The present invention relates to robust, high capacity magnetic filters for removing magnetic and non-magnetic contaminants from commercial process streams in refinery and chemical industries.
Magnetic filters have been used to remove magnetic contaminants from industrial process streams. For example, U.S. Pat. No. 8,506,820 to Yen et al. and U.S. Pat. No. 8,636,907 to Lin et al. describe filters having removable permanent magnetic bars that are disposed within non-magnetic sleeves. During the filtration process, magnetic contaminants adhere onto the external surfaces of the sleeves. The contaminants disengage from the sleeves once the permanents magnetic bars are removed from the sleeves. Prior art devices also employ metal matrices that are magnetized by magnetic fields produced by an external electromagnetic coil as exemplified by U.S. Pat. No. 3,539,509 to Heitmann et al., U.S. Pat. No. 3,873,448 to Isberg et al., U.S. Pat. No. 4,594,160 to Heitmann et al, U.S. Pat. No. 4,722,788 to Nakamura, and U.S. Pat. No. 5,766,450 to Herman et al. Prior art magnetic filters with metal matrices are deficient in that the filters are low capacity with uneven contaminant capture and accumulation across the matrix.
The present invention is based in part on the recognition that the efficiency of magnetic filters, that are equipped with metal matrices in the form of metal packing materials, can be significantly enhanced by the generation of uniform magnetic fields within the interior region of the filter that encloses the metal packing materials. The magnetic filters are particularly suited for removing degradation sludge, iron containing particles or flakes, as well as non-magnetic polymeric materials from the process streams in refinery and chemical plants.
Accordingly in one aspect, the invention is directed to a magnetic filter for separating magnetic and non-magnetic contaminants from a contaminated liquid process stream that includes:
a housing having (i) a process stream inlet (ii) a process stream outlet (iii) an interior region between the inlet and outlet (iii) a plurality of vertically oriented, elongated non-magnetic holder sleeves positioned within the interior region;
paramagnetic metal packing material that is randomly distributed in the interior region to form a packed compartment that has a void volume which is above 95 percent; and
means for generating a magnetic field within the packed compartment.
The magnetic filter does not require external coils of insulated wire wound around the housing. The magnetic filter affords a compact design that is capable of developing high intensity, uniform magnetic fields across the packed compartment that is occupied by the paramagnetic metal packing material. As a result, the magnetic filter with its high contact surface area created by the holder sleeves and packing material matrix, can efficiently remove both magnetic and non-magnetic contaminants from industrial process streams.
In another aspect, the invention is directed to a method of removing magnetic and non-magnetic particles from a contaminated liquid process stream that includes the steps of:
(a) providing a magnetic filter device that includes:
(b) activating the means for generating the magnetic field;
(c) connecting the contaminated liquid process stream to the inlet of the magnetic filter, such that as the contaminated liquid process stream initially flows pass the holder sleeves, magnetic contaminants adhere to the exterior of the holder sleeves and to the exterior surfaces of the packing material and subsequently as the contaminated liquid process stream continues pass the filter screen non-magnetic contaminants of the desired size are removed by the filter screen to thereby form a treated process stream that exits through the outlet;
(d) terminating the flow of the contaminated liquid process stream into the inlet;
(e) de-activating the means for generating the magnetic field, to thereby release magnetic contaminants that have adhered to the exterior surfaces of the holder sleeves and packing material; and
(f) flushing out magnetic and non-magnetic contaminants from the screen cylinder.
As shown in
A cover plate 22, which is equipped with a plurality of vertically oriented elongated holder sleeves 24, is fastened to an annular flange 12 that is welded to the outer perimeter along the top opening in housing 4. Holder sleeves 24 are preferably welded to cover plate 22 so as to form integral units therewith. Each elongated holder sleeve 24 is constructed of a non-magnetic metal such as stainless steel and each has a chamber that accommodates one or more magnet blocks that are encased to form a permanent magnetic bar assembly 26. In particular, as shown in
As further illustrated in
Holder sleeve 24, magnet blocks 30 and enclosures 28 preferably have square cross sections but it is understood that they can circular or other configurations. With the permanent magnetic bar assemblies 26 disposed within holder sleeves 24, contaminants containing magnetic materials are attracted by the magnetic fields produced by the permanent magnetic bar assemblies 26 so that contaminants adhere onto the exterior surfaces of the elongated holder sleeves 24, which are within interior region 16. There is no leakage of process fluid into holder sleeves 24 which are completely sealed from interior 16. The permanent magnetic bar assembles 26 are secured to a lifting plate 42 which is connected to a motorized lifting apparatus 40.
