The present disclosure relates to a method for manufacturing a semiconductor electronic device with trench gate.
Vertical-conduction power MOSFETs are known to have a trench-gate region, extending in depth in a semiconductor body and including a conductive region, of doped polysilicon, surrounded and electrically insulated from the semiconductor body by a dielectric region (made, for example, of silicon oxide —SiO2).
A process, which is not necessarily prior art, is disclosed with reference to
On the substrate 1, a structural layer or region 2 is formed, for example by epitaxial growth of silicon, having the first conductivity (N) and a respective concentration of dopants. The substrate 1 and the structural region 2 form, together, a semiconductor body having a thickness, along Z, approximately between 700 μm and 800 μm.
The semiconductor body has a first side 2a opposite to a second side 1b, in the Z direction.
On the first side 2a of the structural layer 2, a multilayer 4 is formed, which includes a first layer 4a, in contact with the first side 2a, for example, of silicon oxide grown via thermal oxidation with a thickness between 5 nm and 100 nm; a second layer 4b immediately on top of the first layer 4a, for example of silicon nitride with a thickness between 10 nm and 20 nm; and a third layer 4c, immediately on top of the second layer 4b, for example of TEOS with a thickness between 300 nm and 500 nm. The first layer 4a has the function of forming an adhesion interface between the structural layer 2, of silicon, and the second layer 4b, of silicon nitride, in order to prevent mechanical stress induced by silicon nitride and prevent nitriding of the surface of the silicon itself, which jeopardizes operation of the device. The second layer 4b forms a hard mask for a subsequent step of etching of the structural layer 2 to form the trenches for the gate region; prevents oxidation where not desired as well the erosion of the silicon itself during a subsequent Chemical Mechanical Polishing process. The third layer 4c forms a hard mask for the step of etching of the structural layer 2.
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Next, a layer of doped polysilicon 22, having the first conductivity type (N) is deposited within the trench 6 and on the gate dielectric layer 20; the polysilicon is deposited also on the wafer surface, in particular on the second layer 4b of SiN. A subsequent Chemical-Mechanical-Polishing (CMP) step, not shown, is carried out for removal of the layer of doped polysilicon 20 from the front of the wafer, laterally to the trench 6. The second layer 4b is used as stop layer for the CMP step.
Processing of the wafer may then continue (not shown) in a known way, to form further electrical structures, including body, source and drain regions, as well as metallization regions for biasing the gate, body, source and drain regions.
In the process described above, the growth of the gate dielectric layer should be carried out on a clean silicon surface of the trench and without any obstacle due to the presence of the second layer 4b of SiN; however, the moment, in the process flow, at which the second layer 4b is removed is crucial and depends by many factors: the second layer 4b cannot be removed before the polysilicon CMP step, because it acts as stopping layer for the CMP and therefore it protects the gate dielectric layer; the removal of the second layer 4b, as well as the final shape of the second layer, are also a consequence of the steps of removing the sacrificial oxide layer and the third layer 4c, as discussed above (in the described process, the lateral erosion of the second layer 4b after a partial or total sacrificial oxide removal, is performed through an isotropic etch, which acts faster from the bottom side, generating a profile of the second layer that is detrimental for the later gate dielectric growth).
The lateral recession of the layer 4b is an isotropic wet etching process, with acts in all the direction of the space, including the bottom surface, resulting in a negative tapered profile, as shown in the drawings. In addition, the oxides of the layers 14 and 4c, partially removed before removal of layer 4b, have a different density and composition: the sacrificial oxide of layer 14 is a thermally grown SiO2, while the oxide of the layer 4c is a Tetraethyl Orthosilicate (TEOS), deposited by Chemical Vapor Deposition (CVD) and then densified. The isotropic wet etch of the silicon nitride of layer 4b has an initial deoxidation step based on HF chemistry, which acts differently on thermal oxide and on the CVD densified oxide. The wet etch rate on the sacrificial oxide layer 14 has been demonstrated slightly higher respect to the one on densified TEOS, so that the bottom surface of the layer 4b is uncovered even faster respect to the top surface of the same layer 4b. Hence, the consequence is that the wet etch step of the layer 4b is more aggressive on the uncovered bottom side of the layer 4b and the etch proceed faster at the bottom side of the layer 4b than at the top side of the layer 4b, so that the final profile is negatively tapered, as shown, which is undesired.
Consequently, there is the need for a process of manufacturing an electronic device that improves the above-described process.
