Patent Grant
11261369
This application is a national phase of International Patent Application No. PCT/CN2018/082088 filed Apr. 6, 2018, which claims the priority benefit of Chinese Patent Application Serial No. 201710240505.9 filed Apr. 13, 2017 and PCT Application No. PCT/US17/068460 filed Dec. 27, 2017.
The disclosed technology generally described hereinafter provides for maleic anhydride copolymers with broadly dispersed ester side chains, and more specifically, to maleic anhydride copolymers with broadly dispersed ester side chains formed from alcohols with more than 25% by weight of alcohols containing greater than 35 carbon atoms.
In production of most wax-containing oils such as crude oils, a major problem occurs when the oil temperature is below the solidification temperature of the wax in the oil, because the wax solidifies and tends to precipitate out and deposit on the piping and other equipment contacted by the oil. Build-up of wax deposits can impact oil production throughput due to reduced effective pipe diameter, also associate with accelerated corrosion. Moreover, wax deposition may cause the oil to lose its ability to flow, and thus cause difficulties in transporting the oil through lines and pumps.
Comb polymers are widely used as wax inhibitors and pour point depressants in oil production and transportation to interfere with the wax crystallization process to reduce deposit amounts and/or improve crude flowability at temperatures below wax appearance temperature. The performance of comb polymers are affected by the varying lengths and proportions of wax alkane chains that are found from crude to crude.
A challenge encountered in the oil production industry is how to efficiently treat crudes that contain very long waxes (i.e. C40+). Currently, there is no efficient way to treat these long waxes because there is no cost-effective, synthetic way to introduce equally long alkyl chains into a comb polymer.
In the upstream industry, additional challenges are encountered, which include how to treat crudes containing heavy wax (high MW wax or high Cn wax, normally defined as >C35 paraffin) to inhibit the wax deposition, as well as how to create a single product that works efficiently for all crudes.
The disclosed technology generally described hereinafter provides for maleic anhydride copolymers with broadly dispersed ester side chains, and more specifically, to maleic anhydride copolymers with broadly dispersed ester side chains formed from alcohols with more than 25% by weight of alcohols containing greater than 35 carbon atoms.
In one aspect of the present technology, a wax inhibitor composition is provided. The wax inhibitor composition comprises at least one alpha-olefin maleic anhydride copolymer of the formula
wherein R1 is selected from hydrocarbyl groups containing 10-30 carbon atoms, and R2 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R2, if not hydrogen, is broadly dispersed, wherein R2 comprises a weight fraction of carbon numbers greater than 30, wherein R2 can be the same or different, and n is a number of repeating units ranging from 1 to 100.
In some embodiments, the at least one alpha olefin maleic anhydride copolymer is prepared by reacting an alpha-olefin containing greater than 10 carbon atoms with maleic anhydride in the presence of a free radical initiator to obtain a high molecular weight copolymer, followed by reacting the high molecular weight copolymer with an alcohol mixture having a dispersed chain length ranging from 10 to 80 carbon atoms.
In some embodiments, the alpha-olefin comprises a range of about 10-30 carbon atoms. In some embodiments, the alpha-olefin comprises at least 18 carbon atoms. In some embodiments, the alpha-olefin is 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacosene, 1-octacosene, 1-hexadecene, 1-tetradecane, or 1-dodecene.
In some embodiments, the alcohol mixture contains more than 25% by weight of alcohols in the alcohol mixture contain greater than 35 carbon atoms.
In some embodiments, the alcohol mixture has a dispersed chain length ranging from C10-C60. In some embodiments, the alcohol mixture has a dispersed chain length ranging from C20-C70. In some embodiments, the alcohol mixture has a dispersed chain length ranging from C30-C80.
In some embodiments, the alcohol mixture comprises a linear aliphatic alcohol containing more than 25% by weight of alcohols in the alcohol mixture contain greater than 35 carbon atoms.
