The invention relates to systems and methods for cleaning and/or processing parts, processing liquids and applying megasonics to liquids. In particular, the invention relates to systems, generators, transducers, probes, signals and methods with frequencies in the megasonic range which support or enhance the application of megasonics energy within liquid.
For years, megasonics energy has been used in manufacturing and processing plants to clean and/or otherwise process objects within liquids. It is well known that objects may be efficiently cleaned or processed by immersion in a liquid and subsequent application of megasonics energy to the liquid. Prior art megasonic systems include transducers, built by bonding piezoelectric ceramics to radiating membranes such as quartz, sapphire, stainless steel, titanium, tantalum, boron nitride, silicon carbide, silicon nitride, aluminum and ceramics, and generators designed to stimulate the transducers at a resonant or antiresonant frequency. The transducers are mechanically coupled to a tank containing a liquid that is formulated to clean or process the object of interest. The amount of liquid is adjusted to partially or completely cover the object in the tank, depending upon the particular application. When the transducers are stimulated by the output signal from the generator to spatially oscillate, they transmit megasonics into the liquid, and hence to the object. The interaction between the megasonics-energized liquid and the object creates the desired cleaning or processing action. However, prior art megasonic systems lack optimum performance, are expensive and sometimes cause damage to the parts being cleaned or processed. The present invention improves performance of megasonic systems, reduces cost and minimizes damage caused by intense megasonic sound energy.
As used herein, megasonics means sound energy with a fundamental frequency from about 350 kHz to about 15 MHz. As used herein, ultrasonics means sound energy with a fundamental frequency from about 18 kHz to about 350 kHz. The term ultrasound as used herein is defined to mean the complete range of ultrasonic and megasonic frequencies, from about 18 kHz to about 15 MHz.
As used herein, “resonant transducer” means a transducer operated at a frequency or in a range of frequencies that correspond to a one-half wavelength (lambda) of sound in the transducer stack. “Harmonic transducer” means a transducer operated at a frequency or in a range of frequencies that correspond to 1 lambda, 1.5 lambda, 2 lambda or 2.5 lambda of sound, and so on, in the transducer stack. The harmonics of a practical physical structure are often not exact integer multiples of the fundamental frequency, the literature sometimes refer to these non-integer harmonics as overtones. Herein, harmonics will mean resonances higher in frequency than the fundamental resonant frequency. “Bandwidth” means the range of frequencies in a resonant or harmonic region of a transducer over which the acoustic power output of a transducer remains between 50% and 100% of the maximum value.
As used herein, a “delicate part” refers to those parts that are undergoing a manufacture, process, or cleaning operation within liquid subjected to ultrasound energy. By way of example, one delicate part is a semiconductor wafer which has extremely small features and which is easily damaged by cavitation implosion. Another delicate part is a modern jet engine turbine blade that can fracture if excited into resonant vibration. A delicate part often defines components in the computer industry, including disk drives, semiconductor components, and the like.
As used herein, “hz” refers to hertz which is cycles per second, “khz” refers to kilohertz and a frequency magnitude of one thousand hertz. “Mhz” refers to megahertz and a frequency magnitude of one million hertz.
As used herein, “successive frequencies” are two or more waveforms that are produced, one at a time, in a series fashion, where at least two different frequencies exist within the set of waveforms. At the output of a generator, these waveforms generally form an AC voltage. In an ultrasound tank, these waveforms are normally represented by an ultrasound wave in the liquid.
As used herein, successive frequencies are said to “sweep” when the period or the half period of two or more of the waveforms are unequal to each other.
Two types of megasonic transducers are used in this invention. The first is a Langevin type transducer sandwich that is described in detail because of the unique features that were invented to allow it to work at megasonic frequencies, the second type of megasonic transducer applicable to this invention is that transducer well know in the art, i.e., an unclamped piezoelectric ceramic bonded to a radiating member, usually a plate or tank constructed of materials such as quartz, stainless steel, titanium, etc.
Sweeping frequency generators change their output frequency through successive frequencies in a bandwidth, e.g., sweeping from the lowest frequency in a chosen bandwidth through the bandwidth to the highest frequency in the chosen bandwidth, then sweeping from this highest frequency through the bandwidth back to the lowest frequency. The function of time for these frequency changes is typically linear, but other functions of time, such as part of an exponential, are possible. As used herein, “sweep frequency” refers to the reciprocal of the time that it takes for successive frequencies to make a round trip, for example, change from one frequency through the other frequencies and back to the original frequency. Although sweep rate might technically be interpreted as the rate of change from one successive frequency to the next, the more common usage for sweep rate will be used herein; that is, “sweep rate” means the same as sweep frequency. It is generally undesirable to operate an ultrasound transducer at a fixed, single frequency (except for some megasonics transducers) because of the resonances created at that frequency. Therefore, an ultrasound generator can sweep the operational frequency through some or all of the available frequencies within the transducer's bandwidth at a “sweep rate.” Accordingly, particular frequencies have only short duration during the sweep cycle (i.e., the time period for sweeping the ultrasound frequency up and down through a range of frequencies within the bandwidth). “Sweep the sweep rate” or “double sweeping” or “dual sweep” refer to an operation of changing the sweep rate as a function of time. In accord with the invention, “sweeping the sweep rate” generally refers to the operation of sweeping the sweep rate so as to reduce or eliminate resonances generated at a single sweep frequency. “Random sweep rate” or “chaotic sweep rate” refer to sweep rates where the successive sweep rates are numbers that are described by no well-defined function, i.e., random or chaotic numbers.
A special case exists in the megasonics frequency range where driving megasonic transducers at a single frequency is preferred over sweeping frequency. This is for applications where the primary cleaning or processing mechanism is microstreaming and where transient cavitation is generally undesirable. These applications usually involve the cleaning or processing of disk type parts, such as semiconductor wafers and media disks used in hard disk drives. Other planar parts, such as flat panel displays are also applicable to non-sweeping frequency megasonics. For odd shaped parts where it is important to fill the tank with sound, sweeping megasonics is useful.
The present invention concerns the applied uses of ultrasound energy, and in particular the application and control of megasonics to clean and process parts within a liquid. Generally, in accord with the invention, one or more ultrasound generators drive one or more ultrasound transducers, or arrays of transducers, coupled to a liquid to clean and/or process the part. The liquid is preferably held within a tank; and the transducers mount on or within the tank to impart ultrasound into the liquid. In this context, the invention is particularly directed to one or more of the following aspects and advantages:
With parenthetical reference to the corresponding parts, portions or surfaces of the disclosed embodiment, merely for the purposes of illustration and not by way of limitation, the present invention provides an improved megasonic system (7002) for coupling megasonics to a liquid, comprising a megasonic transducer assembly of two or more megasonic transducers (7010) having a first piezoelectric ceramic (7011) bonded to a second piezoelectric ceramic (7012), a megasonic generator (7009) having a phase shift network (7032) and an electronic bridge circuit (7031) configured to selectively produce at least a first frequency of operation (7064) and a second frequency of operation (7067) and to selectively produce a driver signal characterized by a first frequency within a first frequency band (7069) and to selectively produce a second frequency within a second frequency band (7070) that is different from and non-contiguous to the first frequency band, the bridge circuit and phase shift network configured to provide an output voltage (7036) and an output current (7037), wherein the output voltage leads the output current by an angle (7046) that is greater than 0 degrees and less than about 90 degrees into the phase shift network, the phase shift network having a non-resistive output circuit (70100) having a Norton equivalent impedance (70122) near infinity at the first frequency of operation, a transmission line (70115) connecting the transducer assembly to the megasonic generator, at least one parallel inductor matching network (7088) between the transmission line and the transducer assembly, at least one sensor (7003) adapted to sense operating conditions of the megasonic system, a processor (7004) communicating with the sensor, non-volatile memory (7005) coupled to the processor, and the processor programmed to receive a signal from the sensor during operation of the megasonic system and to store the signal in the memory for access after operation of the megasonic system when the signal indicates a system error, fault or failure.
In another aspect, the invention also provides a megasonic transducer (7010) comprising a first piezoelectric ceramic (7011) with a positive polarity surface and a negative polarity surface opposite the positive surface, a second piezoelectric ceramic (7012) with a positive polarity surface and a negative polarity surface opposite the positive surface, a resonator plate (7015) having a first surface configured to couple megasonics to a liquid and a second surface, the negative polarity surface of the first piezoelectric ceramic bonded to the positive polarity surface of the second piezoelectric ceramic to form a megasonic piezoelectric assembly (14), and the negative polarity surface of the second piezoelectric ceramic bonded to the second surface of the resonator plate to form a megasonic transducer for producing multiple megasonic frequencies.
The invention also provides a megasonic transducer comprising a first piezoelectric ceramic having a positive polarity surface and a negative polarity surface opposite the positive surface, a second piezoelectric ceramic having a positive polarity surface and a negative polarity surface opposite the positive surface, a resonator plate having a first surface configured to couple megasonics to a liquid and having a second surface, the positive polarity surface of the first piezoelectric ceramic bonded to the negative polarity surface of the second piezoelectric ceramic to form a megasonic piezoelectric assembly, and the positive polarity surface of the second piezoelectric ceramic bonded to the second surface of the resonator plate to form a megasonic transducer for producing multiple megasonic frequencies.
The invention also provides an ultrasound system (7030) comprising an electronic bridge circuit (7031) that provides an operational frequency or operational bandwidth of frequencies and has a first output terminal (7035) and a second output terminal (7034) configured to provide an output voltage (7036) and an output current (7037), a phase shift network (7032) having a first input terminal (7038), a second input terminal (7039), a first output terminal (7040) and a second output terminal (7041), the first output terminal of the bridge circuit coupled to the first input terminal of the phase shift network and the second output terminal of the bridge circuit coupled to the second input terminal of the phase shift network, an ultrasound transducer (7033) having a first input terminal (7042) and a second input terminal (7043), the first output terminal of the phase shift network coupled to the first input terminal of the transducer and the second output terminal of the phase shift network coupled to the second input terminal of the transducer, the bridge circuit, the phase shift network and the transducer configured such that the output voltage leads the output current by an angle (7046) that is greater than 0 degrees and less than about 90 degrees for the operational frequency or bandwidth of frequencies.
The operational bandwidth of frequencies may be the frequencies over which the transducer sweeps (7069, 7070). The electronic bridge circuit may comprise a loop inductance (7050, 7053) of between about 3 nanohenrys and about 27 nanohenrys and at least one gate drive dead time (7049, 7052) of between about 97 nanoseconds and about 787 nanoseconds. The electronic bridge circuit may also comprise at least one power MOSFET transistor as a switching device. The output voltage may lead the output current by an angle that is greater in a middle region of the operational bandwidth of frequencies than an angle at an end region of the operational bandwidth of frequencies and the output voltage may lead the output current by an angle that varies as a function g(f) of the frequency over the operational bandwidth of frequencies to produce a specified function h(f) for power versus frequency over the operational bandwidth of frequencies. The system may further comprise a phase lock loop (7079, 7080) controlling the operational bandwidth of frequencies. The transducer may be a megasonic transducer assembly.
The invention also provides a method of delivering multiple megasonic frequencies to a liquid, comprising the steps of (a) providing a liquid, (b) providing a megasonic transducer or assembly of megasonic transducers configured to selectively produce megasonic energy in the liquid at a first frequency (7064) within a first frequency band (7069) and at a second frequency (7067) within a second frequency band (7070) that is different from and non-contiguous to the first frequency band, (c) coupling the transducer to the liquid and (d) driving the transducer with a megasonics generator (7009) configured to produce the first frequency and the second frequency.
The transducer may be configured to selectively produce megasonic energy in the liquid at sweeping frequencies within the first frequency band and may be configured to selectively produce megasonic energy in the liquid at sweeping frequencies within the second frequency band. The megasonic generator may be configured to selectively produce the sweeping frequencies in the first frequency band and to produce the sweeping frequencies in the second frequency band.
The invention also provides a method of delivering multiple megasonic frequencies to a liquid, comprising the steps of (a) providing a liquid, (b) providing a megasonic transducer or assembly of megasonic transducers configured to selectively produce megasonic energy in the liquid at a single frequency (7064) within a first frequency band (7069) and at sweeping frequencies in the first frequency band, (c) coupling the transducer to the liquid, and (d) driving the transducer with a megasonics generator (7009) configured to produce the single frequency and the sweeping frequencies.
The invention also provides a megasonic system for coupling megasonics to a liquid, comprising a megasonic transducer adapted to couple to a liquid and configured and arranged so as to produce megasonics in the liquid at frequencies within at least a first frequency band and a second frequency band, a megasonic generator coupled to the transducer and configured and arranged to produce a driver signal to the megasonic transducer at one or more frequencies within each of the first and second frequency bands. The second frequency band may be different from and non-contiguous to the first frequency band. The transducer may comprise a first piezoelectric ceramic (7011) with a positive polarity surface and a negative polarity surface opposite the positive surface, a second piezoelectric ceramic (7012) with a positive polarity surface and a negative polarity surface opposite the positive surface, a resonator plate (7015) having a first surface configured to couple megasonics to a liquid and a second surface, the negative polarity surface of the first piezoelectric ceramic bonded to the positive polarity surface of the second piezoelectric ceramic to form a megasonic piezoelectric assembly (7014), and the negative polarity surface of the second piezoelectric ceramic bonded to the second surface of the resonator plate to form a megasonic transducer for producing multiple megasonic frequencies. The transducer may comprise a first piezoelectric ceramic having a positive polarity surface and a negative polarity surface opposite the positive surface, a second piezoelectric ceramic having a positive polarity surface and a negative polarity surface opposite the positive surface, a resonator plate having a first surface configured to couple megasonics to a liquid and having a second surface, the positive polarity surface of the first piezoelectric ceramic bonded to the negative polarity surface of the second piezoelectric ceramic to form a megasonic piezoelectric assembly, and the positive polarity surface of the second piezoelectric ceramic bonded to the second surface of the resonator plate to form a megasonic transducer for producing multiple megasonic frequencies. The transducer may have a resonance frequency and an anti-resonance frequency within the first frequency band, and the frequency within the first frequency band has a value that is greater than the resonance frequency and less than the anti-resonance frequency. The generator and transducer may be configured and arranged to produce sweeping frequencies within at least one of the frequency bands, and the frequency band may be the first frequency band, the transducer may have a resonance frequency and an anti-resonance frequency within the first frequency band, and the sweeping frequencies may be greater than the resonance frequency and less than the anti-resonance frequency.
The invention also provides a system for coupling megasonics to a liquid, comprising a megasonic transducer adapted to couple to a liquid and configured and arranged so as to produce megasonics in the liquid at a first frequency (7064) within a first frequency band (7069) and at sweeping frequencies in the first frequency band, a megasonic generator coupled to the transducer and configured and arranged to produce a driver signal to the megasonic transducer at the first frequency and at the sweeping frequencies. The predominant form of cavitation in the liquid may be stable cavitation when the megasonics is at the first frequency and the predominant form of cavitation in the liquid may be transient cavitation when the megasonics is at the sweeping frequencies. The transducer may have a resonance frequency and an anti-resonance frequency within the first frequency band, and the frequency within the first frequency band may have a value that is greater than the resonance frequency and less than the anti-resonance frequency. The transducer may have a resonance frequency and an anti-resonance frequency within the first frequency band, and the sweeping frequencies may be greater than the resonance frequency and less than the anti-resonance frequency.
The invention also provides a multiple frequency megasonic generator comprising an electronic bridge circuit (7031) configured to selectively produce at least a first frequency of operation (7064) and a second frequency of operation (7067) and to selectively produce a driver signal characterized by a first frequency within a first frequency band (7069) and to selectively produce a driver signal characterized by a second frequency within a second frequency band (7070) that is different from and non-contiguous to the first frequency band, and a controller for generating the first frequency within the first frequency band during a first time period and for generating the second frequency within the second frequency band during a second time period different from and non-contiguous to the first time period. The bridge circuit may be a half bridge circuit. The electronic bridge circuit may be configured to selectively produce a driver signal characterized by sweeping frequencies within at least one of the frequency bands. The electronic bridge circuit may be configured to selectively produce a driver signal characterized by sweeping frequencies within the first frequency band and to selectively produce a driver signal characterized by sweeping frequencies within the second frequency band. The electronic bridge circuit (7031) may have a first output terminal (7035) and a second output terminal (7034) configured to provide an output voltage (7036) and an output current (7037) and may further comprise a phase shift network (7032) having a first input terminal (7038), a second input terminal (7039), a first output terminal (7040), and a second output terminal (7041), the first output terminal of the bridge circuit coupled to the first input terminal of the phase shift network and the second output terminal of the bridge circuit coupled to the second input terminal of the phase shift network, an ultrasound transducer (7033) having an first input terminal (7042) and a second input terminal (7043), the first output terminal of the phase shift network coupled to the first input terminal of the transducer and the second output terminal of the phase shift network coupled to the second input terminal of the transducer, the bridge circuit, the phase shift network and the transducer configured such that the output voltage leads the output current by an angle (7046) that is greater than 0 degrees and less than about 90 degrees for at least one of the frequencies. The transducer may be a megasonic transducer assembly. The electronic bridge circuit may comprise a loop inductance (7050, 7053) of between about 3 nanohenrys and about 27 nanohenrys; and at least one gate drive dead time (7049, 7052) of between about 97 nanoseconds and about 787 nanoseconds. The electronic bridge circuit may be configured to selectively produce a driver signal characterized by sweeping frequencies within at least one of the frequency bands and the output voltage leads the output current by an angle that is greater in a middle region of the sweeping frequencies than the angle at an end region of the sweeping frequencies. The output voltage may lead the output current by an angle (7046) that is greater than 0 degrees and less than about 90 degrees for at least one of the frequency bands. The multiple frequency megasonic generator may further comprise a phase shift network having a non-resistive output circuit (70100) with a Norton equivalent impedance (70122) near infinity at the first frequency of operation. The multiple frequency megasonic generator may further comprise a transducer, a transmission line (70115) between the transducer to the megasonic generator, and at least one parallel inductor matching network (7088) between the transmission line and the transducer. The transducer may have a resonance frequency and an anti-resonance frequency within the first frequency band, and the frequency within the first frequency band may have a value that is greater than the resonance frequency and less than the anti-resonance frequency.
The invention also provides a method of delivering transient megasonic cavitation and stable megasonic cavitation to a liquid, comprising the steps of (a) providing a liquid, (b) providing a megasonic transducer or assembly of megasonic transducers configured to selectively produce megasonic energy in the liquid at single frequencies and at sweeping frequencies within a first frequency band (7069), (c) coupling the transducer to the liquid, (d) driving the transducer with a megasonics generator (7009) configured to produce substantially all of a range of frequencies within the frequency band, and (e) controlling the generator so as to produce megasonic sweeping frequencies that cause predominantly transient cavitation in the liquid during a first time period and so as to produce a megasonic frequency that causes predominantly stable cavitation during a second time period different from and non-contiguous to the first time period.
The invention also provides an ultrasound system comprising a generator for generating a driving signal to power an ultrasound transducer assembly, at least one sensor (7003) adapted to sense operating conditions of the generator, a processor (7004) communicating with the sensor, non-volatile memory (7005) coupled to the processor, and the processor programmed to receive a signal from the sensor during operation of the generator and to store the signal in the memory for access after operation of the generator when the signal indicates a system error, fault or failure, whereby a history of the faults, errors or failures is available after the generator is powered down. The processor may be selected from a group consisting of digital integrated circuits, programmable logic controllers or computers commonly referred to as microprocessors, microcontrollers, CPUs, PICs, PLCs, PCs and microcomputers. The non-volatile memory may be selected from a group consisting of flash memory, EEPROM, magnetic memory and optical memory. The ultrasound transducer assembly may be configured and arranged to couple megasonics to liquid, to couple ultrasonics to liquid, to couple ultrasonics to solid, or to couple ultrasonics to a gas. The non-volatile memory may be RAM powered by a battery. The fault, error or failure may be selected from a group consisting of a low power line voltage condition, a high power line current draw, an over voltage power line condition, an over temperature condition, an over voltage ultrasound driving signal, an over current ultrasound driving signal, an under voltage ultrasound driving signal, an under current ultrasound driving signal, an unlocked PLL condition, an out of specification phase shift condition, an ultrasound drive frequency over a maximum limit, an ultrasound drive frequency under a minimum limit, an excessive reflected power condition, an open ultrasound transducer assembly, a shorted ultrasound transducer assembly, an ultrasound transducer assembly over a maximum capacitance value, an ultrasound transducer assembly under a minimum capacitance value, a high impedance ultrasound transducer assembly, a low impedance ultrasound transducer assembly, a missing interlock, incorrect output power, loss of closed loop output power control, a start up sequence error, an aborted start up sequence, and a shut down sequence error.
Thus, the general object of the invention is to provide a system for coupling megasonics with a liquid at multiple megasonic frequencies and/or sweeping frequencies.
Another object is to provide a transducer for megasonics at multiple frequencies and/or sweeping frequencies.
Another object is to provide a generator for driving at multiple megasonic frequencies and/or sweeping frequencies.
Another object is to provide a generator for driving between a resonance and anti-resonance frequency.
Another object is to provide an ultrasound generator having a phase shift network that provides voltage leading current.
Another object is to provide an inductor for compensating for changes in transducer capacitance.
Another object is to provide a system for individually controlling piezoelectric ceramic segments.
Another object is to provide an inductor matching network.
Another object is to provide a gate drive for power control.
Another object is to provide a system with near infinite output.
Another object is to provide a system having a transmission line with increased stability.
Another object is to provide an ultrasound generator system having non-volatile storage of fault, error and failure codes.