All of the subject matter discussed in the Background section is not necessarily prior art and should not be assumed to be prior art merely as a result of its discussion in the Background section. Along these lines, any recognition of problems in the prior art discussed in the Background section or associated with such subject matter should not be treated as prior art unless expressly stated to be prior art. Instead, the discussion of any subject matter in the Background section should be treated as part of the inventor's approach to the particular problem, which, in and of itself, may also be inventive.
According to an embodiment of the present disclosure, a method for manufacturing a semiconductor electronic device Includes forming, on a first side of a solid body of semiconducting material, a first covering layer of a first oxide of the semiconducting material and forming, on the first covering layer, a second covering layer of a nitride of the semiconducting material. The method includes forming, on the second covering layer, a third covering layer of a second oxide of the semiconducting material and forming a passing opening through the first, second and third covering layers, exposing a portion of the first side of the solid body. The method includes forming a trench at the exposed portion of the solid body, the trench extending within the solid body towards a second side, opposite to the first side along a first direction, of the solid body and growing a sacrificial layer, of the first oxide, within the trench. The method includes selectively etching part of the second covering layer after forming the sacrificial layer and completely removing the sacrificial layer and the third covering layer in one or more etching steps after selectively etching part of the second covering layer.
In one embodiment, a method includes forming, on a semiconductor substrate, a stack of dielectric layers including a first dielectric layer, a second dielectric layer on the first dielectric layer and selectively etchable with respect to the first dielectric layer, and a third dielectric layer on the second dielectric layer and selectively etchable with respect to the first dielectric layer and the second dielectric layer. The method includes exposing the semiconductor substrate by forming an opening in the stack of dielectric layers, forming a trench in the semiconductor substrate via the opening, and forming a fourth dielectric layer on sidewalls of the trench. The method includes recessing the second dielectric layer with respect to the first dielectric layer and the third dielectric layer at the opening by performing a first etching process and depositing a conductive gate material of a switching device in the trench after the first etching process.
In one embodiment, a device includes a switch. The switch includes a semiconductor body of a semiconductor material and including a gate trench and a first dielectric layer on a top surface of the semiconductor body and including an oxide of the semiconductor material. The switch includes a second dielectric layer on a top surface of the first dielectric layer and including a nitride of the semiconductor material and an opening in the first dielectric layer and the second dielectric layer above the trench. The first dielectric layer is recessed relative to the second dielectric layer at the opening. The sidewall of the second dielectric layer is substantially vertical at the opening. The switch includes a gate metal filling the trench and the opening.
For a better understanding of the present disclosure, preferred embodiments thereof are now described, purely by way of non-limiting example, with reference to the attached drawings, wherein:
According to the present disclosure, a power device is provided, in particular a MOS transistor, or IGBT, with source electrode at a front side of the device, a drain electrode at a back side of the device, and a trench gate that extends from the front side towards the back side.
In particular, the present disclosure describes exclusively the manufacturing steps of interest for the disclosure (i.e., regarding formation of a trench gate). Further elements of the electronic device (e.g., edge regions or other electrically active or non-active structures), which are of a per se known type, are not described and illustrated.
On the substrate 101, a structural layer or region 102 is formed, for example by epitaxial growth of silicon (or other semiconducting material), having the first conductivity (N) and a concentration of dopants lower than that of the substrate 1 (e.g., between 1·1015 and 5·1016 ions/cm3). In one embodiment, dopants concentrations are used, for example equal to that of the substrate 101 or higher than that of the substrate 101. The structural region 102 has a thickness, along Z, that is chosen on the basis of the voltage class in which the electronic device is to operate (e.g., 750 V), and is, for example, approximately between 700 μm and 800 μm.
The structural region 102 is delimited by a first side 102a and a second side 102b opposite to one another in the Z direction. The second side 102b of the structural region 102 coincides with the first side 101a of the substrate 101.
According to alternative embodiments (not illustrated), one or more further structural regions, which are, for example, grown epitaxially analogously to the structural region 102, are formed on the first side 101a of the substrate 101.
On the first side 102a of the structural layer 102, a multilayer 104 is then formed, which includes: a first covering layer 104a, in contact with the first side 102a, made, for example, of silicon oxide (in particular, SiO2) grown via thermal oxidation with a thickness between 5 nm and 10 nm; a second covering layer 104b, on top of the first layer 104a, made, for example, of silicon nitride (in particular, Si3N4 or Si2N3) with a thickness between 10 nm and 20 nm; and a third covering layer 104c, on top of the second layer 104b, made, for example, of TEOS with a thickness between 300 nm and 500 nm. In one exemplary embodiment, the second layer 104b is in direct contact with the first layer 104a, and the third layer 104c is in direct contact with the second layer 104b.
