Patent Application
20200282374
The present invention presents a system for and method of processing a particulate material, for example carbonaceous materials, food products or minerals, to produce a processed material having more desirable properties.
The Inventor has previously developed an expanded toroidal bed reactor described in U.S. Pat. No. 7,998,421, the disclosure of which is incorporated herein by reference.
It has been discovered that this device, or a similar device, can be used to process particulate material to achieve desirable properties. In particular, the device can be used to process particulate carbonaceous material to produce activated carbon, metallurgical coke, charcoal or carbonaceous material. Advantageously, this has been found to produce products with a surprisingly high surface area.
The following describes a device that can establish a processing zone which provides for a predictable particle flow path, both circumferentially and helically, in the processing zone to ensure more uniform particle treatment and gas/solid mixing for a given residence time.
The device may be used in a method of processing a particulate material that comprises the steps of:
The chamber comprises a processing zone having a substantially circular transverse cross-section, the fluid flow is introduced into the processing zone at an angle of between 10° and 75° with respect to a tangent of the substantially circular transverse cross-section of the processing zone to establish a fluid flow following a substantially helical path in the processing zone.
It has been recognised that the introduction of the fluid flow into the processing zone within the above-referenced parameters is particularly suitable for establishing a uniform particle flow path. Thus, uniform particle treatment and gas/solid mixing may be achieved.
The particulate material and fluid are in contact with each other in the processing zone.
The fluid flow upon entry into the processing zone may define an angle of between 20° and 60°; or between 30° and 45° with respect to said tangent.
The fluid flow upon entry into the processing zone is preferably inclined upwardly at an angle between 5° and 45°; between 10° and 40°; between 15° and 35°; or between 20° and 30° with respect to a horizontal plane.
The particulate material may be removed at predetermined time intervals in a batch process. Alternatively, the particulate material may be fed continually into the device with egress of the processed particulates occurring automatically owing to their changed mass resulting from processing. It has been discovered that by intentional calibration of the fluid flow, the mass distribution of the processed material leaving the chamber can be predetermined.
The velocity of the fluid flow is preferably controlled so as to be greater than the terminal velocity of particulate material in the chamber that has not yet been sufficiently processed.
The direction of the fluid flow may be developed by at least one nozzle or tube. Alternatively, the direction of the fluid flow is developed by at least one vane or deflector. Preferably, however, a plurality of vanes, deflectors or tubes are employed.
The fluid flow in the chamber preferably can cause the particulate material to undergo both vertical and horizontal displacement. Thus, the mixing of the particulate material with the fluid may be maximised within the chamber.
Although the processing zone may be defined by the walls of the chamber, it is preferably formed by fluid flow in a central region of the chamber to allow particulate material to exit the processing zone and be deposited radially outwardly of the processing zone. The deposited particulate material preferably forms a flowing bed. The chamber preferably has a base inclined downwardly towards the centre of the chamber to bias particulate material in the flowing, bed back towards the processing zone.
The processing zone is preferably annular or toroidal in shape. This may be achieved by providing a central conduit or pillar in the chamber, but is preferably implemented by the helical movement of the fluid flow inside the chamber.
Although the fluid may be introduced into the side or the top of the processing zone, it is preferably introduced at the base thereof. Although in certain arrangements it may be desirable for the fluid to be a liquid, it is more usually a gas. The helical fluid flow is preferably either conical or cylindrical. The apparatus further comprises a flow controller suitable for controlling the velocity of the fluid introduced into the chamber.
For a better understanding of the invention, and to show how the same may be put into effect, reference will now be made, by way of example only, to the accompanying drawings, in which:
A cross-sectional view of a toroidal bed reactor (1) in accordance with a preferred embodiment of the present invention is shown in
Across-sectional view of the lower portion of the reactor (1) is shown in
A hole (8a) for the egress of processed particulates is provided in the base of the housing (3). The hole 8a is preferably annular and centred around the longitudinal axis of the housing (3).
A hole (8b) for the egress of processed particulates is provided in the side of the housing (3), distal from the base of the housing (3). This hole 8b is preferably the exhaust path of the fluid exiting the chamber. In this way, the exhaust fluid may entrain some of the processed particulates.
The vanes (9) direct the gas flow so that it enters the processing zone (5) at an angle a with respect to a tangent (B) of the substantially circular transverse cross-section of the processing zone, as shown in
The advantage of directing the gas flow inwardly at an angle a is that there is an increased mixing of the gas flow. This provides for a uniform distribution of particulate matter as will be described below. A gas flow which is introduced along a tangent of the processing zone (angle α=0°) will produce less mixing of the gas flow, and so will provide a less uniform distribution of particulate matter.
