In the hard disk drive industry, there are generally two ways to coat lubricant onto a magnetic recording disk: a dip-coating process and a thermal vapor phase lubrication process. In the dip-coating process, post sputtered disks, held by a mandrel, are immersed in a lubricant solution, and then lifted from the solution. The lubricant thickness can be controlled by controlling the lubricant concentration and lifting speed of the disk. However, there are some disadvantages associated with this process. For example, it involves using a large amount of expensive and volatile fluorinated solvent, which adversely adds to the cost of the process and also causes environmental issues.
The thermal vapor phase lubrication process involves thermal vaporization of a perfluoropolyether (PFPE) lubricant in a vacuum, followed by condensation of the lubricant vapor onto a room temperature thin film magnetic disk. However, one drawback of this technique is that the PFPE lubricants supplied to the data storage industry are not pure, but rather are mixtures consisting of a distribution of molecular weights. Each molecular weight component of the mixture has a different vapor pressure, and as a result, the mixture is fractionated by molecular weight as the deposition process progresses. As such, disks processed at different times of the process have a different average molecular weight of lubricant deposited, with lighter materials on disks near the beginning of the process and heavier materials on disks later. The cycle of light material to heavier material repeats itself each time the liquid lubricant is recharged into the evaporator. A second drawback is that deposition of lubricant films containing two or more different chemical components will involve a separate evaporation process station for each component. A third drawback is the use of high temperatures for extended periods of time, which may lead to thermal degradation of the PFPE material.
A method, in one embodiment, can include pumping a gas into a reservoir that includes a lubricant. In addition, the method can include changing the gas into a supercritical fluid that extracts lubricant molecules from the lubricant resulting in a mixture of the supercritical fluid and the lubricant molecules. Furthermore, the method can include utilizing the mixture to deposit a lubricant molecule onto a magnetic media.
In another embodiment, a system can include a nozzle and a reservoir coupled to the nozzle and for holding a lubricant. Additionally, the system can include a compressor for pumping a gas into the reservoir and for controlling an internal pressure of the reservoir. Moreover, the system can include a heater for changing the temperature of the reservoir. Note that the compressor and the heater can be for converting the gas into a supercritical fluid within the reservoir that extracts lubricant molecules from the lubricant resulting in a mixture of the supercritical fluid and the lubricant molecules. In addition, the nozzle can be for outputting the mixture towards a magnetic media.
In yet another embodiment, a method can include pumping a gas into a reservoir that includes a plurality of lubricants. The method can also include altering the gas into a supercritical fluid that extracts lubricant molecules from the plurality of lubricants resulting in a mixture of the supercritical fluid and the lubricant molecules. Furthermore, the method can include outputting the mixture from the reservoir to deposit lubricants onto a magnetic disk.
While particular embodiments in accordance with the invention have been specifically described within this Summary, it is noted that the invention and the claimed subject matter are not limited in any way by these embodiments.
The drawings referred to in this description should not be understood as being drawn to scale except if specifically noted.
Reference will now be made in detail to various embodiments in accordance with the invention, examples of which are illustrated in the accompanying drawings. While the invention will be described in conjunction with various embodiments, it will be understood that these various embodiments are not intended to limit the invention. On the contrary, the invention is intended to cover alternatives, modifications and equivalents, which may be included within the scope of the invention as construed according to the Claims. Furthermore, in the following detailed description of various embodiments in accordance with the invention, numerous specific details are set forth in order to provide a thorough understanding of the invention. However, it will be evident to one of ordinary skill in the art that the invention may be practiced without these specific details. In other instances, well known methods, procedures, components, and circuits have not been described in detail as not to unnecessarily obscure aspects of the invention.
Specifically, within the thin film magnetic disk fabrication system 102, one or more thin film magnetic media or disks (e.g., 104) can be fabricated which can be eventually incorporated into one or more hard disk drives. It is noted that the one or more thin film magnetic media or disks 104 can be fabricated in a wide variety of ways. For example in one embodiment, the one or more thin film magnetic media 104 can be implemented to include, but not limited to, a tribological coating that includes a layer of thin amorphous carbon.
