The present invention relates to a photovoltaic device, and more particularly to a thin film photovoltaic module having a plurality of sub-modules spatially arranged next to each other such that at least one sub-module is separated from its immediately next sub-module by a gap, and the plurality of sub-modules is electrically connected to each other in parallel, thereby lowering the operation voltage thereof
A photovoltaic cell converts the energy of sunlight into electricity by the photovoltaic effect. Assemblies of photovoltaic cells are used to make photovoltaic modules or solar panels. Most currently available photovoltaic cells are made from bulk materials such as crystalline silicon or polycrystalline silicon. Photovoltaic cells can also be made of thin film layers deposited on a substrate. Thin film photovoltaic cells reduce the amount of material required thus reducing material cost compared to bulk photovoltaic cells. Thin film silicon cells are becoming increasingly popular due to their low cost, flexibility, light weight, and ease of integration.
Therefore, a heretofore unaddressed need exists in the art to address the aforementioned deficiencies and inadequacies.
The present invention, in one aspect, relates to a thin film photovoltaic module formed on a substrate. The substrate comprises glass, plastic, or metal. In one embodiment, the photovoltaic module includes a first sub-module and a second sub-module.
Each of the first sub-module and the second sub-module comprises a plurality of photovoltaic cells spatially arranged as an array, where each photovoltaic cell has a first conductive layer formed on the substrate, an active layer formed on the first conductive layer, and a second conductive layer formed on the active layer. The plurality of photovoltaic cells in each of the first sub-module and the second sub-module are electrically connected to each other in series such that the second conductive layer in any one but the last cell in a respective sub-module is electrically connected to the first conductive layer of the immediate next cell in the respective sub-module. The active layer includes one or more light absorption layers formed of one or more semiconductors. In one embodiment, the active layer includes an amorphous silicon (a-Si) layer, a micro-crystalline silicon (μc-Si) layer, or both layers. In one embodiment, each of the first conductive layer and the second conductive layer comprises a transparent conducting oxide (TCO) or a metal. The TCO comprises, but is not limited to, zinc oxide (ZnO), tin oxide (SnO2), indium tin oxide (ITO), aluminum tin oxide (ATO), aluminum zinc oxide (AZO), cadmium indium oxide (CIO), cadmium zinc oxide (CZO), gallium zinc oxide (GZO), fluorine tin oxide (FTO), or a combination of them. The metal comprises, but is not limited to, chromium (Cr), copper (Cu), molybdenum (Mo), titanium (Ti), nickel (Ni), aluminum (Al), gold (Au), or silver (Ag).
Each of the first sub-module and the second sub-module further comprises a positive electrode and a negative electrode formed on the second conductive layer of the first cell and on the second conductive layer of the last cell, respectively, in a respective sub-module. The positive electrodes of the first sub-module and the second sub-module are electrically connected, and the negative electrodes of the first sub-module and the second sub-module are electrically connected.
The first sub-module and the second sub-module are spatially arranged next to each other and separated by a gap such that a pair of adjacent electrodes positioned at each side of the gap has the same polarity. In one embodiment, the gap has a width ranging from about 0.1 μm to about 1500 μm.
The pair of adjacent electrodes is electrically connected to each other.
In one embodiment, the pair of adjacent electrodes is electrically connected to each other via a conductive member formed in and/or across over the gap. In one embodiment, the conductive member and the pair of adjacent electrodes are integrally formed. In one embodiment, the conductive member is formed of a material that has an electrical conductivity that is not lower than, preferably higher than, that of the second conductive layer.
In another aspect of the present invention, a photovoltaic module formed on a substrate comprises a plurality of sub-modules, where each sub-module includes a plurality of photovoltaic cells spatially arranged as an array. Each photovoltaic cell comprises a first conductive layer formed on the substrate, an active layer formed on the first conductive layer, and a second conductive layer formed on the active layer. In one embodiment, the active layer includes one or more light absorption layers formed of one or more semiconductors, for example, an a-Si layer, a μc-Si layer, or both layers. In one embodiment, each of the first conductive layer and the second conductive layer comprises a TCO or a metal. The TCO comprises, but is not limited to, ZnO, SnO2, ITO, ATO, AZO, CIO, CZO, GZO, FTO, or a combination of them. The metal includes, but is not limited to, Cr, Cu, Mo, Ti, Ni, Al, Au, or Ag. The plurality of photovoltaic cells in each sub-module is electrically connected to each other in series such that the second conductive layer in any one but the last cell in a respective sub-module is electrically connected to the first conductive layer of the immediate next cell in the respective sub-module.
