Embodiments of the present disclosure relate to active switching technology, and in particular, relates to a manufacturing method of an array substrate and an array substrate.
Active switch is a key device of a display panel and plays a very important role in the performance of display panel. With the rapid development of electronic equipment, electronic equipments of lower power consumption and better endurance are required, as well as display panels of lower power consumption in electronic equipments.
A display panel is defined with an active switch array substrate. However, at present, the leakage current of the active switch of the active switch array substrate is relatively large, and when light irradiates the active switch, photogenerated carriers will also be generated, further increasing the leakage current of the active switch and resulting in higher power consumption of the display panel and poor stability of the active switch.
Embodiments of the present disclosure provide a manufacturing method of an array substrate and an array substrate to reduce leakage current of an active switch of the array substrate and improve stability of the active switch.
Embodiments of the present disclosure provide a manufacturing method of an array substrate, the array substrate includes a plurality of active switches, and the manufacturing method of the array substrate includes:
providing a substrate;
forming a gate electrode, a gate insulating layer, a semiconductor layer, a source-drain electrode layer and a photoresist layer all on the substrate;
patterning the photoresist layer to form a patterned photoresist layer, and the patterned photoresist layer includes a first region, a second region, and a third region between the first region and the second region, and the thickness of the third region ranges from 0.2 microns to 0.8 microns; and,
patterning the source-drain electrode layer by using the patterned photoresist layer as a mask, forming a source electrode of the active switch in a portion covered by the first region, forming the drain electrode of the active switch in a portion covered by the second region, patterning the semiconductor layer, and forming a channel region of the active switch in the portion covered by the third region.
Embodiments of the present disclosure also provides an array substrate which is defined with a plurality of active switches, the active switch is formed by the manufacturing method provided above, and the active switch includes:
a substrate;
a semiconductor layer, a source electrode and a drain electrode all formed on the substrate;
and the source electrode and the drain electrode are located on one side of the semiconductor layer away from the substrate;
the distance between the projection profile of the semiconductor layer on the substrate and the projection profile of the source electrode or the drain electrode on the substrate ranges from 0 to 1.5 microns; the distance between the projection profile of the doping layer on the substrate and the projection profile of the source electrode or the drain electrode on the substrate ranges from 0 to 1.0 microns.
The manufacturing method of the array substrate provided in some embodiments of the present disclosure may reduce the portions of the semiconductor layer of the active switch beyond the source electrode and the drain electrode, reducing light absorption of the semiconductor layer in the active switch, the probability of generating photo-generated carriers, and the leakage current of the active switch. Thus the manufacturing method may correspondingly improve and the stability of the active switch, when the active switch is used in a display panel, power consumption of the display panel may also be reduced.
In order to more clearly explain the technical scheme in the embodiments or example technologies of the present disclosure, the drawings that need to be used in the embodiments or example technical descriptions will be briefly introduced below. Obviously, the drawings in the following description are some embodiments of the present disclosure. For those of ordinary skill in the art, other drawings may be obtained from these drawings without paying creative labor.
In order to make the purpose, technical scheme and advantages of the present disclosure clearer, the technical scheme of the present disclosure will be described clearly and completely by way of implementation with reference to the drawings in the embodiments of the present disclosure. Obviously, the described embodiments are part of the embodiments of the present disclosure, not all embodiments. Based on the embodiments in the present disclosure, all other embodiments obtained by a person of ordinary skill in the art without making creative work fall within the scope of protection of the present disclosure.
