Information
-
Patent Grant
-
6284174
-
Patent Number
6,284,174
-
Date Filed
Monday, December 6, 199925 years ago
-
Date Issued
Tuesday, September 4, 200123 years ago
-
Inventors
-
Original Assignees
-
Examiners
Agents
- Schnader Harrison Segal & Lewis LLP
-
CPC
-
US Classifications
Field of Search
US
- 264 104
- 264 169
- 264 211
- 425 198
- 425 464
-
International Classifications
-
Abstract
A melt spinning pack, including a pack case, a spinneret having many spinning holes positioned at the bottom of the case, a pack cap having a polymer introducing hole at the center positioned at the top of the case, and a flow arranging plate having many flow arranging holes with restricted portions reduced in cross sectional area compared to the inlets of the holes positioned between the spinneret and the pack cap, satisfying the requirement that the contraction percentage R be 50% or less, respectively contained in the case.
Description
TECHNICAL FIELD
The present invention relates to a melt spinning pack used for producing synthetic fibers, and a method for producing synthetic fibers using it.
BACKGROUND ART
The conventional melt spinning pack used for producing synthetic fibers comprises the following parts.
The pack comprises a cylindrical pack case opened in the bottom surface and the top surface, and a spinneret having many spinning holes, a pressure plate having many polymer flowing holes, a wire mesh filter, a cylindrical filter medium containing-spacer, a granular filter bed (usually called a sand bed) contained inside the spacer, and also a pack cap having a polymer introducing hole at the center for introducing a molten polymer and installed to close the top surface of the pack case, respectively contained in this order from bottom to top in the pack case, and also has a first space formed between the bottom surface of the pack cap and the top surface of the granular filter medium, and a second space formed between the top surface of the spinneret and the bottom surface of the pressure plate.
The pack case, spinneret, pressure plate, filter medium-containing spacer and pack cap are usually respectively made of metal.
The granular filter bed is usually a layer of sand consisting of stainless steel particles, glass particles or quartz particles.
The molten polymer as a raw material for producing synthetic fibers is introduced into the first space from the polymer introducing hole formed at the center of the pack cap, passes through the granular filter bed (sand bed) and the wire mesh filter, and further through the many polymer flowing holes of the pressure plate, flows into the second space, and reaches the many spinning holes of the spinneret.
The molten polymer flowing into the many spinning holes passes through these spinning holes and is spun from the spinning holes to form many filaments. The filaments are cooled to form a yarn comprising the multifilament. The yarn is wound around a bobbin installed on a winder. Thus, synthetic fibers are produced.
In some cases, the many filaments are divided into several groups, say, 2 to 4 groups, and the many filaments of each group are formed as one yarn respectively. In this case, from one melt spinning pack, a plurality of, that is, 2 to 4 yarns are produced.
The conventional melt spinning pack has the following problems.
The flowing of polymer which is introduced through the polymer introducing hole provided at the center of the pack cap and flowed into the first space and further come into the granular filter bed (sand bed) is distributed densely in the central region thereof and is less likely to reach the peripheral region. So, the many filaments obtained from the many spinning holes of the spinneret become different from each other in filament diameter and it causes a problem of unevenness of fineness.
Furthermore, the granular filter bed (sand bed) has avoid volume of usually about 40% therein. This means that the granular filter bed (sand bed) has a void of about 40% to allow polymer flow. This structure elongates the dwell time of the polymer in the granular filter bed (sand bed). As a result, the passing time of polymer from introducing from the polymer introducing hole of the pack cap to spinning from the many spinning holes of the spinneret, i.e., the dwell time of the polymer in the pack becomes long. If the dwell time is long, the polymer is deteriorated during the dwell time. The deterioration of the polymer occurs locally in the pack, and at the places at which the polymer is deteriorated and to which the deteriorated polymer moves, it remains in the pack to cause abnormal dwelling. The abnormal dwelling in the pack also causes the filaments to be uneven in fineness. Furthermore, if the deteriorated polymer is spun from the spinning holes, the obtained filaments become irregular in quality in the longitudinal direction, and the filaments are broken before arriving at the winder.
On the other hand, Japanese Publication (Kokaku) No. SHO 39-24309 proposes the following idea for a melt spinning pack.
The spinning pack has a flow arranging plate provided with many flow arranging holes and having a concave bottom surface. The structure is intended to make different in length the many flow arranging holes between the top surface and the bottom surface of the flow arranging plate and to produce uniform polymer flow to the spinneret having many spinning holes.
However, it was found that even if fibers were produced by using the spinning pack, the obtained fiber bundle had relatively great difference of fineness between the filaments. One of the reasons is estimated to be that the space formed between the bottom surface of the flow arranging plate and the top surface of the spinneret has a form likely to cause abnormal dwelling of the polymer.
The above problems of the conventional melt spinning packs arise more remarkably when a yarn is produced from a molten polyester containing an electro-control agent.
Disclosure of the Invention
The object of the present invention is to solve the above problems of the prior art by providing a melt spinning pack capable of producing yarns with good quality less uneven in fineness respectively comprising filaments less uneven in fineness, and a method for producing synthetic fibers by using the pack.
The present invention concerning the melt spinning pack for achieving the above object is as follows:
A melt spinning pack, comprising
(a) a cylindrical pack case opened in the bottom surface and the top surface,
(b) a spinneret having many spinning holes, positioned to close the opening in the bottom surface of the pack case,
(c) a flow arranging plate having many flow arranging holes, positioned above the spinneret,
(d) a pack cap having a polymer introducing hole at the center, positioned above the flow arranging plate and positioned to close the opening in the top surface of the pack case,
(e) a first space in which the outlet of the polymer introducing hole in the bottom surface of the pack cap and the inlets of the flow arranging holes in the top surface of the flow arranging plate are opened,
(f) a second space in which the outlets of the flow arranging holes in the bottom surface of the flow arranging plate and the inlets of the spinning holes in the top surface of the spinneret are opened, and in which the space thickness in the central axis direction of the pack case is substantially uniform in the entire range of the space, and
(g) restricted portions reduced in cross sectional area compared to the inlets of the flow arranging holes, formed in the respective flow arranging holes in the respective sections between the inlets of the flow arranging holes and the outlets of the flow arranging holes.
In the present invention, the conventionally used granular filter bed (sand bed) is not used, and a flow arranging plate having many flow arranging holes is positioned between the first space in which the outlet of the polymer introducing hole in the bottom surface of the pack cap and the inlets of the flow arranging holes in the top surface of the flow arranging plate are opened and the second space in which the outlets of the flow arranging holes in the bottom surface of the flow arranging plate and the inlets of the spinning holes in the top surface of the spinneret are opened. Furthermore, restricted portions reduced in cross sectional area compared to the inlets of the flow arranging holes are formed in the respective sections between the inlets of the flow arranging holes and the outlets of the flow arranging holes. Therefore, in the respective first and second spaces, the polymer can be distributed more uniformly compared to the distribution achieved by the conventional pack.
The following embodiments are preferable in the present invention.
Embodiment 1: In the present invention, the number of flow arranging holes in the peripheral region of the flow arranging plate is larger than that at the central region of the flow arranging plate.
Embodiment 2: In the present invention, the cross sectional area of the restricted portions of the flow arranging holes positioned in the peripheral region of the flow arranging plate is smaller than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the central region of the flow arranging plate, and if flow arranging holes are positioned also in the intermediate region between the peripheral region and the central region, the cross sectional area of the restricted portions of the flow arranging holes positioned in the intermediate region is not smaller than the cross sectional area of the restricted portions of the flow arranging holes positioned in the peripheral region and not larger than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the central region.
This embodiment means that if one of the many flow arranging holes is positioned at the center of the flow arranging plate while the other flow arranging holes are positioned on one geometrical line around the center, the cross sectional area of the restricted portions of the flow arranging holes positioned on the one geometrical line is smaller than the cross sectional area of the restricted portion of the flow arranging hole positioned at the center.
Furthermore, this embodiment means that when there are a plurality of geometrical lines around the center, with the other flow arranging holes positioned on the plurality of geometrical lines, the cross sectional area of the restricted portions of the flow arranging holes positioned on the geometrical lines described between the center and the outermost geometrical line is equal to the cross sectional area of the flow arranging hole positioned at the center, or equal to the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost geometrical line, or smaller than the cross sectional area of the restricted portion the flow arranging hole positioned at the center and larger than the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost geometrical line.