Each sub-module further comprises a positive electrode and a negative electrode formed on the second conductive layer of the first cell and on the second conductive layer of the last cell, respectively, in a respective sub-module. The positive electrode of each sub-module is electrically connected to each other, and the negative electrode of each sub-module is electrically connected to each other, such that the plurality of sub-modules is electrically connected in parallel. In one embodiment, the positive electrode of each sub-module is electrically connected to each other by a first conductive ribbon, and wherein the negative electrode of each sub-module is electrically connected to each other by a second conductive ribbon.
The plurality of sub-modules is spatially arranged next to each other as an array in the same direction as the array of the plurality of cells in each sub-module such that each two adjacent sub-modules are separated by a gap therebetween. In one embodiment, each gap has a width ranging from about 0.1 μm to about 1500 μm.
In one embodiment, a corresponding pair of adjacent electrodes positioned at each side of the gap has the same polarity, and each pair of adjacent electrodes positioned at each side of the gap is electrically connected to each other via a conductive member formed in and/or across over the gap spatially separating the corresponding pair of adjacent sub-modules. In one embodiment, the conductive member and the corresponding pair of adjacent electrodes are integrally formed. In one embodiment, the conductive member is formed of a material that has an electrical conductivity that is not lower than that of the corresponding second conductive layer positioned at each side of the gap.
In yet another aspect of the present invention, a photovoltaic module formed on a substrate comprises a plurality of sub-modules.
Each sub-module includes a plurality of photovoltaic cells spatially arranged as an array. Each photovoltaic cell includes a first conductive layer formed on the substrate, an active layer formed on the first conductive layer, and a second conductive layer formed on the active layer. The plurality of photovoltaic cells in each sub-module is electrically connected to each other in series such that the second conductive layer in any one but the last cell in a respective sub-module is electrically connected to the first conductive layer of the immediate next cell in the respective sub-module.
Each sub-module further includes a positive electrode and a negative electrode formed on the second conductive layer of the first cell and on the second conductive layer of the last cell, respectively, in a respective sub-module. The positive electrode of each sub-module is electrically connected to each other and the negative electrode of each sub-module is electrically connected to each other such that the plurality of sub-modules is electrically connected in parallel. In one embodiment, the positive electrode of each sub-module is electrically connected to each other by a first conductive ribbon, and wherein the negative electrode of each sub-module is electrically connected to each other by a second conductive ribbon.
The plurality of sub-modules is spatially arranged next to each other as an array in the same direction as the array of the plurality of cells in each sub-module.
In one embodiment, at least one sub-module and its immediately next sub-module are configured such that the at least one sub-module is separated from its immediately next sub-module by a gap. In one embodiment, the pair of adjacent electrodes positioned at each side of the gap has the same polarity, and is electrically connected to each other via a conductive member formed in and/or across over the gap. The conductive member is formed of a material that has an electrical conductivity that is not lower than that of the corresponding second conductive layer positioned at each side of the gap.
In another embodiment, at least one sub-module and its immediately next sub-module are configured such that at least one layer of the at least one sub-module is spatially separated from a corresponding layer of its immediately next sub-module.
These and other aspects of the present invention will become apparent from the following description of the preferred embodiment taken in conjunction with the following drawings, although variations and modifications therein may be effected without departing from the spirit and scope of the novel concepts of the disclosure.
The accompanying drawings illustrate one or more embodiments of the invention and together with the written description, serve to explain the principles of the invention. Wherever possible, the same reference numbers are used throughout the drawings to refer to the same or like elements of an embodiment, and wherein:
The present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Like reference numerals refer to like elements throughout.
It will be understood that when an element is referred to as being “on” another element, it can be directly on the other element or intervening elements may be present therebetween. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
It will be understood that, although the terms first, second, third, etc.
may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the present invention.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” or “includes” and/or “including” or “has” and/or “having” when used herein, specify the presence of stated features, regions, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, regions, integers, steps, operations, elements, components, and/or groups thereof.