By utilizing harmonics of certain clamped ultrasound transducers, the invention generates, in one aspect, ultrasound within the liquid in a frequency range of between about 100 khz to 350 khz (i.e., “microsonic” frequencies). This has certain advantages over the prior art. In particular, unlike prior art ultrasonic systems which operate at less than 100 khz, the invention eliminates or greatly reduces damaging cavitation implosions within the liquid. Preferably, the application of microsonic frequencies to liquid occurs simultaneously with a sweeping of the microsonic frequency within the transducer's harmonic bandwidth. That is, microsonic transducers (clamped harmonic transducers) are most practical when there is a sweep rate of the applied microsonic frequency. This combination reduces or eliminates (a) standing waves within the liquid, (b) other resonances, (c) high energy cavitation implosions, and (d) non-uniform sound fields, each of which is undesirable for cleaning or processing delicate parts.
The ultrasound transducers or arrays of the invention typically have a finite bandwidth associated with the range of frequencies about a resonant or harmonic frequency. When driven at frequencies within the bandwidth, the transducers generate acoustic energy that is coupled into the liquid. In one aspect, the invention drives the transducers such that the frequency of applied energy has a sweep rate within the bandwidth; and that sweep rate is also varied so that the sweep rate is substantially non-constant during operation. For example, the sweep rate can change linearly, randomly, chaotically or as some other function of time. In this manner, the invention reduces or eliminates resonances which are created by transducers operating with a single sweep rate, such as provided in the prior art.
At least one ultrasound generator of the invention utilizes amplitude modulation (AM). However, unlike the prior art, this AM generator operates by selectively changing the AM frequency over time. In a preferred aspect of the invention, the AM frequency is swept through a range of frequencies which reduce or eliminate low frequency resonances within the liquid and the part being processed. Accordingly, the AM frequency is swept through a range of frequencies; and this range is typically defined as about 10-40% of the optimum AM frequency. The optimum AM frequency is usually between about 1 hz and 10 khz. Therefore, for example, if the optimum AM frequency is 1 khz, then the AM frequency is swept through a frequency range of between about 850 hz and 1150 hz. In addition, the rate at which these frequencies are varied is usually less than about 1/10th of the optimum AM frequency. In this example, therefore, the AM sweep rate is about 100 hz. These operations of sweeping the AM frequency through a range of frequencies and at a defined AM sweep rate reduce or eliminate unwanted resonances which might otherwise occur at the optimum AM frequency. In another aspect of the invention, for delicate parts with very low frequency resonances, the AM frequency is changed randomly or chaotically or the AM sweep rate is swept at a function of time with a frequency about 1/10th of the AM sweep rate. This random or chaotic AM frequency in combination with a random or chaotic sweep rate of provides elimination of low frequencies in a cleaning liquid, therefore, eliminating low frequency resonances. This combination is sometimes referred to as CRAM.
The invention can utilize several tanks, transducers and generators simultaneously to provide a wet bath of different chemistries for the delicate part. In one aspect, when two or more generators are operating at the same time, the invention synchronizes their operation to a common FM signal so that each generator can be adjusted, through AM, to control the process characteristics within the associated tank. In this manner, undesirable beating effects or cross coupling between multiple tanks are reduced or eliminated. In a preferred aspect, a master generator provides a common FM signal to the other generators, each operating as a slave generator coupled to the master generator, and each slave generator provides AM selectively. In addition, because the transducers in the several tanks are sometimes swept through the frequencies of the transducer's bandwidth, the FM control maintains overall synchronization even though varying AM is applied to the several transducers. The multi-generator FM synchronization also applies to single tank ultrasound systems. That is, the invention supports the synchronized operation of a plurality of generators that are connected to a single tank. In this case, each generator has an associated harmonic transducer array and is driven with a common FM signal and AM signal so that the frequencies within the tank are synchronized, in magnitude and phase, to reduce or eliminate unwanted resonances which might otherwise occur through beating effects between the multiple generators and transducers.
In another aspect, the invention utilizes two or more transducers, in combination, to broaden the overall bandwidth of acoustical energy applied to the liquid around the primary frequency or one of the harmonics. For example, the invention of one aspect has two clamped transducers operating at their first, second, third, or fourth harmonic frequency between about 100 khz and 350 khz. The center harmonic frequency of each is adjusted so as to be different from each other. However, their bandwidths are made to overlap such that an attached generator can drive the transducers, in combination, to deliver ultrasound to the liquid in a broader bandwidth.
In a preferred aspect, two or more transducers, or transducer arrays, operate at unique harmonic frequencies and have finite bandwidths that overlap with each of the other transducers. If, for example, each transducer has a bandwidth of 4 khz, then two such transducers can approximately provide a 8 khz bandwidth, and three such transducers can approximately provide a 12 khz bandwidth, and so on.
In one aspect, the invention provides a single tank system which selects a desired frequency, or range of frequencies, from a plurality of connected ultrasound generators. Specifically, two or more generators, each operating or optimized to generate a range of frequencies, are connected to a mux; and the system selects the desired frequency range, and hence the right generator, according to the cavitation implosion energy that is desired within the tank chemistry.
The invention has additional and sometimes greater advantages in systems and methods which combine one or more of the features in the above paragraphs.
The following patents, each incorporated herein by reference, provide useful background to the invention in the area of ultrasound generators: U.S. Pat. Nos. 3,152,295; 3,293,456; 3,629,726; 3,638,087; 3,648,188; 3,651,352; 3,727,112; 3,842,340; 4,044,297; 4,054,848; 4,069,444; 4,081,706; 4,109,174; 4,141,608; 4,156,157; 4,175,242; 4,275,363; and 4,418,297. Further, U.S. Pat. Nos. 4,743,789 and 4,736,130 provide particularly useful background in connection with ultrasound generators that are suitable for use with certain aspects of the invention, and are, accordingly incorporated herein by reference.
Clamped ultrasound transducers suitable for use with the invention are known in the art. For example, the following patents, each incorporated herein by reference, provide useful background to the invention: U.S. Pat. Nos. 3,066,232; 3,094,314; 3,113,761; 3,187,207; 3,230,403; 3,778,758; 3,804,329 and RE 25,433.
Techniques for mounting or affixing transducers within the tank, and of arranging the transducer and/or tank geometry are, for example, described in U.S. Pat. Nos. 4,118,649; 4,527,901; 4,543,130; and 4,836,684. Each of these patents is also incorporated by reference.
Single chamber ultrasound processing systems are described, for example, in U.S. Pat. Nos. 3,690,333; 4,409,999; 5,143,103; and 5,201,958. Such systems provide additional background to the invention and are, accordingly, incorporated herein by reference.
In one aspect, the invention provides a system for delivering broadband ultrasound to liquid. The system includes first and second ultrasound transducers. The first transducer has a first frequency and a first ultrasound bandwidth, and the second transducer has a second frequency and a second ultrasound bandwidth. The first and second bandwidths are overlapping with each other and the first frequency is different from the second frequency. An ultrasound generator drives the transducers at frequencies within the bandwidths. Together, the first and second transducers and the generator produce ultrasound within the liquid and with a combined bandwidth that is greater than either of the first and second bandwidths.
In applications operating below about 700 khz, the transducers are preferably clamped so as to resist material strain and fatigue. In another aspect, each of the first and second frequencies are harmonic frequencies of the transducer's base resonant frequency. In one aspect, these harmonic frequencies are between about 100 khz and 350 khz.
In applications operating above about 400 khz, the transducers can be unclamped. In another aspect, each of the first and second frequencies are harmonic frequencies of the transducer's base resonant frequency. In one aspect, these harmonic frequencies are between about 400 khz and 7 Mhz.
The frequency range between about 400 khz and 700 khz can be produced by either clamped or unclamped transducers, usually the clamped designs are preferable for sweeping frequencies and the unclamped designs are preferable for non-sweeping frequencies, however, this invention provides for sweeping unclamped megasonic transducers and for driving clamped transducers at single frequencies.
Another aspect of the invention provides a system for delivering megasonics to liquid. In such a system, one or more megasonic transducers have an operating frequency within a megasonic bandwidth. A megasonic generator drives the transducers at frequencies within the bandwidth, and also changes the sweep rate of the frequency continuously so as to produce non-resonating megasonics within the liquid.
Preferably, the generator of the invention changes the sweep rate frequency in one of several ways. In one aspect, for example, the sweep rate is varied as a function of time. In another aspect, the sweep rate is changed randomly or chaotically. Typically, the sweep rate frequency is changed through a range of frequencies that are between about 10-50% of the optimum sweep rate frequency. The optimum sweep rate frequency is usually between about 1 hz and 1.2 khz; and, therefore, the range of frequencies through which the sweep rate is varied can change dramatically. By way of example, if the optimum sweep rate is 500 hz, then the range of sweep rate frequencies is between about 400 hz and 600 hz; and the invention operates by varying the sweep rate within this range linearly, randomly or chaotically, or as a function of time, so as to optimize processing characteristics within the liquid.
The invention further provides a system for delivering amplitude modulated megasonics to liquid. This system includes one or more megasonic transducers, each having an operating frequency within a megasonic bandwidth. An amplitude modulated megasonic generator drives the transducers at frequencies within the bandwidth. A generator subsystem also changes the modulation frequency of the AM, continually, so as to produce megasonics within the liquid and to prevent low frequency resonances at an AM frequency.
Preferably, the subsystem sweeps the AM frequency at a sweep rate between about 1 hz and 100 hz. For extremely sensitive parts and/or tank chemistries, the invention can further sweep the AM sweep rate as a function of time so as to eliminate possible resonances which might be generated by the AM sweep rate frequency. This sweeping of the AM sweep rate occurs for a range of AM sweep frequencies generally defined by 10-40% of the optimum AM sweep rate. For example, if the optimum AM sweep rate is 150 hz, then one aspect of the invention changes the AM sweep rate through a range of about 130 hz and 170 hz.
In still another aspect, a system of the invention can include two or more megasonic generators that are synchronized in magnitude and phase so that there is substantially zero frequency difference between signals generated by the generators. Preferably, a timing signal is generated between the generators to synchronize the signals. In one aspect, a FM generator provides a master frequency modulated signal to each generator to synchronize the signals from the generators.
A generator of the invention can also be frequency modulated over a range of frequencies within the bandwidth of each transducer. In another aspect, the frequency modulation occurs over a range of frequencies within the bandwidth of each transducer, and the generator is amplitude modulated over a range of frequencies within the bandwidth of each transducer.
The systems of the invention generally include a chamber for holding the solution or liquid which is used to clean or process objects therein. The chamber can include, for example, material such as 316L stainless steel, 304 stainless steel, maraging steel, polytetrafluoroethylene, fluorinated ethylene propylene, polyvinylidine fluoride, perfluoro-alkoxy, polypropylene, polyetheretherketone, tantalum, Teflon coated stainless steel, titanium, hastalloy, quartz and mixtures thereof.
The invention also provides a method of delivering broadband megasonic to liquid, including the steps of: driving a first megasonic transducer with a generator at a first frequency and within a first megasonic bandwidth, and driving a second megasonic transducer with the generator at a second frequency within a second megasonic bandwidth that overlaps at least part of the first bandwidth, such that the first and second transducers, in combination with the generator, produce megasonics within the liquid and with a combined bandwidth that is greater than any of the first and second bandwidths.
Preferably, the method includes the step of arranging the bandwidths to overlap so that the transducers and generator produce megasonic energy, at each frequency, that is within a factor of two of megasonic energy produced by the transducers and generator at any other frequency within the combined bandwidth.
The application of broadband megasonics has certain advantages. First, it increases the useful bandwidth of multiple transducer assemblies so that the advantages to sweeping megasonics is enhanced. The broadband megasonics also gives more megasonic intensity for a given power level because there are additional and different frequencies spaced further apart in the megasonic bath at any one time. Therefore, there is less sound energy cancellation because only frequencies of the same wavelength, the same amplitude and opposite phase cancel effectively.
A method of the invention provides the following steps: coupling one or more megasonic transducers to the liquid, driving, with a generator, the transducers to an operating frequency within an megasonic bandwidth, the transducers and generator generating megasonics within the liquid, changing the frequency within the bandwidth at a sweep rate, and continuously varying the sweep rate as a function of time so as to reduce low frequency resonances.
In other aspects, the sweep rate is varied according to one of the following steps: sweeping the sweep rate as a function of time; linearly sweeping the sweep rate as a function of time; and randomly or chaotically sweeping the sweep rate. Usually, the optimum sweep frequency is between about 1 hz and 1.2 khz, and therefore, in other aspects, the methods of the invention change the sweep rate within a range of sweep frequencies centered about an optimum sweep frequency. Typically, this range is defined by about 10-50% of the optimum sweep frequency. For example, if the optimum sweep frequency is 800 hz, then the range of sweep frequencies is between about 720 hz and 880 hz. Further, and in another aspect, the rate at which the invention sweeps the sweep rate within this range is varied at less than about 1/10th of the optimum frequency. Therefore, in this example, the invention changes the sweep rate at a rate that is less than about 80 hz.
Another method of the invention provides for the steps of (a) generating a drive signal for one or more megasonic transducers, each having an operating frequency within an megasonic bandwidth, (b) amplitude modulating the drive signal at a modulation frequency, and (c) sweeping the modulation frequency, selectively, as to produce megasonics within the liquid.
The invention is particularly useful as a megasonic system which couples acoustic energy into a liquid for purposes of cleaning parts. The invention can provide many sound frequencies to the liquid by sweeping the sound through the bandwidth of the transducers. This provides at least three advantages: the standing waves causing cavitation hot spots in the liquid are reduced or eliminated; part resonances within the liquid at megasonic frequencies are reduced or eliminated; and the megasonic activity in the liquid builds up to a higher intensity because there is less cancellation of sound waves.
In one aspect, the invention provides a megasonic bath with transducers having at least two different resonant frequencies. In one configuration, the resonant frequencies are made so that the bandwidths of the transducers overlap and so that the impedance versus frequency curve for the paralleled transducers exhibit maximum flatness in the resonant region.
In another aspect, the invention provides a method and associated circuitry which constantly changes the sweep rate of a megasonic transducer within a range of values that is in an optimum process range. For example, one exemplary process can have an optimum sweep rate in the range 380 hz to 530 hz. In accord with one aspect of the invention, this sweep rate constantly changes within the 380 hz to 530 hz range so that the sweep rate does not set up resonances within the tank and set up a resonance at that rate.
The invention provides for several methods to change the sweep rate. One of the most effective methods is to generate a random or chaotic change in sweep rate within the specified range. A simpler method is to sweep the sweep rate at some given function of time, e.g., linearly. One problem with sweeping the sweep rate is that the sweeping function of time has a specific frequency which may itself cause a resonance. Accordingly, one aspect of the invention is to sweep this time function; however, in practice, the time function has a specific frequency lower than the lowest resonant frequency of the semiconductor wafer or delicate part, so there is little need to eliminate that specific frequency.
Another aspect of the invention solves the problem of delicate part resonance at an amplitude modulation frequency by randomly or chaotically changing or sweeping the frequency of the amplitude modulation within a bandwidth of amplitude modulation frequencies that satisfy the process specifications. For cases where substantially all of the low frequencies must be eliminated, random or chaotic changes of the modulation frequency are preferred. For cases where there are no resonances in a part below a specified frequency, the amplitude modulation frequency can be swept at a frequency below the specified frequency.
Random or chaotic changing or sweeping of the amplitude modulation frequency inhibits low frequency resonances because there is little repetitive energy at a frequency within the resonant range of the delicate part or semiconductor wafer. Accordingly, a resonant condition does not build up, in accord with the invention, providing obvious advantages.
In one aspect, the invention also provides an adjustable megasonic generator. One aspect of this generator is that the sweep rate frequency and the amplitude modulation pattern frequency are randomly or chaotically changed or swept within the optimum range for a selected process. Another aspect is that the generator drives an expanded bandwidth piezoelectric transducer array at a fundamental or harmonic frequency from 351 khz to 7 Mhz.
In another aspect of the invention, an array of transducers is used to transmit sound into a liquid at its fundamental frequency, e.g., 430 khz, and at a harmonic frequency, e.g., 1290 khz. The outputs of generators which have the transducer resonant frequencies and harmonic frequencies are connected through relays to the transducer array. One generator with the output frequency that most closely producers the optimum parameters for the current process is switched to the transducer array.
In yet another aspect, the invention reduces or eliminates low frequency beat resonances created by multiple generators by synchronizing the sweep rates (both in magnitude and in phase) so that there is zero frequency difference between the signals coming out of multiple generators. In one aspect, the synchronization of sweep rate magnitude and phase is accomplished by sending a timing signal from one generator to each of the other generators. In another aspect, a master FM signal is generated that is sent to each “slave” power module, which amplifies the master FM signal for delivery to the transducers. At times, the master and slave aspect of the invention also provides advantages in eliminating or reducing the beat frequency created by multiple generators driving a single tank.
However, when multiple generators are driving different tanks in the same system, this master and slave aspect may not be acceptable because the AM of the FM signal is usually different for different processes in the different tanks. Accordingly, and in another aspect, a master control is provided which solves this problem. The master control of the invention has a single FM function generator (sweeping frequency signal) and multiple AM function generators, one for each tank. Thus, every tank in the system receives the same magnitude and phase of sweep rate, but a different AM as set on the control for each generator.
The invention also provides other advantages as compared to the prior art's methods for frequency sweeping megasonics within the transducer's bandwidth. Specifically, the invention provides a sweeping of the sweep rate, within the transducer's bandwidth, such that low frequency resonances are reduced or eliminated. Prior art frequency sweep systems had a fixed sweep frequency that is selectable for a given application. One problem with such prior art systems is that the single low frequency can set up a resonance in a delicate part, for example, a read-write head for a hard disk drive.
The invention also provides advantages in that the sweep frequency of the sweep rate can be adjusted to conditions within the tank, or to the configuration of the tank or transducer, or even to a process chemistry.
The invention also has certain advantages over prior art single chamber megasonic systems. Specifically, the methods of the invention, in certain aspects, use different frequency megasonics for different process conditions. According to other aspects of the invention, this process is enhanced by selecting the proper megasonic generator frequency that is supplied at the fundamental or harmonic frequency of the transducers bonded to the single megasonic chamber.
In another aspect, a multi-frequency megasonic generator is provided. In one aspect, the generator includes means for switching the frequency of the output signal selectively. The switching means operates such that little or no intermediate frequencies are output during transition between one frequency and another.
Another multi-frequency generator of the invention includes two or more circuits which independently create megasonic frequencies. By way of example, one circuit can generate 40 khz megasonic energy; while another circuit can generate 104 khz energy. A switching network connects the plurality of circuits such that the generator is shut down and relay switching takes place in a zero voltage condition. As above, therefore, the switching occurs such that little or no intermediate frequencies are output during transition between one center frequency and another.
In still another aspect, a two stage megasonic processing system is provided. The system includes (a) one or more transducers with a defined megasonic bandwidth defined by an upper frequency and a lower frequency. The system further includes (b) a frequency generator for driving the transducers from the upper frequency to the lower frequency over a selected or variable time period and (c) a process tank connected with the transducers so as to generate megasonic energy within the tank at frequencies defined by the generator. During a given cycle, the generator drives the transducers from the upper frequency to the lower frequency. Once the lower frequency is reached, a frequency control subsystem controls the generator so as to drive the transducers again from upper to lower frequency and without driving the transducers from lower to upper frequencies. In this manner, only decreasing frequencies—per cycle—are imparted to process chemistries. The system thus provides for removing contamination as the downward cycling frequencies cause the acoustic energy to migrate in an upwards motion inside the tank which in turn pushes contamination upwards and out of the tank.
In another aspect of the invention, the two stage megasonic processing system includes means for cycling from upper-to-lower frequencies every half cycle. That is, once the transducers are driven from upper to lower frequencies over a first half cycle, the generator recycles such that the next half cycle again drives the transducers from upper to lower frequencies. Alternatively, after driving the transducers from upper to lower frequencies for a first half cycle, the system inhibits the flow of energy into the tank over a second half cycle.
The two stage megasonic processing systems of the invention can be continuous or intermittent. That is, in one preferred aspect, the system cycles from upper to lower frequencies and then from lower to upper frequencies in a normal mode; and then only cycles from upper to lower frequencies in a contamination removing mode.
In still another aspect, the invention provides a sensing system which is disposed within the process liquid and monitors certain process characteristics within an ultrasonic process tank. The sensing system preferably is a sensing probe, which includes an enclosure, e.g., made from polypropylene, Teflon or similar material, that transmits megasonic energy therethrough. The enclosure houses a liquid (sample liquid) that is responsive to the megasonics energy in some manner such as to create free radicals and ions from which conductivity can be measured. This conductivity provides an indication as to the number of cavitation implosions per unit volume being imparted to the process chemistry within the tank. A conduit from the enclosure to a location external to the process chemistry is used to measure the characteristics of the sample liquid in response to the energy. In other aspects, a thermocouple is included within the enclosure and/or on an external surface of the enclosure (i.e., in contact with the process chemistry) so as to monitor temperature changes within the enclosure and/or within the process chemistry. According to one aspect, the sample liquid is different from the process liquid. In another aspect, the sample liquid also has the characteristic that it produces chemiluminescence when exposed to cavitation and a photo sensor is enclosed within the sample liquid. Other characteristics within the tank and/or enclosure can be monitored over time so as to create time-varying functions that provide other useful information about the characteristics of the processes within the tank.
In one aspect, the invention provides an megasonic system for moving contaminants upwards within a processing tank, which holds process liquid. A megasonic generator produces megasonic drive signals through a range of frequencies as defined by an upper frequency and a lower frequency. A transducer connected to the tank and the generator responds to the drive signals to impart megasonic energy to the liquid. A controller subsystem controls the generator such that the drive signals monotonically change from the upper frequency to the lower frequency to drive contaminants upwards through the liquid.
In one aspect, the controller subsystem cyclically produces the drive signals such that the generator sweeps the drive signals from the upper frequency to the lower frequency over a first half cycle, and from the lower frequency to the higher frequency over a second one half cycle. The subsystem of this aspect inhibits the drive signals over the second half cycle to provide a quiet period to the liquid.
In other aspects, the first and second one-half cycles can have different time periods. Each successive one-half cycle can have a different time period such that a repetition rate of the first and second half cycles is non-constant. Or, the first one-half cycle can have a fixed period and the second one-half cycle can be non-constant.
