Patent Application
20100222244
The present invention relates to the use of non fluorinated aromatic polymers as additives for fluorinated lubricants.
More specifically the present invention relates to fluorinated lubricant compositions having improved thermal stability at high temperatures in oxidizing environment and in the presence of metals, in particular at temperatures higher than 200° C.
In particular the present invention relates to the use of polymers containing aromatic rings as additives to stabilize perfluoropolyether oils in lubricant compositions at high temperatures in oxidizing environment and in the presence of metals, preferably at temperatures higher than 200° C.
It is known that perfluoropolyether oils (PFPE) at high temperatures in the presence of metals and in oxidizing environment suffer degradative processes causing the break of the perfluoropolyether chains producing volatile products. Therefore the loss of the lubricating performances of the perfluoropolyether oil or of the grease containing the perfluoropolyether oil occurs.
For overcoming this drawback numerous known additives in the prior art are generally used to stabilize the perfluoropolyether oils at high temperatures in oxidizing environment and in the presence of metals thus guaranteeing their stability during the use.
The stabilizing additives for perfluoropolyether oils are generally fluorinated compounds and contain in their molecule fluorinated chains, preferably perfluoropolyether chains, in order to be solubilized and/or dispersed in the perfluoropolyether oils. Some examples of said known additives of the prior art can be mentioned.
U.S. Pat. No. 4,681,693 describes soluble stabilizers having a structure formed of arylphosphines, or their derivatives, for perfluoropolyether lubricants or perfluoropolyether containing greases.
EP 597,369 describes perfluoropolyether-based phosphazene derivatives stabilizers for perfluoropolyether oils.
Patent application US 2003/0203823 describes perfluoropolyethers having dinitroaryl end groups or stabilizers for fluorinated lubricants.
The prior art fluorinated additives are liquid and generally are used in fluorinated lubricating compositions in amounts generally ranging between 1% and 10% by weight. The higher the additive amount the higher the stabilization in the time and thus higher the lubricant life. The amount of additive is about 1% by weight in the applications wherein the part to be lubricated can be subjected to high peak temperatures for short times but the service temperature is not particularly high. For more severe applications wherein a continued use at high temperatures, higher than 200° C., is required, it is necessary to increase the additive amount, generally to values higher than about 5% by weight.
The drawback of using liquid stabilizing additives in high amounts in the preparation of fluorinated greases resides in that the ratios between the liquid component of the grease (the oil plus additive) and the solid component of the grease (the thickener) are changed. High amount increase of the liquid causes an increase of the liquid separation from the solid as the temperature increases, thus changing the initial grease consistency. The oil separation becomes significant at temperatures higher than 200° C. Furthermore, as the working temperatures increase, the liquid additives tend to evaporate more easily.
The need was felt to have available additives for fluorinated lubricants, in particular perfluoropolyether lubricants showing the following combination of properties:
The Applicant has unexpectedly and surprisingly found particular additives capable to solve the above technical problem.
An object of the present invention is the use of a solid polymer at room temperature having a softening or a melting point higher than 150° C., preferably higher than 200° C., and containing in repeating unit at least one aromatic ring, preferably in the backbone, as additive to stabilize fluorinated lubricants, preferably perfluoropolyether oils at high temperatures, preferably higher than 200° C.
The aromatic polymer is preferably selected from non fluorinated polymers, solid at room temperature, having a softening or a melting point higher than 200° C. and containing in the repeating unit at least one aromatic ring, optionally substituted. The polymer can be selected for example from the following classes:
—Ar—COO—; —OCO—Ar—COO—; —Ar—COOR;
Generally the molecular weight (or the number average molecular weight) of the polymer is in the range 500-100,000, preferably 1,000-50,000, more preferably 1,500-30,000; n is an integer such as to obtain the above molecular weight.
The above polymers are solid at room temperature and are in powder form, having an average size preferably in the range 0.1 μm-1,000 μm, more preferably 50 μm-300 μm, still more preferably 1 μm-30 μm.
It is surprising and unexpected that non fluorinated polymers as defined above, and thus not containing fluorinated chains, in particular perfluopolyether chains, are able to stabilize fluorinated oils, in particular perfluoropolyether oils at high temperatures in the presence of metals in oxidizing environment.
The polymers of the invention are used in amounts between 0.1% and 50% by weight, preferably between 1% and 10% by weight, more preferably between 2% and 7% by weight.