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Once the lubricant deposition system 106 produces the one or more lubricated media or disks 108, they can be loaded or inserted into the additional processing system 110. Note that a wide variety of activities can be performed on the one or more lubricated thin film magnetic media 108 by the additional processing system 110. For example in various embodiments, the activities of the additional processing system 110 can include, but is not limited to, a final polishing operation of the one or more lubricated thin film magnetic media 108 (which may be referred to as “tape buff/wipe”), testing the one or more lubricated thin film magnetic media 108 to determine if each will support fly height and to detect any defects, and/or incorporating the one or more lubricated thin film magnetic media 108 into one or more hard disk drives 112. In this manner, the additional processing system 110 can produce one or more hard disk drives 112 that each include one or more lubricated thin film magnetic media or disks 108.
In one embodiment, the lubricant deposition system 200 can implement a supercritical fluid lubrication process in order to deposit one or more lubricants 224 onto the thin film magnetic disk 240. For example in an embodiment, a compressed gas 220 within the lubricant deposition system 200 can be converted into a supercritical fluid that essentially acts as a solvent for the one or more lubricants 224 stored within the lubricant vessel 226. As such, a mixture 230 can be created or generated that includes the supercritical fluid of gas 220 together with molecules of the one or more lubricants 224. Therefore, the supercritical fluid of gas 220 can act as a carrier and a depositor of the one or more lubricants 224, which can be deposited onto the thin film magnetic disk 240. In one embodiment, a supercritical fluid is a substance located between a gas state and a liquid state, thereby including the properties of both the gas and liquid states. A substance can be changed or converted into a supercritical fluid when its temperature and pressure are elevated beyond its thermodynamic critical point. Note that the thermodynamic critical point of a substance can be defined as the combined minimum temperature and minimum pressure at which the substance exhibits both the properties of a gas and a liquid. It is pointed out that a supercritical fluid is able to pass through materials in a manner similar to a gas. At the same time, the supercritical fluid is able to function as a solvent in a manner similar to a liquid.
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The lubricant reservoir 226 of the lubricant deposition system 200 can contain or hold the one or more lubricants 224. It is noted that the one or more lubricants 224 can be implemented in a wide variety of ways. For example in various embodiments, the one or more lubricants 224 can include, but are not limited to, one or more different types of perfluoropolyether (PFPE). In one embodiment, a tetrahydroxy perfluoropolyether, which may be found under the product name of Fomblin® Z Tetraol® (at different molecular weights), can be the lubricant 224, but is not limited to such. In various embodiments, the one or more lubricants 224 can include, but are not limited to, Fomblin® Z-Dol (at different molecular weights), A20H™ (at different molecular weights) by Matsumura Oil Research Corporation (MORESCO), and the like. It is pointed out that the gas reservoir (or vessel or cylinder) 207 can store or hold the one or more gases 206. Note that the one or more gases 206 can be implemented in a wide variety of ways. For example, the one or more gases 206 can be implemented using a gas and/or a liquid such as, but not limited to, carbon dioxide (CO2), methane (CH4), ethane (C2H6), ethylene (C2H4), water (H2O), methanol (CH3OH), ethanol (C2H5OH), acetone (C3H6O), propane (C3H8), and propylene (C3H6). In one embodiment, to improve extraction efficiency of the one or more lubricants 224, additives can be added into the extraction gas 206. For example in an embodiment, a secondary gas/fluid can be added to the primary gas/fluid 206. The secondary gas/fluid or additive can include, but is not limited to, carbon dioxide, methane, ethane, ethylene, water, methanol, ethanol, acetone, propane, and propylene.
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Furthermore in an embodiment, the lubricant deposition unit 244 can include, but is not limited to, the capillary valve 232, the deposition enclosure 242, the vapor shape control devices 236 and 238, and the capillaries 234, 234′, and 234″. It is noted that the capillary valve 232 can control the volume or amount of lubricant 224 to be deposited onto the magnetic disk 240 via the vapor shape control devices 236 and 238. In addition, each of the vapor shape control devices 236 and 238 can generate a cone shaped plume of aerosol 239 and 241, respectively, which includes the one or more lubricants 224. In one embodiment, the pressure within the lubricant deposition unit 244 (or its enclosure 242) can be different (e.g., higher or lower) from the pressure within the lubricant vessel 226 of the lubricant extraction unit 222, thereby enabling the mixture 230 that includes the supercritical fluid of gas 220 and molecules of lubricant 224 to flow or spray onto the thin film magnetic disk 240. It is pointed out that the pressure difference between the lubricant vessel 226 and the deposition enclosure 242 (or deposition area without enclosure 242) can make a difference in the quality of the deposition of the one or more lubricants 224 onto the thin film magnetic media 240. For example in an embodiment, if there is a large pressure difference between the lubricant vessel 226 and the deposition enclosure 242 (or deposition area without enclosure 242), the resulting lubricant aerosols 239 and 241 may be more forceful and may include larger droplets of the one or more lubricants 224.