In one aspect, the first half cycle corresponds to a first time period and the second one half cycle corresponds to a second time period, and the subsystem varies the first or second time periods between adjacent cycles.
Preferably, the subsystem includes means for shutting the generator off during the second one half cycle.
In another aspect, the subsystem includes an AM modulator for amplitude modulating the drive signals at an AM frequency. In one aspect, the AM modulator sweeps the AM frequency. In another aspect, the AM modulator sweeps the AM frequency from a high frequency to a low frequency and without sweeping the AM frequency from the low frequency to the high frequency. The subsystem can further inject a quiet or degas period before each monotonic AM frequency sweep.
In another aspect, there is provided an megasonic system for moving contaminants upwards within a processing tank, including: a processing tank for holding process liquid, a megasonic generator for generating megasonic drive signals through a range of frequencies defined between an upper frequency and a lower frequency, at least one transducer connected to the tank and the generator, the transducer being responsive to the drive signals to impart megasonic energy to the liquid, and a controller subsystem for controlling the generator through one or more cycles, each cycle including monotonically sweeping the drive signals from the upper frequency to the lower frequency, during a sweep period, and recycling the generator from the lower frequency to the upper frequency, during a recovery period, the sweep period being at least nine times longer than the recovery period.
In one aspect, the controller subsystem varies a time period for each cycle wherein the time period is non-constant.
In still another aspect, an megasonic system is provided for moving contaminants upwards within a processing tank, including: a processing tank for holding process liquid; a megasonic generator for generating megasonic drive signals; at least one transducer connected to the tank and the generator, the transducer being responsive to the drive signals to impart megasonic energy to the liquid; and an amplitude modulation subsystem for amplitude modulating the drive signals through a range of AM frequencies characterized by an upper frequency and a lower frequency, the subsystem monotonically changing the AM frequency from the upper frequency to the lower frequency to drive contaminants upwards through the liquid.
In one aspect, the generator sweeps the drive signals from upper to lower frequencies to provide additional upwards motion of contaminants within the liquid.
In another aspect, the AM frequencies are between about 1.2 khz and a lower frequency of 1 hz. The AM frequencies can also cover a different range, such as between about 800 hz and a lower frequency of 200 hz.
In another aspect, the invention provides a multi-generator system for producing megasonics at selected different frequencies within a processing tank of the type including one or more transducers. A generator section has a first generator circuit for producing first megasonic drive signals over a first range of frequencies and a second generator circuit for producing second megasonic drive signals over a second range of frequencies. The generator section has an output unit connecting the drive signals to the transducers. Each generator circuit has a first relay initiated by a user-selected command wherein either the first or the second drive signals are connected to the output unit selectively.
In one aspect, a 24 VDC supply provides power for relay coils.
In another aspect, each generator circuit has a second relay for energizing the circuit. Two time delay circuits can also be included for delay purposes: the first time delay circuit delaying generator circuit operation over a first delay period from when the second relay is energized, the second time delay circuit delaying discontinuance of the first relay over a second delay period after the generator circuit is commanded to stop. The first delay period is preferably longer than the second delay period such that no two generators circuits operate simultaneously and such that all generator circuits are inactive during switching of the first relay.
Each relay can include a 24 VDC coil. A selecting device, e.g., a PLC, computer, or selector switch, can be used to select the operating generator circuit. At selection, 24 VDC connects to the two relays of this operating generator circuit. Preferably, each relay coil operates at a common voltage level.
In one aspect, a variable voltage megasonic generator system is provided, including: an megasonic generator; a switching regulator for regulating a 300 VDC signal to +12V and +15V lines, the generator being connected to the +12V and +15V lines; and a power factor correction circuit connected to AC power. The power factor correction circuit provides 300 VDC output to the generator and to the regulator. The generator thus being automatically operable from world voltage sources between 86 VAC and 264 VAC.
In another aspect, a variable voltage megasonic generator system is provided, including: an megasonic generator; and a universal switching regulator (known to those skilled in the art), connected to AC power, for regulating a set of DC voltages to the generator. The generator thus being automatically operable from world voltage sources between 86 VAC and 264 VAC.
In still another aspect, a variable voltage megasonic generator system is provided. The system includes a megasonic generator and a constant peak amplitude triac circuit connected to AC power. The triac circuit converts the AC power to a 121.6 voltage peak, or less, AC signal. A bridge rectifier and filter connects to the AC signal to rectify and filter the AC signal and to generate a DC voltage less than (86)*(Square Root of 2) volts. A switching regulator regulates the DC voltage to 12 VDC and 15 VDC; and the generator connects to the DC voltage, the 12 VDC and the 15 VDC. In this manner, the generator is thus automatically operable from world voltage sources between 86 VAC and 264 VAC.
In another aspect, the successive multiple megasonic frequency invention described herein is a new class of liquid cleaning and processing equipment where there is one transducer array and one generator that produces a series string of different frequencies within two or more non-overlapping continuous frequency ranges. The transducer array is capable of responding to electrical frequency signals to produce intense sound energy at any frequency within two or more distinct frequency bands. The generator is capable of supplying an electrical frequency signal at any frequency within continuous frequency ranges contained within two or more of the transducer array's frequency bands.
The generator and transducer array produce a series string of different frequency sound waves. The first produced frequency is typically followed by a different second frequency that is in the same frequency range as the first frequency, then this second frequency is typically followed by a different third frequency that is in the same frequency range as the first two frequencies, and this pattern continues for at least the lifetime of a sound wave in the liquid (typically 20 to 70 milliseconds). This results in multiple closely related frequencies of the same frequency range adding up within the liquid to a value of high intensity sound. This high intensity sound field is typically maintained long enough to accomplish a specific part of the cleaning or processing cycle, then the electrical frequency signal output of the generator is controlled to jump to a frequency in a different frequency range, typically in a different frequency band, where different frequencies are again strung together for at least the lifetime of a sound wave in the liquid.
This invention is an improvement over prior art multiple frequency systems because by stringing together different frequencies from the same frequency range for at least the lifetime of a sound wave in the liquid, the sound intensity of these closely related frequencies builds up to a higher value than with any of the prior art multiple frequency systems. This higher intensity sound field does the improved cleaning or processing within the frequency range and then the system jumps to another frequency range where the cleaning or processing effect is different. Again, in the second frequency range the sound intensity builds up to a higher value than with any prior art multiple frequency system and, therefore, the improvement in cleaning or processing occurs within this second frequency range. Also, by maintaining the production of sound in each frequency range for a minimum of 20 milliseconds, there is substantially no intense sound energy produced at frequencies outside of the frequency ranges, this further adds to the build up of the intensity of the sound energy. Each of these improved effects in each of the different frequency ranges adds up to a process that is superior to prior art methods.
A variation of the invention substitutes a fraction of a cycle of a frequency strung together with other fractions of a cycle of sound at different frequencies within a given frequency range before jumping to a different frequency range. Another variation inserts a degas time between jumps from one frequency range to another. Another variation controls the generator to cycle through the frequency ranges in different orders, i.e., several permutations of the frequency ranges are introduced into the liquid during the cleaning or processing cycle. Another variation defines each permutation of a frequency range to be a cleaning packet and the order in which these cleaning packets are delivered to the liquid is varied to produce different cleaning effects. Still other variations introduce phase lock loops, duty cycle control, amplitude control, PLC control, computer control, quiet times, active power control, series resistor VCO control, DAC VCO control, cavitation probe feedback to the generator and digital code frequency selection. In general, this invention is useful in the frequency spectrum 9 khz to 7 Mhz.
The foregoing and other objects of are achieved by the invention, which in one aspect comprises a system for coupling sound energy to a liquid, including at least two transducers forming a transducer array adapted for coupling to a liquid in a container. The transducer array is constructed and arranged so as to be capable of producing intense sound energy in the liquid at any frequency within at least two non-overlapping frequency bands. The system further includes a signal generator adapted for producing a driver signal for driving the transducer array at any frequency from one or more continuous frequency ranges within at least two of the frequency bands. The signal generator drives the transducer array to produce the intense sound energy characterized by a series string of different frequencies within one of the continuous frequency ranges. The generator further drives the transducer array to discontinuously jump amongst the frequency ranges, so as to generate intense sound energy characterized by a series string of different frequencies within at least one additional frequency range in at least one additional frequency band.
Another embodiment of the invention further includes a controller for controlling the frequency of the megasonic energy within the series string of different frequencies. The controller also controls a duration of each frequency in the series string.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by a staircase function.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by a series of monotonically decreasing frequencies.
In another embodiment of the invention, the series of monotonically decreasing frequencies occurs for at least ninety percent of an interval during which the transducer array couples intense sound energy to the liquid.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by a series of frequencies defined by a predetermined function of time.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by a series of frequencies swept from a first frequency to a second frequency at a constant sweep rate.
In another embodiment of the invention, the series of frequencies is swept at a non-constant sweep rate.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by a random or chaotic series of frequencies.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by at least a first group of frequencies from a first frequency band, and a second group of frequencies from a second frequency band, such that at least two groups of frequencies adjacent in time are from different frequency bands.
In another embodiment of the invention, the series string of different frequencies further includes at least one degas interval between periods of time having megasonic energy.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies is characterized by at least a first group of frequencies from a first frequency band, and a second group of frequencies also from the first frequency band, such that at least two groups of frequencies adjacent in time are from the same frequency band
In another embodiment of the invention, the intense sound energy in each of the series string of different frequencies is characterized by at least a fraction of a cycle of the distinct frequency.
In another embodiment of the invention, the fraction of a cycle is one-half of a cycle, and each successive one-half cycle represents a different frequency.
In another embodiment of the invention, the intense sound energy includes frequencies selected from the frequency spectrum 9 khz to 7 Mhz.
In another embodiment of the invention, the frequency ranges are characterized by a center frequency. The center frequency of each higher frequency range is a non-integer multiple of the center frequency of the lowest frequency range, so as to prevent one or more Fourier frequencies of a periodic wave from forming in the liquid.
In another embodiment of the invention, the controller includes a PLC or a computer.
Another embodiment of the invention further includes a probe adapted for measuring one or more parameters associated with the liquid corresponding to sound-produced effects in the liquid. The controller alters the generator driver signal as both a predetermined function of the measured parameters, and according to the desired purpose of the system.
In another embodiment of the invention, each specific frequency range is represented by a distinct digital code. The controller initiates a transition from a first frequency range to a second frequency range in response to the digital code transitioning from a digital code representative of the first frequency range to the digital code representative of the second frequency range.
In another embodiment of the invention, the center frequency of each frequency range corresponds to an output of a voltage controlled oscillator. The output of the voltage controlled oscillator corresponds to an input control signal, and the input control signal is determined by a series string of resistors. The total string of resistors produces the lowest frequency range and each higher string of resistors produces each higher frequency range.
In another embodiment of the invention, the intense sound energy includes megasonic energy.
In another embodiment of the invention, the intense sound energy in the series string of different frequencies occurs continuously for at least 20 milliseconds, within each of the continuous frequency ranges.
In another embodiment of the invention, the output power level of the driver signal is actively maintained by comparing an actual output power level to a specified output power level, and adjusting parameters of the driver signal to make the actual output power level substantially equal to the specified output power level. The parameters of the driver signal may be either amplitude, duty cycle, or some combination thereof.
In another embodiment of the invention, the intense sound energy characterized by the series string of different frequencies further includes one or more quiet time intervals characterized by a substantial absence of intense sound energy.
In another embodiment of the invention, the quiet time intervals are distributed periodically among the intervals of intense sound energy. In yet another embodiment, the quiet time intervals are distributed randomly or chaotically among the intervals of intense sound energy.
In another embodiment of the invention, the quiet time intervals are distributed among the intervals of intense sound energy according to a predetermined function of time.
In another embodiment of the invention, the center frequency for each frequency range is optimized by an automatic adjustment from a circuit that maintains a substantially zero phase shift between an associated output voltage and output current at the center frequency.
In another embodiment of the invention, the order of frequency range transitions varies such that several permutations of frequency ranges can be introduced into the liquid. In other embodiments, each permutation of frequency ranges is defined as a specific cleaning packet, and the order in which the cleaning packets are introduced into the liquid is changed such that each different order produces a different cleaning effect.
In another embodiment of the invention, substantially no intense sound energy is produced at frequencies outside of the frequency ranges.
In another embodiment of the invention, the container holding the liquid is constructed from materials resistant to detrimental effects of the liquids. These materials may include tantalum, polyetheretherketone, titanium, polypropylene, Teflon, Teflon coated stainless steel, or combinations thereof, or other similar materials known to those in the art.
In another embodiment of the invention, the signal generator is capable of producing an infinite number of frequencies contained within each of the unconnected continuous frequency ranges.
In another embodiment of the invention, the signal generator produces an output signal including the FM information for synchronizing other generators or power modules.
In another embodiment of the invention, the center frequency of each frequency range corresponds to an output of a voltage controlled oscillator. The output of the voltage controlled oscillator corresponds to an input control signal, and the input control signal is generated by a DAC (digital-to-analog converter). In other embodiments, the digital input to the DAC produces a stepped staircase analog output from the DAC, resulting in a stepped, staircase sweeping function within a frequency range. In yet another embodiment, the digital input to the DAC produces a random or chaotic staircase analog output from the DAC, resulting in a random or chaotic staircase sweeping function within a frequency range.
In another aspect, the invention comprises a system for coupling sound energy to a liquid. The system includes at least two transducers forming a transducer array adapted for coupling to a liquid in a tank, and the transducer array is constructed and arranged so as to be capable of producing intense sound energy in the liquid at any frequency within at least two non-overlapping frequency bands. The system further includes a signal generator adapted for producing a driver signal for driving the transducer array at any frequency from one or more continuous frequency ranges within at least two of the frequency bands. The signal generator drives the transducer array so as to produce intense sound energy characterized by a plurality of changing frequencies within a first frequency range, followed by a plurality of changing frequencies within a second frequency range. The system so operating reduces a strong antinode below the liquid-to-air interface.
In another aspect, the invention comprises a system for coupling sound energy to a liquid, that includes at least two transducers forming a transducer array adapted for coupling to a liquid in a tank. The transducer array is constructed and arranged so as to be capable of producing intense sound energy in the liquid at any frequency within at least two distinct frequency bands. The system further includes a signal generator adapted for producing a driver signal for driving the transducer array at any frequency from one or more continuous frequency ranges within the at least two frequency bands. The center frequencies of the higher frequency ranges are non-integer multiples of the center frequency of the lowest frequency range to prevent two or more Fourier frequencies of a periodic wave from forming in the liquid. The signal generator drives the transducer array to produce sound energy corresponding to a first set of frequencies from a first frequency range, then produces sound energy corresponding to a second set of frequencies from a second frequency range. The transition from the first frequency range to the second frequency range is discontinuous and occurs after a time interval at least as long as the lifetime of sound energy in the container for frequencies from the first frequency range. The sound energy corresponding to the second set of frequencies continues for a time interval at least as long as the lifetime of sound energy in the container for frequencies from the second frequency range.
In another aspect, the invention comprises multiple frequency generator capable of producing an output signal characterized by any frequency within two or more non-contiguous, continuous frequency ranges. The generator is controlled to change the frequency within a frequency range, and then to change frequencies from one frequency range to a second frequency range before beginning the changing of frequencies in this second frequency range.
In another aspect, the invention comprises a method of delivering successive multiple ultrasound frequencies of intense sound waves to a liquid. The method includes the step of coupling to the liquid an array of transducers that are capable of producing sound energy in the liquid at an infinite number of different frequencies contained within two or more non-contiguous, continuous frequency bands. The method also includes the step of driving the transducer array with a generator capable of producing substantially all of the frequencies within continuous frequency ranges contained within two or more of the transducer array frequency bands. The method further includes the step of controlling the generator so that the produced frequencies change within the frequency ranges according to a function of time, and the frequencies jump amongst the frequency ranges.
The multiple frequency aspects of the invention apply to the special case in the megasonics frequency range where driving unclamped megasonic transducers at a single frequency is preferred over sweeping frequency. This is for applications where the primary cleaning or processing mechanism is microstreaming and where transient cavitation is generally undesirable. This aspect of the invention is a system for coupling sound energy to a liquid, including one or more unclamped megasonic transducers (referred to herein as a transducer array or an array) adapted for coupling to a liquid. The transducer array is constructed and arranged so as to be capable of producing sound energy in the liquid at two or more megasonic frequencies, typically a half wave fundamental frequency (fo) and approximately three times this frequency (3*fo). The system further includes a multiple frequency megasonic generator adapted for producing a driver signal for driving the transducer array at a first megasonic frequency and producing megasonics at this frequency within the liquid. The generator further drives the transducer array to discontinuously jump to at least one additional megasonic frequency, producing megasonics at this other megasonic frequency within the liquid.
In another aspect, the present invention is directed to the creation of an AC switch by electronic circuitry such as triacs, or electromechanical devices such as relays. The AC switch as presented in this invention will exchange a modifying circuitry (which contains resistive, reactive, transforming, and active components) into and out of the power section of a megasonic generator. Therefore, the output of the megasonic generator will be modified by the modification circuitry disclosed, by way of example, herein. The AC switch is operatively connected to the modification circuitry. It switches the modification circuitry into and out of the output stage of the generator. The control circuitry is associated with the AC switch and is adapted to turn off and turn on the AC switch. The AC switch will swap resistive, reactive, transforming, and active components and networks of these components into and out of the power section of megasonic frequency generators. The present invention provides a simple and reliable manner to increase the number of parameters and diversify the capabilities of a megasonic generator.
The AC switch introduces a modification circuit that is able to maintain full power output from a multiple frequency megasonic generator as the frequency of the generator is changed.
This patent will suggest a number of applications in which the AC switch is created by triacs. A triac is a three terminal semiconductor, which controls current in either direction. The triac is suited to create a simple and less expensive AC switch than the use of transistors. Nevertheless, it will be obvious to those skilled in the art that other circuitry can be substituted for triacs. One example of such other circuitry, which simulates a triac, is one that includes back to back silicon-controlled rectifiers. Also, a series/parallel active device configuration, relay, or bi-directional lateral insulated gate bipolar transistor, can act as the AC switch.
The phrase “modification circuitry” as used herein is defined as resistive, reactive, transforming, and active components and networks of these components. The circuitry will have two main leads and one or more control leads available for active components or networks containing active components. One of ordinary skill in the art will readily appreciate that it is possible to introduce a different value of a resistive or reactive component through the use of a transformer; therefore, in some cases a transformer, a transformer winding or a transformer tap can be the part of the modification circuitry that is switched by the AC switch.
The modification circuitry is placed in parallel with an AC switch when it is required that the modification circuitry be inserted into a conduction line of the megasonic generator. The modification circuitry is placed in series with an AC switch when it is required that the modification circuitry be inserted between two nodes of the megasonic generator. When connected in series, the modification circuitry is inserted at any time in the cycle by turning on the AC switch. In the case of a parallel connection, the modification circuitry is removed from the generator when the AC switch is on. The reverse effect will happen when the AC switch is turned off. The addition of a control circuitry to the AC switch supplies turn on and off signals to the AC switch. Where the AC switch is a triac, the control circuitry will provide (1) a turn off signal to the megasonic generator for a period of time at least as long as the triac turn off time, (2) the turn off signal to the triac for a period of time at least as long as the triac turn off time, and (3) concurrent signals for a period of time at least as long as the triac turn off time. The use of this control circuitry is necessary due to the fact that the speed of triacs is too slow to allow them to go off when conducting a megasonic current.
Another embodiment of the invention includes modification circuitry capable of modifying the following parameters of the output of a megasonic generator: frequency; amplitude; power; impedance; and waveform. The parameter will change in accordance to the purpose of the application or generator. The modification includes at least one capacitor, one inductor, one transformer or one resistor. Finally, it can also include an active/passive network with a control circuitry adapted to control the active components in the network.
In another embodiment of the invention, a control circuitry capable of supplying a turn off signal to the AC switch for a duration D1 is illustrated. If the AC switch is a triac, the control circuitry will also supply a turn off signal D2 to the generator, where D1 and D2 are concurrent for a time equal to or greater than the triac turn off time. The same will apply if the AC switch is comprised of back to back silicon controlled rectifiers. In the case of the modification of the output frequency of a megasonic oscillator, the “controller” will represent the control circuit. This controller can be further modified to selectively activate or deactivate components so as to step sweep the output frequency of an oscillator.
In another embodiment of the invention, the AC switch and modification circuitry are electronically in the output of the megasonics generator, but are physically located at or near the megasonic transducer array. This is advantageous in cases where the megasonic current on the cable connecting the generator to the transducer array can be reduced by physically locating the AC switch and modification circuitry at the transducer array.
In yet another aspect of the invention multiple sets of AC switch and modification circuitry are used in a megasonics system. For example, an AC switch and modification circuitry is physically located at the output of the megasonic generator to properly tune the generator output for operation at different megasonic frequencies and a second AC switch and modification circuitry is located at the megasonic transducer array to impedance match and/or reduce megasonic current at the different megasonic frequencies of operation.
In another embodiment of the invention, a megasonic transducer array is constructed and supplied with an AC switch and modification circuitry plus a control line such that it can be efficiently operated at multiple megasonic frequencies.
