1. Field of the Invention
The present invention relates to a magnetic transfer method for a magnetic recording medium, in which method magnetic information (e.g., servo information) is magnetically transferred to a perpendicular magnetic recording medium in which recorded magnetization is in a perpendicular direction to the medium surface; and a magnetic recording medium obtained by the magnetic transfer method.
2. Description of the Related Art
In recent years, magnetic recording/reproducing devices have attained higher recording density so as to realize large capacity and downsizing thereof. In particular, advancement in the field of hard disc drives (HDDs), which are a typical magnetic recording device, has been drastically made.
In view that a quantity of information recorded/reproduced becomes large, demand has arisen for a high-density magnetic recording medium which has a large capacity (i.e., can record a volume of information), which is inexpensive, and in which so-called high-speed access is preferably realized (i.e., required information can be read in a short time). The high-density magnetic recording medium has an information recording area composed of narrow tracks. A so-called tracking servo technique has an important role in enabling the recording medium to reproduce signals at a high S/N ratio by accurately moving a magnetic head in narrow track widths for scanning. For carrying out the tracking servo, a sector servo method is widely employed.
The sector servo method is a method in which a magnetic head scans servo fields to read servo information, and is adjusted in position while confirming its position depending on the servo information. Here, the servo fields are orderly arranged at a certain angle on the data surface of a magnetic recording medium (e.g., magnetic disc) and record servo information such as servo signals for positioning on a track, address information signals of the track, and reproduction clock signals.
The servo information is required to be previously recorded in a magnetic recording medium as a preformat during production thereof. Currently, the preformat is formed with a specialized servo recording device. In one currently used servo recording device, while a magnetic disc is rotated with being disposed proximately to a magnetic head with a width about 75% of a track pitch, the magnetic head is moved from the outer circumference to the inner circumference of the magnetic disc every ½ tracks for recording of servo signals. Thus, it takes a long time to complete preformat recording for one magnetic disc, resulting in causing a drop in production efficiency, and cost elevation.
In order to accurately and efficiently carry out preformat recording, there has been proposed a method in which information of a master recording medium having a pattern corresponding to servo information is magnetically transferred to a magnetic recording medium (see Japanese Patent Application Laid-Open (JP-A) Nos. 2003-203325 and 2000-195048, U.S. Pat. No. 7,218,465 B1, and JP-A Nos. 2004-12142 and 2001-297435).
In this magnetic transfer, a recording magnetic field is applied while a master carrier having a magnetic layer with a pattern corresponding to information (e.g., servo information) to be transferred to a magnetic recording medium (slave medium) (e.g., a magnetic disc for transfer) is closely attached to a magnetic recording medium (slave medium), to thereby magnetically transfer, to the magnetic recording medium, a magnetic pattern corresponding to the pattern of the magnetic layer of the master carrier. This method is advantageous in that it can statically record information without relatively changing the position of the master carrier and the position of the magnetic recording medium, can accurately record preformat information, and can record information in a very short time.
JP-A No. 2004-12142 discloses a magnetic transfer technique based on in-plane magnetic recording in which a magnetization to be recorded is in parallel with the medium surface. JP-A No. 2001-297435 discloses a magnetic transfer technique based on perpendicular magnetic recording in which a magnetization to be recorded is perpendicular to the medium surface.
Perpendicular magnetic recording can be expected to be remarkably improved in recording density as compared with in-plane magnetic recording. Thus, in order to meet the recent requirements for an increase in recording density, development of the perpendicular magnetic recording technique has been continued, and the perpendicular magnetic recording medium is practically used.
Magnetic transfer for a perpendicular magnetic recording medium is carried out as follows. First, a DC magnetic field is applied onto a perpendicular magnetic recording medium (slave disc), to which information is to be transferred, in a perpendicular direction to the disc surface, to thereby initially magnetize a magnetic layer (recording layer) of the disc. After the initial magnetization, an original master for transfer (master disc) is closely attached to the slave disc. In this state, a DC magnetic field is applied in an opposite direction to the initial magnetization, to thereby transfer, to the slave disc, information corresponding to a concavo-convex pattern formed in the surface of the original master for transfer.
Although the quality of a transfer signal depends greatly on the conditions under which a magnetic field is applied during transfer, conventionally, sufficient investigation has not been made on the relationship between the application time of a magnetic field and the quality of a transfer signal. Notably, JP-A No. 2004-12142 difines, in relation to in-plane magnetic recording, the intensity of a DC magnetic field applied after initial magnetization in an opposite direction thereto, but does not refer to the application time of a magnetic field.
In accordance with an increase in magnetic recording density, high-density (short-bit) recording is demanded also in magnetic transfer. As the bit becomes shorter, a magnetic field becomes weaker in a convex portion participating in transfer. In addition, the difference in magnetic field decreases between the convex and concave portions, resulting in reducing the difference between the magnetization quantity brought by the magnetic field in the concave portion and that brought by the magnetic field in the convex portion. Furthermore, larger spacing loss is observed in shorter bits and thus, magnetic transfer is difficult to carry out satisfactorily. In view of this, there is a need to develop a new technique.