Furthermore, relative terms, such as “lower” or “bottom”, “upper” or “top,” and “front” or “back” may be used herein to describe one element's relationship to another element as illustrated in the Figures. It will be understood that relative terms are intended to encompass different orientations of the device in addition to the orientation depicted in the Figures. For example, if the device in one of the figures is turned over, elements described as being on the “lower” side of other elements would then be oriented on “upper” sides of the other elements. The exemplary term “lower”, can therefore, encompasses both an orientation of “lower” and “upper,” depending of the particular orientation of the figure. Similarly, if the device in one of the figures is turned over, elements described as “below” or “beneath” other elements would then be oriented “above” the other elements. The exemplary terms “below” or “beneath” can, therefore, encompass both an orientation of above and below.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure, and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
As used herein, “around”, “about” or “approximately” shall generally mean within 20 percent, preferably within 10 percent, and more preferably within 5 percent of a given value or range. Numerical quantities given herein are approximate, meaning that the term “around”, “about” or “approximately” can be inferred if not expressly stated.
The term “substrate”, as used herein, refers to a thin layer of material such as silicon, silicon dioxide, aluminum oxide, sapphire, germanium, gallium arsenide (GaAs), an alloy of silicon and germanium, indium phosphide (InP), glass, plastic, metal, etc., upon which a semiconductor device, e.g. a photovoltaic cell is applied.
As used herein, the term “plurality” means a number greater than one.
The description will be made as to the embodiments of the present invention in conjunction with the accompanying drawings in
In one embodiment, each pair of adjacent electrodes 107/107 or 108/108 is electrically connected to each other by a conductive member formed of a conductive material. The conductive member can be disposed in and/or across over the gap 105, and/or across over the gap 105. The conductive member can be a conductive bar, a conductive lead, a conductive bus, a conductive ribbon/strip, or other conductive means. The conductive member can be integrally formed with the pair of adjacent electrodes 107/107 or 108/108. Alternatively, the conductive member can be an individually formed member electrically connected to the pair of adjacent electrodes 107/107 or 108/108. Further, the positive electrode 107 of each of the plurality of sub-modules 101, 102, 103 and 104 is electrically connected to each other, for example, by a first electrically conductive ribbon 191, while the negative electrode 108 of each of the plurality of sub-modules 101, 102, 103 and 104 is electrically connected to each other, for example, by a second electrically conductive ribbon 192. In this fashion, the plurality of sub-modules 101, 102, 103 and 104 is electrically connected to each other in parallel. Accordingly, such a photovoltaic module 100 can have a low operation voltage that is comparable to that of a bulk silicon photovoltaic module of the same size. Further, it has advantages in installation over the conventional thin film solar modules.
Each of photovoltaic cells Ca1-Ca5 and Cb1-Cb5 has a front (first) conductive layer 220 formed on the substrate 210, a back (second) conductive layer 240 and a photovoltaic (active) layer 230 sandwiched between the front conductive layer 220 and the back conductive layer 240. In one embodiment shown in
In other embodiments, the photovoltaic layer 230 can be a semiconductor thin film in Group IV elements of the Periodic Table, Group III-V compound semiconductor thin film, Group II-VI compound semiconductor thin film, organic semiconductor thin film or compound thereof. In details, the semiconductor thin film in Group IV elements of the Periodic Table is at least one of a carbon thin film, a silicon thin film, a germanium thin film, a silicon carbide thin film and a silicon germanium thin film, each of which may be in monocrystalline form, polycrystalline form, amorphous form or microcrystalline form, or a combination thereof. For example, the compound semiconductor thin film in Group III-V of the Periodic Table is at least one of gallium arsenide (GaAs) thin film and indium gallium phosphide (InGaP) thin film, or a combination thereof. The compound semiconductor thin film in Group II-VI, for example, includes at least one of a copper indium diselenide (CIS) thin film, a copper indium gallium diselenide (CIGS) thin film and a cadmium telluride (CdTe) thin film, or a combination thereof. Furthermore, the above mentioned organic compound semiconductor thin film can be a mixture of a conjugated polymer donor and PCBM acceptor. In addition, the film structure of the above mentioned photovoltaic layer 230 can be a PN single layer of photoelectric conversion structure, as shown in
The substrate 210 is formed of a material of glass, plastic, or metal. The front conductive layer 220 and the back conductive layer 240 can be formed of the same material or substantially different materials. In one embodiment, each of the front conductive layer 220 and the back conductive layer 240 is formed of TCO, such as ZnO, SnO2, ITO, ATO, AZO, CIO, CZO, GZO, FTO, or a combination of them. In another embodiment, the front conductive layer 220 and the back conductive layer 240 may be formed of a metal, such as Mo, Ti, Ni, Al, Au, Cr or Ag. Other TCO and metals can also be utilized to practice the present invention. According to the present invention, sunlight can be incident onto the photovoltaic cells at either the back conductive layer 240 or the substrate 210. If sunlight is incident onto the photovoltaic cells at the back conductive layer 240, the back conductive layer 240 is formed a transparently conductive material. Otherwise, if sunlight is incident onto the photovoltaic cells at the substrate 210, the substrate 210 is formed of a transparent material such as glass, and the front conductive layer 220 is formed of a transparently conductive material. The former is sometimes referred to “substrate-type photovoltaic cells”, while the latter is sometimes referred to “superstrate-type photovoltaic cells”.