Another embodiment of the invention is a system for coupling ultrasound to a liquid, comprising two or more transducers adapted for coupling to a liquid, the transducers constructed and arranged so as to be capable of producing ultrasound in the liquid at frequencies within at least two frequency bands, and one or more ultrasound generators adapted for producing driver signals for driving the transducers at frequencies in one or more frequency ranges within each of the at least two frequency bands; wherein at least one frequency range is within the microsonic range of frequencies; and, wherein the driver signals in the microsonic range of frequencies are synchronized with a common FM signal; and, wherein the driver signals of the one or more ultrasound generators drive the transducers to produce ultrasound in the liquid characterized by a frequency that sweeps at random, chaotic or pseudo random sweep rates within at least one of the frequency ranges in one of the at least two frequency bands; and, wherein the sweep is monotonic from high frequency to low frequency with a recovery time from low frequency to high frequency that is a shorter time than the monotonic sweep; and, wherein the driver signals are amplitude modulated at a modulation frequency that changes randomly, chaotically or pseudo randomly; and, wherein the one or more ultrasound generators each have an output stage, which comprises, a) modification circuitry which modifies the output stage; b) an AC switch, operatively connected to the modification circuitry, which switches the modification circuitry into and out of the output stage of the ultrasound generator; and c) control circuitry, associated with the AC switch and with the one or more ultrasound generators, which is adapted to turn off and turn on the AC switch, wherein the control circuitry, AC switch and modification circuitry changes the one or more ultrasound generator driver signals to further drive the transducers to change frequency to a different frequency range in a different frequency band, so as to generate ultrasound characterized by a frequency that sweeps at random, pseudo random or chaotic sweep rates within at least one additional frequency range in at least one additional frequency band of the at least two frequency bands. In yet another embodiment of the invention, this system adds power control to the ultrasound by an amplitude modulated driver signal that has off times that vary randomly, chaotically or pseudo randomly while maintaining a specified duty cycle for power control.
In yet another embodiment of the invention, a phase lock loop controlled multiple frequency megasonics generator is capable of producing an output signal characterized by any frequency within two or more non-contiguous, continuous frequency ranges. The generator is controlled by the phase lock loop to change and lock onto a frequency within a frequency range and then to change frequencies from one frequency range to a second frequency range before beginning the changing of frequencies to lock onto a different frequency in this second frequency range.
Another embodiment of the invention is a system for coupling ultrasound to a liquid, comprising one or more transducers adapted for coupling to a liquid, the transducers constructed and arranged so as to be capable of producing ultrasound in the liquid at frequencies within at least two frequency bands, and an ultrasound generator adapted for producing a driver signal for driving the transducers at frequencies in one or more frequency ranges within each of the at least two frequency bands; wherein the driver signal of the ultrasound generator drives the transducers to produce ultrasound in the liquid characterized by successive frequencies within at least one of the frequency ranges in one of the at least two frequency bands; and, wherein the ultrasound generator has an output stage, which comprises, a) modification circuitry which modifies the output stage; b) an AC switch, operatively connected to the modification circuitry, which switches the modification circuitry into and out of the output stage of the ultrasound generator; and c) control circuitry, associated with the AC switch and with the ultrasound generator, which is adapted to turn off and turn on the AC switch, wherein the control circuitry, AC switch and modification circuitry changes the ultrasound generator driver signal to further drive the transducers to change frequency to a different frequency range in a different frequency band, so as to generate ultrasound characterized by successive frequencies within at least one additional frequency range in at least one additional frequency band of the at least two frequency bands.
Another embodiment of the invention is a system for coupling ultrasound to a liquid, comprising, two or more transducers adapted for coupling to a liquid, the transducers constructed and arranged so as to be capable of producing ultrasound in the liquid at frequencies within at least two frequency bands, and, one or more ultrasound generators adapted for producing driver signals for driving the transducers at frequencies in one or more frequency ranges within each of the at least two frequency bands; wherein at least one frequency range is within the microsonic range of frequencies; and, wherein the driver signals of the one or more ultrasound generators drive the transducers to produce ultrasound in the liquid characterized by a frequency that sweeps at random, chaotic or pseudo random sweep rates within at least one of the frequency ranges in one of the at least two frequency bands; and, wherein the driver signals are amplitude modulated at a modulation frequency that changes randomly, chaotically or pseudo randomly; and, wherein the one or more ultrasound generators each have an output stage, which comprises, a) modification circuitry which modifies the output stage; b) an AC switch, operatively connected to the modification circuitry, which switches the modification circuitry into and out of the output stage of the ultrasound generator; and c) control circuitry, associated with the AC switch and with the one or more ultrasound generators, which is adapted to turn off and turn on the AC switch, wherein the control circuitry, AC switch and modification circuitry changes the one or more ultrasound generator driver signals to further drive the transducers to change frequency to a different frequency range in a different frequency band, so as to generate ultrasound characterized by a frequency that sweeps at random, pseudo random or chaotic sweep rates within at least one additional frequency range in at least one additional frequency band of the at least two frequency bands.
Another embodiment of the invention is a system for coupling ultrasound to a liquid, comprising at least two transducers adapted for coupling to a liquid, the transducers constructed and arranged so as to be capable of producing ultrasound in the liquid at frequencies within at least two frequency bands; an ultrasound generator adapted for producing a driver signal for driving the transducers at frequencies in one or more frequency ranges within each of the at least two frequency bands; wherein at least one of the frequency ranges is in the microsonic range of frequencies; and, wherein the driver signal of the ultrasound generator drives the transducers to produce ultrasound in the liquid characterized by successive frequencies within at least one of the frequency ranges in one of the at least two frequency bands; the ultrasound generator changes the driver signal to further drive the transducers to change frequency to a different frequency range in a different frequency band, so as to generate ultrasound characterized by successive frequencies within at least one additional frequency range in at least one additional frequency band of the at least two frequency bands.
Another embodiment of the invention is a system for coupling ultrasound to a liquid, comprising two or more transducers adapted for coupling to a liquid, the transducers constructed and arranged so as to be capable of producing ultrasound in the liquid at frequencies within at least two frequency bands, and, one or more ultrasound generators adapted for producing driver signals for driving the transducers at frequencies in one or more frequency ranges within each of the at least two frequency bands; wherein the driver signals of the one or more ultrasound generators drive the transducers to produce ultrasound in the liquid characterized by a frequency that sweeps at random, chaotic or pseudo random sweep rates within at least one of the frequency ranges in one of the at least two frequency bands; and, wherein the driver signals are continuous wave; and, wherein the one or more ultrasound generators each have an output stage, which comprises a) modification circuitry which modifies the output stage; b) an AC switch, operatively connected to the modification circuitry, which switches the modification circuitry into and out of the output stage of the ultrasound generator; and c) control circuitry, associated with the AC switch and with the one or more ultrasound generators, which is adapted to turn off and turn on the AC switch, wherein the control circuitry, AC switch and modification circuitry changes the one or more ultrasound generator driver signals to further drive the transducers to change frequency to a different frequency range in a different frequency band, so as to generate ultrasound characterized by a frequency that sweeps at random, pseudo random or chaotic sweep rates within at least one additional frequency range in at least one additional frequency band of the at least two frequency bands.
Another embodiment of the invention is a system for coupling megasonics to a liquid, comprising one or more megasonic transducers adapted for coupling to a liquid, the megasonic transducers constructed and arranged so as to be capable of producing megasonics in the liquid at frequencies within at least two frequency bands, and, a megasonics generator adapted for producing a driver signal for driving the transducers at frequencies in one or more frequency ranges within each of the at least two frequency bands; wherein the driver signal of the megasonics generator drives the transducers to produce megasonics in the liquid at a frequency within at least one of the frequency ranges in one of the at least two frequency bands; and, wherein the megasonics generator has an output stage, which comprises (a) modification circuitry which modifies the output stage; (b) an AC switch, operatively connected to the modification circuitry, which switches the modification circuitry into and out of the output stage of the megasonics generator; and (c) control circuitry, associated with the AC switch and with the megasonics generator, which is adapted to turn off and turn on the AC switch, wherein the control circuitry, AC switch and modification circuitry changes the megasonics generator driver signal to further drive the transducers to change frequency to a different frequency range in a different frequency band, so as to generate megasonics at a frequency within at least one additional frequency range in at least one additional frequency band of the at least two frequency bands. Phase lock loop control of one or more of the frequencies in this system is often desirable.
Another embodiment of the invention is an ultrasound generator having an output signal that is frequency modulated with a sweeping frequency waveform and amplitude modulated with a changing frequency; wherein the sweep rate of the sweeping frequency waveform changes randomly, chaotically or pseudo randomly; and, wherein the amplitude modulation frequency changes randomly, chaotically or pseudo randomly.
Another embodiment of the invention is an ultrasound generator having an output signal that is frequency modulated with a sweeping frequency waveform and has continuous wave for its amplitude modulation; wherein the sweep rate of the sweeping frequency waveform changes randomly, chaotically or pseudo randomly.
Another embodiment of the invention is a frequency drive signal (referred to herein as the improved cavitation efficiency drive signal) where the drive signal is provided during a first defined time period and at a first frequency during a beginning portion of the first defined time period, and the drive signal is provided at a second frequency during an ending portion of the first defined time period with the drive signal sweeping from the first frequency to the second frequency during this first defined time period. The frequency of the drive signal is varied from the second frequency to a third frequency; and the drive signal is provided during a second defined time period. This drive signal increases the efficiency of cavitation and can be employed with any of the generator or generator and transducer array systems described in this specification.
Another embodiment of the invention is for improving cleaning or processing by producing a first form of cavitation and a second form of cavitation in a liquid comprising a succession of time periods with at least one time period wherein the first form of cavitation is produced in the liquid, and, at least one of the successive time periods wherein the second form of cavitation is produced in the liquid, wherein the first form of cavitation is predominantly stable cavitation, and, wherein the second form of cavitation is predominantly transient cavitation. This method of improving performance with two forms of cavitation can be employed with any of the generator or generator and transducer array systems described in this specification.
In another embodiment of the invention the second form of cavitation is produced by the improved cavitation efficiency drive signal. A drive signal incorporating the first form of cavitation in at least one time period and the second form of cavitation in the form of the improved efficiency drive signal in another time period can be employed with any of the generator or generator and transducer array systems described in this specification.
In another embodiment of the invention, a method for inactivation of organisms in liquids includes establishing a sequence of one or more periods of predominantly stable cavitation in the liquid and one or more periods of predominantly transient cavitation in the liquid, the respective periods being sufficient to effect a predetermined inactivation of the organisms. In the preferred aspect of the invention the method for the inactivation for microorganisms in liquids further includes adding to the liquid one or more microbiologically active chemicals prior to the establishing steps.
In another embodiment of the invention, combinations of eight process parameters, i.e., multiple frequencies, predominantly stable cavitation, predominantly transient cavitation, a succession of predominantly stable and predominantly transient cavitation, UV light, electric current, an electrolyte and microbiologically active chemicals, are employed to improve the inactivation of organisms, i.e., to reduce the time that it takes to achieve a specified inactivation.
In another embodiment of the invention, a method for inactivation of organisms in aqueous liquids comprises adding an electrolyte to the liquid and passing an electric current through the liquid, whereby the inactivation is effected.
In another embodiment of the invention, a method for inactivation of organisms in liquids comprises applying successive multiple ultrasound frequencies to the liquid, whereby the inactivation is effected.
In another embodiment of the invention involving concurrent multiple ultrasound frequencies, the inventor has found that when an optimum spacing D for transducers results in less power density than is required by the process, the solution is to use random transducer spacing where the radiating membrane surface is uniformly covered by the number of transducers needed to supply the required power density. For a concurrent multiple ultrasound frequency system, the random spacing has one of two configurations. If the transducers are the same type of universal transducer with the ability to produce two or more different frequencies, then the randomly spaced transducers are wired into two or more arrays where adjacent transducers are typically in different arrays. If the transducers are unique for each of the two or more different frequencies, then the randomly spaced transducers include a mix of different frequency transducers such that adjacent transducers are typically a different frequency.
The destructive and constructive interference of the different frequency sound waves results in less transient cavitation compared to sweeping single frequency systems because the resultant wave in the liquid has many frequencies that typically exist for one cycle or less, except for frequencies at or near the average of the individual frequencies. Transient cavitation produced by normal power ultrasonics (defined herein as typically 100 watts per gallon for small volumes on the order of five gallons to 20 watts per gallon for larger volumes on the order of 100 gallons) typically requires several cycles for the cavitation bubble to oscillate up to the critical energy level required for a transient collapse, therefore, for that ultrasonic energy at frequencies where one cycle or less is available, the bubbles grow and then decay, producing microstreaming, but seldom a transient collapse. Although this conventional operation of a concurrent multiple ultrasound frequency system is lacking where predominantly transient cavitation is required, the growth and decay of bubbles simulates the effects of stable cavitation and therefore, this conventional operation of a concurrent multiple ultrasound frequency system will be used herein as one additional method to produce predominantly stable cavitation.
For processes where transient cavitation is required, the present invention improves the amount of transient cavitation from a concurrent multiple ultrasound frequency system by supplying the ultrasonic power to the tank in synchronized high peak power different frequency ultrasonic bursts. This produces the spectrum of frequencies that typically exist for one cycle or less, however, when the synchronized ultrasonic bursts have sufficient peak power to grow the bubbles to the energy levels required for transient cavitation collapse in one cycle or less, then there is transient cavitation at each of these frequencies. The inventor has found that in a normal power system, if a minimum of 84 percent of the energy per cycle is delivered in a maximum of 27 percent of the cycle time, the conditions for improved transient cavitation occur. As higher percentages of the energy are delivered in shorter amounts of the cycle time, the efficiency of transient cavitation improves.
It should be noted that the intermixed random spacing is the preferred transducer configuration for this invention, however, any spacing, intermixed or not intermixed, results in the improved cavitation density of the broad spectrum of transient cavitation that results from the synchronized high peak power different frequency ultrasonic bursts. It should also be noted that the drive signal in each of the synchronized bursts is typically a sweeping frequency, however, single frequency bursts also improve the amount of transient cavitation compared to prior art systems with the same powers and frequencies.
In another embodiment of the invention a system is configured to be capable of supplying both concurrent multiple ultrasound frequencies and successive multiple ultrasound frequencies in series to a liquid. The generator is controlled to supply each type of ultrasound for the programmed periods to accomplish the desired process. This method provides greater efficiency for processes where the unique advantages of each type of ultrasound (concurrent multiple ultrasound frequencies and successive multiple ultrasound frequencies) are useful for part of the process. This embodiment is best achieved with multiple arrays of universal transducers. Consider as an example, two arrays of universal transducers with a first multiple frequency generator driving the first array of universal transducers and with a second multiple frequency generator driving the second array of universal transducers. A controller controls these two generators such that they produce concurrent multiple ultrasound frequencies when the first generator is controlled to operate in a first frequency range while the second generator is controlled to operate in a second frequency range. When the controller controls both generators to operate in the same frequency range, the system produces the first in a series of successive multiple ultrasound frequencies. By programming the controller to work in each mode is series, both concurrent multiple ultrasound frequencies and successive multiple ultrasound frequencies in series are supplied to a liquid. It is noted that some processes are improved when the individual frequency ranges in a set of successive ultrasound frequencies are separated by a time period of concurrent multiple frequency ultrasound frequencies. This special case will be defined herein to be included when both concurrent multiple ultrasound frequencies and successive multiple ultrasound frequencies in series are referred to.
In one form of the invention, two or more transducers (or arrays of transducers) may be driven by a frequency spectrum including distinct frequencies (e.g., F1 and F2 in the case of two transducers or two transducer arrays) for a period of time. Followed by one or more transducers or arrays of transducers being driven by different frequency spectra (e.g., in the case of a single transducer a third frequency F3) for a second period of time (F3 may be equal to F1 or F2 or may be a different frequency). The latter transducers may be one or more of the former transducers or they may be distinct from the former transducers. The application of the different frequency spectra may be in the above described sequence or reversed in time. The time periods can be contiguous or not as desired.
In another embodiment of the invention a new wide range multiple frequency transducer that will operate at regions in each area of the wide frequency range from ultrasonic to microsonic to megasonic is a sandwich type transducer. The unique concept that makes megasonics operation practical in this sandwich type transducer is that the thickness of each piezoelectric ceramic is designed such that an integer number of half wavelengths of sound exist in the ceramic at the megasonics frequency; and the back mass and the front mass with its bonded surface each contain an integer number of half wavelengths plus one quarter of a wavelength at the megasonics frequency. Good design practice calls for the clamping bolt or other clamping assembly to be recessed from the outer surface of the back mass and/or from the radiating surface of the front mass so its load bearing surface or surfaces are at nodal points of the megasonics half wavelengths within the front mass and/or the back mass. Another unique feature of this inventive sandwich type transducer structure (Langevin type structure) when operated at megasonics frequencies is the heat dissipating ability of the stacked structure. This allows reliable off resonance operation of the transducer in ranges around the megasonics center frequency, which allows sweeping in the megasonics frequency range. The inventor has found that sweeping megasonics has advantages over the state of the art single frequency megasonics. The collimated megasonic characteristic of the prior art is reduced by sweeping megasonics and the process efficiency is improved because there is less absorption of sound energy when sweeping compared to prior art single frequency megasonics.
This transducer operates at the lower ultrasonic and/or microsonic frequencies in the same fashion as a Langevin transducer with harmonics, i.e., the lowest frequency is the half wavelength resonance of the complete stack and higher frequencies are harmonics or overtones of this fundamental resonance.
In another embodiment of the invention a multiple frequency band megasonic transducer for producing vibratory motion at a drive surface comprises a transducer assembly extending along the transducer axis of the transducer assembly including:
i. a piezoelectric assembly including a stack of p polarized piezoelectric ceramic elements extending along the transducer axis between a piezoelectric assembly top surface and a piezoelectric assembly bottom surface, each of the polarized piezoelectric ceramic elements having an element top surface and an element bottom surface, and being characterized by a thickness Pi along the transducer axis, where i is an integer 1, 2, . . . , p, each of the element top surfaces and the element bottom surfaces having an electrically conductive layer disposed thereon, and including means for coupling a drive signal to the electrically conductive layers,
ii. a tank wall extending between a tank wall top surface and a tank wall bottom surface, the tank wall having a thickness T in the direction of the transducer axis, the thickness T being small relative to other thicknesses in the transducer assembly, the tank wall top surface forming the drive surface, and the tank wall bottom surface bonded to a front mass effectively adding a thickness T/2 to the front mass;
iii. the front mass extending between the tank wall bottom surface and the piezoelectric assembly top surface, the front mass having a thickness D in the direction of the transducer axis;
iv. a back mass extending between a bottom transducer surface and the bottom piezoelectric assembly surface, the back mass having a thickness B in the direction of the transducer axis;
v. a compression assembly including means for applying a compressive force F across the front mass and the back mass; whereby the front mass, the piezoelectric assembly, the back mass and the tank wall are dimensioned so that in response to the compressive force F:
Pi is equal to niλP/2
D+T/2 is equal to m1λD/2+λD)/4
B is equal to m2λB/2+λB/4
where ni, m1 and m2 are integers and λP is the characteristic acoustic wavelength of the polarized piezoelectric ceramic elements, and λB and λD, are the characteristic acoustic wavelengths of the back mass and the front mass, respectively [where λ=v/f] wherein the transducer is characterized by a vibratory fundamental first frequency having wavelength λf1 equal to
and a vibratory second frequency having wavelength λf2 equal to 2λP.
The invention is next described further in connection with preferred embodiments, and it will become apparent that various additions, subtractions, and modifications can be made by those skilled in the art without departing from the scope of the invention.
A more complete understanding of the invention may be obtained by reference to the drawings, in which:
At the outset, it should be clearly understood that like reference numerals are intended to identify the same structural elements, portions or surfaces consistently throughout the several drawing figures, as such elements, portions or surfaces may be further described or explained by the entire written specification, of which this detailed description is an integral part. Unless otherwise indicated, the drawings are intended to be read (e.g., cross-hatching, arrangement of parts, proportion, degree, etc.) together with the specification, and are to be considered a portion of the entire written description of this invention. As used in the following description, the terms “horizontal”, “vertical”, “left”, “right”, “up” and “down”, as well as adjectival and adverbial derivatives thereof (e.g., “horizontally”, “rightwardly”, “upwardly”, etc.), simply refer to the orientation of the illustrated structure as the particular drawing figure faces the reader. Similarly, the terms “inwardly” and “outwardly” generally refer to the orientation of a surface relative to its axis of elongation, or axis of rotation, as appropriate.
Although the transducer 16 is shown mounted to the bottom of the tank 20, those skilled in the art will appreciate that other mounting configurations are possible and envisioned. The transducer elements 18 are of conventional design, and are preferably “clamped” so as to compress the piezoelectric transducer material.
The transducers 32a, 32b are driven by a common generator such as generator 12 of
The thicknesses 40a, 40b of transducers 32a, 32b, respectively, determine the transducer's fundamental resonant frequency. For purposes of illustration, transducer 32a has a fundamental frequency of 40 khz, and transducer 32b has a fundamental frequency of 44 khz. Transducers 32a, 32b each have a finite ultrasound bandwidth which can be adjusted, slightly, by those skilled in the art. Typically, however, the bandwidths are about 4 khz. By choosing the correct fundamental frequencies, therefore, an overlap between the bandwidths of the two transducers 32a, 32b can occur, thereby adding additional range within which to apply ultrasound 26a′, 26b′ to liquid 22′.
The acoustic energy 26′ applied to the liquid 22′ by the combination of transducers 32a, 32b is illustrated graphically in
The generator connected to lead-outs 42 drives the transducers 32a, 32b at frequencies within the bandwidth 43 to obtain broadband acoustical disturbances within the liquid 22′. As described herein, the manner in which these frequencies are varied to obtain the overall disturbance is important. Most preferably, the generator sweeps the frequencies through the overall bandwidth, and at the same time sweeps the rate at which those frequencies are changed. That is, one preferred generator of the invention has a “sweep rate” that sweeps through the frequencies within the bandwidth 43; and that sweep rate is itself varied as a function of time. In alternative embodiments of the invention, the sweep rate is varied linearly, randomly, chaotically or as some other function of time to optimize the process conditions within the tank 20′.
With further reference to
Those skilled in the art understand that each of the transducers 18 and 32a, 32b,
Accordingly, the benefits of applying a broadband acoustic disturbance to the liquid also apply to the 100-350 khz microsonic frequencies. Similar to
The signal section 112 includes a triangle wave oscillator 114 with a frequency typically below 150 hz. The purpose of the oscillator 114 is to provide a signal that sweeps the sweep rate of the ultrasound frequencies generated by the transducer arrays 122.
