Patent Application
20230202224
The present invention generally relates to a machine-readable optical security device (MrOSD) that is suitable for use in securing (i.e., authenticating and/or aestheticizing) high security products such as high value articles of manufacture or high value documents. The MrOSD includes an optical security device (OSD) coupled to a Mr-component having a characteristic machine readable signature (Mr-signature) such as an infrared (IR) and/or ultraviolet (UV) signature, which may also be visible in reflection or in transmission. The Mr-component imparts a characteristic Mr-signature to the OSD such that the OSD, when coupled along with the Mr-component to a high security product, is identifiable by a signature detector. As such, when the MrOSD is coupled to a high security product, such as a banknote, the signature detector can thereby identify the presence/absence of the OSD and thereby authenticate the high security product. The OSD is a transparent/translucent micro-optic security device through which the signature of the Mr-component can be read by the signature detector.
Optical materials are often employed to authenticate banknotes and other high security products and to provide visual enhancement of manufactured articles and packaging. Such materials have evolved mainly from a drive to resist counterfeiting of certain high value documents or high value articles and/or to render such counterfeiting attempts obvious. Examples of optical materials used in anti-counterfeiting applications include image systems that rely on arrays of lenticular or cylindrical structures or arrays of microlenses to project images that exhibit one or more mobile effects when the optical materials are viewed from varying points of view. Because of these mobile effects, the projected images cannot be effectively reproduced using traditional or contemporary printing and/or photocopying processes.
Optical materials based upon the concept of moiré magnification have been and are currently used in anti-counterfeiting applications. Such materials are typically multi-layered materials that include a lens layer containing an array of lenses, an intermediate spacer layer, and an image layer, which contains an array of image elements (i.e., image icons). The lens layer may be located above or below the image layer (i.e., refractive or reflective optical materials, respectively). The image icons are magnified or otherwise optically altered when viewed through the lenses. Alternative optical materials do not include an optical spacer.
For refractive optical materials, an upper lens layer and an image layer are configured such that when the icons are viewed through the upper lens layer one or more images are projected. These projected images may show a number of different mobile effects when the optical material is viewed from varying points of view (i.e., upon tilting of the optical material).
Multi-layered constructions of optical materials conforming to the above descriptions, which are capable of presenting such effects are described in: U.S. Pat. No. 7,333,268 to Steenblik et al.; U.S. Pat. No. 7,468,842 to Steenblik et al.; U.S. Pat. No. 7,738,175 to Steenblik et al.; U.S. Pat. No. 7,830,627 to Commander et al.; U.S. Pat. No. 8,149,511 to Kaule et al.; U.S. Pat. No. 8,878,844 to Kaule et al.; U.S. Pat. No. 8,786,521 to Kaule et al.; European Patent No. 2162294 to Kaule et al.; European Patent No. EP2164713 to Kaule et al.; U.S. Pat. No. 8,867,134 to Steenblik et al.; and U.S. Pat. No. 10,890,692 to Jordan et al.
Optical materials based upon the concept of moiré magnification may also constitute a single layer system such as those described in U.S. patent application Ser. Nos. 15/215,952 and 15/216,286 to Gregory R. Jordan, both filed Jul. 21, 2016, and in U.S. patent application Ser. No. 14/975,048 to Cape et al., filed Dec. 18, 2015.
These single layer systems can comprise a surface and a periodic array of image relief microstructures having a periodic surface curvature disposed on or within the surface. The image relief microstructures can have a first image repeat period along a first image reference axis within the array, and the periodic surface curvature can have a first curvature repeat period along a first curvature reference axis within the array. Transmission of light through the array, reflection of light from the array, or a combination thereof forms a magnified moiré image.
The image relief microstructures can be (+)-relief or (−)-relief image relief microstructures. In some cases, the image relief microstructures can be (+)-relief image relief microstructures that upwardly project from the surface terminating in an arcuate image generating surface. In other cases, the image relief microstructures can be (−)-relief image relief microstructures that are voids formed within the surface terminating in an arcuate image generating surface. Depending on the desired appearance of the magnified moiré image, the image relief microstructures can be a positive image representation or a negative image representation.
The above-described optical materials can be utilized in a variety of different forms (e.g., strips, patches, security threads, planchettes) with any product and in particular with any security product (e.g., high security products or high value products) such as banknotes, checks, stamps, government letterheads, stock certificates, lottery tickets, other secure documents and other high value or secure commercial products, apparel, identification, passports and other government issued documents, product packaging, or the like, for authentication or aestheticizing purposes. For banknotes and secure documents, these materials are typically used in the form of a strip, patch, or thread and can be fully or partially embedded within the banknote or document, or applied to a surface thereof. For passports or other identification (ID) documents, these materials could be used as a full laminate or inlayed in a surface thereof. For product packaging, these materials are typically used in the form of a label, seal, or tape and are applied to a surface thereof.