Furthermore, the vanes (9) cause the gas to enter the processing zone at an angle β inclined upwardly with respect to a horizontal plane (C), as shown in
The path followed by particulate material (11) introduced into the reactor (1) will now be described for different gas flow paths with reference to
In contrast, when the gas is introduced into the reactor (1) in accordance with the invention (e.g. α is 30° and β is 15°), it follows a helical flow path (E), as shown in
The even distribution of particles in the fluid flow is important to help prevent undesirable effects that may occur when the gas follows the flow path (D) shown in
As shown in
The velocity of the gas entering into the processing zone (5) is advantageously controlled to ensure that it is greater than the terminal velocity of the particulate material. This control of the fluid flow helps to reduce or prevent the collection of particulate material at the base of the reactor (1).
It has been found that if the angle β of entry of the gas into the processing zone is 10° or more above a horizontal plane, and it is inclined at an angle α of 10° or more relative to a tangent to a radial line at the point of entry, the fluid and particulate material follow the fluid path illustrated in
The arrangement of the vanes (9) at the base of the reactor (1) will now be described in greater detail. A single vane (9) is shown in
The slots (15) extend at an angle 13 relative to a reference axis perpendicular to the leading edge (13) of the vane (9), as shown in
A top view of the vanes (9) arranged in an assembly (21) ready for use is shown in
The processing zone (5) is generally annular in shape because of the helical fluid flow inside the housing (3).
By controlling the angle of entry of the fluid into the processing zone to maintain it larger than 10° but less than 75° relative to the tangent to the radial line at the point of entry; and to be greater than 5° but less than 45° relative to said horizontal plane, as shown in
The circulating particles are accelerated by the gas flow in the processing zone (5) in both horizontal and vertical directions to travel tangentially of said circumferential flow until such accelerated particles lose their energy and settle into the flowing bed arranged circumferentially of the processing zone (5). By displacement in the flowing bed, the circulating particles are returned to the base of the processing zone (5) thereby ensuring that all of the particles in the bed are exposed to the processing gases to provide for uniform and rapid processing of said particles.
The device can be used in a process for processing particulate material with a stream of fluid in an annular processing zone. The process includes the steps of supplying the particulate material for processing into the processing zone, discharging processed material from the zone and generating in the processing zone a circumferentially directed flow of fluid to develop a circulating turbulent band of particles. The device advantageously provides a predictable particle flow path both circumferentially and helically, within the processing zone. The process preferably comprises directing the flow of fluid to develop a circulating bed, a flow of fluid directed at an angle relative to the tangent to the radial line to the point of fluid and to the horizontal plane at entry into the processing zone base.
The process may also comprise controlling fluid velocity so that it is greater than the terminal velocity of particles that have not been sufficiently processed at their point of impact on the bed base and less than the terminal velocity of particles that have been processed a desired amount in the superficial space above the bed upper surface.
A method of processing particulate material to produce processed particulate material, the method comprising the steps of: introducing the particulate material into the chamber of a toroidal bed reactor; and providing a flow of fluid into said chamber for entraining the particulate material via inlets at a lower end of the chamber.
In the following example, the particulate material is carbonaceous material. However, other materials may be used, such as minerals or clay.
Although not always the case, the carbonaceous material may be provided in a form that is undesirably wet. For example, it may have in excess of 30% moisture by weight. In fact, it may have more than 60% moisture by weight. Accordingly, an optional pre-processing step of drying the carbonaceous material to below 30% moisture is provided. This may be carried out in a toroidal bed reactor (e.g., of the type described above). The drying step is carried out at a temperature of no more than 600° C. Preferably, the drying is carried out at a temperature of no more than 200° C.
As described above, the chamber comprises a processing zone having a substantially circular transverse cross-section. The fluid flow is introduced into the processing zone at a non-perpendicular angle with respect to a tangent of the substantially circular transverse cross-section of the processing zone to establish a fluid flow following a substantially helical path in the processing chamber.
This fluid flow entrains and transports individual particulate material in a cyclical path during processing. Specifically, as may be seen in
The processing may alter the terminal velocity of the particles. Firstly, the heat of the processing fluid may alter the particles. For example, the particles will be dried. Furthermore, the particles may collide with one another of surrounding structures and break apart by a process of attrition.