As is clear from
Conventionally, in many cases, a magnetic layer of the master carrier has been made of an isotropic soft magnetic material (having no magnetic anisotropy). In general, a soft magnetic layer contained in the master carrier preferably has a high saturation magnetization Ms. Thus, conventionally, Fe7Co3, etc. have been used for forming a magnetic layer of the master carrier (master magnetic layer). Also, paragraph [0006] of JP-A No. 2003-203325 describes that the master magnetic layer preferably has higher saturation magnetization Ms.
However, the master magnetic layer having higher saturation magnetization Ms poses the following problem. Specifically, when the master carrier contains a magnetic layer having high saturation magnetization Ms, a demagnetic field (4π×Ms in a plane) becomes large, resulting in that only part of a magnetic field applied contributes to magnetization.
The intensity of the demagnetic field depends on the shape of a magnetic material (relationship among dimensions thereof).
Taking for example the case where magnetic transfer is carried out on a slave disc having a coercive force He=4,000 Oe, as shown in
As the transfer magnetic field Ha is increased, the magnetization quantity is increased in a portion which is in contact with the slave medium (i.e., a convex portion of the master). But, a large quantity of the magnetic field is leaked to the concave portion of the master carrier (which portion corresponds to a portion of the slave medium where initial magnetization is to be maintained); i.e., the intensity of the initial magnetization is considerably decreased, leading to problematic degradation of the S/N ratio of a transfer signal. In view of the above, conventionally, a magnetic field having an intensity of about the coercive force Hc of a slave medium for magnetic transfer so as to maximize the difference in magnetization between the convex and concave portions. Also in this case, a considerable amount of the magnetic field is leaked to the concave portion due to a demagnetic field, degrading the intensity of the initial magnetization thereof.
Also, in perpendicular magnetic transfer, a magnetic field in the concave portion of the master (i.e., an interbit portion which is not contact with a magnetic layer of the slave medium) is moved to the convex portion for magnetic transfer. When the interbit distance becomes shorter in accordance with an increase in recording density, a magnetic field which can be utilized is decreased, and larger spacing loss is observed. Thus, a conventional magnetic layer cannot satisfy the requirements for magnetic transfer on a short-bit medium.
Meanwhile, JP-A No. 2000-195048 describes that a perpendicularly magnetized film having perpendicular magnetic anisotropy is preferably used as a master magnetic layer for use in perpendicular magnetic recording (see paragraph [0037] of JP-A No. 2000-195048), but does not disclose required characteristic values of the film. Various studies have been made on a perpendicular magnetic anisotropic film in accordance with development of a magnetic recording medium. These studies are not about a magnetic film used in a master carrier, but about a perpendicularly magnetized film used for magnetic recording The physical characteristics required for a magnetic film used in a perpendicular magnetic recording medium are quite different from those required for a magnetic film used in a master magnetic layer. Thus, even if a conventionally studied perpendicularly magnetized film used in a magnetic recording medium is used as is as a master magnetic layer, magnetic transfer cannot be satisfactorily carried out.
When a magnetic layer giving an M-H curve shown in
As described above, it has been found that a perpendicularly magnetized film for use in a magnetic recording medium is not preferably used as a magnetic layer of a master carrier.
U.S. Pat. No. 7,218,465 B1 discloses a master carrier whose concave portions are embedded with permanently magnetizable films having perpendicular magnetic anisotropy. The content of U.S. Pat. No. 7,218,465 B1 is not sufficient for realizing transfer on a short-bit medium. Next will be four reasons for this. First, U.S. Pat. No. 7,218,465 B1 does not describe effective characteristics of a perpendicular magnetic anisotropic film. In lines 58 to 60, column 4 of U.S. Pat. No. 7,218,465 B1, the conditions that saturation magnetization Bsat≧about 0.5 T and magnetic permeability μ≧ about 5 are given as magnetic characteristics of a magnetic material. But, even when Bsat≧about 0.5 T, satisfactory transfer cannot be carried out due to a demagnetic field as described above. Also, regarding the master carrier, it is already known that the condition μ≧100 is sufficient (μ is preferably higher), which is not a newly presented condition.
Second, U.S. Pat. No. 7,218,465 B1 describes that the material of a magnetic film is selected from Ni, NiFe, CoNiFe, CoSiFe, CoFe and CoFeV. But, these materials could not exhibit below-described characteristics in the present invention and thus, could not exhibit satisfactory transfer characteristics.
Third, in the master carrier disclosed in U.S. Pat. No. 7,218,465 B1, as shown in
In addition, when the master and the slave that have been closely attached to each other are separated from each other, the separation is difficult to carry out to adversely affect mass-production suitability. This is because, the contact area is large to increase adhesive force between the master and slave, magnetic binding force (both positive force and negative force), and binding force between the bits and master; i.e., the contact area becomes about twice an area where a concavo-convex master is closely attached to a slave, resulting in that these forces are also about twice.
Fourth, when the slave and master are separated from each other after transfer, they unavoidably slide against each other in a radial direction of the discs. Thus, when a permanently magnetizable film is used, the slave may be modified by the action of the magnetic field generated from the master, problematically degrading an SIN ratio.
The technique disclosed in JP-A No. 2003-203325 is not suitable for transfer on a short-bit medium for the following reasons. Specifically, JP-A No. 2003-203325 discloses a technique of preventing undesirable spread of transfer pattern, in which two perpendicular ferromagnetic films are used as a magnetic layer of a master carrier, and the magnetic flux of one magnetic bit is in an opposite direction to that of another magnetic bit However, only a material having low saturation magnetization Ms can be actually applied to this technique, and TbFeCo and TbFe exemplified in JP-A No 2003-203325 have an Ms of as low as 40 emu/cc and an Ms of as low as 300 emu/cc, respectively. Thus, these cannot be satisfactorily used in a high-density recording medium which is required to have a coercive force Hc of 4,000 Oe or higher.