It has long been recognized that the use of machine testable security features with security devices used on or within a security document or article offer a heightened level of security. In fact, many security products, such as secured documents, include a security device (e.g., security thread) that is disposed on or within the paper, includes one or more machine detectable/readable (Mr-) security features, such as magnetic features that serve to authenticate the security paper and prevent or deter counterfeiting. For example, in GB 2,227,451 B, a security device in the form of a security thread comprises a plastic strip. Along a surface of the plastic strip is a coating of metal and a machine readable, discontinuous track of magnetic material, which is divided into machine-readable word and termination segments.
The above-described optical materials, however, are incompatible with conventional magnetics. Magnetic materials have a degree of inherent color, which renders them visually detectable in reflected and transmitted light and thus interfere with the projected optical images and their corresponding mobile effects. This is particularly true where the magnetic color is different from the pigments used in certain micro-optic materials as contrasting materials. Moreover, other conventional security threads, patches or stripes include materials that obstruct their machine readability. For example, many of these security devices are opaque or include certain materials, such as metals or demetallized areas that interfere with the machine readability of the machine readable components. For these reasons, heretofore it has been impractical to incorporate certain machine readable features into security devices for high value documents or high value articles.
A need therefore exists for an optical material, such as a micro-optic security device, that employs a machine detectable and/or readable feature that does not interfere with the optical effects projected by the optical material and where the optical security device does not interfere with the machine-readable signature.
The present invention provides such a machine-readable optical security device (MrOSD) by avoiding at least one of the above impediments to incorporating a machine readable component into an optical security device. In a particular aspect the present invention provides an MrOSD. In one embodiment of this aspect, the MrOSD comprises an OSD component; and an Mr-component coupled to the OSD and imparting a characteristic machine-readable Mr-signature to the OSD; wherein the Mr-signature displays at least one machine readable Mr-signal within the invisible spectral range; wherein the OSD is transparent or translucent; and wherein the Mr-signature is readable, through the OSD, by a signature detector. In another embodiment, the MrOSD is an IR and/or UV machine-readable optical security device (e.g., micro-optic security thread) that comprises at least one of (i) a first IR-component having a characteristic signature (e.g., IR signature) that is detectable at two or more wavelengths (i.e., IR-wavelengths), (ii) a first UV-component having a characteristic signature (e.g., UV signature) detectable at two or more wavelengths (e.g., UV-wavelengths), (iii) a second IR-component that absorbs IR light and emits light at a different invisible wavelength, and (iv) a second UV-component that absorbs UV light and emits light at a different invisible wavelength.
In another aspect, the present invention provides a method of making an MrOSD. In one particular embodiment of this aspect, this method comprises (i) forming an OSD where the OSD at least comprises (a) a focusing layer of focusing elements, (b) an image layer of image elements disposed relative to the focusing layer such that a synthetic image is projected by the OSD when the image elements are viewed through the focusing elements; and optionally (c) at least one additional layer coupled to at least one of the focusing layer or the image layer and (ii) coupling an Mr-component to the OSD such that the Mr-component imparts a characteristic machine-readable Mr-signature to the OSD; where the Mr-signature displays at least one machine readable Mr-signal within the invisible spectral range; wherein the OSD is transparent or translucent; and wherein the Mr-signature is readable, through the OSD, by a signature detector. In another particular embodiment of aspect, this method comprises (i) forming an OSD where the OSD at least comprises (a) a focusing layer of focusing elements, (b) an image layer of image elements disposed relative to the focusing layer such that a synthetic image is projected by the OSD when the image elements are viewed through the focusing elements; and optionally (c) at least one additional layer coupled to at least one of the focusing layer or the image layer and (ii) introducing (e.g., coupling) at least one Mr-component to the OSD. For this method, the Mr-component is as described above.
In another aspect, the present invention provides a secured product. In one particular embodiment, the secured product comprises an MrOSD, as described herein, wherein the MrOSD is coupled to a substrate of a high security product. In another aspect, the present invention provides a use for the MrOSD. In one particular embodiment, this use comprises using the MrOSD to secure a high security product, wherein the MrOSD is as described herein throughout.
In another aspect, the present invention provides a sheet material and a base platform that are made from or employ the inventive MrOSD, as well as documents made from these materials.
In a particular embodiment of the aspects of the invention presented above, the optical security device of the present invention is a micro-optic security device (MOSD), such as a security thread, that comprises an IR-component with an IR signature that is detectable at two IR-wavelengths, where the ratio of absorption between the two IR-wavelengths is reliably and measurably the same when measured in transmission.
In another exemplary embodiment, the OSD of the MrOSD is a micro-optic security device (e.g., security thread) that comprises an IR-absorbing component that absorbs IR light and emits light at a different invisible wavelength and/or a UV-absorbing component that absorbs UV light and emits light at a different invisible wavelength (e.g., IR and/or UV phosphors). The emitted light may be viewed from the same side as the incident light or from an opposite side of the device.
In view of the present disclosure, various other aspects, embodiments, features and advantages of the invention will, in hindsight, be apparent to a person having ordinary skills in the art (PHOSITA).
