Lubricant for hot forging applications

Abstract
A substantially lead-free lubricant for use in hot forging of metals, especially forging of aluminum and aluminum alloy components. The lubricant comprises one or more oils, graphite, and one or more phosphorus-based additives. Additional additives, such as metallic lubricants and dispersants may also be included. The lubricant does not burn when subjected to temperatures in excess of 300° C.
Description
DETAILED DESCRIPTION OF THE INVENTION

The present invention discloses a lubricant for use in hot-forging applications, such as those utilized in forging aluminum and aluminum workpieces into the desired articles. Such hot forging applications require lubricant materials that do not produce smoke or flame in the general temperature range of about 300° C. to about 600° C. In order to comply with safety and health regulations, such lubricants are substantially lead-free.


The lubricant of the present invention is an oil-based lubricant. The oil utilized may be virtually any composition known in the art, including but not limited to mineral oil, such as naphtenic, aliphatic, paraffinic or steam cylinder oil, vegetable oil, such as sunflower oil, olive oil or rapeseed oil, animal oil, such as lard oil, synthetic oil, such as polyalphaolefins and silicone oil, semi-synthetic oil, such as glycerol trioleate and mixtures thereof. Preferred oils include vegetable, mineral and animal oils. Such oils are commercially available as Process Oil 1000 from Texaco (UK), Lard oil from Welch, Holm and Clark Co. (USA), Soybean oil from BG International (USA.).


A second component of the lubricant is a graphite additive. The graphite may be in any form known in the art, including but not limited to coarse, fine, milled, unmilled, natural, synthetic or mixtures thereof. The graphite component of the lubricant provides for a physical separation between the workpiece and the die during the forging operation. Fine graphite having a particle size distribution with about 90% of the particles below 15 microns in size is especially preferred. Such graphite is commercially available from Acheson Industries, Inc.


One or more phosphorus-based additives are included in the lubricant. The phosphorus additive reduces and eliminates burning of the lubricant at high temperatures. The phosphorus can be in any desired form, such as phosphate, ester phosphate, phosphate amine, ammonium phosphate or mixtures thereof. One preferred phosphorous-based material is phosphate ester. Such phosphorous is commercially available from Connect Chemical (F), Ferro (USA).


The hot forging lubricant composition optionally contains one or more metallic lubricating additives. The metallic additives may be chosen from one or more of the metallic elements, including tin, bismuth, zinc, aluminum or any alloys thereof.


The lubricant composition may optionally contain additional ingredients such as dispersants, rheology modifiers, biocides, anticorrosives, extreme pressure additives, antifoam agents, wetting agents, metal soaps and mixtures thereof.


The lubricant of the present invention comprises in the range of about 1 to about 99 weight percent oil, preferably in the range of about 1 to about 70% oil and most preferably in the range of about 15 to about 40 weight percent oil. The lubricant contains in the range of about 1 to about 99 weight percent graphite, preferably in the range of about 1 to about 30 weight percent graphite and most preferably in the range of about 3 to about 20 weight percent graphite. The lubricant contains in the range of about 1 to about 99 weight percent phosphorous additive, preferably in the range of about 1 to about 80 weight percent phosphorous additive and most preferably in the range of about 30 to about 80 weight percent of the phosphorous additive.


A further embodiment of the invention comprises a method for forging an article. The method comprises the steps of applying the lead-free lubricant to one or both of the forging apparatus or the workpiece to be forged. The workpiece is inserted into the forging apparatus and forged into the desired article. The forging apparatus is opened and the article is easily removed due to the presence of the lubricant. In an alternative embodiment, the workpiece is inserted before the application of the lubricant and the workpiece and die surface are then lubricated simultaneously


The invention is further illustrated by the following non-limiting example:


Example. A lubricant composition may be produced by adequately mixing the raw materials together via standard mixing techniques, such as mastication of stirring. The composition of the samples is shown in Table 1.