The first layer 104a is, in particular, in direct contact with the structural layer 102 and has the function of forming an adhesion interface between the structural layer 102 and the second layer 104b, in order to prevent mechanical stress induced by the material of the second layer 104b on the material of the first layer 104a; further, it prevents nitridation of the surface of the silicon, which can jeopardize the operation of the device. The second layer 104b forms a hard mask for subsequent etching steps; this also prevents oxidation where not desired as well the erosion of the silicon itself during a subsequent Chemical Mechanical Polishing process.
As represented in
In one embodiment, in top plan view on plane XY, the trench 106 is strip-shaped, with main extension along the axis Y ranging from a few microns to a few millimeters, and a width, along the axis X, between 0.5 μm and 1.5 μm. Other layouts are also envisaged for the trench 106; for example, it has, on the plane XY, a generically polygonal shape.
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Since the second layer 104b is sandwiched between the first and the third layer 104a, 104c, the liquid (wet) etching solution etches the second layer 104b from the exposed lateral sides, and penetrates between the first and third layers 104a, 104c as the material of the second layer 104b is removed (in particular laterally, or from a side).
This process step, which can be referred to as “pullback” step, produces a lateral recession of the second layer 104b, to leave the top corners (in one embodiment, of silicon material) of the trench 106 uncovered during the gate dielectric growth. Since the top side 104b′ and the bottom side 104b″ of the second layer 104b are protected by the first and respectively the third layers 410a, 104c, the etching acts only on the exposed lateral side 104b of the second layer 104b, avoiding the formation of the undesired negatively tapered shape shown in
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Then, a layer of doped polysilicon 122, having the first conductivity type (N), and a doping level between 1018 at/cm3 and 1021 at/cm3 is formed (e.g., deposited) within the trench 106 on the gate dielectric layer 120 and, in general, on the front of the wafer 100 (in particular, on the second layer 104b). A subsequent Chemical-Mechanical-Polishing (CMP) step is carried out to remove the layer of doped polysilicon 122 from the front of the wafer 100, except for the trench 106. The second layer 104b has the function of a stop layer for the CM step. Other removal processes may be used without departing from the scope of the present disclosure. In one embodiment, to reduce an undesired erosion of the wafer 100 during the CMP process, it is beneficial to reduce the mechanical component and to amplify the chemical contribution of the CMP chemistry (slurry), which is preferably highly selective. For example, it is possible to choose the slurry among those available on the market. The chemical contribution of the slurry allows to better control the material erosion and its selectivity (via the stoichiometry of the chemical reaction) with respect to the mechanical erosion provided by the pad and diamond disks, which act only as grinders. Such unbalancing can be obtained by reducing the pressure value in the process recipe of the above-mentioned hardware parts, to softly erode the wafer. A possible second option is to tune the chemistry composition of the slurry flowing during the CMP process, which is preferably highly selective.
In one embodiment, when a slurry selective toward the oxide is not available, to match the criteria to leave the gate dielectric (here, of SiO2) unaltered, a slurry highly selective toward the silicon nitride of the second layer 104b is used, for example using a material based on calcinated of Cerium Oxide having a property of enhancing the polysilicon removal rate. Cerium Oxide has a pH value between 7 and 9 and is able to remove polysilicon material, reducing the reaction towards the silicon nitride. In one embodiment, unbalancing the chemical effect with respect to the mechanical includes increasing of the temperature, which acts as enabler of the kinetic reaction. In such conditions, after the complete polysilicon removal, the consumption of the landing silicon nitride is very limited, and the gate dielectric underneath remains untouched and not damaged.
In one embodiment, the SiN as a stopping layer improves the whole process integration because, during the gate dielectric growth, it provides a mechanical resistance creating a waved horizontal silicon profile and a rounded silicon corner on top of the trench 106, which are preferred shapes to reduce wafer stresses and improve electrical performances of the device thus manufactured.
Then, in a way that is not shown in the drawings, body regions, having the second conductivity (P), are formed by known techniques of implantation of dopant species laterally to the trench 106, and thermal diffusion/activation, as well as one or more source regions, having the first conductivity (N), within the body regions.