Particular features of the disclosed invention are illustrated by reference to the accompanying drawings in which:
The term “characteristic signature”, as used herein is intended to mean a unique absorption or transmission (absorption/transmission) pattern, such as that depicted on a spectrogram of a material that is exposed to electromagnetic radiation like IR or UV. This unique pattern may include unique slopes, peaks along a wavelength/frequency scale correlating to particular spectral absorption/transmission curves, or other predetermined identifying spectral characteristics such as the width of two or more absorption/transmission peaks, the height to width relationship of two or more peaks, the ratio of absorption/transmission (height) between two absorption/transmission peaks, or changes in the curvature of the spectrum. These can include absorption/transmission maxima (peaks) and/or absorption/transmission minima and/or absorption/transmission edges at substantially the same wavelengths.
The term “coupling” or “couple”, as used herein, is intended to mean that the component is either directly or indirectly secured to another component.
The term “detectable”, as used herein, is intended to mean reliably measurable IR and/or UV absorbance (or transmittance) at two or more wavelengths using a detector that reacts to IR and/or UV radiation, when the inventive optical security device is present on or partially within a paper or polymer sheet material.
The term “imparting”, as used herein, is to be understood as adding to or enabling the OSD to be authenticated/identified, or its presence or absence to be determined, by the presence or absence of the Mr-signature.
The term “integrated”, as used herein, refers to the incorporation of the Mr-component into a layer or array of the OSD by, for example, having the Mr-component distributed in the formulation used to prepare the OSD layer.
The term “intermittent pattern”, as used herein, is intended to mean that when viewed (by machine or with a viewer that images at the appropriate wavelength) in IR or UV illumination, an optionally repeating pattern (e.g., an encoded pattern) may be seen on the micro-optic security device.
The term “integration” or “integrating”, as used herein, is intended to mean that the subject component is added to at least a bulk portion of another component of the invention.
The term “introducing”, as used herein, is intended to mean that the subject component is added to another component of the invention by integration or layering.
The term “layering”, as used herein, is intended to mean that the subject component is coupled to another component in a continuous or discontinuous layer under or over another referenced component/layer of the invention such that at least one surface of each component is substantially parallel to a surface of the other component/layer.
The term “spectral range”, as used herein refers to the relative ranges of wavelengths among the electromagnetic range including, for example, the UV-spectral range, the IR-spectral range, the visible-spectral range, the x-ray-spectral range, etc.
Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by a PHOSITA. All publications, patent applications, patents and other references mentioned herein are incorporated by reference in their entirety. In case of conflict, the present specification, including definitions, will control. In addition, the materials, methods, and examples are illustrative only and are not intended to be limiting.
As noted above, the present invention may be described in several aspects, including an MrOSD, methods of manufacturing an MrOSD, a secured product comprising an MrOSD, use of an MrOSD in securing certain security products and certain sheet materials, base platforms or documents made from an MrOSD. Particularly, the MrOSD, forming elements of these aspects of the invention, comprises an OSD and an Mr-component that is coupled to the OSD.
The optical security device (OSD) of the present invention is either (a) a multi-layered material or (b) a single-layered material. Exemplary multi-layered materials include those having one or more focusing element layers coupled to one or more image layers. At least one of the focusing element layers includes an array of focusing elements while at least one of the image layers includes an array of image elements. The focusing element layer having the array of focusing elements is layered with the image layer having the array of image elements such that when the image elements are viewed through the focusing elements, from at least one point of view, a synthetic image is projected by the OSD. It is contemplated within the scope of the present invention that the multi-layered material, in certain embodiments, includes additional layers or arrays. For example, in one such embodiment, the OSD further includes an optical spacer layer that is disposed between the image layer and the focusing element layer. Alternatively, where the OSD is a single-layered material, the single-layered construction is made up of a substrate with a surface having a periodic array of image relief microstructures and a periodic surface curvature disposed on or within the surface, which forms a magnified moiré image.
In hindsight from the present disclosure, various suitable OSDs will become apparent to a PHOSITA. For example, certain suitable OSDs are as described in U.S. Pat. No. 7,333,268 to Steenblik et al., U.S. Pat. No. 7,468,842 to Steenblik et al., and U.S. Pat. No. 7,738,175 to Steenblik et al. and these OSDs include focusing element layers formed from a variety of formulation materials such as substantially transparent or clear, colored or colorless polymers such as acrylics, acrylated polyesters, acrylated urethanes, epoxies, polycarbonates, polypropylenes, polyesters, urethanes, and the like, using a multiplicity of methods that are known in the art of micro-optic and microstructure replication, including extrusion (e.g., extrusion embossing, soft embossing), radiation cured casting, and injection molding, reaction injection molding, and reaction casting. High refractive index, colored or colorless materials having refractive indices (at 589 nm, 20° C.) of more than 1.5, 1.6, 1.7, or higher, such as those described in U.S. Patent Application Publication No. US 2010/0109317 A1 to Hoffmuller et al., may also be used in the practice of the present invention. Materials and methods for providing the image layer, spacer layer and additional layers are likewise suitably disclosed in the above incorporated patent documents.