TABLE 1







Lubricant Sample Composition










Ingredient
Weight Percent







Vegetable/Animal Oil
 15%



Fine Graphite
4.4%



Mineral Oil
3.2%



Metal containing Fatty
3.2%



Acid Derivative



Phosphate Ester
 73%



Dispersant
0.2%










The lubricant composition of Table 1 was applied on hot forging dies at temperatures of 440° C.±40° C. The dies were utilized for a series of hot aluminum forging applications and the lubricant did not produce flames during the process. In addition, the lubricant properties relating to the die and the aluminum part being forged were superior.


Many modifications and variations of this invention can be made without departing from its spirit and scope, as will be apparent to those skilled in the art. The specific embodiments described herein are offered by way of example only, and the invention is to be limited only by the terms of the appended claims, along with the full scope of equivalents to which such claims are entitled.

Claims
  • 1. A lead-free lubricant for hot forging comprising one or more oils, graphite and one or more phosphorus-based additives.
  • 2. The lubricant of claim 1, further comprising one or more metallic lubricating additives.
  • 3. The lubricant of claim 1, wherein the one or more oils are selected from the group consisting of mineral oil, vegetable oil, animal oil, synthetic oil, semi-synthetic oil or mixtures thereof.
  • 4. The lubricant of claim 1, wherein the graphite is selected from the group consisting of coarse, fine, milled, unmilled, natural, synthetic or mixtures thereof.
  • 5. The lubricant of claim 1, wherein the phosphorus-based additive is selected from the group consisting of phosphate, ester phosphate, phosphate amine, ammonium phosphate or mixtures thereof.
  • 6. The lubricant of claim 1, wherein the phosphorus-based additive is phosphate ester.
  • 7. The lubricant of claim 2, wherein the one or more metallic additives are selected from the group consisting of bismuth, zinc, tin, aluminum or any alloys thereof.
  • 8. The lubricant of claim 1, wherein the one or more oils comprise in the range of about 1 to about 99 weight percent of the lubricant.
  • 9. The lubricant of claim 1, wherein the one or more oils comprise in the range of about 1 to about 70 weight percent of the lubricant.
  • 10. The lubricant of claim 1, wherein the one or more oils comprise in the range of about 15 to about 40 weight percent of the lubricant.
  • 11. The lubricant of claim 1, wherein the graphite comprises in the range of about 1 to about 99 weight percent of the lubricant.
  • 12. The lubricant of claim 1, wherein the graphite comprises in the range of about 1 to about 30 weight percent of the lubricant.
  • 13. The lubricant of claim 1, wherein the graphite comprises in the range of about 3 to about 20 weight percent of the lubricant.
  • 14. The lubricant of claim 1, wherein the one or more phosphorus based additives comprise in the range of about 1 to about 99 weight percent of the lubricant.
  • 15. The lubricant of claim 1, wherein the one or more phosphorus based additives comprise in the range of about 1 to about 80 weight percent of the lubricant.
  • 16. The lubricant of claim 1, wherein the one or more phosphorus based additives comprise in the range of about 30 to about 80 weight percent of the lubricant.
  • 17. The lubricant of claim 1, further comprising one or more of the group consisting of dispersants, rheology modifiers, biocides, anticorrosives, extreme pressure additives, antifoam agents, wetting agents, metal soaps or mixtures thereof.
  • 18. The lubricant of claim 1, wherein the lubricant does not burn at temperatures greater than about 300° C.
  • 19. The lubricant of claim 1, wherein the lubricant does not burn at temperatures in the range of about 300° C. to about 600° C.
  • 20. A method of hot forging an aluminum or aluminum alloy comprising the steps of applying a coating of the lead-free lubricant of claim 1 to a hot forging apparatus, inserting a workpiece into the apparatus and forging an article from the workpiece.
  • 21. The method of claim 20, further comprising the step of coating the workpiece with the lubricant.