Moreover, this embodiment means that if there is no flow arranging hole at the center, similar relations apply to the innermost geometrical line, the outermost geometrical line and the geometrical lines described between them.
Embodiment 3: In the present invention, the length of the restricted portions of the flow arranging holes positioned in the peripheral region of the flow arranging plate is longer than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the central region of the flow arranging plate, and if flow arranging holes are positioned also in the intermediate region between the peripheral region and the central region, the length of the restricted portions of the flow arranging holes positioned in the intermediate region is not longer than the length of the restricted portions of the flow arranging holes positioned in the peripheral region and not shorter than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the central region.
The meaning of this embodiment can be understood by replacing the cross sectional area of the restricted portions in the explanation for the above embodiment 2 by the length of the restricted portions.
Embodiment 4: In the present invention, the form of the top surface of the flow arranging plate is upwardly conical or pyramidal and the form of the bottom surface of the pack cap is conical or pyramidal to respond to the conical or pyramidal top surface of the flow arranging plate, with the first space formed between the two conical or pyramidal surfaces.
Embodiment 5: In the present invention, an integral filter plate formed by an integral filter medium is provided in the first or second space.
Embodiment 6: In the present invention, the space thickness of the second space is about 1 mm to about 60 mm. It is preferable for preventing the abnormal dwelling and shortening the dwell time of the polymer, that the space thickness of the second space is in this range.
Embodiment 7: In the present invention, the inner peripheral surface of the cylindrical pack case, the outer peripheral surface of the flow arranging plate and the outer peripheral surface of the pack cap are respectively circular in cross sectional form (hereinafter, this pack is called the circular pack of the present invention).
The circular pack of the present invention can be provided in the following preferable embodiments.
Embodiment 8: In the circular pack of the present invention, the flow arranging holes are positioned in such a manner that the centers of the flow arranging holes are positioned on a hole positioning circle described around the center of the top surface of the flow arranging plate, or positioned at the center of the top surface of the flow arranging plate and on a hole positioning circle described around said center.
The former half of this embodiment means a case where there is no flow arranging hole at the center of the flow arranging plate, and the latter half means a case where there is a flow arranging hole at the center of the flow arranging plate.
Embodiment 9: In the circular pack of the present invention, a plurality of concentric hole positioning circles are described instead of said one hole positioning circle.
Embodiment 10: In the circular pack of the present invention, the number of flow arranging holes positioned on a hole positioning circle described in the peripheral region of the flow arranging plate is larger than the number of flow arranging holes positioned on a hole positioning circle described in the central region of the flow arranging plate.
Embodiment 11: In the circular pack of the present invention, the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle of the flow arranging plate is smaller than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region of the flow arranging plate, and if there is an intermediate hole positioning circle between the outermost hole positioning circle and the flow arranging hole(s) positioned in the innermost central region, the cross sectional area of the restricted portions of the flow arranging holes positioned on the intermediate hole positioning circle is not smaller than the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle and not larger than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region.
The meaning of this embodiment can be understood by replacing the geometrical lines in the explanation for the embodiment 2 by hole positioning circles.
Embodiment 12: In the circular pack of the present invention, the length of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle of the flow arranging plate is longer than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region of the flow arranging plate, or if there is an intermediate hole positioning circle between the outermost hole positioning circle and the flow arranging hole(s) positioned in the innermost central region, the length of the restricted portions of the flow arranging holes positioned on the intermediate hole positioning circle is not longer than the length of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle and not shorter than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region.
The meaning of this embodiment can be understood by replacing the geometrical lines in the explanation of the embodiment 2 by hole positioning circles.
Embodiment 13: In the circular pack of the present invention, the form of the top surface of the flow arranging plate is upwardly conical, and the form of the bottom surface of the pack cap is conical to respond to the conical top surface of the flow arranging plate, with the first space formed between the two conical surfaces.
Embodiment 14: In the circular pack of the present invention, an integral filter plate formed by an integral filter medium is provided in the first or second space.
Embodiment 15: In the circular pack of the present invention, the space thickness of the second space is about 1 mm to about 60 mm. It is preferable for preventing the abnormal dwelling and shortening the dwell time of the polymer, that the space thickness of the second space is in this range.
The method for producing synthetic fibers of the present invention to achieve the object is a method for producing synthetic fibers, in which the melt spinning pack stated in the above present invention or any of the preferable embodiments is used, comprising the steps of introducing a molten polymer from the polymer introducing hole of the pack cap, spinning many filaments from the spinning holes of the spinneret and cooling the filaments to form a yarn.
In the method for producing synthetic fibers, an embodiment in which- the molten polymer is a polyester containing an electro-control agent is preferable.
Since polyester fibers with electro-controllability are lower in electric resistance than ordinary polyester fibers, they are less likely to be charged with static electricity, and are used as fibers for clothing.
To produce polyester fibers with electro-controllability, usually a polymer in which an electro-control substance (electro-control agent) for giving electro-controllability coexists with a polyester is prepared for melt spinning. The polymer is supplied into a heated melt spinning pack, and extruded from the many spinning holes of the spinneret installed in the bottom surface of the pack, to form many filaments, and from the filaments, polyester fibers with electro-controllability are produced.
However, most of electro-control substances used are lower in heat resistance than ordinary polyesters. Therefore, when a polyester containing an electro-control agent is spun using any conventional melt spinning pack, the polymer is more thermally deteriorated in the pack than an ordinary polyester, and it may be difficult to produce electro-controllable fibers with good quality. To solve the problem, the melt spinning pack of the present invention which allows the polymer to dwell in it for a shorter period of time than the conventional pack can be preferably used.
Usually used electro-control agents include the following:
Ethylene oxide condensation products, propylene oxide condensation products, polyalkylene ether (polyalkylene oxide) as the condensation product of ethylene oxide and propylene oxide, olyether amides obtained by letting an aminocarboxylic acid, lactam, diamine, dicarboxylic acid or dicarboxylate react with a polyalkylene oxide, polyether esters, polyether ester amide block copolymers.
Any of these electro-control agents is usually used by about 0.2 wt % to about 5 wt % based on the weight of the polymer.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1
is a vertical sectional view showing a conventional melt spinning pack.
FIG. 2
is a vertical sectional view showing an example of the melt spinning pack of the present invention.
FIG. 3
is a vertical sectional view showing another example of the melt spinning pack of the present invention.
FIG. 4
is a cross sectional view showing a half of the X—X arrow section of FIG.
3
.
FIG. 5
is a vertical sectional view showing a further other example of the melt spinning pack of the present invention.
FIG. 6
is a vertical sectional view showing a still further other example of the melt spinning pack of the present invention.
FIGS. 7
are vertical sectional views showing seven examples ((
a
) to (
g
)) of the flow arranging holes formed in the flow arranging plate of the melt spinning pack of the present invention.
THE BEST EMBODIMENTS OF THE INVENTION
At first, the conventional melt spinning pack will be described below more specifically, and subsequently the melt spinning pack and the method for producing synthetic fibers of the present invention will be described in more detail.
FIG. 1
is a vertical sectional view showing the melt spinning pack conventionally used in the field of melt spinning. In
FIG. 1
, the pack
1
comprises a cylindrical pack case
2
opened in the bottom surface and the top surface, and a spinneret
4
having many spinning holes
3
, a pressure plate
6
having many polymer flowing holes
5
, a wire mesh filter
7
, an annular filter medium-containing spacer
8
, a granular filter bed (usually called a sand bed)
9
contained inside the spacer
8
, and also a pack cap
11
having a polymer introducing hole
10
at the center for introducing a molten polymer and positioned to close the top surface of the pack case
2
, respectively contained in this order from bottom to top in the pack case
2
, and also has a first space
12
formed between the bottom surface of the pack cap
11
and the top surface of the granular filter medium
9
, and a second space
13
formed between the top surface of the spinneret
4
and the bottom surface of the pressure plate
6
.
In the pack
1
, the pack case
2
, the spinneret
4
, the pressure plate
6
, the filter medium-containing spacer
8
and the pack cap
11
are usually made of any metal respectively.
The granular filter bed
9
is usually a layer of sand consisting of stainless steel particles, glass particles or quartz particles.
The molten polymer as a raw material for producing synthetic fibers is introduced into the first space
12
from the polymer introducing hole
10
at the center of the pack cap
1
and passes through the granular filter bed (sand bed)
9
and the wire mesh filter
7
and further through the many polymer flowing holes
5
of the pressure plate
6
, flowing into the second space
13
, to reach the many spinning holes
3
of the spinneret
4
.