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For example in one embodiment, one or more lubricants 224 can be put into the lubricant reservoir 226. It is pointed out that the temperature and the pressure of the lubricant reservoir or vessel 226 can be controlled via the compressor unit 212 and the heater unit 228. In this manner, different components of the one or more lubricants 224 can be extracted from the vessel 226 or all of the components of the one or more lubricants 224 can be extracted from the vessel 226. As previously mentioned above, when the compressed gas 220 is a supercritical fluid, it is between a gas state and a liquid state. Accordingly, by adjusting the temperature and/or pressure of the supercritical fluid of gas 220, the density of the supercritical fluid of gas 220 can be gradually changed to be more closely to a liquid or more closely to a gas. In this fashion, the density can be regulated of the supercritical fluid of gas 220. Moreover, it is noted that by changing the density of the supercritical fluid of gas 220, the property of the supercritical fluid of gas 220 can be changed. For example in an embodiment, if the density of the supercritical fluid of gas 220 is altered to be closer to a gas, then the supercritical fluid of gas 220 can have more energy to penetrate the one or more lubricants 224 within the lubricant vessel 226. In one embodiment, if the density of the supercritical fluid of gas 220 is modified to be closer to a liquid, then the supercritical fluid of gas 220 can have more power to extract molecules from the one or more lubricants 224 within the lubricant vessel 226.
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After the compressed gas 220 is received by the lubricant reservoir 226 of
It is noted that in one embodiment, the capillary valve 232 can be coupled to and controlled by the controller 214. Accordingly, once the mixture 230 has been generated, the controller 214 can cause the value 232 to open thereby enabling the mixture 230 to be released from the lubricant reservoir 226 via the capillary 234. As such, the mixture 230 can travel through capillaries 234, 234′, and 234″ to be output by the vapor shape control devices 236 and 238. Note that once the mixture 230 is output from the vapor shape control devices 236 and 238, the supercritical fluid of gas 220 can evaporate from the mixture 230 resulting in lubricant aerosols 239 and 241 that include the one or more lubricants 224. Therefore, the output spray or flow of the lubricant aerosols 239 and 241 can result in the deposition of the one or more lubricants 224 onto one or more surfaces of the thin film magnetic media or disk 240. In an embodiment, the lubricant aerosols 239 and 241 can travel in an essentially line-of-sight path to the magnetic media 240 and condense on its surfaces. It is pointed out that the supercritical fluid of gas 220 evaporates from the mixture 230 when output from the vapor shape control devices 236 and 238 since the supercritical fluid of gas 220 is no longer being compressed or heated. Consequently, the supercritical fluid of gas 220 can revert back to being gas 206.
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It is noted that each of the vapor shape control devices (or nozzles) 236 and 238 can be implemented in a wide variety of ways. For example, each of the vapor shape control devices (or nozzles) 236 and 238 can be implemented with, but is not limited to, a funnel or conical shaped device (as shown), any type of aerosol nozzle, and any type of spray nozzle. In one embodiment, the vapor shape control device 236 can be implemented in a manner different than the vapor shape control device 238, and vice versa. In addition, in an embodiment, the vapor shape control device 236 can be implemented in a manner similar to the vapor shape control device 238, and vice versa.
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In one embodiment, the controller 214 can be electrically coupled to the pump 202, the compressor 212, the voltage supply 218 coupled to the heater 228, and the capillary valves 208 and 232. In this manner, the controller 214 can independently control the operations of the pump 202, the compressor 212, the heater 228 via its voltage supply 218, and the capillary valves 208 and 232. It is noted that the functionality and/or operations of the controller 214 can be controlled or managed by software, by firmware, by hardware or by any combination thereof, but is not limited to such. Moreover in an embodiment, the controller 214 can be part of a user interface for the lubricant deposition system 200.