In one embodiment, processing of the wafer 100 then continues with deposition of pre-metallization dielectric, etching of the latter for opening electrical contacts by photolithography so as to reach and expose respective surface portions of the gate electrode and of the source regions, respective depositions of one or more metal layers that contact the gate electrode and the source regions, and photolithographic definition of the metal layers for completing formation of the source and gate electrodes. A further deposition on the back of the wafer (on the second side 101b of the substrate) enables formation of a drain metallization.
The gate and source metallizations are formed by depositing conductive material on the wafer 100. Likewise, also the drain metallization is formed by a step of deposition of conductive material, in particular metal, on the back of the wafer 100, thus completing formation of the drain terminal.
A vertical-conduction electronic device is thus formed. In operation, an electric current flows vertically (along Z direction) from the source regions to the drain metallization, through the structural region 102 and the substrate 101.
The electronic device 40 according to the present disclosure is, by way of example, one of the following: a vertical-conduction power MOS transistor, a power IGBT, or an MCT (MOS-Controlled Thyristor). Other applications of the disclosed process can be utilized without departing from the scope of the present disclosure.
From an examination of the characteristics of the disclosure provided according to the present disclosure the advantages that it affords are evident.
In particular, the disclosure allows to:
Finally, it is clear that modifications and variations can be made to what has been described and illustrated herein, without thereby departing from the scope of the present disclosure, as defined in the annexed claims.
In particular, even though the description explicitly refers to silicon materials and its oxides, the present disclosure can be readily adapted to other semiconductor materials and respective oxides.
Moreover, the steps of forming the body regions and the source regions may be carried out (and are usually carried out) before the steps of forming the trench 106, so that the body regions and the source regions becomes self-aligned with the lateral sides of the trench 106 once the latter is formed.
In one embodiment, a method for manufacturing an electronic device includes the steps of: forming, on a first side (102a) of a solid body (101, 102) of semiconducting material, a first covering layer (104a) of a first oxide of the semiconducting material; forming, on the first covering layer (104a), a second covering layer (104b) of a nitride of the semiconducting material; forming, on the second covering layer (104b), a third covering layer (104c) of a second oxide of the semiconducting material; forming a passing opening through the first, second and third covering layers (104a-104c), exposing a portion of the first side (102a) of the solid body (101, 102); forming a trench (106) at the exposed portion of the solid body, the trench extending within the solid body towards a second side (101b), opposite to the first side along a first direction (Z), of the solid body; grow a sacrificial layer (114), of the first oxide, within the trench (106); and perform in the order: selectively etch part of the second covering layer (104b), completely remove the sacrificial layer (114) and the third covering layer (104c) in one or more contextual etching steps.
In one embodiment, the method further includes the steps of: forming, within the trench (106) a gate dielectric layer (120); forming, within the trench (106) and on the gate dielectric layer (120), a gate conductive region (122), wherein forming the gate conductive region (122) includes: depositing conductive material within the trench and on the second covering layer (104b), and performing a CMP process to remove the conductive material on the second covering layer (104b), using the second covering layer (104b) as a stop layer for the CMP process.
In one embodiment, the CMP process is performed using a slurry highly selective towards the material of the second covering layer (104b).
In one embodiment, the CMP process is carried out in such a way that the chemical erosion of the conductive material on the second covering layer (104b) prevails over the mechanical erosion of the conductive material.
In one embodiment, the semiconductor material is silicon; the first oxide is silicon oxide, SiO2; the second oxide is TEOS; the nitride material is silicon nitride, Si2N3.
In one embodiment, the second covering layer (104b) has a top side facing the third covering layer (104c), a bottom side facing the first covering layer (104a) and a lateral side connecting the top side and the bottom side, the lateral side being fluidically accessible through the passing opening, and wherein selectively etching part of the second covering layer (104b) includes performing a wet etching of the second covering layer (104b) at the lateral side.
In one embodiment, growing the sacrificial layer (114) includes performing a thermal grow process.
In one embodiment, forming the trench (106) includes etching the solid body for a thickness, along the first direction (Z), between μm 4 and 10 μm, ending within the solid body.
In one embodiment, the method further includes forming a body region laterally to the trench (106) and a source region within the body region; and forming a drain contact at the bottom side of the solid body.
In one embodiment, the device in the group including a vertical-conduction MOS transistor, an IGBT, an MCT.
These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
Number | Date | Country | Kind |
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102023000026448 | Dec 2023 | IT | national |