The molten polymer flowing into the many spinning holes
3
passes through these spinning holes
3
and is spun from the spinning holes
3
and formed into many filaments (not illustrated). These filaments are cooled to form a yarn (not illustrated) as a bundle of multi-filaments. The yarn is wound around a bobbin (not illustrated) installed on a winder (not illustrated). Thus, synthetic fibers are produced.
The conventional melt spinning pack has the problems as described before.
Several embodiments of the melt spinning pack of the present invention to solve the problems are described below.
FIG. 2
is a vertical sectional view showing an example of the melt spinning pack of the present invention.
The pack
21
shown in
FIG. 2
comprises a cylindrical pack case
22
opened in the bottom surface and the top surface, a spinneret
24
having many spinning holes
23
, a flow arranging plate
26
having many flow arranging holes
25
, and a pack cap
28
having a polymer introducing hole
27
at the center, respectively contained in this order from the bottom to the top of the pack case
22
. The opening in the bottom surface of the pack case
22
is closed by the spinneret
24
. The opening in the top surface of the pack case
22
is closed by the pack cap
28
.
Between the bottom surface of the pack cap
28
and the top surface of the flow arranging plate
26
, a first space
29
in which the outlet of the polymer introducing hole
27
and the inlets of the flow arranging holes
25
are opened is formed. Between the bottom surface of the flow arranging plate
26
and the top surface of the spinneret
24
, a second space
30
in which the outlets of the flow arranging holes
25
and the inlets of the spinning holes
23
are opened is formed.
The top surface of the flow arranging plate
26
is upwardly conical, and the bottom surface of the pack cap
28
is also upwardly conical to respond to the top surface of the flow arranging plate
26
. The space between the two conical surfaces is the first space
29
. The vertical height of the clearance formed between the two conical surfaces is almost uniform in the entire range from the outlet of the polymer introducing hole
27
to the periphery of the first space
29
.
The second space
30
is divided into an upper space
33
and a lower space
34
by a pressure plate
32
having the many polymer flowing holes
31
at an intermediate position of the second space
30
in the vertical direction. In the upper space
33
, an integral filter plate
35
is placed on the top surface of the pressure plate
32
.
In this pack
21
, the many flow arranging holes
25
of the flow arranging plate
26
have restricted portions
36
reduced in cross sectional area compared to the inlets of the holes, in the sections between the inlets and outlets of the flow arranging holes
25
.
FIG.
7
(
a
) is a vertical sectional view showing one of the flow arranging holes
25
. Each of the flow arranging holes
25
comprises a cylindrical hole (upper hole)
25
a
with diameter D formed downward from the inlet, a cylindrical hole (lower hole)
25
b
with diameter d smaller than the diameter D formed upward from the outlet and a truncated-conical hole (connecting hole)
25
c
with the diameter gradually reduced from top to bottom, connected to the bottom end of the upper hole
25
a
and the top end of the lower hole
25
b
. The lower hole
25
b
forms a restricted portion
36
in contrast to the upper hole
25
a
. The lower holes
25
b
forming the restricted portions
36
of the respective flow arranging holes
25
positioned in the central to peripheral regions of the flow arranging plate
26
are equal in diameter d and axial length L.
In
FIG. 2
, if the pressure acting on the top surface of the spinneret
24
is not so large as to deform the spinneret
24
, the pressure plate
32
is not required to be used. In this case, the integral filter plate
35
is placed on the top surface of the spinneret
24
in the second space
30
.
When the pressure plate is used, the space thickness of the second space means the space thickness of said upper space.
It is preferable that the space thickness of the upper space is about 1 mm to about 5 mm. A more preferable range is about 2 mm to about 3 mm.
It is preferable that the space thickness of the lower space is about 1 mm to about 5 mm. A more preferable range is about 2 mm to about 3 mm.
In the pack
21
, a pressurized molten polymer flows into the first space
29
from the polymer introducing hole
27
of the pack cap
28
. The introduced polymer fills the first space
29
. The polymer filling the first space
29
flows into the upper holes
25
a
of the respective flow arranging holes
25
, and passes through the connecting holes
25
c
and the lower holes
25
b
, flowing into the upper space
33
of the second space
30
.
The polymer flowing into the upper space
33
of the second space
30
passes through the integral filter plate
35
and further through the many polymer flowing holes
31
of the pressure plate
32
into the lower space
34
of the second space
30
, to fill the lower space
34
. The polymer filling the lower space
34
is continuously extruded as filaments from the respective spinning holes
23
of the spinneret
24
. The extruded many filaments are cooled to form a yarn.
The filaments of the obtained yarn are less uneven in fineness. The reason is that the pack
21
has the restricted portions
36
in the flow arranging holes
25
of the flow arranging plate
26
. If the unevenness of fineness is still large, the relation between the diameter D of the upper hole
25
a
and the diameter d of the lower hole
25
b
of each flow arranging hole
25
can be changed to lessen the unevenness of fineness.
FIG. 3
is a vertical sectional view showing another example of the melt spinning pack of the present invention.
FIG. 4
is a cross sectional view showing a half of the X—X arrow section of FIG.
3
.
The pack
41
shown in
FIGS. 3 and 4
comprises a cylindrical pack case
42
opened in the bottom surface and the top surface, and a spinneret
44
having many spinning holes
43
, a flow arranging plate
46
having many flow arranging holes
45
and a pack cap
48
having a polymer introducing hole
47
at the center, respectively contained in this order from the bottom to the top of the pack case
42
. The opening in the bottom surface of the pack case
42
is closed by the spinneret
44
. The opening in the top surface of the pack case
42
is closed by the pack cap
48
.
Between the bottom surface of the pack cap
48
and the top surface of the flow arranging plate
46
, a first space
49
in which the outlet of the polymer introducing hole
47
and the inlets of the flow arranging holes
45
are opened is formed. Between the bottom surface of the flow arranging plate
46
and the top surface of the spinneret
44
, a second space
50
in which the outlets of the flow arranging holes
45
and the inlets of the spinning holes
43
are opened is formed.
The top surface of the flow arranging plate
46
is upwardly conical, and the bottom surface of the pack cap
48
is also upwardly conical to respond to the conical top surface of the flow arranging plate
46
. The space between the two conical surfaces is the first space
49
. The vertical height of the clearance formed between the two conical surfaces is almost uniform in the entire range from the outlet of the polymer introducing hole
47
to the periphery of the first space
49
.
The second space
50
is divided into an upper space
53
and a lower space
54
by a pressure plate
52
having many polymer flowing holes
51
at an intermediate position of the second space
50
in the vertical direction. In the upper space
53
, an integral filter plate
55
is placed on the top surface of the pressure plate
52
.
In this pack
41
, the many flow arranging holes
45
of the flow arranging plate
46
have restricted portions
56
reduced in cross sectional area compared to the inlets of the holes, in the sections between the inlets and the outlets.
The flow arranging holes
45
have the same form as the flow arranging holes
25
explained in reference to FIG.
2
and FIG.
7
(
a
).
As for the difference between the respective flow arranging holes
25
shown in FIG.
2
and the respective flow arranging holes
45
shown in
FIG. 3
, the restricted portions
36
(the lower holes
25
b
) of the respective flow arranging holes
25
of the flow arranging plate
26
shown in
FIG. 2
are equal to each other in diameter d and axial length L in the entire range from the center to the periphery of the flow arranging plate
26
, while the restricted portions
56
(the lower holes) of the respective flow arranging holes
45
of the flow arranging plate
46
shown in
FIG. 3
become gradually smaller in diameter d in the range from the center to the periphery of the flow arranging plate
46
, though equal to each other in axial length L.
If the pressure acting on the top surface of the spinneret
44
is not so large as to deform the spinneret
44
, the pressure plate
52
is not required to be used. In this case, the integral filter plate
55
is placed on the top surface of the spinneret
44
in the second space
50
.
In the pack
41
, a pressurized molten polymer flows into the first space
49
from the polymer introducing hole
47
of the pack cap
48
. The introduced polymer fills the first space
49
. The polymer filling the first space
49
flows into the upper holes
25
a
of the respective flow arranging holes
45
, and passes through the connecting holes
25
c
and the lower holes
25
b
, flowing into the upper space
53
of the second space
50
.
