Patent Application
20150217493
The invention relates to a method for manufacturing products made of plastics.
Specifically, but not exclusively, the method can be used for making caps for containers provided with a tamperproof band having a flap portion folded inwards, this flap portion being in particular configured for forming an abutting element that cooperates with the neck of the container in order to detach the tamperproof band when the container is first opened.
A method is known for folding an annular flange of a tamperproof band of a cap made of plastics according to which the cap, when it has just been extracted from the mould, has the flange orientated with a tilt that is different from the tilt thereof when in use; the cap is then cooled to ambient temperature, after which the flange is folded mechanically to the use configuration.
From EP 1165391 a method is known for making a cap made of plastics provided with a flexible band that is moulded in the use configuration (folded towards the inside of the cap), and in which the spring-back of the band to the original forming position thereof is forced mechanically immediately after moulding of the cap, by an element of the forming mould or by another element that acts after extraction of the cap from the mould, before cooling of the band.
From U.S. Pat. No. 5,846,471 a method is known for moulding a closure with a safety band provided with flaps extending radially inward and upwards, in which the flaps are first moulded with the desired tilt, then the mould is opened by temporarily altering the angle of tilt of the flaps, lastly the flaps return to the original tilt through the effect of the contact with a part of the mould.
Various aspects of the prior art methods are improvable. First, it would be desirable to be able to decrease the effect of the spring-back of the material after the element made of plastics has been folded, so as to reach easily and reliably a final configuration that is as close as possible to that desired, this drawback being detectable in particular when folding is performed hot. Second, it would be desirable to minimise the yield effect of the material near the folding zone, so that the connection between the folded element and the rest of the workpiece is not weakened, this drawback being detectable particularly when folding is performed cold.
Specifically, but not exclusively, the method can further be used to make caps for containers provided with a skirt portion and with a tamperproof band intended for being separated from the skirt portion when the container is first opened (in order to provide clear proof of opening) through the effect of the breakage of a facilitated breaking zone. The tamperproof band is generally provided with a contrasting arrangement that may comprise, by way of non-limiting example, an inwardly folded flap portion. In particular this contrasting arrangement can be configured to form one or more abutting elements that cooperate with at least one protrusion on the neck of the container in order to detach the tamperproof band when the container is first opened.
Forming the aforesaid facilitated breaking zone by using cutting devices that operate so as to perform a cut (continuous or discrete) along a circumferential zone of the skirt portion is known. Some examples of cutting devices of known type used for this purpose are shown in the patent documents EP 0619168, WO 99/17911, WO 00/44538, WO 2004/004993.
One of the problems of known forming systems of the facilitated detachment zone of a cap made of plastics with tamperproof band consists of the fact of ensuring a clean and precise cut in the plastic material, such as to avoid the risk of anticipated and undesired detachment of the tamperproof band, and simultaneously to ensure that when the container is first opened the band is detached correctly with facility and cleanly. It is therefore necessary or at least advantageous to make the cut within precise tolerances.
Another problem is that of performing the cut rapidly in order to increase productivity.
A further problem is that of choosing suitable conditions for cutting in function of the type of product to be cut, in particular according to the type of plastic material and of the form of product.
Another problem arises if the cutting of the material for forming the tamperproof band coincides with (generally immediately before or after) the guided mechanical folding of the possible flap portion, this folding generally being conducted after moulding to bring this flap portion (when present) to the use configuration in which it faces inwardly the cap and upwards (with reference to the use configuration in which the cap closes the upper mouth of the container that is arranged standing). This folding is generally necessary because in the use configuration the flap portion forms an undercut that would not allow removal from the mould. If the folding step is conducted near the place or time with the step of cutting the tamperproof band, there is thus the problem of finding a work condition that is suitable for correctly performing both operations.
Each of patent publications US 2008/054524 A1, EP-A-1108523, EP-A-1165391 and EP-A-1588673 discloses a method as in the preamble of claim 1.
An object of the invention is to improve the prior art in one or more of the aforesaid aspects.
Another object is to provide a method for manufacturing bodies made of plastics, in particular caps, that is simple, easy and cheap to implement.
A further object is to provide a method for manufacturing products made of plastics provided with a part that is folded after moulding, in which reaching the desired configuration of this folded part in a precise and reliable way is facilitated.
Still another object is to make available a product made of plastics and a method for manufacturing such a product, in which a folded element is connected firmly and strongly to the rest of the body of the product.