In addition, the master carrier disclosed in JP-A No 2003-203325 requires, as a magnetic layer, two different layers made of two different materials and thus, involves complicated production process. Furthermore, similar to the magnetic layer-embedded master carrier (shown in
As described above, conventional techniques are difficult to realize satisfactory magnetic transfer on a short-bit medium.
An object of the present invention is to provide a magnetic transfer method for a magnetic recording medium including application of a pulse magnetic field under predetermined conditions using a magnetic transfer master carrier having perpendicular magnetic anisotropy; and a perpendicular magnetic recording medium obtained by the magnetic transfer method, which medium exhibits an excellent signal quality; i.e., an increased reproduced signal output and small variation in width of a waveform.
Means for solving the problems pertinent in the art are as follows.
<1> A magnetic transfer method for a magnetic recording medium, in which method magnetic information is recorded on a perpendicular magnetic recording medium through magnetic transfer, the method including:
initially magnetizing a perpendicular magnetic recording medium by applying a DC magnetic field thereto in a perpendicular direction, and
applying, to the perpendicular magnetic recording medium, a DC magnetic field for 100 nsec to 1 see in an opposite direction to the magnetic field applied in initial magnetization with the recording medium being closely attached to a magnetic transfer master carrier which transfers magnetic information to the recording medium with being brought into contact with the recording medium,
wherein the master carrier comprises transfer portions on which surfaces a magnetic layer corresponding to magnetic information is laid, and non-transfer portions which are concave portions lower in height than the transfer portions, and
wherein the magnetic layer has perpendicular magnetic anisotropy and has a residual magnetization Mr of 500 emu/cc or lower and a saturation magnetization Ms of 900 emu/cc or higher.
<2> The magnetic transfer method according to <1> above, wherein the magnetic layer of the master carrier is made of CoPt.
<3> The magnetic transfer method according to <1> above, wherein the magnetic layer of the master carrier is made of Co4Pt1 (atomic ratio)
<4> The magnetic transfer method according to <1> above, wherein the master carrier further includes an underlying layer under the magnetic layer, and the underlying layer is made of CoCr, Ru, Pt, or a combination thereof.
<5> The magnetic transfer method according to <1> above, wherein the magnetic layer is laid only on the transfer portions, and the transfer portions with the magnetic layer laid on surfaces thereof are more protruded by the thickness of the magnetic layer than the non-transfer portions.
<6> The magnetic transfer method according to <1> above, wherein the perpendicular magnetic recording medium has a coercive force He of 4,000 Oe or higher.
<7> A magnetic recording medium obtained by a method comprising:
initially magnetizing a perpendicular magnetic recording medium by applying a DC magnetic field thereto in a perpendicular direction,
applying, to the perpendicular magnetic recording medium, a DC magnetic field for 100 nsec to 1 see in an opposite direction to the magnetic field applied in initial magnetization with the recording medium being closely attached to a magnetic transfer master carrier which transfers magnetic information to the recording medium with being brought into contact with the recording medium,
wherein the master carrier comprises transfer portions on which surfaces a magnetic layer corresponding to magnetic information is laid, and non-transfer portions which are concave portions lower in height than the transfer portions, and
wherein the magnetic layer has perpendicular magnetic anisotropy and has a residual magnetization Mr of 500 emu/cc or lower and a saturation magnetization Ms of 900 emu/cc or higher.
The present invention can provide a magnetic transfer method for a magnetic recording medium including application of a pulse magnetic field under predetermined conditions using a magnetic transfer master carrier having perpendicular magnetic anisotropy; and a perpendicular magnetic recording medium obtained by the magnetic transfer method, which medium exhibits an excellent signal quality; i.e., an increased reproduced signal output and small variation in width of a waveform. These can solve the existing problems.
A magnetic transfer method of the present invention for recording magnetic information on a perpendicular magnetic recording medium through magnetic transfer, the method includes initially magnetizing a perpendicular magnetic recording medium by applying a DC magnetic field thereto in a perpendicular direction, and applying, to the perpendicular magnetic recording medium, a DC magnetic field for 100 nsec to 1 see in an opposite direction to the magnetic field applied in initial magnetization with the recording medium being closely attached to a magnetic transfer master carrier which transfers magnetic information to the recording medium with being brought into contact with the recording medium, wherein the master carrier comprises transfer portions on which surfaces a magnetic layer corresponding to magnetic information is laid, and non-transfer portions which are concave portions lower in height than the transfer portions, and wherein the magnetic layer has perpendicular magnetic anisotropy and has a residual magnetization Mr of 500 emu/cc or lower and a saturation magnetization Ms of 900 emu/cc or higher.
A DC magnetic field which acts in an opposite direction to the magnetic field perpendicularly applied for initial magnetization is applied to the perpendicular magnetic recording medium and the magnetic transfer master carrier that have been closely attached to each other for 100 nsec to 1 sec, preferably 1 μsec to 100 msec, more preferably 100 μsec to 10 msec.
