The current disclosure relates to the mechanical attachment of thermally stable polycrystalline diamond to a carrier or substrate. This mechanical attachment may be sufficient to allow the ultimate attachment of the thermally stable polycrystalline diamond to a drill bit or other component using conventional attachment methods, such as brazing.
Components of various industrial devices are often subjected to extreme conditions, such as high impact contact with abrasive surfaces. For example, such extreme conditions are commonly encountered during subterranean drilling for oil extraction or mining purposes. Diamond, with its unsurpassed wear resistance, is the most effective material for earth drilling and similar activities that subject components to extreme conditions. Diamond is exceptionally hard, conducts heat away from the point of contact with the abrasive surface, and may provide other benefits in such conditions.
Diamond in its polycrystalline form has added toughness as compared to single crystal diamond due to the random distribution of the diamond crystals, which avoids the particular planes of cleavage found in single diamond crystals. Therefore, polycrystalline diamond is frequently the preferred form of diamond in many drilling applications or other extreme conditions. A drill bit that utilizes this material is referred to as a PDC (Polycrystalline Diamond Cutter) bit. Polycrystalline diamond can be manufactured in a press by subjecting small grains of diamond and other starting materials to ultrahigh pressure and temperature conditions.
The manufacturing process for a traditional PDC is very exacting and expensive. The process is referred to as “growing” polycrystalline diamond directly onto a carbide substrate to form a polycrystalline diamond composite compact. The process involves placing a cemented carbide piece and diamond grains mixed with a catalyst binder into a container of a press and subjecting it to a press cycle using ultrahigh pressure and temperature conditions. The ultrahigh temperature and pressure are required for the small diamond grains to form into an integral polycrystalline diamond body. The resulting polycrystalline diamond body is also intimately bonded to the carbide piece, resulting in a composite compact in the form of a layer of polycrystalline diamond intimately bonded to a carbide substrate.
The composite compact allows the attachment of the polycrystalline diamond body to other materials via attachment of the bonded carbide substrate to those materials. Unlike polycrystalline diamond, carbide may be easily attached to other materials via conventional methods, such as soldering and brazing. These methods may be performed at relatively low temperatures at which the polycrystalline diamond portion of the composite compact remains stable.
A problem with polycrystalline diamond composite compacts arises from the use of cobalt or other metal catalyst/binder systems to facilitate polycrystalline diamond growth. After crystalline growth is complete, the catalyst/binder remains within pores of the polycrystalline structure. Because cobalt or other metal catalyst/binders have a higher coefficient of thermal expansion than diamond, when the composite compact is heated, e.g., during the brazing process by which the carbide portion is attached to another material, or during actual use, the metal catalyst/binder expands at a higher rate than the diamond. As a result, when the composite compact is subjected to temperatures above a critical level, the expanding catalyst/binder causes fractures throughout the polycrystalline diamond structure. These fractures weaken the polycrystalline diamond body and can ultimately lead to damage to or failure of the composite compact.
Today's polycrystalline diamond material is designed to withstand temperatures at which composite compacts in the form of cutters are brazed to a drill bit (even multiple times), but as bits have been improved and used to drill harder and more abrasive formations, the temperature at the working face of a cutter can significantly exceed the critical temperature.
A new generation of polycrystalline diamond has been developed that utilizes a leached zone of diamond at the working face of the cutter. The majority of the catalyst/binder in this zone has been depleted, most often by acid leaching methods. Examples of current leaching methods are provided in U.S. Pat. No. 4,224,380, U.S. Pat. No. 7,712,553, U.S. Pat. No. 6,544,308, U.S. 20060060392 and related patents or applications. This process renders the polycrystalline diamond body more thermally stable in the leached zone while leaving the remainder of the body to provide attachment to the carbide substrate. Fully leached bodies (referred to hereafter as “thermally stable diamond” or “TSD”) may also be created using these processes. However, such bodies lack a carbide substrate, making it difficult to attach them to other components. After the metal catalyst/binder has been removed from polycrystalline diamond to form TSD, the material is relatively non-wettable and its surface does not readily attach or adhere to other materials.