Herein, take the N-type active switch as an example to explain the working principle of the active switch. When a positive voltage greater than the on voltage of the N-type active switch is applied to the gate electrode 12, an electric field will be generated between the gate electrode 12 and the active layer 14. Under the action of this electric field, a conductive channel will be formed in the active layer 14 so that a conductive state will be formed between the source electrode 161 and the drain electrode 162. The larger the voltage applied to the gate electrode 12, the larger the conductive channel will be. In this condition, when a voltage is applied between the source electrode 161 and the drain electrode 162, carriers will pass through the conductive channel. When a negative voltage lower than the on voltage of the N-type active switch is applied to the gate electrode 12, no electron channel is formed in the active layer 14, and a closed state is formed between the source electrode 161 and the drain electrode 162. The doped layer 15 is formed between the active layer 14 and the source electrode 161, and formed between the active layer 14 and the drain electrode 16, being defined to reduce the resistances against the signals of active layer 14 and the source-drain electrodes 16. Those skilled in the art may understand that the functions of the substrate 11, the gate electrode 12, the gate electrode insulating layer 13, the active layer 14, the doping layer 15 and the source electrode/drain electrode 16 of the active switch provided by the embodiments of the present disclosure are similar to those of the prior art technology, which will not be described here.
In the actual manufacturing process of the active switch, the edge of the formed amorphous silicon layer 14 exceeds the edge of the source electrode and drain electrode 16, i.e. the amorphous silicon tail L2 is formed, and the edge of the formed doped layer 15 exceeds the edge of the source electrode and drain electrode 16, i.e. a tail L1 of the doped layer outside the channel and a tail L3 of the doped layer inside the channel are formed. When the active switch is applied to a liquid crystal display panel, the existence of the above three types of tails, especially the amorphous silicon tail L2, may directly contact or absorb visible light emitted by the backlight module of the liquid crystal display panel. The amorphous silicon layer 14 may react with the visible light to generate light leakage current, thereby further increasing the leakage current of the active switch, resulting in higher power consumption of the array substrate and unstable electrical performance of the active switch.
In order to solve this problem, some embodiments of the present disclosure provide a manufacturing method of an array substrate, which includes a plurality of active switches. Referring to
S10, providing a substrate.
In this embodiment, the substrate may be a glass substrate or a flexible substrate such as polyimide (PI). Those skilled in the art may understand that if the application products and the application scenarios of the active switch of the array substrate are different, the substrate materials of the array substrate are different. Obviously, the substrate materials include, but are not limited to, glass substrates and flexible substrates, and any material that may be used as the array substrate falls within the scope of protection of the present disclosure.
S20, forming a gate electrode, a gate electrode insulating layer, a semiconductor layer, a source electrode-drain electrode layer and a photoresist layer on the substrate.
In this embodiment, the constituent material of the optional gate electrode is aluminum (Al) or molybdenum (Mo), the constituent material of the gate electrode insulating layer is silicon nitride (SiN), and the semiconductor layer may include an active layer and a doped layer, and the constituent material of the active layer is amorphous silicon (a˜Si), the constituent material of the doped layer is heavily doped amorphous silicon, and the optional material may include N-type amorphous silicon or P-type amorphous silicon. The constituent materials of the source-drain electrode layer are molybdenum nitride, aluminum and constituent materials of molybdenum nitride (MON/Al/MON) photoresist layers including resin, sensitizer, solvent and additive, the constituent materials are sequentially stacked, and the sensitizer is a photosensitive component in the photoresist layer, and photochemical reaction may occur to radiant energy in the form of light (especially ultraviolet region). Photoresist may be divided into positive glue and negative glue in terms of disclosure characteristics. For positive glue, the part irradiated by ultraviolet rays may be removed due to chemical property changes, while for negative glue, the part irradiated by ultraviolet rays may remain due to chemical property changes. In this embodiment, the positive glue is optionally used as an example. Those skilled in the art may understand that the constituent materials of each film layer of the array substrate include, but are not limited to, the above examples, and the constituent materials of any film layer structure of the array substrate fall within the scope of protection of the present disclosure; and the manufacturing process of each film layer structure is not specified in the present disclosure, the constituent materials of any film layer structure of the array substrate fall within the scope of protection of the present disclosure.
S30, patterning the photoresist layer to form a patterned photoresist layer, and the patterned photoresist layer includes a first region and a second region, and a third region located between the first region and the second region, and the thickness of the third region ranges from 0.2 microns to 0.8 microns.