When the application time is shorter than 100 nsec, both Hc (coercive force) and Hn (reverse magnetic domain nucleus forming magnetic field) increase. As a result, the convex portion of the master disc is not completely magnetized, potentially degrading the quality of a transfer signal. When the application time is longer than 1 sec, both Hc (coercive force) and Hn (reverse magnetic domain nucleus forming magnetic field) decrease. As a result, a magnetic field in the concave portion of the master disc is greater than Hn, potentially degrading the quality of a transfer signal.
Referring now to the drawings attached, next will be described in detail preferred embodiments of the present invention.
Firstly, with reference to
Specifically, a DC magnetic field (Hi) is applied to a slave disc 10 in a perpendicular direction for initial magnetization as shown in
The slave disc 10 used in this description include a disc-shaped substrate and a magnetic layer made of a perpendicularly magnetized film, wherein at least one surfaces of the substrate is provided with the magnetic layer. Specific examples thereof include high-density hard discs.
The disc-shaped substrate 12 is made of a non-magnetic material such as glass and aluminum (Al). The soft magnetic layer 13 is formed on the substrate 12, and then the non-magnetic layer 14 and the magnetic layer 16 are formed thereon.
The soft magnetic layer 13 effectively stabilizes perpendicular magnetization in the magnetic layer 16 and enhances sensitivity during recording/reproducing. The soft magnetic layer 13 is preferably made of a soft magnetic material such as CoZrN , FeTaC, FeZrN, FeSi alloy, FeAl alloy, FeNi alloy (e.g., permalloy) and FeCo alloy (e.g., permendur). The soft magnetic layer 13 is treated so as to have magnetic anisotropy oriented in a radial direction of a disc (in a radial fashion) (i.e., from the center to the periphery).
The soft magnetic layer 13 preferably has a thickness of 50 nm to 2,000 nm, more preferably 80 nm to 400 nm.
The non-magnetic layer 14 is provided for the purposes of, for example, increasing the perpendicular magnetic anisotropy of the magnetic layer 16 to be formed thereon. The non-magnetic layer 14 is preferably made of, for example, titanium (Ti), chromium (Cr), CrTi, CoCr, CrTa, CrMo, NiAl, ruthenium (Ru), palladium (Pd), Ta or Pt. The non-magnetic layer 14 is formed through sputtering of the above material. The thickness of the non-magnetic layer 14 is preferably 10 nm to 150 nm, more preferably 20 nm to 80 nm.
The magnetic layer 16 is made of a perpendicularly magnetized film (a magnetic film in which most of axes of easy magnetization are arranged perpendicularly to a substrate), and information is recorded on the magnetic layer 16. The magnetic layer 16 is preferably made of, for example, cobalt (Co), Co alloy (e.g., CoPtCr, CoCr, CoPtCrTa, CoPtCrNbTa, CoCrB and CoNi), Co alloy-SiO2, Co alloy-TiO2, Fe or Fe alloy (e.g., FeCo, FePt and FeCoNi).
These materials have a high magnetic flux density, and can be treated so as to have perpendicular magnetic anisotropy by controlling film-forming conditions or its composition. The magnetic layer 16 is formed through sputtering of the above material. The magnetic layer 16 preferably has a thickness of 10 nm to 500 nm, more preferably 20 nm to 200 nm.
In this embodiment, a disc-shaped glass substrate having an outer diameter of 65 mm is used as the substrate 12 of the slave disc 10. This glass substrate is placed in the chamber of a sputtering apparatus. The chamber is reduced in pressure to 1.33×10−5 Pa (1.0×10−7 Torr), and then argon (Ar) gas is introduced to the chamber. The temperature of the substrate in the chamber is adjusted to room temperature, and the first layer (thickness: 80 nm) of the SUL is formed through sputtering on the substrate using a CoZrNb target in the chamber. Then, an Ru layer (thickness: 0.8 nm) is formed on the thus-formed first layer through sputtering using an Ru target in the chamber. Then, the second layer (thickness: 80 nm) of the SUL is formed through sputtering using a CoZrNb target. The SUL formed through sputtering is increased to room temperature while a magnetic field of 50 Oe or higher is applied thereto in a radial direction, and maintained at room temperature.
Next, sputtering is carried out using a CrTi target through discharging with the substrate being adjusted to room temperature, to thereby form a non-magnetic layer 14 made of CrTi (thickness: 60 nm).
Thereafter, similar to the above, Ar gas is introduced to the chamber and then, sputtering is carried out using a CoCrPt target in the same chamber through discharging with the substrate being adjusted to room temperature, to thereby form a granular magnetic layer 16 made of CoCrPt—SiO2 (thickness: 25 nm).
Through the above procedure, a magnetic disc for transfer (slave disc) 10 was formed, which includes, in sequence, a glass substrate, a soft magnetic layer, a non-magnetic layer and a magnetic layer.
The slave disc preferably has a coercive force He of 4,000 Oe or higher, more preferably 5,000 Oe or higher. When the coercive force Hc is lower than 4,000 Oe, unnegligible heat fluctuation may be caused to prevent high-density (short-bit) recording.
Next, the slave disc 10 formed is subjected to initial magnetization. The initial magnetization (DC magnetization) of the slave disc 10 is carried out through application of an initializing magnetic field Hi generated from a device (unillustrated magnetic field applying unit) which is capable of applying a DC magnetic field to a surface of the slave disc 10 in a perpendicular direction (as described above with reference to
Next will be described the master disc 20 serving as a master carrier.