In yet another aspect of the present technology, a comb polymer composition is provided. The comb polymer composition comprises at least one alpha olefin maleic anhydride copolymer of the formula
wherein R3 is selected from hydrocarbyl groups containing 10-40 carbon atoms, and R4 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R4, if not hydrogen, is broadly dispersed, wherein R4 comprises a weight fraction of carbon numbers greater than 30, R5 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R5, if not hydrogen, is broadly dispersed, wherein R5 comprises a weight fraction of carbon numbers greater than 30, wherein R4 and R5 are the same or different, and n is a number of repeating units ranging from 1 to 100.
In some embodiments, the at least one alpha olefin maleic anhydride copolymer is prepared by reacting an alpha-olefin or alpha-olefin mixture with a chain length of greater than 24 carbon atoms with a dicarboxylic acid to obtain a copolymer, followed by reacting the copolymer with an alcohol mixture in the presence of a catalyst, wherein the alcohol mixture contains a fully saturated, linear primary alcohol, having a dispersed chain length ranging from 10 to 80 carbon atoms.
In some embodiments, the alpha-olefin is 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacosene, 1-octacosene, or 1-hexadecene, 1-tetradecane, 1-dodecene, or C30-54 olefin.
In some embodiments, the dicarboxylic acid is maleic anhydride. In some embodiments, the alcohol mixture contains more than 25% by weight of alcohols in the alcohol mixture contain greater than 35 carbon atoms.
In some embodiments, the alcohol mixture has a dispersed chain length ranging from C10-C60. In some embodiments, the alcohol mixture has a dispersed chain length ranging from C20-C70. In some embodiments, the alcohol mixture has a dispersed chain length ranging from C30-C80.
In some embodiments, the alpha-olefin has a chain length of between 24-28 carbon atoms and the alcohol mixture has a dispersed chain length of greater than 25 carbon atoms. In some embodiments, the alpha-olefin has a chain length of greater than 30 carbon atoms and the alcohol mixture has a dispersed chain length of greater than 30 carbon atoms. In some embodiments, the alpha-olefin has a chain length of greater than 30 carbon atoms and the alcohol mixture has a dispersed chain length of greater than 40 carbon atoms.
In some embodiments, the comb polymer composition is used to effectively treat crudes comprising long waxes containing greater than 40 carbon atoms.
In some embodiments, approximately 50-200% of the dicarboxylic acid is esterified with the alcohol mixture.
In yet another aspect of the present disclosure, a method of reducing wax deposition from an oil is provided. The method comprises adding to the oil an effective amount of a wax inhibitor composition comprising at least one alpha olefin maleic anhydride copolymer, wherein the at least one alpha olefin maleic anhydride copolymer is prepared by reacting an alpha-olefin containing greater than 10 carbon atoms with maleic anhydride in the presence of a free radical initiator to obtain a high molecular weight copolymer, followed by reacting the high molecular weight copolymer with an alcohol mixture having a dispersed chain length ranging from 10 to 80 carbon atoms.
In some embodiments, the at least one alpha olefin maleic anhydride copolymer of the formula:
wherein R1 is selected from hydrocarbyl groups containing 10-30 carbon atoms, and R2 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R2, if not hydrogen, is broadly dispersed, wherein R2 comprises a weight fraction of carbon numbers greater than 30, wherein R2 can be the same or different, and n is a number of repeating units ranging from 1 to 100.
In some embodiments, the at least one alpha olefin maleic anhydride copolymer of the formula:
wherein R3 is selected from hydrocarbyl groups containing 10-40 carbon atoms, and R4 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R4, if not hydrogen, is broadly dispersed, wherein R4 comprises a weight fraction of carbon numbers greater than 30, R5 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R5, if not hydrogen, is broadly dispersed, wherein R5 comprises a weight fraction of carbon numbers greater than 30, wherein R4 and R5 are the same or different, and n is a number of repeating units ranging from 1 to 100.
In some embodiments, the alcohol mixture contains more than 25% by weight of alcohols in the alcohol mixture contain greater than 35 carbon atoms. In some embodiments, the oil comprises long waxes containing greater than 40 carbon atoms.