Though various methods of manufacturing the OSD will be apparent in view of the present disclosure, an exemplary method of manufacturing the multi-layered construction comprises forming the image layer by forming an array of image elements, in a radiation cured liquid polymer (e.g., acrylated urethane) that is cast against a base film (i.e., an optical spacer), such as 75 gauge adhesion-promoted polyethylene terephthalate (PET) film; forming the focusing element layer by forming an array of focusing elements in a radiation cured polymer disposed on the opposite face of the base film. Suitable image elements and methods of providing them are described in International Patent Application Publication Nos. WO/2005/052650, WO/2006/125224, WO/2008/008635, WO/2011/019912, WO/2011/163298, WO/2013/028534, WO/2014/143980, WO/2009/017824, WO/2016/044372, WO/2016/011249, WO/2013/163287, WO/2007/133613, WO/2012/103441, WO/2015/148878, WO/2005/106601, and WO2006/087138, which are all incorporated herein in their entirety. In preferred embodiments, the image elements are in the form of voids, solid regions, protrusions, or any combination thereof. Suitable focusing elements and methods of providing them are described in International Patent Application Publication Nos. WO/2005/052650, WO/2006/125224, WO/2008/008635, WO/2011/019912, WO/2011/163298, WO/2013/028534, WO/2014/143980, WO/2009/017824, WO/2016/044372, WO/2016/011249, WO/2013/163287, WO/2007/133613, WO/2012/103441, WO/2015/148878, WO/2017/105504, WO/2005/106601, and WO/2006/087138, which are all incorporated herein in their entirety. In preferred embodiments, the focusing elements are microlenses. The array of focusing elements and the array of image elements are disposed on opposing sides of the base film and are oriented (array alignment or skew) relative to each other such that when the image elements are viewed through the focusing elements a desired synthetic image is projected. Preferably, the image elements are coupled with a contrasting material thereby enhancing the optical effect of the synthetic image. For example, the contrasting material may be coupled to the image elements by coating (e.g., full, partial, or patterned) the front or back of the voids and/or solid regions, by filling the voids, or by coating (e.g., full, partial or patterned) the protrusions. In a preferred embodiment, the image elements are voids that are filled, or substantially filled, with a contrasting material, thereby providing improved contrast between the images projected from the void areas and the surrounding solid regions. Various suitable contrasting materials will be apparent in view of the present disclosure, however Applicant has found it most suitable to use an ink, dye or pigment with sub-micron particle/pigment size. Applying the contrasting material to the image elements may be by gravure-like doctor blading against the film surface, followed by solidifying the filling of contrasting material by suitable means (e.g., solvent removal, radiation curing, or chemical reaction).
Materials, formulations and methods of manufacturing the above-mentioned single-layered construction of the OSD are described in U.S. patent application Ser. Nos. 15/215,952 and 15/216,286, both filed Jul. 21, 2016, and in U.S. patent application Ser. No. 14/975,048, filed Dec. 18, 2015.
The optical security device of the present invention may further comprise additional features and layers, such as those described in U.S. Pat. No. 7,333,268 to Steenblik et al., U.S. Pat. No. 7,468,842 to Steenblik et al., and U.S. Pat. No. 7,738,175 to Steenblik et al. For example, the inventive device may further comprise additional layers (e.g., embedding, sealing or obscuring layers), textured surfaces for better adhesion to further layers, adhesion promoters, etc.
In one such embodiment, the inventive optical security device advantageously contains an obscuring layer on the side of the OSD proximate the image layer of the multi-layer material, or on the backside of the single-layer material, the obscuring layer serving to conceal the device when viewed from the underside of a host sheet material (e.g., a banknote).
The OSD of the present invention is preferably transparent or translucent such that the Mr-component can be readily and/or reliably read by the signature detector through the OSD without the Mr-component interfering (i.e., reducing image resolution, distorting, or blocking) with the synthetic image. As such the layers of the OSD, whether in multi-layered or single-layered construction, must allow such transparency or translucency.
As noted, the MrOSD includes an Mr-component. Various suitable Mr-components will become apparent to a PHOSITA in hindsight of the present disclosure. The Mr-component is coupled with the OSD by integrating one or more of such Mr-components into one or more layers of the inventive MrOSD, or the Mr-component(s) is coupled with the OSD by applying a discrete layer(s) (e.g., Mr-layer) by, for example, coating the Mr-component onto a layer, or between layers, of the OSD or by separately forming an Mr-component layer (e.g., Mr-layer) and subsequently coupling that Mr-layer to the OSD. The Mr-component can be integrated as a mixture, dispersion, solution, emulsion or the like into a layer of the OSD. Other alternative means of integrating the Mr-component with the OSD layer(s) will be apparent, in view of the present disclosure. A discrete layer as used herein is to be understood as a layer that is bordered by a defined interface separating/connecting the OSD layer from/to the Mr-component. Preferably, the Mr-component is a separate layer(s) that is applied or added to the OSD. The Mr-component, whether integrated or discrete, may be present in a continuous fashion (i.e., a solid block) or may be in the form of an intermittent pattern or random distribution. Patterns incorporated herein may provide aesthetics or may provide a unique readable signature. In one embodiment, the pattern is in the form of at least one of horizontal bars, chevrons or zig zags, angled bars, shapes, indicia, or the like, or combinations thereof, and may be visible in reflection, or more likely in transmission at the prescribed wavelengths. Preferably, the pattern is arranged to provide a distinct and recognizable signal when read by a machine. In a particular embodiment, the pattern is a set of equally sized blocks, a set of variable sized blocks, or a set of text.