Patterning the photoresist layer in this embodiment may includes removing portions of different thicknesses from the surface of the relatively flat photoresist layer by using exposure and development technique, thereby forming a patterned (uneven) photoresist layer. The patterned photoresist layer includes the above three regions divided according to the different thicknesses of the photoresist layer and the different functional areas of the active switch.
And The thickness of the third region ranges from 0.2 microns to 0.8 microns 0.2 microns to 0.8 microns, which may ensure that the photoresist of the third region is completely etched in the subsequent etching process, that is, when the active switch corresponding to the third region are completely exposed, the remaining thickness and lateral dimensions of the first region and the second region ensure that their corresponding active switch structure may be effectively covered.
S40. patterning the source-drain electrode layer by using the patterned photoresist layer as a mask, forming the source electrode of the active switch in the portion covered by the first region, forming the drain electrode of the active switch in the portion covered by the second region, patterning the semiconductor layer, and forming the channel region of the active switch in the portion covered by the third region.
Optionally, patterning the source-drain electrode layer includes at least one wet etching of the source-drain electrode layer; the patterning of the semiconductor layer includes at least one dry etching of the semiconductor layer.
In this embodiment, wet etching may include etching the source-drain electrode layer with a mixed solution of phosphoric acid (H3PO4), acetic acid (CH3COOH) and nitric acid (HNO3), and etching the semiconductor layer (including the active layer and the doped layer) with vacuum plasma. The etching gas may include a mixed gas of sulfur hexafluoride (SF6) and chlorine (Cl2) or a mixed gas of sulfur hexafluoride (SF6), oxygen (O2) and helium (He).
Optionally, a halftone mask process is used to pattern the photoresist layer, and the required illumination energy corresponding to the exposure of the third region ranges from 37 millijoules (mJ) to 48 millijoules (mJ).
Optionally,
Optionally,
Optionally, when the value of the remaining thickness Thic. of the photoresist layer 24 ranges from 0.4 to 0.8 microns, the required exposure energy Dose is 1.5 mJ for every 0.1 micron decrease in the remaining thickness Thic. of the photoresist layer 24. When the value of the remaining thickness Thic of the photoresist layer 24 is in the range of 0.2 to 0.4 microns, the required exposure energy Dose is 2.5 mJ for every 0.1 micron decrease in the remaining thickness Thic of the photoresist layer 24. Therefore, it is necessary to control the value of the appropriate exposure energy according to the remaining target thickness of the photoresist layer 24.
Optionally,
Optionally, the remaining thickness Hl of the first region and the second region of the photoresist layer 404 is 1.8 microns to 2.2 microns.
Optionally, the angle a between the pit surface of the photoresist layer 404 and the interface between the photoresist layer 404 and the multilayer functional layer 403 ranges from 28° to 32°.
Optionally, the remaining thickness Hl of the first and second regions of the photoresist layer 24 microns is 2.174 microns, the minimum remaining thickness H2 of the third region is 0.54 microns, and the included angle a between the pit surface and the interface between the photoresist layer 404 and the multilayer functional layer 403 is 30.69°.
Optionally, the third region of the photoresist layer has a thickness uniformity value ranging from 25% to 55%.
Among them, uniformity characterizes the flatness of the retained thickness of the third region, and optionally, the numerical calculation method of uniformity may adopt the following formula:
Among them, Hmax represents the maximum value of the retained thickness of the third region and Hmin represents the minimum value of the retained thickness of the third region. The smaller the value of U % of the uniformity, the better the uniformity of the remaining thickness of the third region of the photoresist layer.