As a result of difficulties in attachment, attempts have been made to mechanically attach TSD bodies to substrates or bits. TSD bodies have previously primarily been used for surface set drill bits, where cutters made from the TSD bodies are generally small and may be embedded into the bit body by more than 50% to effect a mechanical “lock.” One such system is described in U.S. Pat. No. 4,602,691. These and other mechanical locking methods are described in U.S. Pat. No. 7,533,740, U.S. Pat. No. 4,780,274, U.S. Pat. No. 4,629,373 and related patents or applications, but such methods are prone to failure.
For instance, in U.S. Pat. No. 4,780,274, holes in a TSD body were filled with bit matrix. However, due to the low wetting capacity of TSD, the TSD elements were not effectively held by the bit matrix. Furthermore, because the bit body lacks the mechanical strength of cemented carbide or other substrate materials, TSD elements attached to a bit as disclosed in U.S. Pat. No. 4,780,274 are prone to failure under high load or impact.
Similarly, U.S. Pat. No. 4,629,373 discloses a TSD body with surface irregularities that are used in an attempt to mechanically lock the TSD to a substrate. However, the surface irregularities in U.S. Pat. No. 4,629,373 are not sufficient to achieve permanent attachment of the TSD and a substrate because the non-attachability of diamond to other materials is not overcome.
Other techniques seeking to avoid reliance on such mechanical trapping have centered around enhancements to the surface of the TSD that enable it to be brazed to a carbide substrate or carrier in much the same way a traditional polycrystalline diamond composite compact cutter is brazed to a bit. Example brazing methods are described in described in U.S. Pat. No. 4,850,523, U.S. Pat. No. 7,487,849, U.S. Pat. No. 4,225,322 and related patents or applications. Although some level of success has been reported with such techniques, commercial products employing them are not yet available.
Accordingly a need exists for methods of reliably attaching TSD to a substrate, in particular a substrate that will allow the ultimate attachment of the TSD via conventional methods such as brazing or soldering to drill bits or other components used in extreme conditions where TSD is beneficial.
The present invention provides for mechanical attachment of a TSD body to a carrier or substrate sufficient to allow eventual conventional attachment of the TSD to a drill bit or other component.
According to one aspect, the invention includes a composite assembly including a thermally stable diamond (TSD) body having at least one TSD body hole disposed therein. The hole may reach from a top surface of the TSD body to a bottom surface of the TSD body. The composite assembly also includes a substrate having at least one substrate hole disposed therein, the substrate hole being located so as to align with the TSD body hole, and at least one joining pin disposed in the TSD body hole and the substrate hole to mechanically attach the TSD body to the substrate to form a composite assembly. In some embodiments, the composite assembly may lack any non-mechanical attachment between the TSD body and the substrate or may lack certain types of non-mechanical attachments.
According to a second aspect, the invention includes a drill bit including a bit body and a composite assembly according to the first aspect.
According to a third aspect, the invention includes a method of forming a composite assembly. The method includes forming at least one hole in a thermally stable diamond (TSD) body. The hole may reach from a top surface of the TSD body to a bottom surface of the TSD body. The method also includes forming at least one hole in a substrate. The hole may align with the hole in the TSD body when the composite assembly is formed. The method further includes attaching at least one joining pin to the substrate via the at least one hole in the substrate, then placing the at least one joining pin the at least one hole in the TSD body to mechanically attach the TSD body to the substrate to form a composite assembly in which the TSD body and substrate are held together in the composite assembly in the absence of any non-mechanical attachment therebetween.
