The present invention relates to a thin film transistor liquid crystal display (TFT LCD) array substrate and a manufacturing method thereof, and more particularly, to a TFT LCD array substrate manufactured with two masks and a manufacturing method thereof.
In a liquid crystal display (LCD), the optical anisotropy and polarization characteristic of the liquid crystal molecule can be varied through controlling the orientation of the liquid crystal molecule, which in turn varies with the external electric field applied thereto, thus the refraction of light and display of images can be realized. Among various LCDs, the active matrix LCD has attracted much research and development and been widely used in consumer electronics and computers due to their high resolution and superiority in animation display. The active matrix LCD comprises thin film transistors (TFTs) and pixel electrodes arranged in matrix.
The LCD typically comprises an upper substrate, a lower substrate, and liquid crystal layer interposed therebetween. The upper substrate is called a color filter substrate, typically including a common electrode and a color filter. The lower substrate is called an array substrate, typically including TFTs and pixel electrodes. The color filter can be formed on the color filter substrate with several photolithography processes, and the TFTs and pixel electrodes arranged in matrix can be formed on the array substrate in 4-6 photolithography processes, each of which is carried out with repeated thin film deposition, exposure, etching, lifting off and the like. One mask is used in each circle of photolithography process
During manufacturing of TFT LCD, there always exists a need of reducing mask number and accordingly photolithography process number to reduce manufacture cost and improve equipment productivity. The manufacturing technology for TFT LCD array substrate has undergone the map from the seven mask (7 Mask) technology to the current five mask (5 Mask) and four mask (4 Mask) technology used in mass production, and also three mask (3 Mask) technology has been developed.
As mask number decreases, the structure of TFT is evolving continuously. The structure has evolved from co-planar type to normal staggered type, and further to back channel stop type and the back channel etching type, and has also evolved from top gate structure to current bottom gate structure. Removal of some device elements during the evolution of TFT directly results in decrease of the photolithography process number and mask number. For example, the bottom gate type TFT needs no light shielding layer that is used in the top gate type TFT, thus reducing one mask. Also back channel etching type TFT, as compared with the back channel stop type TFT, needs no the etch blocking layer, thus reducing another mask.
After improvement on TFT structure, methods for reducing mask number in the industry shift to the photolithography process itself, i.e., defining different patterns of two layers of thin films with one mask. As well known, the necessary elements of a LCD pixel unit comprise a gate electrode, a gate insulating film, an active film, an ohmic contact film and a source/drain electrode, a transparent pixel electrode, and a TFT passivation protection film. In the 5 Mask process in mass production, the gate electrode, the gate insulating film and the active film as well as the ohmic contact film, the source/drain electrode, the passivation protection film, and the pixel electrode are separately formed in five photolithography processes with respective mask. However, for the 4 Mask process, the gate insulating film, the active film, the ohmic contact film, and the source/drain electrode are formed with one mask in combination. This mask differs from any mask in the 5 Mask process and is a so-called gray tone mask with narrow slits and bars. This mask forms stepwise photoresist with different thicknesses in different regions.
For the conventional mask, transparent and opaque portions are formed thereon and patterned the same as desired device pattern. The opaque portions are generally made of a metal film (e.g., Cr), while the transparent portions are void of any metal film. On the contrary, the gray tone mask additionally has partially transparent regions, e.g., slits with given width and spacing and arranged in order in given regions of the mask. The diffraction among the incident light changes transmitting ratio, so the photoresist corresponding to the partially transparent regions of the mask is subject to exposure different from that corresponding to the transparent regions, and the so-called photoresist partially exposed (gray tone) region is formed. Compared with the photoresist completely unexposed (full tone) region, the photoresist in the gray tone region is subject to partial exposure and is thinner than that in the full tone region.
The 4 Mask technology using a gray tone mask will be explained below with reference to the drawings.
a and 1b are diagrams illustrating an array substrate 100′ of typical back channel etching bottom-gate type TFT. The array substrate comprises a plurality of gate lines 1 and gate electrodes 2; a plurality of data lines 5 and source and drain electrodes 6 and 7; and pixel electrodes 10. A part of the gate electrode (gate protrusion part 11 overlapping with the pixel) and the pixel electrode 10 together constitute a storage capacitor. The TFT is manufactured with a 4 Mask process.