The oscillator 114 is fed into the input of the sweep rate VCO 115 (Voltage Controlled Oscillator). This causes the frequency of the output of VCO 115 to linearly sweep at the frequency of the oscillator 114. The optimum sweep rate frequency output of VCO 115 is typically from about 10 hz, for magnetostrictive elements, to about 1.2 khz, for piezoelectrics. Therefore, the optimum center sweep rate frequency can be anywhere within the range of about 10 hz to 1.2 khz, and that sweep rate is varied within a finite range of frequencies about the center sweep frequency. This finite range is typically set to about 10-50% of the center sweep rate frequency. For example, the center sweep rate frequency for one process might be 455 hz, so the VCO 115 output is set, for example, to sweep from 380 hz to 530 hz. If, additionally, the oscillator 114 is set to 37 hz, then the output of VCO 115 changes frequency, linearly, from 380 hz to 530 hz, and back to 380 hz at thirty seven times per second.
The output of VCO 115 feeds the VCO input of the 2× center frequency VCO 116. The VCO 116 operates as follows. If, for example, the center frequency of VCO 116 is set to 208 khz and the bandwidth is set to 8 khz, the center frequency linearly changes from 204 khz to 212 khz and back to 204 khz in a time of 1.9 milliseconds (i.e., 1/530 hz) to 2.63 milliseconds (i.e., 1/380 hz). The specific time is determined by the voltage output of the oscillator 114 at the time of measurement. Since the voltage output of oscillator 114 is constantly changing, the time it takes to linearly sweep the center frequency from 204 khz to 212 khz and back to 204 khz is also constantly changing. In this example, the time changes linearly from 1.9 milliseconds to 2.63 milliseconds and back to 1.9 milliseconds at thirty seven times per second.
The oscillator 114, VCO 115 and VCO 116 operate, in combination, to eliminate the repetition of a single sweep rate frequency in the range of 10 hz to 1.2 khz. For example, the highest single frequency that exists in the stated example system is 37 hz. If an unusual application or process were found whereby a very low frequency resonance around 37 hz exists, then the oscillator 114 would be replaced by a random or chaotic voltage generator to reduce the likelihood of exciting any modes within the part.
The VCO 116 drives a divide-by-two D flip-flop 117. The purpose of the D flip-flop 117 is to eliminate asymmetries in the waveform from the VCO 116. The output of the D flip-flop 117 is thus a square wave that has the desired frequency which changes at a sweep rate that is itself sweeping. In the stated example, the output square wave from D flip-flop 117 linearly changes from 102 khz to 106 khz and back to 102 khz at different times in the range of 1.9 milliseconds to 2.63 milliseconds. This sweeping of the sweep rate is sometimes referred to herein as “double sweep” or “double sweeping.”
The AC line zero-crossover detection circuit 118 produces a signal with a rise time or narrow pulse at or near the time that the AC line voltage is at zero or at a low voltage, i.e., at or near zero degrees. This signal triggers the adjustable monostable multivibrator 119. The timed pulse out of monostable multivibrator 119 is set to a value between zero degrees and ninety degrees, which corresponds to a time from zero to 4.17 milliseconds for a 60 hz line frequency.
If the maximum amplitude were desired, for example, the monostable multivibrator 119 is set to a time of 4.17 milliseconds for a 60 hz line frequency. For an amplitude that is 50% of maximum, the monostable multivibrator 119 is set to 1.389 milliseconds for a 60 hz line frequency. In general, the monostable multivibrator 119 time is set to the arcsine of the amplitude percent times the period of the line frequency divided by 360 degrees.
The double sweeping square wave output of the D flip-flop 117 and the timed pulse output of the monostable multivibrator 119 feed into the synchronization logic 120. The synchronization logic 120 performs three primary functions. First, it only allows the double sweeping square wave to pass to the output of the synchronization logic 120 during the time defined by the pulse from the monostable multivibrator 119. Second, the synchronization logic 120 always allows a double sweeping square wave which starts to be completed, even if the monostable multivibrator 119 times out in the middle of a double sweeping square wave. And lastly, the synchronization logic 120 always starts a double sweeping square wave at the beginning of the ultrasound frequency, i.e., at zero degrees.
The output of synchronization logic 120 is a double sweeping square wave that exists only during the time defined by the monostable multivibrator 119 or for a fraction of a cycle past the end of the monostable multivibrator 119 time period. The synchronization logic 120 output feeds a power module 121 which amplifies the pulsed double sweeping square wave to an appropriate power level to drive the harmonic transducers 122. The transducers 122 are typically bonded to a tank and deliver sound waves into the liquid within the tank. These sound waves duplicate the pulsed double sweeping characteristics of the output of the signal section 112.
U2 is a XR-2209 precision oscillator with a triangle wave output at pin8. The center frequency of U2 is 1/(RC)=1/((2.2 Kohm) (1 microfarad))=455 hz. The actual output frequency is proportional to the current flowing out of pin4 of U2. At 455 hz, this current is 6 volts/2.2 Kohm=2.73 milliampers. It is generally desirable, according to the invention, to sweep the 455 hz sweep rate through a total change of 150 hz, i.e., 75 hz either side of 455 hz. Since 75 hz/455 hz=16.5%, the current flowing out of pin 4 must change by 16.5% in each direction, that is, by (16.5%) (2.73 milliampers)=0.45 milliampers. The triangle wave from U1 causes this change. The triangle wave changes from 3 volts to 9 volts; therefore, there is 3 volts on either side of 6 volts at pin4 of U2 to cause the 0.45 milliampers change. By making R1=3 volts/0.45 milliampers=6.67 Kohm, the sweep rate is changed 75 hz either side of 455 hz. The actual R1 used in
U3 is an XR-2209 precision oscillator with a center frequency of approximately 1/(RC)=1/((12 Kohm+2.5 Kohm) (330 microfarad))=209 khz with the potentiometer set to its center position of 2.5 Kohm. In the actual circuit, the potentiometer is adjusted to about 100 ohms higher to give the desired 208 khz center frequency. Out of U3 pin4 flows 6 volts/(12 Kohm+2.5 Kohm+100 ohms)=0.41 milliampers. To change the center frequency a total of 8 khz, the 0.41 milliampers is changed by 4 khz/208 khz=1.92%, or 7.88 microampers. This means that R2=3 volts/7.88 microampers=381 Kohm. In
U3 pin7 has a square wave output that is changing from 204 khz to 212 khz and back to 204 khz at a rate between 380 hz and 530 hz. The actual rate is constantly changing thirty seven times a second as determined by U1.
U4 is a D flip-flop in a standard divide by two configuration. It squares up any non 50% duty cycle from U3 and provides a frequency range of 102 khz to 106 khz from the 204 khz to 212 khz U3 signal.
The output of U4 feeds the synchronization logic which is described below and after the description of the generation of the amplitude control signal.
The two 1N4002 diodes in conjunction with the bridge rectifier form a full wave half sinusoid signal at the input to the 40106 Schmidt trigger inverter. This inverter triggers when the half sinusoid reaches about 7 volts, which on a half sinusoid with an amplitude of 16 times the square root of two is close enough to the zero crossover for a trigger point in a practical circuit. The output of the 40106 Schmidt trigger falls which triggers U5, the edge triggered 4538 monostable multivibrator wired in a trailing edge trigger/retriggerable configuration. The output of U5 goes high for a period determined by the setting on the 500 Kohm potentiometer. At the end of this period, the output of U5 goes low. The period is chosen by setting the 500 Kohm potentiometer to select that portion of the leading one-quarter sinusoid that ends at the required amplitude to give amplitude control. This timed positive pulse feeds into the synchronization logic along with the square wave output of U4.
The timed pulse U5 feeds the D input of U6, a 4013 D-type flip flop. The square wave from U4 is invented by U7a and feeds the clock input of U6. U6 only transfers the signal on the D input to the output Q at the rise of a pulse on the clock input, Pin3. Therefore, the Q output of U6 on Pin1 is high when the D input of U6 on Pin3 is high and the clock input of U6 on Pin3 transitions high. This change in the Q output of U6 is therefore synchronized with the change in the square wave from U4.
The synchronized high Q output of U6 feeds U8 Pin13, a 4093 Schmidt trigger NAND gate. The high level on Pin13 of U8 allows the square wave signal to pass from U8 Pin12 to the output of U8 at Pin11.
In a similar way, U8 synchronizes the falling output from U5 with the square wave from U4. Therefore, only complete square waves pass to U8 Pin11 and only during the time period as chosen by monostable multivibrator U5. The 4049 buffer driver U7b inverts the output at U8 Pin11 so it has the same phase as the square wave output from U4. This signal, U7b Pin2 is now the proper signal to be amplified to drive the transducers.
The signal input to
This results in an isolated drive signal on the output of U11 and the same signal on the output of U12, only 180 degrees out of phase. Therefore, U11 drives Q1 on while U12 drives Q2 off. In this condition, a power half sinusoid of current flows from the high voltage full wave DC at B1 through D1 and Q1 and L1 into C1. Current cannot reverse because it is blocked by D1 and the off Q2. When the input signal changes state, U11 turns off Q1 and U12 turns on Q2, a half sinusoid of current flow out of C1 through L2 and D2 and Q2 back into C1 in the opposite polarity. This ends a complete cycle.
The power signal across C1 couples through the high frequency isolation transformer T4. The output of T4 is connected to the transducer or transducer array.
The ceramic 134 of microsonic transducer 128 is driven through oscillatory voltages transmitted across the electrodes 136. The electrodes 136 connect to a ultrasound generator (not shown), such as described above, by insulated electrical connections 138. The ceramic 134 is held under compression through operation of the bolt 132. Specifically, the bolt 132 provides 5,000 pounds of compressive force on the piezoelectric ceramic 134. This transducer invention will be referred to herein as the “reverse bolt construction” transducer.
Amplitude control according to one embodiment of the invention is illustrated in
The amplitude select section 146 selects a portion of the leading quarter sinusoid of rectified signal 145 that ends at the desired amplitude, here shown as amplitude “A,” in a region 148 between zero and 90 degrees and in a region 150 between 180 degrees and 270 degrees of the signal 145. In this manner, the amplitude modulation 152 is selectable in a controlled manner as applied to the signal 154 driving the transducers 156 from the generator 142, such as discussed in connection with
Those skilled in the art will appreciate that the rectification section 144 can also be a half-wave rectifier. As such, the signal 145 will only have a response every other one-half cycle. In this case, amplitude control is achieved by selecting a portion of the leading quarter sinusoid that ends at a selected amplitude between zero and 90 degrees of the sinusoid.
The ultrasound generator of the invention is preferably amplitude modulated. Through AM control, various process characteristics within the tank can be optimized. The AM control can be implemented such as described in FIGS. 3,4,10 and 10A, or through other prior art techniques such as disclosed in U.S. Pat. No. 4,736,130.
This “sweeping” of the AM frequency is accomplished in a manner that is similar to ultrasound generators which sweep the frequency within the bandwidth of a ultrasound transducer. By way of example, U.S. Pat. No. 4,736,130 describes one ultrasound generator which provides variable selection of the AM frequency through sequential “power burst” generation and “quiet time” during a power train time. In accord with the invention, the AM frequency is changed to “sweep” the frequency in a pattern so as to provide an AM sweep rate pattern.
U.S. Pat. No. 4,736,130 describes one AM generator 56,
In addition, each of the generators 206a-206c can and do preferably sweep the frequencies about the transducers' bandwidth centered about the frequencies 40 khz, 72 khz and 104 khz, respectively; and they further sweep the sweep rate within these bandwidths to reduce or eliminate resonances which might occur at the optimum sweep rate.
When the tank 210 is filled with a new chemistry, the operator selects the optimum frequency through the mux select section 212. The mux select section connects to the analog multiplexer (“mux”) 214 which connects to each generator 206. Specifically, each generator 206 couples through the mux 214 in a switching network that permits only one active signal line 216 to the transducers 208. For example, if the operator at mux select section 212 chooses microsonic operation to optimize the particular chemistry in the tank 210, generator 206c is connected through the mux 214 and drives each transducer 208a-208c to generate microsonic ultrasound 201 which fills the tank 210. If, however, generator 206a is selected, then each of the transducers 208 are driven with 40 khz ultrasound.
In order to eliminate “beating” between ultrasound energies 240a-240c of the several transducers 238a-238c and generators 232a-232c, the generators 232 are each driven by a common FM signal 250 such as generated by the master signal generator 244. The FM signal is coupled to each generator through signal divider 251.
In operation, system 230 permits the coupling of identical frequencies, in magnitude and phase, into the tank 236 by the several transducers 238. Accordingly, unwanted beating effects are eliminated. The signal 250 is swept with FM control through the desired ultrasound bandwidth of the several transducers to eliminate resonances within the tank 236; and that sweep rate frequency is preferably swept to eliminate any low frequency resonances which can result from the primary sweep frequency.
Those skilled in the art should appreciate that system 230 of
The common master signal generator 270 provides a common FM signal 272 for each of the generators 262. Thereafter, ultrasound generators 262a-b generate ultrasound 268a-b that is identical in amplitude and phase, such as described above. Similarly, generators 262c-d generate ultrasound 268c-d that is identical in amplitude and phase. However, unlike above, the generators 262 each have an AM generator 274 that functions as part of the generator 262 so as to select an optimum AM frequency within the tanks 264. In addition, the AM generators 274 preferably sweep through the AM frequencies so as to eliminate resonances at the AM frequency.
More particularly, generators 274a-b generate and/or sweep through identical frequencies of the AM in tank 264a; while generators 274c-d generate and/or sweep through identical frequencies of AM in tank 264b. However, the AM frequency and/or AM sweep of the paired generators 274a-b need not be the same as the AM frequency and/or AM sweep of the paired generators 274c-d. Each of the generators 274 operate at the same carrier frequency as determined by the FM signal 270; however each paired generator set 274a-b and 274c-d operates independently from the other set so as to create the desired process characteristics within the associated tank 264.
Accordingly, the system 260 eliminates or prevents undesirable cross-talk or resonances between the two tanks 264a-b. Since the generators within all tanks 264 operate at the same signal frequency 270, there is no effective beating between tanks which could upset or destroy the desired cleaning and/or processing characteristics within the tanks 264. As such, the system 260 reduces the likelihood of creating damaging resonances within the parts 280a-b. It is apparent to those skilled in the art that the FM control 270 can contain the four AM controls 274a-d instead of the illustrated configuration.
The invention thus attains the objects set forth above, among those apparent from preceding description. Since certain changes may be made in the above apparatus and methods without departing from the scope of the invention, it is intended that all matter contained in the above description or shown in the accompanying drawing be interpreted as illustrative and not in a limiting sense.
It is also to be understood that the following claims are to cover all generic and specific features of the invention described herein, and all statements of the scope of the invention which, as a matter of language, might be said to fall there between.
The exact configuration of the back mass depends upon the processing needs of the ultrasound being delivered to a tank. For example, it is typically desirable to have a flat or constant power over frequency, such as shown in
The front mass 82 and/or back mass 84 (the “back mass” also known as “back mass” herein) are preferably made from steel. The front mass 82 is however often made from aluminum. Other materials for the front mass 82 and/or the back mass 84 can be used to acquire desired performance characteristics and/or transducer integrity.
The designs of
Surface cavitation is intense cavitation that occurs at the interface between the solution within the tank and the radiating surface upon which the ultrasound transducers are mounted. There are several problems associated with surface cavitation damage. First, it is often intense enough to erode the material of the radiating surface. This can eventually create a hole in the radiation surface, destroying the tank. The erosion is also undesirable because it introduces foreign materials into the cleaning solution. Surface cavitation further generates cavitation implosions with higher energy in each cavitation implosion than exists in the cavitation implosions in the process chemistry. If the cavitation implosions in the process chemistry are at the proper energy level, than there is the possibility that the higher energy cavitation implosions at the surface cavitation will cause pitting or craters in the parts under process. In addition, the energy that goes into creating the surface cavitation is wasted energy that is better used in creating bulk cavitation.
Most ultrasound processes, including cleaning, have two distinct stages. The first stage is usually preparation of the liquid and the second stage is the actual process. The system 200 of
The invention of
More particularly,
As shown in
The generator 202 preferably produces frequencies throughout the bandwidth of the transducers 204. The generator 202 is thus preferably a sweep frequency generator (described in U.S. Pat. Nos. 4,736,130 and 4,743,789) or a dual sweep generator (described in International Patent Application PCT/US97/12853) that will linearly or non-linearly change frequency from the lowest frequency in the bandwidth to the highest frequency in the bandwidth; and that will thereafter reverse direction and sweep down in frequency through the bandwidth. The invention of
The reason that contamination is forced to the surface 207a of the process chemistry 207 in the system of
Those skilled in the art should appreciate that methods and systems exist for sweeping the applied ultrasound energy through a range of frequencies so as to reduce resonances which might adversely affect parts within the process chemistry. See, e.g., U.S. Pat. Nos. 4,736,130 and 4,743,789 by the inventor hereof and incorporated by reference. It is further known in ultrasound generators to “sweep the sweep rate” so that the sweep frequency rate is changed (intermittently, randomly, with a ramp function, or by another function) to reduce other resonances which might occur at the sweep rate. By way of example, the inventor of this application describes such systems and methods in connection with FIGS. 3, 4, 5A, 5B, 22A, 22B and 22C of International Application No. PCT/US97/12853, which is herein incorporated by reference.
The variable slope of the frequency function 220 of
As illustrated in
As illustrated in
As a function of time, change or “sweep” the power up-sweep rate at optimum values (1 hz to 1.2 khz) of the rate, as shown in
For the case where there is a degas period, such as in
As shown in
Note that in each of
A similar system 310 is shown in
From the above, one skilled in the art should appreciate that the system 310 can be made for more than two frequencies, such as for 40 khz, 72 khz and 104 khz. Such a system is advantageous in that a single transducer array can be used for each of the multiple frequencies, where, for example, its fundamental frequency is 40 khz, and its first two harmonics are 72 khz and 104 khz.
An alternative system is described in connection with
The prior art is familiar with certain meters which measure sound characteristics and cavitations within an ultrasonic tank. Each of the meters gives one number, usually in units of watts per gallon, and sometimes in undefined units such as cavities. However, the activity in a cavitating ultrasonic tank is very complex and no single number adequately describes this activity. For example, as shown in
In most ultrasonic systems, the cavitation density also varies as a function of time. Accordingly, this is a third characteristic that should be measured when measuring ultrasonic activity in a tank.
A characteristic of ultrasonic cavitation in aqueous solutions is the production of free radicals, ions and super oxides. These by-products of the cavitation increase the conductivity of the aqueous solution. A measure of the conductivity is thus a function of the number of cavitation implosions present in the aqueous sample, and the time variation of this conductivity is a measure of how the cavitation density varies as a function of time.
Another characteristic of cavitation is that it heats the aqueous solution. This is because all the energy released during each cavitation implosion becomes heat energy. By measuring the change in temperature of the aqueous sample, therefore, and by knowing its mass and specific heat, one can calculate the total energy released from the cavitation by the following formula: energy (calories) equals specific heat (no units, i.e., a ratio) times mass (grams) times the change in temperature (degrees C.). When the amount of energy released is known, as well as the number of cavitation implosions that released this energy, a division of the quantities gives the energy in each cavitation implosion.
The sensing probe 650 is similar in operation to the sensing probe 402 of
The sensing probe 650 thus includes, within the sensing probe tip 650a, two electrodes 654, 656 to measure conductivity, and a temperature measuring device (e.g., a thermocouple) 658 to monitor the temperature of the fixed mass of aqueous solution 652. These sensing devices 654, 656 and 658 are connected to data wires for sampling of the sensing device responses. A data collection instrument (e.g., an A/D sensor interface board and a computer) connects to the wires 670 out of the sensing probe 650 to measure temperature rise as a function of time, DeltaT=g(t), and to evaluate this quantity over a specific time period t′, in seconds, i.e., DeltaT=g(t′). The data collection instrument also measures the initial conductivity, C0, without ultrasonics, and the conductivity as a function of time, C=h(t), within the ultrasonic field. Fixed constants associated with the sensing probe should also be stored, including the specific heat (p) of the liquid 652, the volume (V) of the liquid 652 (in cubic centimeters), the mass (m) of the liquid 652 (in grams), and the functional relationship n=f(C,C0) between conductivity and the number of cavitation implosions occurring in the sensing probe tip 650a in 8.33 milliseconds determined by counting the sonoluminescence emissions over a 8.33 millisecond period and plotting this versus the conductivity measurement. The instrument then calculates the ultrasonic parameters from this information according to the following formulas:
cavitation density=D=nN=f(C,C0)/V
energy in each cavitation implosion=E=(0.00833)(p)(m)(g(t′))/f(C,C0)/t′
cavitation density as a function of time=f(h(t))/V
These three measured parameters are then fed back to the generator to continuously control the output of the generator to optimum conditions.
The energy in each cavitation implosion decreases as the frequency of the ultrasonics 676 increases and as the temperature of the solution 678 increases. The energy in each cavitation implosion is measured and compared to the optimum value (set by signal lines D-F) for the process, and if the measured value has a higher energy value than the optimum value, as determined by the comparators 686, the center frequency of the generator 680 is increased (by the controller 690 receiving data at the “center frequency input control”) until the values are equal. If there is not enough range in the center frequency adjustment to reach the optimum value, then the temperature of the solution 678 is increased by the control system 690 until the optimum value is reached. An alternative is to utilize a switchable frequency generator, as described above, so as to change the drive frequency to one where the energy in each cavitation implosion is not greater than the optimum value, and without changing the solution temperature.
The cavitation density increases as the ultrasonic power into the tank 684 increases. Therefore, the cavitation density measurement fed back to the generator 680 is compared against the optimum value of cavitation density for the process; and if the measured value is lower than the optimum value, the generator output power is increased (by the controller 690 receiving data at the “power control”) until the two values are equal. If the measured value is greater than the optimum value, the generator output power is decreased until the values are equal.