According to a forth aspect, the invention includes another method of forming a composite assembly. This method includes forming at least one hole in a thermally stable diamond (TSD) body, which may reach from a top surface of the TSD body to a bottom surface of the TSD body, placing at least one joining pin in the hole in the TSD body, placing the TSD body and joining pin in a mold, placing a matrix powder in the mold on the TSD body and infiltrating the matrix powder and the at least one joining pin with an infiltration material to form a substrate attached to the joining pin and mechanically attached to the TSD body in a composite assembly.
According to a fifth aspect, the invention includes yet another method of forming a composite assembly. This method includes forming at least one hole in a thermally stable diamond (TSD) body, which may reach from a top surface of the TSD body to a bottom surface of the TSD body, forming at least one hole in a substrate, which may align with the hole in the TSD body after the composite assembly is formed, placing at least one joining pin in the hole in the TSD body and in the hole in the substrate to form a TSD body/substrate/joining pin assembly, placing a shim of alloy material in the bottom of a mold, placing the TSD body/substrate/joining pin assembly on the alloy material in the mold, and heating the mold to a brazing temperature such that the braze alloy melts, wicks up the sides of the joining pin and bonds the pin to the substrate.
According to a sixth aspect, the invention includes a method of forming a drill bit. The method includes casting a substrate or substrate-like support in a bit body of the drill bit during formation of the bit body by a matrix infiltration process, forming at least one hole in the substrate or substrate-like support, the hole being located so as to align with a TSD body hole to form a composite assembly, forming at least one hole in a thermally stable diamond (TSD) body, wherein the hole may reach from a top surface of the TSD body to a bottom surface of the TSD body, attaching at least one joining pin to the substrate or substrate-like support via the at least one hole in the substrate or substrate-like support, and placing the at least one joining pin the at least one hole in the TSD body to mechanically attach the TSD body to the substrate or substrate-like support to form a composite assembly on the bit body in which the TSD body and substrate are held together in the composite assembly in the absence of any non-mechanical attachment therebetween.
A more complete understanding of the present embodiments and advantages thereof may be acquired by referring to the following description taken in conjunction with the accompanying drawings, which describe particular embodiments of the disclosure, in which like numbers refer to similar components, and in which:
In
The current disclosure provides a composite assembly including a TSD body mechanically attached to a carrier or substrate (which may also be referred to herein as simply a “carrier” or a “substrate”). The disclosure also provides methods of mechanically attaching a TSD body to a carrier or substrate to form a composite assembly. Attachment of the TSD body to a carrier or substrate may be sufficient to allow eventual conventional attachment of the TSD body to a drill bit or other component via the carrier or substrate of the composite assembly. The disclosure also includes drill bits including carrier assemblies and methods of forming such bits.
According to specific embodiments, the TSD body may be attached to the substrate by mechanical techniques that do not require adhesives, glue, brazes or welds between the substrate and the TSD body. Joining pins such as nails or rivets may be used to mechanically latch the two pieces together. “Joining pins” and “joining pin” as used herein may refer to one pin or multiple pins. The appropriate number of pins to be used in a given composite assembly may be determined by one of ordinary skill in the art using the disclosure contained herein. In selected embodiments, in addition to the mechanical attachment provided by joining pins, the TSD body and the substrate may also be non-mechanically attached, for instance by an infiltrant material. Regardless of whether any non-mechanical attachments are also present, the joining pins may provide sufficient mechanical attachment between the TSD and the substrate such that non-mechanical attachment between the two pieces is not necessary. The joining pins may be fixed to the TSD and substrate in various manners described in the following exemplary embodiments.
According to a first embodiment described in
Holes (15a) may be formed during the initial polycrystalline diamond growing process by the use of tungsten carbide or other extensions from the initial substrate on which the polycrystalline diamond is formed. This tungsten carbide or other material may later be removed during the leaching process used to convert the polycrystalline diamond to TSD.
Alternatively, holes (15a) may be formed by electric discharge machining (also called “EDM”) or by laser cutting.