In the embodiment shown in
As used herein, the sentence/term “bit is shot” or “short bit” means that, in
In any embodiments shown in
The following description is mainly about the embodiment shown in
Table 1 shows preferred magnetic characteristics of the magnetic layer 204 of the master disc 20. For comparison, Table 1 also shows magnetic characteristics of a perpendicular magnetic recording film serving as a recording layer of the slave disc 10.
Next will be described the reasons why a magnetic layer having magnetic characteristics shown in Table 1 is suitably used as the magnetic layer of the master carrier
[Comparison of Perpendicular Magnetic Anisotropic Film with Magnetic Isotropic Film]
As shown in
In the graph of
As shown in
Such effect that is given by perpendicular magnetic anisotropy reduces a magnetic field at the concave portions, and the boundary region has a sharp magnetic field distribution (i.e., drastic change in magnetic field is observed between the convex and concave portions).
The horizontal axis of the graph of
The residual magnetization Mr of a master magnetic layer is preferably smaller. When the residual magnetization Mr is equal to or greater than a certain value, a master disc undesirably generates a magnetic field even after completion of application of a transfer magnetic field. As a result, unnecessary transfer is caused when the master disc 20 is separated from the slave disc 10, leading to occurrence of signal noise.
After the transfer step as shown in
In the slave disc, the portions indicated by reference numeral 102, which are other than the portions attached to the convex portions, must be maintained so as to have an initial magnetization. The master magnetic layer having a high residual magnetization Mr undesirably generates a magnetic field even after completion of application of a transfer magnetic field. Thus, when the discs slide against each other in an in-plane direction during separation thereof, part (indicated by reference numeral 103) of each portion (indicated by reference numeral 102) which corresponds to the concave portion is adversely affected by a residual magnetic field, resulting in degradation of initial magnetization thereof.
In order to avoid such a problem, the residual magnetization Mr of the master magnetic layer is adjusted to 500 emu/cc or lower. The reason for this will next be described.
From the graph of
In
Next, there will be examined the effects of such a residual magnetic field to a slave disc having undergone transfer. In a slave disc having a magnetic layer exhibiting an M-H curve shown in
After a magnetic transfer step, if the master disc 20, which has a perpendicular magnetic anisotropic film with a residual magnetization Mr of 1,000 emu/cc (SQ=1), and the slave disc 10 slide against each other by several tens nanometers in an in-plane direction during separation thereof at a transfer magnetic field of 0, a magnetic field of about 3.5 kOe generated from a convex portion changes the initial magnetization of the slave disc from −1 to −0.5 as shown in the M-H curve of
Also, when a master disc having a perpendicular magnetic anisotropic film with a residual magnetization Mr of 500 emu/cc (SQ=0.5) is used, a magnetic field generated from the convex portion is lower than 2 kOe (
Thus, in the case where a perpendicular magnetic anisotropic film having a residual magnetization Mr of 500 emu/cc (SQ=0.5) is used, even when the master and slave discs slide against each other in an in-plane direction, almost no effects are given by a magnetic field generated (lower than 2 kOe). As shown in the M-H curve of
Notably, when a perpendicular magnetic anisotropic film used has a residual magnetization Mr lower than 500 emu/cc, as shown in
In actual manufacturing steps, when the master disc 20 is separated from the slave disc 10 after the magnetic transfer step, the discs unavoidably slide against each other by about 100 nm in a radial direction. Thus, it is important that a master magnetic layer used has a residual magnetization Mr of 500 emu/cc or lower.
The reason why effects of a residual magnetic field are examined at a point 10 nm distant from the master surface is reasonable as follows. Specifically, in the layer structure of the slave disc 10 (see
That is, in the state where the master disc 20 is closely attached to the slave disc 10 during transfer, the magnetic layer of the master disc 20 is about 10 nm distant from the magnetic layer 16 of the slave disc 10, since non-magnetic films (e.g., a protective layer) is provided between the magnetic layers. Actually, the interdistance between the magnetic layers may be greater than 10 nm. But, the greater the interdistance between the magnetic layers, the weaker a magnetic field generated. Thus, effects of a residual magnetic field are examined at a point 10 nm distant from the master surface.
Regarding anisotropy constant Ku (erg/cm3), presumably, perpendicular magnetic recording media are required to have a value KuV/(kT) of 60 or more for maintaining information recorded by magnetization. In this value, V denotes a magnetization inversion volume (cm3), k denotes a Boltzmann constant (1.38×10−16 erg/deg) and T denotes a temperature.
The magnetization inversion volume V becomes smaller in accordance with an increase in recording density. Thus, for producing perpendicular magnetic recording media, a material used must have a high anisotropy constant Ku.
In contrast, regarding the master magnetic layer, information recording is carried out based on a magnetic pattern formed in a magnetic layer. Preferably, the magnetic pattern is formed only during transfer (only during application of a magnetic field for recording), and the magnetic pattern disappears after transfer (during completion of application of the magnetic field).