The polymer flowing into the upper space
53
of the second space
50
passes through the integral filter plate
55
and further through the many polymer flowing holes
51
of the pressure plate
52
into the lower space
54
of the second space
50
, to fill the lower space
54
. The polymer filling the lower space
54
is continuously extruded as filaments from the respective spinning holes
43
of the spinneret
44
. The extruded many filaments are cooled and form a yarn.
The filaments of the obtained yarn are further less uneven in fineness compared to those obtained by using the pack shown in FIG.
2
. The reasons are that the pack
41
has the restricted portions
56
in the flow arranging holes
45
of the flow arranging plate
46
, and that the restricted portions
56
become gradually smaller in hole diameter d in the range from the center to the periphery of the flow arranging plate
46
. If the unevenness of fineness is still large, it can be lessened by readjusting the relation between the diameter D of the upper hole
25
a
of each flow arranging hole
25
and the diameter d of the lower hole
25
b
, and the diameters d of the respective lower holes
25
b
regionally different in the range from the center to the periphery of the flow arranging plate
46
.
The diameters d of the lower holes
25
b
are selected to satisfy the following relation. The cross sectional area of the restricted portions
56
of the flow arranging holes
45
positioned in the peripheral region of the flow arranging plate
45
is kept smaller than the cross sectional area of the restricted portions
56
of the flow arranging holes
45
positioned in the central region of the flow arranging plate
46
, and if the flow arranging holes
45
exist also in an intermediate region between the peripheral region and the central region, the cross sectional area of the restricted portions
56
of the flow arranging holes
45
positioned in the intermediate region is kept not smaller than the cross sectional area of the restricted portions
56
of the flow arranging holes
45
positioned in the peripheral region and not larger than the cross sectional area of the restricted portions
56
of the flow arranging holes
45
positioned in the central region.
FIG. 5
is a vertical sectional view showing a further other example of the melt spinning pack of the present invention.
The pack
61
shown in
FIG. 5
comprises a cylindrical pack case
62
opened in the bottom surface and the top surface, and a spinneret
64
having many spinning holes
63
, a flow arranging plate
66
having many flow arranging holes
65
, and a pack cap
68
having a polymer introducing hole
67
at the center, respectively contained in this order from the bottom to the top of the pack case
62
. The opening in the bottom surface of the pack case
62
is closed by the spinneret
64
. The opening in the top surface of the pack case
62
is closed by the pack cap
68
.
Between the bottom surface of the pack cap
68
and the top surface of the flow arranging plate
66
, a first space
69
in which the outlet of the polymer introducing hole
67
and the inlets of the flow arranging holes
65
are opened is formed. Between the bottom surface of the flow arranging plate
66
and the top surface of the spinneret
64
, a second space
70
in which the outlets of the flow arranging holes
65
and the inlets of the spinning holes
63
are opened is formed.
The top surface of the flow arranging plate
66
is flat. In the first space
69
between the top surface of the flow arranging plate
66
and the bottom surface of the pack cap
68
, a sweeping plate
71
is positioned. The upper surface of the sweeping plate
71
is upwardly conical, and the bottom surface is downwardly conical though being upwardly conical in the central portion. The sweeping plate
71
has a polymer flowing hole
72
formed from the vertex of the conical top surface to the vertex of the conical form in the central portion of the bottom surface.
The bottom surface of the pack cap
68
is also upwardly conical to respond to the conical top surface of the sweeping plate
71
. The vertical height of the clearance
69
a
between the two conical surfaces is almost uniform in the entire range from the outlet of the polymer introducing hole
67
to the periphery of the first space
69
. The clearance
69
a
communicates to the clearance
69
b
between the bottom surface of the sweeping plate
71
and the top surface of the flow arranging plate
66
.
The second space
70
is divided in to an upper space
75
and a lower space
76
by a pressure plate
74
having many polymer flowing holes
73
at an intermediate position of the second space
70
in the vertical direction. In the upper space
75
, an integral filter plate
77
is placed on the top surface of the pressure plate
74
.
In the pack
61
, the many flow arranging holes
65
of the flow arranging plate
66
have restricted portions
78
reduced in cross sectional area compared to the inlets of the holes, in the sections between the inlets and the outlets.
The flow arranging holes
65
have the same form as the flow arranging holes
45
explained in reference to FIG.
3
. The restricted portions
78
(the lower holes
25
b
) of the respective flow arranging holes
65
become gradually smaller in hole diameter d in the range from the center to the periphery of the flow arranging plate
66
, though equal to each other in axial length L.
If the pressure acting on the top surface of the spinneret
64
is not so large as to deform the spinneret
64
, the pressure plate
74
is not required to be used. In this case, the integral filter plate
77
is placed on the top surface of the spinneret
64
in the second space
70
.
The integral filter plate
77
can also be placed on the top surface of the flow arranging plate
66
instead of being placed on the top surface of the pressure plate
74
, or one each of the integral filter plate
77
can also be placed on both the plates.
In the pack
61
, a pressurized molten polymer flows in to the first space
69
from the polymer introducing hole
67
of the pack cap
68
. The introduced polymer passes through the clearance
69
a
formed between the bottom surface of the pack cap
68
and the top surface of the sweeping plate
71
and through the polymer flowing hole
72
formed at the center of the sweeping plate
71
, and flows in to the clearance
69
b
formed between the bottom surface of the sweeping plate
71
and the top surface of the flow arranging plate
66
.
The polymer filling the clearance
69
a
flows in to the upper holes
25
a
of the respective flow arranging holes
65
and passes through the connecting holes
25
c
and the lower holes
25
b
, flowing in to the upper space
75
of the second space
70
.
The polymer flowing in to the upper space
75
of the second space
70
passes through the integral filter plate
77
and further through the many polymer flowing holes
73
of the pressure plate
74
, and flows in to the lower space
76
of the second space
70
, filling the lower space
76
. The polymer filling the lower space
76
is continuously extruded as filaments from the respective spinning holes
63
of the spinneret
64
. The extruded many filaments are cooled and form a yarn.
The respective filaments of the obtained yarn are further less uneven in fineness compared to those obtained by using the pack shown in FIG.
3
. The reasons are that the pack
61
has the restricted portions
78
in the flow arranging holes
65
of the flow arranging plate
66
, that the restricted portions
78
become gradually smaller in hole diameter d in the range from the center to the periphery of the flow arranging plate
66
, and that the first space
69
has the sweeping plate
71
. If the unevenness of fineness is still large, it can be lessened by readjusting the relation between the diameter D of the upper hole
25
a
of each flow arranging hole
25
and the diameter d of the lower hole
25
b
, the diameters d of the respective lower holes
25
b
regionally different in the range from the center to the periphery of the flow arranging plate
46
, and the form of the sweeping plate
71
.
FIG. 6
shows a vertical sectional view showing a still further other example of the melt spinning pack of the present invention.
The pack
81
shown in
FIG. 6
comprises a cylindrical pack case
82
opened in the bottom surface and the top surface, and a spinneret
84
having many spinning holes
83
, a flow arranging plate
86
having many flow arranging holes
85
and a pack cap
88
having a polymer introducing hole
87
at the center, respectively in this order from the bottom to the top of the pack case
82
. The opening in the bottom surface of the pack case
82
is closed by the spinneret
84
. The opening in the top surface of the pack case
82
is closed by the pack cap
88
.
Between the bottom surface of the pack cap
88
and the top surface of the flow arranging plate
86
, first space
89
in which the outlet of the polymer introducing hole
87
and the inlets of the flow arranging holes
85
are opened is formed. Between the bottom surface of the flow arranging plate
86
and the top surface of the spinneret
84
, a second space
90
in which the outlets of the flow arranging holes
85
and the inlets of the spinning holes
83
are opened is formed.
The top surface of the flow arranging plate
86
is upwardly conical, and the bottom surface of the pack cap
88
is also upwardly conical in response to the conical surface of the flow arranging plate
86
. The space between the two conical surfaces is the first space
89
. The vertical height of the clearance between the two conical surfaces is almost uniform in the entire range from the outlet of the polymer introducing hole
87
to the periphery of the first space
89
.
The second space
90
is divided in to an upper space
93
and a lower space
94
by a pressure plate
92
having many polymer flowing holes
91
at an intermediate position of the second space
90
in the vertical direction. In the upper space
93
, an integral filter plate
95
is placed on the top surface of the pressure plate
92
.
In the pack
81
, the many flow arranging holes
85
of the flow arranging plate
86
have restricted portions
96
reduced in cross sectional area compared to the inlets of the holes, in the sections between the inlets and the outlets.