In some embodiments, the weight percent of the high molecular weight copolymer in the wax inhibitor composition is in a range from 0.1% to 100%. In some embodiments, the oil comprises a wax content of 0.1% to 100% by weight. In some embodiments, the oil is a crude oil having a wax content of 0.1% to 100%. In some embodiments, the weight percentage of the wax inhibitor in the crude oil is in a range from 0.001% to 1%.
These and other features of the disclosed technology, and the advantages, are illustrated specifically in embodiments now to be described, by way of example, with reference to the accompanying diagrammatic drawings, in which:
The disclosed technology generally to maleic anhydride copolymers with broadly dispersed ester side chains, where these novel copolymers can be used as wax inhibitors or wax crystallization enhancers. The disclosed technology provides novel copolymers that can be used to treat a broad range of crudes containing short or long waxes, and is especially successful in treating crudes containing very long waxes (C40+).
The maleic anhydride copolymers contain broadly dispersed ester side chains on a carbon number, where “broadly dispersed” can be understood to mean as having both short and very long side chains. The broadly dispersed ester side chains provide a significant benefit of the copolymer performance, especially on crudes containing heavy wax, and on applications that enhance wax crystallization. By obtaining the broadly dispersed ester side chains, the copolymers of the present technology can be used with both crudes containing very long waxes, as well as for a broad range of crudes. This is significant as these copolymers can reduce the burden of preparing a range of comb polymers for wax treatment since many comb polymers only work for a narrow range of crudes.
The broadly dispersed ester side chains of the present technology are formed by using a select group of alcohols that are fully saturated, long chain, linear alcohols. These alcohols are of high molecular weight, have greater crystallinity, and have a high purity with high (e.g. >80%) primary alcohol concentration. The alcohols used to build the ester side chains of the copolymers of the present technology contain an especially significant heavy fraction, that is more than 25% by weight of the alcohol contains greater than 35 carbon atoms.
In some embodiments, a wax inhibitor composition is provided. The wax inhibitor composition comprises at least one alpha-olefin maleic anhydride copolymer. In some embodiments, the alpha-olefin maleic anhydride copolymer is represented by the formula:
wherein R1 is selected from hydrocarbyl groups containing 10-30 carbon atoms, and R2 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R2, if not hydrogen, is broadly dispersed, wherein R2 comprises a weight fraction of carbon numbers greater than 30, wherein R2 can be the same or different, and n is a number of repeating units ranging from 1 to 100.
As used herein the term “hydrocarbyl” refers to any combination of straight-chain, branched-chain, or cyclic alkyl, alkenyl, alkynyl, aryl groups, or the respective group substituted with one or more substituents, including, but not limited to, groups such as alkyl, alkenyl, alkynyl, aryl, cycloalkyl groups and any combination thereof.
The alpha-olefin maleic anhydride copolymer of the wax inhibitor composition is prepared by reacting an alpha-olefin containing greater than 10 carbon atoms with maleic anhydride in the presence of a free radical initiator (such as dicumylperoxide, but other free radical initiators are useful in this context of the present technology and are known to those skilled in the art) to obtain a high molecular weight copolymer. In some embodiments, a Lewis-acid catalyst may be present.
The high molecular weight copolymer may be made by any of the methods known in the art, e.g. by solution polymerization with free radical initiation. The high molecular weight copolymer is subsequently reacted with an alcohol mixture having a dispersed chain length ranging from 10 to 80 carbon atoms in order to build the ester side chains present. However, it should be understood that all linear aliphatic alcohols containing a significant heavy fraction (e.g. >25 wt % of Cn>35) can be used to achieve the effect of the present technology. Additionally, subsequent to the formation of the alpha-olefin maleic anhydride copolymers of the present technology, the separation or pouring into cold alcohols to precipitate pure polymer is not necessary.
In some embodiments, the alpha-olefin comprises a range of about 10-30 carbon atoms. In other embodiments, the alpha-olefin comprises at least 18 carbon atoms. In some embodiments, the alpha-olefin is 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacosene, 1-octacosene, 1-hexadecene, 1-tetradecane, or 1-dodecene. In a specific embodiment, the alpha-olefin is 1-octadecene.