Thus, the anisotropy constant Ku of the master magnetic layer may be small In this point, a magnetic material for a perpendicular magnetic recording medium is greatly different from that for a master carrier
The reverse magnetic domain nucleus forming magnetic field Hn of the master magnetic layer is preferably equal to or lower than a magnetic field applied, since the saturation magnetization Ms of the master magnetic layer is effectively utilized. In general, the magnetic field applied does not exceed the coercive force Hc of a magnetic layer of the slave disc 10. Thus, the Hn of the master magnetic layer is adjusted to be equal to or lower than the He of the slave magnetic layer (i.e, Hn of master magnetic layer≦He of slave magnetic layer).
When the coercive force He of the master magnetic layer is too high, the master magnetic layer is not magnetized by a magnetic field applied
Also, magnetic transfer cannot be carried out. Application of a high transfer magnetic field disadvantageously generates a magnetic field at concave portions. Thus, the coercive force He of the master magnetic layer is preferably 2,000 Oe or lower, more preferably 500 Oe or lower.
As described above, the master disc 20 having a perpendicularly magnetized film exhibiting magnetic characteristics shown in Table 1 attains transfer at an excellent S/N ratio for the following four reasons: (1) a transfer magnetic field increases at convex portions (transfer portions) which are attached to the slave disc 10, (2) a magnetic field is reduced at concave portions (non-transfer portions) by virtue of no demagnetic field, (3) the boundary region between the convex and concave portions has a sharp magnetic field distribution, and (4) undesirable transfer is not caused by the residual magnetization of the master disc 20 having undergone transfer.
For example, the material for the master magnetic layer exhibiting magnetic characteristics shown in Table 1 is preferably CoPt, more preferably Co4Pt1 (atomic ratio). Table 1 shows the magnetic characteristics of the master magnetic layer made of Co4Pt1.
Needless to say, the material which can be used in the present invention is not limited thereto. Any other materials can be used, so long as they exhibit required characteristic values as described above.
Also, an underlying layer may be formed under a magnetic layer of the master disc 20. For example, the material for the underlying layer is preferably Pt, Ru and CoCr, more preferably CoCr whose Cr content is 25 atom % or higher, Pt and Ru. These materials may be used alone or combination.
The thickness of the underlying layer is preferably 0.5 nm to 30 nm, more preferably 1 nm to 10 nm.
As described above with reference to
In such a concavo-convex master carrier, when a conventional magnetic isotropic film is used as a magnetic layer, the bit portion must have a high aspect ratio (i.e., a ratio of the size in a depth direction to the size in a down-track direction). This is because a magnetic field must be effectively applied to the convex portion during transfer in consideration of the effects of a demagnetic field generated.
However, manufacturing of a concavo-convex master carrier having a high aspect ratio involves problems. For example, when a master disc is separated from an original master or is replicated, the convex portion of the master disc is chipped to become a reject product. When the aspect ratio exceeds 1, the reject product is increasingly yielded.
In contrast, a magnetic film having perpendicular magnetic anisotropy used in the present invention does not involve a demagnetic field and thus, the aspect ratio can be low and production yield is remarkably improved.
Also, the master disc 20 in the present invention is attached to a slave disc in a smaller surface area, as compared with a magnetic layer-embedded master disc (
In order to further obtain the above-described advantageous effects, preferably, only portions corresponding to transfer signals have a convex shape; i.e., the other portions have a concave shape. In the case of transfer of servo signals, a data region has a concave shape. When a master disc having too large concave portions is superposed on a slave disc, the concave portions may be deformed and attached to a portion of the slave disc. In this case, small convex portions may be formed in the large concave portions to prevent such unfavorable phenomenon.
With reference to
Next, the original plate 30 is set on a high-precision rotary stage or X-Y stage provided in an electron beam exposure apparatus (not shown), an electron beam modulated correspondingly to a servo signal is applied while the original plate 30 is being rotated, and a predetermined pattern 33 is formed on the substantially entire surface of the resist layer 32; for example, a pattern that corresponds to a servo signal and that linearly extends in the radial direction from the rotational center to each track is formed at portions corresponding to frames on the circumference by writing exposure (electron beam writing) (see
Subsequently, as shown in
Subsequently, as shown in
Thereafter, as shown in
Subsequently, as shown in
Subsequently, as shown in
The original master 36 over which the metal plate 40 has been laid in the above manner is removed from the electrolytic solution placed in the electrodepositing device, and then immersed in purified water placed in a releasing bath (not shown).
In the releasing bath, the metal plate 40 is released from the original master 36 (releasing step), to thereby produce a master substrate 42 as shown in
Next, as shown in
Thereafter, the master substrate 42 is punched out so as to have a predetermined inner diameter and a predetermined outer diameter. Through the above procedure, a master disc 20 having a concavo-convex pattern is fabricated, which has a magnetic layer 48 (which corresponds to a magnetic layer 204 in
When the master disc 20 is closely attached to the slave disc 10, the magnetic layer 48 tends to be scratched. Thus, the protective layer is formed to prevent the master disc 20 from such scratch formation. The lubricating layer prevents, for example, scratch formation by friction generated when the master disc is attached to the slave disc 10 and thus, improves the master disc in durability.
Specifically, a master disc having a preferred layer structure has, on the magnetic layer, a carbon film having a thickness of 2 nm to 30 nm and serving as a protective film, and has a lubricating layer on the protective film. Also, for improving adhesiveness between the magnetic layer 48 and the protective film, an adhesiveness-improving layer made, for example, of Si may be formed on the magnetic layer 48 before formation of the protective film.
