Patent Application
20050069700
The present invention relates to a process for the manufacture of high performance polyimide hollow fibres. Specifically, the invention enables simple manufacture of high performance polyimide gas separation membranes using environmentally friendly solvents for the preparation of the dope solutions, bore fluids and coagulation solutions of hollow fibre manufacturing processes.
Polyimides are known to be useful for the manufacture of membrane materials. In particular, fluorinated polyimides containing 2,2′-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) as a monomer component have been identified as promising membrane materials for their high gas permeability and selectivity due to their rigid primary structures with bulky CF3 groups, which tend not only to inhibit efficient packing of polymer chains but also reduce local segmental mobility. For example, 6FDA-2,6-DAT polyimide (poly(2,6-toluene-2,2′-bis(3,4-dicarboxyphenyl) hexafluoropropane diimide), was reported to possess excellent intrinsic gas separation properties with a selectivity of CO2 over CH4 around 45. 6FDA-based polyimides also exhibit many other desirable properties such as spinnability, thermal and chemical stability and mechanical strength. These important properties make the commercial applications of these membranes for gas separation practical.
Asymmetric hollow fibres are one of the most preferred membrane morphologies for gas separation due to their high ratio of membrane surface area to volume. The ideal asymmetric hollow fibre membranes should consist of a defect-free ultra-thin skin layer supported by a porous substructure layer. But it is still a challenge to fabricate hollow fibre membranes with a completely defect-free ultra-thin dense skin layer due to the complexity of the formation mechanism and process of hollow fibre spinning.
In terms of preparing asymmetric hollow fibre membranes, it is important to choose an appropriate spinning system and proper spinning conditions. Usually, the spinning system is a ternary system with one polymer, one solvent and one non-solvent. However, a binary (one polymer and one solvent) system has proved workable for the preparation of hollow fibres. Thus, the addition of a non-solvent into spinning dopes is not a pre-condition to form ultrathin skin layer hollow fibre membranes.
U.S. Pat. No. 5,674,629 (to Institut Francais du Petrole) reports that hollow fibre membranes spun from a polyimide containing 6FDA-2,6-DAT using a 1,4-dioxane/N-methyl-pyrollidone(NMP) dope solvent have impressive properties. Pure gas tests conducted at 118 psi show a permeance of 162 GPU (1 GPU=1×10−6 cm3 (STP)/cm2·s·cmHg) for CO2 and a selectivity of 74 for CO2/CH4, whereas mixed gas tests at 368 psi exhibit a permeance of 155 GPU for CO2 and a selectivity of 59 for CO2/CH4. However, the spinning system and conditions reported in this patent are unsuitable for scale-up. This is due to the following facts: (1) 6FDA-2,6DAT polyimide does not dissolve well in the solvent mixture 1,4-dioxane and NMP. Thus, it is not easy to prepare a fully dissolved solution. (2) The bore fluid is made up of a mixture of acetic acid, water and 1,4-dioxane. (3) The external coagulant comprises a 52 wt % acetic acid aqueous solution, which has to be maintained during the experiment. Acetic acid is a corrosive solvent, while 1,4-dioxane is a toxic solvent. Both are not desirable for fibre spinning on a large scale because of these properties.
It is an object of the present invention to develop a process for the manufacture of polyimide hollow fibres which avoids the use of inconvenient and environmentally unfriendly solvents but which maintains good levels of performance in the resultant fibres.
Accordingly, the present invention provides a process for the manufacture of a polyimide hollow fibre comprising the steps of:
It will be appreciated that steps (i) and (ii) need not be performed in any particular order and may indeed be performed simultaneously.
In the context of the present specification the term “tube” is not limited to tubes of circular cross-section but is intended to include tubes with any cross-sectional shape including, for example, square, rectangular or hexagonal cross-section. However, a circular cross-section is preferred.
In a preferred embodiment of the present invention, the solvent in step (i) comprises 60-95 wt % N-methylpyrollidone and 5-40 wt % ethanol. More preferably, the solvent in step (i) comprises 60-90 wt % N-methylpyrollidone and 10-40 wt % ethanol. Even more preferably, the solvent in step (i) comprises 70-90 wt % N-methylpyrollidone and 10-30 wt % ethanol.
In a preferred embodiment of the present invention, the bore fluid comprises 85-100 wt % N-methylpyrollidone and 0-15 wt % water. More preferably, the bore fluid comprises 90-100 wt % N-methylpyrollidone and 0-10 wt % water. Even more preferably, the bore fluid comprises 90-99 wt % N-methylpyrollidone and 1-10 wt % water. Most preferably, the bore fluid comprises 93-96 wt % N-methylpyrollidone and 4-7 wt % water.