The flow arranging holes
85
have the same form as the flow arranging holes
25
explained in reference to FIG.
2
and FIG.
7
(
a
). As for the difference between the respective flow arranging holes
25
shown in FIG.
2
and the respective flow arranging holes
85
shown in
FIG. 6
, the restricted portions
36
(the lower holes
25
b
) of the respective flow arranging holes
25
of the flow arranging plate
26
shown in
FIG. 2
are equal to each other in hole diameter d and axial length L in the entire range from the center to the periphery of the flow arranging plate
26
, while the restricted portions
96
(lower holes) of the respective flow arranging holes
85
of the flow arranging plate
86
shown in
FIG. 6
become gradually longer in axial length L in the range from the center to the periphery of the flow arranging plate
85
, though equal to each other in hole diameter d.
If the pressure acting on the top surface of the spinneret
84
is not so large as to deform the spinneret
84
, the pressure plate
92
is not required to be used. In this case, the integral filter plate
95
is placed on the top surface of the spinneret
84
in the second space
90
.
In the pack
81
, a pressurized molten polymer flows in to the first space
89
from the polymer introducing hole
87
of the pack cap
88
. The introduced polymer fills the first space
89
. The polymer filling the first space
89
flows in to the upper holes of the respective flow arranging holes
85
and passes through the connecting holes and the lower holes, flowing in to the upper space
93
of the second space
90
.
The polymer flowing in to the upper space
93
of the second space
90
passes through the integral filter plate
95
and further through the many polymer flowing holes
91
of the pressure plate
92
and flows in to the lower space
94
of the second space
90
, filling the lower space
94
. The polymer filling the lower space
94
is continuously extruded as filaments from the respective spinning holes
83
of the spinneret
84
. The extruded many filaments are cooled and form a yarn.
The respective filaments of the obtained yarn are further less uneven in fineness compared to the filaments obtained by using the pack shown in FIG.
2
. The reasons are that the pack
81
has the restricted portions
96
in the flow arranging holes
85
of the flow arranging plate
86
, and that the restricted portions
96
become gradually longer in axial length L in the range from the center to the periphery of the flow arranging plate
86
. If the unevenness of fineness is still large, it can be lessened by readjusting the relation between the diameter D of the upper hole
25
a
of each flow arranging hole
85
and the diameter d of the lower hole
25
b
, and the axial lengths L of the respective lower holes
25
b
regionally different in the range from the center to the periphery of the flow arranging plate
86
.
The axial lengths L of the lower holes
25
b
can be decided to satisfy the following relation. The length of the restricted portions
96
of the flow arranging holes
85
positioned in the peripheral region of the flow arranging plate
85
is kept longer than the length of the restricted portions
96
of the flow arranging holes
85
positioned in the central region of the flow arranging plate
86
, and if the flow arranging holes
85
exist also in the intermediate region between the peripheral region and the central region, the length of the restricted portions
96
of the flow arranging holes
85
positioned in the intermediate region is kept not longer than the length of the restricted portions
96
of the flow arranging holes
85
positioned in the peripheral region and not shorter than the length of the restricted portions
96
of the flow arranging holes positioned in the central region.
FIGS. 7
are vertical sectional views showing seven examples ( (
a
) to (
g
)) of the flow arranging holes formed in the flow arranging plate of the melt spinning pack of the present invention.
FIG.
7
(
a
) has already been explained.
The flow arranging hole
25
B shown in FIG.
7
(
b
) is a modification of the flow arranging hole
25
shown in (
a
), and has an intermediate hole
25
B
d
between the upper hole
25
a
and the connecting hole
25
c
. In FIG.
7
(
b
), the flow arranging plate
26
B has flow arranging holes
25
B, each consisting of a cylindrical upper hole
25
B
a
with diameter D, a first connecting portion
25
B
e
like a truncated cone in succession to it, a cylindrical intermediate hole
25
B
d
in succession to it, a second connecting hole
25
B
c
like a truncated cone in succession to it, and a cylindrical lower hole
25
B
b
(restricted portion
36
B) with diameter d in succession to it.
The flow arranging hole
25
C shown in FIG.
7
(
c
) is another modification of the flow arranging hole
25
shown in (
a
), and has an expanded hole
25
C
d
expanded in diameter, downstream of the lower hole
25
b
. In FIG.
7
(
c
), the flow arranging plate
26
C has flow arranging holes
25
C, each consisting of a cylindrical upper hole
25
C
a
with diameter D, a first connecting hole
25
C
c
like a truncated cone in succession to it, a cylindrical lower hole
25
C
b
(restricted portion
36
C) with diameter d in succession to it, a second connecting hole
25
C
e
like an inverted truncated cone in succession to it, and a cylindrical enlarged hole
25
C
d
with a diameter larger than said diameter d and smaller than said diameter D in succession to it.
The flow arranging hole
25
D of a flow arranging plate
26
D shown in FIG.
7
(
d
) is a conical hole with diameter D at the top, and the outlet of the flow arranging hole
25
D in the bottom surface of the flow arranging plate
26
D forms a restricted portion
36
D with diameter d.
The flow arranging hole
25
E of a flow arranging plate
26
E shown in FIG.
7
(
e
) is a modification of the flow arranging hole
25
D shown in (d),and somewhat curved at the top of a conical hole. The outlet of the flow arranging hole
25
E in the bottom surface of the flow arranging plate
26
E forms a restricted portion
36
E.
The flow arranging hole
25
F of a flow arranging plate
26
F shown in FIG.
7
(
f
) has a funnel-shaped upper hole
25
F
a
with diameter D at the top, and a lower hole
25
F
b
with diameter d in succession to it. The lower hole
25
F
b
forms a restricted portion
36
F.
The flow arranging hole
25
G of a flow arranging plate
26
G shown in FIG.
7
(
g
) is a modification of the flow arranging hole
25
F shown in (
f
) and the funnel-shaped upper hole
25
F
a
of (f) is replaced by a semi-spherical upper hole
25
G
a.
In succession to the upper hole
25
F
a
is a lower hole
25
G
b
with a diameter d which forms a restricted portion
36
E.
Of the flow arranging holes shown in FIGS.
7
(
a
) through (
g
), the flow arranging hole shown in (
a
) is recommended since desired restricted portions can be designed and since restricted portions as designed can be formed in the many flow arranging holes.
In the embodiments shown in
FIGS. 2 through 6
, it is preferable that the following relation is satisfied.
A case of the pack shown in
FIG. 2
is described below. It is preferable that D and d are selected to satisfy the relation of R≦50%, where R is the contraction percentage represented by (Sb/Sa)×100%, Sa is the sectional area of the upper hole
25
a
and Sb is the sectional area of the lower hole
25
b
.
If the above relation is satisfied, the flow resistance necessary for more uniformly distributing the molten polymer in to the first space
29
can be given to the polymer, and furthermore, the flow resistance of the polymer at the upper holes
25
a
of the flow arranging holes
25
can be lessened.
A case of the pack shown in
FIGS. 3 and 4
is described below. In reference to
FIG. 4
, on the top surface of the flow arranging plate
46
, the many flow arranging holes
45
are positioned with their centers on the four concentric circles
45
a
,
45
b
,
45
c
and
45
d
described around the center
45
o
of the flow arranging plate
46
, with the number of the flow arranging holes on each circle kept not larger than that on the adjacent outer circle. The circles to have the flow arranging holes
45
positioned are called hole positioning circles
45
a
,
45
b
,
45
c
and
45
d.
When the diameter of each hole positioning circle, the number of flow arranging holes existing on each hole positioning circle, and the hole diameter and length of the restricted portions of the hole adjusting holes are variables, it is preferable for less unevenness of fineness that the relation of the following formula (I) or (II) is satisfied.
If there is a flow arranging hole at the center 45° of the flow arranging plate
46
, it is preferable that the relation of the following formula (I) is satisfied.
0.5≦(
Ln/Tn
)/(2×
Lo/do
)≦2.5, (I)
where
Tn=(3×Nn×dn
4
/32/Dn),
do: Hole diameter of the restricted portion of the flow arranging hole positioned at the center of the flow arranging plate
Lo: Length of the restricted portion of the flow arranging hole positioned at the center of the flow arranging plate
dn: Hole diameter of the restricted portions of the flow arranging holes positioned on the n-th hole positioning circle from the center of the flow arranging plate
Ln: Length of the restricted portions of the flow arranging holes positioned on the n-th hole positioning circle from the center of the flow arranging plate
Dn: Diameter of the n-th hole positioning circle from the center of flow arranging plate
Nn: Number of the flow arranging holes positioned on the n-th hole positioning circle from the center of the flow arranging plate.