It is generally contemplated herein that the Mr-component is an ink vehicle and can be incorporated in the various embodiments described herein. Such ink vehicles can be transparent or pigmented. In one particular embodiment, the MrOSD comprises an OSD coupled to the Mr-component and where the Mr-component is at least one of an IR-absorbing IR-component and a UV-absorbing UV-component(s). In a further particular embodiment, this Mr-component is in the form of an ink vehicle, and is coupled to the OSD by being mixed in with a formulation used to make an opacifying layer of the OSD. While not always the case it is contemplated herein that the quantity of the Mr-components may be varied, in this particular embodiment, the IR-absorbing or UV-absorbing Mr-component(s) is present in the ink vehicle in a quantity ranging from about 30 to about 70% by wt. A quantity of the ink vehicle ranging from about 30 to about 70% by wt. is added to the formulation used to make the opacifying layer. The thickness of the opacifying layer, in this exemplary embodiment, ranges from about 0.5 to about 5 microns.
In another exemplary embodiment, the Mr-component(s) is applied between the image layer and the opacifying layer of the inventive optical security device.
In yet another exemplary embodiment, the Mr-component(s), in the form of a coating composition, is used to form a layer directly or indirectly on the image layer, which serves to replace the opacifying layer or which constitutes an additional layer(s). A pattern can be formed through the coating process by use of a mask allowing selected intermittent areas to be coated. If applied as a separate layer, the coating composition may be applied between two opacifying layers. The resulting layer may be at least as thick as each opacifying layer.
The various Mr-components are detectable by various means known or apparent to a PHOSITA including various known IR-machines, UV-machines and the like. As noted, the Mr-component may be selected from (i) a first IR-component imparting an Mr-signature to the OSD which includes at least two Mr-signals, that are detectable, at 2 or more wavelengths within the IR spectral range, (ii) a first UV-component imparting an Mr-signature to the OSD which includes at least two Mr-signals, that are detectable, at 2 or more wavelengths within the UV spectral range, (iii) a second IR-component that absorbs IR-light of a first wavelength and emits light at a second different wavelength, and (iv) a second UV-component that absorbs UV-light and emits light at a second a different wavelength. The Mr-signature is a predetermined characteristic set of Mr-signals. These characteristic set of Mr-signals can be detected by, for example, a spectrometer that provides a graphical display of the Mr-signals. These Mr-signals may be plotted on a graph having an x-axis of wavelengths and a y-axis of % transmittance or % absorption over a range of wavelengths and a range of % transmittance/absorption. As such the Mr-signature may include various Mr-signals (peaks, valleys, area under curve, distance between peaks or valleys, slope between particular peaks or valleys, etc.). As noted, the second IR-component absorbs light within the IR-spectral range and emits light at a second and different wavelength. In a preferred embodiment, the second and different wavelength is within a separate invisible spectral range. However, it is also contemplated herein that the second and different wavelength is either in the visible spectral range or is within the same spectral range as the absorption. This is likewise for the second UV-component.
In one embodiment, the MrOSD comprises an OSD component coupled to an Mr-component, as described herein, where the Mr-component is an IR-absorbing IR-component. This IR-component is presented as an ink vehicle having an IR-taggant distributed therein that is detectable at a predetermined wavelength (or set of wavelengths) within the IR-spectral range. Alternatively, the Mr-component is a UV-absorbing UV-component, where said UV-component is presented as an ink vehicle having a UV-taggant distributed therein, that is detectable at a predetermined wavelength (or set of wavelengths) within the UV-spectral range.
Various suitable Mr-components are selected based on the desired predetermined wavelengths at which the Mr-signals are desired. Accordingly, various predetermined wavelengths are contemplated. For example, in certain embodiments where the MrOSD includes a first IR-component and/or a first UV-component, each are independently detectable at 2 or more wavelengths and in a particular embodiment, the IR-component is detectable within a spectral range from about 750 nm to about 850 nm (preferably about 800 nm) (with about 70-80% absorption; preferably 75%) and about 850 nm to about 950 nm (preferably 870 nm-890 nm) (with about 75-80% absorption; preferably about 77-78% absorption) while the UV-component, if present, is detectable at about 10 nm to about 400 nm (preferably about 200-300 nm; preferably 275 nm) (with about 70-80% absorption; preferably 75% absorption) and about 300-400 nm (preferably 350 nm) (with about 75-85% absorption; preferably 80% absorption). In one exemplary embodiment, the Mr-component includes an IR-absorbing component where this component is detectable, by an IR-machine, only in the infrared region of the electromagnetic spectrum or it may be detectable in the infrared region and observable (and possibly also machine detectable) in the visible regions of the spectrum. In a preferred embodiment, the IR-absorbing component is detectable in the near-infrared (NIR) region of the electromagnetic spectrum.