Cavitation density as a function of time is controlled by the amplitude modulation (AM) pattern of the generator output 692. Therefore the measured cavitation density as a function of time is measured and the generator's AM pattern is adjusted (via the controller 690 receiving data at the “AM Control”) until the measured function equals the optimum function.
A characteristic of the sample liquid 652a is that it produces photons when exposed to ultrasonic cavitation. These photons are measured by the photo sensor 657 to provide information about the cavitation field. According to one preferred embodiment, the photo sensor 657 is a photo multiplier tube, and the individual photons are measured and counted by the photo multiplier tube. The measurement of the photons provides a measure of the energy and the number of cavitation implosions present in the sample liquid, and the variation of this photon counting over time is a measure of how the cavitation density varies as a function of time. In alternative embodiments, if a more primitive device is used for the photo sensor 657, for example, a photo diode, the average intensity of the light output within the sample liquid can be measured, which provides a measure of the total energy in the cavitation implosions present in the sample liquid, and the variation of this total energy over time is a measure of how the cavitation density varies as a function of time. Alternatively, more than one photo sensors, which belong to different types of photo sensors, may be used within the sensing probe 650b.
The sensing probe in
100 VAC Japan, and intermittently during brown-outs in the U.S.
120 VAC U.S.
200 VAC Japan
208 VAC U.S.
220 VAC Most of Europe except Scandinavia and U.K.
240 VAC U.S., U.K., Norway, Sweden and Denmark
“Z” VAC Corresponding to unusual voltages found in France and other world locations
These voltages are obviously problematic for industry suppliers of ultrasound generators, who must supply the world markets. The invention of
In
Those skilled in the art should appreciate that methods and systems exist for utilizing the power line to acquire amplitude control for ultrasound generators. By way of example, the inventor of this application describes such systems and methods in connection with FIGS. 3, 4, 5A, 5B and 7 of International Application No. PCT/US97/12853. Specifically, an amplitude control subsystem is achieved by rectifying the AC power line and selecting a portion of the rectified line voltage that ends at the desired amplitude (such as between zero and 90 degrees or between 180 degrees and 270 degrees of the signal). In this manner, amplitude modulation is selectable in a controlled manner as applied to the signal driving the transducers from the generator. For example, by selecting the maximum amplitude of 90 degrees in the first quarter sinusoid, and 270 degrees in the third quarter sinusoid, a maximum amplitude signal is provided. Similarly, a one-half amplitude signal is generated by choosing the 30 degrees and 210 degrees locations of the same sinusoids. By way of a further example, a one-third amplitude signal is generated by choosing 19.5 degrees and 199.5 degrees, respectively, of the same sinusoids.
In another embodiment, the selected AC voltage angle can be reduced to lower the DC voltage to reduce the amplitude of the ultrasound drive signal.
The “power up sweep” features of the invention also apply to amplitude modulation, where an AM pattern of the AM frequency varies according to the power up-sweep techniques discussed above, and preferably at the same time with the techniques of “sweep the sweep rate”, as discussed herein. With power up-sweep AM, the AM pattern modulation creates an additional upward force on contamination while eliminating low frequency resonances.
Note that the sweep rate of the change of the AM frequency along the slope 616 can and preferably does change at a non constant sweep rate. The rate of AM frequency change can thus be non-constant. The degas period 612 can also be non constant. The degas period 612 can also be substantially “0”, so that no time is permitted for degas.
Generally, there are three ways to change the AM frequency. The burst length “L” (
A common feature in prior art tanks (ultrasound and non-ultrasonic) is a quick dump rinse feature (QDR) where a large valve in the bottom of the tank opens to allow the solution in the tank to quickly drain out of the tank. This QDR feature reduces the contamination residing on the parts under process as compared to the contamination that would reside if the liquid were removed more slowly from the tank, or if the parts were pulled out of the tank.
The conventional stacked transducer consists of a front mass, active polarized piezoelectric ceramic elements and a back mass. The length “L” of the transducer (from front mass to back mass) basically determines the transducer's primary and harmonic frequencies. As the fundamental frequency of the transducer becomes higher, the thickness of each of the transducer elements is reduced until they become impractical.
In
Another configuration of the transducer in
Most transducers discussed herein are longitudinal vibrators with elements sandwiched by a center bolt that holds the transducer assembly together and that provides a compressive bias to the active piezoelectric components (i.e., sandwiched between the a front mass and back mass or back mass). Since piezoelectric ceramic is strong under compression, but weak in tension, the constant compressive force provided by the spring constant of the bolt greatly improves the reliability of this transducer over other configurations.
The longitudinal vibrating transducer is normally connected to the tank or other surface that is to receive the sound energy by epoxy or brazing, or by a mechanical stud, or by a combination of these schemes.
The invention of
As in other transducers herein, the transducer 900 includes piezoelectric ceramics 916, associated electrodes 918, and lead-outs 920 for the electrodes 918.
The bias bolt 904 thus provides the first compressive force similar to other transducers herein. That is, the bolt 904 slides through the front mass 922 via the through-hole 924, and continues on through the ceramics 916. The back mass 910 has threads 910a which mate with the bolt 904; and thus the bolt 904 screws into the back mass 910. By tightening the bolt 904 into the back mass 910, the bolt 904 firmly seats into the counter-sink 922a of the front mass 922 and compression is applied to the ceramics 916.
As an alternative, the threads in the back mass 910 can be thru-holed; and a nut against the back mass can replace the threads to support compression bias on the piezoceramic 916.
The second compressive force derives from the operation of the second bolt 906, which compresses the epoxy 926 after seating within the counter-sink 904a of the first bolt 904 and after tightening the nut 914 onto the bolt 906. The front mass 922 is then bonded to the tank 908 via an epoxy layer 926. The second compressive force keeps a compressive bias on the epoxy 926 bond between the front mass 922 and the tank surface 908.
As an alternative, it is possible to eliminate the Belleville disc spring washer 912 and rely entirely on the spring tension in the second bolt 906; but the added feature of the Belleville disc spring washer 912 provides a larger displacement before tension goes to zero.
The second compressive bias of transducer 900 provides at least three improvements over the prior art. First, during the epoxy curing process, the bias keeps force on the epoxy bond 926 (even if the epoxy layer thickness changes during a liquid state) resulting in a superior bond. Second, during operation of the transducer 900, the reliability of the bond 926 is enhanced because of the constant mechanical compressive force. That is, epoxy bonds are weakest in shear forces, and reasonably strong in tension but superior in compression. Third, during abnormal conditions (e.g., a mechanical jar to the bonding surface) that might dislodge a conventionally bonded transducer, the second compression force with its spring characteristics absorbs the mechanical shock and protects the epoxy bond.
Those skilled in the art should appreciate that the double compression transducer 900 provides increased reliability when mounted with most any surface, and not simply an ultrasound tank 908.
The PCB 1030 and transducers 1032 are also substantially “integral” in construction so as to be a single unit. This provides structural integrity, and reduces the cost and size of the system.
The internal piezoceramics 1058 connect to wiring to drive the elements 1058 in the normal way. To protect the wiring and ceramics, it can be made from Teflon which is soldered to the ceramic 1058 by known methods, such as illustrated by solder joint 1064. This transducer will be referred to herein as the “acid transducer type construction”.
Drive network 2018 includes a blocking network 2028 and a multi-state power switch network 2030, which is coupled to the controller 2022 by way of line 2022a. The drive network 2020 includes a blocking network 2032 and a multi-state power switch network 2034, which is coupled to the controller 2022 by way of line 2022b.
In drive network 2018, the blocking network 2028 and switch network 2030 provide a unidirectional current flow path characterized by a first impedance from the potential +V through the first primary winding 2013d1 of center-tapped primary winding 2013d of transformer 2013 when the switch network 2030 is in a first (conductive) state. The networks 2028 and 2030 provide an oppositely directed current flow path characterized by a second impedance from circuit ground 2023a through 2013d1 to the potential +V when the switch network 2030 is in a second (non-conductive) state. The first impedance of the flow path established when network 2030 is in its first state is lower than the second impedance of the flow path established when the network 2030 is in its second state.
In drive network 2020, the blocking network 2032 and switch network 2034 provide a unidirectional current flow path characterized by a third impedance from the potential +V through the second primary winding 2013d2 of center-tapped primary winding 2013d of transformer 2013 when the switch network 2032 is in a first (conductive) state. The networks 2032 and 2034 provide an oppositely directed current flow path characterized by a fourth impedance from circuit ground 2023b through 2013d2 to the potential +V when the switch network 2034 is in a second (non-conductive) state. The third impedance of the flow path established when network 2034 is in its first state is lower than the fourth impedance of the flow path established when the network 2030 is in its second state.
The impedance (Z) of drive network 2018 when switch network 2030 is in its second state may be primarily determined by resistor 2028b (of value “R”), in which case Z has a value substantially equal to R for current flow in a direction toward +V, and a “near-infinity” value (i.e. relatively high) for current flow away from +V. In other embodiments, Z may be non-linear, normally lower at the beginning of operation in the second state and higher at times after the second state begins. For example, a metal oxide varistor (MOV) in parallel with a resistor (R) may be the primary determining factor for Z. In this case, at the beginning of operation in the second state when the voltage across Z is high, the low impedance of the on MOV primarily determines Z and later in the second state, as the voltage drops below the MOVs breakdown potential, Z is primarily determined by R.
A similar situation occurs for the impedance of drive network 2020 when switch network 2034 is in its second state.
Where the circuit 2000 is adapted to drive a ultrasound transducer, the capacitive element 2012 may be an electrostrictive device suitable for use as a ultrasound transducer. With such a configuration, for example, the controller 2022 may effectively control the circuit 2000 to drive such ultrasound transducers at a selectively controlled frequency. In various forms of the invention, the controller 2022 may be adaptively controlled so as to track variations in the resonant frequency for the respective ultrasound transducers, or to frequency modulate the frequency with a function such as a power up-sweep function, described above.
In operation, the controller 2022 cyclically switches the switch network 2030 between its first and second states at a frequency f (f=1/T), where f is less than or equal to fr (fr=1/Tr), where fr is the resonant frequency of the series LC network formed by 2012 and 2040, approximately equal to 1/(2*PI*Square Root(LC)), where PI is approximately 3.14159. During each cycle, network 2030 is controlled to be in its first state for a period greater than or equal to Tr/2, but less than or equal to T/2, at the beginning of each cycle. Network 2030 is controlled to be in its second state for the remainder of each cycle.
Similarly, the controller 2022 also cyclically switches the switch network 2032 between its first and second states at the frequency f (f=1/T). During each cycle, network 2032 is controlled to be in its first state for a period greater than or equal to T/2, but less than or equal to T/2, at the beginning of each cycle. Network 2032 is controlled to be in its second state for the remainder of each cycle. In the presently described embodiment, the start time for each cycle of the switching of network 2030 is offset by T/2 from the start time for each cycle of the switching of network 2034. In other forms, the start time for the cycle of the switching network 2030 may be offset by at least Tr/2 and less than Tr/2+D, where D equals T−Tr.
An AC voltage waveform (V0) at frequency f is impressed across the capacitive element 2012. Generally, this voltage waveform V0 passes from low to high and from high to low with a sinusoidal waveshape (at frequency fr). After rising from its low peak level to its high peak level, the voltage waveform stays substantially at its high peak level (except for droop due to resistive losses) for a period ½(T−Tr), or D/2, before passing from that high peak level to its low peak level. Similarly, upon returning to the low peak level, the voltage waveform V0 remains at that level (except for droop due to resistive losses) for a period ½(T−Tr), or D/2, before again passing to the high peak level.
Thus, the voltage impressed across capacitive element 2012 rises and falls at the resonant frequency fr with the capacitive element 2012 being maintained in its fully charged state for a “dead” time which is adjustably dependent upon the switching frequency f of the controller 2022. Accordingly, the drive frequency to the element 2012 may be adjustably controlled.
Where the element 2012 is a ultrasound transducer, circuit 2000 is used to drive that transducer at a frequency adjusted to match the optimal drive frequency. In various embodiments, variations in that optimal drive frequency may be detected and the controller may be adjusted in closed loop fashion to adaptively track such variations.
Blocking network 2028 includes a diode 2028a in parallel with a resistor 2028b, and the blocking network 2032 includes a diode 2032a and a resistor 2032b. The single inductor (L) 2040 operates in resonance with the element 2012.
Circuit 2000 is particularly useful with “fast” switching devices (such as bipolar, MOS and IGBT transistors) which do not require an extended turn-off time. In operation, the capacitive element 2012 and transformer 2013 function like the circuit of
In another implementation of circuit 2000,
With further reference to
In operation, power is applied to one generator (e.g., the 40 khz generator coupled to remote connector 2104a) via the 24 VDC signal from the rotary switch 2102. The following sequence then occurs with respect to FIGS. 58-60:2098 compatible with this embodiment. In
If the rotary switch 2102 is turned to the next position, e.g., to the 72 khz generator position, the following sequence occurs (assuming, worst case, that the rotary switch is moved very fast so there is zero time between the 40 khz position and the 72 khz position):
To avoid this “worst case” scenario, extra margin is provided by providing an off position between each rotary switch generator position. That is, the rotary switch can be labeled as follows:
OFF-40 khz-OFF-72 khz-OFF-104 khz-OFF-170 khz
Generators connected within this system preferably have a four socket reverse sex square flange AMP CPC receptacle with arrangement 11-4 (AMP part number 206430-1) installed on the rear of the generator. The mating four pin plug (AMP part number 206429-1) has the following pin connections:
The cable from the AMP plug is for example a Manhattan/Cot PIN M39025 control cable with four #24 AWG wires, with the following color codes: Pin#1 red; Pin#2 green; Pin#3 blue; and Pin#4 white.
Generators within this system can have a nine socket reverse sex square flange AMP CPC receptacle with arrangement 17-9 (AMP part number 211769-1) installed on the rear of the generator according to the following connections.
Socket #1: +RF output
Socket #2: not used
Socket #3: +RF output
Socket #4: −DC test point
Socket #5: −RF output, ground
Socket #6: cable shield, ground
Socket #7: +DC output interlock
Socket #8: +DC input interlock
Socket #9: waveform test point
The mating nine pin plug (AMP part number 211768-1) can have the following pin outs and color code when supplied with a three wire RF cable.
Pin#1: +RF output red
Pin #3: +RF output red
Pin #5: −RF output green/yellow
All pin#5s can for example be wired together and connected to the −RF transducer lead. All pin #1's are then connected together and connected to the +RF transducer lead coming from one-half of the transducers. All pin #3's are then connected together to the +RF transducer lead coming from the other one-half of the transducers. The only exception to this is when the generators do not all drive the same number of transducers.
The rotary switch 3010 (e.g., similar to the switch 2102,
As used herein, “lifetime” of a sound wave in a liquid contained in a tank or other container is defined as the time for the sound wave to decay from 90% to 10% of its intensity value after the sound energy input to the tank or container is stopped. Lifetime is a function of the sound frequency, type of liquid, shape and material of the container, and loading of the container.
As used herein, “degas time”, “quiet time”, “transition time” and “off time” are periods of time when the generator is supplying no electrical frequency drive signal to the array of transducers.
As used herein, “permutations of frequency ranges” means different orders of supplying the frequency ranges to the liquid. For example, if there are four frequency ranges, there are twenty-four permutations of these four frequency ranges.
As used herein, “cleaning packet” is defined as a permutation of frequency ranges.
As used herein, “intense” sound energy is defined as sound energy having amplitude suitable for cleaning and processing components; such amplitudes typically produce cavitation as is well known to those in the art.
As used herein, “frequency band” is defined as a continuous set of frequencies over which a transducer array can generate intense sound energy. These frequency bands are typically located around the fundamental frequency and the harmonics of the transducer array.
In
In
It should be noted that the center frequencies of this design are not integer multiples of the lowest (fundamental) frequency. The integer multiples of 39.75 khz are 79.5 khz, 119.25 khz, 159 khz, 198.75 khz, 238.5 khz, 278.25 khz, etc. None of these integer multiples are equal to the center frequencies of this design or the complete set of center frequencies possible with the transducer design in
It should also be noted that rather than a binary code to specify the frequency ranges, it is possible to use a BCD code or any other digital code to specify the frequency ranges. It is also possible to accomplish the same selection function with an analog level, for example, the analog level could be put into an ADC (analog to digital converter) and the ADC output could be used to drive the binary selection circuitry.
The system 70 in
A further advantage of this multiple frequency system is that it can reduce the intense cavitation region that occurs just below the liquid air interface. The location of this region is frequency dependent, therefore, by jumping from one frequency range to another, the intense region changes position and is averaged over a larger area.
An alternate way to control the frequency changes of this invention is shown in
It should be noted that the changing of frequency within a frequency range or amongst frequency ranges could be done with digital circuitry, analog circuitry or a hybrid combination of analog and digital circuitry. In the case of pure analog control, frequency changes within a range are normally high resolution, e.g., a different frequency every one half of a cycle, every one-quarter of a cycle or lesser fraction of a cycle. In the case of digital circuitry or hybrid analog digital circuitry, the resolution of changes depends on the speed at which the digital number is changed. This causes the staircase type of function when the resolution is low, e.g., several cycles of one frequency before several cycles of a different frequency are produced. In the purest sense, all changes can be considered a staircase function because, for example, the one half cycle changes can be considered stairs with a width equal to the time of the one half cycle.
The above designs adjust the duty cycle of the generator output to regulate and/or control the output power of the system. It is sometimes advantageous to regulate and/or control the output power of the system by adjusting the amplitude of the generator's output voltage instead of the duty cycle. One way to accomplish this is by replacing the DC power supply in
It is well known in the cleaning industry that each different frequency best removes a specific type and size of contamination. The inventor of this system has observed that the order in which the different frequencies are delivered to the liquid produces a new cleaning effect that best removes a specific type and size of contamination. For example, if the system produces three frequency ranges, say centered on 71.5 khz, 104 khz and 167.2 khz, then there are six different orders or permutations of the frequency ranges that can be delivered to the liquid. They are (71.5, 104, 167.2); (71.5, 167.2, 104); (104, 71.5, 167.2); (104, 167.2, 71.5); (167.2, 71.5, 104) and (167.2, 104, 71.5). Since contamination typically occurs in many different types and sizes, the more new cleaning effects that the contamination is exposed to, the more contamination that will be removed. An additional advantage is obtained by changing the order in which the different permutations of frequency ranges are delivered to the liquid. If in the example, each permutation is considered a cleaning packet, then there are six cleaning packets. There are 720 different ways these cleaning packets can be ordered, each producing a useful cleaning effect that can be supplied in a practical manner with this inventive system.
The generator detailed in
Referring now to the drawings in detail, for the ease of the reader, like reference numerals designate identical or corresponding parts throughout the views depicted in the drawings. It should be noted that each embodiment of the present invention is not depicted by a drawing; nor are each of the notable applications of the present invention depicted by a drawing.
The first structure 44 defined in
Capacitor 36 and triac 37 demarcate the second structure 45 in
The above two structures can form a more complex structure 46 which is an active/passive modification circuitry comprising capacitors 19, 36 and triac 37. This modification circuitry is in parallel with triac 35 to form the third structure 46, which is a parallel structure. The practical effect of this third structure 46 is to connect the ultrasound generator output directly to the transducer array when triac 35 is on. When triac 35 is off, it will place a capacitance in series with the transducer array (either capacitor 19 or 19 plus 36 depending on the state of triac 37) when triac 35 is off. This is useful when generating lower frequencies in a multiple frequency ultrasound generator, because when triac 35 is on, it eliminates the higher frequency structures from the system.
The fourth structure 47 present, as shown in
The fifth structure 48, as shown in
The sixth structure 49, as shown in
The five gates of triacs 35 to 43 can be controlled individually, as are the gates as depicted in
The
The binary code for the logic in
When the capacitance of the transducer 77 is defined to be a capacitance value 77, then with all the triacs in their off state, oscillator 10 produces a frequency approximately equal to f1 where
When triac 83b is turned on by the controller 12, thereby putting a high level on line 74 during operation of the oscillator (while maintaining the high level on line 74 or while maintaining the current flow through triac 83b or maintaining both of these conditions, i.e., maintaining the on state of triac 83b), the oscillator changes frequency from the above value to approximately f2, where
Therefore, the oscillator frequency made a step change from frequency f1 to a lower frequency f2.
In a similar fashion, when triac 84b is then turned on by the controller 12, thereby putting a high level on line 75 during operation of the oscillator (while maintaining the on state of triacs 83b and 84b), the oscillator changes frequency from the above value to approximately f3, where
Therefore, the oscillator frequency made a step change from frequency f2 to a lower frequency f3.
In a similar fashion, when triac 85b is then turned on by the controller 12, thereby putting a high level on line 76 during operation of the oscillator, the oscillator changes frequency from the above value to approximately f4, where
Therefore, the oscillator frequency made a step change from frequency f3 to a lower frequency f4.
The above examples show a method to step sweep the output frequency of an oscillator from a high frequency to a lower frequency by successively turning on additional series structures comprising a capacitor modification circuitry and a triac. According to the invention, it is then necessary for the controller 12 to output a short circuit between lines 72 and 73 to turn the oscillator 10 off before the triacs 83b, 84b and 85b can be turned off. In a preferred embodiment, the controller 12 turns off all the triacs during this generator off time. The generator off time is timed to be at least as long as the triac turn off time plus the decay time of the sound field. Then the cycle of turning on the triacs one at a time to step sweep from the highest frequency f1 to the lowest frequency f4 can occur again. The controller then starts another oscillator off time where all the triacs are turned off and the cycle repeats. This step swinging operation can be accomplished with the control circuit, as shown in
It is clear to those skilled in the art that the circuit in
Any permutation of these eight frequencies (8! or 40,320 permutations) can be organized into a cycle by the controller 12 and supplied to the transducer. It should be noted that for any frequency change that does not require a triac to be turned off, the frequency change can be accomplished without the controller 12 turning off the oscillator. However, if any frequency change occurs where one or more triacs have to be turned off, then the controller 12 concurrently turns off the oscillator for a time at least as long as the turn off time of the triacs plus the decay time of the sound field.