A gate metal film is formed on a transparent substrate, and a gate pattern, which includes the gate line 1 and gate electrode 2 as well as the gate protrusion part 11 for constituting the storage capacitor, is formed with the first mask by photolithography and etching process, as shown in
A gate insulating film 3, a semiconductor film 4 (e.g. an intrinsic semiconductor film), an ohmic contact film (not shown and e.g., a doped semiconductor film) and a source/drain metal film 15 are formed in order. Stepwise photoresist pattern as shown in
On the array substrate a second insulating dielectric film, i.e., the passivation protection film 8 is formed, and a third mask is used to define the protection film, as shown in
A transparent conductive film is formed on the passivation protection film 8, and a pixel electrode 10 is formed with a fourth mask, thereby achieving the TFT device as shown in
Based on the 4 Mask technology, a 3Mask technology has been developed, in which the protection film and the transparent conductive film in the above process are completed in combination with a single mask. This modification is illustrated in
Compared with the conventional 4 Mask technology, the 3 Mask technology simplifies the manufacturing processes and improves the utilization ratio of the equipment, but it still suffers from the drawbacks such as complicated manufacturing process, low productivity, and low utilization ratio of the equipment.
An aspect of the present invention is a TFT LCD array substrate manufactured with two masks and the manufacturing method of the same, which overcome the drawbacks in the conventional technology. The aim of providing 2 Mask manufacture process is to avoid the drawbacks and limitations associated with the 5 Mask or 4 Mask methods described above. More specifically, the present invention simplifies the manufacture process of the TFT LCD array substrate, removes the drawbacks in the process, and improves the yield, and furthermore reduces the number of the used masks to improve the equipment utilization ratio and productivity.
The present invention provides a method for manufacturing a TFT LCD array substrate by utilizing the gray tone mask technology and the photoresist lifting-off technology with only two masks in two photolithography processes, and a TFT LCD array substrate manufactured by the same. In the resultant array substrate, the gate line and the data line are perpendicular to and intersect with each other to define the pixel area, and one of the gate line and the data line is continuous and the other is discontinuous. The array substrate is covered with a passivation protection film. The segments of the disconnected gate line or the data line are connected together through the via hole formed in the passivation protection film and the connecting conductive film formed on the passivation protection film. The data lines and the source and drain electrodes of the TFT are made of the same source/drain metal film, and the connecting conductive film and the pixel electrode are made of the same conductive film in the same photolithography process.
With the gray tone mask and the photoresist lifting-off technology, the TFT LCD array substrate can be manufactured by using only two masks in two photolithography processes, so that the manufacture process can be simplified and the production cost can be reduced. In the TFT LCD array substrate, the connection of the segments of the discontinuous gate lines or data lines, the connection of the source electrodes and the data lines, and the connection of the gate lines, the data lines, and the external circuit, are all achieved by a transparent conductive film with the second gray tone mask in manufacturing.
The present invention will be described in detail by reference to the accompanying drawings and the particular embodiments.
a is a top view of a typical TFT LCD pixel manufactured by the 4 Mask process in the conventional technology, and
b is a cross-sectional view along the line 1b-1b in
a is a top view showing a pixel after the first mask process in the conventional technology, and
b is a cross-sectional view along the line 2b-2b in
a is a top view of a pixel after the second mask process in the conventional technology,
b is a cross-sectional view along the line 3b-3b of the pixel after a photoresist pattern is formed on the source/drain electrode,
c is a cross-sectional view along the line 3b-3b of the pixel after the source/drain electrode are etched,
d is a cross-sectional view along the line 3b-3b of the pixel after the photoresist in the photoresist partially retained region is removed, and
e is a cross-sectional view along the line 3b-3b of the pixel after the etching of the doped semiconductor is completed and the photoresist is lift off.
a is a top view showing the pixel after the third mask process in the conventional technology, and
b is a cross-sectional view along the line 4b-4b in
a is a top view of a pixel after a photoresist pattern is formed on the passivation film in the conventional technology;
b is a cross-sectional view along the line 5b-5b of the pixel after a photoresist pattern is formed on the passivation film;
c is a cross-sectional view along the line 5b-5b of the pixel after the passivation film is etched for via holes;
d is a cross-sectional view along the line 5b-5b of the pixel after the photoresist in the photoresist partially retained region is removed;
e is a cross-sectional view along the line 5b-5b of the pixel after the conductive film is deposited; and
f is a cross-sectional view along the line 5b-5b of the pixel after the photosensitive material is lift off.