The Mr-component in one embodiment is selected from the group of suitable IR-taggants and the group of IR-detectable pigments forming part of an ink vehicle. Suitable pigments and taggants are described in U.S. Pat. No. 6,926,764, which is incorporated herein in its entirety. Accordingly, the ink vehicle can be an ink set comprising a first set of ink including an IR-taggant with a first Mr-signal, and a black, yellow or magenta dye; and a second set of ink including a pigment with a second Mr-signal; wherein the first Mr-signal and the second Mr-signal are substantially the same; and wherein the ink set includes at least two inks of different colors. Preferably the second ink set include cyan having a pigment which provides a Mr-signature with at least one Mr-signal that is substantially the same as at least one Mr-signal provided by the IR-taggant. As such, the substantially the same Mr-signals are within 10 nm of each other. Particularly, in a preferred embodiment, the IR-taggant is a phthalocyanine and preferred pigments are crystallographic X-forms of phthalocyanine. In more preferred embodiments, the IR-taggant is at least one of a substituted phthalocyanine, a naphthalocyanine, a metal-containing phthalocyanine or a poly-substituted phthalocyanine or combinations thereof. Benzenethiol-substituted copper-phthalocyanines are preferred IR-taggants; more preferably para-toluenethiol-persubstituted copper-phthalocyanine of the formula:
In one such embodiment, the IR-absorbing component is an IR-reactive pigment sold as part of an ink or ink vehicle under the trade designation SICPATalk by SICPA SA, Av de Florissant 41, 1008 Prilly, Switzerland. The pigment may be an organometallic pigment such as a metal-containing phthalocyanine pigment which absorbs or reflects more than 75% of any near IR light when viewed in transmission (% T<25% from 750-950 nm), and which is viewable at the following wavelengths: 750 nm; and 900 nm. The ratio of absorption between the two IR-wavelengths is equal to about 35 percentage points. This pigment has an off-white body color in the visible region of the electromagnetic spectrum.
Suitable IR-absorbing components are described in GB 2,168,372, where certain IR- or UV-absorbing materials that are invisible or transparent in the visible region are disclosed, and in WO 90/1604 where certain IR-taggants are described, which exhibit narrow absorption characteristics; those including rare earth compounds. Other suitable IR-absorbing components are described in EP 553614 where certain phthalocyanines are used as a printing ink and provide spectral absorption in the wavelength range of 700 to about 1200 nm. EP 484018 describes suitable phthalocyanines having absorption wavelengths maximum between about 680 and 900 nm. EP 408191 describes substituted phthalocyanines with characteristic wavelength absorptions in the range of 700 to 1500 nm that are also suitable in the present invention. Naphthalocyanine compounds are also suitable and are described further in EP134518 as IR-absorbers the absorbing near IR (NIR) radiation in the spectral range of 750 to 900 nm, which may be used as dyes or pigments.
In another such embodiment, the IR-absorbing component is an IR-reactive pigment sold as part of an ink or ink vehicle under the trade designation LUMOGEN-S by BASF Corporation, 100 Park Ave., Florham Park, N.J. 07932. This pigment is invisible in the visible region of the electromagnetic spectrum.
The ink or ink vehicle may be added to one or more layers of the optical security device, or it may be used to prepare one or more coatings or separate layers that are applied or added to the device. In the above embodiment, the ink vehicle is either mixed in with a composition used to form a pigmented or obscuring layer on the print or object layer, or is used to make a coating or separate layer that is applied or added to the pigmented or obscuring layer.
When the ink vehicle is mixed in with a composition used to from a pigmented or obscuring layer, the pigmented sealing or obscuring layer can be formed using one or more of a variety of opacifying coatings or inks, which include both solvent and solvent-free coatings or inks (both curing and non-curing). In an exemplary embodiment, the sealing or obscuring layer is formed using a pigmented coating comprising a pigment, such as titanium dioxide, dispersed within a binder or carrier of curable polymeric material. Preferably, the sealing or obscuring layer is formed using radiation curable polymers and has a thickness ranging from about 0.5 to about 5 microns.
When used to make a coating or separate layer that is applied or added to the pigmented or obscuring layer, the ink or ink vehicle may be used alone or added to an existing formulation.
In one embodiment, the Mr-signature includes at least two Mr-signals in the invisible spectral range. Here the at least one of the Mr-signal is in the visible and/or UV-spectral range and at least one Mr-signal is in the IR-spectral range. Alternatively, the Mr-signal is in the visible and/or IR-spectral range and at least one Mr-signal is in the UV-spectral range. In a further embodiment, the Mr-signature includes at least one Mr-signal in the near IR-spectral range (NIR).