As further shown in
As shown in
In a preferred arrangement, the packed compartment is filled with paramagnetic metal packings of different sizes in a graded fashion, for example, with the largest ones on the top and smallest ones at the bottom. This distribution of the packings enhances the filter's ability to capture non-magnetic particles from the process fluid. The packed compartment has a void volume (volume of empty unpacked compartment minus volume of actually occupied by the solid of the packings) that is typically at least 95 percent and preferably from 96 to 99.9 percent.
In use, the permanent magnetic bar assembles 26 are first lowered into the holder sleeves 24. As contaminated process stream enters inlet 6 and flows into the filter interior region 16, the configurations and positions of holder sleeves 24 and baffles 70 evenly distribute the flow of contaminated fluid downward to allow the contaminated fluid to come into maximum contact with holder sleeves 24 and paramagnetic metal packings 32 in order to attract magnetic contaminants. The strong magnetic fields developed by the plurality of permanent magnetic bar assemblies 26 cause magnetic contaminants to deposit onto the outer surfaces of holder sleeves 24 and onto the surfaces of the paramagnetic metal packings 32. In addition, large particles, including both magnetic and non-magnetic contaminants, are removed from the contaminated liquid by being physically entrapped by the paramagnetic metal packings 32. Treated process fluid which is substantially free of the contaminants is channeled towards the outlet 10. The magnetic filter 2 is preferably structured as a two-stage filtration wherein the number of permanent magnetic bar assemblies 26 and the associated magnetic fields are sufficient to initially attract a desired amount of magnetic contaminants from the contaminated liquid process stream onto the outer surface of holder sleeves 24 and the paramagnetic metal packings 32 capture magnetic and non-magnetic contaminants of the desired size from the contaminated liquid process stream.
As the outer surfaces of holder sleeves 24 become evenly layered with magnetic contaminants and the packings 32 loaded with magnetic and non-magnetic contaminants, the pressure drop across magnetic filter 2 gradually increases until a programmed set point of the filter control system 72 is reached whereupon the operating cycle terminates by executing the following automatic sequence: (1) closing inlet process flow control valve 8, (2) closing outlet process flow control valve 14, and (3) removing plurality of the permanent magnetic bar assembles 26 simultaneously by raising the lifting plate 42 to releases major portions of the magnetic contaminants that have been deposited on the outer surface of holder sleeves 24 and the paramagnetic metal packings 32. The contaminants fall onto the bottom of filter housing 4. Drain valves 20 and flush fluid valve 44 are opened in sequence, allowing a flush fluid, which can be a cleaned process fluid, into the filter interior region 16. The flush fluid is introduced via inlet 36 and control valve 44 at a sufficiently high flow rate to wash off residual magnetic contaminants from the outer surface of holder sleeves 24 and to wash off both magnetic and non-magnetic contaminants from packings 32. The flush fluid, with entrained magnetic and non-magnetic contaminants, is discharged through drain pipe 18 and control valve 20.
Once the cleaning cycle is completed, automatic control systems 72 initiates the operating cycle in reverse sequence: (1) closing valve 44, (2) closing valve 20, (3) lowering lifting plate 42 to slidably reinserted the plurality of permanent magnetic bar assembles 26 into holder sleeves 24, (4) opening process fluid outlet valve 14, and (5) opening process fluid inlet valve 8.
Dual screen cylinders 138,158 are preferably constructed of two concentric vertically arranged layers of non-magnetic metal screens. The inner, finer screen 158 typically has a mesh size of 1 to 200 and preferably 10-100 wires per inch. The outer, coarser screen 138 typically has a mesh size of 10-100 and preferably 10-50 wires per inch. The top end of each screen is attached to rim 180 and the lower side of each screen is attached to the upper perimeter of the non-filtering section 140, which is preferably configured as a cone with tube 142 at the apex. The size of opening in tube 142 is large enough to accommodate the large particles that accumulate in the filtration process so that contaminates can be readily flushed out during cleaning cycle. The middle and lower portions of holder sleeves 124 are partially enclosed by screen cylinders 138,158 while the upper portion of holder sleeves 124 extend out from cover plate 122, which is secured to annular flange 112. A metal screen 134 at the lower end of the packed compartment supports the paramagnetic metal packings 132.