If there is no flow arranging hole at the center 45° of the flow arranging plate
46
, it is preferable that the relation of the following formula (II) is satisfied.
0.5≦(
Ln/Tn
)/(
L
1
/T
1
)≦2.5, (II)
where
Tn=(3×Nn×dn
4
/32/Dn), Tn=(3×N
1
×d
1
4
/32/D
1
)
d
1
: Hole diameter of the restricted portions of the flow arranging holes positioned on the innermost hole positioning circle
L
1
: Length of the restricted portions of the flow arranging holes positioned on the innermost hole positioning circle
D
1
: Diameter of the innermost hole positioning circle
N
1
: Number of the flow arranging holes positioned on the innermost hole positioning circle
dn: Hole diameter of the restricted portions of the flow arranging holes positioned on the n-th hole positioning circle from the center of the flow arranging plate
Ln: Length of the restricted portions of the flow arranging holes positioned on the n-th hole positioning circle from the center of the flow arranging plate
Dn: Diameter of the n-th hole positioning circle from the center of flow arranging plate
Nn: Number of the flow arranging holes positioned on the n-th hole positioning circle from the center of the flow arranging plate.
A case of the pack shown in
FIG. 2
is described below. If the angle of the vertex of the conical top surface of the flow arranging plate
26
is α, it is preferable to select the angle α to satisfy 100°≦α≦180°. If the angle is in th is range, the passage lengths of the polymer flowing in the first space
29
from the polymer introducing hole
27
to the respective flow arranging holes
25
become less different, to lessen the difference in the dwell time of the polymer flowing down through the respective flow arranging holes
25
. This also makes the filaments obtained from the respective spinning holes
23
less uneven in fineness.
The integral filter plate is preferably a filter plate formed by a nonwoven fabric of metal fibers. In this case, it is preferable that the diameter of the metal fibers used in the nonwoven fabric is 5 to 50 μm. It is preferable that the areal unit weight of the metal fibers used in the nonwoven fabric is 50 to 2,000 g/m
2
. The filter plate is a s ingle nonwoven fabric of metal fibers or a laminate consisting of nonwoven fabrics of metal fibers.
If one each integral filter plate is used on the top surface of the pressure plate and the top surface of the flow arranging plate, it is preferable that the diameter of the metal fibers used in the nonwoven fabric placed on the top surface of the flow arranging plate is 5 to 200 μm.
EXAMPLES
The present invention is described below in detail in reference to examples.
Example 1 and Comparative Example 1
As the melt spinning pack for Example 1, the same melt spinning pack
21
of the present invention as shown in
FIG. 2
, except that it did not have the pressure plate
32
was used. The contraction percentage R of the restricted portions of the flow arranging holes
25
of the flow arranging plate
26
was 16%. As the integral filter plate
35
, a nonwoven fabric of metal fibers with a diameter of 20 μm and an areal unit weight of 800 g/m
2
was used. The number of the spinning holes
23
of the spinneret
24
was 48. The 48 spinning holes were divided in to two equal 20 portions, for obtaining two yarns (the first and second yarns) respectively consisting of 24 filaments.
As the melt spinning pack for Comparative Example 1, the conventional melt spinning pack shown in
FIG. 1
was used. The number of the spinning holes
3
of the spinneret
4
was 48. The 48 spinning holes were divided in to two equal portions, for obtaining two yarns (the first and second yarns) respectively consisting of 24 filaments.
Both the packs were used to melt-spin nylon
6
respectively. The spun yarns were drawn and wound. Each yarn was intended to achieve a fineness of 70 deniers.
The properties of the respectively obtained yarns and the polymer dwell times (the times taken for the polymer introduced from the polymer introducing hole to go out of the spinning holes) of the respective packs are shown in Table 1.
TABLE 1
|
|
Comparative
|
Example 1
Example 1
|
|
|
Total
First yarn
69.8
68.9
|
fineness
(deniers)
|
Second yarn
70.2
71.1
|
(deniers)
|
Fineness
Between yarns
0.4
2.2
|
difference
(deniers)
|
Within yarn
2.5
4.8
|
(%)
|
Dwell time
90
150
|
(sec)
|
|
It can be seen that the finenesses (69.8 and 70.2 deniers) of the yarns produced by using the pack of the present invention (Example 1) were closer to the intended fineness (70 deniers) than the finenesses (68.9 and 71.1 deniers) of the yarns produced busing the conventional pack (Comparative Example 1).
It can be seen that the fineness difference between the first and second yarns produced by using he pack of the present invention (Example 1) was 0.4 denier, while that by using the conventional pack (Comparative Example 1) was 2.2 deniers, and therefore that the latter was 5 to 6 times the former.
The fineness difference (%) with in each yarn was obtained from the following formula: Fineness difference with in each yarn (%)=[(Standard deviation of finenesses of the respective filaments constituting the yarn)/ (Arithmetical mean of the finenesses of the respective filaments constituting the yarn)]×100.
The fineness difference with in each yarn of the yarns produced by using the pack of the present invention was 2.5%, while that by using the conventional pack (Comparative Example 1) was 4.8%. The latter was about twice the former.
The dwell time (90 seconds) of the present invention (Example 1) was far shorter than that (150 seconds) of the conventional example (Comparative Example 1). Th is means that the polymer was less deteriorated by heat in the pack of the present invention, being advantageous for producing fibers with good quality.
Example 2 and Comparative Example 2
As the melt spinning pack for Example 2, the melt spinning pack
41
of the present invention shown in
FIGS. 3 and 4
was used. The angle α of the vertex of the conical top surface of the flow arranging plate
46
was 160°. As the integral filter plate
55
, a woven fabric of metal fibers with a diameter of 20 μm and an areal unit weight of 800 g/m
2
was used. The number of the spinning holes
43
of the spinneret
44
was 48. The 48 spinning holes were divided in to two equal portions, for obtaining two yarns (the first and second yarns) respectively consisting of 24 filaments. The other conditions are shown in Table 2.
As the melt spinning pack for Comparative Example 2, the conventional melt spinning pack shown in
FIG. 1
was used. The number of the spinning holes
3
of the spinneret
4
was 48. The 48 spinning holes were divided in to two equal portions, for obtaining two yarns (the first and second yarns) respectively consisting of 24 filaments.
Both the packs were used to melt-spin nylon
6
respectively, and the spun yarns were drawn and wound. Each yarn was intended to achieve a fineness of 70 deniers.
The properties of the respectively obtained yarns and the polymer dwell times in the respective packs are shown in Table 3.
TABLE 2
|
|
Hole
|
Diameter
diameter
Diameter
|
Position of
Number of
of flow
of
Length of
of hole
|
flow
flow
arranging
restricted
restricted
positioning
|
arranging
arranging
holes
portions
portions
circle
|
holes
holes
D (mm)
d (mm)
L (mm)
(mm)
|
|
Center
1
2.0
0.8
9.0
0
|
45o
|
1st circle
25
2.0
0.7
9.0
28
|
45a
|
2nd circle
45
2.0
0.7
9.0
58
|
45b
|
3rd circle
50
2.0
0.7
9.0
77
|
45c
|
4th circle
60
2.0
0.6
9.0
90
|
45d
|
|
TABLE 2
|
|
Hole
|
Diameter
diameter
Diameter
|
Position of
Number of
of flow
of
Length of
of hole
|
flow
flow
arranging
restricted
restricted
positioning
|
arranging
arranging
holes
portions
portions
circle
|
holes
holes
D (mm)
d (mm)
L (mm)
(mm)
|
|
Center
1
2.0
0.8
9.0
0
|
45o
|
1st circle
25
2.0
0.7
9.0
28
|
45a
|
2nd circle
45
2.0
0.7
9.0
58
|
45b
|
3rd circle
50
2.0
0.7
9.0
77
|
45c
|
4th circle
60
2.0
0.6
9.0
90
|
45d
|
|
It can be seen that the finenesses (70.2 and 69.9 deniers) of the yarns produced by using the pack of the present invention (Example 2) were closer to the intended fineness (70 deniers) than the finenesses (68.9 and 71.1 deniers) of the yarns produced by using the conventional pack (Comparative Example 2).