An advantage of the invention is to give rise to a manufacturing method of a product made of plastics that is implementable with known manufacturing systems or with few and simple modifications to such systems.
Another advantage is to provide a suitable method for manufacturing caps made of plastics, each comprising a tamperproof band having an annular side wall and an annular flange, in which this flange is folded inwards and is configured for expanding radially during the application of the cap to the mouth of a container, thus facilitating the passage of the tamperproof band, to then yield to the original position at the end of the application, forming an abutting element that is able to cooperate, at the first opening of the container, with a corresponding abutting element associated with the container to cause the detachment of the tamperproof band.
In a second aspect, a further object is to provide a method for manufacturing products made of plastics provided with a facilitated detachment zone, in which this zone is makable in a precise and reliable manner.
Still another object is to make available a product made of plastics, and a method for manufacturing the object, in which an element that is detachable from the rest of the product body is connected along a facilitated detachment zone constructed in a precise manner.
An advantage of the invention is to give rise to a manufacturing method of a product made of plastics that is implementable with known manufacturing systems or with few and simple modifications to such systems.
Another advantage consists of a versatile method that is able to perform a material removal step effectively in a product made of plastics, in particular a precise and reliable cut in a cap made of plastics, also for different types of product, for example by varying the type of material and the form of the product.
A further advantage is to provide method that is suitable for manufacturing caps made of plastics, each cap comprising a tamperproof band that is detachable when the container is first opened.
Such objects and also others are all reached by the method according to one or more of the claims set out below.
The element that is folded after moulding may comprise, as already said, the flexible flange with which a tamperproof band of a cap made of plastics is normally provided. This foldable flange may have any of the geometries of known foldable flanges: this flange may comprise, for example, an only smooth and continuous annular strip, or an only annular strip provided with one or more interruptions such as through holes and/or non-through openings, or an element that extends annularly and is wholly or partially corrugated, or a series of elements (flaps) that are connected to the side wall of the tamperproof band and are spaced apart from one another, or a series of elements that are arranged annularly and are interconnected one another, and any other known type of foldable flange of a tamperproof band.
The element that is folded after moulding can have been moulded in the same configuration (for example with the same tilt) that this element should assume after subsequent folding, or can have been moulded in a different configuration (tilt), such as, for example, a suitable configuration for facilitating the extraction of the element from the forming cavity. In the specific case of the production of caps with a tamperproof band it is possible to provide for the foldable flange of the tamperproof band being moulded in the use configuration, i.e. pointing towards the upper wall of the cap (where “upper” is defined with reference to the configuration in which the cap closes the upper mouth of a container arranged in a standing position), or in a different configuration in which, for example, the foldable flange of the tamperproof band faces an opposite side to the upper wall of the cap. It is known that it is generally necessary a folding operation after moulding because in order to enable the cap to be extracted from the forming cavity the flange will in general have to be folded on the opposite side to the upper wall of the cap.
The folding operation can be performed with a mechanical guiding device, in particular with a mechanical guiding device of known type. This guiding device can be configured for operating in the mold or also in a position outside the mold.
The moulding operation can be performed by injection-moulding or by compression-moulding or by any other plastic material forming process. The moulding device can be configured for operating continuously or intermittently.
The cooling operation can be performed by using a cooling active arrangement, such as, for example, a cooling tunnel, a cooling fluid conveyor, a conveyor belt provided with a cooling device, etc.
The cooling operation can be performed by using a passive cooling arrangement, such as, for example, a path arranged between the molding zone and the folding zone and configured in such a manner that each molded piece is conducted along the path and thus reaches the folding zone having the desired temperature. This path may also include a waiting and storage step (with controlled temperature and/or waiting time) of the molded product. This path may have a preset and known temperature (for example, ambient temperature). This path can be configured so that a given molded product can travel the path from the molding zone to the folding zone in a pre-established time or a time preset as a function of the type of product and/or of the desired folding temperature and/or the temperature of the path.
It is possible to use the manufacturing method disclosed here not only for caps made of plastic but also for other types of product (in particular for moulded products made of plastics having a part folded after extraction from the forming cavity), or also for elements that are generally folded in a force and/or guided manner after moulding and have no annular shape and/or are not connected to the rest of the body of the moulded piece along a connecting or folding zone of annular shape.
According to an embodiment of the invention, a product manufacturing method comprises the steps of moulding a piece made of plastic material having at least a skirt portion, forming by removing material on the skirt portion a facilitated detachment zone that separates an edge portion from the rest of the skirt portion, and selecting the temperature of the plastic material of the skirt portion at which this removal of material is conducted in function of an intermediate physical transition temperature of the plastic material.