a is a cross-sectional view along the line 7a-7a in
b is a cross-sectional view along the line 7b-7b in
c is a cross-sectional view along the line 7c-7c in
a is a cross-sectional view along the line 10a-10a in
b is a cross-sectional view along the line 10b-10b in
c is a cross-sectional view along the line 10c-10c in
a is a cross-sectional view along the line 12a-12a in
b is a cross-sectional view along the line 12b-12b in
c is a cross-sectional view along the line 12c-12c in
a is a cross-sectional view along the line 14a-14a in
b is a cross-sectional view along the line 14b-14b in
c is a cross-sectional view along the line 14c-14c in
a is a cross-sectional view along the line 16a-16a in
b is a cross-sectional view along the line 16b-16b in
a is a cross-sectional view along the line 18a-18a in
b is a cross-sectional view along the line 18b-18b in
a is a cross-sectional view along the line 20a-20a in
b is a cross-sectional view along the line 20b-20b in
a is a cross-sectional view along the line 22a-22a in
b is a cross-sectional view along the line 22b-22b in
a is a cross-sectional view along the line 23a-23 in
b is a cross-sectional view along the line 23b-23b in
a is a cross-sectional view along the line 25a-25a in
b is a cross-sectional view along the line 25b-25b in
The TFT LCD array substrate and the preferred embodiments thereof according to the present invention will be described in detail with reference to the drawings.
As shown, the array substrate according to the first embodiment comprises a transparent insulating substrate 100 on which are formed a gate line 101 and a data line 105, which are perpendicular to and intersect with each other to define a pixel area. The TFT for each pixel is formed at intersection of the gate line 101 and the data line 105 and completely over the gate line 101. The TFT includes a gate electrode, a gate insulating film 103, an intrinsic semiconductor film 133, a doped semiconductor film 134, a source electrode 106 and a drain electrode 107 (which are parts of the source/drain metal film 115, as shown in
Each gate line 101 is continuous on the substrate 100, while the data line 105 is interrupted by the gate line 101 to be discontinuous but is connected through the via holes 125 over the data line by the conductive film 128 connecting the data line. The source electrode 106 is formed over the intersection of the gate line 101 with the extension line of the data lie 105, and is not directly connected with the data line 105 but through the via hole 126 over the source electrode and the conductive film 128. As shown, the conductive film 128 simultaneously connects the discontinuous data line 105 and the source electrode 106 over the gate line 101.
a-7c are cross-sectional views along the lines 7a-7a, 7b-7b, and 7c-7c in
As shown in the
The source/drain metal film 115 shown in
A TFT device shown in
As shown, the gate insulating film 103 prevents contact between the gate metal film 131 and the source/drain metal film 115, and the passivation protection film 108 prevents contact between the conductive film 137 and the gate metal film 131 and makes the source/drain metal film 115 contact with the transparent conductive film 137 in the predetermined regions.
The manufacture process for the array substrate of the above structure will be illustrated with reference to
In the first step shown in
The photoresist pattern shown in
The thickness of the photoresist in the photoresist partially retained region is less than that in the photoresist completely retained region. For this first gray tone mask, the opaque portion includes two layers of thin film material, which may be chrome and chromium oxide, the partially transparent portion includes one layer of thin film material, which may be chromium oxide only, and the fully transparent portion is free of the above thin film material. In addition, the partially transparent portion of the gray tone mask may includes slits and bars with given spacing and in the predetermined direction.