Note that experiments in accordance with various embodiments of the invention have been performed with a lubricant deposition system similar to the lubricant deposition system 200 of
In another experiment in accordance with one embodiment of the invention, 1 gram of Fomblin® Z Tetraol® 2000 and 1 gram of A20H™ 2000 were added to a stainless steel extractor vessel (e.g., reservoir 226). The extractor vessel (e.g., 226) was heated to 45° C. and compressed carbon dioxide gas (e.g., 220) was introduced to the extractor vessel (e.g., 226). While the pressure in the extractor vessel (e.g., 226) reached 125 bars, the valve (e.g., 232) was opened. It is pointed out that given these conditions within the extractor vessel (e.g., 226) and before the valve (e.g., 232) was opened, a mixture (e.g., 230) had been generated within the extractor vessel (e.g., 226) that include a supercritical fluid of carbon dioxide (e.g., 220) along with molecules of both of the lubricants (e.g., 224). Accordingly, once the valve (e.g., 232) was opened, the lubricants (e.g., 224) were deposited onto one or more surfaces of the magnetic media (e.g., 240). Utilizing the Fourier transform infrared (FTIR) calculation, the total thickness of the lubricants (e.g., 224) on the surface of the magnetic disk (e.g., 240) was about 21.1 A or 2.11 nm. In addition, the FTIR calculation showed that the lubricant layer contained 19.4 A (or 1.94 nm) of A20H-2000 and 1.7 A (or 0.17 nm) of Z Tetraol 2000.
The lubricant deposition system 200 can be modified in a wide variety of ways. For example in one embodiment, the lubricant deposition system 200 can be altered such that multiple compressed gases (e.g., 220) can be pumped into the lubricant reservoir 226. In an embodiment, the lubricant deposition system 200 can be changed so that the vapor shape control devices (or nozzles) 236 and 238 can each be coupled to a separate lubricant reservoir similar to the lubricant reservoir 226.
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It is noted that the lubricant deposition system 200 may not include all of the elements illustrated by
Specifically in one embodiment, the lubricant deposition system 200′ can include an array or multiple vapor shape control devices or nozzles (e.g., 250, 252, 254, and 256) that can be utilized for depositing one or more lubricants (e.g., 224) onto each surface of the thin film magnetic media 240 to further improve lubricant deposition uniformity, but is not limited to such. It is understood that the lubricant deposition system 200′ of
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In one embodiment, the lubricant deposition system 200′ can include, but is not limited to, a lubricant extraction unit 222 and a lubricant deposition unit 244′. For example in an embodiment, the lubricant extraction unit 222 can include, but is not limited to, the lubricant vessel 226 for storing one or more lubricants 224, and the heater unit or coil 228 for heating the lubricant vessel 226 along with its contents to a certain temperature. It is noted that the lubricant extraction unit 222 can also include the capillary 216 for receiving the compressed gas 220 from the compressor 212, wherein the capillary 216 can be coupled to an input or inlet of the lubricant vessel 226. In this fashion, the compressed gas 220 can be pumped by the compressor 212 into the lubricant vessel 226 where it can be mixed with the one or more lubricants 224 stored therein. In an embodiment, to improve extraction efficiency of the one or more lubricants 224, one or more additives can be added to the extraction gas 206 before it is compressed by the compressor 212.
Additionally in one embodiment, the lubricant deposition unit 244′ can include, but is not limited to, the capillary valve 232, the deposition enclosure 242, the vapor shape control devices (or nozzles) 250, 252, 254, and 256, and the capillaries 234, 234′, and 234″. Note that the capillary valve 232 can control the volume or amount of lubricant 224 to be deposited onto the magnetic disk 240 via the vapor shape control devices 250, 252, 254, and 256. Furthermore, each of the vapor shape control devices 250, 252, 254, and 256 can generate a cone shaped plume of aerosol 239′, 239″, 241′, and 241″, respectively, which includes the one or more lubricants 224. In one embodiment, the pressure within the lubricant deposition unit 244 (or its enclosure 242) can be different (e.g., higher or lower) from the pressure within the lubricant vessel 226 of the lubricant extraction unit 222, thereby enabling the mixture 230 that includes the supercritical fluid of gas 220 and molecules of lubricant 224 to flow or spray onto the thin film magnetic disk 240. It is noted that the pressure difference between the lubricant vessel 226 and the deposition enclosure 242 (or deposition area without enclosure 242) can make a difference in the quality of the deposition of the one or more lubricants 224 onto the thin film magnetic media 240. For example in one embodiment, if there is a large pressure difference between the lubricant vessel 226 and the deposition enclosure 242 (or deposition area without enclosure 242), the resulting lubricant aerosols 239′, 239″, 241′, and 241″ may be more forceful and may include larger droplets of the one or more lubricants 224.
