The present invention relates to magnet assemblies in general and, more particularly, to a magnet assembly with a geometry that improves magnetic field uniformity.
Cycloidal mass analyzers are unique sector mass analyzers as they exhibit perfect double focusing, making them ideal for incorporating spatial aperture coding, which can increase the throughput of a mass analyzer without affecting the resolving power. Cycloidal mass analyzers utilize orthogonal electric and magnetic fields and the ion travel paths are coplanar with the electric field. As governed by the Lorentz force, the perpendicular magnetic field induces circular motion on the ions. The electric field affects the kinetic energy of the ions. Combined, the magnetic and electric fields induce cycloidal trajectories.
The unique focusing properties of the cycloidal mass analyzer depends on having highly uniform fields. For a completely uniform electric field, the focal plane is aligned with the plane of the ion source exit slit. A uniform gradient in the electric field shifts the focal plane above or below the plane of the ion source exit slit, while a uniform gradient in the magnetic field rotates the focal plane. For an ion imaging system, these field perturbations blur the image captured by the detector. With aperture coding, a blurred image can make reconstruction more difficult and lower the resolving power.
Thus, there is a need for magnet assemblies that exhibit improved magnetic field uniformity for use in cycloidal mass analyzers and other applications that require high magnetic field uniformity.
An object of the invention is to solve at least the above problems and/or disadvantages and to provide at least the advantages described hereinafter.
The present invention provides an opposed dipole magnet assembly that exhibits higher magnetic field uniformity than traditional magnetic assemblies used in cycloidal mass analyzers, such as H-shaped magnet assemblies. The opposed dipole magnet assembly includes two permanent magnets that are spaced apart and oriented such that their respective magnetization directions are parallel. Plates formed of a material exhibiting magnetic permeability are attached to top and bottom surfaces of the two permanent magnets so as to form a hollow field region. With this geometry, the magnetic field in the hollow field region is in a direction antiparallel to the magnetic field directions of the two permanent magnets.
An embodiment of the invention is a magnet assembly, comprising: a first permanent magnet having a top surface and a bottom surface and a first magnetization direction; a second permanent magnet having a top surface and a bottom surface and a second magnetization direction, wherein the second permanent magnet is spaced apart from the first permanent magnet, and wherein the first and second permanent magnets are positioned and oriented such that the first and second magnetization directions are parallel; a first material that exhibits magnetic permeability affixed to the top surfaces of the first and second permanent magnets; and a second material that exhibits magnetic permeability affixed to the bottom surfaces of the first and second permanent magnets; wherein the first and second permanent magnets and the first and second high materials that exhibit magnetic permeability together define a hollow field region, wherein a magnetic field direction in the hollow field region is antiparallel to the first and second magnetization directions.
Another embodiment of the invention is a method of making a magnet assembly, comprising: providing two permanent magnets with respective top and bottom surfaces; positioning and orienting the two permanent magnets such that they are spaced apart and such that their respective magnetization directions are parallel; affixing a first material that exhibits magnetic permeability to the top surfaces of the two permanent magnets; and affixing a second material that exhibits magnetic permeability to the bottom surfaces of the two permanent magnets; wherein the two permanent magnets and the first and second high materials that exhibit magnetic permeability together define a hollow field region, wherein a magnetic field direction in the hollow field region is antiparallel to the magnetization directions of the two permanent magnets.
The invention will be described in detail with reference to the following drawings, in which like reference numerals refer to like elements, wherein:
In the following detailed description of various embodiments of the present invention, numerous specific details are set forth in order to provide a thorough understanding of various aspects of one or more embodiments. However, the one or more embodiments may be practiced without some or all of these specific details. In other instances, well-known methods, procedures, and/or components have not been described in detail so as not to unnecessarily obscure aspects of embodiments.
Articles “a” and “an” are used herein to refer to one or to more than one (i.e. at least one) of the grammatical object of the article. By way of example, “an element” means at least one element and can include more than one element. Unless otherwise defined, all technical terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs.
While preferred embodiments are disclosed, still other embodiments of the system and method of the present invention will become apparent to those skilled in the art from the following detailed description, which shows and describes illustrative embodiments. As will be realized, the following disclosure is capable of modifications in various obvious aspects, all without departing from the spirit and scope of the present invention. Also, the reference or non-reference to a particular embodiment of the invention shall not be interpreted to limit the scope of the present invention.