The aforesaid intermediate physical transition temperature could comprise, for example, the alpha-type physical transition temperature of the plastic material.
The material removal step, a step that forms a facilitated detachment zone that separates an edge portion from a skirt portion, can be performed simultaneously, for example before or after or during a guided folding step of a protruding part that protrudes from the aforesaid edge portion.
The invention can be better understood and implemented with reference to the attached drawings that illustrate some embodiments thereof by way of non-limiting example.
A method is now disclosed for manufacturing products made of plastics, in particular for manufacturing caps for containers, such as, for example, a method for manufacturing any of the caps illustrated in
The method includes the step of molding a piece made of a synthetic plastic material, for example a semi-crystalline plastic material, in which the molded piece can have at least a skirt portion and an edge portion (for example of annular shape) connected to the skirt portion along a connecting zone that may be, for example, of annular shape (closed or open) or arranged along a region with a circumferential extent, and which may be continuous or discontinuous (for example dashed). As is known, a cap made of synthetic plastics is normally provided with this skirt portion that generally (when the cap is coupled with a neck of a container for closing the top mouth thereof) surrounds at least part of the neck. This skirt portion can be provided with a thread for screwing to the neck of the container. It is possible to manufacture other types of caps provided with other arrangements (of known type) of coupling with the container (alternatively or additionally to a screw coupling arrangement). This molding step may include an operation performed with a molding arrangement and with operating methods that are substantially of known type. This molding may include one or more injection-molding operations (performed with arrangements and methods of known type), or one or more compression-molding operations (also performed with arrangements and methods of known type) or other operations (conducted with arrangements and methods of known type) for heat-forming a product made of synthetic plastic material.
During this moulding step a product part is also moulded (generally a part protruding or emerging from a main body) that is then intended for folding. This part intended for folding can be, as in the specific case, the aforesaid edge portion connected to the skirt portion. This part intended for folding can be a part that in the final product will form an undercut and can thus in general not be extracted from the forming cavity remaining in the desired final configuration (i.e. in the undercut configuration). In such cases a subsequent folding operation is conducted after moulding. It is possible that the manufacturing method in subject provides that the piece is moulded in such a manner that this undercut part (flap) already assumes in the forming cavity the final use configuration (i.e. the undercut configuration): in this case this undercut part will thus be deformed during the step of extracting the moulded piece from the forming cavity in the direction of the extraction that causes the undercut moulded part (flap) to overturn outwards. In order to facilitate and/or guide the return of this undercut part to the use configuration (corresponding, exactly or approximately, to the moulding configuration in the forming cavity) folding is conducted.
It is also possible for the manufacturing method in subject to mould the piece so that the part intended to be undercut is formed with a configuration different from the use configuration, in particular it is possible for this part to be moulded in a configuration that is already able to enable/facilitate extracting from the forming cavity. In the specific case of the production of caps made of plastics, it is thus possible for the portion to be folded (which in practice is the flap part of the tamperproof band of the cap that is intended to form, in use, the abutting element that abuts on the collar of the neck of the bottle) is already formed during the moulding step in the use configuration—i.e. folded inwards and upwards (with reference to the usual configuration in which the cap is applied to the neck of a standing container) i.e. to the closing portion or top portion of the cap, which portion is generally disc-shaped—or in a configuration other than the use configuration, for example an axial configuration (not tilted with respect to the axis of the cap) or with a slight tilt inwards but oriented on a side opposite the closing portion of the cap (in practice an orientation of the type of the flap 2 illustrated in
The manufacturing method, after moulding the product and opening the forming cavity, provides to mechanically folds in a guided manner the aforesaid annular portion around the connecting zone (or folding zone) at a preset folding temperature (as will be explained better below) that is greater than ambient temperature.
This folding may occur before the hot product that has just be subjected to the hot moulding operation is completely cooled, or after complete cooling of the moulded product and subsequent second heating thereof at a preset temperature that is greater than ambient temperature, this second heating being able to be conducted immediately after cooling or at a great distance of time and/or of space from cooling.
With reference to
The manufacturing method comprises the step of selecting the aforesaid preset folding temperature (i.e. the temperature of the material of the moulded product or, more in particular, of the portion of this product to be folded, during the folding operation) in function of the alpha-type physical transition temperature Tα of the plastic material from which the product for moulding has been obtained.
