The present application claims priority to German Patent Application No. 102020110502.9 filed on Apr. 17, 2020. The entire contents of the above-listed application is hereby incorporated by reference for all purposes.
The present invention relates to the manufacture of beverages, in particular low-oxygen, carbonated beverages.
In filling lines for beverages, containers, for example bottles, cans etc., are treated in a plurality of successive process steps. Here, the process steps are in general performed in separate treatment stations which can be combined, for example, as modules of one common plant concept. A container treatment plant for glass bottles or plastic bottles, e.g. of polyethylene terephthalate (PET), polypropylene (PET) etc., can comprise, for example, a blow moulding means, a filling device, a carbonation device, a closing device, a labelling device, a packaging device, a cleaning device, a pasteurisation device, an inspection device etc. as separate, modularly designed treatment stations. The individual treatment stations, which perform successive process steps, are in general connected in series one behind the other, one or several transport devices providing the transport of the containers from the treatment stations to the respective downstream treatment stations.
It is getting increasingly important in beverage production to reduce the oxygen content or, in general, the foreign gas proportion, for example nitrogen or air, to in particular clearly extend the durability of the filled beverages and avoid chemical reactions with the pack (in particular can) as well as problems during the filling process. Moreover, higher filling temperatures can be permitted in this way, involving lower costs for cooling. Some beverages, for example beer and soda pops, are mixed with carbon dioxide. The open-loop/closed-loop control of the degassing for oxygen reduction and of the carbonation, however, involve problems in view of the complexity of the process operations and the precision and reliability of the achieved values for the degree of oxygen reduction and carbonation. For example, in the manufacture of beverages with syrup, oxygen is typically introduced by adding the syrup, after the degassing of water to the degassed water. Very high amounts of required stripping gases or a relatively high, undesired oxygen content which can lead to a bursting of the cans and an impaired quality during storage when the beverage is packaged into (coated) cans pose particular problems.
It is the object underlying the invention to provide a, compared to prior art, more reliable and efficient manufacture of carbonated beverages with a well-controlled, reduced oxygen content and with a well-controlled CO2 content.
The above-mentioned object is achieved by providing a method for the manufacture of a carbonated beverage, the method including the steps of:
providing oxygen-reduced water;
mixing the oxygen-reduced water with a mixing component (for example syrup, concentrate, or flavours) to obtain a beverage mixture;
adding a gas comprising CO2 (and which can, for example, comprise N2) to the beverage mixture to obtain a beverage mixture mixed with CO2;
reducing the oxygen content of the beverage mixture mixed with CO2 in a first (stripping gas) container to obtain an oxygen-reduced beverage mixture mixed with CO2;
discharging the oxygen-reduced beverage mixture mixed with CO2 from the first container;
determining the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 (for example during or after the discharge in a discharge line of the first container); and
adding further CO2 to the discharged, oxygen-reduced beverage mixture mixed with CO2 on the basis of the determined CO2 content to obtain a finally carbonated beverage (which can be packaged, for example into bottles or cans, in the further course of the process).
When oxygen-reduced water is mentioned, this can mean degassed water, i.e. for example water that has passed through a degassing means.
For example, the addition of the gas comprising CO2, which can serve as a stripping gas in the oxygen reduction, to the beverage mixture to obtain the beverage mixture mixed with CO2 can be accomplished such that the beverage mixture mixed with CO2 is not saturated with CO2. This in particular applies to the point where the gas is added or to the location where it flows into the first container or to an inlet valve of the first container.