A further object of the present invention are fluorinated lubricant compositions comprising (% by weight):
Component A) is preferably selected from the following classes:
The preferred perfluoropolyether oils are those of the classes (1), (4), (5), (8) or their mixtures and are available on the market with the trademark FOMBLIN® and marketed by Solvay Solexis S.p.A.
Component B), when present, can be selected from the thickneners known in the prior art for perfluoropolyether oils, for example talc, silica, boron nitride, PTFE, or mixtures thereof. When silica is used, the amounts generally range from 1% to 10% by weight with respect to the total of the composition; when talc, boron nitride or PTFE are used, the amounts can range from 5% to 40% by weight with respect to the total, more preferably from 5% to 35%.
Preferably PTFE in powder is used as component B), more preferably PTFE having an average particle size between 0.01 μm and 0.3 μm. The PTFE can be obtained by the known polymerization techniques, in particular by microemulsion, emulsion or dispersion. Furthermre, it can also be subjected to irradiation. Known processes for preparing said polymer are described in patent application US 2005/0075250 and in patents U.S. Pat. No. 4,864,006, U.S. Pat. No. 6,297,334, U.S. Pat. No. 6,576,703.
Component C) is the above defined aromatic polymer. The above polymers of the classes from (a) to (g) are marketed by Solvay Advanced Polymers (SAP).
The amount of component C) preferably ranges from 0.1% to 10% by weight, more preferably from 2% to 7% with respect to the perfluoropolyether oil, when it is used as additive in the lubricant compositions. Component C) can be present in larger amounts, up to 50% when it is used in greases not containing thickeners.
Component D) is preferably selected from the known additives of the prior art, for example it can be mentioned, as antiwear additives, molybdenum sulphide, molybdenum organic compounds, boron nitride, graphite, phosphazene derivatives, in particular phosphazene derivatives as those described in U.S. Pat. No. 5,124,058 and in patent application US 2003/0176738 in the name of the Applicant. As antirust additives, the disodic sebacate, functionalized derivatives of carboxylic acids, as described in U.S. Pat. No. 6,025,307, can be mentioned.
The compositions of the present invention can be in the form of oils or greases.
The lubricant compositions of the present invention are prepared according to the prior art procedures.
A preferred embodiment for preparing a grease comprises the following steps:
When component D) is liquid, it is premixed in the oil(s) before the addition of the solid components B) and C); when component D) is solid, it is premixed with components B) and C).
The grease obtained by the present process is ready to be used.
The grease consistency depends on the total concentration of B) and C). As a matter of fact, by suitably using B) and C) in the above concentration ranges, all the greases of the penetration NLGI classes can be obtained, as defined in the ASTM D217 method.
The lubricating compositions of the present invention show an improved thermal stability, in particular in applications where a continuous service temperature higher than 200° C., in the presence of metals and in oxidizing environment, is required.
As said, the lubricating compositions of the invention can be in the form of oils or greases. The Applicant has indeed surprisingly and unexpectedly found that component C) is also able to thicken the perfluoropolyether oils. As a matter of fact, when component B) is absent, the compositions of the present invention are under the form of greases when C) is in amounts higher than 10%.
Besides, tests carried out by the Applicant have shown that the fluorinated greases obtained from the components A) and C) show an improved combination of properties, that is a higher thermal stability in combination with a lower oil separation, in comparison with known fluorinated greases obtained from components A) and B), the penetration being the same (see the comparative Examples). In particular A) plus C) compositions show, besides an improved thermal stability in the presence of metals at high temperatures and a lower oil separation, also an improved wear value with low and high loads and an improved resistance to corrosion in comparison with the compositions obtained from A) and B) (see the Examples).
Component C) can also be a polymer having a low number molecular weight polymer (oligomer), generally lower than 500, and thus appearing in the form of a liquid. Also in this case the additive C) is capable to stabilize the perfluoropolyether oil in oxidizing environment and in the presence of metals when used in grease compositions.
Some illustrative but not limitative Examples of the invention follow.
Penetration
Thermooxidative Stability Test in the Presence of Metals
Oil Separation
Four-Ball Wear Test
Estreme-Pressure Four-Ball Wear Test
Emcor Test
A composition of the invention is prepared by mixing 332.5 g of component A) formed of a perfluoroplyether oil of class (5), commercially known as Fomblin® M30, 142.5 g of component B) formed of PTFE in powder, commercially known as Algoflon® L206, and 25 g of powder of component C) formed of the polymer of the class a) having the following structure:
with n=74, having a first melting temperature of 280.5° C.
A homogeneous grease is obtained which shows a penetration value of 285 mm/10′.