Optionally,
Optionally, the manufacturing method includes two wet etches and two dry etches, and the wet etches and the dry etches are alternately performed. Specifically, it may include: first wet etching, patterning the source-drain electrode layer to form a metal wire structure of the source electrode region, the drain electrode region and the active region; First dry etching to form an island structure of semiconductor layer (including an active layer and a doped layer), i.e. an patterned semiconductor layer (including an active layer and a doped layer); a second wet etching, patterning the source-drain electrode layer to form a source electrode in the source electrode region and a drain electrode in the drain electrode region; In the second dry etching, the semiconductor layer (including the active layer and the doped layer) is etched, that is, the semiconductor layer (including the active layer and the doped layer) is etched to form an active switch structure.
Optionally, the dry etching may be over etched by 10%, and optionally, the etching time is 76 seconds, thereby further reducing the portions of the semiconductor layer beyond the source electrode and drain electrode.
Optionally, the feature size loss on each side of photoresist layer 414 is 0.94 microns.
Optionally, the manufacturing method further includes performing at least one photoresist ashing operation, the photoresist ashing operation being defined between the dry etching operation and the wet etching operation. Specifically, after the first dry etching, a photoresist ashing operation is performed before the second wet etching to remove the photoresist in the third region to expose the source-drain electrode layer in the channel region.
Optionally,
The active switch structure of the array substrate thus formed reduces the portions of the semiconductor layer beyond the source electrode and drain electrode, that is, the portions of the active layer beyond the source electrode and drain electrode are reduced, and the portions of the doped layer beyond the source electrode and the drain electrode are reduced, thereby reducing the light absorption by the semiconductor layer of the active switch of the array substrate and the probability of generating photo-generated carriers, as well as reducing the leakage current of the active switch, and correspondingly improving the stability of the active switch.
Optionally, the ratio of the lateral etching rate to the longitudinal etching rate in the photoresist ashing operation ranges from 1:0.9 to 1:1.5.
Optionally,
Optionally, in the photoresist ashing operation, the etching gas includes sulfur hexafluoride and oxygen.
Optionally, when the ratio of the lateral etching rate to the longitudinal etching rate is 1:0.9, the etching gas is oxygen. When the ratio of lateral etching rate to longitudinal etching rate is 1:1.5, the etching gas is sulfur hexafluoride and oxygen, and the flow ratio of sulfur hexafluoride to oxygen ranges from 0.02 to 0.1.
In the photoresist ashing operation, gas generates plasma under the action of a radio frequency power source electrode in a vacuum environment, and the plasma bombards or reacts with the surface of the photoresist layer with high energy to ash the photoresist layer, i.e., the photoresist layer is thinned or removed. By adding sulfur hexafluoride gas, the longitudinal etching rate of the photoresist layer may be accelerated, and by controlling the type and flow rate of the gas, the ratio of the lateral etching rate to the longitudinal etching rate of the photoresist layer may be controlled to vary in the range of 1:0.9 to 1:1.5.
Optionally, the flow rate of sulfur hexafluoride ranges from 200 sccm to 800 sccm, and the flow rate of oxygen ranges from 8000 sccm to 10000 sccm, so that the ratio of the lateral etching rate to the longitudinal etching rate of the photoresist layer is controlled to range from 1:0.9 to 1:1.5.
Therefore, the first region of the photoresist layer after the photoresist ashing operation precisely covers the source electrode and the second region precisely covers the drain electrode, that is, the projection of the first region of the photoresist layer on the substrate is nearly coincident with the projection of the source electrode of the active switch on the substrate, and the projection of the second region of the photoresist layer on the substrate is nearly coincident with the projection of the drain electrode of the active switch on the substrate, so that in the subsequent dry etching process, the portions of the semiconductor layer (including the active layer and the doped layer) beyond the photoresist layer are etched away, that is, the portions of the semiconductor layer (including the active layer and the doped layer) beyond the source electrode and drain electrode are etched away, so that the active switch structure formed on the array substrate reduces the portions of the semiconductor layer beyond the source electrode and drain electrode, that is, the portions of the active layer beyond the source electrode and drain electrode, and the portions of the doped layer beyond the source electrode and drain electrode, thereby reducing the light absorption by the semiconductor layer of the active switch, and the possibility of generating photo-generated carriers, as well as reducing the leakage current of the active switch, and correspondingly improving the stability of the active switch
And the smaller the distance between the projection profile of the active layer 230 on the substrate 200 and the projection profile of the source electrode 251 or the drain electrode 252 on the substrate 200, the smaller the probability that the active layer 230 absorbs light, thereby reducing the probability that the active switch may generate photo-generated carriers, that is, reducing the leakage current of the active switch. Similarly, the smaller the distance between the projection profile of the doping layer 240 on the substrate 200 and the projection profile of the source electrode 251 or the drain electrode 252 on the substrate 200, the smaller the probability of absorbing light absorption by the doping layer 240, thus reducing the probability of generating photo-generated carriers by the active switch, that is, reducing the leakage current of the active switch.