The terminal velocity of an aggregated mass of particles may eventually become greater than the velocity of fluid flow introduced into the chamber at which point the particles will not be entrained by the fluid flew in the processing zone, and will not be forced radially outwardly. At this point, they will descend through the hole 8a under the force of gravity.
There may also be provided an outlet 8b at the upper end of the chamber for the exhaust of fluid out of the chamber. Fine processed particulate material may be entrained in the exhaust fluid and exit the chamber via the outlet 8b.
In preferred embodiments, the fluid flow is introduced at a velocity selected so as to achieve a predefined amount of processing of the particulate material within the chamber prior to egress from the chamber.
Preferably, this is achieved by introducing the fluid flow at a velocity selected so as to achieve a predefined residence time of the supplied particulate material within the chamber prior to egress from the chamber.
The preferred fluid flow (whether it be expressed as velocity, mass flow rate, volume flow rate, etc.) for the method may be determined by a calibration process using the device prior to the above-described processing. The calibration process comprising the steps of: introducing a particulate material into a chamber, the particulate material comprising a distribution of masses; providing a flow of fluid at a known velocity into said chamber for entraining the particulate material via inlets at a lower end of the chamber; and monitoring the mass of particulates exiting the chamber.
Alternatively, the preferred fluid flow for the method may be determined by a feedback process during the above-described process. The feedback process comprising the steps of: monitoring the mass of particulates exiting the chamber via hole 8a during processing; increasing the fluid flow in response to the mass of particulates being below a predetermined lower mass value; and decreasing the fluid flow in response to the mass of particulates being above a predetermined upper mass value.
The preferred fluid flow rate for carbonaceous material particles with a water content of less than 10% will preferably be selected to provide a residence time of at least 10 seconds, preferably no more than 500 seconds.
The fluid flow is introduced at a temperature of at least 600° C. However, it has been found that fluid in the range 800° C. to 1100° C. is preferable for producing activated carbon or charcoal material.
The fluid flow preferably has a temperature in the range 600° C. to 1100° C.
The method is preferably used in a staged manner. Firstly, the above-described optional drying step may be used.
An optional intermediate step may be used in which the dried particulate material is processed in a toroidal bed reactor in which the temperature of the fluid flow is from 600° C. to 800° C. This stage produces a product that can be used as a final product in some applications. Preferably, however, this is just an intermediate product that can be used in the final stage.
In the final stage the above described method is applied with a fluid flow temperature greater than 800° C. and preferably, from 800° C. to 1100° C.
Each of the stages may be carried out in a single toroidal bed reactor, or may be implemented in separate toroidal bed reactors.
In order to achieve the temperatures of the final stage, additional heating means may be provided, external to the chamber, to increase the temperature of the fluid flow. That is, the fluid is preferably preheated prior to introduction into the chamber. This is the case even when the fluid is recycled exhaust gas taken from the chamber exhaust outlet 8b.
In fact, in some embodiments, the recycled exhaust gas may comprise volatile constituents be taken from the chamber, and this may be combusted to increase the fluid temperature prior to the reintroduction of the fluid back in to the chamber.
With general applicability to other materials, but with particular benefit for the processing of carbonaceous material, the oxygen content of the chamber may be controlled.
In preferred embodiments means for measuring the oxidising agent content of the chamber is provided. Such devices are well known and include laser measuring devices. This may, for example, include means for measuring the amount of moisture, CO, CO2, or O2, etc. in the chamber.
An amount of oxidising agent in the fluid can be modulated in order to prevent the amount of oxidising agent in the chamber from exceeding 20%. More preferably, an amount of oxidising agent in the fluid can be modulated in order to prevent the amount of oxidising agent in the chamber from exceeding 10%. Most preferably, in particular for carbonaceous material, the amount of oxidising agent in the fluid can be modulated in order to prevent the amount of oxidising agent in the chamber from exceeding 7%.
An amount of oxidising agent in the fluid can be modulated, for example, by supplying a mix of oxygen or aft with recirculated exhaust gases.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1718393.0 | Nov 2017 | GB | national |
This application is a national stage entry under 35 U.S.C. 371 of PCT Patent Application No. PCT/GB2018/053207, filed Nov. 5, 2018, which claims priority to United Kingdom Patent application Ser. No. 17/183.930, filed Nov. 7, 2017, the entire contents of each of which is incorporated herein by reference.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/GB2018/053207 | 11/5/2018 | WO | 00 |