That means, according to the invention, an at least two-stage carbonation takes place. In a first stage, CO2 is supplied to a mixture of an oxygen-reduced water and a mixing component, wherein this CO2 can in particular serve as a stripping gas for removing oxygen from the mixture. Oxygen that is introduced by the mixing component can, due to its generally lower viscosity compared to the mixing component itself (in particular in the case of syrup), better exit from the mixture than from the mixing component. Such an oxygen reduction is accomplished in a corresponding first container which, for example, can be placed under a vacuum of 0.7 to 0.9 bar absolute, for example. If the first container is placed under a vacuum, the amount of stripping gas (CO2 and optionally one further gas component) added to the beverage mixture can be reduced since the vacuum facilitates a degassing of the oxygen. Moreover, flavour losses are reduced in the degassing of the mixture compared to a degassing of the mixing component alone. Moreover, by the use of oxygen-reduced water in the first container, less oxygen must be removed, thereby further reducing flavour losses.
The CO2 content of the oxygen-reduced beverage mixture mixed with CO2 can be determined by measuring the CO2 content in the first container and/or after the discharge from the first container. For example, the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 can be measured by a volume expansion method, an optical measuring method, or a membrane-based measuring method. By a measurement with the aid of a suited sensor, the CO2 content, which essentially depends on the concrete composition and thus the CO2 solubility of the beverage mixture, can be very precisely determined. The exact determination of the CO2 content in turn permits an exact control of a further CO2 supply for the desired final carbonation of the beverage mixture.
For example, the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 exiting from the first container after the reduction of the oxygen content in the first container is determined and, depending on the determined amount of the CO2 present in this mixture after it has exited from the first container, a final carbonation for the finished beverage is performed. Thus, the CO2 content of the finished beverage to be packaged can be exactly and reliably controlled, whereby the CO2 demand is reduced.
The provision of the oxygen-reduced water can comprise the degassing of the water in a second container placed under a vacuum, whereby in a simple and efficient way, the oxygen content of the finished beverage product can be reduced already before mixing water with the mixing component.
As mentioned, the first container can be placed under a vacuum to accelerate a degassing of oxygen from the beverage mixture mixed with CO2. Both the vacuum of the first container and that of the second container can be generated by means of the same vacuum pump which can facilitate the complete course of the process. In particular, the vacuum pump can be a cleanable or CIP-capable vacuum pump.
According to a further embodiment of the method according to the invention, at least a portion of the discharged, oxygen-reduced beverage mixture mixed with CO2 is returned into the first container, in particular via a circuit line. In this way, further oxygen reduction can be achieved during a repeated stay of the oxygen-reduced beverage mixture mixed with CO2. According to a further embodiment, the measurement of the gas content of CO2 and/or oxygen can be accomplished within the circuit line, in particular in line.
During the return into the first container, further CO2 and/or N2 can be added to the oxygen-reduced beverage mixture mixed with CO2, which can serve as a stripping gas during the further oxygen reduction in the first container.
According to a further embodiment, the addition of the gas comprising CO2 to the beverage mixture to obtain the beverage mixture mixed with CO2, and the addition of the further CO2 to obtain the finally carbonated beverage, are accomplished from the same CO2 source, whereby the complete assembly of the plant used for carrying out the method can be facilitated.
Furthermore, according to a further embodiment of the method according to the invention, the beverage mixture and/or the beverage mixture mixed with CO2 can be heated before the reduction of the oxygen content of the beverage mixture mixed with CO2 in the first container, whereby the oxygen reduction in this container can be facilitated. Thereby, for example, the demand of stripping gas can also be decreased.
Moreover, not only the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 exiting from the first container, but also its oxygen content can be determined. Depending on the residual oxygen content, a vacuum in the first container can be controlled. In this manner, a vacuum in the first container can be increased (that means the pressure in the first container is reduced) if the measurement of the residual oxygen content of the oxygen-reduced beverage mixture mixed with CO2 shows, compared to a predetermined limiting value, an excessively high oxygen content in the oxygen-reduced beverage mixture mixed with CO2 discharged from the first container. Furthermore, depending on the measured value for the residual oxygen content in the oxygen-reduced beverage mixture mixed with CO2 discharged from the first container, the amount of CO2 can be controlled during the addition of the gas comprising CO2 to the beverage mixture to obtain the beverage mixture mixed with CO2. It can thus be further ensured that in the final product, the desired degree of carbonation and the reduced oxygen content are obtained.