In a preferred embodiment of the present invention, the coagulation solvent is water.
In a preferred embodiment of the present invention, the tube of the dope solution filled with the bore fluid is generated by a spinneret. Such a method of spinning hollow fibres is well known in the art and is reported in detail in “Formation of ultrathin high-performance polyethersulfone hollow fibre membranes” Chung et. al., J.Membr.Sci. 133, (1997), 161. The method is summarised herein with reference to
In a preferred embodiment, the temperature of the spinneret is controlled such that it remains in the range of from 25° C. to 80° C., more preferably from 60° C. to 75° C.
The process of the present invention is particularly suitable for the synthesis of polyimide hollow fibres wherein the one or more polyimides is/are selected from polyimides having the structure shown in Formula I below:
wherein n is sufficient to provide a viable polymer for a hollow fibre membrane, wherein each of the n Ar1 groups is a quadrivalent organic group independently selected from the group consisting of:
wherein each of the n Ar2 groups is a divalent organic group independently selected from the group consisting of:
wherein Z is a divalent organic group selected from the group consisting of:
and X, X1, X2 and X3 are each independently selected from the group consisting of: hydrogen, C1-5alkyl, C1-5alkoxy, phenyl or phenoxy groups.
Most preferably the process may be applied to the synthesis of a polyimide hollow fibre wherein the polyimide is of the general formula:
wherein n is sufficient to provide a viable polymer for a hollow fibre membrane.
In a preferred embodiment of the present invention, n is a number sufficient to provide a polymer with an inherent viscosity of at least 0.3 dL/g as measured at 25° C. on a 0.5% by weight solution in N-methylpyrrolidone.
In a preferred embodiment of the present invention the one or more polyimides is/are present in the dope solution provided by step (i) in an amount of from 15-40 wt %, more preferably in an amount of from 20-30 wt %.
In a preferred embodiment of the present invention, after generation in step (iii) but before being brought into contact with a coagulation solvent in step (iv), the tube of dope solution filled with bore fluid passes through an air gap. Preferably the air gap is less than or equal to about 40 mm, more preferably in the range of from 6 to 10 mm.
Following synthesis of the hollow fibre it may be subjected to various other treatment steps. Thus, after step (iv) the hollow fibre may be washed with water and/or methanol and/or hexane and then dried in air and/or a vacuum oven. In a particularly preferred embodiment the post-treatment comprises storing the fibres in water, performing solvent exchange with methanol then hexane, drying in air then relocating to a vacuum oven for further drying. The most preferred post-treatment involves storing in water for three days followed by:
In another embodiment, the present invention also provides a polyimide hollow fibre whenever produced by a process as hereinbefore described. The hollow fibre preferably has an outer diameter of from 50 μm to 5000 μm, more preferably from 100 μm to 1000 μm, and an inner diameter of from 25 μm to 4900 μm, more preferably from 25 μm to 900 μm
The present invention will now be further described by way of the following examples.
A stoichiometric amount of 2,2′-bis(3,4-carboxylphenyl) hexafluoropropane dianhydride (6FDA) was added to a solution of 2,6-diamino toluene (2,6-DAT) in N-methylpyrollidone (NMP) with stirring under argon at ambient temperature. 24 h later, a mixture of acetic anhydride and triethylamine (the molar ratio of acetic anhydride/triethylamine to 6FDA was 4:1) was slowly added to the solution to complete imidization for 24 h. The resultant polymer was slowly precipitated in methanol. After being filtered and washed with fresh methanol, the resultant polymer was dried at 150° C. under vacuum for 24 h. Its inherent viscosity was measured in NMP.
Dopes made from 28 wt % 6FDA-2,6-DAT (intrinsic viscosity (IV) in NMP of 0.66 dl/g) in NMP were employed as the spinning solutions. The bore fluid composition used was a 95:5 (by weight) mixture of NMP and water with a flow rate of 0.18 ml/min, while the fibre take-up speed was around 375 cm/min. Tap water at room temperature was used as the coagulant. The details of the dry-jet wet spinning conditions are listed in Table 1.
The procedure of post treatment of the fibre is described as follows:
After drying, the fibres were cut into lengths of 10-15 cm, and small test samples were made with 8-10 fibres. The fibre samples were mounted in a stainless steel module and coated with silicone rubber. The testing pressure was controlled from 20-200 psi and the gas testing sequence is in the order of O2, N2, CH4 and CO2. The gas permeation rate was determined by a digital bubble flow meter.
