provides a low-temperature superconducting coil, in which a low-temperature superconducting wire including a low-temperature superconducting filament and a stabilizing matrix encompassing the filament is wound, in which an MIT material is interposed between adjacent low-temperature superconducting wires. In this case, an MIT material layer may have a structure which is in contact with the stabilizing matrix.
According to the present invention, it is possible to provide a superconducting wire structure, which is capable of achieving a low stabilizing matrix ratio while coping with heat caused by a quench phenomenon. Accordingly, it is possible to reduce manufacturing cost and achieve a high current density.
Hereinafter, the present invention will be described by describing exemplary embodiments of the present invention with reference to the accompanying drawings.
In the specification of the present invention, a low-temperature superconducting wire refers to a superconducting wire, in which a critical temperature of a superconducting material is lower than a liquid nitrogen temperature, compared to a high-temperature superconducting wire, in which a critical temperature is higher than a liquid nitrogen temperature. There is no absolute critical temperature based on which a low-temperature superconducting wire is discriminated, but roughly, a wire having a critical temperature lower than 77 K that is a liquid nitrogen temperature is a low-temperature superconducting wire. The superconducting wire is used by being cooled with liquid helium. Further, a low-temperature superconducting coil is applicable to a superconducting magnet of Magnetic Resonance Imaging (MRI), Nuclear Magnetic Resonance (NMR), a nuclear fusion device, a large collider, and the like.
As illustrated in
In the present invention, the low-temperature superconducting filament 110 may be formed of a minimum of one kind of superconducting material selected from the group consisting of NbTi, NbZr, Nb3Sn, V3Ga, Nb3Ge, and Nb3Al. In the present invention, the filament 110 has a longitudinally extended predetermined shape, regardless of a shape of a cross-section. As illustrated, in the present invention, the filament 110 may have a wire form, of which a cross-section has a circular shape, but unlike this, the filament 110 may have a hollow pipe form including an internal structure. Further, the filament may also include an additional metal layer or superconducting material layer on the interior or exterior thereof.
In the present invention, as the stabilizing matrix, a conductive metal, such as copper, aluminum, and silver, may be used.
In the meantime, the MIT refers to a material which has low electrical conductivity at a temperature lower than a predetermined temperature (transition temperature) to operate as an insulator, but exhibits a sharp increase in electrical conductivity at a temperature of the transition temperature or higher.
Even in the specification of the present invention, the MIT is used as the substantially same meaning as a general usage thereof. However, the MIT suitable for the present invention has a transition temperature equal to or higher than a critical temperature of a superconducting wire and has an electrical conductivity rate before and after a section including the transition temperature of preferably 103 or more, more preferably, 105 or more.
In the present invention, the MIT has a transition temperature equal to or higher than a critical temperature of a superconducting material used in the wire. A transition temperature of the MIT may be preferably less than a critical temperature of the superconducting material+150 K. and more preferably, less than the threshold temperature+100 K. Further, in consideration of the feature that high heat enough to cause burn-out of the coil is generated when the quench is generated, a transition temperature of the MIT usable in the present invention may be around a room temperature. As a matter of course, the transition temperature of the MIT may be equal to or higher than the critical temperature of the superconducting material, but is not essentially limited thereto.
An example of the MIT material suitable for the present invention may include a vanadium oxide. A V2O3 phase in the vanadium oxide is divided into a typical insulator, but the vanadium oxide of a composition of VO, VO2, and VnO2n-1 (herein, n=2 to 9) has a transition temperature and exhibits an electrical metal-insulator transition characteristic.
Referring to
A transition temperature value of the vanadium oxide expressed by VnO2n-1 (n=2 to 9) may be calculated with an appropriate model.
In the meantime, in the present invention, as the MIT material, various materials exemplified below may be used.
Referring to
In the illustrated drawing, each superconducting wire 100 includes a low-temperature superconducting filament 110, a stabilizing matrix 120, and an MIT layer 130.
Within the superconducting coil, each superconducting wire 100 is in contact with a minimum of one another superconducting wire in an upper or lateral direction, and as a result, the superconducting wire 100 is adjacent to another superconducting wire 100 with the MIT layer 130 interposed therebetween. In the foregoing structure, quench is generated in the superconducting wire 100, and when a temperature of the corresponding superconducting wire is increased due to the heat according to the generation of the quench to become a transition temperature of the MIT layer 130 or higher, the MIT layer 130 acts as a conductive path. Accordingly, a current of the superconducting wire 100, in which the quench is generated, may bypass to the adjacent superconducting wire 100.
In the foregoing coil structure, there is an advantage in that when each superconducting wire satisfies a specific temperature condition according to an operation state, the superconducting wire is capable of escaping from an electrically isolated state within an insulating material. That is, in the coil structure of the present invention, the superconducting wire may use the stabilizing matrix of the adjacent superconducting wire as a bypass path. Accordingly, a ratio of the stabilizing matrix configuring each wire may be considerably decreased.
In the present invention, the MIT layer 218 may be coated by an appropriate application method. For example, the MIT layer 218 may be formed by sputtering. Unlike this, a wet method of forming the required MIT layer 218 from a solution in the form of a paste may be used as a matter of course. To this end, a polymer material may also be used as a binder of the MIT material, and further, in this case, the polymer binder may also include conductive polymer.
Further, unlike this, the MIT layer may also be formed by a method of welding or joining a separately manufactured strip-type MIT layer.
Referring to
In the present exemplary embodiment, the MIT layer 330 may be provided by various schemes. For example, the MIT layer 330 may be manufactured by impregnating the superconducting wire formed of the superconducting filament 110 and the stabilizing matrix 120 with an MIT solution or impregnating the coil, in which the superconducting wire is wound, with an MIT solution, and then molding and drying the superconducting wire or the coil.
The exemplary embodiments of the present invention have been described with reference to the accompanying drawings, but those skilled in the art will understand that the present invention may be implemented in another specific form without changing the technical spirit or an essential feature thereof. Thus, it is to be appreciated that the embodiments described above are intended to be illustrative in every sense, and not restrictive.
The present invention is applicable to a superconducting magnet of Magnetic Resonance Imaging (MRI), Nuclear Magnetic Resonance (NMR), and the like.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2016-0114596 | Sep 2016 | KR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2016/013433 | 11/22/2016 | WO | 00 |