The above-mentioned object is also achieved by providing a device for manufacturing carbonated beverages, the device being configured to carry out the method according to any one of the preceding claims, and in particular by providing a filling line for packaging a carbonated beverage, in particular having such a device, the filling line comprising:
a mixing means (for example, a valve-controlled supply line from a reservoir for the mixing component) which is configured to mix oxygen-reduced water and a mixing component to provide a beverage mixture;
a first container for oxygen degassing of the beverage mixture mixed with CO2 to provide an oxygen-reduced beverage mixture mixed with CO2;
a first carbonation means configured to mix the beverage mixture with a gas containing CO2 to provide the beverage mixture mixed with CO2 and which is connected to a supply line connected to the first container;
a discharge line connected to the first container;
a first measuring means configured to measure a CO2 content of the oxygen-reduced beverage mixture mixed with CO2;
a second carbonation means connected to the discharge line; and
an open-loop/closed-loop control means configured to control the operation of the second carbonation means on the basis of the CO2 content measured by the first measuring means.
The first measuring means can be at least partially arranged within the first container, or it can be connected to the discharge line.
A CO2 source can be connected with the first and the second carbonation means.
Furthermore, the mentioned filling line can comprise a second container configured for degassing water to provide the oxygen-reduced water, and a (in particular cleanable) vacuum pump connected to the first and the second container to generate a vacuum in these containers.
Moreover, the filling line can comprise a second measuring means connected to the discharge line and configured to measure an oxygen content of the oxygen-reduced beverage mixture mixed with CO2 in the first discharge line, wherein the open-loop/closed-loop control means can be configured to control, on the basis of the determined oxygen content, the vacuum pump and thus the vacuum of the first container, and/or the first carbonation means and thus the amount of the gas during the addition of the gas comprising CO2 to the beverage mixture to obtain the beverage mixture mixed with CO2.
According to a further embodiment, the filling line furthermore comprises a heating means arranged upstream of the first container in the process flow direction, and which is configured to heat the beverage mixture and/or the beverage mixture mixed with CO2 before the reduction of the oxygen content of the beverage mixture mixed with CO2 in the first container.
While in all of the above-described embodiments, the mentioned first container can be placed under a vacuum, an atmospheric pressure or overpressure can be present in the first container as an alternative in all above-described embodiments depending on the concrete application.
For the addition of gases or gas mixtures to liquids, such as beverage mixtures, in the sense of the invention, any devices known from prior art can be utilised or used, respectively, such as nozzles, e.g. Venturi nozzles.
The present invention also comprises the manufacture of beverages in which nitrous oxide (laughing gas) or a mixture of nitrous oxide and CO2 is to be contained instead of CO2. In this case, instead of CO2, nitrous oxide or a mixture of nitrous oxide and CO2 can be added to the beverage mixture.
Further features and exemplary embodiments as well as advantages of the present invention will be illustrated more in detail hereinafter with reference to the drawings. It will be understood that the embodiments do not exhaust the field of the present invention. It will be furthermore understood that some or all features described below may also be combined with each other in a different way.
The present invention provides a method and a device as well as a filling line for the manufacture of beverages, in particular of low-oxygen, carbonated beverages. Here, an at least two-stage reduction of oxygen, i.e. first a reduction of oxygen in the water used for the beverage, and then a reduction of oxygen of a beverage mixture of the oxygen-reduced water and a selected mixing component, for example syrup, concentrate, flavour etc., is accomplished. Compared to prior art, a desired oxygen content and CO2 content of the finished product provided for packaging can be achieved more reliably, and the amount of the stripping gas used for oxygen reduction can be reduced. One example of a device or filling line 100, respectively, for the manufacture of such beverages is shown in
The filling line 100 shown in
The thus manufactured beverage mixture mixed with CO2 is conducted via a line 104 into the first container 110 where a reduction of the oxygen content is effected by means of the CO2 serving as a stripping gas (second oxygen reduction stage). Upon the reduction of the oxygen in the beverage mixture mixed with CO2 in the first container 110, the beverage mixture exits from the first container 110 via the discharge line 105.