With reference to
Another application of the present invention is to change the output power and amplitude of a ultrasound generator. With some ultrasound generators that are not of the self-oscillating type (
In an ultrasonic or microsonic cleaning or processing liquid, it is known that a particular frequency or a set of closely spaced frequencies will resonate a certain size population of bubbles or voids within the liquid. A conventional sweeping frequency ultrasonic or microsonic cleaning or processing signal produces a particular frequency or a set of closely spaced frequencies followed by the next particular frequency or set of closely spaced frequencies adjacent to the first particular frequency or set of closely spaced frequencies.
Unfortunately, cavitation efficiency suffers with this type of conventional sweeping frequency ultrasonic or microsonic cleaning or processing signal because the first particular frequency or set of closely spaced frequencies depletes members of that certain size population of bubbles or voids within the liquid leaving a smaller population for the second adjacent particular frequency or set of closely spaced frequencies to resonate.
There is shown in
In a preferred embodiment, drive signal 3100 can be maintained in the upper half of a bandwidth. The bandwidth is typically 10% of the center frequency (unless the system employs a special design/procedure, e.g., overlapping transducers frequency ranges). Therefore, for a center frequency at the high end of the microsonic frequency range (350 khz), the bandwidth is typically 35 khz. For 40 khz ultrasonic transducers, the bandwidth is typically about 4 khz. After a defined period of time (i.e., before cavitation efficiency suffers) at point 3102, the frequency is changed to a new frequency that is typically one half bandwidth lower than the current frequency. This change in frequency may occur by sweeping the frequency to the new lower frequency (not shown; wherein the sweep time is typically less than 25% of the defined period of time), or stepping the frequency to the new lower frequency, as shown in
While a one half bandwidth frequency jump is typical, other amounts are possible. For example, the frequency may be jumped by a much larger percentage of the bandwidth, e.g., from a frequency proximate the lower limit of the bandwidth to a frequency proximate the upper limit of the bandwidth, such as from point 3110 to point 3112. Less than one-half bandwidth changes can also be used and are an improvement over the prior art; however, they are not as optimum an improvement as the preferred embodiment described herein.
Further, while the system is described above as sweeping the frequency between points 3104 and 3106, other configurations are possible. For example, the frequency may be maintained constant (not shown) during the defined period of time. Alternatively, the frequency may be changed (between points 3104 and 3106) via one or more frequency steps (shown in phantom); or the set of closely spaced frequencies between points 3104 and 3106 may be random frequencies (not shown).
This frequency sweeping and frequency jumping continues until striking the lowest frequency in the bandwidth (at point 3110). At this point, the frequency jumps to the highest frequency in the bandwidth (to point 3112), and the sweeping and jumping process is repeated until the lowest frequency in the bandwidth is reached again (not shown). This high cavitation efficiency process is repeated and continued for the time needed in that particular bandwidth.
If a multiple frequency generator is driving a multiple frequency transducer array with a set of defined bandwidths (e.g., multiple harmonic or overtone bandwidths), then after the time needed in a particular bandwidth has elapsed, the drive signal may change to a different bandwidth and may produce a similar high cavitation efficiency signal in that different bandwidth. Also, in the case of a multiple frequency generator driving a multiple frequency transducer array with a set of defined bandwidths, the change or jump (upon the depletion of a certain size population of bubbles or voids within the liquid) can be to a frequency in another bandwidth. This has the added advantage that besides a new bubble population for increased cavitation efficiency, the cavitation in the prior bandwidth typically produced bubbles that are resonant in the new bandwidth to which the signal changed or jumped.
In the prior art generator and transducer array systems, it is typical to have amplitude modulation of a frequency modulated waveform as the output signal from the generator and driving the transducer array. A typical amplitude modulation pattern is full wave modulation and a typical frequency modulation pattern is a triangular sweeping frequency waveform. The inventor has found that the cleaning or processing efficiency when using this type of waveform drops off as the process continues because the single form of cavitation produced by the given waveform can not do all aspects of the process efficiently. The inventor has found that using two forms of cavitation, where the first form is predominantly stable cavitation and the second form is predominantly transient cavitation, allows the process to proceed to a more complete level, for example, in the case of a cleaning process, the two forms of cavitation applied in succession over a given time span result is a lower percentage of particles left on the part being cleaned than will occur with one form of cavitation being applied over the same time span.
There is shown in
The following waveforms and systems are used to produce predominantly stable cavitation and the existence of any one or combination at the output of a generator or system supplements the classical definition of stable cavitation for the purposes of this invention. (1) Rapidly changing frequencies (sweep rates) where the frequency change (df/dt) is greater than (0.106)*(fc) Mhz per second, where fc is the average of the highest frequency in khz and the lowest frequency in khz in the set of rapidly changing frequencies (typically, this set of frequencies is within a bandwidth of operation of the transducer array) and the delivered power is in the range of 25 to 60 watts per transducer. (2) Narrow rectangular pulse width amplitude modulation where the pulse width is less than 24/Pp milliseconds, where Pp is the peak power of the pulse in watts and the frequency change (df/dt) ranges from zero to less than (0.106)*(fc) Mhz per second. (3) Irregular shaped amplitude modulation where the area under the power versus time curve for each pulse is less than 24 milliwatt-seconds per transducer in the array. (4) Changing to a new frequency set or bandwidth before the onset of imploding cavitations, this is typically before 24 milliwatt-seconds per transducer of acoustic power is delivered at the current frequency set or bandwidth. (5) Sweeping a full wave modulated waveform at a rate below (0.106)*(fc) Mhz per second while chopping the amplitude into pulses that change in width to maintain an area under each pulse curve that is less than 24 milliwatt-seconds per transducer. (6) Applying conventional normal power operation to a concurrent multiple ultrasound frequency system where the growth and decay of bubbles simulates the effects of stable cavitation.
Waveforms to produce transient cavitation are well known to those skilled in the art of ultrasonic cleaning. Optimum sweep rates, typically in the range of 120 to 550 hz combined with wide pulses or full wave modulation (typically repetitive every 8.33 milliseconds or every 10 milliseconds) produce the best state of the art cavitation. Improved transient cavitation efficiency as described above and shown in
The teachings above and as shown in
It has long been known that the microbiological action of certain microbiologically active chemicals such as glutaraldehyde or IPA is improved by the application of ultrasound to the microbiologically active chemicals. A review of the literature shows that this ultrasound was the type that has predominantly transient cavitation or was generated by equipment known to produce predominantly transient cavitation. The use of ultrasound with predominantly stable cavitation as described herein gives additional improvement in the speed of the microbiological effect of the microbiologically active chemicals. This microbiological effect is further improved by a succession of predominantly stable and predominantly transient cavitation.
The inventor has found that the addition of an electrolyte, for example, NaCl, to an aqueous solution, the application of UV light and/or the application of an electric current have a significant microbiological effect toward improving the speed of organism inactivation. Consider these organism inactivation processes along with the cavitation processes described herein, i.e., predominantly stable cavitation, a succession of predominantly stable and predominantly transient cavitation, predominantly transient cavitation and multiple frequency processes, and many improved (improvement is defined as achieving inactivation or reducing the process time needed to achieve a specified inactivation) organism inactivation processes result. Some of the most effective ones showing the greatest improvement over prior art are listed below.
Microbiologically active chemicals with a succession of predominantly stable and predominantly transient cavitation produced within this chemistry.
Aqueous chemistries with an electrolyte added, and electric current flowing through the chemistry.
Clear liquids such as water with UV light applied and a succession of predominantly stable and predominantly transient cavitation applied.
Microbiologically active chemicals with multiple frequencies applied to this chemistry.
Applying a succession of different frequencies (multiple frequencies) to the liquid.
Simulating the effects of stable cavitation with normal power operation of a concurrent multiple ultrasound frequency system by the growth and decay of bubbles to enhance the production of active media in the liquid such as hydrogen peroxide, ozone, super oxygen, ions and other radicals which have a chemical inactivation effect on the organisms
It is understood by one skilled in the art that many other combinations of the eight stated process parameters, i.e., multiple frequencies, predominantly stable cavitation, predominantly transient cavitation, a succession of predominantly stable and predominantly transient cavitation, UV light, electric current, an electrolyte and microbiologically active chemicals, give improved ways to inactivate organisms.
In another preferred embodiment, a method for cleaning and processing is provided by supplying both concurrent multiple ultrasound frequencies and successive multiple ultrasound frequencies in series to a liquid to improve the efficiency of the cleaning or processing.
In another embodiment of the invention a method for cleaning or processing an object in a liquid medium comprises the steps of driving two or more first transducer arrays coupled to the liquid medium for a first time period, each of the first transducer arrays being driven at an associated drive frequency, the above frequencies being different from each other, driving one or more second transducer arrays coupled to the liquid medium for a second time period, the second time period being different from the first time period, each of the second transducer arrays being driven at an associated drive frequency. This embodiment also includes the method where the first time period precedes the second time period. This embodiment also includes the method where the first and second time periods are contiguous. This embodiment also includes the method where the first and second time periods are non-contiguous. This embodiment also includes the method where the drive frequency of at least one of the second transducer arrays is the same as the drive frequencies of one of the first transducer arrays. This embodiment also includes the method where the drive frequencies of the second transducer arrays are different from the drive frequencies of the first transducer arrays. This embodiment also includes the method where at least one of the first transducer arrays includes only a single transducer. This embodiment also includes the method where at least one of the first transducer arrays includes two or more transducers. This embodiment also includes the method where at least one of the second arrays includes only a single transducer. This embodiment also includes the method where at least one of the second transducer arrays includes two or more transducers.
In another embodiment of the invention a method for cleaning or processing an object in a liquid medium comprises the steps of driving two or more first transducer arrays coupled to the liquid medium for a first time period, each of the first transducer arrays being driven at an associated drive frequency, the above frequencies being different from each other, driving one or more second transducer arrays coupled to the liquid medium for a second time period, the second time period being different from the first time period, each of the second transducer arrays being driven at an associated drive frequency and where the second time period precedes the first time period. This embodiment also includes the method where the first and second time periods are contiguous. This embodiment also includes the method where one of the transducers of the first transducer array is one of the transducers of the second transducer array.
A resonant standing wave of the particular frequency being employed can be formed within transducer assembly 770 in which transducer assembly 770 experiences maximum molecular displacement at the antinodes of the resonant standing wave within it and no molecular displacement at the nodes of the resonant standing wave. While heat generation at the interfaces is not generally a limitation at frequencies in the lower microsonic and ultrasonic ranges, ultrasonic transducers cannot generally be operated off resonance in the upper microsonic and megasonic ranges and cannot therefore be swept off of their center frequencies at frequencies in the upper microsonic and megasonic ranges because polarized piezoelectric ceramic elements 755 and 757 over-heat due to the friction at the interfaces between one another and between them and front mass 753 and back mass 759, making high amplitude resonance within the processing tank impossible with previous constructions.
In the embodiment shown in
By constructing transducer assembly 770 with each layer of a particular thickness, transducer assembly 770 can be operated at a frequency within the upper microsonic and megasonic ranges and sweep within the lower microsonic and ultrasonic frequency ranges because at the highest frequency, the nodes of the high frequency wave exist at the interfaces and there is no agitation (positive or negative displacement) of the molecules at the nodes, reducing energy losses due to friction between the components and allowing transducer assembly 770 to become under damped when operated at the upper microsonic or megasonic frequency, resulting in resonance within transducer assembly 770 and the ability of transducer assembly to create cavitating power at the higher frequencies. By constructing transducer assembly 770 such that the nodes of the fundamental frequency exist at the interfaces, coupled with the cooling effect of back mass 759 and front mass 753, megasonic and upper microsonic sweeping is possible. Thus, transducer assembly 770 of the present invention can be operated throughout the lower microsonic and ultrasonic ranges, and at a specific frequency in the upper microsonic and megasonic ranges, as well as at sweeping frequencies as much +/−5% of the center frequency in the upper microsonic and megasonic ranges. The inventor has experimentally found unique advantages over the single frequency prior art megasonics equipment by sweeping frequency at megasonic frequencies. The collimated megasonic characteristic of the prior art is reduced by sweeping megasonics and the process efficiency is improved because there is less absorption of sound energy when sweeping compared to prior art single frequency megasonics.
The same transducer assembly 770 can also be operated throughout the ultrasonic and low microsonic frequency ranges because, even though the nodes and antinodes may not exist at the interfaces, the friction and heat generated at these relatively low frequencies is not significant enough to damage the piezoelectric ceramics. Transducer assembly 10 operates in the low ultrasonic and/or low microsonic frequencies in the same fashion as a Langevin transducer with harmonics, i.e., the lowest frequency is the half wavelength resonance of the complete stack, and higher frequencies are harmonics or overtones of this selected or fundamental resonance.
The thickness of transducer assembly 770 determines the “fundamental resonant frequency.” The fundamental resonant frequency of a transducer is that specific frequency or bandwidth in the ultrasonic frequency range at which the transducer can be operated. “Bandwidth” is the range of frequencies in a resonant or harmonic region of a transducer over which the acoustic power output of a transducer remains at least 50% of the maximum output value. Typically, this bandwidth is approximately plus or minus as much as 5% of the center frequency. For example, a 40 khz transducer can be used at approximately 40 khz+/−2 khz, or between 38 and 42 khz; and at 700 khz the transducer can be used at approximately 700 khz plus or minus as much as 35 khz, or at an off-center frequency range with a minimum value of 665 khz and a maximum value of 735 khz.
In addition, according to the embodiment of transducer assembly 770 shown in
Furthermore, back mass 759 is also an integer number of half wavelengths of the fundamental frequency plus one quarter wavelength thick. As with front mass 753, this thickness places an antinode of the resonant standing wave at the back most surface of transducer assembly 770, i.e., back surface 772 of back mass 759. Having an antinode at back surface 772 of back mass 759 allows for positive and negative displacement at that point of back mass 759 which supplies and equal and opposite reaction to the positive and negative displacement of front mass 753 at the interface with processing tank 769 so that transducer assembly 770 can exert a high force on tank 769. That is, front mass 753 exerts a pulse against processing tank 769 and back mass flexes in an opposite direction. Without this extra quarter wavelength thickness, there would be no displacement at back surface 772 of back mass 759 and no way to have an opposite reaction to the displacement force of the front surface of front mass 753 towards processing tank 769. It is important to note that while the most efficient operation results if every interface is at a node, it is not necessary that every node be at an interface. That is, additional nodes can exist within front mass 753, polarized piezoelectric ceramic elements 755 and 757, and back mass 759.
Back mass 759 and front mass 753 can be made of steel, aluminum, aluminum alloys, titanium, titanium alloys, ceramic, quartz, or most any other material that is able to conduct sound (i.e., does not absorb sound waves). Examples of materials which absorb sound, and are therefore not useful materials for constructing back mass 759 and front mass 753, include Teflon, sponge, rubber, and polypropylene. Furthermore, if transducer assembly 770 is mounted within processing tank 769, the material(s) chosen must be able to resist any corrosive characteristics of the cleaning solution. Still further, front mass 753 and back mass 759 can be made of different materials for the same transducer assembly 770. For example, transducer assembly 770 can be constructed with back mass 759 being made of silicon and front mass 753 made of aluminum.
Because sound travels at different speeds in various materials, the exact thickness of both front mass 753 and back mass 759 depend on the material chosen and the speed of sound in that particular material. If sound moves through a material relatively fast, a thicker amount of the material would be needed to be as thick as the same integer number of half wavelengths as compared to a material in which sound moves slower.
Polarized piezoelectric ceramic materials are generally very strong when compressed, but weak when under tension, i.e. pulled apart. Polarized piezoelectric drive elements 755 and 757 rapidly expand and contract when subject to an electric current. As they expand, without clamping assembly 771, they would go into tension and consequently have short life spans. By using clamping assembly 771, polarized piezoelectric ceramic elements 755 and 757 of transducer assembly 770 remain under constant pressure throughout the entire cycle of expansion and contraction.
The double bolt construction of transducer assembly 770 is only used for illustrative purposes. It is the location of the nodes at interfaces 754, 756 and 758 of transducer assembly 770 along with the antinodal points of the resonant standing wave approximately at the junction surface between front mass 753 and processing tank 769 and at the back surface of back mass 759 that allows it to operate at both one frequency or a bandwidth of frequencies at the highest frequency (megasonic and upper microsonic) and an additional set of frequency bandwidths throughout the lower frequencies (low microsonic and low ultrasonic). However, one of ordinary skill in the art will recognize that other clamping assemblies known in the art which keep ultrasonic transducer 770 under pressure may also be employed.
Transducer assembly 770 depicted in
The specific nodal pattern exists for only one frequency or bandwidth around a center frequency in the megasonic or upper microsonic range, and operation of transducer assembly 770 of the present invention is, in some cases, limited to this one selected frequency, as is common with megasonic equipment. This transducer assembly 770, however, is also capable of operating throughout the low microsonic and low ultrasonic ranges. In a more general case, frequency changes (for example, sweep frequency) around this specific center frequency with nodes 754, 756 and 758 being slightly displaced from the interface at the frequencies off of a center frequency result in six distinct ways transducer assembly 770 of
as a single frequency megasonic transducer;
as a sweeping frequency transducer in the megasonic frequency range, capable of reliably producing high intensity sweeping frequency sound at these high frequencies;
as a sweeping frequency transducer in the upper microsonic frequency range, capable of reliably producing high intensity sweeping frequency sound at these high frequencies;
in multiple frequency systems where there is single frequency drive at a megasonic frequency and sweeping frequency drive at one or more frequencies in the low ultrasonic and/or low microsonic frequency ranges;
in a multiple frequency system where there is sweeping frequency drive at a megasonic frequency and sweeping frequency drive at one or more frequencies in the low ultrasonic and/or microsonic frequency ranges; and in a multiple frequency system where there is sweeping frequency drive at an upper microsonic frequency and sweeping frequency drive at one or more frequencies in the low ultrasonic and/or microsonic frequency ranges.
The ultrasonic generator drives the transducers at frequencies within a bandwidth to obtain broadband acoustical disturbances within the liquid. In one embodiment, the ultrasonic generator sweeps at frequencies through the overall bandwidth and simultaneously varies the rate at which those frequencies are changed. That is, the ultrasonic generator has a “sweep rate,” the rate at which the ultrasonic generator changes from one frequency within the bandwidth to the next, which varies as a function of time (a phenomenon denoted herein as “sweeping the sweep rate”). The sweep rate could also be varied linearly, randomly, or as some other function of time to optimize the process conditions within the cleaning tank. In an alternate embodiment, the ultrasonic generator produces a “random sweep rate,” as defined supra.
As further identified herein, this system is also applicable in certain embodiments to ultrasonics. For example,
As shown in
With further reference to
Megasonic transducers as are known in the art are driven at a resonance frequency or at an anti-resonance frequency. In contrast, in the preferred embodiment the megasonic transducers are driven at a frequency between resonance and anti-resonance. Further, when a megasonic transducer consists of multiple piezoelectric ceramic segments in parallel, as is practiced in the prior art, and these multiple piezoelectric ceramic segments in parallel are driven by a generator with a phase lock loop (PLL) used to maintain operation at the anti-resonant frequency, because of an averaging effect, conventional state of the art generators drive some of the piezoelectric ceramic segments at a frequency higher than the anti-resonant frequency. This causes lower performance operation of those segments. This lower performance operation is overcome in the preferred embodiment because all of the piezoelectric ceramic segments are driven between their individual resonant and anti-resonant frequencies.
For megasonic systems where the PLL locks on the anti-resonant, four techniques are provided that accomplish the improved performance of driving every piezoelectric ceramic segment in any transducer assembly at a frequency between its individual resonant and anti-resonant frequencies. The first technique uses a matching network at the piezoelectric ceramic segments to cause zero phase shift at a frequency lower than the anti-resonant frequency of the lowest frequency piezoelectric segment. The second technique uses a network in the output of the megasonic generator to cause zero phase shift at a frequency lower than the anti-resonant frequency of the lowest frequency piezoelectric segment. The third technique uses a PLL designed to lock onto a non-zero phase shift condition, in this case, a phase angle occurring between resonance and anti-resonance. The fourth technique delays the true voltage signal prior to sending it to the phase detector of the PLL so that when the PLL locks onto zero phase shift, it is maintaining a condition where the true voltage leads the current, which is the condition for operation between resonance and anti-resonance with a PLL designed to search for the anti-resonant frequency.
For megasonic systems where the PLL locks onto the resonant frequency rather than the anti-resonant frequency, the improvement of driving at a frequency between resonance and anti-resonance still applies. However, there are several implementation changes that must be made because when a PLL controlled megasonic generator is designed to operate at the anti-resonant frequency, the PLL searches toward lower frequencies when the output current leads the output voltage and the PLL searches toward higher frequencies when the output voltage leads the output current. The operation is reversed when a PLL controlled megasonic generator is designed to operate at the resonant frequency. The PLL searches toward higher frequencies when the output current leads the output voltage and the PLL searches toward lower frequencies when the output voltage leads the output current. Four techniques that accomplish the improved performance of driving every piezoelectric ceramic segment in a transducer assembly at a frequency between its individual resonant and anti-resonant frequencies for PLL search arrangements designed to lock onto the resonant frequency may be used.
The first technique uses a matching network at the piezoelectric ceramic segments to cause zero phase shift at a frequency higher than the resonant frequency of the highest frequency piezoelectric segment. The second technique uses a network in the output of the megasonic generator to cause zero phase shift at a frequency higher than the resonant frequency of the highest frequency piezoelectric segment. The third technique uses a PLL designed to lock onto a non-zero phase shift condition, in this case, a phase angle occurring between resonance and anti-resonance. The fourth technique shifts the true voltage signal back in time prior to sending it to the phase detector of the PLL so that when the PLL locks on zero phase shift, it is maintaining a condition where the true voltage leads the current, which is the condition for operation between resonance and anti-resonance with a PLL designed to search for the resonant frequency.