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It is pointed out that each of the vapor shape control devices (or nozzles) 250, 252, 254, and 256 can be implemented in a wide variety of ways. For example, each of the vapor shape control devices (or nozzles) 250, 252, 254, and 256 can be implemented with, but is not limited to, a funnel or conical shaped device (as shown), any type of aerosol nozzle, and any type of spray nozzle. In one embodiment, the vapor shape control devices 250, 252, 254, and 256 can each be implemented in a different manner. Moreover, in an embodiment, all of the vapor shape control devices 250, 252, 254, and 256 can be implemented in a similar manner.
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In one embodiment, the functionality and/or operations of the controller 214 can be controlled or managed by software, by firmware, by hardware or by any combination thereof, but is not limited to such. Furthermore in an embodiment, the controller 214 can be part of a user interface for the lubricant deposition system 200′.
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The lubricant deposition system 200′ can include, but is not limited to, the pump 202, the gas reservoir 207, the compressor 212, the controller 214, the voltage supply 218, the heater 228, the lubricant vessel 226, the valves 208 and 232, the capillaries 204, 210, 216, 234, 234′, 234″, and 246, the vapor shape control devices (or nozzles) 250, 252, 254, and 256, and the deposition enclosure 242. Specifically in one embodiment, an output of the pump 202 can be coupled to an input of the gas reservoir 207 via the capillary 204. An output of the gas reservoir 207 can be coupled to an input of the compressor 212 via the capillary 210 and the capillary valve 208. An output of the compressor 212 can be coupled to an input of the lubricant reservoir 226 via the capillary 216. An output of the lubricant reservoir 226 can be coupled to the vapor shape control devices (or nozzles) 250, 252, 254, and 256 via the capillaries 234, 234′, and 234″ and the capillary valve 232. An output of the deposition enclosure 242 can be coupled to an input of the pump 202 via the capillary 246. The controller 214 can be coupled to control the pump 202, the capillary valves 208 and 232, the compressor 212, and the voltage supply 218 which controls the heater 228.
It is noted that the lubricant deposition system 200′ may not include all of the elements illustrated by
Specifically, method 400 can include adding one or more lubricants into a lubricant vessel for deposition onto one or more thin film magnetic disks. In addition, a thin film magnetic media (or disk) can be loaded into a lubricant deposition enclosure. A supercritical fluid can be utilized to deposit the one or more lubricants onto the one or more surfaces or sides of the thin film magnetic media. The lubricated thin film magnetic media can be removed from the lubricant deposition enclosure. Additionally, a determination can be made as to whether there is another thin film magnetic media to process. If so, process 400 can return to the operation involving loading a thin film magnetic media into the lubricant deposition enclosure. However, if it is determined that there is not another thin film magnetic media to be processed, process 400 can be ended. In this manner, a supercritical fluid can be utilized to deposit one or more lubricants onto thin film magnetic media in accordance with various embodiments of the invention.
At operation 402 of
At operation 404, a thin film magnetic media or disk (e.g., 240) can be loaded or inserted into a lubricant deposition enclosure (e.g., 242). It is noted that operation 404 can be implemented in a wide variety of ways. For example, operation 404 can be implemented in any manner similar to that described herein, but is not limited to such.
At operation 406 of
At operation 408, the lubricated thin film magnetic media can be removed from the lubricant deposition enclosure. It is pointed out that operation 408 can be implemented in a wide variety of ways. For example, operation 408 can be implemented in any manner similar to that described herein, but is not limited to such.
At operation 410 of
The foregoing descriptions of various specific embodiments in accordance with the invention have been presented for purposes of illustration and description. They are not intended to be exhaustive or to limit the invention to the precise forms disclosed, and many modifications and variations are possible in light of the above teaching. The invention is to be construed according to the Claims and their equivalents.