In one embodiment, the IR-absorber imparts an Mr-signature that includes a first absorption at a first wavelength and a second absorption at a second wavelength where the first absorption is lower than the second absorption and the first wavelength is lower than lower than the second wavelength. As such, the slope of the Mr-signature over this wavelength range is a negative slope thereby giving the OSD a characteristic signature readily identifiable and detectable by a signature detector. In a preferred embodiment, this Mr-signature is displayed as a positive slope if the MrOSD is missing, tampered with or is otherwise not authentic.
The invention also provides a secured product comprising the MrOSD, wherein the MrOSD is coupled to a substrate of a high security product. As noted, a high security product includes high value articles and high value documents. The MrOSD may be embedded within the substrate or layered over the surface of the substrate and thereby affixed by a suitable adhesive element. Examples of suitable adhesive elements include pressure, heat or water activated adhesives. Naturally, other adhesive elements will be apparent in view of the present disclosure.
In a preferred embodiment of the secured product, an OSD is at least partially embedded within a paper banknote and the IR-component is present in an amount ranging from about 0.5 gsm to about 5 gsm; more preferably from about 2 gsm to about 3.5 gsm. Applicant has found that surprisingly the emission from the IR-absorbing component is most reliably detectable when within these ranges. Alternatively, where the OSD is embedded in a polymeric security document, such as a polymeric banknote, the IR-absorbing component coupled to the OSD is present in an amount ranging from about 0.5 gsm to about 5 gsm, preferably, from about 2 gsm to about 3.5 gsm in order to enable detection. Suitable infrared detectors for detecting infrared rays in the near-, middle- and far-infrared wavelength ranges include: an LED or incandescent IR emitter in combination with a line scanner, CCD camera, photodiode or other similar detection device.
The invention also provides a use for the MrOSD to secure high security products. As such the MrOSD when coupled to a high security product, is able to thwart counterfeit attempts by being able to authenticate the high security product or aestheticize the high security product. For example, the MrOSD provides a predetermined characteristic Mr-signature to the high security product such that a missing or tampered OSD will be indicated by a recognizable difference in the Mr-signature that is distinguishable from the predetermined characteristic Mr-signature.
The invention also provides a method of making the MrOSD. In one embodiment, this method comprises (i) forming an OSD which at least comprises (a) a focusing layer of focusing elements, and (b) an image layer of image elements disposed relative to the focusing layer such that a synthetic image is projected by the OSD when the image elements are viewed through the focusing elements; and optionally (c0 at least one additional layer; and (ii) introducing at least one Mr-component to the OSD. The Mr-component is as described herein. Likewise, the Mr-component is coupled to the OSD as described herein.
When the inventive optical security device is used in paper (e.g., paper banknotes or documents), or applied to a surface of the paper, in order to be detectable (i.e., reliably measurable) the signal intensity or the height of the absorption/transmission peaks generated by the IR-reactive pigment is preferably greater than about 10 percent (%) (more preferably, greater than about 25%) of the noise level or signal intensity of the surrounding paper.
When the inventive optical security device is used in polymer sheet materials (e.g., polymer banknotes or documents), or applied to a surface of the polymer sheet material, in order to be detectable (i.e., reliably measurable) the signal intensity or height of the absorption/transmission peaks generated by the IR-reactive pigment is preferably greater than about 50% (more preferably, greater than about 75%) of the noise level or signal intensity of the surrounding polymer sheet material.
It is noted that while the IR or UV absorbance (or transmittance) of these Mr-components may be detectable from the isolated optical security device, once the device is placed, for example, on or partially within a paper sheet material, the effect becomes scattered or weak, which may render the effect undetectable or not reliably measurable. In an exemplary embodiment of the present invention, the polymer(s) used to make the inventive optical security device is 100% transmissive, and the optical security device is present on or partially within a paper sheet material having a basis weight ranging from about 70 to about 110 grams per square meter (g/m2 or gsm). In this exemplary embodiment, the characteristic IR-signature of the inventive MrOSD is reliably measurable in that the device absorbs or reflects more than 75 percent (%) of any near IR light when viewed in transmission (% T<25% from 750-950 nanometers (nm)).
In one exemplary embodiment, the IR-absorbing component is detectable in only the infrared region of the electromagnetic spectrum and is present in the form of a binary code. Two means for authentication are offered by way of this embodiment of the inventive optical security device, namely, the characteristic IR signature and the IR binary code.
In another exemplary embodiment, the IR-absorbing component is detectable in both the infrared and the visible regions of the electromagnetic spectrum and is present in the form of a binary code. Four means for authentication are offered by this embodiment, namely, the characteristic IR signature, the IR binary code, the visible appearance, and the visible binary code.
The UV-absorbing component used in the subject invention may be observable in only the ultraviolet region of the electromagnetic spectrum or it may be observable in both the ultraviolet and the visible regions of the electromagnetic spectrum. Similar to the IR-absorbing component, the UV-absorbing component may be present in a continuous manner or in the form of an intermittent pattern.