Next, as shown in
In the closely attaching step in
If necessary, before closely attached to the master disk 20, the slave disk 10 is subjected to a cleaning process (e.g., burnishing) in which minute protrusions or attached dust on its surface is removed using a grind head, a polisher or the like.
As to the closely attaching step, there is a case where the master disk 20 is closely attached only to one surface of the slave disk 10 as shown in
Next, the magnetic transfer step will be described with reference to
Using an unillustrated magnetic field applying unit, a recording magnetic field Hd is applied, in the opposite direction to the initializing magnetic field Hi, to the slave disk 10 and the master disk 20 that have been closely attached to each other at the closely attaching step. Magnetic transfer is carried out as a magnetic flux generated through formation of the recording magnetic field Hd enters the slave disk 10 and the master disk 20.
In the present embodiment, the intensity of the recording magnetic field Hd is approximately equal to that of He of the magnetic material forming the magnetic layer 16 of the slave disk 10.
As to the magnetic transfer, while the slave disk 10 and the master disk 20 closely attached to each other is being rotated by a rotating unit (not shown), the recording magnetic field Hd is applied by the magnetic field applying unit, to thereby magnetically transfer, to the magnetic layer 16 of the slave disk 10, information recorded on the master disk 20 in the form of the protrusion pattern. In addition to the above, a mechanism of rotating the magnetic field applying unit may be provided such that the magnetic field applying unit is rotated relatively to the slave disk 10 and the master disk 20.
In the case where this magnetic transfer apparatus is used to carry out initial magnetization and then to carry out magnetic transfer, an electric current is applied which flows in the opposite direction to an electric current applied to the coil 63 of the magnetic field applying unit 60 during initial magnetization. This makes it possible to generate a recording magnetic field in the opposite direction to the magnetization direction at the time of initial magnetization. In the magnetic transfer, while the slave disk 10 and the master disk 20 closely attached to each other is being rotated, the recording magnetic field Hd is applied by the magnetic field applying unit 60, and the information recorded on the master disk 20 in the form of the protrusion pattern is magnetically transferred to the magnetic layer 16 of the slave disk 10; accordingly, the rotating unit (not shown) is provided. Apart from the above, a mechanism of rotating the magnetic field applying unit 60 may be provided such that the magnetic field applying unit 60 is rotated relatively to the slave disk 10 and the master disk 20.
In the present embodiment, magnetic transfer is carried out by applying a recording magnetic field Hd which is equivalent in strength to 60% to 125%, preferably 70% to 115%, of the coercive force Hc of the magnetic layer 16 of the slave disk 10 used in the present embodiment.
Thus, on the magnetic layer 16 of the slave disk 10, information of a magnetic pattern, such as a servo signal, is recorded as a recording magnetization Pd which is in the opposite direction to the initial magnetization Pi (see
Notably, the magnetic transfer method of the present invention is carried out, the protrusion pattern of the master disc 20 may be a negative pattern rather than a positive pattern as shown in
[Investigation on Conditions Under which Magnetic Transfer is Carried Out]
In the case where information is magnetically transferred to a perpendicular magnetic recording medium based on the concavo-convex pattern formed in the surface of the master disc, when the state where initial magnetization is carried out is expressed by a hysteresis curve in the vicinity of an Mz/Ms of −1 in
Also, a perpendicular coercive force (He shown in
Hc(t)=Ha{1−[(kT/KV)ln(At)]n} <Equation 1>
where Ha denotes an anisotropic magnetic field (Oe); k denotes a Boltzmann constant (1.38×10−16 erg/deg); T denotes a measurement temperature; K denotes an anisotropy constant (erg/cm3); V denotes a magnetization inversion volume (cm3); A denotes a spin precession frequency (2×109 sec−1)/ln2; and n denotes a parameter depending on alignment of moment (½ in general)
Thus, when an external magnetic field is applied to the master disc being closely attached to the magnetic recording medium having undergone initial magnetization, as shown in the above Equation 1, the coercive force He and the reverse magnetic domain nucleus forming magnetic field Hn change depending on a change in magnetic field application time (application speed). Qualitatively, as the application time is shorten (i.e., application speed is increased), the coercive force He and the reverse magnetic domain nucleus forming magnetic field Hn tend to increase.
When the magnetic field application time is too long, both He (coercive force) and Hn (reverse magnetic domain nucleus forming magnetic field) decrease. As a result, a magnetic field in the concave portion of the master disc is greater than Hn, degrading the quality of a transfer signal.
In contrast, when the magnetic field application time is too short, both He (coercive force ) and Hn (reverse magnetic domain nucleus forming magnetic field) increase. As a result, the convex portion of the master disc is not completely magnetized, degrading the quality of a transfer signal In addition, signal quality is also degraded by eddy current formed.
In a perpendicular magnetic recording medium (a medium to which information is to be transferred) which gives a hysteresis curve as shown in
2×(Hc−Hn)<(magnetic field in L portion of master)−(magnetic field in S portion of master) <Expression 2>
where “L portion” is a surface (land) of the convex portion 210 in the concavo-convex pattern of the master disc 20 (see
In magnetic transfer, a slave disc is magnetized using a master disc having a difference in magnetic field between the concave and convex portions. This difference brought by the concavo-convex pattern is determined to some extent the design of the pattern. But, as described above, the hysteresis curve depends on time and thus, Hc and Hn change depending on a change in application time of an external magnetic field. Specifically, even when magnetic fields in the L and S portions are each constant, in the perpendicular magnetic recording medium, the difference between the magnetization quantity brought by the magnetic field in the L portion and that brought by the magnetic field in the S portion changes depending on a change in magnetic field application time.