All the photovoltaic cells in each sub-module are electrically connected in series such that the second conductive layer 240 of any one but the last photovoltaic cell is electrically connected to the first conductive layer 220 of the immediate next photovoltaic cell. For example, for the first sub-module 201, the back conductive layer 240 of the first photovoltaic cell Cal is electrically connected to the front conductive layer 220 of the second photovoltaic cell Ca2 through a groove or opening 235, which is formed by the laser scribing process, as shown below in
Still referring to
According to the present invention, the first sub-module 201 and the second sub-module 202 are spatially arranged next to each other and separated by a spatial gap (or space) 260. In one embodiment, the gap 260 has a width, W, ranging from about 0.1 μm to about 1500 μm. The first sub-module 201 and the second sub-module 202 are fabricated such that the second sub-module 202 is a mirror image of the first sub-module 201, and the two adjacent electrodes, for example, electrodes 208a and 208b, positioned on each side of the gap 260 have the same polarity. In this illustrative example shown in
Further, an additional grooves or openings 625a and 625b may be defined in the front (first) conductive layers 620 of the corresponding photovoltaic cells, as shown in
As shown in
In the example shown in
In the exemplary embodiment shown in
Referring to
One aspect of the present invention also provides a photovoltaic module having a plurality of sub-modules formed on a substrate. Each sub-module includes a plurality of photovoltaic cells spatially arranged as an array, each cell having first and second conductive layers sandwiching an active layer therebewteen. The cells in each sub-module are electrically connected to each other in series. Each sub-module further includes positive and negative electrodes formed on the second conductive layers of the first and last cells, respectively, in a respective sub-module. The positive electrode of each sub-module is electrically connected to each other and the negative electrode of each sub-module is electrically connected to each other such that the plurality of sub-modules is electrically connected in parallel. In one embodiment, the positive electrode of each sub-module is electrically connected to each other by a first conductive ribbon, and wherein the negative electrode of each sub-module is electrically connected to each other by a second conductive ribbon.
The plurality of sub-modules is spatially arranged next to each other as an array in the same direction as the array of the plurality of cells in each sub-module.
In one embodiment, at least one sub-module and its immediately next sub-module are configured such that the at least one sub-module is separated from its immediately next sub-module by a gap. In one embodiment, the pair of adjacent electrodes positioned at each side of the gap has the same polarity, and is electrically connected to each other via a conductive member formed in and/or across over the gap. The conductive member is formed of a material that has an electrical conductivity that is not lower than that of the corresponding second conductive layer positioned at each side of the gap.
In another embodiment, at least one sub-module and its immediately next sub-module are configured such that at least one layer of the at least one sub-module is spatially separated from a corresponding layer of its immediately next sub-module.
In brief, the present invention, among other things, recites a photovoltaic module having a plurality of sub-modules spatially arranged next to each other such that at least one sub-module is separated from its immediately next sub-module by a gap and each pair of adjacent electrodes formed on two adjacent sub-modules has the same polarity. Such a photovoltaic module can have a low operation voltage that is comparable to that of a bulk silicon photovoltaic module of the same size. Comparing with a conventional thin film solar module, the invented photovoltaic module has advantages in installation.
The foregoing description of the exemplary embodiments of the invention has been presented only for the purposes of illustration and description and is not intended to be exhaustive or to limit the invention to the precise forms disclosed. Many modifications and variations are possible in light of the above teaching.
The embodiments were chosen and described in order to explain the principles of the invention and their practical application so as to activate others skilled in the art to utilize the invention and various embodiments and with various modifications as are suited to the particular use contemplated. Alternative embodiments will become apparent to those skilled in the art to which the present invention pertains without departing from its spirit and scope. Accordingly, the scope of the present invention is defined by the appended claims rather than the foregoing description and the exemplary embodiments described therein.