In the discharge line 105, a measuring means 160 is provided for measuring the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 from the first container 110. However, it can be preferred to arrange the measuring means 160 at least partially within the first container for measuring the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 in the first container 110. The measuring result is forwarded to an open-loop/closed-loop control means 170. This open-loop/closed-loop control means 170 can control a metering means 180, for example a control valve, through which CO2 originating from the CO2 source 140 can flow via a line 103′. This CO2 can then be, on the basis of the measuring result delivered from the measuring means 160, added to the oxygen-reduced beverage mixture mixed with CO2 in a second carbonation means 190 (second carbonation stage, final carbonation). The finally carbonated beverage mixture can then be supplied to a buffer tank and/or a filler (not shown in
A further embodiment of a device or filling line 200, respectively, according to the invention is shown in
Both the degassing of the water in the second container 220 and the degassing of oxygen in the beverage mixture mixed with CO2 in the first container 210 are accomplished under a vacuum which is effected by means of one single (in particular cleanable) vacuum pump 292 which is connected to the second container 220 via the line 207, and to the first container 210 via the line 208. The degassing of oxygen in the beverage mixture mixed with CO2 in the first container 210 is effected, for example, under a vacuum of 0.7 to 0.9 bar. The choice of the vacuum in the first container 210 (stripping gas container) can be done depending on the beverage product, in particular the content and the composition of the volatile or taste-forming flavours. If relatively high (low) amounts of volatile flavours are present, a relatively low (high) vacuum is selected. Principally, by applying a vacuum, a higher volume flow rate into the stripping gas container can be achieved as compared to an atmospheric pressure with the same amount of CO2 gas, whereby the degassing efficiency can be increased, the degassing efficiency being higher the higher the vacuum is.
The degassed water exits from the second container 220 via the line 201, and a mixing component (such as syrup, concentrate or flavours) is supplied to the degassed water from a reservoir 230 via the line 202. Furthermore, the filling line 200 comprises a CO2 source 240 for delivering CO2 via the line 203. The CO2 source 240 can be supplemented by an N2 source (not shown in
The thus manufactured beverage mixture mixed with CO2 is conducted via a line 204 into the first container 210 where a reduction of the oxygen content is effected (second oxygen reduction stage). Upon the reduction of the oxygen in the beverage mixture mixed with CO2 in the first container 210, the beverage mixture exits from the first container 210 via the discharge line 205. The discharge line is part of a circuit line 206 via which at least a portion of the oxygen-reduced beverage mixture mixed with CO2 can be returned into the first container 210 for further oxygen reduction.
In the circuit line 206, a measuring means 260 for measuring the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 from the first container 210 is provided. As an alternative, the measuring means 260 can also be arranged in the discharge line 205, for example upstream of the second carbonation means 290. This can be advantageous if too much non-dissolved gas is present in the circuit line 206 which would render measurements more difficult. However, it can be preferred to arrange the measuring means 260 at least partially within the first container for measuring the CO2 content of the oxygen-reduced beverage mixture mixed with CO2 in the first container 210. The measuring result is forwarded to an open-loop/closed-loop control means 270. This open-loop/closed-loop control means 270 can cause a return of at least a portion of the oxygen-reduced beverage mixture mixed with CO2 into the first container 210 or into the supply line 204 for further oxygen reduction on the basis of the measured value delivered by the measuring means 260 for the CO2 content, for example via suited control valves. Furthermore, the open-loop/closed-loop control means 270 can control, depending on the measured CO2 content, the pre-carbonation in the first carbonation means 250 via a control line 208. This open-loop/closed-loop control means 270 can moreover control a metering means 280, for example a control valve, through which CO2 originating from the CO2 source 140 can flow via a line 203′. This CO2 can then be, on the basis of the measuring result delivered from the measuring means 260, added to the oxygen-reduced beverage mixture mixed with CO2 in a second carbonation means 290 (second carbonation stage, final carbonation).