In the first embodiment, a network 7032 is placed between the electronic bridge circuit 7031 (preferably a half bridge 7048 or full bridge 7051 topology) and the assembly of transducers 7033 (preferably a transducer assembly that is a sweeping frequency or a transducer assembly that operates at various single frequencies within a PLL search bandwidth depending on the particular resonant frequency characteristics of the transducer assembly). The network is synthesized in combination with the transducer impedance characteristics such that the drive signal from the electronic bridge circuit always has the voltage leading the current by a phase angle between about one degree and about 89 degrees within the bandwidth of operation. This results in the simplest, least expensive, most reliable and most efficient sweeping frequency generator 7009. A further improvement is to synthesize the network such that the magnitude of its phase shift is highest at the resonant frequency of the transducer assembly or in the middle region of the bandwidth of frequencies and decreases or approaches zero as the frequency sweeps to either end of the bandwidth. This adds a feature of a more constant power versus frequency over the sweep bandwidth. Data indicates that cleaning improves as the power versus frequency curve approaches a flat line. Although this network shows the greatest advantage at megasonic frequencies where losses are often higher than at lower ultrasonic frequencies, this phase shifting network is also applicable to other ultrasonic frequencies in the range from about 18 kHz up through the megasonic frequencies.
An electronic bridge circuit (a half bridge or full bridge topology) operates with current flowing forward through the switching devices and backwards through antiparallel or body diodes in parallel with the switching devices. When current through one of the diodes is reversed, the phase shift network in combination with the transducer impedance characteristics sets up a condition that the device that the diode is in parallel with is also on. This allows the reverse recovery current of the diode to flow with low voltage across the diode (i.e., the switching device on voltage). Therefore, there is insignificant power dissipation due to this reverse recovery current. Without the phase shift network in combination with the transducer impedance keeping the electronic bridge circuit output voltage leading the output current by an angle that is greater than 0 degrees and less than about 90 degrees, operational conditions occur where current through at least one of the diodes is reversed when the device that the diode is in parallel with is off. This causes the reverse recovery current of the diode to flow from the power supply voltage of the electronic bridge circuit to ground. Therefore, there is power dissipation due to this reverse recovery current equal to the power supply voltage times the reverse recovery current integrated and averaged over time. This power dissipation typically occurs every half cycle of the electronic bridge circuit resulting in significant power loss and inefficiency.
The preferred embodiment employs either a half bridge topology or a full bridge topology. An electronic bridge circuit 7031 with an output supplying an output voltage 7036 and an output current 7037 and operational over a bandwidth of frequencies is provided. The electronic bridge circuit is coupled to a phase shift network 7032 and the phase shift network is coupled to a transducer assembly 7033. The electronic bridge circuit has output terminals from which the output voltage and the output current are supplied. The phase shift network has input terminals and output terminals, and the output terminals of the electronic bridge circuit are coupled to the input terminals of the phase shift network. The transducer assembly has input terminals, the output terminals of the phase shift network are coupled to the input terminals of the transducer assembly. The phase shift network coupled with the transducer assembly causes the output voltage of the electronic bridge circuit to lead the output current of the electronic bridge circuit by an angle greater than 0 degrees and less than about 90 degrees for all frequencies within the bandwidth of frequencies. An added enhancement to the operation of the electronic bridge circuit is to employ a loop inductance of between 3 nanohenrys and 27 nanohenrys and gate drive dead times between 97 nanoseconds and 787 nanoseconds to reduce spurious oscillations and to increase efficiency of the system.
The electronic bridge circuit with phase shift network and with transducer assembly can be used to produce a specific power curve versus frequency (P=h(f)) by synthesizing the phase shift network coupled with the transducer assembly such that the output voltage of the electronic bridge circuit leads the output current of the electronic bridge circuit by an angle that varies as a function of frequency g(f) over the bandwidth of frequencies to produce the specified function h(f) for the power versus frequency over the bandwidth of frequencies. The bandwidth of frequencies for the electronic bridge circuit are typically the set of lock frequencies for a phase lock loop which sets the system frequency or, if the system sweeps frequency, then the bandwidth of frequencies are the range of frequencies over which the system sweeps.
As shown in
As shown in
The phase of the voltage 7036 and current 7037 out of electronic bridge circuit 7031 is determined by the impedance into terminals 7038 and 7039 of phase shift network 7032. Since phase shift network 7032 is coupled to ultrasound transducer assembly 7033, the impedance into terminals 7038 and 7039 of phase shift network 7032 is both a function of the phase shift network 7032 impedance and the transducer assembly 7033 impedance. This impedance into terminals 7038 and 7039 of phase shift network 7032 is synthesized such that the voltage 7036 leads the current 7037 by a phase angle 7046 of between about one degree and eighty nine degrees.
As mentioned above,
In the preferred embodiment, shown in
The megasonic generator of the preferred embodiment is designed to be capable of switching between single frequency operation and sweeping frequency operation. Generator 7009 produces a process that is superior to conventional state of the art processes because it allows two distinct cavitation characteristics to be employed in the cleaning or processing operation. For example, a multiple frequency megasonic system operating at a phase lock loop frequency of 950 kHz or a phase lock loop frequency of 2.85 MHz is provided to also sweep frequency in a bandwidth around 950 kHz and in a second bandwidth around 2.85 MHz. A delicate part with critical cleaning requirements may require transient cavitation to remove some of the contamination, but the typical transient cavitation existing in a conventional state of the art 1 MHz megasonic system is too harsh and does damage to the part. With this embodiment of generator 7009, the mode of sweeping frequency around 2.85 MHz is used for gentle transient cavitation, followed by single frequency 950 kHz, and followed by single frequency 2.85 MHz to produce stable cavitation of sizes appropriate for submicron particle removal.
As mentioned above, one of the preferred combinations of modes possible with system 7002 is a process in which mode 7068 is performed first, followed by mode 7064, followed by a final process step of mode 7067. This process is advantageous because a delicate part with critical cleaning requirements may require transient cavitation to remove some of the contamination, but the typical transient cavitation existing in a state of the art megasonic system is too harsh and does damage to the part. With this method, mode 7068 sweeps at the third overtone frequency 7070, which produces gentle transient cavitation. Mode 7068 is then followed by a single frequency at the fundamental frequency 7064 and is then followed by a single frequency at the third overtone 7067 to produce stable cavitation of sizes appropriate for submicron particle removal.
Another combination of modes not available in state of the art megasonic systems is a multiple frequency process consisting of different megasonic frequencies produced by the same megasonic transducer assembly. For example, with system 7002 capable of producing mode 7064 and mode 7067, a process is provided that employs this multiple megasonic frequency operation. The advantage to this system and process over state of the art megasonic systems is that each different frequency removes a different particle size most effectively. Therefore, a larger range of contamination can be cleaned in a shorter time by this process and system, that is the process concept shown in
Another combination of modes is a significant advance over state of the art megasonic systems. This combination of modes does not require the capability of multiple frequencies, but rather uses sweeping frequency for one time period in one megasonic frequency band around one megasonic frequency, followed by single frequency operation for a second time period at the megasonic frequency. For example, system 7002 may produce mode 7065 and mode 7064. Another example is to produce mode 7068 and mode 7067.
For larger systems having the modes shown in
In another embodiment, the megasonic generator is provided with multiple driver sections each with independent PLL (phase lock loop) and closed loop power control. Each of the multiple generator sections is configured and wired to drive one segment or section of piezoelectric ceramic transducer. This new system 7083 gives the process engineer power control over each transducer segment or section while each segment or section is operating at an optimum closed loop frequency. The process engineer can then adjust each segment or section of a particular megasonic transducer for uniformity or for another specified power distribution curve that the process requires. The closed loop power control then maintains this condition for long term process optimization.
The system shown in
In the preferred embodiment, the generator 7009, transducer 7033 and transducer matching network 7088 are configured for higher efficiency and lower cost than exists with state of the art megasonic systems. One conventional configuration is to connect the piezoelectric transducer to the generator through a cable. This is inefficient because the current flowing into and out of the capacitive component of the piezoelectric transducer causes heating of the cable and power loss. Another present day configuration is to use a transformer and reactive components at a piezoelectric megasonic transducer to match the impedance of the piezoelectric megasonic transducer to a coax cable impedance, typically 50 ohms. A coax cable of the proper impedance (typically 50-ohm RG-58 type coax cable) is used to connect this matched piezoelectric megasonic transducer to the generator. This is expensive because the matching transformer at megasonic frequencies is costly.
In the preferred embodiment, an inductor 7089 (with a value in the range PI/(ŵ2*Co) to 1/(ŵ2*Co), where PI=3.14159, w=2PIf, Co is the parallel capacitance of the piezoelectric transducer, and f is the frequency of operation) is connected in parallel with the piezoelectric transducer at the transducer and uses any cable 70115 to connect this assembly to the generator. The generator has a LC output network 70100 which drives this cable, inductor 7089 and piezoelectric transducer 7033.
The cost reduction of a single inductor 7089 versus a matching transformer 7086 network 7085 (prior art shown in
In another embodiment, a gate drive (where the duty cycle is non constant and the float side gate drive is the inverted ground side gate drive with dead times added) waveform for a half bridge is provided that will improve operation during power control when using gate duty cycle for the power control function in a megasonic generator. It eliminates the 3*Fo voltage changes that occur at the center of the half bridge when power is reduced. This improved gate drive still had a deficiency in that is was possible to have a condition where a forward biased antiparallel diode in one side of the half bridge could be reverse biased when the switching device is turned on in the other side of the half bridge. This condition dissipates energy and this impulse of energy in the circuitry causes noise and oscillations. Although this condition is common in state of the art ultrasonic generators, as frequency is raised to the 1 MHz range, this dissipation becomes a rather large problem. In this embodiment, the narrow gate pulses in the float side of the half bridge that meter the power to the load are always started when the current flowing from the center of the half bridge is negative, i.e., current flowing toward the half bridge typically through the ground side switching device. This solves the problems and results in a power control system that is small and low cost.
In another embodiment, the megasonic generator is designed and configured to have no resistive components or other lossy elements in the output stage. Unlike conventional state of the art megasonic generators where the output impedance matches the coax cable impedance, usually 50 ohms, this embodiment of the megasonic generator output stage does not have operating problems with mismatched loads or transducers because power reflected by the load or transducer is again reflected by the megasonic generator output stage back to the load or transducer. This results in a higher efficiency system when the transducer becomes mismatched due to temperature, age or other changes.
With reference to
In this embodiment, sensor 7003 is a conventional temperature sensor that responds to an over temperature condition within the generator, processor 7004 is a conventional PIC, and memory 7005 is conventional EEPROM. The temperature sensor manufactured by Analog Devices and the PIC and EEPROM manufactured by Microchip may be used in the preferred embodiment.
While a temperature sensor, PIC and EEPROM are used in the preferred embodiment, it is contemplated that other sensors, processors or memory may be used. For example, it is contemplated that a digital integrated circuit, microprocessor, microcontroller, CPU, PLC, PC or microcomputer may be used as a processor. In addition, it is contemplated that a magnetic memory, flash memory or optically memory may be used as the memory element. In addition, it is contemplated that other sensors or an array of sensors may be used to sense a fault, error or failure. For example, sensors may be employed or adapted to determine a low power line voltage condition, a high power line current draw, an over voltage power line condition, an over temperature condition, an over voltage ultrasound driving signal, an over current ultrasound driving signal, an under voltage ultrasound driving signal, an under current ultrasound driving signal, an unlocked PLL condition, an out of specification phase shift condition, an ultrasound drive frequency over maximum limit, an ultrasound drive frequency under a minimum limit, an excessive reflected power condition, an open ultrasound transducer assembly, a shortened ultrasound transducer assembly, an ultrasound transducer assembly over a maximum capacitance value, an ultrasound transducer assembly under a minimum capacitance value, a high impedance ultrasound transducer assembly, a low impedance ultrasound transducer assembly, a missing interlock, incorrect output power, loss of closed loop output power control, a start up sequence error, an aborted start up sequence, or a shut down sequence error. Thus, system 7007 may be used to determine and record the history of numerous different faults, errors and failures of interest with respect to troubleshooting and repair of the generator or system.
The invention may be embodied in other specific forms without departing from its spirit or essential characteristics. The present embodiments are therefore to be considered as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of the equivalency of the claims are therefore intended to be embraced therein. Accordingly, while the presently-preferred form of the system has been shown and described, and several embodiments discussed, persons skilled in this art will readily appreciate that various additional changes and modifications may be made without departing from the spirit of the invention, as defined and differentiated by the following claims.
The subject application is a continuation-in-part of commonly owned and co-pending U.S. patent application Ser. No. 11/827,288 filed Jul. 11, 2007, entitled “Ultrasound System”, and Ser. No. 11/704,875 filed Feb. 9, 2007, entitled “Apparatus, Circuitry, Signals, Probes and Methods for Cleaning and/or Processing with Sound”, each of which are expressly incorporated herein by reference. Ser. No. 11/704,875 has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 11/704,875: U.S. patent application Ser. No. 11/704,875 filed Feb. 9, 2007, entitled “Apparatus, Circuitry, Signals, Probes and Methods for Cleaning and/or Processing with Sound”, still pending, is a continuation-in-part of co-pending U.S. patent application Ser. No. 11/177,750 which is expressly incorporated herein by reference. This application has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 11/177,750: U.S. patent application Ser. No. 11/177,750 filed Jul. 8, 2005, entitled “Apparatus, Circuitry, Signals, Probes and Methods for Cleaning and/or Processing with Sound”, still pending, is a continuation-in-part of co-pending U.S. patent application Ser. No. 11/173,468 which is expressly incorporated herein by reference. This application has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 11/173,468: U.S. patent application Ser. No. 11/173,468 filed Jul. 1, 2005, entitled “Organism Inactivation Method and System”, still pending is a continuation-in-part of U.S. patent application Ser. Nos. 10/855,135 and 11/047,110, each of which is expressly incorporated herein by reference. Each of these applications has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 10/855,135: U.S. patent application Ser. No. 10/855,135 filed May 27, 2004, entitled “Apparatus, Circuitry, Signals and Methods for Cleaning and/or Processing with Sound”, (now U.S. Pat. No. 7,211,928, granted May 1, 2007) is a continuation-in-part of commonly owned U.S. patent application Ser. Nos. 10/178,751 and 10/825,036, each of which is expressly incorporated herein by reference. Each of these applications has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 10/178,751: U.S. patent application Ser. No. 10/178,751 filed Jun. 24, 2002, entitled “Apparatus, Circuitry and Methods for Cleaning and/or Processing with Sound Waves”, (now U.S. Pat. No. 6,822,372, granted Nov. 23, 2004), which is a continuation in part of four U.S. patent application Ser. Nos. 09/370,302, 09/609,036, 09/678,576 and 10/029,751 the priority claim of each is described below. Priority claim of U.S. patent application Ser. No. 11/177,750: U.S. patent application Ser. No. 11/177,750 filed Jul. 8, 2005, entitled “Apparatus, Circuitry, Signals, Probes and Methods for Cleaning and/or Processing with Sound”, still pending, is a continuation-in-part of co-pending U.S. patent application Ser. No. 11/173,468 which is expressly incorporated herein by reference. This application has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 11/173,468: U.S. patent application Ser. No. 11/173,468 filed Jul. 1, 2005, entitled “Organism Inactivation Method and System”, still pending is a continuation-in-part of co-pending U.S. patent application Ser. Nos. 10/855,135 and 11/047,110, each of which is expressly incorporated herein by reference. Each of these applications has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 10/855,135: U.S. patent application Ser. No. 10/855,135 filed May 27, 2004, entitled “Apparatus, Circuitry, Signals and Methods for Cleaning and/or Processing with Sound”, still pending is a continuation-in-part of commonly owned U.S. patent application Ser. Nos. 10/178,751 and 10/825,036, each of which is expressly incorporated herein by reference. Each of these applications has a priority claim that is detailed below. Priority claim of U.S. patent application Ser. No. 10/178,751: U.S. patent application Ser. No. 10/178,751 filed Jun. 24, 2002, entitled “Apparatus, Circuitry and Methods for Cleaning and/or Processing with Sound Waves”, (now U.S. Pat. No. 6,822,372, granted Nov. 23, 2004), which is a continuation in part of four U.S. patent application Ser. Nos. 09/370,302, 09/609,036, 09/678,576 and 10/029,751 the priority claim of each is described below. Priority claim of U.S. patent application Ser. No. 09/370,302: U.S. patent application Ser. No. 09/370,302 filed Aug. 9, 1999, entitled “Probe System for Ultrasonic Processing Tank”, still pending, which is a division of U.S. patent application Ser. No. 09/097,374 (now U.S. Pat. No. 6,016,821, granted Jan. 25, 2000); which is a continuation of U.S. patent application Ser. No. 08/718,945 (now U.S. Pat. No. 5,834,871, granted Nov. 10, 1998) and U.S. Provisional Application No. 60/049,717 filed Jun. 16, 1997, each of which is expressly incorporated herein by reference. Priority claim of U.S. patent application Ser. No. 09/609,036: U.S. patent application Ser. No. 09/609,036 was filed Jun. 30, 2000, entitled “Circuitry to Modify the Operation of Ultrasonic Generators” (now U.S. Pat. No. 6,462,461, granted Oct. 8, 2002), which is expressly incorporated herein by reference. Priority claim of U.S. patent application Ser. No. 09/678,576: U.S. patent application Ser. No. 09/678,576 filed Oct. 3, 2000, entitled “Apparatus and Methods for Cleaning and/or Processing Delicate Parts”, (now U.S. Pat. No. 6,433,460, granted Aug. 13, 2002) is a Divisional Application of Continuation-in-Part application Ser. No. 09/066,158, filed Apr. 24, 1998 (now U.S. Pat. No. 6,181,051, granted Jan. 30, 2001), which is a continuation of U.S. patent application Ser. No. 08/718,945 filed on Sep. 24, 1996 (now U.S. Pat. No. 5,834,871, entitled “Apparatus And Methods For Cleaning And/Or Processing Delicate Parts”), and U.S. Provisional Patent Application Ser. No. 60/023,150, filed on Aug. 5, 1996, each of which is expressly incorporated herein by reference. Priority claim of U.S. patent application Ser. No. 10/029,751: U.S. patent application Ser. No. 10/029,751 filed Oct. 29, 2001, entitled “Multiple Frequency Cleaning System” (now U.S. Pat. No. 6,538,360, granted Mar. 25, 2003) is a divisional application of U.S. patent application Ser. No. 09/504,567 entitled “Multiple Frequency Cleaning System,” filed on Feb. 15, 2000 (now U.S. Pat. No. 6,313,565, granted Nov. 6, 2001), the disclosure of which is entirely incorporated herein by reference. Priority claim of U.S. patent application Ser. No. 10/825,036: U.S. patent application Ser. No. 10/825,036 filed Apr. 15, 2004, entitled “A Multi-Generator System for an Ultrasonic Processing Tank”, still pending, is a continuation-in-part of commonly-owned U.S. patent application Ser. No. 09/370,302 filed Aug. 9, 1999, entitled “Probe System for Ultrasonic Processing Tank” (now U.S. Pat. No. 7,004,016 granted Feb. 28, 2006); which is a division of U.S. patent application Ser. No. 09/097,374 (now U.S. Pat. No. 6,016,821, granted Jan. 25, 2000); which is a continuation of U.S. patent application Ser. No.: 08/718,945 (now U.S. Pat. No. 5,834,871, granted Nov. 10, 1998) and U.S. Provisional Application No. 60/049,717, each of which is expressly incorporated herein by reference. Priority claim of U.S. patent application Ser. No. 11/047,110: U.S. patent application Ser. No. 11/047,110 is a continuation-in-part of commonly-owned U.S. patent application Ser. No. 09/370,302 filed Aug. 9, 1999, entitled “Probe System for Ultrasonic Processing Tank” (now U.S. Pat. No. 7,004,016 granted Feb. 28, 2006); which is a division of U.S. patent application Ser. No. 09/097,374 (now U.S. Pat. No. 6,016,821, granted Jan. 25, 2000); which is a continuation of U.S. patent application Ser. No. 08/718,945 (now U.S. Pat. No. 5,834,871, granted Nov. 10, 1998) and U.S. Provisional Application No. 60/049,717, each of which is expressly incorporated herein by reference.
Number | Date | Country | |
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60049717 | Jun 1997 | US | |
60023150 | Aug 1996 | US | |
60049717 | Jun 1997 | US |
Number | Date | Country | |
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Parent | 09097374 | Jun 1998 | US |
Child | 09370302 | US | |
Parent | 09066158 | Apr 1998 | US |
Child | 09678576 | US | |
Parent | 09504567 | Feb 2000 | US |
Child | 10029751 | US | |
Parent | 09097374 | Jun 1998 | US |
Child | 09370302 | US |
Number | Date | Country | |
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Parent | 08718945 | Sep 1996 | US |
Child | 09097374 | US | |
Parent | 08718945 | Sep 1996 | US |
Child | 09066158 | US | |
Parent | 08718945 | Sep 1996 | US |
Child | 09097374 | US |
Number | Date | Country | |
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Parent | 11827288 | Jul 2007 | US |
Child | 11978316 | US | |
Parent | 11177750 | Jul 2005 | US |
Child | 11827288 | US | |
Parent | 11173468 | Jul 2005 | US |
Child | 11177750 | US | |
Parent | 10855135 | May 2004 | US |
Child | 11173468 | US | |
Parent | 10178751 | Jun 2002 | US |
Child | 10855135 | US | |
Parent | 09370302 | Aug 1999 | US |
Child | 10178751 | US | |
Parent | 09609036 | Jun 2000 | US |
Child | 10178751 | US | |
Parent | 09678576 | Oct 2000 | US |
Child | 09609036 | US | |
Parent | 10029751 | Oct 2001 | US |
Child | 10178751 | US | |
Parent | 10825036 | Apr 2004 | US |
Child | 10855135 | US | |
Parent | 09370302 | Aug 1999 | US |
Child | 10825036 | US |