In one exemplary embodiment, the UV-absorbing component is observable in only the ultraviolet region of the electromagnetic spectrum and is present in the form of a binary code. Two means for authentication are offered by the inventive optical security device of this embodiment, namely, the characteristic UV signature and the UV binary code.
In another exemplary embodiment, the UV-absorbing component is observable in both the ultraviolet and the visible regions of the electromagnetic spectrum and is present in the form of a binary code. Four means for authentication are offered by this embodiment, namely, the characteristic UV signature, the UV binary code, the visible appearance, and the visible binary code.
In yet another exemplary embodiment, a combination of IR-absorbing and UV-absorbing components are present in the MrOSD. One or both of these components may also be observable in the visible region and may be present in either a continuous or intermittent pattern.
The MrOSD may be used in the form of, for example, a security strip, thread, patch, or overlay and mounted to a surface of, or partially embedded within a fibrous or non-fibrous (e.g., polymer) sheet material (e.g., banknote, passport, ID card, credit card, label), or commercial product (e.g., optical disks, CDs, DVDs, packages of medical drugs), etc., for authentication purposes. The inventive device may also be used in the form of a standalone product (e.g., substrate for subsequent printing or personalization), or in the form of a non-fibrous sheet material for use in making, for example, banknotes, passports, and the like, or it may adopt a thicker, more robust form for use as, for example, a base platform for an ID card, high value or other security document.
When used in the form of a security strip, thread, patch, or overlay, the total thickness of the inventive device is preferably less than about 50 microns (more preferably, less than about 45 microns, and most preferably, from about 10 to about 40 microns).
The security strips, threads, patches and overlays may be partially embedded within or mounted on a surface of a document. For partially embedded strips and threads, portions thereof are exposed at the surface of the document at spaced intervals along the length of the strip or thread at windows or apertures in the document.
The inventive optical security devices may be at least partially incorporated in security papers during manufacture by techniques commonly employed in the papermaking industry. For example, the inventive security device in the form of a strip or thread may be fed into a cylinder mould papermaking machine, cylinder vat machine, or similar machine of known type, resulting in partial embedment of the strip or thread within the body of the finished paper.
The security strips, threads, patches and overlays may also be adhered or bonded to a surface of a document with or without the use of an adhesive. Bonding without the use of an adhesive may be achieved using, for example, thermal welding techniques such as ultrasonic welding, vibration welding, and laser fusing. Adhesives for adhering the inventive devices to a surface of a document may be one of hot melt adhesives, heat activatable adhesives, water-activated adhesives, pressure sensitive adhesives, and polymeric laminating films. These adhesives are preferably crosslinkable in nature, such as UV cured acrylic or epoxy, with crosslinking achieved while the adhesive is in the melt phase.
Suitable documents into which the MrOSD may be integrated or otherwise embedded include those of any kind having financial value, such as banknotes or currency, bonds, checks, traveler's checks, lottery tickets, postage stamps, stock certificates, title deeds and the like, or identity documents, such as passports, ID cards, driving licenses and the like, or non-secure documents, such as labels. The MrOSD is also contemplated for use with consumer goods as well as bags or packaging used with consumer goods.
In another contemplated embodiment, the inventive device forms part of a label construction. The inventive device may be placed on the inside of a package, so that the synthetic image(s) remains visible.
When used in the form of a base platform for an ID card, high value or other security document, the total thickness of the inventive device is preferably less than or equal to about 1 millimeter (mm) including (but not limited to) thicknesses: ranging from about 200 to about 500 microns; ranging from about 50 to about 199 microns; and of less than about 50 microns.
While various embodiments of the present invention have been described above, it should be understood that they have been presented by way of example only, and not limitation. Thus, the breadth and scope of the present invention should not be limited by any of the exemplary embodiments.
The invention will be further clarified by reference to certain specific drawings reflecting certain specific embodiments of the present invention.
The Mr-component may be present in a continuous manner or in the form of an intermittent pattern. As best shown in
In one embodiment, as illustrated in
In a further exemplary embodiment, as depicted in
In another exemplary embodiment, as depicted in
In another exemplary embodiment, as depicted in
The MrOSD, in one embodiment, is illustrated by
A secured product prepared using the MrOSD of
The presence of an authentic MrOSD can be confirmed by a signature detector. An authentic MrOSD will indicate a predetermined characteristic Mr-signature. An exemplary predetermined characteristic Mr-signature (800) is depicted by
It should be understood that the Mr-component may alternatively be integrated into multiple layers of the OSD. Moreover, it is also contemplated herein that the focusing elements are reflective or a combination of refractive and reflective. Alternative predetermined Mr-signatures are also contemplated, including specific absorption or emission at specific wavelengths.
This application is a division of U.S. application Ser. No. 15/868,530, filed Jan. 11, 2018, which claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Patent Application No. 62/457,226, filed Feb. 10, 2017, the disclosures of which are incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 62457226 | Feb 2017 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15868530 | Jan 2018 | US |
| Child | 18175489 | US |