The finally carbonated beverage mixture can then be supplied to a buffer tank and/or a filler (not shown in
Furthermore, a further measuring means 294 for measuring the oxygen content of the oxygen-reduced beverage mixture mixed with CO2 from the first container 210 is incorporated in the circuit line 206. As an alternative, the measuring means 294 can also be arranged in the discharge line 205, for example upstream of the second carbonation means 290. This can be advantageous if too much non-dissolved gas is present in the circuit line 206 which would render measurements more difficult. This further measuring means 294 is also connected to the open-loop/closed-loop control means 270 to supply the latter with measuring results for the oxygen content. On the basis of these measuring results for the oxygen content of the oxygen-reduced beverage mixture mixed with CO2, the open-loop/closed-loop control means 270 can control the operation of the vacuum pump 292 via a control line 207.
In the embodiment shown in
The devices/filling lines 100, 200 shown in
In the embodiment shown in
In the embodiment shown in
Upon the degassing in the stripping gas container, the degassed pre-carbonated beverage mixture is discharged, and its CO2 content is measured 406, and its oxygen content is measured 407. The measurement of the CO2 content of the beverage mixture can be, as an alternative or in addition, effected within the container. The measuring results are forwarded to an open-loop/closed-loop control means. On the basis of the measuring results, the vacuum generated for degassing the water and the pre-carbonated beverage mixture and the amount of the CO2 added during pre-carbonation 404 can be controlled. If the oxygen content measured downstream of the stripping gas container is too high, the pressure can be further reduced. Furthermore, on the basis of the measuring results, at least a portion of the degassed beverage mixture mixed with CO2 can be returned to the stripping gas container for further degassing 408. This can be done while further adding stripping gas, such as further CO2 or N2 or sterile air. Finally, on the basis of the measuring results for the CO2 content, a final carbonation 410 of the product to be filled is effected.
In the above-described methods and by means of the above-described modules of a filling line, the respectively generated amounts of finally carbonated finished beverages and altogether supplied CO2 can be continuously monitored and separately summed up. The altogether supplied amount of CO2 is composed of the residual amount of CO2 in the beverage mixture downstream of the stripping gas container (corresponding to the difference between the amount of CO2 supplied during pre-carbonation and the amount of CO2 discharged in the stripping gas container) and the amount supplied during final carbonation. The amount of CO2 supplied to the final carbonation can be controlled with high precision such that the sum ratio of the total CO2 amount to the amount of the finished beverage corresponds to the desired final content of CO2 in the finally mixed beverage. Here, it can be of advantage to reduce, at certain intervals or when certain sum values are reached, the respective sums (for the amount of CO2 and the finished beverage) corresponding to a desired ratio of the amount of finished beverage to the amount of CO2, whereby the measuring/control precision can be increased since even minor deviations can be recognised in the controlling process relative to the sums of the amounts due to the reduction thereof.
Furthermore, in all embodiments, the mass flow rate of the CO2 serving as a stripping gas for the reduction of the oxygen content can be controlled by open-loop/closed-loop control utilising a pressure differential between the CO2 gas pressure in a CO2 source and the pressure in the stripping gas container by means of an actuator, such as a control valve. For the determination of the amount of the CO2 serving as a stripping gas, one can take into consideration a prior charge of the degassed water which is pre-carbonated in the stripping gas container (for example in the first container 110 shown in
In the exemplary methods shown in
While in all embodiments described with respect to
Number | Date | Country | Kind |
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102020110502.9 | Apr 2020 | DE | national |