For example, the folding temperature can be selected so as to be less than the aforesaid alpha-type physical transition temperature Tα. Further, the aforesaid folding temperature can be greater than the beta-type physical transition temperature Tβ of the plastic material. The aforesaid Tα and Tβ transition temperatures, that can vary in function of the material and of other parameters, are temperatures that are known in the technology of plastic material. A short explanation of these transition temperatures Tα and Tβ of the materials is provided below.
It is known that polymeric semi-crystalline plastic material (for example PE, PP, PA, POM, PET, etc) are distinguished by having some parts in an amorphous phase (in which the polymeric chains are disordered, giving rise to more flexible zones) and other parts in a crystalline phase (in which the polymeric chains are ordered, giving rise to stiffer zones). It is also known that the semi-crystalline polymers have, in addition to a melting temperature Tm in which the transition between the solid and the liquid phase occurs, also a glass transition temperature Tg in which the amorphous portion passes from a stiff solid phase to a plastic solid (rubbery) phase, whilst for the amorphous polymers the glass transition temperature Tg indicates the transition between a stiff solid phase (glass and fragile) and a rubbery solid phase that, as the temperature increases, is then transformed into a viscous liquid phase.
Above the glass transition temperature Tg reciprocating movements between segments of a polymeric chain become possible. At temperatures below the glass transition temperature Tg movements can still occur in the mass of the polymer, in general limited to small groups of atoms. These movements are characterised by transition temperatures (so-called secondary transition temperatures) generally indicated by Tβ, Tγ, Tδ. In certain cases, below the temperature Tg, whilst the movements of relatively long polymeric chain segments (i.e. containing a certain number of monomeric units) are blocked, certain secondary movements are still possible, for example the movements of shorter chain segments or of small groups of atoms contained in the single monomeric units; the movements of other groups of atoms can then be blocked only below the temperature Tβ, whereas other movements of the same groups of atoms and/or certain movements of other groups of atoms can be blocked only below the temperatures Tγ or Tδ.
In particular it has been found, always by dynamic-mechanical analysis techniques, that isotactic polypropylene (i-PP) shows three transition steps γ-, β- and α- in the −150 to 150° C. temperature range, and that the polyethylene (PE) below the melting point Tm shows three transition points in which the transition γ occurs in a range comprised between −150 and −100° C. whilst the transition a generally occurs between 30 and 100° C., in function of the type of PE. It is generally considered that for semi-crystalline polymers the transition a represents the crystalline phase and in fact originates from some movements inside the crystals.
In
The applicant has found that the folding (and/or the cut) of a part of a piece obtained by moulding plastic material (for example the folding of a flap portion of a safety band of a cap made of plastics), if performed at a temperature that is approximately the same or less than the transition temperature Tα of the material (temperature below which movements inside the crystallites cannot occur) and above the transition temperature Tβ (glass transition temperature), or also above the ambient temperature Tamb if Tamb>Tβ, is better than a folding (and/or cutting) of the same part (flap portion) conducted at a temperature that is greater than the transition temperature Tα (for example by conducting folding immediately after hot moulding of the cap with band, by a tool inside the mould or as soon as the cap is extracted from the mould), or better than a folding (and/or cutting) of this part (flap portion) made after cooling of the moulded piece (cap with tamperproof band provided with flap portion) at ambient temperature.
In particular it has been found that if the flap portion of the safety band is folded at a temperature that is approximately the same or less than the transition temperature Tα, the spring-back of the flap portion after the folding operation is reduced. This reduction in the spring-back could be due to the fact that at the transition temperature Tα or at temperatures slightly less than Tα, some parts or zones or components of the semi-crystalline plastic material that form the cap (for example the crystallites contained in the mass of material) have lost, at least partially, their mobility. It has also been found by the applicant that folding at the aforesaid temperature (greater than the ambient temperature and about the same or slightly less than the temperature Tα) does not produce on the folded part, in particular along the folding zone, significant yielding phenomena or other types of weakening.
In greater detail, it has been found that in a cap made of plastics, for example like one of those disclosed with reference to
The caps illustrated in
In the examples illustrated here the moulded products (in particular caps with an annular safety band showing the first opening of a container closed by the cap) each have an annular part (or flaps portion) that is folded after forming and is connected to the rest of the body of the product along a connecting zone or folding zone of annular shape. It is nevertheless possible to use the manufacturing method disclosed here also for folded elements that do not have an annular shape and/or which are not connected to the rest of the body of the moulded piece along a connecting or folding zone of annular shape.