Operation of magnet filter 102 is similar to that of magnetic filter 2. With the permanent magnetic bar assembles 126 fully inserted into the holder sleeves 124, a contaminated process stream entering inlet 106 with control valve 108 initially flows into upper plenum or chamber 182. The holder sleeves 124 and baffles 170 evenly distribute the flow of contaminated fluid initially downward and outwardly into inner screen cylinder 158. The distance or gap between cover plate 122 and rim 180 should be configured to allow the contaminated fluid to come into maximum contact with the exterior surfaces of holder sleeves 124 and paramagnetic metal packings 132 to enhance collection of magnetic contaminants. The strong magnetic fields developed by the plurality of permanent magnetic bar assembles 126 within the holder sleeves 124 cause magnetic contaminants to deposit onto the outer surfaces of the holder sleeves 124 and the surfaces of the paramagnetic metal packings 132. Subsequently, as the process fluid passes through inner and outer screens 158,138 large particles, including both magnetic and non-magnetic contaminants, are removed from the liquid by the paramagnetic metal packings 132 and the dual screen cylinders. A treated process fluid which is substantially free of the contaminants is channeled towards lower plenum or chamber 184 and exits the magnetic filter through outlet 110 and control valve 114.
As the outer surfaces of holder sleeves 124 are evenly layered with magnetic contaminants, screen cylinders 138,158 become clogged with non-magnetic contaminants, and the paramagnetic metal packings 132 are loaded with magnetic and non-magnetic contaminants, the pressure drop across the magnetic filter 104 rises eventually passing the set point of the control system 172. Upon completion of the operating cycle, the cleaning cycle begins as per the procedures described magnetic filter 2 depicted in
Paramagnetic metal packings 232 are randomly distributed within the housing 204 in between the plurality of holder sleeves 224. A metal screen 234, positioned at the bottom of the magnetic filter 202, along with metal screens 254 retain the paramagnetic metal packings 232 within the packed compartment. Baffles 270 channel the flow of contaminated process fluid through the packed compartment and into contact with the external surfaces of the holder sleeves 224 and paramagnetic metal packings 232.
Operation of magnetic filter 202 is regulated by a control system 272, which includes antenna 274 and control valve antennas 278. In particular, connection of the current source 290 to wire leads 292,294 causes paramagnetic contaminants to be attracted to and adhere to the external surfaces of a holder sleeves 224. The presence of the uniform magnetic fields also magnetizes the paramagnetic metal packings 232 so as to attract magnetic contaminants as a process stream flows through the packed compartment. The filtration and clean-up operations are essentially the same as those described for the magnetic filter 2 (
2B. The top end of each screen is attached to rim 380 and the lower side of each screen is attached to the upper perimeter of the non-filtering section 340, which is preferably configured as a cone with tube 342 at the apex. Metal screens 354 at process stream inlet pipe 306 with control valve 308, process stream outlet pipe 310 with control valve 314, and flush fluid inlet pipe 336 with control valve 344 retain the randomly distributed paramagnetic metals packings 332 within a packed compartment of the filter housing 304.
An array of holder sleeves 324 is fitted into holes on the cover plate 322 which is fastened to an annular flange 312. Paramagnetic metal cores or bars 326 are disposed into the holder sleeves 324. Each paramagnetic metal bar 326 has a coil of insulated wire 320 that is closely spaced and tightly wrapped around the bar. Insulation gaskets 352 are positioned between adjacent paramagnetic metal bars 326 and holder sleeves 324.
Paramagnetic metal packings 332 are randomly distributed within dual screen cylinders 338,358 in between the plurality of holder sleeves 324. A metal screen 334, positioned at the bottom of the magnetic filter 302, along with metal screens 354 retain the paramagnetic metal packings 332 within the packed compartment.
Operation of magnetic filter 302 is regulated by a control system 372, which includes antenna 374 and control valve antennas 378. With leads 392,394 connected to the current source 390, a contaminated process stream flows into upper plenum or chamber 382 where baffles 370 direct the flow into contact with holder sleeves 324 and paramagnetic metal packings 332. The process stream passes through inner and outer screens 358,338 and into lower plenum or chamber 384 and exits the magnetic filter. Once the filtration process is finished upon reaching the predetermined pressure drop, the current is disconnected and the cleaning process initiated as per the procedures previously described for the operations depicted in
The robust magnetic filters can remove paramagnetic particles or sludge, and at least a portion of the non-magnetic sludge from the petroleum or chemical process streams. Carbon steel, a common material for plant construction, tends to be corroded by any acidic contaminants in a process stream of the refinery or chemical plant. As the result, ferrous ions are formed, which react with sulfur, oxygen and water to form paramagnetic FeS, FeO, Fe(OH)2, Fe(CN)6, etc. in the form of fine particles or visible flakes. These paramagnetic materials tend to attract other degradation sludge, making a major portion of the contaminants paramagnetic. By employing the inventive magnetic filter at appropriate streams, a substantially large portion of the contaminants can be effectively removed. It is expected that only a small percentage of the contaminants which are non-magnetic (or weak-magnetic) will not be captured. For treating contaminated streams with high non-magnetic contaminant content, the employment of the dual screens should be sufficient to remove the additional non-magnetic contaminants.