The present invention is particularly suited for implementing a cycloidal mass analyzer, and will be described in this context. However, it should be appreciated that the present invention can be used in connection with any application in which high magnetic field uniformity is desired.
As discussed above, the unique focusing properties of the cycloidal mass analyzer depends on having highly uniform fields. One type of magnet assembly that has been traditionally used for cycloidal mass analyzers is an “H-shaped” magnet assembly, so called because the magnetic flux lines through a cross-section resemble the letter “H.” The present invention provides an opposed dipole magnet assembly that exhibits higher magnetic field uniformity than traditional magnetic assemblies, such as H-shaped magnet assemblies.
Both the traditional H-shaped magnet assembly and the opposed dipole magnet assembly of the present invention will be discussed and compared in more detail below. The performance of both the H-shaped magnet assembly and the opposed dipole magnet assembly of the present invention are evaluated via simulations that were performed with the COMSOL® Multiphysics simulation software (version 5.2) using the AC/DC and Charged Particle Tracing modules (hereinafter collectively referred to as “COMSOL”). The AC/DC module calculates the magnetostatic and electrostatic fields, while the Charged Particle Tracing module simulates ions travelling through the mass analyzer.
To reduce computation time while maintaining high fidelity in the regions of interest, the ion travel plane is meshed more finely than the remainder of the geometric model. The ion travel plane is meshed with a minimum element size of 5 μm and a maximum element size of 0.5 mm. The volume around this plane contains mesh elements between 1 mm and 80 mm in size. The magnet assemblies are meshed with elements between 14.4 mm and 80 mm in size. A box extends more than 300 mm beyond the magnet assembly in every direction with mesh elements ranging in size from 56 mm to 400 mm. It is important to note that this bounding box must be sufficiently large to prevent the edges of the simulation from affecting the field simulation. The size of the bounding box was determined by increasing its size until further increases no longer affected the simulated field.
Two types of materials were used for the magnet geometric models: annealed grade 416 stainless steel (SS) and the rare earth permanent magnet Nd—Fe—B. Material properties for the 416 SS were obtained from the nonlinear magnetic materials library in COMSOL. The library defines a B—H curve for the material, which allows for more accurate calculations than using a single permeability value. This also allows COMSOL to simulate magnetic saturation of the material. The Nd—Fe—B magnet, grade N50, is defined with a remnant flux density Br of 1.4 T and minimum coercivity of 923 kA/m.
The electric field model assumes copper electrodes, with material properties obtained from the COMSOL materials library. Using the electrostatic physics interface in COMSOL, electrode voltages were assigned to the model to generate a constant value electric field along the region of interest.
Simulated ion trajectories were used to evaluate the quality of the new magnetic and electric sectors. To isolate the effect of the magnetic field, the magnet array results assume a completely uniform electric field of 706 V/m. Electric sector results use simulated magnetic and electric fields.
To simulate ion trajectories, singly and doubly charged argon with mass to charge ratios of m/z=40 and m/z=20, respectively, were emitted from an ion source with an aperture at the geometric center of the magnet. The aperture is spatially coded with a modified S11 pattern, a binary Hadamard code. The pattern consists of three slits. It has overall dimensions of 550×350 with a total open area of 300×350 Its smallest feature is 50×350 μm. The ions had energies of 14±2 eV and an angular distribution of 0.0±9.5° in the x-y plane measured from the y-axis. The angular distribution in the y-z plane is 0°. Ions with mass to charge ratios of 20 and 40 were chosen, as they reach opposite ends of the detector array used in the cycloidal mass analyzer.
In the H-shaped magnet assembly example shown in
Differing initial energies and angles cause each ion to follow a different path through the field.
To investigate the aperture imaging quality, the place where each ion crossed the detector plane was examined and a detector reading was simulated by plotting a histogram and binning ion locations to match the detector in the experimental apparatus. The detector has 1704 detection elements along the length of the x-axis. Each element is 12×3 mm. The histogram was normalized to a peak value of 100.
In summary, aperture imaging quality was good for m/z of 20. However, aperture imaging quality for m/z of 40 was relatively poor. The main difference between the 20 m/z and 40 m/z ion trajectories is that the 40 m/z trajectories cover a larger area, over which the magnetic field varies by greater than 1%. Therefore, one can conclude that, assuming a uniform electric field, a magnetic field variation of less than 1% is required for good aperture imaging.