It is in particular possible, in order to reduce both the yield in the folding zone and spring-back after folding, that the aforesaid folding temperature is greater than a limit temperature Tinf equal to
in which Tα is the alpha-type physical transition temperature of the plastic material, and Tamb is the ambient temperature (which can vary significantly, depending on the place of manufacture).
Particularly in order to reduce both the yield in the folding zone and spring-back after folding, the aforesaid folding temperature can be less than a limit temperature Tsup that is equal to Tsup=Tα+10° C., in which Tα is the alpha-type physical transition temperature of the plastic material.
The aforesaid folding temperature could be comprised, for example in order to reduce both the yield in the folding zone and spring-back after folding, in an interval of values with an upper limit value Tsup=Tα+Δsup and a lower limit value Tinf=Tα−Δinf, in which Δsup is comprised between 0° C. and 20° C. and Δinf is comprised between 0° C. and 40° C. The folding temperature could be comprised, for example, between Tα−40° C. and Tα, or between Tα−40° C. and Tα+10° C., or between Tα−20° C. and Tα.
The aforesaid plastic material used in forming the product may comprise, as said, semi-crystalline plastic material, in particular one of the following materials or a mixture of materials containing at least one or more of the following materials: polyethylene, polypropylene, polyethyleneterephthalate.
It is possible to provide, after the molding step and before the folding step, a step of cooling in a controlled manner at least a part of the molded piece to be folded. This cooling step may include the operation of directing a flow of a cooling fluid (for example air) to the part of a molded piece to be cooled. The cooling fluid can have a temperature that is preset and controllable by a heat-conditioning device (of known type) that can be provided with a control unit that receives a desired value of the temperature of the cooling fluid and/or of the product to be cooled.
It is, for example, possible to provide during the aforesaid cooling for the moulded piece to be moved along a preset cooling path comprised between a moulding zone and a folding zone. This cooling path may comprise, for example, a transferring channel (closed or at least partially open), and/or a rotating tunnel, and/or a cooling silo, and/or a conveyor belt, or any other cooling system that is in particular suitable for operating continuously or discretely on a series or a considerable number of products.
It is possible to provide along the aforesaid path a measuring device being provided for measuring the temperature of the products (in particular of the zone intended for folding) and/or the temperature of a zone of the path. This measuring device is configured for emitting a signal that is received from a control unit that can, for example, control the cooling arrangement placed along the path and/or can control the travel time of the molded pieces along the path so as to vary the temperature, for example, with a feedback control as a function of a desired temperature.
With reference to
The cap further has a skirt portion or tubular portion 7 that emerges from the peripheral end of the upper portion 6. The skirt portion 7 can have internally (as in this case) a thread for coupling a corresponding thread borne by the neck of the container. It is possible to provide other types of cap provided with a system (of known type) of coupling with the container that is different from the screw coupling. To the end of the skirt portion 7 opposite the closing portion 6 an annular tamperproof band 8 is connected that is configured for detaching from the portion of skirt 7 when the container is first opened to indicate clearly that first opening has occurred. The annular tamperproof band 8 is connected to the skirt portion 7 by an annular facilitated breaking zone. This facilitated breaking zone can be obtained after moulding by means of the action of removing the material obtained with a cutting tool of known type. In the cap the breaking zone is obtained by cutting and is indicated by a dashed line 9.
The annular tamperproof band 8 is provided with an annular flap part 10 folded inwards and upwards (with reference to the use configuration of the cap coupled with the neck of the standing container). This annular flap part 10 is intended, when the container is first opened, to act as an axial abutment with an abutting element (for example a collar) protruding radially from the neck of the container for limiting or preventing axial movement of the safety band integrally with the rest of the cap when the latter is raised to enable the container to be opened.
In the specific case the annular flap part 10 is formed by a body extending in a circumferential direction around the edge of the safety band 8. This annular flap part 10 has a series of radial protrusions or corrugated elements. In the specific case this annular flap part 10 comprises a plurality of triangular elements connected in series one after the other along a respective side. This folded annular flap part 10 may comprise an upper edge, that faces upwards (with reference to the use configuration of the cap that closes the upper neck of the standing container), i.e. that faces the upper closing part the upper closing part 6 of the main body of the cap, in which this upper edge has an undulating or zigzag shape, forming overall a plurality of radial protrusions protruding inwards and arranged alongside one another in a circumferential direction.