Optionally, the distance between the projection profile of the active layer 230 on the substrate 200 and the projection profile of the source electrode 251 or the drain electrode 252 on the substrate 200 may be 0 to 0.8 microns, and the distance between the projection profile of the doped layer 240 on the substrate 200 and the projection profile of the source electrode 251 or the drain electrode 252 on the substrate 200 may be 0 to 0.5 microns. Optionally, when the projection profile of the active layer 230 on the substrate 200 is 0 micron apart from the projection profile of the source electrode 251 or the drain electrode 252 on the substrate 200, and the projection profile of the doping layer 240 on the substrate 200 is 0 micron apart from the projection profile of the source electrode 251 or the drain electrode 252 on the substrate 200, the semiconductor layer (including the active layer 230 and the doping layer 240) does not absorb light and no photo-generated carriers are generated in the active switch, so that the leakage current of the active switch is 0 and the stability of the corresponding active switch is high.
It should be noted that the active switches of 6 rows and 6 columns are optionally shown in
The array substrate provided in some embodiments of the present disclosure includes the above-mentioned active switch, which reduces the portions of the semiconductor layer beyond the source electrode and drain electrode, i.e., the portions of the active layer beyond the source electrode and drain electrode, and the portions of the doped layer beyond the source electrode and drain electrode, thereby reducing the light absorption by the semiconductor layer of the active switch of the array substrate and the possibility of generating photo-generated carriers, as well as reducing the leakage current of the active switch and correspondingly improving the stability of the active switch.
Embodiments of the present disclosure also provide a liquid crystal display device.
Optionally, the display panel 300 includes an array substrate 310, a pixel electrode 320, a encapsulation layer 330, a liquid crystal molecule layer 340 and a common electrode 350, and the deflection of the liquid crystal molecules in the liquid crystal molecule layer 340 is controlled by applying an electric field between the pixel electrode 320 and the common electrode 350, thereby realizing display. It should be noted that as shown in
Those skilled in the art may understand that the application range of the active switch of the array substrate includes but is not limited to display panels, and any electronic devices that may integrate the above active switch fall within the scope of protection of the present disclosure.
It is to be noted that the above are only optional embodiments of the present disclosure and the technical principles used by them. It may be understood by those skilled in the art that the present disclosure is not limited to the specific embodiments described herein, and various obvious changes, readjustments, combinations and substitutions may be made to those skilled in the art without departing from the scope of protection of the present disclosure. Therefore, although the present disclosure has been described in more detail through the above embodiments, the present disclosure is not limited to the above embodiments, but may include more equivalent embodiments without departing from the concept of the present disclosure, and the scope of the present disclosure is determined by the scope of the appended claims.
Number | Date | Country | Kind |
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201810196074.5 | Mar 2018 | CN | national |
The present application is a Continuation Application of PCT Application No. PCT/CN2018/113606 filed on Nov. 2, 2018, which claims the benefit of Chinese Patent Application No. 201810196074.5 filed on Mar. 9, 2018. All the above are hereby incorporated by reference.
Number | Date | Country | |
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Parent | PCT/CN2018/113606 | Nov 2018 | US |
Child | 16253440 | US |