In view of this, in an embodiment of the present invention, the application time of a DC magnetic field is optimized to maximize the difference between the magnetization quantity brought by the magnetic field in the L portion and that brought by the magnetic field in the S portion.
In contrast, when the magnetic field application time is too long, a curve drawn by a dotted line in
When the magnetic field application time is optimized (i.e., the magnetic field application speed is optimized), a curve drawn by a solid line in
As used herein, “the difference between the magnetization quantity brought by the magnetic field in the L portion and that brought by the magnetic field in the S portion” (indicated by “a,” “b” or “c” in
As described above, an optimally-adjusted magnetic field application time attains, in the medium, a large difference between the magnetization quantity brought by the magnetic field in the L portion and that brought by the magnetic field in the S portion, improving the quality of the waveform of a transfer signal to be read (e.g., achieving a great output value and/or a constant width of the waveform).
A perpendicular magnetic recording medium obtained by the above-described method according to an embodiment of the present invention is mounted in use to, for example, a magnetic recording/reproducing device such as hard disc devices, and can provide a high recording density magnetic recording/reproducing device having high servo accuracy and preferred recording/reproducing characteristics.
The present invention will next be described by way of examples, which should not be construed as limiting the present invention thereto.
Using a magnetic transfer master carrier having perpendicular magnetic anisotropy in the present invention (the master carrier having a magnetic layer with a residual magnetization Mr of 500 emu/cc and a saturation magnetization Ms of 900 emu/cc, and having a magnetic layer-covered transfer portion corresponding to magnetic information and a concave non-transfer portion lower in height than the transfer portion) (Example 1) and a magnetic transfer master carrier having a conventional magnetic layer (having no perpendicular magnetic anisotropy) (Comparative Example 1), the relationship between the magnetic field application time and the quality of the waveform of a reproduced signal (transferring performance) was investigated. The results are shown in Table 2.
The slave disc used in the experiments had a coercive force He of 4,000 [Oe]. After initial magnetization, the slave disc was closely attached to a master disc having a concavo-convex pattern radially formed from 50 nm to 300 nm in a circumferential direction and 50 nm to 300 nm in a radial direction. In this state, a DC magnetic field was applied perpendicularly to the disc surface while the application time thereof was being changed from 1 ns (nano second) to 1,000 s (second), whereby information corresponding to the concavo-convex pattern was magnetically transferred to the slave disc. The information of the thus-obtained slave disc was reproduced for evaluation of the waveform of a reproduced signal output.
As shown in
Next will be described an apparatus used for evaluating a servo signal transferred to the slave disc.
The slave disc is fixed by the axis of a spindle motor so as to be rotated at a predetermined speed (revolution). A magnetic head is disposed proximately to the slave disc surface at a predetermined flying height. The magnetic head can be moved by a positioner to a predetermined position, and is used for recording/reproducing.
Also, a synchroscope (oscilloscope) is connected to the magnetic head, and displays the waveform of a signal read by the magnetic head. The synchroscope is also connected to the spindle motor, and an index signal, which is output when the rotator of the spindle motor is in a predetermined rotation angle, is input as a trigger signal to the synchroscope.
As is clear from Table 2, when the transfer magnetic field application time was varied, the magnetic transfer master carrier having a perpendicularly magnetized film (Example 1) was found to exhibit, at any transfer magnetic field application times, higher reproduced signal outputs and smaller variation in width of a waveform than the magnetic transfer master carrier having a conventional magnetic film (Comparative Example 1). Thus, the master carrier of Example 1 was found to give better signal quality.
In Example 1, first, the output value gradually increased in accordance with increasing of the magnetic field application time, and was the maximum value “1.83” at an application time of 0.001 ms. At application times of 0.01, 0.1, 1, 10, 100 and 1,000, the output value decreased in accordance with increasing of the magnetic field application time.
Meanwhile, first, the variation in width of a waveform was gradually smaller in accordance with increasing of the magnetic field application time, and was the minimum value “0.55” at an application time of 0.001 ms. At application times of 0.01, 0.1, 1, 10, 100 and 1,000, the variation was larger in accordance with increasing of the magnetic field application time. Comprehensively judging from the output value and the variation, the magnetic field application time is preferably 100 ns to 1 sec, more preferably 1 μs to 100 ms, still more preferably 100 μs to 10 ms.
When a magnetic field is applied at an application time falling within the above range, the quality of transfer signals can be improved.
Strictly speaking, different magnetic materials have different characteristics (hysteresis curve and time dependency thereof). But, known materials used in the perpendicular magnetic recording medium generally show almost the same results as given above. Thus, an optimal magnetic field application time falls within the above range.
The perpendicular magnetic recording medium obtained by the present magnetic transfer method for a magnetic recording medium is mounted in use to, for example, a magnetic recording/reproducing device such as a hard disc device, and can provide a high recording density magnetic recording/reproducing device having high servo accuracy and preferred recording/reproducing characteristics.
Number | Date | Country | Kind |
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2008-076668 | Mar 2008 | JP | national |