In the specific case the cap has a seal 11, for example disc-shaped, arranged below the upper closing portion 6 and intended in use to act as a fluid seal, in the known manner, on the upper end of the neck of the container.
The annular flap part 10 is subjected to a folding operation in the use configuration, like the one illustrated in
The folding operation may consist, as said, of modifying the orientation of the flap part 10 in a mechanically guided manner. Typically, this orientation is modified such that the flap part 10 is moved from a configuration in which it faces downwards (still with reference to the use configuration of the cap), i.e. facing an opposite side to the upper closing portion 6 of the cap, to a configuration in which it faces upwards, i.e. faces the aforesaid upper closing portion 6. The folding operation occurs by using a folding tool that is substantially of known type, i.e. any of the folding tools of known type for folding in use position an annular flap part of a safety band of a moulded cap made of plastics. As said, the folding operation occurs when the temperature of the moulded piece, in particular the temperature of the flap part that has to be folded, is not only less than the forming temperature or the outlet temperature of the moulded piece from the forming cavity, but more in particular at a still lower temperature, i.e. a temperature that is less than the alpha transition temperature of the plastic material with which the cap is made.
In particular, if the temperature Tα of the material is approximately 80° C., the folding temperature is approximately 40-80° C., or approximately 70-80° C.; if the temperature Tα is approximately 70° C., the folding temperature is approximately 40-70° C., or approximately 60-70° C.; if the temperature Tα is approximately 100° C., the folding temperature will be approximately 60-100° C., or approximately 90-100° C. In practice, it is possible to use a temperature range between Tinf=Tα−30/40° C. and Tsup=Tα+0/10° C.
The operation of forming the facilitated detachment zone of the safety band occurs subsequently, in practice immediately after (or previously, in fact immediately before) so that the temperature at which this subsequent operation is conducted is substantially the same as or slightly below or slightly above (for example with a difference of not more than 5-15° C. below or above) the temperature at which folding is performed. As said, forming the facilitated detachment zone may comprise removing material, in particular removing performed by a cutting tool. Therefore also the cutting operation (which in general comprises a continuous cut or a series of cuts performed along an external or internal circumferential zone of the cap) may occur with advantage at a temperature that is approximately the same as or less than the alpha transition temperature of the material of the cap.
The cutting devices used for forming the facilitated detachment zones are of known type and do not therefore require particular explanations.
With reference to
In
In
It is thus provided that a cap is manufactured with a folding of the annular flap part 10 at a temperature selected on the base of the type of material and in particular on the base of the alpha transition temperature of the material, and in which the operation of forming the facilitated detachment zone (which operation may comprise removal of material by cutting tool) is conducted before (or after) the folding operation of the annular flap part. The two operations (removal of material and folding) can occur in rapid succession (by means of devices of known type), for which reason in practice the execution temperature for both operations is less or almost the same as the alpha transition temperature of the material and greater than ambient temperature.
It is further possible that no folding operation is provided in a cap but a forming operation of the facilitated detachment zone is provided (an operation that may comprise as said a removal of material by means of a cutting tool) and that this operation is performed at a temperature selected as disclosed above, i.e. on the basis of the type of material and, in particular, of the alpha transition temperature of the material, for which reason in practice the execution temperature can be approximately the same or less than the alpha transition temperature of the material.
In
In the cap in
In
With reference to
With reference to
The cutting and folding device 208 is of the type disclosed above. Amongst the cutting devices that are usable for forming the facilitated detachment zone are included all known devices used for this purpose such as, for example, the devices disclosed in the following patent publications EP 0619168, WO 99/17911, WO 00/44538, WO 2004/004993, which are deemed to be incorporated by reference.
In
In
| Number | Date | Country | Kind |
|---|---|---|---|
| MO2008A000270 | Oct 2008 | IT | national |
| MO2008A000271 | Oct 2008 | IT | national |
This application is a continuation of application Ser. No. 13/125,142 with an effective filing date of Jul. 11, 2011. application Ser. No. 13/125,142 is a §371 National Stage Entry of PCT International Application No. PCT/IB2009/054639 filed Oct. 21, 2009. PCT/IB2009/054639 claims priority of IT Application No. MO2008A000270 filed Oct. 23, 2008 and IT Application No. MO2008A000271 filed Oct. 23, 2008. The entire content of these applications is incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 13125142 | Jul 2011 | US |
| Child | 14613524 | US |