TSD may be produced by any conventionally available methods. For example, it may be produced by the methods described in U.S. Pat. No. 4,224,380, U.S. Pat. No. 7,712,553, U.S. Pat. No. 6,544,308, or U.S. 20060060392 and related patents or applications, incorporated in material part by reference herein.
An alternative leaching method using a Lewis acid-based leaching agent may also be employed. In such a method, the PCD containing catalyst may be placed in the Lewis acid-based leaching agent until the desired amount of catalyst has been removed. This method may be conducted at lower temperature and pressure than traditional leaching methods. The Lewis acid-based leaching agent may include ferric chloride (FeCl3), cupric chloride (CuCl2), and optionally hydrochloric acid (HCl), or nitric acid (HNO3), solutions thereof, and combinations thereof. An example of such a leaching method may be found in U.S. Ser. No. 13/168,733 by Ram Ladi et al., filed Jun. 24, 2011, and titled “CHEMICAL AGENTS FOR LEACHING POLYCRYSTALLINE DIAMOND ELEMENTS,” incorporated by reference in its entirety herein.
In particular embodiments, the TSD body (20) may have a higher diamond density that is typically used in traditional polycrystalline diamond elements because such diamond densities will not interfere with attachment of the TSD body (20) to the substrate (30) or with the formation of a adequately leached element.
According to other embodiments, such as the example shown in
According to a particular embodiment, the dampening material may have a high coefficient of thermal conductivity, may be easily deformed, and may have a melting point higher than temperatures experienced during normal use of the composite assembly. For instance, the dampening material may primarily include a copper alloy. In some embodiments, it may include gold or silver.
According to a second embodiment, a composite assembly (10) as described in
According to a third embodiment, a composite assembly (10) as described in
Alloy material (27) and any other alloy material described herein may, in some embodiments, be any type of material commonly used for attachment of the substrate portion of polycrystalline diamond compacts to other components, such as drill bits. The alloy material (27) may be provided in any form, but in particular embodiments it may be in the form of a thin foil. In particular embodiments it may include a Group VIII metal or copper (Cu), gold (Au), or silver (Ag).
According to a fifth embodiment, shown in
According to a sixth embodiment, shown in
The composite assemblies of the present disclosure, such as those described in embodiments one to six may be in the form of a cutter for an earth-boring drill bit, such as a fixed cutter bit. In certain other embodiments the composite assemblies may be used in directing fluid flow or for erosion control in an earth-boring drill bit. For instance, they may be used in the place of abrasive structures described in U.S. Pat. No. 7,730,976, U.S. Pat. No. 6,510,906, or U.S. Pat. No. 6,843,333, each incorporated by reference herein in material part.
When used in a drill bit as cutters or for directing fluid flow or erosion control, composite assemblies may be attached to the bit body by brazing, soldering, press fitting, or other methods known in the art of drill bit manufacture. Composite assemblies may also be used in drill bits in place of other elements, such as bearings.
The composite assemblies of the present disclosure, such as those described in embodiments one to six, may also be used in other items containing polycrystalline diamond elements or other superabrasive elements, such as machine tools. In such embodiments, the composite assemblies may be attached using methods known for attachment of traditional polycrystalline diamond assemblies.
According to a seventh embodiment,
In
According to an eighth embodiment, another composite assembly (11) with interlocking surfaces is shown in
Interlocking surfaces 18a and 18b also help in assembly of the composite assembly (11) by facilitating alignment of the holes.
Although only exemplary embodiments of the invention are specifically described above, it will be appreciated that modifications and variations of these examples are possible without departing from the spirit and intended scope of the invention. For instance, specific embodiments in which composite assemblies are contained in drill bits as well as methods of forming such drill bits are described herein. One skilled in the art of making other devices containing polycrystalline diamond elements, such as machine tools, may adapt the devices and methods described herein for use with such other devices. Additionally, although generally planar TSD bodies are depicted in the figures, TSD bodies may take any shape. For instance, the TSD bodies may have thicker regions where high wear is expected, such as at the working surface.
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