It can be seen that the fineness difference between the first and second yarns produced by using the pack of the present invention (Example 2) was 0.3 denier, while that by using the conventional pack (Comparative Example 2) was 2.2 deniers, and therefore that the latter was about 7 times the former.
The fineness difference with in each yarn of the yarns produced by using the pack of the present invention (Example 2) was 2.3%, while that by using the conventional pack (Comparative Example 2) was 4.8%. The latter was about twice the former.
The dwell time ( 90 seconds) of the present invention (Example 2) was far shorter than that (150 seconds) of the conventional example (Comparative Example 2). Th is means that the polymer was less deteriorated by heat in the pack of the present invention, being advantageous for producing fibers with good quality.
Example 3 and Comparative Example 3
As the melt spinning pack for Example 3, the melt spinning pack
41
of the present invention shown in
FIGS. 3 and 4
was used. The angle α of the vertex of the conical top surface of the flow arranging plate
46
was 180°. As the integral filter plate
55
, a nonwoven fabric of metal fibers with a diameter of 20 μm and an areal unit weight of 800 g/m
2
was used. The number of the spinning holes
43
of the spinneret
44
was 40. The 40 spinning holes were divided in to four equal quarters across the center of the spinneret
44
, for obtaining four yarns (the first, second, third and fourth yarns) respectively consisting of 10 filaments. The other conditions are shown in Table 4.
As the melt spinning pack for Comparative Example 3, the conventional melt spinning pack shown in
FIG. 1
was used. The number of the spinning holes
3
of the spinneret
4
was 40. The 40 spinning holes were divided in to four equal quarters across the center of the spinneret
4
, for obtaining four yarns (the first, second, third and fourth yarns) respectively consisting of 10 filaments.
Both the packs were used to melt-spin nylon
6
respectively, and the spun yarns were drawn and wound. Each yarn was intended to achieve a fineness of 30 deniers.
The properties of the respectively obtained yarns and the polymer dwell times in the respective packs are shown in Table 5.
TABLE 4
|
|
Hole
|
Diameter
diameter
Diameter
|
Position of
Number of
of flow
of
Length of
of hole
|
flow
flow
arranging
restricted
restricted
positioning
|
arranging
arranging
holes
portions
portions
circle
|
holes
holes
D (mm)
d (mm)
L (mm)
(mm)
|
|
Center
1
2.0
0.6
7.0
0
|
45o
|
1st circle
15
2.0
0.6
7.3
24
|
45a
|
2nd circle
30
2.0
0.6
7.6
46
|
45b
|
3rd circle
46
2.0
0.6
8.0
70
|
45c
|
4th circle
55
2.0
0.6
8.5
94
|
45d
|
|
TABLE 4
|
|
Hole
|
Diameter
diameter
Diameter
|
Position of
Number of
of flow
of
Length of
of hole
|
flow
flow
arranging
restricted
restricted
positioning
|
arranging
arranging
holes
portions
portions
circle
|
holes
holes
D (mm)
d (mm)
L (mm)
(mm)
|
|
Center
1
2.0
0.6
7.0
0
|
45o
|
1st circle
15
2.0
0.6
7.3
24
|
45a
|
2nd circle
30
2.0
0.6
7.6
46
|
45b
|
3rd circle
46
2.0
0.6
8.0
70
|
45c
|
4th circle
55
2.0
0.6
8.5
94
|
45d
|
|
In Table 5, the fineness difference refers to the difference between the maximum total fineness and the minimum total fineness of the four yarns. In the conventional example (Comparative Example 3), the fineness difference was 2.4 deniers, but it decreased to 1.1 in the present invention (Example 3).
The dwell time (270 seconds) of the polymer in the pack of the present invention (Example 3) was far shorter than the dwell time (650 seconds) in the conventional example (Comparative Example 3). Th is means that the polymer was less deteriorated by heat in the pack of the present invention, being advantageous for producing fibers with good quality.
Comparative Example 4
The melt spinning pack used for Comparative Example 4 was the melt spinning pack disclosed in FIG. 1 of Japanese Patent Publication (Kokoku) No. SHO 39-24309 as said publicly known document. The diameter of the flow arranging holes of the flow arranging plate (breaker plate) was 2 mm. The spinneret used was the same as that used for Example 3. On the upper flow arranging plate indicated by symbol 8 in FIG. 1 of Japanese Patent Publication (Kokoku) No. SHO 39-24309 as said publicly known document, the same integral filter plate as used in Example 3 was placed.
The pack was used to melt-spin the same nylon 6 as used in Example 3, and the spun yarns were drawn and wound. Each yarn was intended to achieve a fineness of 30 deniers.
The properties of the obtained yarns, the dwell time of the polymer in the pack and the yarn breaking frequency during spinning are shown in Table 6 together with the results of Example 3.
TABLE 6
|
|
Comparative
|
Example 3
Example 4
|
|
|
Total
1st yarn
29.5
28.9
|
fineness
(deniers)
|
2nd yarn
30.4
31.0
|
(deniers)
|
3rd yarn
30.6
31.1
|
(deniers)
|
4th yarn
29.5
29.0
|
(deniers)
|
Fineness
Between yarns
1.1
2.2
|
difference
(deniers)
|
Yarn breaking frequency
0.5
2.0
|
(times/per ton)
|
Dwell time
270
670
|
(sec)
|
|
The fineness difference in the conventional example (Comparative Example 4) was 2.2 deniers, but that of the present invention (Example 3) decreased to 1.1.
The yarn breaking frequency during spinning was 2.0 (times/per ton) in the conventional example (Comparative Example 4), but that in the present invention (Example 3) was 0.5 (time/per ton), being improved to ¼.
The dwell time (270 seconds) of the polymer in the pack of the present invention (Example 3) was far shorter than the dwell time (670 seconds) in the conventional example (Comparative Example 4). This means that the polymer was less deteriorated by heat in the pack of the present invention, being advantageous for producing fibers with good quality.
INDUSTRIAL APPLICABILITY
The melt spinning pack of the present invention can be used for producing synthetic fibers with good quality, and is especially suitable for producing a plurality of synthetic fiber yarns less uneven in fineness respectively consisting of fibers less uneven in fineness.
Claims
- 1. A melt spinning pack, comprising:(a) a cylindrical pack case opened in the bottom surface and the top surface, (b) a spinneret having many spinning holes, positioned to close the opening in the bottom surface of the pack case, (c) a flow arranging plate having many flow arranging holes having upper holes and lower holes, positioned above the spinneret, (d) a pack cap having a polymer introducing hole at the center, positioned above the flow arranging plate and positioned to close the opening in the top surface of the pack case, (e) a first space in which the outlet of the polymer introducing hole in the bottom surface of the pack cap and the inlets of the flow arranging holes in the top surface of the flow arranging plate are opened, (f) a second space in which the outlets of the flow arranging holes in the bottom surface of the flow arranging plate and the inlets of the spinning holes in the top surface of the spinneret are opened, and in which the space thickness in the central axis direction of the pack case is substantially uniform in the entire range of the space, and (g) restricted portions reduced in cross sectional area compared to the inlets of the flow arranging holes in the respective sections between the inlets of the flow arranging holes and the outlets of the flow arranging holes in direct or indirect succession to the upper holes of said flow arranging holes, and satisfying the following formula: R≦50%, where: R=the contraction percentage represented by the formula (Sb/Sa)×100%; Sa=sectional area of said upper hole of said flow arranging hole; and Sb=sectional area of said lower hole of said flow arranging hole.
- 2. A melt spinning pack, according to claim 1, wherein the number of the flow arranging holes positioned in the peripheral region of the flow arranging plate is larger than the number of the flow arranging holes positioned in the central region of the flow arranging plate.
- 3. A melt spinning pack, according to claim 2, wherein, if flow arranging holes are positioned only in the peripheral region and the central region of the flow arranging plate, the cross sectional area of the restricted portions of the flow arranging holes positioned in the peripheral region of the flow arranging plate is smaller than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the central region of the flow arranging plate, and if flow arranging holes are positioned in the intermediate region between the peripheral region and the central region, the cross sectional area of the restricted portions of the flow arranging holes positioned in the peripheral region of the flow arranging plate is smaller than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the central region of the flow arranging plate and the cross sectional area of the restricted portions of the flow arranging holes positioned in the intermediate region is not smaller than the cross sectional area of the restricted portions of the flow arranging holes positioned in the peripheral region and not larger than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the central region.