Similar to the process in
During the above etching process, different etching methods, etching solutions, and etching gases can be used to ensure the control over the selection ratio among different materials, the profile, and the critical dimension (CD). During the formation of the data line 105, the source electrode 106, and the drain electrode 107, for example, the gate insulating film 103, the intrinsic semiconductor film 133, and the doped semiconductor film 134 can be etched by similar methods, i.e., plasma etching or reactive ion etching (RIE), and the etching of the three layers of films can be performed in the same equipment by adjusting the etching gas and the etching conditions. The etching of the above different films can be performed in the same equipment with different combination of the etching gases of SF6, Cl2, O2, He, etc. and different selected gas flux. For example, the combination of SF6, Cl2, and He can be used to etch the semiconductor film; the combination of SF6, O2, and He can be used to etch the insulating film; and the combination of Cl2 and O2 can be used to etch the metal film. For the optimization of device structure and high process efficiency, the etching parameters for the different films, e.g., plasma power, pressure, and distance between the electrodes, are different from each other. The etching of semiconductor film is usually performed in a plasma chamber with relatively low pressure and high power, which produces more intensive ion bombardment and sputtering etching; the etching of insulating thin film and metal thin film is usually performed in a plasma chamber with relatively high pressure and low power, which produces more intensive chemical reactive ion etching (RIE). For example, the semiconductor film can be removed efficiently by feeding into the equipment SF6 in tens of standard cubic centimeters per minute (seem) and Cl2 in thousands of seem with the power of thousands of watts and the pressure in tens of mTorr (microns of Hg); the insulating film can be removed efficiently by feeding into the equipment SF6 in hundreds of seem and O2 in hundreds of sccm with the power of thousands of watts and the pressure in hundreds of mTorr. During the formation of the data line 105, the source electrode 106 and the source/drain electrode 107, the source/drain metal film can be removed by the etching with chemical etching solution and also can be removed by the plasma etching or RIE, depending on the material of the source/drain metal film. For example, the metal film can be removed efficiently by feeding into the dry etching equipment with Cl2 in hundreds to thousands of seem and O2 in thousands of sccm and with the power of thousands of watts and the pressure in hundreds of mTorr. During the formation of the gate line 101, the gate line protrusion part 111, the insulating dielectric of the storage capacitor 138, and the TFT channel 112, by the plasma etching or RIE with the above conditions, the source/drain metal film 115 and the doped semiconductor film 134 can be successively etched and removed in the same equipment. The wet etching is only used to remove the metal thin film, in which a mixed solution of nitric acid, hydrochloric acid, and acetic acid in given ratio of concentration is commonly used, and is performed by immersing or spraying at the temperature of tens of Celsius degrees.
In the second step of
Similar to the process of
First, with the method similar to that for etching the gate insulating film 103, the via holes 125 on both ends of the data line, the via hole 126 over the source electrode, and the via hole 127 over the drain electrode, as shown in
With a method similar to that for forming the gate metal film 131 and the source/drain metal film 115, a layer of transparent conductive film 137 is formed on the entire substrate. The vacuum condition of the sputtering chamber and the electrodes and their accessories are controlled so that no transparent conductive film is deposited on the sidewall of the photoresist in the photoresist completely retained region 118. Then the array substrate is dipped into a chemical solution for photoresist lifting off. With a lifting off process, the photoresist and the transparent conductive film thereon (in the photoresist completely retained region) which has partially retained in thickness after photoresist ashing are removed, while the conductive film in the via holes in the original photoresist-free region and the photoresist partially retained region is retained to form the pixel electrode 110 connected with the drain electrode 107 and the conductive film connecting the data line 105 and the source electrode 106, i.e., the conductive film 128 connecting the data lines. Since no transparent conductive film is deposited on the sidewall of the photoresist in the photoresist completely retained region 118, the ordinary photoresist lifting-off solution, such as the acetone, isopropanol, alcohol, or the mixed solution thereof, can directly etch the photoresist on the sidewall of the photoresist in the photoresist completely retained region 118, and no special lifting-off solution is required to etch other materials like the transparent conductive film. To completely lift off the photoresist as well as the conductive film thereon, excluding that in the pixel portion and the via holes in the passivation film, the lifting-off process is performed together with spraying, vibrating, or supersonic wave. Then the TFT LCD array substrate is completed with a 2Mask process.
A TFT LCD array substrate 200 according to the second embodiment of present invention is shown in
The array substrate 200 in the second embodiment comprises a gate line 201 and a data line 205, which are perpendicular to and intersect with each other to define a pixel area. The TFT for each pixel is formed over the gate line 201 in the vicinity of the data line 205. The TFT includes a gate electrode 202, a source electrode 206, a drain electrode 207, a gate insulating film 226, an intrinsic semiconductor film 227 and a doped semiconductor film 228. A storage capacitor is formed between the gate line protrusion part 211 and the pixel electrode 210. The pixel electrode 210 is connected with the drain electrode 207 through the via hole 221 over the drain electrode. Each data line 205 is continuous on the substrate. Each gate line 201 is discontinuous and interrupted by the data line 205 and is connected through the via hole 217 over the both ends of the gate line by the conductive film 218 connecting the gate line. The source electrode 206 is formed over the gate electrode and is connected with the data line 205 through the via hole 220 over the source electrode, the conductive film 222 connecting the data line and the source electrode, and the via hole 219 over the data line.
a and 16b are cross-sectional views along the line 16a-16a and 16b-16b in
As shown, the gate metal film 225 is formed on the transparent substrate, and is made of material with low resistivity and high reflectivity. The gate insulating film 226 and the intrinsic semiconductor film 227 cover all the gate metal film 225, except the lead pads in peripheral region of the array substrate. The ohmic contact film 229 is made of the doped semiconductor film 228, and the doped semiconductor film 228 only retains in the region contacted with the source/drain metal film 236.