In some embodiments, the alcohol mixture refers to a C10-C80 alcohol blend with an average number of carbon atoms in a range from 25 to 50. Each of alcohols in the alcohol mixture contains 10 to 80 carbon atoms, while the alcohols in the alcohol mixture are proportioned for the alcohol mixture contain more than 25% by weight of alcohols in the alcohol mixture contain greater than 35 carbon atoms.
In some embodiments, the alcohol mixture includes at least one C10-C80 alcohol blend. In some embodiments, the alcohol mixture includes at least two C10-C80 alcohol blends.
In some embodiments, the alcohol mixture has a dispersed chain length ranging from C10-C60. In some embodiments, the alcohol mixture has a dispersed chain length ranging from C20-C70. In some embodiments, the alcohol mixture has a dispersed chain length ranging from C30-C80.
In yet another embodiment, a comb polymer composition is provided. The comb polymer composition of the present technology can be used to effectively treat crudes comprising long waxes containing greater than 40 carbon atoms and is more effective than other commercial additives.
The comb polymer composition comprises at least one alpha-olefin maleic anhydride copolymer. In some embodiments, the alpha-olefin maleic anhydride copolymer is represented by the formula:
wherein R3 is selected from hydrocarbyl groups containing 10-40 carbon atoms, and R4 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R4, if not hydrogen, is broadly dispersed, wherein R4 comprises a weight fraction of carbon numbers greater than 30, R5 is selected from a hydrogen or hydrocarbyl groups containing 10-80 carbon atoms, and R5, if not hydrogen, is broadly dispersed, wherein R5 comprises a weight fraction of carbon numbers greater than 30, wherein R4 and R5 are the same or different, and n is a number of repeating units ranging from 1 to 100.
In some embodiments, the comb polymer composition can also be used as wax enhancer in some applications where accelerated wax crystallization is desired. One example of such applications is oil de-waxing. In such applications, wax crystal formation is preferred as wax is an important industrial raw material, and a de-waxed oil, which has better low temperature flowability, is useful in many areas.
The alpha-olefin maleic anhydride copolymer of the comb polymer composition is prepared by reacting an alpha-olefin or alpha-olefin mixture with a chain length of greater than 10 carbon atoms with a dicarboxylic acid to obtain a copolymer, followed by reacting the copolymer with an alcohol mixture in the presence of a catalyst, wherein the alcohol mixture contains a fully saturated, linear primary alcohol, having a dispersed chain length ranging from 10 to 80 carbon atoms.
In some embodiments, the alpha-olefin is 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacosene, 1-octacosene, or 1-hexadecene, 1-tetradecane, 1-dodecene, or C30-54 olefin.
In some embodiments, the dicarboxylic acid is maleic anhydride. In some embodiments, approximately 50-200% of the dicarboxylic acid is esterified with the alcohol mixture, where the alcohol mixture contains more than 25% by weight of alcohols in the alcohol mixture contain greater than 35 carbon atoms.
In some embodiments, the alpha-olefin has a chain length of between 24-28 carbon atoms and the alcohol mixture has a dispersed chain length of greater than 25 carbon atoms. In some embodiments, the alpha-olefin has a chain length of greater than 30 carbon atoms and the alcohol mixture has a dispersed chain length of greater than 30 carbon atoms. In some embodiments, the alpha-olefin has a chain length of greater than 30 carbon atoms and the alcohol mixture has a dispersed chain length of greater than 40 carbon atoms.
In some embodiments, the comb polymer composition is added in a range of about 500 ppm of the waxy oil. In other embodiments, the comb polymer composition is added in a range of about 100 ppm of the waxy oil, and in other embodiments, about 2000 ppm of the waxy oil.