The grease is then subjected to the thermooxidative stability test in the presence of metals carried out at 250° C.
After 24 h a percent weight loss of 1.5% is determined. After 72 h a loss of 2.1% is determined.
The oil separation test resulted equal to 7.4% by weight.
The Example 1 is repeated, wherein at the place of component C), 25 g of the stabilizing additive having a perfluoropolyether basis described in the Example 1 of patent application US 2003/203,823, are used, of formula
wherein the number average molecular weight of the perfluoroplyether chain is 1,996 and m/n=1.2.
A homogeneous grease is obtained showing a penetration value of 290 mm/10′.
The grease is then subjected to the thermooxidative stability test in the presence of metals carried out at 250° C. After 24 h a percent weight loss of 0.1% is determined. After 72 h a loss of 0.3% is determined.
The oil separation test resulted equal to 9.5% by weight.
The Example 1 is repeated, without component C).
A homogeneous grease showing a penetration value of 287 mm/10′ is obtained.
The grease is then subjected to the thermooxidative stability test in the presence of metals carried out at 250° C. After 24 h a loss of 48.2% is determined. After 72 h a loss of 58%, corresponding to the almost total loss of component A) is determined.
The oil separation test resulted equal to 7.5% by weight.
The comparison of the data relating to the oil separation of the Examples 1-3 shows that, the penetration being equal, the perfluoropolyether greases of the present invention containing solid stabilizing additives show a good stability in combination with a lower basic oil separation in comparison with the known greases containing liquid stabilizing additives; besides, said reduced separation results comparable with the separation occurring in the greases as such, that is not containing additives.
The Example 1 is repeated, wherein component C) is selected in the class (b) and corresponds to the poly(2,6-diphenyl-1,4-phenylenoxide), having melting point of 460° C., commercially known as Tenax®-TA 80/100.
A homogeneous grease showing a penetration value of 278 mm/10′ is obtained.
The grease is then subjected to the thermooxidative stability test in the presence of metals carried out at 250° C. After 24 h a percent weight loss of 1.3% is determined.
Furthermore the oil separation test resulted equal to 6.4% by weight.
The Example 4 is repeated, wherein component C) is selected in the class (b) and corresponds to the polyphenylenoxide, wherein R═R′═H, commercially known as PPO® SA120, having Mn=2350 and softening point of 210° C.
A homogeneous grease showing a penetration value of 281 mm/10′ is obtained.
The grease is then subjected to the thermooxidative stability test in the presence of metals carried out at 250° C. After 24 h a percent weight loss of 1.6% is determined.
The oil separation test resulted equal to 5.6% by weight.
The comparison of the data of the Examples 4-5 with those of the Example 3 (comparative) shows that the non fluorinated polymers used in the present invention are capable to stabilize the perfluoropolyether lubricants at high temperatures.
Besides the greases of the present invention show a lower oil separation in comparison with the greases not containing any additive, the penetration being equal.
The Example 1 is repeated, wherein component C) is selected in the class (f), commercially known as Xydar® SRT-400, having melting point of about 370° C.
A homogeneous grease showing a penetration value of 282 mm/10′ is obtained.
The grease is then subjected to the thermooxidative stability test in the presence of metals carried out at 250° C. After 24 h a percent weight loss of 0.6% is determined.
The oil separation test resulted equal to 5.9% by weight.
A composition of the invention is prepared by mixing 640 g of component A) formed of a perfluoropolyether oil of class (5), commercially known as Fomblin® M30, and 360 g of component C) formed of the same polymer described in the Example 1.
A homogeneous grease is obtained which is characterized as penetration, oil separation, wear, E.P. 4-ball wear.
The obtained results are the following:
The Example 7 is repeated, wherein component C) is absent, by using 700 g of the oil of the Example 1 and 300 g of polytetrafluorethylene (PTFE) commercially known as Algoflon® L206.
The so obtained grease has been subjected to the same characterizations reported in the Example 7 and the following results were obtained:
The comparison of the data of the Example 7 with those of the Example 8 (comparatve) shows that the polymer C) of the present invention, besides conferring an improved thermal stability and a lower oil separation, is also able to thicken the perfluooropolyether oils giving rise to greases showing, furthermore, improved wear and corrosion properties in comparison with greases containing PTFE as thickener, the penetration being comparable.
| Number | Date | Country | Kind |
|---|---|---|---|
| M12006A 000066 | Jan 2006 | IT | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2007/050245 | 1/11/2007 | WO | 00 | 7/10/2008 |