Arrows denote the direction of the magnetic flux lines. The magnets 210A/210B are spaced apart and oriented such that their respective magnetization directions are parallel (in the +z-direction in the illustrative embodiment of
The two plates 220A/220B may be formed of any material exhibiting magnetic permeability, such as a ferromagnetic metal (e.g., any metal that comprises iron, nickel and/or cobalt). The material exhibiting magnetic permeability is preferably a high permeability material. The phrase “high permeability material” refers to a material having a relative permeability preferably greater than 10. In one embodiment, the plates 220A/220B are formed of stainless steel (SS), such as 416 SS.
Plate 220A is affixed to the top surfaces of magnets 210A and 210B, and plate 220B is affixed to bottom surfaces of magnets 210A and 210B so as to form a hollow field region 230. The plates 220A/220B may be affixed using any means known in the art such as, for example, adhesives, mechanical fastening, welding and the like. The top and bottom surfaces of the magnets 210A/210B to which plates 220A/220B are affixed are preferably perpendicular to the magnetization direction of the magnets 210A/210B. Further, the plates 220A/220B do not have to physically contact the surfaces of magnets 210A/210B. For example, there may be an adhesive layer (not shown) between the magnets 210A/210B and the plates 220A/220B in order to affix the plates 220A/220B to the magnets 210A/210B. As another example, one may optionally include a layer of material for corrosion protection (not shown), such as nickel plating, between the plates 220A/220B and magnets 210A/210B.
In the embodiment illustrated in
The plates 220A/220B, together with the magnets 210A/210B, produce a −z-direction field in the field region 230 (for magnet 210A/210B magnetization directions of +z), which is the ion travel region. In contrast to the H-shaped magnet discussed above, the magnets 210A/210B are magnetized antiparallel to the direction of the field in the hollow field region 230.
In the illustrative embodiment shown in
The hollow field region 230 of the magnet assembly 200 is preferably accessible from at least one side of the magnet assembly 200 so as to allow for the insertion and removal of items, such as components for a cycloidal mass analyzer. In the embodiment illustrated in
To investigate the aperture imaging quality, detector readings were simulated utilizing the same method described above in connection with the H-shaped magnet assembly 100.
For both 20 m/z and 40 m/z, the signal returns to baseline between each slit following the aperture pattern. A simulation with a 50 μm slit produced 50 μm images at both 20 m/z and 40 m/z locations, indicating good imaging for both 20 m/z and 40 m/z ions and confirming that aperture imaging requires a magnetic field variation of less than 1%.
To verify the simulations, an opposed dipole magnet assembly 200 was fabricated and the magnetic field for the fabricated assembly was mapped in the plot of FIG. 2E using a Lakeshore 460 Gaussmeter with 3-axis Hall probe mounted on a precision XYZ station, which is incorporated into a LabVIEW real time data acquisition system. The experimental results are plotted as ‘x’s in
At step 320, a material exhibiting magnetic permeability, preferably a high permeability material, is affixed to the top surfaces of the two permanent magnets. Then, at step 330, a second material exhibiting magnetic permeability, preferably a high permeability material, is affixed to the bottom surfaces of the two permanent magnets. In one preferred embodiment, the first and second materials exhibiting magnetic permeability are plates, and the plates may be affixed to the surfaces of the magnets using any means known in the art such as, for example, adhesives, mechanical fastening, welding and the like.
As discussed above, the present invention is particularly suited for implementing a cycloidal mass analyzer.
The cycloidal mass analyzer 400 includes a vacuum manifold 410 (only a portion of the vacuum manifold 410 is shown so as to not obscure the hollow field region 230), an ion source 420, a detector 430, an electric sector 435 and other cycloidal mass analyzer components that are positioned in the hollow field region 230. The cycloidal mass analyzer 400 also includes components outside the hollow field region 230, such as a heat pipe 440 and vacuum feedthroughs 450.
The foregoing embodiments and advantages are merely exemplary, and are not to be construed as limiting the present invention. The description of the present invention is intended to be illustrative, and not to limit the scope of the claims. Many alternatives, modifications, and variations will be apparent to those skilled in the art. Various changes may be made without departing from the spirit and scope of the invention.
This application claims priority to U.S. Provisional Application Ser. No. 62/566,581, filed Oct. 2, 2017, whose entire disclosure is incorporated herein by reference.
This invention was made with government support under Federal Grant No. DE-AR0000546 awarded by the Department of Energy. The government has certain rights in this invention.
Number | Date | Country | |
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62566581 | Oct 2017 | US |