*calculation based on gas permeation properties of dense film: O2/N2 selectivity of 5.0 and permeability of 11.3 barrer at 35° C. and 2 atm
Table 2 summarises the pure-gas and mixed-gas performances of 6FDA-2,6DAT asymmetric composite hollow fibre membranes at various conditions. The initial permeance of CO2 is 300 GPU (1 GPU=1×10−6 cm3 (STP)/cm2·s·cmHg) and the selectivity for CO2/CH4 is 65 at 200 psi, which is comparable with the reported data in U.S. Pat. No. 5,674,629 (CO2 permeance of 162 GPU and CO2/CH4 selectivity of 74). This clearly demonstrates that these dope spinning system and process conditions can produce 6FDA-2,6DAT asymmetric composite hollow fibres membranes with similar performance to those reported in U.S. Pat. No. 5,674,629.
After the hollow fibers experienced 185-day physical ageing and reached the equilibrium state, the mixed gas permeation tests were conducted. The CO2 and CH4 permeances are 59 GPU and 1.46 GPU, respectively, which correspond to CO2/CH4 selectivity of about 40. Even though the selectivity in the mixed gas system drops, the overall performance is still very impressive for the application of CO2/CH4 separation. In addition, since the reported CO2/CH4 selectivity from the dense 6FDA-2,6-DAT membrane was about 45-46 at 35° C., it strongly suggests that the CO2/CH4 selectivity value obtained from the current mixed gas tests is more consistent (and reliable) with the literature values than that reported in U.S. Pat. No. 5,674,629.
150 g 6FDA-2,6 DAT polyimide (IV=0.61 dl/g) was dried in a 120° C. vacuum oven for 48 hr. After natural cooling to room temperature, the above polyimide was put into a one-litre round-bottom flask. 367.2 g of N-methyl-2-pyrrolidone (from Merck Schuchardt, Purity/99%, used as received) was poured into the flask. The above mixture (29% polyimide in NMP) was stirred using a mechanical stirring system (50 rpm) under a nitrogen atmosphere (200 ml/min) for 72 hr to form the spinning dope. The viscosity of the spinning dope was 130 Pa·s under the share rate of 10 m.s−1. The spinning dope was poured into a 1-litre stainless steel spinning tank. Degassing was carried out under vacuum for 24 hr (the vacuum was applied for 1 hr, then the vacuum valve was turned off and the tank was kept under vacuum status for 24 hr). 10 atm nitrogen was fed into the tank as the back-pressure. A 0.066 ml/rev gear pump was employed to drive the spinning dope to a spinneret. A 15 μm online filter was used to avoid spinneret blocking caused by particles. A spinneret with OD/ID=0.8 mm/0.5 mm was used for spinning (the length of dope path at the orifice was 1.8 mm). 95% NMP in water was employed as the bore fluid, which was delivered by a syringe pump. The air gap distance between the spinneret and coagulant was 5 mm. The spinneret temperature was set at 70° C. The dope delivery rate was 0.33 ml/min while bore fluid delivery rate was 0.1 ml/min, the fibre take-up velocity was 2.18 m/min. A defect-free hollow fibre with OD/ID=355/173 μm was formed. The spinning condition was summarized in Table 3.
The as-spun hollow fibres were kept in water for 3 days. Then the fibres were moved to solvent exchange. The procedure of solvent exchange is described below:
1054 pieces of fibre were assembled into a stainless steel shell of ID=18 mm to form a module with a 0.6 m effective separation length. The module specifications are listed in Table 4.
The module was tested by mixing gas of 40% carbon dioxide in methane. The mixed gas testing results are listed in Table 5.
1 GPU = 1 × 10−6 cm3(STP)/cm2 · s · cmHg
The spinning dope was prepared by dissolving 6FDA-2,6-DAT polyimide (IV of 0.61 dl/g in NMP), in a mixed solvent comprising NMP and ethanol (EtOH) as a non-solvent.
The spinning conditions were as listed in Table 6.
The as-spun fibres have OD of 360 μm and ID of 190 μm. The results of pure gas test for O2, N2, CO2 and CH4 of these hollow fibre membranes at 100 psi are shown in Table 7. The hollow fibre membranes prepared are defect free and have selectivities close to that of dense 6FDA-2,6-DAT polyimide membranes.
1 GPU = 1 × 10−6 cm3(STP)/cm2-s-cmHg
| Number | Date | Country | Kind |
|---|---|---|---|
| 0126881.2 | Nov 2001 | GB | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/GB02/05065 | 11/8/2002 | WO |