- 4. A melt spinning pack, according to claim 2 or 3, wherein, if flow arranging holes are positioned only in the peripheral region and the central region of the flow arranging plate, the length of the restricted portions of the flow arranging holes positioned in the peripheral region of the flow arranging plate is longer than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the central region of the flow arranging plate, and if flow arranging holes are positioned in the intermediate region between the peripheral region and the central region, the length of the restricted portions of the flow arranging holes positioned in the peripheral region of the flow arranging plate is longer than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the central region of the flow arranging plate and the length of the restricted portions of the flow arranging holes positioned in the intermediate region is not longer than the length of the restricted portions of the flow arranging holes positioned in the peripheral region and not shorter than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the central region.
- 5. A melt spinning pack, according to claim 2, wherein the form of the top surface of the flow arranging plate is upwardly conical or pyramidal and the form of the bottom surface of the pack cap is conical or pyramidal to respond to the conical or pyramidal top surface of the flow arranging plate, with the first space formed between the two conical or pyramidal faces.
- 6. A melt spinning pack, according to claim 2, wherein an integral filter plate formed by an integral filter medium is provided in the first or second space.
- 7. A melt spinning pack, according to claim 2, wherein the space thickness of the second space is about 1 to about 60 mm.
- 8. A melt spinning pack, according to claim 1, wherein the inner peripheral face of the cylindrical pack case, the outer peripheral face of the flow arranging plate and the outer peripheral face of the pack cap are respectively circular in cross sectional form.
- 9. A melt spinning pack, according to claim 8, wherein the flow arranging holes are positioned in such a manner that the centers of the flow arranging holes are positioned on a hole positioning circle described around the center of the top surface of the flow arranging plate, or positioned at the center of the top surface of the flow arranging plate and on a hole positioning circle described around said center.
- 10. A melt spinning pack, according to claim 9, wherein a plurality of concentric hole positioning circles are described instead of said one hole positioning circle.
- 11. A melt spinning pack, according to claim 10, wherein the number of flow arranging holes positioned on a hole positioning circle described in the peripheral region of the flow arranging plate is larger than the number of flow arranging holes positioned on a hole positioning circle described in the central region of the flow arranging plate.
- 12. A melt spinning pack, according to claim 11, wherein, if flow arranging holes are positioned only in an innermost central region and on an outermost hole positioning circle, the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle of the flow arranging plate is smaller than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region of the flow arranging plate, and if there is an intermediate hole positioning circle between the outermost hole positioning circle and the innermost central region, the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle of the flow arranging plate is smaller than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region of the flow arranging plate and the cross sectional area of the restricted portions of the flow arranging holes positioned on the intermediate hole positioning circle is not smaller than the cross sectional area of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle and not larger than the cross sectional area of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region.
- 13. A melt spinning pack, according to claim 11 or 12, wherein, if flow arranging holes are positioned only in an innermost central region and on an outermost hole positioning circle, the length of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle of the flow arranging plate is longer than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region of the flow arranging plate, and if there is an intermediate hole positioning circle between the outermost hole positioning circle and the flow arranging hole(s) positioned in the innermost central region, the length of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle of the flow arranging plate is longer than the length of the restricted portion(s) of the flow arranging hole(s) positioned on the innermost central region of the flow arranging plate and the length of the restricted portions of the flow arranging holes positioned in the intermediate hole positioning circle is not longer than the length of the restricted portions of the flow arranging holes positioned on the outermost hole positioning circle and not shorter than the length of the restricted portion(s) of the flow arranging hole(s) positioned in the innermost central region.
- 14. A melt spinning pack, according to claim 11, wherein the form of the top surface of the flow arranging plate is upwardly conical or pyramidal, and the form of the bottom surface of the pack cap is conical or pyramidal to respond to the conical top surface of the flow arranging plate, with the first space formed between the two conical surfaces.
- 15. A melt spinning pack, according to claim 11, wherein an integral filter medium is provided in the first or second space.
- 16. A melt spinning pack, according to claim 8, wherein the space thickness of the second space is about 1 to about 60 mm.
- 17. A method for producing synthetic fibers, characterized by using the melt spinning pack stated claim 1, introducing a molten polymer form the polymer introducing hole of the pack cap, spinning many filaments from the spinning holes of the spinneret and cooling the filaments to form a yarn.
- 18. A method for producing synthetic fibers, characterized by using the melt spinning pack stated claim 8, introducing a molten polymer from the polymer introducing hole of the pack cap, spinning many filaments from the spinning holes of the spinneret and cooling the filaments to form a yarn.
- 19. A method for producing synthetic fibers, according to claim 17 or 18, wherein the molten polymer is a polyester containing an electro-control agent.
- 20. A melt spinning pack, according to claim 1, wherein a flow arranging hole is positioned at the center of the flow arranging plate and satisfying the following formula:0.5≦(Ln/Tn)/(2×Lo/do)≦2.5, where: Tn={square root over ( )}(3×Nn×dn4/32/Dn), do=hole diameter of the restricted portion of the flow arranging hole positioned at the center of the flow arranging plate; Lo=length of the restricted portion of the flow arranging hole positioned at the center of the flow arranging plate; dn=hole diameter of the restricted portions of the flow arranging holes positioned on the nth hole positioning circle from the center of the flow arranging plate; Ln=length of the restricted portions of the flow arranging holes positioned on the nth hole positioning circle from the center of the flow arranging plate; Dn=diameter of the nth hole positioning circle from the center of the flow arranging plate; and Nn=number of the flow arranging holes positioned on the nth hole positioning circle from the center of the flow arranging plate.
- 21. A melt spinning pack, according to claim 1, wherein flow arranging holes are positioned only on concentric hole positioning circles located a distance D away from the center of the flow arranging plate and satisfying the following formula:0.5≦(Ln/Tn)/(Ll/Tl)≦2.5, where: Tn=3(3×Nn×dn4/32/Dn), T1=3(3×N1×d14/32/D1), d1=hole diameter of the restricted portions of the flow arranging holes positioned on the innermost hole positioning circle of the flow arranging plate; L1=length of the restricted portion of the flow arranging hole positioned on the innermost hole positioning circle of the flow arranging plate; D1=diameter of the innermost hole positioning circle of the flow arranging plate; N1=number of the flow arranging holes positioned on the innermost hole positioning circle of the flow arranging plate; dn=hole diameter of the restricted portions of the flow arranging holes positioned on the nth hole positioning circle from the center of the flow arranging plate; Ln=length of the restricted portions of the flow arranging holes positioned on the nth hole positioning circle from the center of the flow arranging plate; Dn=diameter of the nth hole positioning circle from the center of the flow arranging plate; and Nn=number of the flow arranging holes positioned on the nth hole positioning circle from the center of the flow arranging plate.
- 22. A melt spinning pack, according to claim 5, wherein an angle ∝ of vertex of the conical or pyramidal top surface of the flow arranging plate satisfies the following formula:100°≦∝≦180°.
- 23. A melt spinning pack, according to claim 1, further comprising a first integral filter plate positioned above said spinneret and below said flow arranging plate.
- 24. A melt spinning pack, according to claim 23, further comprising a second integral filter plate positioned above said flow arranging plate.
- 25. A melt spinning pack, according to claim 23 or claim 24, wherein said first integral filter plate is a nonwoven fabric of metal fibers.
- 26. A melt spinning pack, according to claim 25, wherein said metal fibers have a diameter in the range of 5-50 μm.
- 27. A melt spinning pack, according to claim 24, wherein said second integral filter plate is a nonwoven fabric of metal fibers.
- 28. A melt spinning pack, according to claim 27, wherein said metal finers have a diameter in the range of 5-200 μm.
- 29. A melt spinning pack, according to claim 25, wherein said metal fibers have an areal unit weight in the range of 50-2000 g/m2.
Priority Claims (1)
Number |
Date |
Country |
Kind |
10-94934 |
Apr 1998 |
JP |
|
PCT Information
Filing Document |
Filing Date |
Country |
Kind |
102e Date |
371c Date |
PCT/JP99/01531 |
|
WO |
00 |
12/6/1999 |
12/6/1999 |
Publishing Document |
Publishing Date |
Country |
Kind |
WO99/51798 |
10/14/1999 |
WO |
A |
US Referenced Citations (3)
Foreign Referenced Citations (4)
Number |
Date |
Country |
39-24309 |
Oct 1964 |
JP |
43-7734 |
Apr 1969 |
JP |
47-21249 |
Jun 1972 |
JP |
53-34018 |
Mar 1978 |
JP |