The gate line 201 is a part of the discontinuous gate metal film 225 and is covered with the gate insulating film 226, the intrinsic semiconductor film 227, and the passivation protection film 208. The via holes 217 at both ends of the gate line penetrate the passivation protection film 208, the intrinsic semiconductor film 227, and the gate insulating film 226 to expose the gate line 201. The gate line 201 is interrupted by the data line 205 formed by the source/drain metal film 236 and the layers of thin film underlying the data line. The gate metal film 225, the gate insulating film 226, the intrinsic semiconductor film 227, and the doped semiconductor film 228 are also retained under the data line 205. The passivation protection film 208 covers the data line, over which the via hole 219 is in the vicinity of the TFT. Excluding the data line 205 and the gate line 201 as well as the TFT device, no metal thin film exists under the passivation protection film 208. The entire array substrate 200 is covered by a layer of insulating dielectric film, i.e., the passivation protection film 208, and is only opened at the portions for leading out the connecting wire. The conductive film for the connecting wire and the transparent conductive film constituting the pixel electrode may bc of the same material and formed with the same mask.
From the figures, the TFT thus manufactured differs from that by the conventional 4Mask process in that, the source electrode and the data line are not connected with each other directly, i.e., the source/drain metal film is disconnected between the source electrode and the data line. The connection of the source/drain metal film is achieved by the transparent conductive film through the via holes. Furthermore, the gate line is discontinuous and is interrupted by the data line. The discontinuous gate line is connected by the transparent conductive film at the via holes. These two differences and the sequential deposition of three layers of thin films described below allow for formation of the array substrate with two masks.
The manufacture process for the array substrate with the above structure will be illustrated by reference to
As shown in
As shown in
As shown in the
As shown in
The etching of the passivation protection film 208, the intrinsic semiconductor film 227, and the gate insulating film 226 are performed successively, to form in the photoresist-free region the via hole 219 over the data line, the via hole 220 over the source electrode, the via hole 221 over the drain electrode, and the via holes 217 over both ends of the gate line, respectively, as shown in
With a method similar to that of forming the gate metal film and the source/drain metal film, a layer of transparent conductive film 224 is formed on the entire substrate, as shown in
The TFT structure described in the above examples are not the unique structure of the present invention, and changes such as that in the shape of the source/drain electrode and in the storage capacitor can be realized with the 2 Mask process described above. Other modifications and changes in device structure and manufacture step are also possible, and these modifications and changes do not depart from the spirit and scope of the present invention. Therefore, the present invention comprises all the modifications and changes in accordance with the claims.
It should be appreciated that the embodiments described above illustrate but do not limit the present invention. Although the present invention has been described herein with reference to the preferred embodiments, it is to be understood by those skilled in the art that the present invention can be realized with different material and equipment as necessary, and that various other modification and equivalents can be made herein without departing from the spirit and scope of the present invention.
Number | Date | Country | Kind |
---|---|---|---|
2006 1 0082971 | Jun 2006 | CN | national |
2006 1 0082972 | Jun 2006 | CN | national |
Number | Name | Date | Kind |
---|---|---|---|
20060141685 | Kim et al. | Jun 2006 | A1 |
20070246707 | Deng | Oct 2007 | A1 |
20070272926 | Deng | Nov 2007 | A1 |
20080030639 | Qiu | Feb 2008 | A1 |
20080061295 | Wang | Mar 2008 | A1 |
20080100766 | Ming | May 2008 | A1 |
20080105873 | Wang | May 2008 | A1 |
20080105874 | Wang | May 2008 | A1 |
20080111136 | Qiu | May 2008 | A1 |
20080111934 | Wu | May 2008 | A1 |
20080117347 | Zhang | May 2008 | A1 |
20080123007 | Cui | May 2008 | A1 |
20080123030 | Song | May 2008 | A1 |
20080142802 | Qiu | Jun 2008 | A1 |
20080142819 | Liu | Jun 2008 | A1 |
Number | Date | Country |
---|---|---|
03-249735 | Nov 1991 | JP |
04-348144 | Dec 2004 | JP |
2006-68442 | Jun 2006 | KR |
Number | Date | Country | |
---|---|---|---|
20070298554 A1 | Dec 2007 | US |