In yet another embodiment, a method of reducing wax deposition from an oil is provided. The oil comprises long waxes containing greater than 40 carbon atoms. In some embodiments, the oil comprises a wax content of 0.1% to 100% by weight. In some embodiments, the oil is a crude oil having a wax content of 0.1% to 100%. In such embodiments, wherein the weight percentage of the wax inhibitor in the crude oil is in a range from 0.001% to 1%.
The method comprises adding to the oil an effective amount of a wax inhibitor composition, where the wax inhibitor composition comprises an alpha-olefin maleic anhydride copolymer. The alpha-olefin maleic anhydride copolymer of the wax inhibitor composition is prepared by reacting an alpha-olefin containing greater than 10 carbon atoms with maleic anhydride in the presence of a free radical initiator to obtain a high molecular weight copolymer, followed by reacting the high molecular weight copolymer with an alcohol mixture having a dispersed chain length ranging from 10 to 80 carbon atoms.
In some embodiments, the alpha-olefin maleic anhydride copolymer is represented by Formula (I) described above, and in other embodiments, the alpha-olefin maleic anhydride copolymer is represented by Formula (II) described above. In some embodiments, wherein the weight percent of the high molecular weight copolymer in the wax inhibitor composition is in a range from 0.1% to 100%.
The present invention will be further described in the following examples, which should be viewed as being illustrative and should not be construed to narrow the scope of the invention or limit the scope to any particular invention embodiments.
Table 1 provides a description of the experimental examples and commercial products, where mol % is mol ratio of alcohols to maleic anhydride, theoretically the mol % range can be 0-200% as there are two carboxylic acid moiety on maleic anhydride.
Wax Deposition Inhibition
Wax deposition inhibitions of these samples were evaluated on PSL CF-15 cold finger or self-designed cold finger following industrial standard cold finger testing protocol, using Surrogate oils (Exxon Mobile Aromatic 150/Exxsol D60 blends provided with commercial waxes), Doctored crudes (non-waxy crudes provided with about 5 wt % Wako44 commercial wax and 5 wt % Wako68 commercial wax) and real crudes.
Pour Point Depression
A summary of the cold finger test results of these samples are summarized in Table 2 below.
As shown in Table 2, the experimental chemistry significantly inhibit wax deposition in cold finger test in two crudes containing very long waxes (>3% nC40+), while Commercial-1 is not responsive. Tuning chemistry can also make the experimental chemicals act as wax enhancer to promote wax crystallization in crude with low WAT, as can be seen by the results from EXP-2/3 on China Crude 3 crude.
Maleic Anhydride Copolymers
It was clearly shown that the maleic anhydride copolymers with the dispersed ester side chains of the present disclosure (e.g. the polymers with C10-80 alcohol side chains) showed improved performance over all commercial additives. FIG. 2 provides the cold finger test results where the oil is characterized as 5% Wako44 wax+5% Wako68 wax in D60/A150 (7/3 v/v), WAT 33.8° C., wax content: 10%. The cold finger was run at 35/25° C., 200 rpm, 4 hrs, 60 g oil. As can be seen in
Additionally, the maleic anhydride copolymers with the dispersed ester side chains (i.e. broadly distributed side chains) and compositions thereof as provided by the present disclosure perform in surrogate oils with heavy or light wax content, the surrogate oil with heavy wax is characterized as 5% Wako44 wax+5% Wako68 wax in D60/A150 (7/3 v/v), the surrogate oil with light wax is characterized as 4.5% Aldrich53 wax+0.5% SinoPec80 wax in D60/A150 (7/3 v/v).
While embodiments of the disclosed technology have been described, it should be understood that the present disclosure is not so limited and modifications may be made without departing from the disclosed technology. The scope of the disclosed technology is defined by the appended claims, and all devices, processes, and methods that come within the meaning of the claims, either literally or by equivalence, are intended to be embraced therein.
| Number | Date | Country | Kind |
|---|---|---|---|
| 201710240505.9 | Apr 2017 | CN | national |
| PCT/US17/68460 | Dec 2017 | WO | international |
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|---|---|---|---|
| PCT/CN2018/082088 | 4/6/2018 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2018/188523 | 10/18/2018 | WO | A |
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